Appendix B Physical Property Tables TABLE BA B2 B3 Ba BS BO BI BS BO Selected Physical Property Data Heat Capacities ‘Vapor Pressure of Water Antoine Equation Constants Properties of Saturated Steam: Temperature Table Properties of Saturated Steam: Pressure Table Properties of Superheated Steam Specific Enthalpies of Selected Gases: SI Units Specific Enthalpies of Selected Gases: American Engineering Units B.10. Atomic Heat Capacities for Kopp’s Rule B.1L Integral Heats of Solution and Mixing at 25°C PAGES 628-634 635-637 638-639, 640-641 642-643 644-649 650-651 652 652 693 653, 027‘Table B.1 Selected Physical Property Data® SG Mag Toa) AAT) (aay (any Compound Formula Mol. Wt. (204°) Ta(°C)* Kimo! TCC! kot TK)! Pfatmy ks! kJ/mol Acetaldehyde CHsCHO 4405. 0.783" 123.7 = izes 2st 4610 = =1662(g)=1192.4(8) Acetic acid = CH;COOH 60.05. 1.049 166 120911822439 S048 57.1 = 486.181) 871.6511) 438:15(¢) -919.73(8) Acetone HO 58.08 0.791 -950 5.69 560 302 508.0470 =248.2(1), ~1785.7(1) =216.7(g) -1821.4(g) Acetylene = GH 2604 Ss = 81S 1763085 61.64226.75(Q) —1299.6(8) Ammonia NHs 103 — “78 $653 3343-23351 4055113 —67.20(1) =46.19(g) ~382.58() Ammonium NH\OH 3503 — - - = = = = -366.48(aq) hydroxide Ammonium — NHWNO; 80.05 L725" 1696 5.4 Decomposes at 210 =365.14(0) 7 nitrate =399,36(aq) Ammonium — (NH,)SO. 132.14 1.769 513 = Decomposes at 513°C =11793(¢) sulfate after mel =1173.1(@q) Aniline CHiN 93.12 1.022 63 — 1842 _ 524 = — Benzaldehyde CsHsCHO 106.12 1.046 26.0 - 90s — 88831) -3520.0() —40104(8) = Benzene CoH 78.11 0879 553 9837 SUI 30.765 502.6 aK 448.66(1)— =3267.6(0) +82.93(g) O15(e) Benzoicacid G)HaOz 122.12 1.266!" 122.2 — 2498 7 . 7 = ~3226.7(2) Benzyl alcohol C)HyO 108.13 L045 =154 — 252 7 = : ~ ~3741.8(0) Bromine Br, 15983 3.119 74 108 586 310 BH 10 0) = L2-Butadiene CH, 5409 = 1365 - Wo. ~ 446 = = = 13-Butadiene — CyHg 5409 = 1091 S 46 ose a7. a = n-Butane CiHio 5812 1383 4.66106 22.305 425.17 37471470) —2855.6(1) 124.2) —2878.5(8) Isobutane Caio S812 — 4540 11.73 21.292 4081360 =158.4(1) — — 2849.00), 1345(g) ~2868.8(8) 1-Butene CoH 56.10 — 3480-625 21916 419.6397 +117) ~2718.6(8) Calcium, cacy 64.10 2.220" = = = —62.76(6) = carbide Calcium CaCO; 100.09 2.93 Decomposes at 825°C = 1206.40) = carbonate Caleium cach, 110.99 2.152" 782 2837 >1600 = = — = 794,96(6) chloride axipuaddy zoCalcium Ca(OH): 74.10 2.24 (-H:0 at 580°C) 986.596) = hydroxide Calcium oxide CaO 5608 3.32 2570 50 2850 = = = =635.6(¢) = Calcium Cay(PO)2 310.19 3.14 1670 - - - = = =a138(0) = phosphate Calcium CasiOs 11617 2915 1530 48.62 - - = = =1584(6) . silicate Calcium CaSO, 136.15 2.96 - - - - 270) 7 sulfate —1450.4(aq) Calcium CaS0-2H,O 172.18 232 (15120 at 128°C) = - ~ — -2021(6) 7 sulfate (gypsum) Carbon c 12010 2.26 3600 460 4200 - - = Oe} =393.51(0) (graphite) Carbon co; ry =566 833 (Sublimesat -78"C) 3042729 412.90) = dioxide at 5.2 atm 393.512) = Carbon cS: 7614 126777 1121439 4625 28 5520 78.0 4+87.9() — —1075.2()) disulfide +1153(g) —-1102.6(8) Carbon co 2801 -205.1 0837-191 6021330 HHS 1105%(g)_ 282.998) monoxide bon ck 153.84 1.595 -29 251 767 05564450 139511) ~352.2(1) tetrachloride =106.7ig)— ~385.0(g) Chlorine ch mo — =101.00 6406-3406 204 IT 76.1 0) = Chlorobenzene CeHsCl 112.56 1.107 45 13210 365 RA HG = = Chloroethane CHCl See ethyl chloride Tpdapted in part from D. M. Himmelblau, Basie Principles and Calculations in Chemical Engineering, 3ed Edition, ©1974, Tables D1 and F1, Adapted by permission of Jal, Inc, Englewood Cliffs, NJ. Melting point at | atm. Heat of fusion at Ty and 1 atm, Prentice, “Boiling point at 1 atm ‘Heat of vaporization at and 1 atm. ‘Critical temperature, +c iical pressure “Heat of formation at 25°C and 1 atm, ‘Heat of combustion at 25°C and 1 atm. Standard states of products are CO,(g), HO(), SOg(g), HCIaq), and N,(g). To calculate B47? with HyO(g) as a product, add 4401, to the tabulated value, where n, = moles HO formedimole fuel burned. Af to keallmol, divide given value by 4.184; t0 convert to Btuflb-mote, multiply hy 43028, "To conve! (continued) doag reaiskud sajqey Mua 6x9‘Table B.1 (Continued) Afi Te)" BAT) (aHeys (aneyy Compound Formula Mol. Wt. TCC) KWImol__ TCC} —_kmol_—TAKYPe(atmy—_KkS/mol Kimot Chloroform = CHC 11939 637 = 610 5360 540 131.8) ~373() Copper Cu 63.54 1083 BOL 2595 3046 - ic) = Cuprie CuSO, 159.61 Decomposes > 600°C =769.9(c) - sulfate ~843.1(aq) Cyclohexane Hin 8416 0.779 67 2677 807 301 553.7 404 156201) —3919.901) =123.1(g) — -3953.0(2) Cyctopentane — CsHyp 7013 0.745 934 0.609 493 2730 S118 4455 —1059(1) — -3290.9(1) =T1Ag) ~3319.5(g) n-Decane CH 14228 0.730 299 - 1B8 = — 619.0208 249.71) -67783(1) - ~68297(2) Diethylether (CzHs),0 74.12 0.708" = —1163 7.30 346 2605467356 27281) -2726.711) Ethane CoH 3007 — = 1833, 2859-886 14.72, 305.448. ~8467(g) ~1559.9(g) Ethylacetate C\HyO2 88.10 0.901 838 = 71000 5231 378 46321) ~2246.4(1) =426.8(2) = Ethyl alcohol G:HsOH 46.07 0.789 ~1146 5.021 785 3858 516.3630 27753(1) ~1366.91(1) (Ethanol) =23531(8) ~1409.25(8) Ethyl benzene CyHio 106.16 0.867 -9467 9.163 1362 35.98 619.7370 12.460) 4568901) +29.79(g) -4607.1(8) Ethyl bromide C:HsBr 108,98 1.460 =1191 — 38320 Ses =54.4(8) = Ethylchloride CHCl 6452 0.903" = —1383 4.452 Bt 2474604 52.0— —105.0(2) = SE thy! Cis 14220717 = ~ M85 34275670 264 250501) —5407.1(1) hexane =210.9(g) ~3509.8(g) Ethylene GH 2805 — 169.2 3350-1037 1354 (283.1505 +5228(g) —1410.99(g) Ethylene CHO: 6207 1B” 13 NB 1972 569 = = ~4515(1) -11795(1) glycol —387.1(g) a Ferric oxide FeO; 159.70 5.12 Decomposes at 1560°C -822.2(0) Ferrous oxide FeO 7185 37 = - a = - — — ~2665¢e) -_ Ferrous Fes 87.92 484 1193 = - - = ~ =95.1(6) - sulfide Formaldehyde tzCO 3003 0815-2" — —92 = -193 244 — —-=11590(@) = 563.462) Formic acid CH;02——46.03.—*1.220 830 1268 woos 22.250 = 409.20)" =262.8(1) 362.68) — Glycerol CoHyOs 92.09 1.26057 1820. 1830 2000 — - = =665.9(1) — —1661.1(1) Helium He 400 — 269.7 002-2689 = 0084 5.26 2.26 (2) = axipusddy 9¢9100.20 0.684 959 1403 9843-3169 5402 270 =224.4(1)— 4816.91) n-Heptane ~187.8(g) 4853.5 -Hexane 86.17 0.659 95.32 13.03 68.74 28.85 299 = 198, 4163.1 167.28) -4194.8( Hydrogen 2016 = — 259.19 O12 =252.76 0.904 333-128 (8) =285.84(2) Hydrogen 80.92 - =86 - -67 - —_- = =36.23(8) _ bromide Hydrogen HCL 3647 1142 199-850 16.1 3246 81S -92.31(8) = chloride Hydrogen HCN 21030 = -14 - 6 . = ~ — +130.54(8) = ide Hydrogen HF 200 - 83 - 20 — 532 = 268.6(g) - fluoride =3165(aq, = 200) Hydrogen HLS, 3408 — 85.5 238-603 «18673736 BBY. ~562.59(8) sulfide Todine L 2538 4.93 - 1842 er . Iron Fe 558577 15.1 2800 354.0 _ = = Lead Pb 20721 11.337/2" 510 1750 179.9 = 7 Lead oxide PbO 22321 95 "7 4m 213 = = = Magnesium = Mg 2432 1.74 92 20 B18 - - = Magnesium MgCl 95.23 2325" 714 8.1 18 136.8 - - e chloride Magnesium 583424 Decomposes at 350°C - eo hydroxide Magnesium. 4032 365 2900 m4 3600 = | = = oxide Mercury 200.61 13.546 3887 — 356.9 — - - (0) = Methane 1604 = 1825 094 1615 8179 190.70 458 =7485(g) —-89036(2) Or 7408 0.933 989) - ST — 5067 46.30 40.4) = 159501) 1 CHO 3208 0.792 919 31676473827 513.20 78.50 238.61) 201.218) N 31.06 we 9n7 - - — 499 73.60 (2) c 9 = - -24 — 416.1 65:80 81.928) - Te9 soigey Ausadoug yeoiskug632 Appendix B 0 (pas) = @)ti- STE HE UE SOHUR, LETS ane 06S oz o6'ezt ta stuoydsoud (OL = “beg suzl— pre = @)rtgzi- — OezwOHT-) oer EtH tet 0096 "OdH — suoydsoud = @x06— (s)s-e90e (Wrssi~ —s09 veep ag It St gelL 16 HOSH'D ououd @ssuee~— @ooc-— 66 ter L662 rer ZS9I- HELO SSD suatued-| @eezse-— @Bozet- = Wscose- Weetti- ze Ie eee = Vo ito sTzL HED suetuodos, @roese— papi ~ We (i Ge Ce ee ee “HQ auetuag-u = @o Lo ISL HO L6zBI- pO SeBIZ- = — ~—nze 0 wo8KKO (eIse- @ez- = 2.981 1 Sosodiwoo9¢] 061-1006 FORTHE. pe onexo @ezss— — @psoz— Weours- — (eere-stz ss sen — ots LOLLY ote @otz19- 7 Wsvzi9e- — osez- vez ss st Ge ee SieU cee ee) on ‘apixo 7 @sist ove = sue gg = 16-921 OPH O'N snomin aprconna, _ @eo+ 066 = Ole on vig _ s6- arr 0% "ON us80.IN sprowad = I = = i a = 0€ 4 €9T—ZO8O SON uaonin = @icow+ os oreet EL SISI- «ez oet- 3S te ON @ppxoouIN 2pIxo1p = @eee+ oo otey ez sees eO- — wor ‘ON uo8onIN @o see oret uss BS6I- OLD oe 'N _uaifosnin (sz60e- = — = ~ coz — ss GOTT IEE NFOFH®D auazuaqosIN (be)s-902- = (erset- = oe og ol otros ewes fONH —pppainin a 0 7 = = CaS Zsrt_ 6B 98S N PXOIN @usis- = - = = sue — ows SPVT 9rRzL HM ousjequden 20194 (oere- = = 7 ow 8 = Tes sow orze HED ua Kuo Tow /E towns duneya OL iow AO) OWT OIL Gr) IM TON BIRO punodwo> CHV) —rolcl9) CLT CODES os (panunwoa) Va ae,Physical Property Tables 633 (pamunu0>) @syv97s— (estes— (9 9861— (@)o's902— (Wrowe— pss (s)N0ze— (ooze— @)ev601- = @yeeue— = @)srger- (yr ose- = ()L99F— _ (be)Fo9r— ()9 92>— = (9)6468- = LIP _ @or- = (eeztt— _ ()9's6~ = (Jo 1s8— _ Beret (Dorse— ele (Weo1e- (B)esst— (Docooe- $66 (ir Oe+ vor (aereor— Wont oes oer (zm t— _ sasodwos9q = = vo eve abZE 18 SasOd ODA, = ‘Oe08E 18 sesodwwio9aq, ost i = set FER = ssi Lert 91 — cout sol $8 _ Dabs 1 sesodwooeq, - e042” sesodus0s9q, = = oezz wht veo HeRE Tost PSR ees wus = cos WOL6 = TSE PSL OLLP- OE woe LER WT SE Danse We saumgns wor osc 1STz 086 068 uz one ws 808 out 0s 66~ Los~ i zssi- aoust— wh si 9% 9se'l 869% 891T isez OE17 gore eesz weet oz sez x80 ssvo oso uxez wt sovzt soe soz ovo ons vor 16r sree 66'S01 Lovet lors 60709 voz 6009 6009 soz ute Solel 06 ez ‘osten S?eN Fosten FON"N fONeN HOPN NOUN DPN Soo%N *OSHEN ‘OOHYN ‘ors BHD HO'H'D HOH oH oH sou a unpos apyins umntpos areyins ‘wnipos aun tunipos aver umipog aprxorphy umipos apiurso umnipos 2puoty> ‘wnipog arvuogie ‘winipos aneyinsiq wnipos areuoqueot wnipos aprxomp ‘woot auszttaq adoug-w royooye &dosdos} foyoote Vdorg-u suayAdord sundosg apixonund sruoydsoyd (enw) sruoydsoud634 Appendix B 0 _ _ Levit 06, vo Sole OPTL = 8E'S9. UZ UZ, @Besosr— — (B)s6L1 (tezssr— Were ote 819 Love SeSEL ieee: 1980 9T90I HD auahx-d @Bev6sr— — (8)66'81+ (Wozssr- (Wrrre~ LSE S19 RIE EH PhL—ROSELBT'Se~ RRO. OT9O1 MHI uOKX-0 @erosr— (BT LI+ Wetssr— — Werse- ore 619 oror oveel Siete ies cise ee ae auayhX-u = Gee'tz— = (es'ssz-€81Z_— LEY gvOF HTT. Som) gt OH sore @Beevee— @)oous+ (Wecoce—— (Doozt+ OF HHS EYEE OTT. «GI99—HHH- —-99KD_ET HD suaniey, =e (be)Is L06— pre a Weer — Deore resesodwosad —L8'6—SEOL PERT 8086 FOSTH aunying aprxoun oe @arsoe- eR For ow eee srse OL L008 ‘os ayins apixo1p = @ossez— SLL LOH 6H OOI- ORL BSL- = LON ‘os ferent (orutjoouow) = Ooeo+ - ~ Les hhh LIL GIL GL es ose "5 anyins, (orquious) _ @)o _ _ Les opby voor eu woz Es9ST ‘s anying aregnsonp = @rau- = - . = - — LL LPRsL tOFS7=N ‘unipos jouyry lowypy duneyrg OPE OME — OWL OUT —f6)"\L(obie0Z) WML TOW eNO punoduioy, lH) vl) LEV DWV os (ponunued) Pa a14eE,Physical Property database uietyimegrates tabulated heat ‘capactes ‘Table B.2 Heat Capacities* Form 1: C,{kJ/(mol-°C)] or [kJ/(mol-K)] = a + 6T + cT? + dT? Form 2: C,[kmol-*C)] or {kJ/(mol-K)] = a+ BT + eT? Example: (Cy)acsun) = 0.07196 + (20.10 X 10-8) ~ (12.78 x 10-*)T? + (34.76 X 10" YT, where T is in °C. ‘Note: The formulas for gases are strictly applicable at pressures low enough forthe ideal gas equation of state to apply Range Mol. ‘Temp. (Units Compound Formula Wi. State Form Unit aX10 bx10 x08 dk 102 _of 7) Acetone CHCOCH, 5808 1 1 °C 1230186 30-60 Ge Cerise: 2010. 1278 34760-1200 Acetylene CH 2604 g 1 C4243 053. —5.033 18200-1200 Air O00 a ce eae oniaya 0101 =1.965 0-150 ee roo clio 000 1.965 273-1800 Ammonia NH 703g LC 35.15.2984 442 66860-1200 An (NIYSO, 21S et KS 275. 328 Benzene CoH BN 1 1 16S Bd 6-67 le Ch idey seo) 2520) 71310-1200 Isobutane Cio cy) Ge ee Sr 49870-1200 n-Butane Catia S812 g 1 C9230 2788 =15.47 34980-1200 Isobutene CiHy CS Ga (3 ee See 50500-1200 Calcium carbide Cay 6410 c 2K 68D 119 86X10 = — 298-720 Caleium carbonate CaCOs Ur) cee ee ee Calcium hydroxide Ca(OH), 7410 eK 8S 216-373 Calcium oxide CaO BOS Ge Or ee 23-1173 Carbon c mo © 2 KIB 1.095 4.891 x 10" 273-1373 Carbon dioxide co; 401g 1 C361L 4233 2.87 7.464 0-1500 Carbon monoxide CO mo 0g 128951003548 22200-1500 Carbon tetrachloride CCl, 15381 1K 9339 12.98 273-343 Chiorine Ch 2 gg 1 °C 3360 1367 1.607 54730-1200 Copper Cu 654 6 1K 2276 06117 213-1357 “Adapted in part {rom D. M. Himmelblau, Basic Principles and Calculations in Chemical Engineering, 3rd Edition, © 1974, Table E.1. Adapted by permission of Prentice-Hall, Inc, Englewood Cliffs, NI (continued ) S€9 soigey Auiadoig teatskuaTable B2 (Continued) Range Mol ‘Temp. (Units Compound Formula Wt. State Form Unit aX 10° bx 10° of) Cumene GH 12019 1 °C 1392 53.76 0-120 (Isopropyl benzene) Cyclohexane GHp 8416 gE CGO 49.62 0-120 Cyclopentane GH = 713g C7339 39.28 01200 Ethane GH. 3007 og 1 "C4937 13.92 0-1200 Ethyl alcohol GHOH 4607 1 1 103.1 0 (Ethanol) 4 1588 100 e 1 6134 15.72 0-120 Ethylene Hy 205g 1 440.75 11.47 0-1200 Ferric oxide FeO; 15970 ee 2 1034 6.711 273-1097 Formaldehyde CHO 3003 gt 34.28 4.268 0-120, Helium He 400g 208 0-1200 n-Hexane CMe 867 1 216.3 20-100 e ol 13744 40.85 0-1200 Hydrogen Hy 206g 1 28.84 0.00765 0-150 Hydrogen bromide HBr m2 og 29.10 ~0.0227 0-120 Hydrogen chloride HC! 3647 go 29.13 -0.1341 0-120 Hydrogen cyanide HCN 2103 gd 353 2.908 0-120 Hydrogen sulfide HS 3408 og 3351 1.547 0-1500 Magnesium chloride MgCh 9523 © I a tse 273-991 Magnesium oxide MgO 4032 © 2 45.44 0.3008 273-2073 Methane cH, [aon ae 3431 5.469 0-1200 ge o1 1987 5021 273-1500 Methyl alcohol CHOH 3206 11 7586 1683 0-65 (Methanol) e 1 42.93 8301 0-700 Methyl cyclohexane CGHy = 98.18 gE C123 5853 0-1200 Methyl cyelopentane CyHis 8416 gd CORRS 8ST 0-120 Nitric acid NHO; 6302, 11°C 1100 5 Nitric oxide NO wool og 1 C2950 8188 0-350 ampueddy 9¢9Nitrogen Nitrogen dioxide Nitrogen tetraoxide Nitrous oxide Oxygen n-Pentane Propane Propylene Sodium carbonate Sodium carbonate decahydrate Sulfur Sulfuric acid Sulfur dioxide Sulfur trioxide Toluene Water N: NO: N24 N,0 GH Hy Hy Na;COs NayCOy 10H,0 H,SO5 SO SO) CiHy HO 28.02 46.01 92.02 44.02 32.00 RAS 44.09 42.08, 105.99 286.15 32.07 (Rhombic) (Monoclinic) 98.08 64.07 80.07 92.13 18.016 © Il °c °c °c °C cc °C °C cS oo cc 29.00 36.07 757 37.66 29.10 195.4 1148: 68.032 59.580 121 535.6 152 183 1391 38.91 48.50 148.8 94.18 75.4 33.46 0.2199 3.97 125 4151 1.158 43.68 34.09 2259 m1 2.68 1.84 15.59 3.904 9.188 324 38.00 0.6880 0.5723 -2.88 -113 = 2.694 0.6076 18.99 10.17 3.108 -8540 27.86 0.7604 2871 787 10s? 1311 42.26 371 24.60 8.606 32.40 8033 3.593 0-150 0-120 0-300 0-120 0-1500 0-36 0-1200 01200 041200 288-371 298, 273-368 368-392 10-45 0-1500 0-100 ono 0-120 0-100 0-150 L€9 salqny Ausdorg [worsdya638. Appendix B Table B3 Vapor Pressure of Water* po(mm Hg) versus TCC) Example: The vapor pressure of liquid water at 43°C is 6230 mm Hg TC) 00 010203 OS HT | M4 1361 134813361324 1312 130012881276 1.264 1.253 ~13 1490 1477 14641450 1437-1428 1411 139913861373 Tee = 12,1632 1617 L602 158815741559 1546 1532 1518 1504 ML 1785 1.769 1.753 1.737 1.722.707 1.691 1676 1661 1.686, 10 1.950 1.934 1.916 1.899 1.883 1.865 1.849 1.833 «1817 1.800 -9 2431 2.122 2093 2075 2.057 2030 2021 2.003 1.985 1.968. 8 2326 2.306 2.285 2266 «224 «2.226 «2207-2187 21682149 -7 2537 2515 2493 2.472 2.450 2429 2408 2387 «2367 2346 -6 2765 2.742 2718 2695 2672-2689 2603 2581 2559 -5 3013 2987 2.962 2937 2912 2.887 2838 2813 2790 ~4 3280 3252-3205 3.198 3.471 3.144 3.091 3.065 3.039 3 3568 3539 3509 3480 3451 3.422 3364 3.336 3.308, -2 3880 3.848 3816 3.785 3.753 3.722 3.660 3.630 3.599 “1 4217 4.182 4147 4113-4079 4.045 3.979 3.946 3.913, =0 457945424504 4.467 4.431 4.395 43234287 4252 | 0 4579 4613 4.687 4681 4.715 4.750 4820 4855 4.890 1 4926 4962 4998 5034 5.070 5.107 S181 5.219 $256 Liquid 25.294 5.332 5.370 5.408 5.447 5.486 5565 5.605 5.645 water 35.685 5.725 5.766 5.807 5.848 5.880 5973 6.015 6.058 4 6101 6.144 6.187 6230 6.274 6.318, 6.408 6453 6.498, S 6543 6589 6635 6681 6.728 6.775 6869 6.917 6.965 6 (7.013 7.062 7.111 7160 7209 7259 7309 7.360 7.411 7.462 7 7513 7565 7617 7.669 7.722. 7.775 7828 «7.882 7.936 7.990 8 8045 8.100 8155 8211 8.267 83238380 8437-8494 «BST 9 8609 8.668 8.727 8786 8845 8.905 8.965 9.025 9.086 9.147 10 9209 9.271 9333 9395 9458 9521 9585 9.649 9.714 9.779 11 9844 9.910 9.976 10.042 10.109 10.176 10.244 10312 10380 10.449 12 10518 10588 10658 10.728 10.799 10870 10941 11.013 11.085 11.158 13 11231 11305 11379 11.453 11528 11.604 11.680 11.756 11833 11910 14 11.987 12.065 12144 12.223 12.302 12382 12.462 12543 12624 12.706 15 12.788 12.870 12.953 13037 13.121 13.205 13.290 13373 1346113547 16 13.634 13.721 13809 13898 13.987 14076 14.166 14256 14347 14.438, 17 14530 14.622 14.715 14809 14.903 14.997 15.092 15.188 15.284 15.380 18 15477 15575 18673 15.772 15871 15971 16771 16171 16272 16374 19 16477 16.581 16.685 16.789 16894 16.999 17.105 17.212 17319 17.427 20 17.535 17.644 17.753 17.863 17.974 18085 18.197 18.309 18422 18.536 21 18.650 18.765 18880 18996 19.113 19.231 19.349 19.468 19.587 19.707 22 19.827 19.948 20.070 20.193 20316 20.440 20565 20.690 20815 20.941 23 21.068 21.196 21.324 21.453 21.583 21714 21845 21.977 22.110 22.243, 242237722512 22.648 22.785 22.922 23.060 23.198 23.337 23476 23.616 “From R. H, Perry and C. H. Chilton, Eds, Chemical Engineers’ Handbook, Sth Edition, McGraw-Hill, New York, 1973. ‘Tables 3-3 und 3-5. Reprinted by permission of McGraw-Hill Book Co. (continued)Physical Property Tables 639 ‘Table B3 (Continued) TGC) 00 tly 02 0s ose Ose 061 8 07 0s og 25 23.756 23897 24039 24.182 24.326 24.471 24.617 24.764 24.912 25.060 26 25.209 25.359 25,509 25.660 25.812 25.964 26.117 26.271 26426 26.582 27 26.739 26897 27.055 27.214 27374 27535 27.696 27.858 28021 28.185 28 28.349 28514 28680 28847 29.015 29.184 29.354 29.525 29.697 29.870 29 30.043 30.217 30392 30.568 30.745 30.923 31.102 31.281 31.461 31.642 30 31.824 32007 32.191 32376 32.747 32934 33.122 33312 33,503 31 33.695 33.888 34082 34276 34.667 34.864 35.062 35.261 35.462 32 35.663 35.865 36.068 36.272 36.683 36.891 37.099 37.308 37.518, 33° 37.729 37.942 38.155 38.369 38.801 38.018 39.237 39.457 39.677 34 39.898 40.121 40.344 40.569 41.023 41.251 41.480 41.710 41.942 35° 42.175 42.409 42.644 42.880 43.355 43595 43.836 44.078 44320 36 44.563 44.808 45.054 45.301 45799 46,050 46302 46.556 46.811 37 47.067 47.324 47.582 47.841 48364 48.627 48.891 49.157 49.424 38 49.692 49.961 50.231 50.502 51.048 51.323 51.600 51.879 52.160 39 52.482 52.725 53.009 53.294 53.867 54.156 54.446 54.737 55.030 40 53.324 5561 55.91 5621 S681 S711 S741 97.72 5803 41 5834 5865 58.96 59.27 59.90 60.22 6054 6086 61.18 42 6150 6182 62.14 62.47 B13 6346 63.79 64.12 64.46 43 6480 65.14 65.48 65.82 6651 6686 6721 6756 6791 44 6826 6861 68.97 69.33 7005 7041 (7077 71147151 45 7188 7225 72.62 72.99 TBI4 74.12 7450 7488 75.26 46 75.65 76.04 76.43 76.82 7760 78.00 7840 7880 79.20 47 79.60 80.00 80.41 80.82 8164 8205 8246 8287 83.29 48 83.71 84.13 84.56 84.99 8585 8628 86.71 87.14 87.58 49 88.02 8846 8890 89.34 9024 90.69 91.14 91.59 92.05 Tec) 0 1 2 3 4 3 6 7 8 9 50 9251 97.20 102.09 107.20 11251 118.04 123.80 129.82 136.08 142.60 60 149.38 156.43 163,77 171.38 179.31 187.54 196.09 204.96 214.17 223.73 70 2337 «243.9 2546 «265.7 2772-2891 30431413273 341.0 80 355.1 369.7 3849 400.6 4168 433.6 «450.9 468.7 487.1 506.1 pve) Oe Oe 90 $25.76 527.76 529.77 531.78 $3380 3582 537.86 539.90 41.95, 91 546.05 548.11 550.18 55226 554.35 556.44 558.53 560.64 562.75 92 366.99 569.12 57126 57340 $7555 577.71 57987 582.04 584.22 93 588.60 590.80 593,00 595.21 597.43 599.66 601.89 604.13 606.38 94 610.90 61317 615.44 617.72 620.01 62231 624.61 626.92 629.24. 95 633.90 636.24 93859 640.94 64330 645.67 648.05 650.43 652.82 96 657.62 660.03 662.45 664.88 667.31 669.79 672.20 674.66 677.12 97 682.07 684.55 687.04 689.54 692.05 694.57 697.10 699.63 702.17 98 707.27 70983 71240 714.98 71756 720.15 722.75 72536 727.98 99 733.24 735.88 73853 741.18 743.85 746.52 749.20 751.89 754.58 100 760.00 76272 76545 768.19 770.93 773.68 77644 779.22 782.00 101 78757 79037 793.18 796.00 79882 801.66 804.50 80735 81021640 Appendix B Table B4 Antoine Equation Constants? 8 . Fee PinmmHg, Tin°c Example: The vapor pressure of acetaldehyde at 25°C is determined as follows: _ _1600.017 35+ 291.809 => Pepn,o25°C) = 17%! = 902 mm Hg Hogi p” = A- 089 Pestyo(25°C) = 8.00552 2.9551 Compound Formula Range °C) a 8 c Acetaldehyde CHO 0.210344 8.00552 1600017 291.809 Acetic acid CH.O: 298101265 7.38782 1533313 222309 ‘Acetic acid* GH: 01036 7.18807 1416.7 225 Acetic anhydride CiHsO3 628101394 7.14948 1444.718 199.817 Acetone GsHsO 12910553 7.11714 1210.595 229.664 Acrylic acid C)H.O2 20.010 70.0 5.65204 648.629 154.683 ‘Ammonia* NH 8310 60 7.55466 1002.71 247.885 Aniline GoHAN 102.610 185.2 7.32010 1731515 206.049 Benzene GHs 14510809 689272 1203531 219.888 n-Butane n-CiHig = 78010 -0.3 6.82485 943.453 239.711 i-Butane i-CiHy — =85.1t0~11.6 6.78866 899.617 241.942 1-Butanol CiHlwO 89.210 125.7 7.36366 1305198 173.427 2-Butanol CWO 72.4t0107.1_ 7.20131 1157.000 168.279 1-Butene Cis -775t0-3.7 653101810261 228.066 Butyric acid CiHsO2 — 20.0t0 150.0 8.71019 243.014 255.189 Carbon disulfide cS 3.610799 6.94279 1169.10 241.593 Carbon tetrachloride CCy_—= 14.1 1076.0 687926 1212021 226.409 Chlorobenzene CHSC 620101317 6.97808 1431.03 217.550 Chlorobenzene* CoHsCL 010.42 7.10690 1500.0 2240 Chiorobenzene* GHC 4210230 6.94504 141312 216.0 Chloroform CHC — 10410603 6.95465 1170.966 226.232 Chioroform* CHCh — 3010150 6,90328 116303 2274 Cyclohexane CoHiz —'19.91081.6 6.84941 1206.01 223.148 Cyctohexanol CcHzO 93.7t0160.7 6.25530 912.866 109.126 n-Decane n-CioHar 94510 175.1 6.95707 1503,568 194.738 L-Decene CoH — 86810 171.6 6.95433 1497527 197.056 1,1-Dichloroethane CHC 3880176 697702 1174022 229.060 1,2-Dichloroethane CHCl -308t0994 7.02530 1271.254 222.927 Dichloromethane CHC —-40.01040 7.40916 1325938 252.616 Diethyl ether CiHwO — -60.8t019.9 6.92032 1064.066 228.799 Diethyl ketone CsHwO —565t01113 7.02529 1310281 214.192 Diethylene glycol CeHiO2 130.010 243.0 7.63666 1939.359 162.714 Dimethyl ether GHsO =782t0 -24.9 6.97603 889.264 241.957 Dimethylamine GH)N 7181069 7.08212 960.242 221.667 N.N-Dimethylformamide C3HyNO 30.01090.0 6.92796 140.869 196.434 1.4-Dioxane CiHsO2 20.010 105.0 7.43155. 1554.679 240.337 Ethanol CHsO 19610934 8.11220 1592.864 226.184 Ethanoiamine CH)NO 65.4t0170.9 7.45680 1577670 173.368 Ethyl acetate CahO2 15610758 7.10179 1244951 217.881 Ethyl acetate CiHaO2 — -20t0 150 7.09808 1238710 2170 Ethyl chloride GHsCl -55.9t0125 6.98687 1030.007 238.612 Ethylbenzene CoH 565101371 6.95650 1423543 213.091 “Adapted from T. Boublik,V. Fried, and E. Hala, The Vapour Pressures of Pure Substances, Elsevier, Amsterdam, 1973. If marked with an asterisk (*), constants are from Lange's Handbook of Chemistry, ‘9th Edition, Handbook Publishers, Inc, Sandusky, OH, 1956. (continued )Table B.4 (Continued) Physical Property Tables a Compound Ethylene glycol Ethylene oxide 1.2-Ethylenediamine Formaldehyde Formic acid Glycerol n-Heptane i-Heptane 1-Heptene n-Hexane i-Hexane 1-Hexene Hydrogen Cyanide Methanol Methanol Methyl acetate Methyl bromide Methyl chloride Methyl ethy! ketone Methyl isobutyl ketone Methyl methacrylate Methylamine Methyleyclohexane Naphthalene Nitrobenzene Nitromethane n-Nonane I-Nonene n-Octane i-Octane L-Octene n-Pentane i-Pentane 1 -Pentanol 1-Pentene Phenol -Propanol 2-Propanol Propionic acid Propylene oxide Pyridine Styrene Toluene 1.1. .-Trichloroethane 1.1.2-Trichloroethane ‘Trichloroethytene Vinyl acetate Water* Water* meXylene o-Xylene p-Xylene Formula CHO: CHO (CyHsNz HCHO (CH:02 CyHyOs n-CHig i-CrHig Gls n-CoHs i-CsHyy Cath HCN HOH CH;OH C3HsO7 (CH;Br (CH;Cl CsHsO CoH0 CsH3Q, CHN GH CoHs CoHSNO: (CH;NO; r-CoHon CoHis CFs i-CsHis Coie SH i-CsHi CsH2O CsHio CHO C3HsO C3HsO C3HsO2 C3H.O- CsHsN CoH GHs GH3Ch GHsCls GHC, ‘CsHsO2 10) 2,0 mCsHo o-CsHio PCatla Range (°C) 50.0 to 200.0 0310318. 265 to LITA = 109.4 to ~223 37.4 t0 100.7 183.3 t0 260.4 25.9 10 99.3 185 10 90.9 21.6 10.945 13.0 1069.5 1280 61.1 15.9 0 643 =16.4 t0 46. 14.9 10 83.7 2010 140 18 to 558, ~70.0 103.6 -75.0 105.0 428 10 88.4 21.7 to 162 39.2 10 89.2 ~83.1 t0 6.2 256 to 101.8, 803 t0 179.5 134.1 0 2106 55.7 t0 136.4 703 to 151.8 66.6 to 147.9 52.9 to 126.6 41.7 to L185 44.9 t0 122.2 13.3 10 368. 16.3 10 286 74.7 to 1560 12.810 30.7 107.2 to 181.8 60.2 to 104.6 523 to 89.3 724 t0 1283 24.2 10348 673 to 1529 29.9 t0 144.8 353 to ILS 5.410 16.9 50.0 to 113.7 17.8 10 865 21.8 t0 720 010.60 60 to 150 59.2 to 1400 635 to 145.4 58.3 to 139.3, A 8.09083 8.69016 7.16871 7.19978 7.58178 6.16501 6.90253 6.87689 6.91381 6.88535 6.86839 6.36880 7.52823 8.08097 7.97863 7.06524 7.09084 7.09349 7.06356 6.67272 8.40919 7.33690 6.82827 7.03358 7.11562 7.28166 6.93764 6.95777 6.91874 6.88814 6.93637 esad7t 6.73457 7.18246 6.84268 7.13301 7.74816 7.74021 7271423 7.01443 7.04115 7.06623 6.95805 8.64344 6.95185 6.51827 7.21010 8.10765 7.96681 7.00646 7.00154 6.98820 B 2088.936 005.779 1336.235 970.595 1699.173 1036.056 1267828, 1238.122 1265.120 1175817 1151-401 1154.646 1329.49 182.271 1473.11 157.630 1046,066 948.582 1261339 1168.408 050.467, 1011.532 1273.673 1756.328 1746.586 1446.37 1430.459 1437.862 1351.756 1319529 1355.79 1060.793 992.019 1287.625 1083.206 1516.790 1437.686 1359517 1733418 1086.369 1373.79 1507434 1346.73 2136.621 1314.410 1018.603 1296.130 1750.286 1668210 1460.183 1476393 1451.792 i 203.454 334,765 194.366 244,124 260.714 28.097 216.823 219.783, 220.051, 224.867 228.477 226.046 260.418 239.726 2300 219.726 244.914 249,336 221.969 191.944 274.369 233.286 221.723 204.842 201.783 227.600 201.808 205.814 209,100 211.625 213.022 231.541 729.564 161.330 233.344 174.954 198.463, 197.527 207.724 228.594 214.979 214.985 219.693, 302.769 209.197 192.731 226,635 735.000 228,000 214.827 213.872 215.111 oat642 Appendix B ‘Table BS Properties of Saturated Steam: Temperature Table! ¢en*/kg) O(earke) Alkire) TC) _P(bar) Water Steam Water Steam Water Evaporation Steam 0.01 0.00611 0.001000 206.2 zero 2375.6 = +0.0 2501.6 2501.6 2 0.00705 0.001000 1799 8423783 8424968 2505.2 4 0.00813 0.001000 157.3 168 2381.1 16.8 2492.1 2508.9 6 0.00935 0.001000 1378 25.2 23838 252 © 2487425126. 8 0.01072 0.001000 121.0 33.6 2386.6 33.6 2482.6 2516.2 10 0.01227 0.001000 106.4 42.0 23893 42.0 2477.9 2519.9 12 0.01401 0.001000 938 50.4 23021 S04 2873.2 2523.6 14 0.01597 0.001001 82.9 ‘588 23948 58.8 2468.5 2527.2 16 0.01817 0.001001 73.4 ee ee 2463.8 2530.9 18, 0.02062 0.001001 65.1 75.5 2400.3 75.5 2459.0 2534.5 20 0.0234 0,001002 57.8 83.9 2403.0 83.9 2454.3 2538.2 22 0.0264 001002 S15 922 24058 92.2 24896 =~ 25418 24 0.0298 0.001003 45.9 100.6 2408.5 100.6 2444.9 2545.5 25 0.0317 0.001003 434 1048 2409.9 1048 24825 2547.3 26 0.0336 0.001003 41.0 108.9 2411.2 108.9 2440.2 2549.1 28 0.0378 0.001008 367 1173 24140 1173 24354 2852.7 30 0.0424 0.001004 329 © 125.7 2416.7 125.7 24307-25564 32 0.0875 O001005 296 1340 2419.4 1340 24259 25600 4 0.0532 0.001006 26.6 142.4 24221 142.4 2421.2 2563.6 36 0.0594 0.001006 24.0 150.7 2424.8 150.7 2416.4 2567.2 38 0.0662 0.001007 21.6 1591 24275 1591 24117-25708 40 0.0738 010081955 1674 24302 1675 24069 25744 42 0.0820 0.001009 17.69 175.8 2432.9 175.8 2402.1 2577.9 44 0.0910 0.001009 16.04 184.2 2435.6 184.2 2397.3 2581.5 46 0.1009 0.001010 1456 192.5 2438.3 192.5 2392.5 2585.1 48 0.1116 0.001011 13.23 200.9 2440.9 200.9 2387.7 2588.6 50 0.1234 0.001012 12.05 209.2 2443.6 209.3 2382.9 2592.2 520.1361 0001013 1098 2177 2446 2177 2BTT (2595 54 0.1500 0.001014 10.02 226.0 2449 226.0 2373 2599 56 0.1651 O.00101S 9.158 2344 2451 2344 = 23682602 58 0.1815 0.001016 8.380 2428 2454 = 242.8 2363 2606 60 0.1992 0.001017 7.678 251.1 2456 = 251.1 2358 2609 62 0.2184 0.001018 7.043 2595 2459 2595 23532613 64 0.2391 0001019 6.468 267.9 2461 267923482616, 66 0.2615 0.001020 5.947 276.2 2464 276.2 2343 2619 68 0.2856 0.001022 5.475 2846 2467 2846 = 23382623 “From R. W. Haywood, Thermodynamic Tables in ST (Metric) Units, Cambridge University Press, London, 1968.7 eg > 0.4303 specivolume, 0 i. specificinternal energy, and = specificenthalpy. Nore: (continued )Physical Property Tables 643 Table BS (Continued) (me rkg) O(ksikg) A(ksrke) TCC) _P(bar) Water Steam Water Steam Water Evaporation Steam 70 03117 0.001023 5.045 2930 2469 2930 ©2333 2626 72 0.3396 0.001024 4.655 3014 2472 3014 23292630. 74 03696 0.001025 4.299 3098 2874 3098 23232633, 76 04019 0.001026 3.975 3182 2476 3182 2318-2636, 78 0.4365 0.001028 3.679 3264 2479 3264 «©2313. 2639) 80 0.4736 0.001029 3.408 3348 2482 3349 2308 82 05133 0.001030 3.161 3432 2484 343.3 ©2303 84 05558 0.001032 2934 351.6 2487 351.7 2298 86 0.6011 0.001033 2.727 360.0 2489 3601 2293 88 0.6495 0.001034 2536 3684 2491 3685 2288 90 07011 0.001036 2361 376.9 2493 3770 2282 92 0.7560 0.001037 2200 3853 2496 385.4 ©2277 94 0.8145 0.001039 2.052 3937 2499 3038 ©2272 96 0.8767 0.001040 1.915 4021 2501 402.2 ©2267 98 0.9429 0.001042 1.789 410.6 2504 410.7 2262 100 1.0131 0.001044 1.673 4190 2507 41912287 102 1.0876 0.001045 1566 427.1 2509 4275 2251‘Table B.6 Properties of Saturated Steam: Pressure Table” Von'hke) O(KsrKg) i(k) P(bar) Tec) Water Steam Water Si Water____Evaporation _Steam 0.00611 0.01 0.001000 206.2 zero 2375.6 +00 2501.6 2501.6 0.008 38 0.001000 159.7 158 2380.7 158 2492.6 25085 0010 70 .001000 1292 293 23852 293 2485.0 2siaa 0.012 97 6.001000 108.7 406 2388.9 406 24783 25193 oor 20 6.001000, 93.9 50323920 503 2473.2 25235 0016 140 0.001001 228 539 (2304.8, 589 24684 25273 ois, 159 6.001001 740 665 23074 665 2464.1 25306 0.020 1s 6.001001 610 BS 23096 735 24602 25336 0.022 190 0.001002 612 8 2401.7 798 24566 2536.4 0.024 204 0.001002 564 857 24036 857 24533 2539.0 0.026 217 0.001002 523 911 24054 ou 24502 2541.3, 0.028 230 ‘o.oo1002 487 962 2407.1 96.2 24473 2543.6 0.030 244 0.001003, 45.7 101.0 2408.6 1010 24446 2545.6 0.035, 267 0.001003, 305 ig 24122 118. 24385 25504 0.040 290 0.001004 348 114 24153 ria 2433.1 25545 0.045, 31.0 0.001005 31 130024181 1300 24282 25582 0.050 32.9 0.001005 282 137824206 B78 24238 2561.6 0.060 36.2 0.001006 23.74 11S 2425.1 1515 24160 25675 0.070 39.0 0.001007 2053 163424289 163.4 2409.2 23726 0.080 415 0.001008, 1810 1B9 24323 173.9 24032 25771 0.090 438 0.001009 16.20 1933 24353 1833. 2307.9 2581.1 0.10 458 0.001010 1467 1918-24380 1918 2392.9 25848 oat 417 o.oo. 1342 197 aos W907 2348.4 2588.1 012 404 001012 1230 2009 Baa 2069 2384.3 25912 013 sil 0.001013 a7 237248502137 2380.4 25940 oa 526 0.001013, 10.69 200 © 24470200 23767 2596.7 axipuaddy $49ous 540 0.16 553 017 596.6 ous. 578, 19 59.0 020 60.1 022 62.2 024 64.1 0.26 65.9 0.28 615 030 69.1 035 27 0.40 759 os 187 0.50, 813 035 837 0.60 86.0 0.65 88.0 0.70 90.0 075 918 0.80 935 085 95.2 0.90 96.7 0.95 98.2 1.00 99.6 1.01325 100.0 (atm) 001014 o.oo1015 0.001015 0.001016 0.001017 001017 0.001018 001019 6.001020 6.001021 0.001022 0.001025, 0.001027 0.001028 0.001030 0.001032 0.001033 0.001035 0.001036 0.001037 0.001039 0.001040 0.001041 0.001042 0.001043, 0.001044 10.02 9.43 891 845 8.03 765 700 645 5.98 5.58 523 433 3.99 3.98 3.24 2.96 2.73 233 2.36 222 2.087 1972 1,869 1777 1.694 1.673 226.0 231.6 236.9 242.0 2468 2515 260.1 268.2 2756 282.7 289.3 304.3 3176 3296 340.5 350.6 359.9 368.5 376.7 384.4 391.6 398.5 405.1 aud 4174 4190 2448.9 2450.6 2452.3, 2453.9 2455.4 2456.9 2459.6 2462.1 2464.4 2466.5 2468.6 2473.1 2477.1 2480.7 2484.0 2486.9 2489.7 2492.2 2945 2496.7 2498.8 25008 2502.6 2504.4 2506.1 2506.5 2260 2316 236.9 242.0 246.8 2515 260.1 268.2 275.7 282.7 2803 304.3, 3177 3296 340.6 350.6 359.9 368.6 3768 384.5 3917 398.6 405.2 aus 4175 419.1 2373.2 23700 2366.9 2363.9 2361.1 2358.4 2353.3, 23486 2344.2 23400 2336.1 23272 2319.2 23120 2305.4 22993 2293.6 22883 22833 2786 2741 269.8 2265.6 2261.7 257.9 2256.9 2599.2 2601.6 2603.8 2605.9 2607.9 2609.9 2613.5 26168 2619.9 2622.7 2625.4 2631.5 2636.9 2641.7 2646.0 2649.9 2653.6 2656.9 2660.1 2663.0 2665.8 268.4 2670.9 2673.2 2675.4 2676.0 “From R, W. Haywood, Thermodynamic Tables in $I (Metric) Units, Cambridge University Press, London, 1968. 7 specific enthalpy. Nove kik % 0.43 energy, and Hl Bulb. = specitie volume, O = specific (continwed ) SPO sAIqRL suodosg yeoishyg‘Table B.6 (Continued) Vm? kp) O(kaikg) ACKI/K P(bar) TCC) Water Steam __Water Steam Water Evaporation __ Steam 1 1023 0.001046 = 1.549 428.7 25092 4288 22508 26796 12 1048 ooords = 1.428 439.2 2512.1 B94 244.1 2683.4 13 107 o.or049 1.395 449.1 25147 449.2 2318 2687.0 14 1093 6.001051 1236 4583 25172 45K 2319 26003 1s m4 0.00103 1.159 4610-25195 467.1 2226.2 2693.4 16 1133 0.001055 1.091 475225217 4754 22209 2696.2 17 1152 0.001086 1.031 4830 25237 483.2 2187 2699.0 18 1169) 0.001088. 0.977 4905 2525.6 490.7 22108 27015 19 118.6 0.001059 0.929 497.6 25275 4978 2206.1 2704.0 20 1202 0.001061 0.885 5045 2529.2 504.7 2201.6 27063, 22 1233 0.001064 0810 5745324 5176 2193.0 27106 24 126.1 0.001066 0.746 529.4 2535.4 529.6 2184.9 mas 26 1287 0.001069 0.693 540.6 2538.1 540.9 21773 27182 28 1312 ooo107! 0.646 S51. 2540.6 5514 2170.1 215 30 1335 0.001074 0.606 561.1 2543.0 S614 21632 mar 32 1358 0.001076 0.570 506 2545.2 5709 2136.7 272016 34 1379 0.001078 0538 5796 25472 3799 21304 27303 36 1399 0.001080 0510 588.1 2549.2 5885 2144 27329 38 1418 0.001082 0.485 596.4 2551.0 596.8 21386 27353 40 143.6 o.0o1084 0.462 604.2 2552.7 604.7 21330 27376 42 145.4 0.001086 0.442 618 2554.4 6123 2127.5, 2739.8 44 147.1 0.001088 0.423 6191 2555.9 619.6 21223 27419 46 148.7 0.001089 0.405 626.2 2557.4 626.7 2117.2, 2743.9 438 1503 0001091 0.389 6330 25588 6335 21122 2745.7 50 1518 0.001093 0375 6396 2560.2 640.1 21074 20875 35 1353 0.001077 0.342 655.2 2563.3 655.8 2095.9 2751.7 60 1388 ooo = 0315 669.8, 2566.2 6104 2085.0 27355 6s 162.0 0.00105 0.292 683.4 2568.7 oat 20747 2738.9 70 165.0 0.001008 0273 6963 2571.1 ont 20649 2762.0 aupuoddy 991S 1678 0.001112 0.2554 7085 2573.3 709.3 2055.5 27648, 80 1704 0.001115 0.2403, 7200 2575.5 7209 2046.5 27675 85 1729 0.001118 0.2268 BL 2577.1 7320 2037.9 2769.9 90 175.4 0.001121 0.2148 7H.6 25788, 742.6 2029.5 27721 95 77 0.001124 0.2040 7518 2580.4 752.8 2021.4 2774.2 100 1799 0.001127 0.1943, 615 2581.9 162.6 2013.6 2776.2 105) 182.0 0.001130 0.1855 7108 2583.3, 772.0 2005.9 27780 110 184.1 (0.001133 01774 799 2584.5 14 1998.5 27197 ns 186.0 0.001136 0.1700 788.6 2585.8 789.9 1991.3 27813 120 1880 0.001139 0.1632 797.1 2586.9 798.4 1984.3 2782.7 125 189.8 0.001141 0.1569 8053 2588.0 806.7 19774 2784.1 130 191.6 001144 ost 813.2 2589.0 8147 1970.7 2785.4 “4 195.0 0.001149 0.1407 8285 2500.8 830.1 1987.7 20818 15 1983 0.001154 01317 842.9 25924 8447 1945.2 2789.9 16 201.4 0.001159 041237 856.7 2503.8 858.6 1933.2 20917 7 2043 0.001163 0.1166 869.9 2595.1 8718 1921.5 2793.4 18 207.1 0.001168 0.1103 882.5 2596.3 884.6 19103 27948 9 209.8 0.001172 0.1047 894.6 2597.3, 896.8 18993 2796.1 20 212.4 0.00117 0.0995 906.2 2598.2 908.6 1888.6 27972 21 2149 0.001181 0.0949 917s 2598.9 920.0 1878.2 27982 2 2172 0.001185 0.0907 9283 2599.6 9310 1868.1 2799.1 B 2196 0.001189 0.0868, 938.9 2600.2 9416 1858.2 20098 m4 2218 0.001193 0.0832, 949.1 2600.7 951.9 1848.5 2800.4 25 2239 0.001197 0.0799 959.0 2601.2 962.0 1839.0 2800.9 26 2260 0.001201 0.0769 968.6 2601.5 oT 1829.6 2801.4 2 228.1 0.001205, 0.0740 978.0 2601.8 981.2 1820.5 2801.7 28 230.0 0.001209 oo7i4 987.1 2602.1 990.5 IIL 2802.0 29 232.0 0.001213, 0.0689 996.0 2602.3, 999.5 1802.6 2802.2 30 2338 0.001216 0.0666 1004.7 2602.4 1008.4 1793.9 2802.3, 32 2374 0.001224 0.0624 1021.5 2602.5, 1025.4 17769 2802.3 34 240.9 0.001231 0.0587 1037.6 2602.5, 1041.8 17603 2802.1 36 2442 0.001238 0.0554 1053.1 2602.2 1057.6 17449 2801.7 38 2473 0.001245 0.0524 1068.0 2601.9 10727 1728.4 2801.1 (continued) Lp9 saiqey Auadorg pwoiskyg‘Table B.6 (Continued) Vim'rke) (ke) Atkiikg) P(bar) TEC) ater Steam Water Steam Water Evaporation Steam 40 2503 0.001252 0.0497 10s2.4 26013 1os74 17129 28003 2 2532 010001259 0.0473 1096.3 200017 LoL 1097.8 27094 44 256.0 01001266 0.0851 1098 25999 His 1682.9 27983 46 2588 0.001272 0.0430 11229 2509.1 1288 1668.3 20971 48 2614 0.001279 0.0412 1135.6 2508.1 Hans 1653.9 2798.7 50 263.9 0.001286 0.0394 1148025970 11545 1639.7 2798.2 32 266.4 0.001292 0.0378 1160.1 2595.9 1166.8 1625.7 27926 34 2688 0.001299 0.0363 1719 2594.6 11789 16119 27908 56 amd (0.001306 0.0349 1183.5 25933 11908 1598.2 27890 58 23 0.001312 0.0337 11947 2591.9 12023 1584.7 27870 60 2756 0.001319 0.0324 1205.8 25904 1213.7 15713 27850 oy ma 0.001325 0.0313 12166 25888 12248 15580 27829 “4 2798 0.001332 0.0302 12272 2587.2 1235.7 15449 27806 66 2818 0.001338 0.0292 1237.6 2585.5 1246.5 1531.9 27783 68 2838 0.001345 0.0283 1247.9 2583.7 12870 15189 27139 0 2858 0.001351 0.0274 1258.0 2581.8 1267.4 1506.0 27735 n 287.7 0.001358 0.0265 1267.9 2579.9 12776 1493.3, 27709 ” 2896 0.001364 0.0257 12776 2578.0 1287.7 1480.5 27683 1 214 6.001371 0.0249 1287.2 25759 12976 1467.9 27655 18 293.2 0.001378 0.0242 1296.7 25738 1307.4 14353 27628 80 295.0 0.001384 0.0235 1306.0 29717 13171 1442.8 27599 2 296.7 6.001391 0.0229 13152 25695 1326.6 14303 27570 84 2984 0.001398 0.0222 1324.3, 2567.2 1336.1 14179 27540 86 300.1 ‘0.001404 0.0216 13333 2564.9 1345.4 1405.5 27509 88 301.7 o.oo1ai1 0.0210 1342.2 2562.6 13546 1393.2 2478 90 303.3 0.001418 0.02050 1351.0 2560.1 13637 1380.9 27446 2 3049) 0.001425 0.01996 1359.7 2557.7 13728 1368.6 24 4 3064 0.001432 o.01945 13682 2555.2 1381.7 1356.3 27380 axpuaddy gro96 98, 100 105 10 1S 120 125 130 135 140 Mas 150 135 160 165 170 175 180 185 190 9s 20 205 210 215 220 212 (Critical point) 308.0 309.5 3110 3146 3180 3214 324.6 3218 330.8 3338 336.6 3304 3421 3448 347.3 349.8 352.3 354.6 3570 359.2 3614 363.6 365.7 367.8 369.8 371.8 373.7 374.15 0.001439 0.001446 0.001453 0.001470 0.001489 0.001507 0.001527 0.001547 0.001567 (0.001588 0.001611 0.001634 0.001658 0.001683 0.001710 0.001739 0.00170 0.001803 0.001840, 0.001881, 0.001926 0.001977 0.00204 0.00211 0.00220 0.00234 0.00267 0.00317 0.01897 0.01849 01804 0.01698, 0.01601 o.o1st1 0.01428 0.01351 0.01280 0.01213 0.01150 0.01090 0.01034 0.00981, 0.00931 0.00883 000837 0.00793 0.00750 0.00708 0.00668 60,0068 0.00588 0.00546 0.00502 0.00451 0.00373 0.00317 1376.7 1385.2 1303.5 1141 1434.2 1454.0 173.4 1492.7 1511.6 1530.4 1549.1 1567.5 1586.1 1604.6 1623.2 1641.8 1661.6 1681.8 1701.7 17217 1742.1 1763.2 1785.7 18107 18400 1878.6 1952 2038 2552.6 25500 2547.3 25404 33.2 2525.7 25178 2509.4 25006 2491.3, 2481.4 2471.0 2459.9 2448.2 2436.0 2423.1 2409.3 2394.6 2378.9 2362.1 23438 2323.6 23008 2744 2242.1 2198.1 2114 2038 13906 13993 1408.0 14295 14506 14713 1491.8 15120 1532.0 I5si.9 157L6 1591.3 loro 1630.7 1650.5 16705 1691.7 17133 17348 1756.5 1778.7 1801.8 1826.5 1853.9 1886.3, 1928.9 201 2108 1344, 1319 13197 12892 1258.7 1228.2 1974 11664 1135.0 1103.1 l77 1037.7 loos. 969.6 9343 8983 859.9 8200 779.1 7366 692.0 642 S919 532.5 4613 366.2 185 0 27347 212 247 21187 2709.3, 2699.5 2689.2 2678.4 2667.0 2655.0 2642.4 2629.1 2615.0 2600.3 25849 25688 2551.6 25333 25139 2493.1 24706 2446.0 24184 2386.4 23476 2295.2 2196 2108 salqny. Susodoag tworskug org,650 Appendix B Table B.7 Properties of Superheated Steam? Ptbar) Sard Sard | Temperature (C)— (20) Water steam | 50 8 100150250080 ee = 2595 «aes 2) 2g aT «ITT ec. 7 eee ei i ae eee ce aia . 4 7 = a es Se ot tis ass | 2599 6026s 2783288 ss) tre 280 | 2a 2a 2516588 Ses oom 147 ae 160 ays) ae aa) ms) os @ ane 26460 [2339] 2683 27) 30S ITT (13g sous aso | 2092339 | 25123586 3h) 289 ¥ ocoiws 324 | ooo —oons | 341389 3s ds gS to airs pense | 2093 ago | 2676 amass ans wos) sits 25061 | 2092 © 39 | sor 583 3ash sD ¥ oooios “169 | coor —oootas |e _ 94 24026287 30 A ear mars | 2097 © g43 aga 622] 85S amt 36S 68 css) 0 36 25602 | 20923138 ats ats | 2583 Sek 80) 288 F ooo 0375 | coor: amis oooioe oni | as2s 047s ©0502 30° A 26 a762 | 201g? signs | oars wes cs) 8 wis 2s | e137 a8? ats | 20a P ocotts 018s | cootor © .o0103 ammo oon» 20 m6 2972 | oss ans oat asa (iz) 2 06225982 | 290 3s ats ga 8502 ¥ oo118 0.09850 | coo1n: —on102 amis acol09 ovnrt6 40 wea e003 | m7). moa (2503) 0 10824 20013 | 2085 5307800 ¥ coors do997s | cooior olor auoiosaooi0y ants A 237 maso | 28 eras asa © 12088 25904 | 20833164173 ota P caoise 00x25 | ooo1or — apolgs amas a00t09 oooris A pi m9 | 261 3303852 O 1960 257 | 20g1 31236782889 ¥ 000139 0023s | eo0i01 00102 gio © a0107 amis to 8 eo 27 | 278 m9 aS GSS] 10858 Guo 8 5s 2573 | a8 Taig 73 BS OA ABI P oamiss oo1si | cooio1 —oooi02 —ammias 00109 00115 00124 00D lo 8 te0 asso | 21 808033850862 13382 Gary 2 15861 4599 | 2070 07 aig? © BHO 106771316 P gore —o0103 | ooox01 © ootc2 © o0ni04 amie ooniis 00123 amNI3 200A 1806S ass | 254 3000S hd 10867 (657) 2 17857 5008 | 2063309725772 s0T o.o020s 9005875 | como —cooice —om103 anos amis oonIz2 00036 zie.) R 2108 2108 | 2382373575 BoL4 1087013828 Gui) 9 20078 2078 | 060 3092 sso 63TH) 1809 owsi7 coosi7 |_cooto0 _oootar _oooius _a.00108 _ounlis a.00122 0.00135 2 8 7 BOT SOT GT sas 408TS SLT oO os = 2057 a7 422084 1052012978 p= = 00109 ooo1et-—oo0103 oo0108 900113 amntz2 —ooOLss cr t= meso aL ans so mas2— oma 13287 ooo 7 m0 Son? 108 G87 BSS 10SDL—12887 = = 000850 ooOIoL 00103 cOI0T oops onw12t _a.mMI33 mf = = 293542568 wok ISA 10936 BBE Oo ef = mre 300s alias 2593 eo — 00008911 0.00100 ooia2 Laois o9o11T MoI aaN129 100 = 93S aS ROMS NBO 1ST Oo os = 1965 3957051 S044 7983 9990 aL eo = 00009737 0.009852 o.001000 coDios 00108 ots oo0rz2 “Adapted from R. W, Haywood, Thermodynamic Tables in SI (Metric) Units, Cambridge University Press, London, 1968. ‘Water isa liquid in the enclosed region between SO°C and 350°C. Hl = specific enthalpy (kitkg), 0 = specific internal energy (Klis), ¥ = specific volume (m'/kg). Now: kkg x 0.4303 = Btulb,, (continued )Physical Property Tables 651 ‘Table B.7 (Continued) Pier) ‘Temperate CO)— a) moss 00280 aes Tse? rosso 10 een se seat re 00) aga ee ee ee es se) «ss 0 ea? ee ee i ake a7, 0 25 us a2 os 2 3m 85 wie 39a. oy 0 me oe mas 30S STL 0 6 ert 758 ass 901 10 RST 3g 3885 sais a8 os) 0 me Da 0 OM (ue an ook 46 so 8 mm a a9 3813 (sis) 0 213s sa 338 Post? O68 OT O75 oso wo Reems ae sau (7s) 0 258 ea 5335 Pom 03 035) aT? oan mR mo 58 ek 3602 ey 0 m6 sa a9 aist als 07s ake oa wo Re Bae 788 es) 2 22 Soma B63 80 P ouT 0079» anes os ous oath C0 im ee Ss ame 3802 ere) C28 8 37 Asi P oous —oaszt 565.0809 0063 o0T3s ia ee m9 sao (350) 0286729 ags_ 59 is hat P cos 003s oae17 —oiso sts nse to kas a0 mus 367 Guy 2 eeu Sera Emer 00x 00298 ase s6 ooo aos 10 Rasa as 57083835 Gey 0 ne 285 hos sor 7 P oo1s? ois azo 0.229 ast 0028s 20 2 tay 0k ask a8 Son (657) 0 deg me ie P ooo 00127 ool oi oat nie) 2 ms MDa 3683380 Guin) 0 23 m6 mas zs ® ooosis? —ooti0 90130 oie 001% dors 2 oR 2s 3165607 23am ie) 6 ms 830 e356 ° oompi7e coun pier avis o0i66 ea 2s sos, a7 a5 a0 oO 6 203 aso zis Sa est P o0w2sso 000673 oan¥sso 0102 ons 00136 nie sof ee mms weakest, 0 am as aaah atk 8D P 00175 o.0R861 oom88s2 OONSLI2omDs!12aUTIM —a0nTT=2 oDuEsIE wo OL ag 8a aHus N06 8 tess taka ess dst P oonisis 000168 oaoi8es oMmmH6 2654 a0usIOs a0536 —a0N%85D652 Appendix B Table B8 Specific Enthalpies of Selected Gases: SI Units eee eee A(kiimol) Reference state: Gas, Pry = 1 atm, Ty = 25°C T Air Op No Hh COCO, OE Oe 0) “0-073 -073 -072 -073 -092 -084 0.00 0.00 0.000.000.0000 Ssi>. 219 224-219-216 29-202 SIS S31 S13 5065.16. 7.086 tye ea ei) | 796 a7 se 057) 124 11.72 1151089 11.25 16351323 1437 150314241383 143821341701 1755 1841 1739 168117372653 20.91 2080 2186 2059 «1981 20823188 24.92 2410 2535 2386-2285 «2413-3736 ©2905 2746 2889 2719-2593 749 42.94 3332 1000-3086 32.47 3056 © 2904 «9148.60 37.69 11003431 36.07 33.99 3219 3437 54.33 42.18 12003781 39.70 37.46 3539 3787 60.14 46.78 1300 4134 4338 ©4097-3862 41.40 65.98 51.47 14004489 47.07 4451 41.90 4495 71.89 56.25 1500 4845 50.77 48.06 45.22 4851—-77.84 «61.09 er ee SSSSSSSFEu- Table B.9 Specific Enthalpies of Selected Gases: American Engineering Units eee SSS A(Buwilb-mole) Reference state: Gas, Prt T Air Qe 320-312-315 312 1 0 o 0 100 160162160 20000 858875857 BAB 85912 300 1563 160215581539 1564 2108-1818 400 227523422265 2231 227631292652 500 2993-3094 2976-2925 29944192 3499. 600 700 800 900 3719-3858 369436213720 52034359 4451 46334418 4319454 6495233 S192 S418 S150 S021 S195. 75996122 5940 621258895725 5943, 8790 7025 1000 6695 7015-6635. 6433«6702. «100157944 110074597826 73997145. 7467112638880 1200 8230-8645 S151 7861 823912533983] 1300 90109471 89228581 90213820 10799 14009797 10304-9699 9306 9091512211783, 1500 1059011142 10485 1003510606 16436. 12783, 160011392 1198811278 10769 1140917773 13798 1700 1220012836 1208011509 12220 1911914831 1800 1301613691 1288812254 13036 2046915877 1900 13837 1455113702 1300313858 2184016941, 200014663 1541514524 1375914688 232111819Table BALL Integral Heats of Solution and Mixing at 25°C Physical Property Tables 653 Table B.10 Atomic Heat Capacities for Kopp’s Rule* Cuddl(g-atom*C)} Element Solids Liquids c 75 2 H 96 18 B ul 20 Si 16 24 ° a 25 F 2a 29 Pp B 31 s 26 31 All Others 26 3 “D.M. Himmelblau. Basie Principles and Calculations in Chemical Engineering, 3rd Euition. Prentice-Hall, Englewood Clits NJ. 1974. p. 270. ee ee (AA Dicuy (AA son r(mol H,O/mol solute) _ kJ/mol HCI kJ/mol NaOH. 0s i 15 2 3 4 5 10 20 28 30 40 50 100 200 500 1000 2000 5000 10000 50000 100000 500000 26.22 = 48.82 = =36.85 28.87 61.20 34.43 64.05 -37.74 69.49 4251 -T178 42.84 -72.59 42.72 =73.00 42.59 -13.26 42.51 85 4234 =74.20 42.26 -7452 42.38 14.68 42.47 -74.82 ~4255 -74.93 42.68 ~74.99 -4272 75.08 =42.80 75.10 = 75.14 42.99 (Ala) xss04 kJ/mol H2SOs 15.73 28.07 36.90 41.92 48.99 54,06 58.03 67.03 -72.30 -73.34 -73.97 ~16.73 ~7857 84.43 ~87.07 93.64 95.31 =96.19 a ea “From J. C. Whitwell and R. K. Toner, Conservation of Mass and Energy: pp. 344-346. Copyright © 1969 by McGraw-Hill, Inc. Useu with permission of McGraw-Hill