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CLS Aipmt-17-18 XII Che Study-Package-5 SET-2 Chapter-5 PDF
CLS Aipmt-17-18 XII Che Study-Package-5 SET-2 Chapter-5 PDF
Surface Chemistry
Solutions
SECTION - A
Objective Type Questions
1. Which one of the following is a property of physisorption?
(1) Non-specific nature (2) High specificity (3) Irreversibility (4) Single layer adsorption
Sol. Answer (1)
Physisorption is non-specific, reversible, multilayred.
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228 Surface Chemistry Solution of Assignment (Set-2)
6. The graph plotted against adsorption versus pressure P at constant temperature, the Freundlich equation at
points A, B, C respectively are (if n > 1)
C
B
x
m A
p
x x 1 x x x x 1
(1)
kp,
kp n , kp 0 (2)
kp, kp n ,
kp n
m m m m m m
x 1 x x 1 x x 1 x
(3)
kp n , kp n ,
kp n (4) kp ,
kp n , kp n
m m m m m m
Sol. Answer (1)
x
A, linear kp [n = 1]
m
x
B, curve kp1/n [n 1]
m
x
C is independent of pressure.
m
x
= kp0 = k [n ]
m
x
7. The intercept on Y-axis in the graph of log versus log P gives
m
1
(1) (n > 1) (2) k (3) log k (4) Temperature
n
Sol. Answer (3)
x
kp1/n
m
x
log k 1 log P
log
m n
c x
y m
intercept
x x x x
log log log
(1) log (2) m (3) m (4) m
m
log P log P log P log P
x 1
log = n
m
log K
log P
10. In adsorption from solution phase, the Freundlich adsorption isotherm is modified as
x x x x
(1) k.T1/n (2) R.T1/n (3) nkP1/n (4) kC1/n
m m m m
Sol. Answer (4)
Pressure is replaced by concentration term.
14. Which of the following processes best describes the purification of muddy water by addition of alum?
(1) Absorption (2) Coagulation (3) Dialysis (4) Electrodialysis
Sol. Answer (2)
Alum coagulates the impurities present in muddy water, which settles down.
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230 Surface Chemistry Solution of Assignment (Set-2)
1
Protecting power
Gold number
20. Movement of colloidal particles under the influence of electric field is called
(1) Electrophoresis (2) Dialysis (3) Ionisation (4) Electrodialysis
Sol. Answer (1)
Fact.
22. Gelatin is often used as an ingredient in the manufacture of ice-cream. The reason for this is
(1) To prevent the formation of a colloid (2) To stabilize the colloid and prevent crystal growth
(3) To cause the mixture to solidify (4) To improve the flavour
Sol. Answer (2)
Fact.
26. The potential difference between the fixed charged layer and the diffused layer having opposite charge is called
(1) Zeta potential (2) Streaming potential (3) Dorn potential (4) Colloidal potential
Sol. Answer (1)
Definition (Fact)
27. When dilute aqueous solution of AgNO3 (excess) is added to KI solution, positively charged sol particles of
AgI are formed due to adsorption of ion
(1) K+ (2) Ag+ (3) I– (4) NO3–
Sol. Answer (2)
Ag+ ion is adsorbed on AgI.
Ag
Ag Ag
Ag AgI Ag
Ag Ag
Ag
28. In the preparation of AgI sol, AgNO3 is added to excess of potassium iodide solution. The particles of the sol
will acquire
(1) Negative charge (2) Positive charge (3) No charge (4) Unpredictable
Sol. Answer (1)
Concentration of I– ion is much larger than Ag+.
I– is adsorbed on AgI solution forming negative solution.
29. Which of the following method is not employed for the purification of colloids?
(1) Electrodialysis (2) Dialysis (3) Ultracentrifugation (4) Peptisation
Sol. Answer (4)
Peptisation : It is process of formation of colloidal solution.
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232 Surface Chemistry Solution of Assignment (Set-2)
30. During purification of colloidal sol by ultracentrifugation which of the following is observed?
(1) Colloidal particles are settled at the bottom of ultracentrifuge tube
(2) Impurities are settled at the bottom of the ultracentrifuge tube
(3) Impurities are removed through ultrafilters
(4) Its rate can be increased by applying pressure
Sol. Answer (1)
Due to centrifugal force, colloidal particles are settled at the bottom of ultracentrifuge rule.
Ag+
+
Ag Ag+
Ag+ Ag+
+
Ag
32. Which of the following is with highest and lowest flocculation value among Al+3, Na+, Mg+2, Ba+2?
(1) Al+3, Na+ (2) Na+, Al+3
(3) Ba+2, Al+3 (4) They have same flocculation value
Sol. Answer (2)
1
Flocculation value
Total charge an cation/anion
33. Most effective coagulant for a colloidal solution of arsenic sulphide in water is
(1) 0.1 M sodium phosphate (2) 0.1 M zinc sulphate
(3) 0.1 M zinc nitrate (4) 0.1 M aluminium chloride
Sol. Answer (4)
As2S3 is a negative colloid and to coagulate it, positive cation which highest charge is required.
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Solution of Assignment (Set-2) Surface Chemistry 233
35. Colloidal particles in soap sol carry
(1) Negative charge (2) Positive charge
(3) No charge (4) Either positive or negative charge
Sol. Answer (1)
Fact.
36. Which of the following metallic sols cannot be prepared by Breding’s arc method?
(1) Gold (2) Silver (3) Platinum (4) Sodium
Sol. Answer (4)
Solution of inert metal are prepared by breeding arc method.
39. When FeCl3 solution is added to NaOH a negatively charged sol is obtained. It is due to the
(1) Presence of basic group (2) Preferential adsorption of OH– ions
(3) Self dissociation (4) Electron capture by sol particles
Sol. Answer (2)
FeCl3 + NaOH Fe2O3.xH2O/OH–
[Concentration of OH– ion is large and in case of cold NaOH solution, negatively charged solution is formed.]
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234 Surface Chemistry Solution of Assignment (Set-2)
SECTION - B
Previous Year Questions
1. The coagulation values in millimoles per litre of the electrolytes used for the coagulation of As2S3 are given
below : [NEET-Phase-2-2016]
I. (NaCl) = 52
II. (BaCl2) = 0.69
III. (MgSO4) = 0.22
The correct order of their coagulating power is
(1) I > II > III (2) II > I > III (3) III > II > I (4) III > I > II
Sol. Answer (3)
1
Coagulating power
Coagulation value
2. Which one of the following characteristics is associated with adsorption? [NEET-2016]
(1) G and S are negative but H is positive (2) G is negative but H and S are positive
(3) G, H and S all are negative (4) G and H are negative but S is positive
Sol. Answer (3)
Adsorption is a spontaneous process with release in energy and decreases the randomness of adsorbed
substance
G, H & S all are negative.
3. Fog is a colloidal solution of [NEET-2016]
(1) Gas in gas (2) Liquid in gas (3) Gas in liquid (4) Solid in gas
Sol. Answer (2)
Fact.
4. Which property of colloidal solution is independent of charge on the colloidal particles? [AIPMT-2015]
(1) Tyndall effect (2) Coagulation (3) Electrophoresis (4) Electro-osmosis
Sol. Answer (1)
5. Which property of colloids is not dependent on the charge on colloidal particles? [AIPMT-2014]
(1) Coagulation (2) Electrophoresis (3) Electro-osmosis (4) Tyndall effect
Sol. Answer (4)
6. Which of the following statements is correct for the spontaneous adsorption of a gas? [AIPMT-2014]
(1) S is negative and, therefore, H should be highly positive
(2) S is negative and therefore, H should be highly negative
(3) S is positive and, therefore, H should be negative
(4) S is positive and, therefore, H should also be highly positive
Sol. Answer (2)
For a spontaneons process G should be negative.
7. Which one of the following statements is incorrect about enzyme catalysis? [AIPMT (Prelims)-2012]
(1) Enzymes are denaturated by ultraviolet rays and at high temperature
(2) Enzymes are least reactive at optimum temperature
(3) Enzymes are mostly proteinous in nature
(4) Enzyme action is specific
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Solution of Assignment (Set-2) Surface Chemistry 235
Sol. Answer (2)
Reactivity of enzymes are temperature dependent and they are most reactive at optimum temperature.
8. In Freundlich Adsorption isotherm, the value of 1/n is [AIPMT (Prelims)-2012]
(1) 1 in case of physical adsorption (2) 1 in case of chemisorption
(3) Between 0 and 1 in all cases (4) Between 2 and 4 in all cases
Sol. Answer (3)
1
x
kp n ; where n is the number of layers adsorbed.
m
n = 1, 2, 3...
1 1 1
& = 1, , ,...0
n 2 3
9. The protecting power of lyophilic colloidal sol is expressed in terms of [AIPMT (Prelims)-2012]
(1) Critical miscelle concentration (2) Oxidation number
(3) Coagulation value (4) Gold number
Sol. Answer (4)
Fact.
10. If x is amount of adsorbate and m is amount of adsorbent, which of the following relations is not related to
adsorption process? [AIPMT (Prelims)-2011]
x
(1) pT (2) x/m = f(p) at constant T
m
(3) x/m = f(T) at constant P (4) p = f(T) at constant (x/m)
Sol. Answer (1)
1
x x
kp n so, p T is invalid
m m
11. The Langmuir adsorption isotherm is deduced using the assumption [AIPMT (Prelims)-2007]
(1) The adsorbed molecules interact with each other
(2) The adsorption takes place in multilayers
(3) The adsorption sites are equivalent in their ability to adsorb the particles
(4) The heat of adsorption varies with coverage
Sol. Answer (3)
FACT
12. A plot of log x/m versus log p for the adsorption of a gas on a solid gives a straight line with slope equal to
[AIPMT (Prelims)-2006]
1
(1) – log k (2) n (3) (4) log k
n
Sol. Answer (3)
x
∵ = k × P1/n
m
x 1
log = logk + logP
m n
13. Which one of the following forms micelles in aqueous solution above certain concentration?
[AIPMT (Prelims)-2005]
(1) Urea (2) Dodecyl trimethyl ammonium chloride
(3) Pyridinium chloride (4) Glucose
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236 Surface Chemistry Solution of Assignment (Set-2)
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Solution of Assignment (Set-2) Surface Chemistry 237
21. Position of non polar and polar part in micelle
(1) Polar at outer surface but non polar at inner surface (2) Polar at inner surface non polar at outer surface
(3) Distributed over all the surface (4) Are present in the surface only
Sol. Answer (1)
Polar part interact with H2O molecule which polar solvent [like dissolves like].
22. According to the adsorption theory of catalysis, the speed of the reaction increases because
(1) The concentration of reactant molecules at the active centres of the catalyst becomes high due to
adsorption
(2) In the process of adsorption, the activation energy of the molecules becomes large
(3) Adsorption produces heat which increases the speed of the reaction
(4) Adsorption lowers the activation energy of the reaction
Sol. Answer (4)
Function of catalyst is to reduce activation energy, so that rate of reaction increases.
P.E Ea Eb < Ea
Eb (in presence
of catalyst)
23. Which of the following forms cationic micelles above certain concentration?
(1) Sodium dodecyl sulphate (2) Sodium acetate
(3) Urea (4) Cetyltrimethylammonium bromide
Sol. Answer (1)
Large alkyl part with positive polar end.
SECTION - C
Assertion - Reason Type Questions
1. A : AgI changes to negatively charged colloidal solution in presence of KI.
R : It is due to adsorption of I– on AgI.
Sol. Answer (1)
I– is adsorb on the surface of AgI, due to its high concentration.
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238 Surface Chemistry Solution of Assignment (Set-2)