Capítulo 6

6.1-1
~
a. CpO =30.35 J / mol k
2

~
b. CpCO =29.44 J /mol k
~
c. CpCH =41.89 J /mol k
4

~
d. CpCO =42.10 J / mol k
2

~
e. CpC H =118.12 J /mol k
6 6

6.1-2
~
a. Cp H O =75.41 J /mol k
2

~
b. Cp CH OH =85.73 J /mol k
3

~
c. CpC H2 3
OH =121.71 k J /mol k
~
d. CpC H =¿133.66 J /mol k
6 6

6.1-3
~
a. Cpm=39.47 J /mol k
~
b. Cpm=33.45 J /mol k
c. 31.45 J /mol k
6.1-4
~
a. Cp H O =75.59 J /mol k
2

~
Cp C H 2 5
OH =126.04 J /mol k
~
b. Cpm=123.04 J /mol k
6.1-5

Kgmol
N 1=6.75
h
MJ
Q=−622.58
h
6.1-6

Análisis de grados de libertad

m C
NVI
3 3
T 3
VU 2
3 8
NBI
BM -1 -1
VC -1
-1 -2
NEI
CC 0 0
FC -1 -1
RA 0 0
TC -3
VUC -2
-1 -6
GL 1 0

Kgmol
N 1=16.65
h
Kgmol
N 2=38.77
h
Kgmol
N 3=55.43
h
Kg
F 2=2326.20
h
6.1-7

T S aceite =58.48℃

6.1-8

Q=205.31 MJ /h
6.1-11
a. F 3Agua=1478.57 Kg/h

b. T 4=53.12 ℃

c. T 2=36.30 ℃

d. T 2=36.85 ℃

6.1-12

F 1=1000 Kg /h

F 2=2000 Kg/h

F 3=3000 Kg/h

W 3A =0.3333

W 3B=0.6667
T 3=352.20 K=79.05 ℃

6.1-13

F 3=396 Kg/h
T 2=55.56 ℃

6.1-14

Kgmol
a. N 2=100
h
Kgmol
N 4H O =30.26
2
h

N 5H O =N 4 =30.26
2

b. T 1=587.81℃
 6.1-15

M S P G
m c m c c m c
NVI
C 7 7 7 7 11 8 8
T 3 3 5 4
VU 2 2 4 2
7 12 7 12 20 8 14
NBI
BM -3 -3 -3 -3 -6 -3 -3
BE -1 -1 -2 -1
-3 -4 -3 -4 -8 -3 -4
NECI
C -3 -3 -2 -2 -3 -1 -1
F -1 -1 0 0 -1 -1 -1
RA 0 0 -1 -1 -1 0 0
T -2 -2 -4 -4
VU -2 -1 -3 -1
-4 -8 -3 -6 -12 -2 7
GL 0 0 1 2 0 3 3
BmM 0 1 1 1
BeM 0 1 1
BmS 0 0
BeS

b. Orden d calculo

BeM BMS BeS BMG BeG

BMM
 BMS BeM BeS BNG BeG

c. T 3=85.91 ℃

Kgmol
d. N 4 =412.25
h
Kgmol
N 5=1287.75
h
Kgmol
N 5A =12.75
h
Kgmol
N 5B =170
h
Kgmol
N 5C =1105
h
MCal
Q=740.10
h

e. X 5A =0.0100

X 5B=0.1320

X 5C =0.8580
6.2-1
~
a. ∆ H 0f glucosa
=−301.20 Kcal /mol
~
b. ∆ H 0f fructosa
=−299.20 Kcal /mol
~
c. ∆ H 0f lactosa
=−530 Kcal /mol
~
d. ∆ H 0f sacarosa
=−531.19 Kcal /mol
6.2-2
~0
a. H r =−42.48 Kcal /mol
~
b. ∆ H r ( 35 ℃ )=−147.66 KJ /mol
6.2-3

r =97 Lbmol/h

N 3CO =97 Lbmol /h

2

N 3CO =3 Lbmol/h
~
∆ H r ( 573.15 K )=−128666.66 KJ /Lbmol

N 1=3348.14 Lbmol /h

N 3=3399.64 Lbmol /h

X 3N =0.7780
2

X 3CO =0.0285
2

X 3CO =0.0009

X 3O =0.1926
2

Comprobación del balance

Sustanci MS NSEnt FSEnt NSSal FSSal

a
N2 28 74060.86 44060.86
O2 32 22499.50 20952.66
CO 28 2800.00 84
CO2 44 0.0 4268.0
99360.36 99365.52

6.2-4

a. Análisis de grados de libertad

R1 R2 P G
m c m c m c m c
NVI
VC
T
VU
11 17 11 17 17 27 12 18
NBI
 BM -6 -6 -5 -5 -11 -11 -6 -6
BE -1 -1 -2 -1
-7 -5 -6 -11 -13 -6 -7
NEI
CC -1 -1 -4 -4 -4 -4 -3 -3
FC 0 0 0 0 0 0 0 0
RA 0 0 -1 -1 -1 -1 0 -1
TC -3 -3 -5 -4
VUC -1 -2 -3 -1
-1 -5 -5 -10 -5 -13 -3 -9
GL 4 5 1 1 1 1 3 2

El problema está subespecificado y se puede tomar una base de cálculo para solucionarlo

b. Orden de cálculo

R1 R2 P G
GL m c m c m c m c
5
BCN
BmR2
BcR2
BmR1
BcR1

BMR1 BCR1 BMG BCG

B.C BMR2 BCR2

BMG BCG BMR1 BCR1

c.

N 1=100 mol /h

N 2=500 mol /h

N 3=500 mol /h

N 4 =100 mol/ h
 N 5=100 mol /h

N 6=500mol /h
r 1=100 mol /h

r 2=3 mol /h

r 3=96 mol /h

N 2I =290 mol /h

N 2B =1 mol/h

N 2D=209 mol /h

N 3I =290 mol /h

N 3B =104 mol /h

N 3D=106 mol / h

N 4E=3 mol /h

N 4C =97 mol/h

N 5E=99mol /h

N 5C =1 mol /h

N 6I =290 mol/h

N 6B =200 mol /h

N 6D=10 mol /h

d. T 4=727.62 K=454.47 ℃

e. Q=5900.10 KJ /h

f. X RB 1=99.04 % X RB 2=48 ℃

X CR 2=98.97 %