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Diethanolamine Functionalized Waste Tea Activated Carbon For CO2 Adsorption
Diethanolamine Functionalized Waste Tea Activated Carbon For CO2 Adsorption
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International Conference on Chemical, Environmental and Biological Sciences (CEBS-2015) March 18-19, 2015 Dubai (UAE)
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International Conference on Chemical, Environmental and Biological Sciences (CEBS-2015) March 18-19, 2015 Dubai (UAE)
variation are shown in Fig. 3. Rapid attainment of MWTAC > UWTAC. The clear distinction and better
breakthrough point (135 s) was observed at high feed flow rate adsorption observed with amine modified adsorbent
(150 mL/min) which was attributed to fast preponderance of (MWTAC) was attributed to dual (chemical and physical)
numerous molecules contact to the static or inelastic vacant sorption through formation of bicarbonate and carbamate and,
sites of the adsorbent. Whereas, gradual and longer time of permeation of CO2 molecules to the pores; unlike the UWTAC
breakthrough point (900 s) attainment was associated with the adsorption that was probably physically based [3,18].
low feed flow rate (90 mL/min). Low feed flow rate may have
created or given room for ample residence time thereby
enabling chronological adsorption of CO2 molecules
enormously. It has also been observed by other researchers
also that concurrent reduction of CO2 adsorption and
breakthrough time occurs at higher influent flow rate of the gas
[18].
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International Conference on Chemical, Environmental and Biological Sciences (CEBS-2015) March 18-19, 2015 Dubai (UAE)
IV. CONCLUSION [17] Tan, I.A.W., Ahmad, A.L., Hameed, B.H. 2008. Adsorption of basic
dye using activated carbon prepared from oil palm shell: batch and
Modification of mesoporous waste tea activated fixed bed studies. Desalination, 225(1–3), 13-28.
carbon with diethanolamine was successfully carried out and [18] Lee, C.S., Ong, Y.L., Aroua, M.K., Daud, W.M.A.W. 2013.
used for the adsorption of carbon dioxide from gaseous Impregnation of palm shell-based activated carbon with sterically
hindered amines for CO2 adsorption. Chemical Engineering Journal,
mixture (CO2 and N2). The 1.0 M MWTAC adsorbent 219, 558-564.
removed CO2 from the fluid in both physical and chemical
processes (physisorptive). The optimum conditions for
adsorbing CO2 were at adsorption column temperature of 30
o
C, 10 % CO2 feed concentration, 90 mL/min influent fluid
flow rate, 3 g adsorbent (1-2 mm particle sizes) dosage.
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