Test 04 - FST 4 - 23 03 20 - Adv Paper 1 PDF

JEE ADVANCED PATTERN
FST-4 (23-03-2020)
Time: 3 Hours LEADER & ENTHUSE (SCORE-3) Maximum Marks: 180
PAPER-1 WITH SOLUTION

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Some Useful Data
Quantity Values
Constant of gravitation 6.67259 × 10–11 N-m2 kg–2
Speed of light in vacuum 2.99792458 × 108 m s –1
Avogadro constant 6.0221367 × 1023 mol–1
Gas constant 8.314510 JK–1-mol–1
Boltzmann constant 1.380658 × 10–23 JK–1
8.617385 × 10–5 eV K–1
Stefan-Boltzmann constant 5.67051 × 10–8 W m–2 - K–4
Wien’s displacement law constant 2.897756 × 10–3 m -K
Charge of proton 1.60217733 × 10–19 C
Mass of electron 9.1093897 × 10–31 kg
5.48579903 × 10–4 u
Mass of proton 1.6726231 × 10–27 kg
1.007276470 u
Permeability of vacuum 4 × 10–7 NA–2
Permittivity of vacuum 8.854187817 × 10–12 C2 N–1 m–2
Faraday constant 96485.3029 C mol–1
Planck constant 6.6260755 × 10–34 J-s
4.1356692 × 10–15 eV-s
PAPER-1
PART-I : PHYSICS
SECTION-I : One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE THAN ONE may be correct. You will be awarded 4 marks if all the
correct option(s) is/are chosen and zero mark if none of the option is chosen. For each correct answer
+1 mark will be awarded if no incorrect option is chosen. In all other cases minus two (–2) mark will be
awarded.

1. Consider one mole of an ideal gas whose volume changes with temperature as V  , where  is
T
a constant. Heat is supplied to the gas to raise its temperature by T. If adiabatic constant then
choose the correct options.
(A) The work done in the process is RT
(B) The work done in the process is –RT
R T
(C) Change in internal energy of gas is
 –1
RT
(D) Change in internal energy of gas is –
 –1
2. A ray of light is incident normally on one face of a prism as shown in figure. The refractive index
5 4
of the material of the prism is and the prism is immersed in water of refractive index , then
3 3
Nucleus Education-Leader + Enthuse All (Score–3)_23032020
5
(A) The angle of emergence 2 of the ray is sin 1   .
8
 5 
(B) The angle of emergence 2 of the ray is sin 1  .
4 3
 7 
(C) The angle of emergence 2 of the ray is sin 1  .
3 4 
(D) Total internal reflection will not occur at P if the refractive index of water increases to a value
5
greater than by dissolving some substance
2 3
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PAPER-1
3. A block of mass M is suspended from a vertical spring of mass m as shown in the figure. When
block is pulled down and released the mass oscillates with maximum velocity v.
1
(A) Max kinetic energy of spring block system is (M m) v2
2
1 m
(B) Max kinetic energy of spring block system is  M  v2
2 3
mv 2
(C) Max kinetic energy of spring is
6
mv 2
(D) Max kinetic energy of spring is
2
4. The upper end of the string of a simple pendulum is fixed to a vertical z-axis and set in motion such
that the bob moves along a horizontal circular path of radius 2 m, parallel to the xy plane, 5m above
the origin. The bob has a speed of 3 m/s. The string breaks when the bob is vertically above the
x-axis, and it lands on the xy plane at a point (x, y)
(A) x = 2 m (B) x > 2 m (C) y = 3 m (D) y = 5 m
PAPER-1
5. Figure shows a container filled with a liquid of density . Four points A, B, C and D lie on the
vertices of a vertical square. Points A and C lie on a vertical line and points B and D lies on a
horizontal line. Choose the correct statement(s) about the pressure at the four points.
(A) PD = PB (B) PA< PB = PD< PC

PC  PA PC  PA
(C) PD = PB = (D) PD = PB =
2 2
6. The circuit shown is in steady state
Choose the correct options :

(A) charge on 1 F capacitor is same as charge on 3 F capacitor
(B) charge on 2 F capacitor is 2 C
(C) current through the battery is 2A
(D) current is same in each external resistance
SECTION-II : Integer Value Correct Type

This section contains 8 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
7. A point electric dipole of dipole moment P = 81 × 10 –9 C-m is placed in the uniform external field
of magnitude E0 = 27 N/c such that p || E0 . In this case one of the equipotential surfaces enclosing
the dipole forms a sphere with dipole at centre. The radius of this sphere is R in metres. Find the
value of R.
8. In an -decay the Kinetic energy of  particle is 48 MeV and Q-value of the reaction is 50 MeV.
The mass number of the mother nucleus is 20A. Find the value of A. (Assume that daughter
nucleus is in ground state).
9. A metal of threshold frequency 0 is illuminated by radiations of frequency 20 and 40, one after
another. If 1 and 2 are respective minimum de-Broglie wavelength of emitted electrons in the
1
two cases, then  n. Find n :
2
PAPER-1
10. Three blocks A, B and C having masses m kg, 2 kg and 3 kg are attached by massless strings and
ideal pulleys as shown in the figure. When the system is released from rest if the block ‘A remains
stationary, the mass of block ‘A’ is (in kg)
11. Two isosceles prism of prism angle A and refractive index  are placed with their bases touching
each other. This system can act as a crude converging lens. The focal length of the lens for,
A = 100,  = 1.5 and a ray of light incident on a prism at a height of 1 cm from its base, is
approximately.
h=1cm
12. A right-angled prism ABC is immersed in a liquid of refractive index 4\3 incident and emergent
rays are parallel as shown. The minimum value of refractive index of prism.
A
90°
B C
13. During an adiabatic process, the pressure of a gas is found to be proportional to the cube of its
Cp
temperature. The ratio of for the gas is :
Cv
14. Meter bridge is used to find resistance of a wire using a standard resistance 20  with 0.5%
tolerance. The unknown resistance is placed in left gap of the meter bridge. The null point is
obtained at 60.0 cm from left end. The maximum permissible error in this measurement is 0.1 cm.
Find the maximum error in measurement of the resistance.
PAPER-1
SECTION-III : Paragraph Type
This section contains 2 Paragraphs each describing theory, experiment and data etc. Six questions relate
to two paragraphs with two questions on each paragraph. Each question of a paragraph has
ONLY ONE is correct answer among the four choices (A), (B), (C) and (D). You will be awarded
3 marks if only the correct option is chosen and zero mark if none of the option is chosen. (–1) marks
will be awarded for incorrect answers in this section.
Paragraph for question nos. 15 & 16
A solid sphere of radius r and mass m is projected vertically downward
in a viscose liquid with velocity 3v0. The density of ball is 2 and that
of liquid is . After long time the ball is moving downward with
3V
constant velocity v0.
Fnet = Net force on the ball V
Fv = Viscose force on the ball

P = Power of gravitation force
15. Correct graph to show variation of various quantities with time is :

Fv Fv
(A) (B)
time time
P
Fnet
(C) (D)
time time
16. Which of the following is correct statements :

mg
(A) The coefficient of viscosity of the liquid is
rv0
(B) Drag force at initial moment is 2 mg
(C) Drag force when ball is moving with constant velocity is 3mg
(D) Magnitude of initial acceleration is g
PAPER-1
Two coherent point sound sources S1 and S2 are placed as shown in the figure. Both are emitting
sound of frequency 165 Hz. S1 is ahead of S2 in phase by -radian. (Speed of sound is 330 m/s)
17. How many times maximum sound can be observed on line AB :

(A) 7 (B) 6 (C) 5 (D) None of these
18. If power of sources are same and equal to 7200  watt. Resultant intensity (in watt/m2) at point B
will be :
(A) ( 50  18)2 (B) ( 30  18)2 (C) ( 50  18)2 (D) None of these

PAPER-1
PART-II : MATHEMATICS
awarded.
19. Consider ƒ : R → R satisfying the equation ƒ(x + y) = ƒ(x – y) + ƒ(x).ƒ(y) ∀ x, y ∈ R. Identify the
correct statement(s)
π
(A) ƒ(2014) + ƒ(2015) = ƒ(2016) (B) sin–1 (ƒ(2)) + cos–1 (ƒ(3)) =
2
π
(C) ƒ(2014) – ƒ(2015) = ƒ(2016) (D) sin–1 (ƒ(3)) + cos–1 (ƒ(2)) =
2
 x{x}2 x∉I
20. Let ƒ(x) =  , where [x], {x} denotes greatest integer function and fractional part
[x] x∈I
function respectively. In x ∈ [0, 5], which of the following statement(s) is/are correct ?
(A) ƒ(x) is discontinuous at 4 points in [0, 5]
(B) Jump of discontinuity at x = 3 is 3.
 9  19
(C) ƒ'   =
2 4
(D) RHD at x = 4 is equal to zero
cos3 x + cos5 x π

21. If ∫ (1 − cos2 x)(2 − sin 2 x) dx =

F(x) + C, F   =
2
0 , where C is arbitrary constant, then-
(A) F(x) ≤ 0 ∀ x ∈ (0, π) (B) F(x) ≥ 0 ∀ x ∈ (0, π)

(C) F(x) ≥ 4∀ x ∈ (π, 2π) (D) F(x) ≤ 4 ∀ x ∈ (π, 2π)
 −π π 
22. Let ƒ : (0, ∞) →  ,  be a function defined as ƒ(x) = tan–1 (n x) and g be the inverse function
 2 2
of ƒ, then
(A) g'(0) = g"(0) ≠ –1 (B) ƒ'(1) = g'(0)
(C) ƒ"(1) = –1 (D) g"(0) = – 1
23. Gradient of the line passing through the point (2, 8) and touching the curve y = x3, can be
(A) 3 (B) 6 (C) 9 (D) 12
7 7
PAPER-1
24. We have 19 identical gems available with us which are needed to be distributed among A, B and C
such that A always gets an even number of gems. The number of ways this can be done is P, then
the value of P is greater than or equal to
(A) 72 (B) 92 (C) 100 (D) 110

2x 2
25. Sum of values of x, for which ƒ(x) = ∫ (t − 2)(t + 1)3 (t − 3) 2 dt has local maxima ?
0
26. Minimum value of 7sin2x + 10cosec2x – 9, x ≠ nπ (n ∈ I) will be
x n (a + sin(x n )) + (b − sin(x n ))
27. Let ƒ(x) = lim is continuous at x = 1, then (a + b + 1) is
n →∞ (1 + x n ) sec(tan −1 (x n + x − n ))
28. The x intercept of the tangent to a curve F(x,y) = 0 is equal to the ordinate of the point of contact.
d2x
The value of at the point (1, 1) on the curve is
dy 2
29. ƒ : [0, 1] → R and also x, y ∈ [0, 1], such that xƒ(y) + yƒ(x) ≤ 1 then maximum value of
1
ƒ(x)
12 ∫ dx is equal to
0
π
30. Cosine of the acute angle between the curves y = 3x–1.log e x and y = xx – 1 is-
31. If y bx + 3 , b > 0 is the equation of a common tangent of the circle (x – 3)2 + y2 = 9 and the
3=
parabola y2 = 4x, then the value of 'b' is
32. The greatest value of the term independent of x in the expansion of [x sin α + (cosα/x)]20 as α is
real is 20C 10 2–β . Then the value of β will be
8 8
PAPER-1


1 1  π
If sinA + sinB = & cosA + cosB = where A, B∈  0,  .
4 3  2
(A + B)
33. The value of sin equals
2
3 4 3 4
(A) (B) (C) (D)
4 5 5 3
3(A + B) 
34. The value of tan   can be
 2 
107 77 97 117
(A) − (B) (C) (D) −
44 44 44 44
Position vectors of points A and B are 2iˆ + ˆj − 2k,

ˆ ˆi + ˆj respectively. Point C is such that AC is
perpendicular to OC(O is origin). AC = 2 2 , BC = 1 and C does not lie in xy-plane.

35. OC is equal to
1 3
(A) (B) 1 (C) (D) 2
2 2
     

36. OA × OB + OB × OC + OC × OA is equal to
(A) 1 (B) 4 (C) 2 (D) 9
9 9
PAPER-1
PART-III : CHEMISTRY
awarded.
37. Which of the following reaction will produce chlorobenzene as a major product?
(A) C6H5NH2 
NaNO2
HCl;0C
 
Heat
 (B) C6H5NH2 
NaNO2
HCl;0C
 
CuCl

(C) C6H6 + C6H5COCl 
AlCl3
 (D) C6H6 + Cl2 
hv

38. Angular part of a wave function is given as

1
 15  2
X  ,  =   sin 2  cos 2 , Which of the following is correct for the given equation :
 4 
(A) Orbital has two angular nodes
(B) Nodal planes are found in xy and yz planes
(C) Equation belongs to d x 2  y2 orbital
(D) Equation represents 3dxy
39. Select the CORRECT statement(s) about Contact process ?

(A) V2O5 is used as a catalyst.
(B) It is commercially used to prepare oleum.
(C) H2SO4 is obtained by hydrolysis of SO3 gas
(D) H2SO4 is obtained by hydrolysis of H2S2O7
–5
40. To 100 ml of an aqueous solution of 0.1 M CH3COOH (Ka = 2 × 10 ), 0.01 mol of HCl(g) is
passed. Select correct options regarding the resulting solution.
–4
(A) Degree of dissociation of acetic acid in resulting solution is 10
(B) pH of resulting solution is nearly 1
–15
(C) Degree of dissociation of water in resulting solution is 1.8 × 10
– –7
(D) Concentration of OH ions contributed by water is resulting solution is 10 M.
41. Which of the following reagent(s) can be used for protection of amine (–NH2) group of aniline
during electrophilic aromatic substitution reaction and that too without changing orientational
effect ?
(A) (CH3CO)2O (B) C6H5SO2Cl (C) KMnO4/OH– (D) C6H5COCl
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PAPER-1
42. Consider a PV diagram for reversible isothermal process carried out on an ideal gas. Which of the
following quantities can be obtained from area under the curve, projected on volume axis ?
(A) |G| (B) WPV (C) q (D) TΔS

43. How many compounds will require only 3 moles of HIO4 for complete reaction :
OH O NH2
OH
(1) OH O (2) O O (3) O O
OCH3 NH2
OH O
OH OH
O
(4) (5) (6)
O OH OCH3
OH OH
44. For a first order sequential reaction, A 

k1
 B 
k2
C , k1 = 2.31 × 10–3 s–1 and
k2 = 1.1 × 102 s–1 and initial molar concentration of A is 2.0 M. The molar concentration of C at
time t = 15 min is : (ln2 0.69)
45. NH4NO3   ‘X’ + H2O

Oxidation state of N in compound ‘X’ is -
46. Which of the following reactions are correctly matched with its major product :
(1) Ph–CCH   PhCH2CHO

1%HgSO4 HCl
dil.H2SO4
(2) CH2 CCl4
Cl
Me
H2SO4
Br2 H Br
(3) (4) CCl4 H Br

OH OH O Me
(i) MeCl (excess) Cl alc. KOH
(5) Ph Ph (6)
(ii) AgOH 
NH2 (iii) 
PAPER-1
47. Find out bond enthalpy of C = O (in kJ/mol) using following informations :
Hatomisation [Cgraphite,s] = 700 kJ/mol
Hf [CO2, g] = – 400 kJ/mol
BE(O=O) = 500 kJ/mol
Resonance energy of CO2 = – 200 kJ/mol
48. How many anions will give colourless acid vapour / gas with conc. H 2SO4 on reaction with
following given anions ?
CH3COO– , Cl– , Br– , S2– , SO32–, BO33– , NO2–, C2O42– , I–
49. The pKa values of H3PO4 are 2.12, 7.21 and 12.67 Calculate the pH of resulting solution formed
by mixing 0.1M, 100 mL H3PO4 aqueous solution with 0.1M 200 mL Na3PO4 aqueous solution.
50. Find the number of complexes which are paramagnetic in nature.

[NiCl4]–2, [PtCl4]–2, [IrF6]–3, [Ag(NH3)2]+, [Fe(H2O)6]+2, [Co(H2O)6]+3


+3
Presence of Fe in an aqueous solution can be made by addition of sodium acetate (in excess)
when a reddish brown colour is formed.

Read the above short write up & answer the following question–
51. Reddish brown colour is due to formation of–
(A) [Fe(H2O)4(CH3COO)2]+ (B) [Fe(CH3COO)6]3–
(C) Fe(OH)2(CH3COO) (D) [Fe2(H2O)4(CH3COO)4]2+
52. Excess of sodium acetate is added in the above test. It is because –

(A) It act as buffer to control pH of the reaction, otherwise reaction is made reversible
(B) It makes the solution alkaline which destroys acidic effect if any
(C) sodium acetate has low ksp value
(D) sodium acetate has high ksp values
PAPER-1
Consider the following reaction scheme to answer the next two questions.
OH
Cl
14
NaOH CH2–CH=CH–CH3
A
53. What is structure of A?

CH3
14
O–CH2–CH=CH–CH3 O–CH–CH=CH2
14
(A) (B)
OH OH
14
CH2–CH=CH–CH3
(C) (D)
CH3–CH–CH=CH 2
14
54. If A is heated to 200°C, the major product will be :

OH CH3 OH 14
CH–CH=CH2 CH2–CH=CH–CH3
14
(A) (B)
OH OH
(C) (D)
14
CH2–CH=CH–CH3 CH3–CH–CH=CH2
14
PAPER-1
ANSWER KEY & SOLUTION
PART-I : PHYSICS
1. BC 2. AD 3. BC 4. AC 5. ABD 6. ABCD 7. 3.00
8. 100.00 9. 3.00 10. 4.80 11. 11.5 12. 1.88/1.89 13. 1.5
14. 0.37 15. B 16. D 17. B 18. A
19. ABCD 20. ABC 21. AC 22. ABC 23. AD
24. ABC D 25. 0.00 26. 8.00 27. 1.00 28. 1.00
29. 3.00 30. 1.00 31. 1.00 32. 10.00 33. C
34. D 35. B 36. C
37. AB 38. ABC 39. AD 40. BC 41. ABD 42. ABCD 43. 2.00
44. 1.75 45. 1.00 46. 2.00 47. 700.00 48. 6.00 49. 9.94 50. 2.00
51. C 52. A 53. A 54. A
SOLUTION | PART-I : PHYSICS_PAPER-1 | JEE ADVANCED

1. (BC)

PV = nR  
V
R
P = 2
V
R
V2
W   Pdv  V 2
dv
V1
 1 1
= –R  2 –   –R(T2 – T1 ) = –RT
 V V1 
nR(T2 – T1 ) RT
U  
 –1  –1
2. (AD)
Initially at P, there is TIR, Therefore at Q (Snell’s law)
5 4
sin 30  sin 2
3 3
5 5
 sin 2   2  sin 1  
8 8
5 5/ 2 3
If w > sin C >  C > 60°
2 3 2/3
Therefore, now TIR will not occur at P.
PAPER-1
3. (BC)
If at any instant elongation in spring is x and velocity of block is v from equilibrium position then
2
1 2 1 2 1Lm v  1 1 1 m v 2 L3
ET  kx  Mv   dy  y  = kx2  Mv 2  ;
2 2 2 0 L L  2 2 2L L 3
1 1 m
ET  kx2   M   v 2
2 2 3
5. (ABD)
According to Pascal's law,
PB = PD
because B and D lie on the same horizontal plane.
Let l be the side of the square. Then the vertical distance between A and C is l 2 .
L
PB = PD = PC –g ....(i)
2
L
Similarly, PB = PD = PA + g ....(ii)
2
P P
PB = PD = A C
2
6. (ABCD)

– 0.5  + 6 – 5 =0
2
 = 2A
 q 
–  3 = 0
2 2 2
q = 2C.
7. (3.00)
E0 sin  = Et
kpsin 
E0 =
r3
1/3
 kp 
r=  
 E0 
k = 9 × 109
P = 81 × 10–9 cm
E0 = 27 N/c
1/3
 9 109  81109 
r=   = 3m.
 27 
PAPER-1
8. (100.00)
my
We have K = ×Q
my  m
A4 A4
  K = Q  48 = × 50  A = 100
A A
9. (3.00)
p 2max 1 h2
hv = hv0 + Kmax = hv0 + = h0 +
2m e 2me  min
2
h2
 1 =  0× 2  h0 =
2me .12
h2 1
2 = 40  3h0    3
2me . 22 2
10. (4.80)
FBD of ‘B’ and ‘C’
 T –2g = 2a .... (1)
and 3g – T = 3a .... (2)
For A T = mg
12g
2x  mg  m  4.8kg
5
11. (11.5)
h
For small angles tan   .
f 
h
Also tan  =  = ( – 1) A 
h
f
f
 1 A

100  radian
18
118
f  11.5 cm
0.5  3.14
12. (1.88/1.89)
  C , 90   C
So   450 
P sin 450   sin900 
 90   90  
P   2
sin 450
PAPER-1
13. (1.50)
P  T3
P = KT3
3
 PV 
P=K  
 nR 
P2V3 = constant ; PV3/2 = constant
C 3
= p 
Cv 2
16. (D)
(15 & 16)
mg
(A) 6rvo = 2mg – mg  =
6rv0
(B) FV = 6rv0= 3mg
(C) Find drag force = mg
(D) At initial moment
mg + 3mg – 2mg = ma
a=g
18. (A)
Phase difference at A is 9(S2 is lag in phase)
Phase difference at B is 3(S1 is lag in phase)
So, 6 times maximum sound can be observed from A to B.
7200
intensity at A, 1 =  18 watt/m2
4(10) 2
7200
intensity at B, 2 =  50 watt/m2
4(6)2
resultant intensity at B = 1 + 2 + 2 1 2 cos5 = ( 50  18)2 .
PAPER-1
19. [A,B,C,D]
Sol. At x = y = 0 : ƒ(0) = 0
At x = 0; ƒ (y) = ƒ(–y) ⇒ ƒ is even
replace y → – y :
ƒ(x – y) – ƒ(x + y) = ƒ(x). ƒ(–y)
∴ ƒ(x).ƒ(y) – ƒ(x). ƒ(–y)
⇒ ƒ(x) (ƒ(y) + ƒ(–y)) = 0
⇒ ƒ(x) = 0 or ƒ(y) = – ƒ(–y) (ƒ is odd)
∴ either ƒ(x) = 0 or ƒ(x) is simultaneously odd and even.
∴ ƒ(x) = 0 only.
20. [A,B,C]
 0 x=0
 x3 x ∈ (0,1)

 1 x =1
 2
 x(x − 1) x ∈ (1, 2)
 2 x=2
 2
f (x) =  x(x − 2) x ∈ (2,3)
 3 x=3
 2
 x(x − 3) x ∈ (3, 4)

 4 x=4
2
 x(x − 4) x ∈ (4,5)

 5 x=5
DC at x = 1, 2, 3, 4
At x = 3, jump of discontinuity = ƒ(3–) – ƒ(3+) = 3
9 d 9 19
( 2
)
x ( x − 4 ) at x =
ƒ ' 
= is
 2  dx 2 4
RHD at x = 4 DNE
21. [A,C]
cos3 x(1 + cos 2 x)
Sol. ∫ sin 2 x(2 − sin 2 x) dx
(1 − sin 2 x)(2 − sin 2 x)
= ∫ sin 2 x(2 − sin 2 x) cos xdx
Put sinx = t
1 − t2 1 π
⇒ F(x) = ∫ t 2 dt = − − sin x + C  F  = 0 ⇒ C = 2
sin x 2
 1 
⇒ F(x) = 2 −  sin x + 
 sin x 
18 18
PAPER-1
22. [A,B,C]
Sol. ƒ(x) = tan–1 (lnx)
⇒ g(x) = etan x
⇒ g'(x) = etan x . sec2 x
⇒ g''(x) = etan x . sec2 x (sec2 x + 2 tan x)
= etanx . sec2x (1 + tan x)2
⇒ g'(0) = 1 = g''(0)
⇒ ƒ '(0) = 1
⇒ ƒ ''(1) = –1
23. [A,D]
Sol. y' = 3x 1 2
x3 − 8
3x 1 2 = 1 ⇒ x 1 = –1 or 2
x1 − 2
y' = 3 or y' = 12
24. [A,B,C, D]
Sol. A + B + C = 19
Case I : If A = 0 then number of ways = 20C 1
Case II : If A = 2 then number of ways = 18C 1
Case III : If A = 4 then number of ways = 16C 1
: : : :
: : : :
Case X : If A = 18 then number of ways = 2C 1
∴ total no. of ways = 20C 1 + 18C 1 + 16C 1 + ...........+ 2C 1 = 110
25. [0.00]
Sol. ƒ '(x) = (2x2 – 2) (2x2 + 1)3 (2x2 – 3)2 4x = 8x (x – 1) (x + 1) (2x2 + 1)3 (2x2 – 3)2,
for (–1, 1)
ƒ '(x) = 8x(x – 1) (x + 1) ⇒ local maxima at x = 0
26. [8.00]
10
Sol. y = 7sin2x + −9
sin 2 x
y min lies at sinx = 1
⇒ y min = 7 + 10 – 9 = 8
27. [1.00]
x n ( a + sin x n ) + ( b − sin x n )
Sol. lim
n →∞ 2
(1 + x n ) 1 + ( x n + x − n )
a+b
ƒ(1) =
2 5
ƒ(1 ) = 0 = ƒ(1–)
+
⇒ a+b = 0 ⇒ a+b+1 = 1
19 19
PAPER-1
28. [1.00]
y
Sol. x intercept = x −
m
y
Hence x − =
y
m
dx x − y
=
dy y
dx
2 x−y
d x dy
=
dy 2 y2
dx d2x
At x = 1, y = 1, = 0, 2 = −1
dy dy
29. [3.00]
1
Sol. D= ∫ ƒ ( x ) dx , Let
0
x = sinθ
π /2 π /2
⇒ ∫ ƒ ( sin θ ) cos θ dθ ⇒ ∫ ƒ ( cos θ ) sin θ .dθ

0 0
π /2 π /2
⇒ 2D = ∫ ( cos ƒ ( sin θ ) + sin θƒ ( cos θ ) ) dθ ≤ ∫ 1dθ

0 0
π
1
ƒ(x)
⇒ D≤ 2∫ dx ≤ 3
4 0
π
30. [1.00]
Sol. Point of intersection of the curve (1, 0)
 y = 3x–1.ln(x)  y = xx – 1
3x −1 dy
∴ y' = + 3x–1.(ln(x))2 = xx [1 + ln(x)]
x dx
dy  dy 
 = 1= m1  = 1= m 2
dx  x =1 dx  x =1
∴ Angle between the curve θ = 0º
∴ cosθ = 1.
31. [1.00]
1
Sol. Equation of tangent of parabola ≡ y = mx +
m
1
3m +
m =3 1
So, ⇒m=±
1 + m2 3
20 20
PAPER-1
32. [10.00]
r
20 20 − r  cos α 
=
Sol. Tr +1 Cr (x sin α)  
 x 
= 20C r (sin α)20–r (cos α)r x20–2r
⇒ 20 – 2r = 0 ⇒ r = 10
1
T 11 = 20C 10 10
(sin 2α)10 ≤ 20C 10 2–10
2
33. [C]
34. [D]
Sol. 4sinA + 4sinB = 1
1
sinA + sinB = ...(i)
4
1
cosA + cosB = ...(ii)
3
From (i) and (ii)
A+B A−B 1
2sin   cos  =
 2   2  4
A+b A−B 1
2cos   cos  =
 2   2  3
A+B 3
∴ tan  =
 2  4
A+B A+B 3
=
sin  =
 sin  
 k −1   2  5
 k    A + B 
tan  (A + B)  =
tan  3  
 k −1    2 
A+B 3 A+B
3tan   − tan  
 2   2 
=
A+B
1 − tan 2  
 2 
3 27
3· −
4 64 = 144 − 27 117
==
9 4(16 − 27) −44
1 − 3·
16
21 21
PAPER-1
35. [B]
Sol. AC = 2 2
 
⇒ | c − a |= 2 2
2  
⇒| c | +9 − 2a ⋅ c =8
 
| c |2 −2a ⋅ c =−1 ...(i)
  
AC ⊥ OC ⇒ (c − a) ⋅ c =0
2  
| c |= a ⋅c ...(ii)
36. [C]
     
Sol. OA × OB + OB × OC + OC × OA
= 2 (area of ∆ABC)
A
B
C
i j k
1
⇒ 2⋅ 1 0 −2
2
1 8 4
− −
9 9 9
16 ˆ 2 ˆ 8 ˆ
⇒ i − j− k =2
9 9 9
22 22
PAPER-1
40. (B,C)
MolesofCH3COOH = 0.1 × 0.1 = 0.01 mol.
MolesofHCl = 0.01 mol
+ 0.01
[H ]f = = 0.1M
0.1
pH = 1
– +
CH3COOH CH3COO + H
0.1 – x x (x + 0.1)
–5 x ×0.1
2 × 10 =
0.1
–5
x = 2 × 10
2×10–5 –4
 CH3COOH = = 2 × 10
0.1
+ – –14 –
H2O H + OH , 10 = 0.1 × [OH ]
– –13
[OH ] = 10 M
10 –3
–16 –15
(H2O) = 1000 = 18 × 10 = 1.8 × 10
18
42. (A,B,C,D)
(A) dG = VdP – SdT (at constant temperature, SdT = 0)
 dG   VdP
But H = 0 and
dH = dU + PdV + VdP
 0 = 0 + PdV + VdP
 VdP = – PdV
 G = area projected on volume axis.
(B) W   PdV
(C) U = 0 (isothermal)
So q = W
(D)  dq =  TdS  q = TS
PAPER-1
44. (1.75)
Since, k2 >> k1 , therefore given sequential reaction converts as follows
A 
k1
C
 [A]0 = [A]t + [C]t
0.693
t1/2 = × 103 sec
2.3
= 300 sec
= 5 Min
2
[A]t = = 1/4 (After 3 t1/2)
23
7
[C]t = = 1.75 M
4
47. (700.00)
C(s) + O2 (g)  CO2(g)
rH = H atomisation [Cgraphite,s] + O = O – [2C = O + RE of CO2]
– 400 = 700 + 500 – [2C = O + 200]
2C = O = 1600 – 200 = 1400

C = O = 700 kJ
49. (9.94)
H3PO4+ Na3PO4 NaH2PO4 + Na2HPO4

10 20 0 0
0 10 10 10
NaH2PO4 + Na3PO4 2Na2HPO4
10 10 0
0 0 10
pKa 2 + pKa 3 7.21+12.67
pH = = = 9.94
2 2
QUESTION PAPER FORMAT AND MARKING SCHEME
19. The question paper has three parts: Physics, Mathematics and Chemistry.
20. Each part has three sections as detailed in the following table:
NAME OF THE CANDIDATE :_____________________________________________
ROLL NO. :_______________________
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
_______________________ ____________________________
Signature of the Candidate Signature of the invigilator

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JEE ADVANCED PATTERN

PAPER-1 WITH SOLUTION

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR.

Name of the Candidate Form Number

I have verified all the information filled in by the Candidate.

Signature of the Candidate Signature of the invigilator

CHOOSE WISE TO RISE

x-axis, and it lands on the xy plane at a point (x, y)

(A) x = 2 m (B) x > 2 m (C) y = 3 m (D) y = 5 m

(A) PD = PB (B) PA< PB = PD< PC

Choose the correct options :

SECTION-II : Integer Value Correct Type

Fv = Viscose force on the ball

15. Correct graph to show variation of various quantities with time is :

16. Which of the following is correct statements :

17. How many times maximum sound can be observed on line AB :

(A) ( 50  18)2 (B) ( 30  18)2 (C) ( 50  18)2 (D) None of these

cos3 x + cos5 x π

21. If ∫ (1 − cos2 x)(2 − sin 2 x) dx =

(A) F(x) ≤ 0 ∀ x ∈ (0, π) (B) F(x) ≥ 0 ∀ x ∈ (0, π)

SECTION-II : Integer Value Correct Type

26. Minimum value of 7sin2x + 10cosec2x – 9, x ≠ nπ (n ∈ I) will be

SECTION-III : Paragraph Type

Paragraph for question nos. 33 & 34

Paragraph for question nos. 35 & 36

Position vectors of points A and B are 2iˆ + ˆj − 2k,

perpendicular to OC(O is origin). AC = 2 2 , BC = 1 and C does not lie in xy-plane.

     

38. Angular part of a wave function is given as

(D) Equation represents 3dxy

39. Select the CORRECT statement(s) about Contact process ?

SECTION-II : Integer Value Correct Type

44. For a first order sequential reaction, A 

45. NH4NO3   ‘X’ + H2O

Oxidation state of N in compound ‘X’ is -

(1) Ph–CCH   PhCH2CHO

50. Find the number of complexes which are paramagnetic in nature.

SECTION-III : Paragraph Type

Paragraph for question nos. 51 & 52

when a reddish brown colour is formed.

52. Excess of sodium acetate is added in the above test. It is because –

53. What is structure of A?

54. If A is heated to 200°C, the major product will be :

SOLUTION | PART-I : PHYSICS_PAPER-1 | JEE ADVANCED

resultant intensity at B = 1 + 2 + 2 1 2 cos5 = ( 50  18)2 .

⇒ ∫ ƒ ( sin θ ) cos θ dθ ⇒ ∫ ƒ ( cos θ ) sin θ .dθ

⇒ 2D = ∫ ( cos ƒ ( sin θ ) + sin θƒ ( cos θ ) ) dθ ≤ ∫ 1dθ

(D)  dq =  TdS  q = TS

2C = O = 1600 – 200 = 1400

H3PO4+ Na3PO4 NaH2PO4 + Na2HPO4

NAME OF THE CANDIDATE :_____________________________________________

ROLL NO. :_______________________

and shall abide by them of the candidate.

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