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We Create Chemistry: That Makes Coatings Love Resins and Additives
We Create Chemistry: That Makes Coatings Love Resins and Additives
Innovatielaan 1
8466 SN Nijehaske
We create chemistry
that makes coatings
P.O. Box 390
8440 AJ Heerenveen
The Netherlands
BASF SE
67056 Ludwigshafen
Germany
www.basf.com/resins
The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.
Table of contents
Renewable systems 59
BASF’s Biomass balance apporach 60
Natural oil-based polyols 62
Properties of natural oil-based polyols 68
4 Market technology matrix
2019
Market technology matrix
2019 5
Water-based systems
Colloidals and non-cross-linking acrylic dispersions Joncryl® / Acronal® 20 1 1 - - - - - - - - - -
Polyisocyanates Basonat ®
32 - 1 1 1 - 1 1 1 1 1 1 1
Epoxy resins 34 - - - - - 1 - - - - 1 1
Waterpoxy®
Amine adducts 34 - - - - - 1 - - - - 1 1
Solvent-based systems
Acrylic polyols Joncryl® 46 - 1 1 1 - 1 - - - 1 1 1
Polyisocyanates Basonat ®
52 - 1 1 1 - 1 1 1 1 1 1 1
Amine Laromin® 54 - - - - - - - - - - 1 1
Renewable systems
Natural oil-based polyols Sovermol® 64 - 1 1 1 1 1 - 1 1 1 1 1
6 Market technology matrix
2019
Market technology matrix
2019 7
Radiation-curable systems
Epoxy acrylates 82 1 1 1 1 1 - - - 1 - 1 1
Polyester acrylates 84 1 1 1 1 1 - - - 1 - 1 -
Unsaturated polyesters 90 1 1 1 1 1 - - - 1 - 1 1
UV specialties 90 1 1 1 1 1 - - 1 1 1 1 1
UV monomers 92 1 1 1 1 1 - 1 1 1 1 1 1
Water-based UV resins 94 1 1 1 1 1 1 - - 1 1 1 -
Formulation additives
Solvent-based and solvent-free systems
Defoamers 112 1 1 1 1 1 1 1 1 1 1 1 1
Performance additives
UV absorbers 144 1 1 1 1 1 1 1 1 1 1 - 1
Chimassorb® / Tinuvin® /
HALS 146 1 1 1 1 1 1 1 1 1 1 - 1
Lignostab®
Light stabilizer blends 148 1 1 1 1 1 1 - - - - - -
Antioxidant blends - - - - - - 1 - - 1 1 -
Our goal is to understand the unique challenges faced by each industry as well as
the impact of the respective market trends. Our dedicated team works to develop
innovative, custom-made, and sustainable solutions to advance your formulations.
Take a look at our far-reaching portfolio. In collaboration with our experts you will
surely find the perfect match of products to suit your needs. This brochure will give
you an overview of the comprehensive and steadily growing portfolio. Our recent
product launches are marked with NEW.
Water-based systems
Water-based
Bitte Kurzversion des Kapiteltitels systems
eintragen
2019 1111
2019
Water-based systems
We are driving market conversion by setting new trends and industry standards
in terms of cost and performance.
In our view, finding the best match means delivering We provide a broad technology toolbox consisting of
high-performance for your formulation without several water-based technologies offering a variety of
harming the environment. For example, our products choices to match your specific requirements – ranging
make it possible to produce long-lasting and resilient from acrylic dispersions to polyurethane dispersions
coatings while, at the same time, reducing the output and polyurethane acrylic hybrids.
levels of volatile organic compounds (VOC).
Water-based systems
12 Water-based systems
2019
Water-based systems
2019 13
Acrylic dispersions
for water-based systems
Rheology profile Joncryl®
Acronal® PRO, Joncryl®, and Luhydran® dispersions are the key product lines within
our comprehensive portfolio. They allow you to choose from a range of water-based
technologies and can be formulated according to the desired application method:
spraying, dipping, roller, and curtain coating, as well as manual applications such as
brushing and rolling.
The interior wood furniture and flooring market is very diverse. It encompasses Selected recommendations Selected recommendations for medium-/
assembled contemporary furniture, cabinets, self-assembled flat-stock furniture for for economic flat-stock furniture high-quality furniture and flooring
home and office, as well as parquet and solid wood, ranging from factory-applied Colloidal Conventional RC
be modified – from a natural look to strong grain our water-based dispersions and system solutions Joncryl® 77-E Joncryl® 1915-E Joncryl® 8224 Joncryl® HYB 6336
enhancement. designed to match your targeted properties. Joncryl® 79 Joncryl® 8225 Joncryl® HYB 6430
Low VOC
Joncryl 8223
®
Joncryl® U 4190
Joncryl® 8225
The biggest challenge within the industrial metal coatings industry today is providing
Primer / monocoat matt DTM / monocoat glossy
Product maturity
environmentally sustainable products that offer the perfect balance between coating
Joncryl®
properties and performance attributes. The range of acrylic emulsions that we offer PRO
1555
Joncryl® Joncryl® Acronal® Established
should be able to meet your needs. PRO
1532
PRO
1537
PRO
8977
Acronal® Acronal®
Joncryl® PRO Acronal® Acronal®
PRO 761 PRO PRO
PRO 763
(250–400 Growing
Customer support is well served with products applications while also providing the latitude to 1522 763 780 µm)
designed to attain high-performance in clear and optimize product performance attributes such as wet Acronal®
Joncryl® PRO
pigmented coatings. Our portfolio’s diversity of and dry adhesion, early water resistance, corrosion PRO 7600
(new)
1554
products allows the coatings manufacturer to design and chemical resistance, hardness, good intercoat (new) Acronal®
PRO
coatings for primer, direct to metal, and topcoat adhesion, and excellent exterior durability. 770
(new)
New
C2 C3 C4 C5
Acronal® PRO 770 (new) Superior performance Improved corrosion resistance and chemical
Active corrosion protection (barrier against
Primer oxygen, water + ions) + adhesion to metal Joncryl® PRO 1554 (new) resistance (new technology); improved wet
80 µm surface + provide surface for adhesion DTM coating High gloss, chemical + UV resistance adhesion
25–40 µm no anticorrosive pigments Workhorse, benchmark, robust, good
Acronal® PRO 761
application properties, good early water
Metal Metal Acronal® PRO 7600 (new) Good corrosion resistance and chemical
resistance, adhesion to galvanized steel Joncryl® PRO 1522
resistance
Universal, cost-effective; especially suited
Acronal® PRO 763
for thick layers (> 80 µm) Joncryl® PRO 1532 Fast drying, block resistance
Acronal® PRO 780 Improved corrosion resistance Joncryl® PRO 1537 Improved hardness vs. Joncryl® PRO 1532
Acronal® PRO 8977 Improved block resistance, harder High anti-blocking, good adhesion,
Joncryl® PRO 1555
fast drying
Water-based systems
18 Water-based systems
2019
Water-based systems
2019 19
Joncryl® and Basonol® PU polyurethane PUD (special properties) Joncryl® OH and Basonol® AC Basonat® polyisocyanates for
dispersion and Joncryl® HYB acrylic / Drying process: phase separation OH-functional acrylic dispersions water-based systems
PUD hybrid dispersions
Joncryl® / Basonol® PUD and acrylic / PUD hybrid Besides the OH-functional primary dispersions Joncryl® Years ago it was unthinkable to use polyisocyanate
dispersions are manufactured using an NMP- and OH and Luhydran®, BASF has developed Basonol® AC, cross-linkers in water-based coatings.
NEP-free process, resulting in solvent-free products. a completely new class of core-shell, OH-functional Hydrophilic modifications of aliphatic polyisocyanates
Due to the chemical structure of phase-separated hard Hard phase dispersions with very low emulsifier content that are opened the field of 2K PU coatings to water-based
and soft domains, this product class exhibits a wide Rich in H-bonds especially suited for high-gloss 2K PU topcoats. applications.
variety of unique properties that can be tailored for and electrostatic They can compete with traditional secondary acrylic The Basonat® HW range allows the manufacturing of
different coating applications on wood, metal, and interactions: dispersions at a lower isocyanate demand. water-based 2K PU coatings with a sufficiently long pot
plastic. physical cross-linker life and a broad formulation latitude, with properties
close to those of solvent-based 2K coatings.
N-C-O-R-O
Soft phase The hydrophilic modified polyisocyanates from the
HO
(Mainly macrodiols) Basonat® HW range are emulsifiable in water, as
OH HO
C-N-R-N-C control of elastic supplied, or can be diluted with suitable solvents. For
properties example, they can be used together with OH-functional
acrylic dispersions and PUDs.
The low viscosity polyisocyanates from the Basonat® HA
range can be incorporated homogeneously into
secondary dispersions, like PUDs.
Advantages of PUDs
Synergistic
combination of the
Better-defined
water phase
“best of two worlds”
Mechanical properties
Film formation
Appearance
Hybrid technology
Advantages of acrylics
Water-based systems
20 Water-based systems
2019
Water-based systems
2019 21
Colloidals
Excellent penetration, minimal grain raising, excellent clarity and sandability,
Joncryl® 95-E Translucent dispersion 30.0 100 8.0 70 20 43 fast drying. Alkali-soluble dispersion for quick-drying interior stains, wood 2 - 2 - - - -
sealers
High viscosity at low solids content, high transfer with roller coaters, good
flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as
Joncryl® 661 Semi-translucent dispersion 44.0 60 2.1 154 - 70 2 - 2 - - - -
a thickener in various acrylic water-based paints, especially for roller coating
applications
High viscosity at low solids content, high transfer with roller coaters, good
flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as
Joncryl 663
®
Semi-translucent dispersion 40.0 450 6.2 131 - 30 2 - 2 - - - -
a thickener in various acrylic water-based paints, especially for roller coating
applications
High transfer with roller coaters, good flow, leveling, and good pigment
wetting. Alkali-soluble dispersion for use as thickener in various acrylic
Joncryl 670
®
NEW Semi-translucent dispersion 46.0 85 4.5 - 12 - 2 - 2 - - - -
water-based paints, especially for roller coating applications. Increased
solids content compared to Joncryl® 663
Joncryl® non-cross-linking
acrylic dispersions
1 Suited 2 Highly recommended
Good water resistance, good intercoat adhesion with 100% UV systems, good
Joncryl® 8223 Semi-translucent dispersion 30.0 250 8.2 100 <5 21 2 - 2 - - - -
pigment wetting, dispersion for economic industrial wood and board primers
Very fast drying, excellent block resistance and stackability, dispersion recom-
Joncryl® 8224 Translucent dispersion 45.0 70 7.7 53 10 - 2 2 2 - - - -
mended for primers and topcoats
Excellent clarity, very fast drying, good block resistance, good stackability.
Joncryl® 8225 Translucent dispersion 45.0 75 7.8 57 <5 - Low-VOC dispersion for use in fast industrially applied clear lacquers for 2 2 2 - 2 - -
furniture and flat-stock coatings
Excellent scratch resistance and block resistance, fast drying, good chemical
Joncryl® 8226 Semi-translucent dispersion 42.0 75 7.9 36 20 - resistance and clarity. Dispersion for industrial interior wood coatings on fast 1 2 2 - - - -
lines
Corrosion protection without the use of active pigments at 30–40 µm dry film
Joncryl® PRO 1522 Translucent dispersion 45.0 400 9.0 - 26 34 thickness, high gloss, exterior durability and compatibility with anticorrosive - 2 - 2 - - -
pigments, corrosion category medium duty, C2–C3 topcoat, direct to metal
High Tg, good hardness development, good water and chemical resistance,
Joncryl® PRO 1537 Translucent dispersion 46.0 250 8.4 49 45 46 1 1 1 2 - - -
good adhesion; application: industrial and wood coating primer on primer
Improved corrosion resistance (at 30–40 µm dry film thickness) and chemical
Joncryl® PRO 1554 NEW Semi-translucent dispersion 41.5–44.0 250–1,750 7.5–8.9 30 25 - resistance (new technology); improved wet adhesion, high gloss, exterior - 2 - 2 - - -
durability, corrosion category medium duty, C2–C3
High gloss, high hardness, fast drying and UV resistance, good chemical
Core
Joncryl® 8322 Semi-translucent dispersion 41.0 500 8.6 18 30 resistance and sandability; economical, good clarity; application: topcoat for 1 2 2 2 - 1 -
shell
wood and industrial coatings (corrosion category light duty, C1–C2)
Clear and pigmented coating; high clarity and chemical resistance, excellent
Core block and hardness development; blending partner for UV dispersions;
Joncryl 8330
®
Semi-translucent dispersion 38.0 50 8.1 25 33 1 2 2 1 - 1 -
shell application: topcoat for wood and industrial coatings (corrosion category light
duty, C1–C2)
Core Good scratch resistance, dispersion for interior with superior plasticizer and
Joncryl® 8333 White dispersion 45.0 250 7.2 24 58 1 2 2 1 - 1 -
shell hand cream resistance
Fast drying, good block resistance, good blending partner to reduce the
Core
Joncryl® 8336 Semi-translucent dispersion 40.0 75 8.0 25 <5 solvent demand, balanced chemical resistance. Dispersion for industrial 1 2 2 1 - 1 -
shell
applied clear and pigmented finishes for primer and topcoat
Excellent stain resistance, very good solvent resistance and excellent blocking
Core resistance, enabling IKEA R2 and DIN 68861-1B in pigmented formulations.
Joncryl® 9502 NEW White opaque dispersion 42 75 8 45 40 2 2 2 1 1 - -
shell Provides good grain enhancement (“Anfeuerung”) on different wood types as
clear coat
OH-functional dispersions
Dispersion for 2K PU high-performance, high-gloss topcoats; excellent
Basonol® AC 1120W NEW White dispersion 42.5 100 7 15 <5 120 compatibility with polyisocyanates, excellent gloss and leveling in combination 1 2 1 2 1 - -
with very good chemical resistance, good flexibility and scratch resistance
Polyurethane dispersions
Basonol® PU 1035 W is used in 1K stoving and 2K primer applications for
plastic and metal substrates; excellent adhesion to various substrates (plastic,
Basonol® PU 1035 W NEW Translucent dispersion ~ 43 ~ 35 6–8 35 - <0 e-coat, metal); excellent flexibility; formulation robustness; universal blending 2 - - 2 2 - -
partner for acrylic dispersions; zero add-on of NMP, NEP, and other organic
solvents
Soft PUD with good adhesion on metal substrates, very elastic at good
Joncryl® U 4310 Semi-translucent dispersion 40.0 < 100 8.0 - - <2 toughness, high chemical resistance, heat resistant, high gloss, good barrier 1 - 1 1 - 2 -
to water and water steam; suitable for glass fiber sizing
PUD especially developed for basecoats with improved drying speed; good
Joncryl® U 5168X NEW White dispersion 36.0 ~ 78 7.8 - - <5 2 2 - 2 2 2 -
pigment-wetting properties
Water-based systems
30 Water-based systems
2019
Water-based systems
2019 31
Free Substrate
Non-volatile at Viscosity at Temperature Acid
Product Type of product Solvent formalde- Key properties
2 h, 125 °C [%] 23 °C [mPa·s] reactivity reactivity Wood Metal Plastic Glass Concrete
hyde [%]
Melamine-formaldehyde resin / methanol-butanol-mixed-etherified
Mixed-etherified melamine resin, Methanol-butanol-mixed-etherified resin for water-based and solvent-based coatings;
Luwipal® 052 69 – 72 4,000–6,500 Butanol Medium - < 1.0 1 2 - 1 -
high methylolation degree high baking reactivity; for automotive application
Melamine-formaldehyde resins / methanol-etherified
For water-based coatings. Very high baking reactivity, for furniture foil and industrial
Luwipal® 063 Melamine resin, high imino content 68 – 72 500–800 Water High Low < 0.6 1 2 - 1 -
applications
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for
Luwipal® 066 93 – 96 2,000–6,000 - Low High < 0.6 1 2 - 2 -
fully methyl-etherified furniture foil and coil-coating applications
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for
Luwipal® 066 LF 93 – 96 2,000–6,000 - Low High < 0.3 1 2 - 2 -
fully methyl-etherified furniture foil and coil-coating applications: low formaldehyde content
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for
Luwipal® 066 ULF 93 – 96 2,000–6,000 - Low High < 0.1 1 2 - 2 -
fully methyl-etherified furniture foil and coil-coating applications; no CMR labeling
Melamine resin, high etherification Methanol / For solvent-based and water-based coatings. Medium to high reactivity, for furniture foil
Luwipal® 069 79 – 83 2,500–3,500 Medium Medium < 1.5 1 2 - 1 -
degree ethanol and industrial applications
Melamine resin, balanced For solvent-based and water-based coatings. High baking reactivity, for furniture foil,
Luwipal® 072 73 – 77 4,000–7,000 Isobutanol High - < 1.0 1 2 - 2 -
imino-methylolation degree coil, automotive and industrial applications
Melamine resin, balanced For water-based coatings. High baking reactivity, for furniture foil, coil, automotive and
Luwipal® 073 78 – 82 3,000–5,000 Water High Low < 0.5 1 2 - 2 -
imino-methylolation degree industrial applications
Melamine resin, balanced For water-based coatings. High baking reactivity, for furniture foil, coil, automotive and
Luwipal® 073 LF 78 – 82 3,000–5,000 Water High Low < 0.3 1 2 - 2 -
imino-methylolation degree industrial applications; low formaldehyde content
Carbamate resins
Carbamate resin / Carbamate resin for water-based coatings; medium to high acid reactivity. For foil and
Plastopal® BTM N / A 2,500–3,700 Water Low Medium < 2.1 1 2 - 1 -
medium-etherified furniture coatings
Carbamate resin / Carbamate resin for water-based coatings; medium to high acid reactivity. For foil and
Plastopal® BTW 75 – 79 1,000–1,500 Water Low Medium < 0.8 1 2 - 1 -
medium-etherified furniture coatings with lower formaldehyde content than Plastopal® BTM
Water-based systems
32 Water-based systems
2019
Water-based systems
2019 33
Basonat® polyisocyanates
Viscosity at 23 °C
Product Type of product Solids by weight [%] Solvent NCO [%] Key properties and applications
[mPa·s]
Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 2000 HDI allophanate 100 500–900 - 18.5–21.5
water-based 2K PU wood coatings
Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 3000 HDI allophanate 100 200–400 - 19.0–20.0
water-based 2K PU wood coatings
Low-viscous trimer for high-solid 2K PU coatings without limitation in chemical resistance and reactivity. It can also be combined with water-emulsifiable Basonat® HW types and
Basonat® HI 2000 NG HDI isocyanurate low-viscous 100 900–1,500 - 22.5–23.5
secondary dispersions for water-based 2K PU wood coatings; NG: reduced color drift in formulations
Hydrophilically modified HDI Easy-mixing version of Basonat® HW 1000 providing a combination of fast drying and easy mixing for water-based 2K PU systems in combination with primary and secondary
Basonat® HW 2000 100 1,500–3,000 - 17.5–18.5
isocyanurate dispersions
Hydrophilically modified HDI All-purpose, hydrophilic polyisocyanate for general use with primary and secondary dispersions in water-based 2K PU coatings for low VOC systems with balanced properties
Basonat® HW 2100 100 2,000–3,600 - 16.9–17.9
isocyanurate regarding miscibility, resistance, and reactivity
Hydrophilically modified HDI Easy emulsification in combination with high chemical resistance. New patented stabilization technology. Low solvent demand for hand mixing together with fast hardness
Basonat® HW 4000 100 3,000–3,500 - 18.5–19.5
isocyanurate development. Compatible with primary and secondary dispersions for use in DIY 2K PU floor coatings or high-quality furniture coatings
Water-based systems
34 Water-based systems
2019
Water-based systems
2019 35
Hydrogen Substrate
Type of Solids by Viscosity High Specific gravity Epoxy
Product Appearance Key properties equivalent weight
product weight [%] [mPa·s] thickness [g/cm3] equivalent weight Wood Metal Plastic Glass Concrete
(HEW)
Epoxy resins
Particularly useful in the formulation of industrial maintenance and concrete
Emulsion of solid
protection coatings; offers combined with Waterpoxy® 751 as curing agent
Waterpoxy® 1422 epoxy resin in Milky emulsion 55 4,000 No 0.96 1,150 - 2 - 1 2
fast tack-free and curing times as well as good chemical resistance; improved
water
gloss and hardness compared to Waterpoxy® 1455
Hydrogen Substrates
Type of Solids by Viscosity High Specific gravity Free amine Yellowing
Product Appearance Key properties equivalent weight
product weight [%] [mPa·s] thickness [g/cm3] content [%] resistance Wood Metal Plastic Glass Concrete
(HEW)
Amine adducts
Excellent wetting, flow, and resistivity properties, for concrete and metal
Water-based protection formulations (i.e. primers, protective coatings, self-leveling
Waterpoxy 751
®
Solution 59 11,750 Yes 1.09 ~ 0.2 High 225 - 2 1 1 2
amine adduct floorings); combined with Waterpoxy® 1455 / 1422, it offers very fast drying
speed and very long pot life
Curing agent solution; very low shrinkage properties makes it useful for
water-based epoxy self-leveling flooring with high thickness application; used
Water-based
Waterpoxy® 760 Solution 60 6,500 Yes 1.09 ~ 0.2 High in combination with standard liquid epoxy resin, it shows a definable end 210 - - - 1 2
amine adduct
of pot life and good chemical resistance; low temperatures do not limit the
application and curing behavior
Grinding resins
Joncryl® 8078 Clear liquid 32.0 1,750 8.3 224 8,500 101 Excellent pigment wetting, resolubility, compatibility, and rheology stability for pigment pastes
Joncryl® HPD 71-E Clear liquid 31.0 200 8.5 221 17,000 120 Excellent viscosity stability, pigment wetting, and color development
Joncryl® HPD 496-E NEW Clear liquid 34.5 500 8.5 178 5,500 58 Enables high-concentrated dispersions, excellent color development, low maintenance, pH-neutral
Joncryl® Wax 35 Additive Semi-translucent dispersion 34.5 25 9.8 130 Polyethylene wax to improve scratch resistance, slip, and block resistance
Solvent-based systems
Solvent-based systems
Melamine curing 1K stoving technology is still a widely and surface hardness at a high flexibility with the poly
Solvent-based systems
performance behavior is still unbeatable compared to especially pancreatin, tree resin, and petrol resistances.
other curing technologies. Basonol® HPE can significantly The properties of the final film can be significantly superior
boost chemical and mechanical performances to a level to the pure acrylate system. BASF’s unique cross-linking
close to 2K Polyurethane coatings. Basonol® HPE as co- technology and the right choice of monomers to build up
binder in acrylate / melamine curing systems can improve the highly branched polyester provides high weathering
the network density to increase chemical resistance, stability and reduced sensitivity to hydrolysis.
Polyisocyanates for conventional
and high-solid 2K PU coatings BASONOL HPE 1170B
®
BASONOL HPE 1170 B BASONOL HPE 1170 B
Acrylate 10% Basonol® HPE 1170 20% Basonol® HPE 1170 Acrylate 10% Basonol® HPE 1170 20% Basonol® HPE 1170
reference reference
§§ Slight increase of surface hardness at longer oven §§ 20% of Basonol® HPE 1170 B has significant impact
Basonol HPE hyperbranched polyesters
® drying time on surface hardness
§§ More hardness / reactivity at low temperatures
100 – 120 °C
For environmental and workers’ protection in 2K PU a complementing solution is needed to address a
coatings, low- to medium-solids solvent-based possible drop in curing speed and hampered hardness
systems can be substituted by high-solids solvent- and resistance of the cured film. Using Basonol® HPE as Daimler Etch Test – tree resin resistance and pancreatin
based systems. Two options for achieving high-solid a co-binder improves curing speed at increased pot life Tree resin resistance 30 32 34 36 38 40 42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 °C
content are reducing the molecular weight of polyols in systems based on low molecular weight polyacrylates Acrylic reference
and reducing the glass transition temperature. and polyisocyanates. The recommended dose rate is
+ 10% HPE 1170B
To leverage the full potential of these systems, 5–30% (solids on resin solids).
+ 20% HPE 1170B
+ 10% HPE 1265B
+ 20% HPE 1265B
Conventional 2K PU High-solid 2K PU §§ Minimal impact on VOC Joncryl® polyol grades are hydroxyfunctional acrylic chemistries to improve performance at reduced VOC
copolymers for solvent-based coatings. They can be levels. Basonol® HPE is an especially effective co-binder
used as binders for cross-linking with polyisocyanates for producing outstanding coating performances in
such as Basonat® or in combination with other binder low-VOC systems.
42 Solvent-based systems
2019
Solvent-based systems
2019 43
Solvent-based systems
Luwipal® grades – Plastopal® grades – Luwipal® and Plastopal® grades /
Melamine-formaldehyde Urea-formaldehyde resins non-volatile content (NVC)* versus reactivity**
and benzoguanamine resins
1 Methanol-etherified melamine resin 1 Benzoguanamine and mixed-etherified melamine resins 1 Butanol-etherified melamine resins 1 Urea resins
Applications for this class of products include baking Applications for this class of products include baking
finishes, acid-curing finishes, and physically drying finishes, acid-curing finishes, and physically drying NVC (%) NVC (%)
finishes. Both solvent-based and water-based systems finishes. Depending on resin structure, both solvent- 100 100
A B
may be formulated, depending on the resin structure. based and water-based systems can be formulated.
Luwipal® grades are the preferred choice wherever In contrast to melamine-formaldehyde resins, 80 80
the paint finish must provide resistance to weathering, Plastopal® grades are the preferred choice in cases
yellowing, and chemicals, and especially hardness and where the paint finish requires good adhesion, 1
1
luster. resistance to overbaking, flexibility, and economic 60 60
Solvent-based systems
Compatibility Viscosity profiles
of Laropal® A 81 of Laropal® A 81 in various solvents
9,000
Cellulose nitrate 1
8,000
Ethyl cellulose 0
Laropal A 81 ®
7,000
Cellulose acetobutyrate 1
Laropal® A 81 has an excellent reputation as a Laropal® A 81 does not yellow, and is highly resistant Chlorinated rubber 1 6,000
Viscosity [mPa·s]
high-quality aldehyde grinding resin. Its outstanding to the effects of humidity and temperature. This means VC copolymers 1 5,000
compatibility with all the main binders and organic that it can be used for all outdoor applications in
solvents used in industrial coatings makes it the 1K acrylic, 2K PU, or stoving systems. Laropal® A 81 Acrylic resins 1 4,000
preferred solution for universal mixing systems and aldehyde resin by BASF is a world-class binder for Urea-formaldehyde resins 1
3,000
pigment pastes alike. producing highly compatible solvent-based pigment
Melamine-formaldehyde
pastes. resins 1 2,000
When combined with our Efka® dispersing agents,
Alkyd resins 1 1,000
pigment pastes with the following properties can be BASF’s universal Laropal® grinding resin is the market
created: high pigment loading, excellent color strength, standard for all state-of-the-art mixing systems. As well Epoxy resins 1 0
and good flow behavior combined with a high degree as increasing the efficiency of your mixing processes, 70 65 60 55 50
Hydrocarbon resins 1
of stability. this highly flexible product reduces inventory and saves Laropal® A 81 [%]
Laropal® A-8L
One fits all –
Laropal A-8L is a liquid grinding resin. Since it is an
®
On top of that, easier handling is guaranteed since the Laropal®, the universal grinding resin for mixing systems
aldehyde-based resin, it is as universal as Laropal® dilution step can be skipped, no dust is released
A 81. Laropal® A-8L has been designed in such a way, during processing, and it is easy to pump. Without Laropal® With Laropal®
that, compared to pigment pastes based on Laropal®
A 81, significant lower VOCs can be reached (depending Pigment
on pigment).
4 pigments 4 pigments
1
Nitrocellulose 2
Two-component polyurethane 3
Epoxy
46 Solvent-based systems
2019
Solvent-based systems
2019 47
Solvent-based systems
1 Suited 2 Highly recommended
OH number Substrate
Solids by Viscosity OH number
Product Appearance Solvent Tg [°C] on solids Key properties and applications
weight [%] [mPa·s] on solids [%] Wood Metal Plastic Glass Concrete
[mg KOH/g]
100% solid polyol used in both 2K PU and acid-curable coatings offering good chemical resistance and
Joncryl® 581 Clear solid resin 100.0 Solid - 62 4.7 155 2 2 1 1 -
hardness. Solid polyol suitable for high-quality furniture and floor coatings in solvent-based systems
Good outdoor durability, high gloss, and gloss retention. Conventional-solids workhorse polyol, very fast
Joncryl® 587 Clear solid resin 100.0 Solid - 60 2.8 94 drying with long pot life, and excellent UV and chemical resistance, solid form provides cost benefit and 2 2 1 1 -
formulator versatility
Acrylic polyol with good hardness, stain resistance, and pigment dispersibility, broad resin compatibility and
Joncryl® 552 Clear liquid 62.0 5,500 n-Butyl acetate 49 2.7 90 1 2 1 1 -
useful as a low-VOC modifier for office furniture and general metal coatings
Fast cure version of Joncryl® 507, with outstanding reactivity / pot life behavior. Low VOC polyol offering
Joncryl® 922 Clear liquid 80.0 5,500 Butyl acetate 7 4.2 145 1 2 1 1 -
good drying time and pot life characteristics; useful as a sole binder or a modifier for higher Tg polyols
Very soft and reactive polyol with high OH number to obtain a very good chemical resistance against several
solvents, used to plasticize and / or to reduce VOC in 2K PU coatings; as a sole binder it forms a rubber-like
Joncryl® 963 Clear liquid 100 7,500 - -63 3.9 130 1 2 2 1 -
coating with extremely high flexibility and very good adhesion on difficult substrates; good outdoor durability
with proper light stabilization
Hyperbranched polyesters
Hyperbranched polyester that shows low impact on VOC for high-solid coatings; significantly faster drying,
Basonol® HPE 1170 B Clear liquid 69–71 4,000 n-Butyl acetate 20 8.2 270 early hardness development, and cross-linking. Improved chemical resistance and reflow behavior for 2K 1 2 2 2 -
PU high-solid refinish clear coats and 2K PU high-solid topcoats, but also usable for conventional systems
Hyperbranched polyester as low OH value alternative with similar property profile as Basonol® HPE 1170
Basonol® HPE 1265 B Clear liquid 64–66 2,400 n-Butyl acetate 38 5.5 180 B, at slightly higher VOC. It shows fast curing speed with fast hardness development for early handling and 1 2 2 2 -
early polishing
Catalyst for 2K PU
Basionics® KAT 1 is a metal-free curing catalyst for polyurethane reactions. It is a low-viscous liquid with
ionic character displaying high catalytic activity at low temperatures and forced drying conditions. The
White to slightly yellow,
Basionics® Kat 1 > 97 500–2,000 - - - - catalyst is active in coatings formulations and adhesives. In conventional solvent-based and high-solid 1 2 2 1 1
clear to slightly turbid
formulations, the addition of Basionics® KAT 1 enhances the curing speed at lower temperature at a longer
pot life
48 Solvent-based systems
2019
Solvent-based systems
2019 49
Solvent-based systems
1 Suited 2 Highly recommended
Free Substrate
Non-volatile at Viscosity at Temperature Acid
Product Type of product Solvent formalde- Key properties
2 h, 125 °C [%] 23 °C [mPa·s] reactivity reactivity Wood Metal Plastic Glass Concrete
hyde [%]
Co-cross-linker
Low-viscous and low-molecular-mass blocked isocyanate cross-linker. Deblocking and cross-linking start
at temperatures above 120 °C. No formaldehyde released during cross-linking. It does not cross-link with
Triazine derivative (melamine-based
Larotact® 150 10–50 n-Butanol - - - itself, making it an optimum cross-linker yielding an advantageous flexibility / hardness relation. Best use - 2 - 1 -
blocked isocyanate)
in combination with amino resins or alone. Preferred fields of application are automotive, industrial, and
coil-coating finishes
Melamine-formaldehyde resins / butanol-etherified
Butanol / For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 012 Melamine resin, high imino content 56–60 600–1,000 Medium - < 0.5 - 2 - 1 -
xylene lower solids content than Luwipal® 016
Melamine resin, high MW / For solvent-based, medium-solid automotive or industrial coatings with very high baking reactivity; fast
Luwipal® 014 50–54 600–1,000 Butanol High High < 1.0 - 2 - 1 -
high imino physical drying
Melamine resin, high MW / i-Butanol-etherified resin; for solvent-based, medium-solid automotive or industrial coatings with very high
Luwipal® 015 52–55 1,300–2,000 Isobutanol High - < 0.5 - 2 - 1 -
high imino baking reactivity; fast physical drying
Butanol /
Luwipal® 016 Melamine resin, high methylolation 72–75 6,000–10,000 Medium - < 0.4 For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity - 2 - 1 -
xylene
Melamine resin, high methylolation, For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 018 71–75 4,000–7,000 Butanol Medium - < 0.6 - 2 - 1 -
higher etherified standard for automotive clear-coat applications
Melamine resin, high methylolation, Butanol / For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 018 BX 64–68 900–1,400 Medium - < 0.6 - 2 - 1 -
higher etherified xylene standard for automotive clear-coat applications; solvent cut butanol / xylene
Melamine resin, high methylolation, For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 018 RF 68–72 3,000–6,000 Butanol Medium - < 0.4 - 2 - 1 -
higher etherified standard for automotive clear-coat applications; reduced formaldehyde content
For acid-curable solvent-based furniture and wood floor coatings with high reactivity and excellent chemical
Luwipal® 044 ULF Fully butyl-etherified melamine resin 94–97 2,000–5,000 - Low High < 0.1 2 2 - 1 -
resistance; no CMR labeling
Melamine-formaldehyde resins / methanol-butanol-mixed-etherified
Mixed-etherified melamine resin, Methanol-butanol-mixed-etherified resin for water-based and solvent-based coatings; high baking
Luwipal® 052 69–72 4,000–6,500 Butanol Medium - < 1.0 1 2 - 1 -
high methylolation degree reactivity; for automotive application
Melamine-formaldehyde resins / methanol-etherified
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for furniture foil and
Luwipal® 066 93–96 2,000–6,000 - Low High < 0.6 1 2 - 2 -
fully methyl-etherified coil-coating applications
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for furniture foil and
Luwipal® 066 LF 93–96 2,000–6,000 - Low High < 0.3 1 2 - 2 -
fully methyl-etherified coil-coating applications: low formaldehyde content
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for furniture foil and
Luwipal® 066 ULF 93–96 2,000–6,000 - Low High < 0.1 1 2 - 2 -
fully methyl-etherified coil-coating applications; no CMR labeling
Melamine resin, balanced For solvent-based and water-based coatings. High baking reactivity, for furniture foil, coil, automotive and
Luwipal® 072 73–77 4,000–7,000 Isobutanol High - < 1.0 1 2 - 2 -
imino-methylolation degree industrial applications
Solvent-based systems
1 Suited 2 Highly recommended
Free
Non-volatile at 2 h, Viscosity at 23 °C Temperature Acid
Product Type of product Solvent formalde- Key properties Wood Metal Plastic Glass Concrete
125 °C [%] [mPa·s] reactivity reactivity
hyde [%]
Urea resins
Carbamate resin, Carbamate resin for solvent-based coatings; medium to high acid reactivity. For wood and
Plastopal® BTB 59–62 1,600–2,400 Butanol Low Medium < 0.5 2 2 - 1 -
medium-etherified floor coatings, suitable as sole binder
Urea resin,
Plastopal® EBS 400 B 59–62 1,400–1,700 Butanol Low Medium < 0.8 Universal resin with low baking reactivity; for general wood and industrial applications 2 2 - 1 -
medium-etherified
Urea resin, i-Butanol-etherified resin with low baking reactivity; for general wood and industrial
Plastopal® EBS 400 I 59–62 1,400–1,700 Isobutanol Low Medium < 1.0 2 2 - 1 -
medium-etherified applications
Urea resin,
Plastopal® H73 IB 59–62 4,000–7,000 Isobutanol Medium High < 0.4 i-Butanol-etherified resin; high acid reactivity; for furniture, floor, and industrial coatings 2 2 - 1 -
highly etherified
Urea resin, Medium acid reactivity; low solvent content; high gloss; for furniture, floor, and industrial
Plastopal® H85 EB LF 83–88 3,000–6,000 Butanol / ethanol Low Medium < 0.3 2 2 - 1 -
medium-etherified coatings; low formaldehyde content
Plastopal® RH Urea resin, low-etherified 59–62 1,000–1,300 Butanol / xylene High Low < 0.6 Very high baking reactivity for industrial primers - 2 - 1 -
Polyvinyl chlorides
Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 15 Fine white powder 12–18 30 46–48 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 2 1 - 2
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics
Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 25 Fine white powder 20–26 35 48–52 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 2 1 - 2
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics
Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 35 Fine white powder 30–40 35 48–52 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 2 1 - 2
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics
Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
mineral substrates, as well as for printing inks (PVC / acrylic gravure inks) and road marking paints, resistant
Laroflex® MP 45 Fine white powder 40–50 35 48–52 - 2 1 - 2
to hydrolysis. Requires additional plastification using plasticizers or soft resins. Can be blended with alkyds
or acrylics
Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 60 Fine white powder > 50 35 48–52 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 1 1 - 1
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics
52 Solvent-based systems
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Solvent-based systems
2019 53
Basonat® polyisocyanates
and Larotact® co-cross-linker
Solvent-based systems
Viscosity at
Product Type of product Solids by weight [%] NCO [%] Solvent Key properties and applications
23 °C [mPa·s]
Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 2000 HDI allophanate 100 500–900 18.5–21.5 -
water-based 2K PU wood coatings
Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 3000 HDI allophanate 100 200–400 19.0–20.0 -
water-based 2K PU wood coatings
Biurets
Basonat® HB 100 HDI biuret 100 2,500–4,000 22.0–23.0 - Basonat® HB polyisocyanates for general use 2K PU coatings such as general industry, high-performance wood coatings, automotive topcoats, especially plastic substrates
Methoxypropyl acetate /
Basonat® HB 175 MP/X HDI biuret 75 130–300 16.0–17.0 Basonat® HB polyisocyanates for general use 2K PU coatings such as general industry, high-performance wood coatings, automotive topcoats, especially plastic substrates
Xylene 1:1
Basonat® HB 275 B HDI biuret 75 100–180 16.0–17.0 n-Butyl acetate Basonat® HB polyisocyanates for general use 2K PU coatings such as general industry, high-performance wood coatings, automotive topcoats, especially plastic substrates
n-Butyl acetate / Biuret grades known as polyisocyanates for general use in 2K PU coatings; applications extend from automotive topcoats, especially for plastic substrates, to general industry and
Basonat® HB 475 B/X HDI biuret 75 100–250 16.0–17.0
Xylene 1:1 high-performance wood coatings
Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coating. They are compatible and cross-linkable with most hydroxy-acrylic
Basonat® HI 145 B NG HDI isocyanurate 45 < 10 9.7–10.1 n-Butyl acetate
resins, e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations
Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coating. They are compatible and cross-linkable with most hydroxy-acrylic
Basonat® HI 152 B NG HDI isocyanurate 52 6–20 11–12 n-Butyl acetate
resins, e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations
Isocyanurate trimers known for low initial color, high weather resistance, high cross-link density, and perfect for high-performance 2K PU coatings, e.g. for 2K PU automotive OEM
Basonat® HI 172 S NG HDI isocyanurate 72 70–120 15.3–16.6 Solvesso® 100
and refinish; NG: reduced color drift in formulations
n-Butyl acetate / Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coatings; compatible and cross-linkable with most hydroxy-acrylic resins,
Basonat® HI 180 B/S NG HDI isocyanurate 80 130–250 16.9–18.3
Solvesso® 100 1:1 e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations
n-Butyl acetate / Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coatings; compatible and cross-linkable with most hydroxy-acrylic resins,
Basonat® HI 190 B/S NG HDI isocyanurate 90 450–600 19.3–20.3
Solvesso® 100 1:1 e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations
n-Butyl acetate / Isocyanurate trimers known for low initial color, high weather resistance, high cross-link density, and perfect for high-performance 2K PU coatings, e.g. for 2K PU automotive OEM
Basonat® HI 268 B/S NG HDI isocyanurate 68 39–55 14.5–15.5
Solvesso® 100 1:1 and refinish; NG: reduced color drift in formulations
Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coatings; compatible and cross-linkable with most hydroxy-acrylic resins,
Basonat® HI 290 B NG HDI isocyanurate 90 400–600 19.3–20.3 n-Butyl acetate
e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations
Low-viscous trimer for high-solid 2K PU coatings without limitation in chemical resistance and reactivity. It can also be combined with water-emulsifiable Basonat® HW types and
Basonat® HI 2000 NG HDI isocyanurate low-viscous 100 900–1,500 22.5–23.5 -
secondary dispersions for water-based 2K PU wood coatings; NG: reduced color drift in formulations
Solvent-based systems
1 Suited 2 Highly recommended
Grinding resins
Condensation product of urea with Excellent compatibility with common coating resins. Excellent solubility. Good pigment wetting. Improves hardness, gloss,
Laropal® A 81 Solid 100 - - 57 40 ≤3
aliphatic aldehydes and adhesion. Resistance to yellowing. Used as grinding resin or co-binder
Condensation product of urea with Excellent compatibility and solubility with common coating resins. Good pigment wetting. Improves hardness, gloss, and
Laropal® A 101 Solid 100 - - 73 35 ≤5
aliphatic aldehydes adhesion. Resistance to yellowing. Used as grinding resin or co-binder
Condensation product of urea with Excellent compatibility and solubility with common coating resins. Good pigment wetting. Improves gloss, and adhesion.
Laropal® A-8L Liquid 78–83 7,000–15,000 49.5 – 8 90 ≤ 50
aliphatic aldehydes Resistance to yellowing. Used as grinding resin
Unsaturated polyesters
Unsaturated polyester resin for the formulation of sandable and polishable coatings and surfacers for wood
Ludopal® P 6 Solution in styrene 64–67 900–1,200 29–33 1.531–1.534 2 1 1 - -
and metal, dissolved in styrene. Suitable for gelcoats
Unsaturated polyester resin for the formulation of sandable and polishable coatings and surfacers for wood
Ludopal® U 150 Solution in styrene 64–67 900–1,100 27–31 1.524–1.527 2 1 1 - -
and metal, dissolved in styrene. Suitable for gelcoats
Hydrogen Substrate
Solids by weight Viscosity at 23 °C
Product Physical form Water content [%] equivalent weight Key properties and applications
[%] [mPa·s] Wood Metal Plastic Glass Concrete
(HEW)
Amine
Laromin® C 260 is mainly used to harden low viscosity liquid epoxy resins for low-solvent or solvent-free
coatings, construction trade, or marine coatings. Combinations of Laromin® C 260 with solid epoxy resins
Laromin® C 260 Liquid 99 6–10 < 0.2 27 - 2 1 - 2
and solvents are used as hardeners for industrial and anticorrosion coatings. It can also be used for curing
concrete topping, self-leveling concrete, repair mortars, as well as highly filled wearing surfaces
56 Solvent-based systems
2019
Solvent-based systems
2019 57
Soft resins
Solvent-based systems
1 Suited 2 Highly recommended
Acrylic resins
130–200 Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Acronal® 4 F Liquid 99.0 150 –40 0–1 1 1 1 - 1
(50% in ethyl acetate) binders for coatings with good flexibility and excellent adhesion
Acronal® 4 L approx. Polymer of butyl acrylate, dissolved in acetate; soft acrylic resin, resistant to light and aging, for plasticizing
Solution in ethyl acetate 50.0 1,600–2,600 –6 –40 - 1 1 1 - 1
50% in ethyl acetate cellulose nitrate and chlorine-containing binders for coatings with good flexibility and excellent adhesion
Acronal® 500 LC Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Solution in ethyl acetate 40.0 9,000–14,000 (25 1/s) –4 - - 1 1 1 - 1
40% in ethyl acetate binders for coatings with good flexibility and excellent adhesion
Copolymer of vinyl isobutyl ether and n-butyl acrylate, dissolved in ethyl acetate; soft acrylic resin, resistant
Acronal® 700 L approx.
Solution in ethyl acetate 51.0 500–800 –4 - 0–2 to light and aging, for plasticizing cellulose nitrate and chlorine-containing binders for coatings with good 1 1 1 - 1
50% in ethyl acetate
flexibility and excellent adhesion
Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Acronal® 9020
Solution in o-xylene 65.0 1,000–2,500 34 - 0–1 binders for coatings with good flexibility and excellent adhesion. Main application: plastification of PVDF 1 1 1 - 1
65%ig in o-xylene
for coil coatings
Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Acronal® LR 8820 Liquid 98.5 20,000–50,000 (25 1/s) 109 –45 - - 1 1 - 1
binders for coatings with good flexibility and excellent adhesion
Compatible with many other resin systems, used as modifying resin to confer flexibility and improves
Joncryl® 611 Solid 99.0 150 (40% in toluene) - - 1 1 - - -
adhesion. Product is soluble in alcohols, aldehydes, ketones, and aromatic hydrocarbons
Vinyl ethers
Lutonal® A 25 Poly(vinyl ethyl ether) Liquid > 90 2.5–6.0 (100 1/s) > 55 –43 0–15 Plasticizing soft resin, i.e. for cellulose nitrate coatings. It also acts as an adhesion promoter 1 1 1 1 -
Lutonal A 50 app.
®
Plasticizing soft resin, i.e. for cellulose nitrate coatings. It also acts as an adhesion promoter.
Poly(vinyl ethyl ether) Solution 50 5–20 (25 1/s) 9 –30 0–4 1 1 1 1 -
50% in ethanol 50% solution in ethanol
Lutonal® I 60
Poly(vinyl isobutyl ether) Solution 35 0.3–4.5 (100 1/s) 26 –27 0–8 Plasticizing soft resin. It also acts as an adhesion promoter. 35% solution in white spirit 1 1 1 1 -
35% in white spirit
Lutonal® M 40, Plasticizing soft resin, i.e. for cellulose nitrate coatings. It also acts as an adhesion promoter.
Poly(vinyl methyl ether) Solution 70 50–250 (25 1/s) 11 –49 0–15 1 2 1 1 -
45% in o-xylene Used as co-binder for anti-fouling coatings. 70% solution in ethanol
Glycoluril
Plastigen® G ULF Glycoluril resin 93–96 900–1,400 Solution in n-butanol 77 < 400 Hazen Carbamide soft resin, as adhesion promoter and plasticizing resin for solvent-based coatings 1 1 1 1 -
Bitte Kurzversion des Kapiteltitels
Renewable
eintragen
5959
systems
2019 2019
Renewable systems
Renewable systems
hand with ever better performance. At the same time, applied coatings must meet the
increasing demand for health-friendly and resource-saving solutions. The paints and
coatings industry can profit from these trends by delivering products that offer high-
performance while consuming fewer resources and causing less emissions. Adding
value with more sustainable solutions will most likely become a key growth driver.
We at BASF can help you meet these future demands. Discover our advanced
renewable solutions to set your products apart from the competition!
60 Renewable systems
2019
Renewable systems
2019 61
Renewable systems
costs, and safeguard human well-being and the environment. This demand can be
expected to keep growing long into the future.
The coatings industry can benefit from the trend by Surprise your customers with added
delivering products that offer outstanding performance ecological benefit!
while consuming fewer resources and causing less
emissions. §§ Drives the use of sustainable renewable feedstock
With the biomass balance approach, BASF offers you §§ Saves fossil resources and reduces greenhouse gas
more sustainable resins and additives while maintaining emissions
the same product performance as ever. §§ Independently certified by third party
§§ Same product quality and properties
In this approach, the fossil resources are replaced
by sustainable biomass such as bio-naphtha or biogas
already at the beginning of the production process. If you are interested in our sustainable solutions, please
In a calculatory process certified by a third party, the contact us – our experts will be glad to advise you.
applied share of renewable resources is then virtually
allocated to the new product line. According to this
calculation, up to 100 % of the fossil resources Read more about biomass balance at
can be replaced by renewable raw materials. basf.com/biomassbalance
Hydrolysis stability
Natural oil polyols are polyfunctional alcohols based on renewable raw materials like
rapeseed oil, castor oil, soybean oil, and palm kernel oil. The practical advantages of Sovermol® polyether / polyester
these products include good adhesion, excellent workability, and good weathering
Renewable systems
Hydrophobic properties
properties. They can also be used on a wide variety of different substrates.
Hydrolysis stability
Polyols based on natural oils have a very pronounced The modular system of our Sovermol® product group
hydrophobic character. For this reason, oleochemical includes other important features, such as being 100% Hydrophobic properties
polyols create significantly less carbon dioxide by virtue solid, good gloss development, and good pigment-
of the side reaction of the isocyanate. In high humidity wetting characteristics. The latest generation of BASF Hydrolysis stability
and high temperature conditions, these special polyols Sovermol® products combines sustainability with
are able to create networks without bubbles or foam performance, thus meeting the requirements of today’s
formation. Besides good hydrophobicity, polyols producers and consumers. Hardness can be regulated
based on oleochemicals exhibit excellent hydrolysis without using plasticizers and the group features Hydrophobic properties
resistance, chemical resistance, and UV resistance, excellent UV stability and long-term weathering
as well as low viscosity. This latter characteristic is performance. Some markets where Sovermol® is being
especially important in spraying applications. used include concrete flooring, wind blades, pipeline Polyester
coatings, protective coatings, and adhesives.
64 Renewable systems
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Renewable systems
2019 65
Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve-
ment of glass transition temperature; high cross-linking density, hydrophilic; improvement of chemical
Sovermol® 100 Branched polyether - 3.0 64 880 6,000
Renewable systems
1 2 1 1 2
resistance; drinking and potable water application possible upon product-specific confirmation according
to local legislation
Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve-
ment of glass transition temperature; high cross-linking density, hydrophilic; improvement of chemical
Sovermol® 100 N NEW Branched polyether - 3.0 65 860 5,900 1 2 1 1 2
resistance; drinking and potable water application possible upon product-specific confirmation according to
local legislation (N: different production site)
Branched polyether / Drinking and potable water application possible upon product-specific confirmation according to local
Sovermol® 320 80–100% 2.8 180 310 1,000 1 2 1 1 2
polyester legislation; high shore D hardness (D ~ 80); good mechanical properties
Branched polyether / Polyol for UV-stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 80);
Sovermol® 750 65–80% 3.0 178 315 1,100 [20 °C] 1 2 1 1 2
polyester hydrophobic; high saponification stability; excellent chemical resistance; hydrolysis stable; high-Tg polyol
Branched polyether / High shore D hardness (D ~ 90); hydrophobic; high saponification stability; excellent chemical resistance;
Sovermol® 760 65–80% 3.5 145 390 2,300 1 1 1 1 2
polyester hydrolysis stable; extremely high-Tg polyol; high heat resistance
Branched polyether / Polyol for UV-stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 90);
Sovermol® 780 50–65% 3.0 110 510 2,300 [20 °C] 1 2 1 2 2
polyester hydrophobic; excellent chemical resistance; hydrolysis stable; high-Tg polyol
Branched polyether /
Sovermol® 805 65–80% 3.5 330 170 3,500 Universal polyol; excellent impact resistance; shore D hardness (D ~ 70) 2 2 2 1 2
polyester
Branched polyether /
Sovermol® 810 65–80% 3.3 244 230 900 Polyol for encapsulation systems; hydrolysis stable; hydrophobic; low viscosity; high filler content possible 2 1 1 1 2
polyester
Branched polyether / Low-viscous universal polyol binder for pigment pastes and crack-bridging flooring; good chemical resis
Sovermol® 815 80–100% 3.5 260 215 1,600 2 1 1 1 2
polyester tance, hydrophobic, good elastic, memory effect
Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; excellent flexibility at
Sovermol® 818 Fatty acid polyester 80–100% 2.6 238 236 750 2 2 2 1 2
temperatures below 0 °C; good bonding properties
Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; good bonding
Sovermol® 819 Fatty acid polyester 80–100% 2.6 234 240 850 2 2 2 1 2
properties
66 Renewable systems
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Renewable systems
2019 67
Gel time prolonger; reactive diluent; hydrophobic; good adhesive properties on metal surfaces; contains
Sovermol® 860 Aliphatic polyol 80–100% 2.5 270 210 530 [20 °C] 2 2 1 1 2
epoxy groups (Ep-O = 0.3 to 1.4%)
Renewable systems
Sovermol® 908 Aliphatic dimer alcohol 80–100% 2.0 272 206 2,300 Crack-bridging coatings; good saponification stability; hard elastic performance; hydrophobic 1 1 1 1 2
Slightly branched Hydrophobic; plasticizer for polyol; soft elastic performance; drinking and potable water application possible
Sovermol® 1005 80–100% 2.2 460 122 800 [20 °C] 2 2 1 1 2
aliphatic diol upon product-specific confirmation according to local legislation
Soft elastic performance; drinking and potable water application possible upon product-specific
Sovermol® 1014 Aliphatic triol 80–100% 2.5 350 160 700 2 2 1 1 2
confirmation according to local legislation
Fatty acid polyester Ep content Non-reactive diluent; VOC-free acc. to 2004/42/EU; UV-stable performance; plasticizer for polyols and
Sovermol® 1055 80–100% - EEW = 333 15 [20 °C] 1 1 1 1 2
with epoxy groups 4.6–5.0% epoxy resins
Sovermol® 1058 Fatty acid polyester 80–100% - - - 5 [20 °C] Non-reactive diluent; VOC-free acc. to 2004/42/EU; hydrophobic; plasticizer for polyols 1 1 1 1 2
Branched polyether / High-performance polyol for coatings, putties, and adhesives, low viscosity; extremely hydrophobic;
Sovermol® 1092 65–80% 2.8 198 283 800 2 2 1 1 2
polyester hardness similar to epoxy systems; hard elastic performance; good self-leveling properties
Branched polyether /
Sovermol® 1093 65–80% 2.8 245 229 2,500 Polyol; high hardness; hydrophobic performance; hard elastic; water repellency 2 2 2 1 2
polyester
Slightly branched
Sovermol® 1102 80–100% 2.1 245 230 400 [20 °C] Universal copolyol; gel time prolonger; reactive diluent hydrophobic; UV-stable; soft elastic performance 1 2 1 1 2
polyether / polyester
Sovermol® 1140 Fatty acid polyester 80–100% 2.7 267 210 1,000 Universal polyol for adhesives; gel time prolonger; hard flexible performance; hydrophobic 1 1 1 1 2
68 Renewable systems
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2019 69
Properties of Sovermol®
natural oil-based polyols
After stoichiometric cross-linking with MDI polymer
(NCO = 31%, functionality = 2.4)
Gel time ASTM D Shore hardness A / D (EN ISO 868) ISO 527-3 Type 5 ISO 527-3 Type 5 ISO 34-1 DIN EN ISO 604 DIN EN ISO 178 DIN 53453 DIN 53754
Product 2471-88 (30 g mass) Tensile strength Tear resistance Compression Bending strength Impact resistance Abrasion
[h:min] 1st day 2nd day 14th day 28th day Elongation [%]
[MPa] [N/mm] strength [MPa] [MPa] [mJ/mm²] [mg/1,000 R]
Sovermol® 100 /
0:20 100 / 77 100 / 77 100 / 80 100 / 80 n.m. n.m. n.m. n.m. 107 2 n.m.
Sovermol® 100 N
Renewable systems
Sovermol® 760 0:19 100 / 86 100 / 88 100 / 90 100 / 90 42 1 6 45 57 4 15
Sovermol 805
®
0:47 75 / 30 86 / 42 98 / 64 98 / 69 17 65 88 n.m. 8 121 68
Sovermol 810
®
0:55 77 / 32 86 / 42 98 / 66 98 / 67 18 39 60 n.m. 10 34 79
Sovermol 815
®
1:00 83 / 39 92 / 52 99 / 75 99 / 77 21 34 70 n.m. 22 24 28
Sovermol 818
®
1:24 60 / 18 78 / 31 94 / 50 96 / 60 18 58 64 n.m. 6 113 77
Sovermol 819
®
0:59 69 / 24 85 / 39 96 / 62 97 / 64 18 66 70 n.m. 7 107 88
Sovermol 830
®
0:55 70 / 25 85 / 39 96 / 63 100 / 65 19 65 73 13 6 126 42
Sovermol® 908 0:12 66 / 24 78 / 34 84 / 40 84 / 42 14 122 38 n.m. 1 96 n.m.
Sovermol® 1005 1:47 n.m. 4 / n.m. 22 / n.m. 38 / 10 1 24 3 n.m. 0.3 n.m. n.m.
Sovermol 1093
®
0:59 96 / 60 n.m. 100 / 87 100 / 87 43 4 25 n.m. 54 34 n.m.
Sovermol 1102
®
3:15 n.m. 39 / 10 89 / 45 94 / 56 13 52 47 n.m. 2 38 75
Sovermol 1140
®
6:07 n.m. 50 / n.m. 98 / 61 99 / 69 10 1 14 9 16 10 n.m.
Radiation-curable systems
BASF is the first choice for high-performance radiation-curable resins. Our Laromer®
range enables you to create coatings as well as printing formulations tailored to your
needs. Your challenges are our challenges, and constantly spur us on to improve
our product portfolio with innovative new solutions for your coating and printing
formulations.
With our continuous high focus on research and development, investments in assets
and people, and our close interaction with formulators and machine manufacturers,
we are shaping the future of radiation-curable resins – for example with our water-
Radiation-curable systems
based UV resins.
Oligomers Monomers
Our extensive portfolio of oligomers, our strong Reactive diluents are key ingredients in most UV and
technical center, and our passionate team of experts EB formulations for matching the viscosity to a wide
are dedicated to fulfilling your requirements for variety of application conditions. Additionally, they
state-of-the-art UV and EB formulations. We offer a influence performance properties like reactivity,
broad portfolio of oligomers including UV 100% and hardness, and adhesion. BASF offers a broad portfolio
UV waterborne resins. of high-quality monomers for the coating and printing
industries.
72 Radiation-curable systems
2019
Radiation-curable systems
2019 73
UV LED curing is continuing to make significant inroads A high-performance UV coating needs to meet other Anti-
Product Type Viscosity (23.0 °C) Product Type Adhesion
into traditional UV curing markets used to work with prerequisites besides adhesion to the metal, e.g. good corrosion
mercury lamps as radiation source until now. UV LED Amine-modified anticorrosion properties. That’s why we offer UV resins Adhesion
Laromer® PO 8996 0.05 – 0.09 Pa·s Laromer® PA 9083 3 1
radiation sources, apart from their considerably longer polyether acrylate that can be used in combination with acidic adhesion promoter
service life than mercury lamps, do not emit infrared promoters and low-shrinkage, hydrophobic UV diluents.
radiation evolving as heat. As a consequence, heat- Amine-modified Since the cross-linking of UV coatings is done at room
Laromer® PO 9144 0.10 – 0.20 Pa·s Laromer® TBCH Diluent 3 2
polyether acrylate
sensitive substrates like plastic films in packaging or temperature, UV technology is also very economical.
wood in furniture applications can be processed without Amine-modified
any difficulties caused by heating in contrast to mercury Laromer® PO 94 F 0.45 – 0.75 Pa·s
polyether acrylate Laromer® LR 8887 Diluent 3 3
lamps.
Amine-modified
Laromer® PO 9137 0.50 – 0.90 Pa·s Anticorrosion
polyether acrylate Laromer® UP 9151
However, due to the quasi-monochromatic emission resin
2 3
of commercial UV LED radiation sources in the wave
Amine-modified
length range of 360–410 nm, the number of suitable Laromer® PO 9067 0.50 – 0.90 Pa·s
polyether acrylate
photoinitiators, absorbing this red-shifted UV radiation
is rather limited; particularly photoinitiators with proper Laromer® PO 9139
Amine-modified
2.0 – 6.0 Pa·s
surface cure are missing. This lack of surface cure for polyether acrylate
UV LED formulations triggered by oxygen inhibition
Radiation-curable systems
requires the use of highly reactive monomer and Laromer® PE 8981 Polyester acrylate 4.0 – 14.0 Pa·s
oligomer acrylates to compensate these surface cure
deficiencies. A dedicated range of monomer and Modified epoxy
Laromer® LR 9019 12.0 – 20.0 Pa·s
oligomer acrylates with a very fast UV cure response is acrylate
available, covering beyond printing and packaging
markets also furniture and flooring as well as automo-
tive and industrial applications.
74 Radiation-curable systems
2019
Radiation-curable systems
2019 75
Abrasion resistance is of utmost importance in the Many different applications require a highly scratch-re- The weather resistance properties of UV and EB Recently, there has been a strong interest in using UV
world of high-quality flooring products. Product sistant coating to assure a long service life. Examples coatings open up a wide range of outdoor and EB curable technology to coat metal and plastic
selection can sometimes be test-method-dependent include high-performance automotive clear coats and applications. The key to formulating such weather-re- substrates. These non-absorbing substrates require
and a close and specific match is often needed. plastics coatings as well as furniture and flooring sistant coatings is the use of aliphatic urethane careful selection of radiation-curable raw materials to
For each test method, we offer the optimal solution. coatings. Highly scratch-resistant surfaces can be acrylates in combination with a suitable photoinitiator. ensure that the coatings formulation achieves the
achieved via two alternative routes: through resins with To achieve the best possible weather resistance, we necessary adhesion performance. This can be
either high functionality or nano-modification. offer the Tinuvin® product range (UV absorbers and achieved by employing dual cure resins, film shrinkage
HALS). control, substrate wetting optimization, or an acidic
adhesion promoter.
Radiation-curable systems
Laromer® PE 56 F - 1 3 Laromer® UA 8987 N 2 High functionality Laromer® UA 8987 N 2 - Laromer® UA 9059 - - 3
Laromer® PE 9032 - 2 2 Laromer® UA 9048 3 High functionality Laromer® UA 9048 3 - Laromer® PA 9083 3 2 -
Laromer® UA 9065 - 2 - Laromer® UA 9136 3 High functionality Laromer® UA 9050 3 - Laromer® PR 9000 1 3 2
Laromer® PR 9052 3 - - Laromer® UA 9047 3 High functionality Laromer® UA 9033 N - 3 Laromer® UA 9072 2 2 2
Laromer® TMPTA 3 1 3 Laromer® TMPTA 2 High functionality Laromer® UA 9089 - 3 Laromer® PR 9013 1 1 2
PO 9137
120
UV resins
110
Viscosity – reactivity
100 100
UA 9005 Aqua
80 80
UA 9149 Aqua
PO 94 F LR 9019 PE 9079
PE 55 Aqua
70 70
UA 9065
Radiation-curable systems
PO 9067 LR 9023
EA 8765 R PE 56 F
50 50
PE 55 F
UA 9154 Aqua PO 84 F EA 9138 PE 9084
PO 8996
UA 8983 Aqua PE 22 Aqua PE 8981 PE 9032
40 40
UA 9095 Aqua PR 9058 UA 9136
PO 9007 EA 9082
EA 9145 PE 9074
UA 8949 Aqua LR 8986 UA 9059 Aqua PE 9004
30 30
PO 9144 UA 9033 N
PE 9123 UA 9048 UA 9073
PE 9045 PE 9121
PR 9052
EA 9097
PO 83 F
20 PO 9034 UA 9047 20
UA 8987 N UP 9118
PE 46 T PE 9142
PR 9119
PO 8967
Reactivity [m/min]
PE 9128 PE 8800
UP 35 D
10 10
UP 9151
PO 43 F
UP 9096 UP 9115 EA 9101 PR 8985
UA 19 T
LR 8863 PE 8907 PE 9126 UA 9072
PO 33 F GPTA UA 9089 PR 9013
PO 9102
UA 9030
0 0
PPTTA
10 55 100 550 1,000 5,500 10,000 50,500 100,000 550,000 1,000,000
Viscosity at 23 °C [mPa·s]
1 Epoxy acrylates 1 Water-based products 1 Polyether acrylates 1 Unsaturated polyesters All products were cured with 1 UV lamp 120 W/cm. Photoinitiator for water-based and amine-modified products 4% 1-hydroxycyclohexyl phenyl ketone /
1 Polyester acrylates 1 Urethane acrylates 1 Amine-modified polyether acrylates 1 Special radiation-curable products benzophenone (1:1), all others 4% 1-hydroxycyclohexyl phenyl ketone
Film thickness: 25 µm
78 Radiation-curable systems
2019
Radiation-curable systems
2019 79
UV resins
Hardness – flexibility
10 10
UA 9072
UA 9030
9 9
UA 9059 Aqua
UA 9073
UA 9033 N
7 PE 55 Aqua 7
PE 9126
PE 8907 PE 9142
PE 9074
6 PE 9045 6
PE 56 F PE 9004
Radiation-curable systems
PE 8981
PE 55 F
UA 9149 Aqua
UA 9095 Aqua
PE 9084 PE 46 T
PE 9128 PO 9102 UP 9115 PE 22 Aqua
5 PO 77 F PE 9079 PE 9032 5
PE 9123 EA 9101 EA 9097
PE 9121 UP 35 D
UA 8987 N
EA 8765 R PO 9067
LR 9023 UA 9005 Aqua
PO 84 F
4 4
LR 9019 PO 9034
PO 94 F PO 8997 PO 83 F PE 8800
PO 9137
PO 9007 PR 9058 EA 9145
PO 8996 LR 8986
PO 9139 UA 9147 Aqua
PO 9144 UP 9096 PO 43 F
3 EA 9138 3
UP 9151
EA 9143 EA 9082
EA 9124
UA 9047 PO 8967
UA 9134 Aqua
GPTA
2 2
UP 9118 UA 9135 Aqua
UA 9112 Aqua
Erichsen cupping [mm]
PO 33 F LR 8863
PR 9013
PPTTA
1 PR 8985 1
UA 9048 UA 9050
PR 9119
UA 9136
PR 9052
0 0
20 40 60 80 100 120 140 160
1 Epoxy acrylates 1 Water-based products 1 Polyether acrylates 1 Unsaturated polyesters All products were cured with 1 UV lamp 120 W/cm. Photoinitiator for water-based and amine-modified products 4% 1-hydroxycyclohexyl phenyl ketone /
1 Polyester acrylates 1 Urethane acrylates 1 Amine-modified polyether acrylates 1 Special radiation-curable products benzophenone (1:1), all others 4% 1-hydroxycyclohexyl phenyl ketone
Film thickness: 25 µm
80 Radiation-curable systems
2019
Radiation-curable systems
2019 81
PPTTA PPTTA
GPTA GPTA
TMPTA TMPTA
HDDA HDDA
TPGDA TPGDA
Radiation-curable systems
DPGDA DPGDA
PO 9102 PO 9102
POEA POEA
LR 8887 LR 8887
TBCH TBCH
Viscosity at 23 °C [mPa·s] Reactivity [m/min] Pendulum hardness [oscil.] Erichsen indentation [mm]
Formulation: 70 parts Laromer® PE 56 F, 30 parts monomer, 4 parts 1-hydroxycyclohexyl phenyl ketone / benzophenone (1:1) Formulation: 70 parts Laromer® PE 56 F, 30 parts monomer, 4 parts 1-hydroxycyclohexyl phenyl ketone / benzophenone (1:1)
Film thickness: 25 µm Film thickness: 25 µm
82 Radiation-curable systems
2019
Radiation-curable systems
2019 83
Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Epoxy acrylates
Laromer® EA 8765 R Aliphatic - 0.6–1.2 2.0 330 1 3 3 1 Partially water-soluble, flexible, highly reactive 1 2 1 1 1 1 1 -
Laromer® EA 9082 Aromatic TPGDA [30%] 6.0–9.8 2.0 158 4 2 2 4 Standard epoxy acrylate, low viscosity 1 2 1 1 3 1 1 1
Soybean oil
Laromer® EA 9101 - 13.0–20.0 3.8 3.5 1 3 1 1 Flexibilizing co-resin, outstanding pigment wetting 1 2 1 1 3 1 1 1
acrylate
Laromer® EA 9124 Aromatic HDDA [20%] 7.0–15.0 2.0 181 4 1 2 4 Standard epoxy acrylate with good adhesion 1 - 1 1 3 1 1 1
Laromer EA 9138
®
Aromatic TPGDA [25%] 10.0–20.0 2.0 176 4 2 2 4 Standard epoxy acrylate, medium viscosity 1 - 1 1 3 1 1 1
Laromer® EA 9143 Aromatic GPTA [25%] 35.0–55.0 2.3 175 4 2 2 4 Standard epoxy acrylate, high viscosity 1 2 1 1 3 1 1 1
Laromer® EA 9145 Aromatic DPGDA [30%] 4.0–6.5 2.0 159 4 2 2 4 Standard epoxy acrylate, low viscosity 1 2 1 1 3 1 1 -
Radiation-curable systems
curing
Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Polyester acrylates
Well-balanced properties with high toughness; diluted version of
Laromer® PE 46 T 2.0–2.5 2.5 60 2 2 2 3 1 2 1 1 1 1 1 1
Laromer® PE 56 F
Laromer® PE 8907 0.5–2.0 2.0 120 1 4 2 3 Highly flexible, use in combination with hard, less flexible binders 1 - 1 3 - - - -
Laromer® PE 8981 4.0–14.0 2.9 80 1 3 4 3 Highly reactive and flexible, UV LED curing 1 - 1 3 - 1 3 1
Radiation-curable systems
Tough, chemical-resistant; abrasion-resistant in parquet
Laromer® PE 9074 7.0–13.0 2.3 50 2 3 3 3 1 2 1 3 - 1 3 1
applications (falling sand), low yellowing
Laromer® PE 9121 7.0–13.0 4.2 44 2 3 3 3 Low yellowing, good abrasion resistance (falling sand) 1 - 1 3 3 - - 1
Laromer® PO 8996 None 0.05–0.09 25 2.6 2 2 3 3 Reactive, low color and viscosity, UV LED curing 1 2 1 3 - 3 3 1
Laromer® PO 9067 None 0.4–0.7 34 2.6 2 2 3 3 Reactive, good substrate wetting, UV LED curing 1 - 1 1 - 1 - 3
Laromer PO 9137
®
NEW None 0.5–0.9 88 2.4 2 2 4 3 Outstanding reactivity, UV LED applications 1 - 3 3 - - - 1
Laromer® PO 9139 NEW None 2.5–8.0 88 3.3 3 2 4 3 Outstanding reactivity, UV LED applications 1 - 3 3 - - - -
Radiation-curable systems
Laromer® PO 9144 NEW None 0.1–0.3 - 2.6 2 2 3 3 Low viscosity with good reactivity 1 - 1 1 - 1 1 1
Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Type of resin Hardness Elasticity Reactivity Key properties
[content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Polyether acrylates
Alkoxylated TMP
Laromer® PO 33 F None 0.07–0.13 2.7 30 3 1 1 3 Low yellowing, low odor, reactive diluent 1 2 1 3 - 3 1 3
triacrylate
Laromer® PO 9007 - None 0.8–1.5 3.0 130 3 2 3 4 Lowest amount of extractables, scratch-resistant 1 2 1 3 1 1 1 1
Laromer PO 9034
®
- None 0.35–0.6 2.6 58 1 4 2 2 Partially water-soluble, adjustable to spray viscosity 1 2 1 1 1 1 1 1
Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Type of resin Hardness Elasticity Reactivity Key properties
23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Urethane acrylates
Elastic, low yellowing, flexible at low temperatures,
Laromer® UA 19 T Aliphatic TPGDA [35%] 14.0–32.0 2.9 10 2 3 1 1 1 2 1 1 1 1 1 3
weathering-resistant
Laromer® LR
Laromer® UA 9030 Aliphatic 80.0–150.0 2.2 12 1 4 1 1 Highly elastic, low yellowing, good adhesion 1 - 1 1 1 1 1 3
8887 [30%]
Radiation-curable systems
Laromer® UA 9050 Aliphatic BuAc [20%] 1.5–5.0 8.3 10 4 1 3 4 monomer-free (solvent-based) version of 1 2 3 3 1 1 - -
Laromer® UA 9048
2.0–15.0
Laromer® UA 9073 Aromatic - 2.0 9 2 3 2 2 Flexible and tough with high viscosity 1 2 1 1 1 1 1 3
[60 °C]
Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Unsaturated polyesters
Unsaturated
Laromer® UP 35 D DPGDA [45%] 3.0–6.0 3.5 11 2 3 2 3 Good adhesion and good sanding properties 1 2 1 1 1 1 1 -
polyester
Unsaturated DPGDA / TMPTA
Laromer® UP 9118 26.0–31.0 4.5 7 3 1 3 3 Hard, good chemical resistance 1 2 1 1 3 1 1 -
polyester [42%]
Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Radiation-curable systems
UV specialties
Adhesion Acidic adhesion promoter; co-binder to increase
Laromer® PA 9083 - 1.2–3.5 1.0 - - - - - 1 2 1 3 1 1 1 1
promoter adhesion on metal and plastic
Laromer® UV monomers
Viscosity Molecular
Density APHA color Europe Japan China Canada Korea USA Australia Philippines
Product Chemical name Structure at 23 °C Stenomeric weight CAS number
[g/cm3] [Pt-Co] REACH ENCS IECSC DSL ECL TSCA AICS PICCS
[mPa·s] [g/mol]
UV monomers
Dipropylene glycol
Laromer® DPGDA ~8 Yes 1.05 242 57472-68-1 Max. 150 1 2 1 1 1 1 1 -
diacrylate
Laromer® HDDA Hexanediol diacrylate ~6 Yes 1.02 226 13048-33-4 Max. 150 1 2 1 1 1 1 1 1
Radiation-curable systems
Laromer® LR 8887 Trimethylolpropane formal
~ 40 Yes 1.09 200 66492-51-1 Max. 200 1 - 1 1 1 1 1 1
(CTFA) monoacrylate
Laromer® POEA Phenoxyethyl acrylate ~8 Yes 1.10 192 48145-04-6 Max. 250 1 - 1 1 1 1 1 1
Ethoxylated (5.0)
Laromer® PPTTA pentaerythritol 130–190 No 1.14 572 51728-26-8 Max. 100 1 2 1 3 1 1 1 1
tetraacrylate
4-t-Butylcyclohexyl
Laromer® TBCH ~9 Yes 0.94 210 84100-23-2 Max. 100 1 2 1 3 1 1 1 -
acrylate
Trimethylolpropane
Laromer® TMPTA ~ 130 Yes 1.10 296 15625-89-5 Max. 150 1 2 1 1 1 1 1 1
triacrylate
Tripropylene glycol
Laromer® TPGDA ~ 11 Yes 1.04 300 42978-66-5 Max. 150 1 2 1 1 1 1 1 1
diacrylate
Solid content Viscosity at Functionality Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Type of resin pH value Hardness Elasticity Reactivity Key properties
[%] 23 °C [Pa·s] calculated resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS
Water-based UV resins
Polyester acrylate Hard, chemical resistance, good sanding proper-
Laromer® PE 22 Aqua 48–52 0.15–0.5 3.6 4–6 2 2 2 4 1 - 1 3 3 1 - 1
emulsion ties, easy to matt
Polyester acrylate
Laromer® PE 55 Aqua 48–52 0.25–0.65 3.7 4–6 2 3 3 3 Tough, easy to matt, adhesion to PVC 1 2 1 3 3 1 1 1
emulsion
Aliphatic
Good grain enhancement, good chemical and
Laromer® UA 8949 Aqua urethane acrylate 38–42 0.015–0.18 2.7 7–9 2 3 2 4 1 2 3 3 - 1 3 -
weathering resistance
dispersion
Aromatic
Laromer® UA 8983 Aqua urethane acrylate 38–42 0.05–0.3 1.6 6–8 2 4 2 2 Excellent physical drying properties 1 2 - 3 - 1 - 1
dispersion
Aromatic
Laromer® UA 9005 Aqua urethane acrylate 38–42 0.02–0.25 5.2 7–9 4 2 2 4 Excellent scratch and chemical resistance 1 2 3 1 3 1 - 3
dispersion
Radiation-curable systems
Laromer® UA 9095 Aqua 37–39 0.01–0.5 3.8 7.3–8.3 4 2 2 3 1 - - 3 - 1 - -
dispersion yellowing
Solvent-based systems
Formulation additives
BASF is a premier provider of formulation additives for the paints and coatings
industry. With a full complement of respected brands and a broad technology base
Bio-based systems
of dispersing agents, wetting agents and surface modifiers, defoamers, and rheology
modifiers, our unique portfolio helps to enable performance-driven products which
meet the latest and most stringent environmental regulations.
Efka® Hydropalat®
Radiation-curable systems
The Efka® brand offers a broad selection of Under the Hydropalat® brand, BASF presents a
dispersing agents, wetting agents and surface selection of substrate wetting, colorant compatibilizing,
modifiers, defoamers, and rheology modifiers for flow control, and slip agents for water-based industrial
non-aqueous formulations. and automotive coatings.
Providing a range of standard and highly efficient The long-established Rheovis® range comprises
dispersing agents for aqueous systems and for a broad portfolio of synthetic rheology modifiers for
universal pigment concentrates, the Dispex® and aqueous systems, including non-ionic associative
Dispex® Ultra brands portfolio includes polymeric, (HEUR / HMPE), anionic associative (HASE), and
oligomeric, and surfactant-based dispersing agents. non-associative thickener (ASE) technologies.
Formulation additives
Foamaster® and FoamStar®
Performance additives
98 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 99
Dispersing agents
Solid particles such as pigments and fillers are BASF’s knowledge of pigment chemistry and surface BASF offers a full range of dispersing agents for all prepared that are designed to optimally fit pigment
important components of paints and coatings and treatments combined with our know-how about paints and coatings formulations containing highly and resin chemistry.
need to be dispersed and stabilized well in the dispersing agents and their technology enables us efficient solutions for aqueous, solvent-based, high-
formulations to assure consistent color, quality, to find optimum solutions for our customers and their solid, or 100% solids systems and for pigment As illustrated, dispersing agents designed with CFRP
and durability. formulation challenges. concentrates. The broad technology portfolio includes consist of two defined blocks that are produced by
Highly specialized additives are needed to wet, polymeric, oligomeric, and surfactant-based dispersing sequential polymerization of monomers or monomer
disperse, and stabilize dry pigment powders in liquid Favored properties agents. mixtures. Typically, a longer stabilizer block is
formulations. Dispersing agents represent an essential synthesized first, which has to be compatible with the
component of most paint and coating formulations. BASF’s dispersing agents product range relevant paint systems. The anchoring block contains
Their specialized function ensures color strength, for water-based systems functional groups which interact strongly with the
gloss, viscosity stability, and prevents sedimentation of pigment surface to allow for efficient and stable
Advanced
particles. Today, high-quality coatings of high brilliance Low-molecular Oligomeric High-molecular
high-molecular adsorption. For demanding applications like organic
weight dispersants weight
and color strength are characterized by a perfect dispersants (FAME) dispersants
weight pigments, the anchoring block typically contains aminic
dispersants
pigment dispersion, optimal pigment particle size, and Primary particles Aggregates Agglomerates groups, which can optionally be modified further.
long-term stabilization of the dispersed particles in the Dispex® AA Dispex® Ultra PA
Dispex® Ultra FA Dispex® Ultra FA
Favored energy state Dispex® CX Dispex® Ultra PX
formulation.
Formulation additives
§§ Optimum properties at low particle size viscosity reduction, enhanced gloss, increased color All toolbox products comply with the major ecolabel
§§ Energy required to mill down pigment intensity, and hiding power. standards. Based on innovative new chemistry,
§§ Stabilization required to keep particles apart a combination of amine- and acid-functional
Efka® PX and Dispex® Ultra PX grades are very polymers was found that provides universal affinity
Dry pigments Need for dispersion, whereby optimum properties of a pigment are achieved
versatile and powerful product groups for sol- to pigment surfaces (FAME technology). With this
at low particle size vent-based and aqueous applications, respectively. set of dispersants it is possible to formulate inorganic
Although non-controlled free-radical polymerization pigments at high pigment loading while also achieving
can lead to good dispersing agents, polymers with excellent results with organic pigments and carbon
Key benefits for your formulation a highly defined architecture can be more efficient, blacks. The products carry no, or only mild, labeling,
resulting in improved colorant stability and broader which allows the formulator their use in label-free
§§ Shorter dispersion time §§ Improved tone development system compatibilities. colorant formulations at a maximum concentration of 10%,
§§ Enhanced gloss §§ Prevention of flooding and floating This exact degree of control in polymer synthesis is provided no other components with similar labeling are
created by the award-winning controlled free radical used.
§§ Increased color strength and hiding power §§ Prevention of flocculation
polymerization (CFRP) technology. It enables the
§§ Reduced viscosities §§ Prevention of settling of pigments and fillers precise design of polymer structures. With the CFRP For all dispersing additives BASF experts have worked
technology, well-defined block copolymers can be out guide formulas for a variety of pigments in order to
support formulators and developers.
100 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 101
Wetting agents and surface modifiers are essential BASF Formulation Additives offers a broad portfolio Fluorinated polyacrylates are a very versatile class of Fluorinated polyacrylate
components of modern paints and coatings. They of wetting agents and surface modifiers for water- interfacially active additives. They are widely used in at the liquid / air interface
provide a formulation with adequate wetting properties, based and solvent-based systems based on various the coating industry as flow and leveling agents. Pure
enhance different component compatibility, and chemistries. polyacrylate copolymers are highly appreciated for their Illustration of fluorinated polyacrylate at the liquid / air
improve the surface of a coating. Our broad portfolio flow performance, although they do not significantly interface. The block copolymer arrangement makes
of wetting agents and surface modifiers offers highly reduce the surface tension of a formulation. However, maximum use of the fluorinated side chains.
effective products for almost every paint and coating Product a straight polyacrylate cannot solve problems like
Chemistry Characteristics
range
system. cratering, poor substrate wetting, and other problems
Most coating systems need good flow and leveling related to surface tension. Fluorinated polyacrylates
in order to have a smooth appearance. A flat and Alkoxylated Low-foaming substrate wetting
have been developed as a result. These polyacrylates
even surface will give a higher gloss and is therefore Hydropalat® with fluorinated side chains can lower the surface
surfactant agents for waterborne applications
eye-catching. As shown, wetting agents and surface tension of a formulation. They combine excellent flow
modifiers can have a strong influence on coating and leveling with anti-cratering and good wetting
properties like substrate wetting, slip, flow, and leveling. behavior.
Substrate wetting agents with
Efka® Silicone
generally very low static surface
Hydropalat® surfactants In comparison to organo-modified silicones and
tension
Controlling coating effects straight polyacrylates, fluorocarbon-modified
polyacrylates have clear advantages with respect
Several coating effects such as substrate wetting, flow to flow, substrate wetting, and fish-eye resistance. Statistical copolymer
and leveling, surface slip, and defoaming are controlled Cost-effective substrate wetting On the other hand, polysiloxanes can provide
Hydropalat® Sulfosuccinates agents with excellent dynamic
by wetting agents and surface modifiers. strong surface slip and anti-blocking effects and
surface tension reduction Fluorinated side chains
reduce surface tension.
Defoaming / deairation Slip / hydrophobization Leveling The newest generation of fluorinated acrylates are
block copolymers with fluorinated side chains. These
High-performance acrylate unique products are made via controlled free radical
Efka® (Fluorinated)
leveling agents for waterborne
Hydropalat® polyacrylates
and solvent-based applications polymerization (CFRP), which allows the synthesis of
block copolymer structures and to concentrate the
Coating Flow fluorinated side chains in one polymer block only.
Such an arrangement makes best use of the
Defoaming wetting agents based on
Star-shaped fluorinated side chains and guarantees maximum Polyacrylate backbone
Formulation additives
Hydropalat® star-shaped polymers for excellent
Substrate wetting polymers effectiveness with respect to substrate wetting and
dynamic surface tension reduction
anti-cratering behavior.
Substrate Block copolymer
102 Formulation additives
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Formulation additives
We create chemistry that makes coatings love resins and additives 103
Defoamers
For paint manufacturers and applicators, foam control All defoamers are characterized by a certain balance BASF Formulation Additives offers a broad selection A very special defoaming technology is our award-
is one of the major tasks to ensure a smooth and even between compatibility and incompatibility in a given of defoamer technologies to the paint and coatings winning FoamStar® series. The FoamStar® polymer
appearance of the paint film. Thus, high-performing system. On the one hand, the active ingredient in the market. The portfolio ranges from standard mineral is a hyper-branched polymer with a 3D star-shaped
defoamers are needed to prevent the formation of defoamer must be almost insoluble in the paint oil defoamer technologies to aqueous emulsion structure, containing hydrophilic as well as hydrophobic
bubbles in liquid paints. They reduce foam and avoid formulation. A defoamer must form small defoamer defoamers and up to our innovative FoamStar® elements.
foam formation during the production, application, droplets which are able to migrate into the foam technology. Unlike conventional mineral oil and silicone defoamers,
and transport of paint formulations. lamellae. In order to ensure long-term defoaming Today, most defoamers are sophisticated formulations the FoamStar® molecule defoams on a molecular level.
Especially in industrial surroundings, foam is a very efficiency the defoamer droplets have to be stable designed to fit together with paint and coating formula- It acts as a unique surfactant interacting with the
undesirable phenomenon that can emerge during in the system and should not dissolve upon storage. tions in the best possible way. Usually the formulations foam-stabilizing surfactants and destabilizes the foam
dispersing processes, pumping, stirring operations, are based on raw materials with a low surface tension bubbles. When combined with conventional defoamer
or while applying paints. This foam can, for example, On the other hand, no surface defects such as craters such as silicone, mineral oils, fatty acids, and fluorocar- types it yields faster bubble-break times and improves
increase the production time, create difficulties in filling should be generated in the final paint film due to bons. the overall efficiency. Bubble-break time is the time in
vessels, reduce the efficiency of many high-speed defoamer incompatibility. The defoamer must therefore seconds needed to break all macro bubbles in a paint
operations, and promote surface defects like craters, be sufficiently compatible with the binder. Thus, every film; the shorter the time the better the defoamer.
fish eyes, pinholes, and weak points in the dried film. defoamer is formulated on a tightrope between
compatibility and targeted incompatibility.
In order to explain the working mechanism of
defoamers, there is no single overarching defoamer Product range Chemistry Characteristics
theory in the scientific literature. However, for aqueous
systems all theories have some explanations and
prerequisites in common. It is generally accepted that
Foamaster®
a defoamer active should:
MO Mineral oil Macro foam, universal
§§ Possess a “controlled incompatibility” with the
formulation to be defoamed. This “controlled NO Natural oil Renewable, low S-VOC
incompatibility” must remain even after long-term FDA, better odor,
WO White oil
storage low fogging
§§ Have a low surface tension
FoamStar®
§§ Exhibit a de-wetting effect
Universal, easy
Formulation additives
§§ Have the capability to penetrate into the foam ED Emulsion defoamers
to incorporate
lamellae and to spread effectively on the liquid /
High efficiency,
gas interface PB Polymer-based
no silicone
Efka®
Polymer-based High efficiency,
PB
defoamers no silicone
Rheology modifiers
Rheological modifiers are key ingredients in paints and Rheology modifiers from BASF reduce dripping and BASF offers nearly all commercially used classes of characteristic properties. The table below highlights
coatings as they help control the coating application spattering of paint during roller or brush application. synthetic rheology modifiers for water-based paints the benefits and areas of use of each product class.
and the final appearance. Without these special Sag resistance of paint is improved by a rapid but and coatings. Each product class has its own
additives, such media would be as “runny” as water. controlled viscosity increase after application.
During application, paints would spatter in all During transport and storage of the paint, rheology
directions, have little hiding power, and exhibit a modifiers prevent sedimentation of the pigments Polyurethanes, polyethers Acrylics
Property / influence on
much shorter shelf life. Rheology modifiers enable within a formulation. Rheology modifiers ensure (Rheovis® PU, Rheovis® PE) (Rheovis® AS, Rheovis® HS)
formulators to adjust the flow behavior of paints and that the end product achieves the desired balance
Low shear viscosity Medium contribution High contribution
coatings. That way, painters benefit from improved between consistency, durability, and good application
viscosity and application characteristics. properties. High contribution (high film thickness by roller /
High shear viscosity Low contribution, less impact on film thickness
brush application)
Viscosity [mPa·s] Spattering Improves spattering Low effect
105
Storage
104 Gloss Low to no effect Matting effect possible
10 3
Sag, leveling Influence of surfactants Low to high, must be tested in each case Hardly any (AS), moderate (HS)
102
Stirring
10 Painting Low to no tendency to syneresis
Syneresis Tendency to syneresis
depending on type
1
0.01 0.1 1 102 103 104
Good to moderate effect
Scrub and wash resistance Very good effect
depending on type
Brookfield Stormer ICI Shear rate [s-1]
Controlled stress rheometer
Viscosity profile and shear rates at different application scenarios including corresponding measurement equipment
Especially our Rheovis® PU and PE series of The rheological behavior of aqueous paints and
associative thickeners represent a class of coatings can be rendered either more Newtonian
BASF offers six classes of The naming of our products corresponds ground-breaking materials based primarily on hydro- (brush, roll-on, curtain coating) or more pseudoplastic
rheology modifiers for paints to their chemical composition and shear phobically modified polyether and polyurethane (sprayable) in nature to ensure optimized application
and coatings profile derivatives. properties.
With these rheology modifiers, it is possible to create
Formulation additives
§§ Alkali swellable emulsions (ASE) a wide variety of rheological profiles, imparting superb
Rheology modifiers
§§ Hydrophobically modified alkali swellable emulsions attributes to a broad range of water-based paints and
(HASE) coatings.
Rheovis® HS 1xxx Associative acrylic (HASE)
§§ Hydrophobically modified polyurethanes (HEUR)
Rheovis® AS 1xxx Non-associative acrylic (ASE)
§§ Hydrophobically modified polyethers (HMPE) Key benefits for your formulation
§§ Attapulgites (inorganic rheology modifiers) Rheovis® PE 1xxx Associative polyether (HMPE) §§ Broad rheology profile §§ Low impact on water uptake
§§ Castor oil and wax-based thixotropes §§ Highly efficient across many resin types §§ Low impact on water whitening
Rheovis® PU 1xxx Associative polyurethane (HEUR)
§§ pH-independent §§ Excellent leveling
Attagel® Organoclay types §§ Improved wash and scrub resistance §§ Reduced spattering
11xx = low shear 12xx = mid shear 13xx = high shear 19xx = solids
106 Formulation additives
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Formulation additives
We create chemistry that makes coatings love resins and additives 107
Formulation additives
All products except Rheovis® PU 1214 and Rheovis® PU 1250 comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
108 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 109
Formulation additives
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
110 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 111
FoamStar® defoamers
Formulation additives
combination of effectiveness and compatibility
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
112 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 113
Efka® defoamers
Solvent-based solution of
Unsaturated polyester, epoxy, and polyurethane
Efka® PB 2720 defoaming substances, Before or after processing 0.1–10.0 - ~ 60 - - 1 1 - - 1 1
systems
silicone-free
Solvent-based solution
of defoaming substances Polyurethane curtain coatings and stoving
Efka SI 2022
®
Before or after processing 0.1–1.0 - > 90 - - 1 - 1 - 1 1
with modified silicone enamels
compounds
Solvent-based solution
of defoaming substances Physically drying systems and medium- to
Efka SI 2035
®
End of processing 0.5–1.0 - > 95 - - 1 1 1 - 1 1
with modified silicone long-oil air-drying alkyds
Formulation additives
compounds
Solvent-based solution
of defoaming substances Solvent-based industrial finishes, including
Efka® SI 2040 End of processing 0.1–0.7 - > 95 - - 1 - 1 1 1 1
with modified silicone roller, brush, and airless spray applications
compounds
Solvent-based solution
UV-curing and EBC systems; highly effective
of defoaming substances
Efka SI 2721
®
Before or after processing 0.5–1.0 - > 95 - - - 1 1 defoaming in clear and matted systems; - - 1
with modified silicone
defoaming substances in 2-ethylhexyl acrylate
compounds
Solvent-free solution of
Solvent-free epoxy and polyurethane systems,
defoaming substances
Efka SI 2723
®
Prior to processing 0.5–1.5 - < 25 - - 1 1 1 low odor, high-solid 2-pack systems and - 1 1
with modified silicone
solvent-free radiation-curing systems
compounds
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
114 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 115
Ammonium polyacrylate For inorganic pigments and extenders; more hydrophobic than
Dispex® CX 4240 40 - - < 0.1 1 1 - - - - 1
(co-)polymer Dispex® AA 4040
Low molecular weight dispersing agents mainly designed for water-based systems, surfactant-like types
Wetting and dispersing agent for aqueous formulations; suitable
Dispex® Ultra FA 4416 Mixture of surfactants 75 - - <2 - 1 - - - 1 -
for organic and inorganic pigments and pigment concentrates
Formulation additives
Dispex® Ultra PX 4275 Copolymer 37.5 - - < 0.5 1 1 - - designed for semi-gloss and high-gloss paint formulations and 1 1 1
pigment concentrates
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
116 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 117
Formulation additives
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
118 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 119
Low molecular weight dispersing agents mainly designed for solvent-based systems, conventional types
Surface-active anionic Anti-settling agent for non-aqueous systems; provides good
Efka® FA 4600 35.5 - - 27.5 - - 1 - - 1 -
compounds anti-settling properties in polar systems
Blend of fatty alcohol Anti-settling agent for non-aqueous systems; good anti-settling
Efka® FA 4601 47 - - 16 - - 1 - - 1 -
sulfates properties for medium-polar systems
Hydroxyl functional
Efka® FA 4608 unsaturated modified 100 85 - <1 1 - 1 - Solvent-based systems including low to polar solvents - 1 -
carboxylic acid
Modified polyurethane
Efka® PU 4046 40 19 - 60 - - 1 1 General industrial coatings 1 - 1
polymer
Formulation additives
Modified polyurethane High-quality industrial finishes including automotive OEM and
Efka® PU 4047 35 17 - 65 - - 1 1 - 1 1
polymer refinish
Second generation of
High-quality industrial, automotive, and refinish applications,
Efka® PU 4061 modified polyurethane 30 8 - 70 - - 1 - 1 - -
strong viscosity-depressing properties
polymer
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
120 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 121
Acrylic block copolymer Highly efficient dispersing agent for ß- and ε-blue
made by controlled free Cu-phthalocyanine pigments and pigment green; high gloss
Efka PX 4350
®
51 12 - 49 - - 1 - 1 1 -
radical polymerization due to excellent compatibility; for high-quality solvent-based
(CFRP) industrial and automotive coatings
Formulation additives
- - 1 - 1 1 1
pigments incl. α-blue Cu-phthalocyanine pigments; high gloss
due to excellent compatibility; tin-free
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
122 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 123
Formulation additives
Highly effective, low-foaming, substrate-wetting
Hydropalat® WE 3650 Modified alkoxylates 0.5–2.0 > 96 < 0.5 1 1 - - - 1 1 1
agent for water-based coatings
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
124 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 125
Formulation additives
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
126 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 127
Formulation additives
Polysiloxane-modified with unsaturated
Efka® SL 3883 Reactive polysiloxanes 0.2–1.0 70 30 - - 1 1 1 terminal groups; UV-curing systems for wood, - - 1
plastic, and paper coatings
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
Bitte Kurzversion des Kapiteltitels
We create
We chemistry
create chemistry
that makes
Performance
eintragen
that coatings
additives
makes coatings
love resins
loveand
resins
additives 129
129
and additives
Performance additives
Organic coatings and inks with aesthetical, protective, and other functional properties
are exposed to a variety of environmental and artificial factors such as solar radiation,
humidity, temperature change, microbiological attack, air pollutants, and many more.
In order to assure that coatings will maintain their beautiful appearance, we offer the
most comprehensive portfolio of stabilizers and other performance additives: UV
absorbers (UVA) and hindered amine light stabilizers (HALS) for effective stabilization
against the detrimental effects of light and weathering, as well as phenolic and
non-phenolic antioxidants against thermally induced degradation during production,
processing, and service life. The product range is completed with optical brighteners.
Performance additives
130 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 131
BP UVA based on 2-hydroxy-benzophenone are HALS are mainly derivatives of 2,2,6,6-tetramethyl Tinuvin® DW range Irganox® and Irgafos®
mainly used in applications where low to medium piperidine (TMP). They act as radical scavengers and
protection is required. inhibit the photo-oxidative degradation of polymers. The Tinuvin® DW range is based on aqueous Irganox® and Irgafos® antioxidants (AO) protect
preparations of light stabilizers designed for coatings, plastics, and fibers against thermal
BTZ UVA based on 2-(2-hydroxyphenyl)-benzotriazole water-based coatings and inks. degradation during processing, production, and
show a broader spectral coverage combined with a service life. Irganox® comprises a complete range of
better photopermanence than BP and are used in Tinuvin® blends AO based on sterically hindered phenols or thioethers,
various applications such as plastics, textiles, and as well as blends of different AO classes. Irgafos® are
coatings. They fulfill medium (industrial / architectural / Tinuvin® 5000 blends are liquids based on synergistic so-called secondary AO process stabilizers based on
wood) to high-end (automotive) protection requirements. combinations of UVA and HALS, thereby combining phosphite chemistry.
easy handling with excellent compatibility and solubility
HPT UVA based on 2-hydroxyphenyl-s-triazine exhibit in most organic solvents, resins, and binder systems. Tinopal®
superior photopermanence and heat stability and a
higher extinction coefficient compared to BTZ and BP. Lignostab® Tinopal® optical brighteners (fluorescent whitening
HPT also show excellent chemical resistance. agents) are designed to brighten coatings or to mask
In contrast to BP and BTZ, mono-resorcinyl-triazines Lignostab® are lignin-stabilizing additives for wood yellowing. Tinopal® can also be used as a marker
do not interact with certain metal ions (e.g. catalysts pretreatment that engender color retention and where fluorescence is employed to detect film voids
or production-related impurities) or with strong alkali. improved durability. or for registration and identification purposes.
HPT is the UVA class of choice for applications
involving high baking temperatures and / or extreme
environmental conditions.
Performance additives
132 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 133
Background of light
and heat stabilization
How UV radiation and heat promote degradation of organic substrates.
Light- or heat-induced oxidation of organic materials Photo-oxidation in the presence of light and oxygen Mechanism of light and / or thermally induced oxidation
is a complex radical process involving initiation, is the prevailing mechanism under interior and ambient
propagation, chain branching, and autocatalytic conditions. The main consequence is discoloration
1 3 4
chain and termination reactions. Both initiation steps of the substrate (i.e. yellowing) or fading of colorants h·ѵ R•
generate free radicals (R•) to enter this cyclic process. (e.g. in wall paints or inks). Under exterior weathering CH CH* O2
Performance additives
134 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 135
UV absorbers
Tinuvin® and Chimassorb® UV absorbers (UVA) prevent the degradation of both The required concentration of UVA Mode of action of 2-(2-hydroxyphenyl)-
coatings and substrates by filtering out harmful UV radiation during the photolysis for effective protection depends on benzotriazole (BTZ) and
the dry film thickness of the coating 2-hydroxyphenyl-s-triazine (HPT) UV
cycle before subsequent photo-oxidation can take place. and the absorption coefficient of the absorbers
choosen UVA
converting absorbed light energy (h•ѵ) into heat. First the Lambert Beer law allows the amount of UVA
the UVA chromophore CH absorbs radiation energy needed for proper light protection to be calculated for 20–40 µm 4–2 -
HO O
(h•ѵ) and becomes an energy-enriched excited-state a given film thickness d. Increased c or d results in HPT h·ѵ
H +
R2 N N R2 R2 N N R2
CH*, which causes an electronic rearrangement, e.g. increased filter effect and therefore increased protection ΔT
N N
a reversible intramolecular proton transfer. The CH* against harmful UV radiation. In addition, the law also
40–80 µm 2–1 R3 R3 R3
is then deactivated by a radiationless release of heat infers that the filter effect is strongly influenced by R3
energy (ΔT) and reverts to its original form (ground coating thickness; the thinner the coating, the more
state). UVA are necessary. Hence UVA on their own are
insufficient for protecting the surface of a coating itself
The main criteria for selecting UVA are their specific (where thickness d approaches 0). It follows, then, that General structures of 2-hydroxyphenyl-benzophenone (BP), 2-(2-hydroxyphenyl)-
photo-physical (primary) and physical (secondary) UVA cannot effectively prevent the formation of surface benzotriazole (BTZ), and 2-hydroxyphenyl-s-triazine (HPT) UV absorbers
properties. Photo-physical properties of UVA are defects resulting from photo-degradation under exterior
absorbance A (= measure of the filter effect of a UVA conditions. For exterior conditions the combination of
at a certain wavelength) and the extinction coefficient UVA and HALS creates synergistic effects producing R1
ε, which is a molecule-specific constant that indicates excellent protection against surface defects and H
O O HO R1
the efficiency of the filter effect of a chromophore. The discoloration. For interior conditions, the use of UVA HO
N
absorbance A is a direct measure of the filter effect and alone is normally sufficient for preventing both the N R2 N N R2
is in inverse logarithmic relation to the transmittance T colorant fading of coatings and inks as well as the R1 R
3 N N
R2
(= amount of light penetrating through a coating / yellowing of resins. R3 R3
plastic). The absorbance A and the transmittance T BP BTZ HPT
of UVA depend both on the chemical class and the Photo-permanence (i.e. physical / chemical loss of UVA
molecular weight. The UV absorption spectra of during service life) and heat stability (i.e. low volatility)
Tinuvin® UV absorbers and of blends thereof, as well are basic requirements for UVA efficacy in the final
of the Chimassorb® UVA are shown on pages application.
140 / 141. Lambert Beer law
Performance additives
§§ Chromophore concentration c
§§ Light path length or film thickness d
§§ Extinction coefficient ε
136 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 137
1.50 2.5
Spectra were recorded with 1.0 Spectra were recorded with
20 mg/l in toluene, path = 1 cm 20 mg/l in toluene, path = 1 cm
1.25 Spectra were recorded with
20 mg/l in toluene, path = 1 cm 1.6 2.0
0.8 Spectra were recorded with
1.00 20 mg/l in toluene, path = 1 cm
1.2 1.5
Absorbance [AU]
Absorbance [AU]
Absorbance [AU]
Absorbance [AU]
0.6
0.75
0.8 1.0
0.4
0.50
0.4 0.5
0.25 0.2
0 0
0 0
290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430
Wavelength [nm] Wavelength [nm] Wavelength [nm] Wavelength [nm]
Tinuvin® 326 Tinuvin® Carboprotect® Tinuvin® 900 Tinuvin® 384-2 Tinuvin® 928 Tinuvin® 400 Tinuvin® 405 Tinuvin® 460 Tinuvin® 477 Tinuvin® 479
1.0 1.0
1.5 1.5
Spectra were recorded with Spectra were recorded with Spectra were recorded with Spectra were recorded with
20 mg/l in toluene, path = 1 cm 20 mg/l in toluene, path = 1 cm 40 mg/l in toluene, path = 1 cm 40 mg/l in toluene, path = 1 cm
1.25 1.25
0.8 0.8
1.0 1.0
Absorbance [AU]
Absorbance [AU]
Absorbance [AU]
Absorbance [AU]
0.6 0.6
0.75 0.75
0.4 0.4
0.5 0.5
0 0
0 0
290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430
290 310 330 350 370 390 410 430 280 300 320 340 360 380 400
Wavelength [nm] Wavelength [nm]
Wavelength [nm] Wavelength [nm]
Performance additives
Chimassorb® 81 Tinuvin® 171 Tinuvin® 99-2 Tinuvin® 1130 Tinuvin® 5248 Tinuvin® 5251 Tinuvin® 5050 Tinuvin® 5060 Tinuvin® 5151
138 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 139
The Tinuvin® DW (N) range is based on aqueous preparations of light stabilizers Tinopal® fluorescent optical brighteners (OB) are designed to brighten or enhance
designed for all water-based applications. Based on novel encapsulated additive the appearance of coatings, adhesives, and sealants by producing a perceived
technology (NEAT), Tinuvin® DW (N) has low viscosity, is solvent-free, storage- and “whitening” effect and also serve to mask yellowing.
sedimentation-stable, and has no EUH 208 label.
1.00
Tinopal® NFW Liquid
0.80
Tinuvin® DW (N) comprises a range of selected BTZ This allows to add them at the end of the production Tinopal®
and HPT UVA as well as HALS preparations. These process under normal stirring conditions without
Rel. intensity
0.60
light stabilizer preparations are based on a proprietary specific equipment and / or dispersing aids, e.g. Tinopal® can also be used where fluorescence can
encapsulation technique where active agents are emulsifiers or cosolvent. provide a mean to determine film thickness, and 0.40
essentially dissolved in an acrylic copolymer matrix. After being incorporated into the liquid paint they for registration and identification purposes, e.g.
The NEAT-based preparations exhibit excellent do not impair paint properties and storage stability. in adhesives and sealants as a fluorescent tracer 0.20
long-term storage stability without any sedimentation The Tinuvin® DW (N) range fully maintains dry film in in-line assurance inspections. OB are dyes that
or phase separation in their delivery form. The absence properties such as inherent color, gloss, and trans work by re-emitting light through the mechanism 0
of EUH 208 label and of co-solvents make them the parency. Other properties such as water permeability of fluorescence. They absorb light in the ultraviolet 275 325 375 425 475 525 575 625
Wavelength [nm]
ideal choice for low to zero VOC applications. They are and blocking resistance, hardness, and scratch region of the electromagnetic spectrum (usually
Fluorescence min / max Absorption min / max
easy to incorporate and homogeneously disperse into resistance are not affected. 340–370 nm), and emit light in the blue region
1.00
water and / or water-based paints. (typically 420–470 nm). Tinopal® OB CO
0.80
The Tinopal® range is available in a powder form that
is soluble in solvent or water and as a solution for
direct use in various applications. Due to the limited 0.60
Rel. intensity
Tinuvin® 5000 series photostability of optical brighteners, which can result
in yellowish degradation products, their use for 0.40
The Tinuvin® 5000 series and other Tinuvin® blends offer synergistic combinations 1.00 0
Tinopal® SFP
of UVA and HALS against surface defects while also maintaining color and gloss 275 325 375 425 475 525 575 625
Wavelength [nm]
retention in coating applications. 0.80 Fluorescence min / max Absorption min / max
1.00
Tinopal® SFP
Rel. intensity
0.60
The Tinuvin® 5000 series is attractive for its combination them particularly suitable for coatings exposed to high 0.80
of easy handling with its excellent compatibility and baking temperatures and / or extreme environmental
0.40
solubility in most solvent-based coating systems. conditions. Furthermore, they are not sensitive
Rel. intensity
0.60
The Tinuvin® 5000 family matches all performance to high pH and certain metal ions, i.e. there is no
requirements for architectural, industrial, and formation of colored complexes. Blends containing 0.20 0.40
automotive applications. The broad UV absorbance N-OR HALS are especially suitable for oxidative curing
Performance additives
of BTZ-based blends makes them suitable for a and acid-catalyzed systems. The non-basic character 0.20
0
wide range of coatings on wood, plastic, and metal prevents potential interactions with acidic paint
275 325 375 425 475 525 575 625
substrates. HPT-based blends show high thermal ingredients such as catalysts, biocides, and pigments. Wavelength [nm] 0
stability and superior photopermanence, which makes 275 325 375 425 475 525 575 625
Fluorescence min / max Absorption min / max Wavelength [nm]
N N
R1 N O (CH2)8 O N R1 R2
N R
2
N N R N CH3 pkb ~ 5–6 Tinuvin® 292
The mode of action of HALS is largely independent surfactants, catalysts, or certain acid-treated pigments, O O
of the applied film thickness, which in turn means which can result in limited formulation stability
that they can also act at the coating surface where or the deactivation of HALS or of other additives. N N
R N (CH2)2 OR pkb ~ 7–8 Tinuvin® 622 SF
only minor protection is provided by a UVA (see Furthermore, basic HALS can interfere with the R 1
R1
Lambert Beer law). In clear coats they protect against curing process of acid-catalyzed or oxidation-based A B
surface defects such as loss of gloss or cracking, curing systems. Because non-basic N-OR HALS do
whereas in pigmented coatings they prevent chalking not interact, they are the products of choice for all R N OR pkb ~ 8–10 Tinuvin® 123
Tinuvin® 152
and discoloration. Such surface defects eventually applications where traditional basic HALS fail. Typical structures of hindered amine light stabilizers (HALS) Tinuvin® 249
lead to substrate erosion due to increased water A: linked by diester; B: linked by triazine ring
Tinuvin® 5100
permeability and the loss of physical and protective The usage amount of UVA and HALS strongly
properties. Today, a large variety of HALS utilizing depends on the concentration of pigments (acting as
mono-, di-, or oligo-functional TMP are available; their UV screeners) and the final thickness of the coating.
wide range of physical and chemical properties enable Clear coatings require higher amounts of UVA
Denisov cycle
them to fulfill the multiple requirements of the coatings (and lower dose levels of HALS) whereas opaque
and plastics industries. pigmented coatings require higher amounts of HALS
(and lower UVA dose levels). Typical usage amounts
1 2 R• 3
According to the “Denisov cycle” the mode of action are listed in the table below. The usage amount of UVA
of HALS is a cyclic regenerative process. In the in pigmented coatings depends on the pigments used.
h·ѵ, O2
presence of oxygen (O2) and UV radiation (h•ѵ), the The lightfastness or weather stability of some organic N R N O• N OR
HALS compound is converted into the corresponding pigments can be improved by addition of UVA,
nitroxyl radical NO• as an active species that traps free whereas for inorganic pigments the use of UVA can be
RO• radicals through the formation of an aminoether dispensed with. R'OH + R=O R'OO •
N-OR structure. N-OR interacts with ROO• forming
intermediates, which then decompose into harmless
Typical UVA and HALS use levels
decomposition products, thereby reforming the active
species NO•. The cyclic nature of the stabilization Mode of action of hindered amine light stabilizers (HALS)
according to the Denisov cycle
process along with the regeneration of the active
Pigmentation Active UVA [%]1 Active HALS [%]2
species explains the high and long-term efficiency
of HALS.
Clear 1–2 1
Besides solubility and compatibility, the first selection
criteria for HALS is their basicity. The basicity of
HALS is governed by the substitution pattern on the Semi-transparent 1–2 1–2
piperidine nitrogen: H or alkyl-substituted HALS are
Performance additives
basic, whereas aminoether-(N-OR)-functionalized
HALS are considered as non-basic. Basic HALS Opaque 0–1 1–2
are highly efficient and long-term stable; they can,
however, undergo acid / base interactions with certain 1
% active UVA on binder solids (DFT ~ 40 µm)
formulation components such as biocides, 2
% active HALS on binder solids (does not depend on DFT)
142 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 143
Antioxidants (AO)
AO structures
AO prevent thermally induced oxidation of polymers in coatings during heat exposure, Hindered phenol AO Phosphite AO Thioether AO
processing, and curing or baking at high temperatures, as well as during their service R2
OH
R1
R2
S(R)2
life. Irganox® and Irgafos® denote different primary sterically hindered phenolic AO R3 O P(R)3-x
Mechanism of AO
Unlike HALS, AO are a non-regenerative reaction Hindered phenol AO
mechanism, which in turn means that both primary and Hindered phenol AO
§§ activity over broad temperature range (RT to melt)
secondary AO are essentially consumed and rendered
ineffective after reaction. Conversely, HALS are usually §§ improve long-term thermal stability OH O• O O O
R2 R1 R2 R1 R2 R1 R2 R1 R2 R1
not effective in preventing thermal degradation but do §§ non-regenerative mechanism, consumption during + ROO· + ROO·
have the advantage that the regenerative nature of reaction • - ROR3
HALS allows them to function over much longer time R3 R 3
OOR O
R3 R3
p-Benzoquinone
scales. This makes them well suited as light stabilizers,
although some oligo-functional HALS can also Phosphite AO
be effective heat stabilizers under long-term and Phosphite AO Thioether AO
§§ phosphites are processing stabilizers
moderately low heat exposure conditions.
§§ stable against hydrolysis R2
R 2
Primary AO such as the sterically hindered phenols §§ no colored reaction products R3 O P + ROOH R3 O P=O + ROH S(R)2 + ROOH (R)2S=O + ROH
deactivate free radicals (RO•) formed during thermal
R1 3 R1 3
oxidation and interrupt breakdown reactions via a
kinetic mechanism. Primary AO work by donating Thioether AO
hydrogen atoms to preferably oxygen-centered radicals
§§ thiosynergists “like it hot”
(RO•, ROO•), thereby interrupting the autoxidation
§§ rate of ROOH decomposition increases with ΔT Effective use temperatures for the different classes of stabilizers
process. Phenolic AO are multipurpose products for
a broad temperature range and are mainly used to §§ designed to protect against high-temperature aging Long-term thermal stability (LTTS) Melt processing stability
increase the long-term thermal stability of various
coatings or plastics.
Oligomeric HALS Hindered amines
Secondary phosphite AO decompose peroxides
§§ HALS with AO properties
(ROOH) formed during the autoxidation process
§§ work up to 120 °C Thiosynergists
and extend the performance of primary AO through
synergistic effects. §§ stable against light, migration, and extraction
Today, hydrolytically stable phosphites and divalent Hindered phenols
§§ regenerative mechanism in contrast to AO
sulfur compounds are the most widely used secondary
AO. Applications include heat stabilization during Phosphites
synthesis, processing, mixing, extrusion, and curing
of coatings that are baked or cured at relatively high
0 50 100 150 200 250 300
Performance additives
temperatures (e.g. coil coatings and powder coatings).
°C
Solid Melt
144 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 145
Water-based UV absorbers
Tinuvin® 400-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture 1 1 1 1 Blue-shifted UVA for water-based high-performance applications, excellent spectral coverage in combination with Tinuvin® 479-DW
Tinuvin® 477-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture - 1 1 1 Red-shifted UVA for high-performance water-based wood coatings
UVA with extremely high extinction coefficient, for highest durability requirements in water-based clear coats, specifically suited for thin
Tinuvin® 479-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture 1 1 - 1
film applications
Tinuvin® 1130 Benzotriazole Liquid - Mixture 1 1 1 1 UVA for medium-performance solvent-based and water-based coatings (may require addition of cosolvent)
Tinuvin® 9945-DW (N) Benzotriazole Liquid 45% active - Mixture - 1 1 1 Multipurpose UVA for medium to high durability requirements for water-based formulations
Solvent-based UV absorbers
Benzophenone (BP)
Chimassorb® 81 (ED) Benzophenone Solid 47–51 326 - 1 1 1 UVA for moderate durability requirements; mass stabilization of gel coats
Benzotriazole (BTZ)
Tinuvin® 99-2 Benzotriazole Liquid 95% in MPA** - 452 - 1 1 1 UVA for medium-performance solvent-based coatings
Tinuvin® 326 Benzotriazole Solid 138–142 316 - 1 1 1 Chlorinated red-shifted UVA, allows < 1% transmittance up to 370 nm; limited solubility in organic solvents
Tinuvin® 384-2 Benzotriazole Liquid 95% in MPA** - 452 1 1 - - Multipurpose UVA for medium to high durability requirements, minimum color impact in refinish clear coat applications
Tinuvin 900
®
Benzotriazole Solid 138–142 448 1 1 - - UVA for medium to high durability requirements in powder and coil coating applications, limited solubility in organic solvents
Tinuvin 928
®
Benzotriazole Solid 109–113 442 1 1 - - UVA for medium to high durability requirements in powder and coil coating applications, excellent solubility in organic solvents
Tinuvin® 1130 Benzotriazole Liquid - Mixture 1 1 1 1 UVA for medium-performance solvent-based and water-based coatings (may require addition of cosolvent)
Very red-shifted UVA for protection of aromatic epoxy systems, especially recommended for carbon or glass fiber reinforced composites;
Tinuvin® Carboprotect® Benzotriazole Solid 132–136 560 1 1 - -
allows < 1% transmittance up to 420 nm
Tris-ResorcinylTriazine (TRT), high photo- and thermal-permanence
Tinuvin® 460 Tris-Resorcinyltriazine Solid 97–101 630 - 1 - - Red-shifted UVA with extremely high extinction coefficient, allows ~ 1% transmittance up to 370 nm, limited solubility in organic solvents
Tinuvin® 477 Tris-Resorcinyltriazine Liquid 80% in MPA** - Mixture - 1 1 1 Red-shifted UVA with high extinction coefficient, for high durability wood coating requirements, allows < 1% transmittance up to 370 nm
HydroxyPhenylTriazine (HPT), best photo- and thermal-permanence, no interaction with amines, strong alkali, or any metal catalysts
Liquid 85% in Blue-shifted UVA for high durability requirements in clear coat applications including UV-curing systems, excellent spectral coverage in
Tinuvin® 400 Hydroxyphenyltriazine - 647 1 1 1 1
1-methoxypropan-2-ol combination with Tinuvin® 479
Tinuvin® 405 Hydroxyphenyltriazine Solid 73–77 584 1 1 - - Blue-shifted UVA for high durability requirements in powder clear coats, excellent spectral coverage in combination with Tinuvin® 479
UVA with extremely high extinction coefficient, for highest durability requirements in clear coats, powder coatings, or UV-curing systems,
Tinuvin® 479 Hydroxyphenyltriazine Solid 39–43* 678 1 1 1 1
specifically suited for thin film applications
Performance additives
* Tg [°C]
** 1-methoxy-2-propyl acetate
146 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 147
Multipurpose basic HALS for color-sensitive applications such as refinish coatings, use in water-based coatings may require addition of
Tinuvin® 292 HP N-alkyl HALS Liquid - 509 / 370 1 - - -
cosolvents, may interact with sensitive dispersion binders
Multipurpose basic HALS for various applications, use in water-based coatings may require addition of cosolvents, may interact with
Tinuvin® 292 N-alkyl HALS Liquid - 509 / 370 1 1 1 1
sensitive dispersion binders
Multipurpose basic HALS for color-sensitive applications such as refinish coatings, use in water-based coatings may require addition of
Tinuvin® 292 HP N-alkyl HALS Liquid - 509 / 370 1 - - -
cosolvents, may interact with sensitive dispersion binders
Tinuvin® 770 DF (ED) N-H HALS Solid 81–85 480 - 1 - - HALS suitable for powder-coating applications
Tinuvin® 152 N-OR HALS Solid 72–76 757 1 1 - - Non-migrating, reactable low basic HALS for polar solvent-based coatings over plastic substrates (e.g. polycarbonate, ABS substrate)
Non-basic HALS, no exudation from solvent-based polar coatings, low viscosity and very low inherent color; use in water-based coatings
Tinuvin® 249 Non-basic HALS Liquid - 482 1 1 1 -
may require addition of cosolvents
Tinuvin® 622 SF Oligomeric N-R HALS Solid - 3,100–4,000 - 1 - - Low-basic HALS for powder-coating applications with very good antioxidant properties, limited solubility in organic solvents
Tinuvin® 5100 N-OR HALS Liquid - 737 - 1 1 1 Non-basic HALS for oxidative curing coatings
Lignostab 1198 L
®
Lignin stabilizer Liquid 20% in water - 172 - - 1 1 Lignin stabilizer solution for wood impregnation
Performance additives
148 Performance additives
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Performance additives
We create chemistry that makes coatings love resins and additives 149
Tinuvin® 5050 BTZ / N-alkyl HALS Liquid - Mixture - 1 1 1 UVA / HALS blend for solvent-based applications
Tinuvin 5060
®
BTZ / N-OR HALS Liquid - Mixture - 1 1 1 UVA / non-basic HALS blend for solvent-based oxidative curing coatings
Tinuvin 5151
®
BTZ / N-alkyl HALS Liquid - Mixture 1 1 1 1 UVA / HALS blend for solvent-based coatings, use in water-based coatings may require addition of cosolvent
Tinuvin® 5248 HPT / N-alkyl HALS Liquid - Mixture 1 1 - 1 UVA / HALS blend for high-performance solvent-based applications
Tinuvin® 5251 HPT / N-alkyl HALS Liquid - Mixture 1 1 - 1 UVA / HALS blend for high-performance solvent-based applications
Tinuvin® 5333-DW (N) UVA / HALS Liquid 40% active - - - 1 1 1 High-performance UVA / non-basic HALS blend for water-based applications with broad spectral coverage
Tinuvin B 75 (ED)
®
AO / N-alkyl HALS / UVA Liquid - Mixture - - 1 - Stabilizer blend for furniture and flooring applications
Performance additives
150 Performance additives
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Performance additives
We create chemistry that makes coatings love resins and additives 151
Irganox® 245-DW Phenol Liquid 40% active - 587 - 1 - - AO for water-based coating applications
Irganox 1035
®
Phenol Solid 63–78 643 - 1 - - AO for solvent-based coating applications
Irganox® 1076 (ED) Phenol Solid 50–55 531 1 1 - - AO for solvent-based and powder-coating applications
Irganox® 1425 Calcium phosphonate Solid > 260 695 - 1 - - Stabilizer for synthesis of polyester resins
Irgafos® 168 (ED) Phosphite Solid 183–186 647 1 1 - - AO for solvent-based and powder-coating applications, prevents yellowing in direct gas fired ovens
Antioxidant blends
Irganox® B 225 (ED) Phenol / phosphite Solid > 100 - - 1 - - AO blend for powder-coating applications
Irganox B 900
®
Phenol / phosphite Solid 59–61 - 1 1 - - AO blend for powder-coating applications
Optical brighteners
Tinopal® NFW LIQ Biphenyl-stilbene Liquid 20% active - 563 - 1 - 1 Liquid optical brightener for water-based white and pastel-tone paints, clear coats, overprint varnishes
Tinopal® OB CO Benzoxazole Solid 196–203 431 - 1 - 1 Solid optical brightener for solvent-based white and pastel-tone paints, clear coats, overprint varnishes
Tinopal SFP
®
Triazine-stilbene Solid - 1,305 - 1 - 1 Water-soluble optical brightener for photographic color developer baths or as fluorescent tracers
Performance additives
Contacts
Contact
Worldwide
Europe, Africa, West Asia
BASF Nederland B.V.
Asia North America
Resins & Additives
BASF (China) Co., Ltd. BASF Corporation
Innovatielaan
No. 1
300, Jiangxinsha Road, 24710 West Eleven Mile Road
8466 SN Shanghai
Pudong, Nijehaske200137 Southfield, Mi 48034
P.O. China
P.R. Box 390 USA
8440 AJ Heerenveen
The Netherlands
Phone: +86-21-2039-5213 US and Canada:
dispersions-asiapacific@basf.com Phone: +1-800-231-7868
Tel.: +31 51 3619-619 dpsolutions@basf.com
Fax: +31 51 3619-600
Mexico:
resins@basf.com Phone: +52-55-5325-2600
contactoed@basf.com
BASF SE
67056 Ludwigshafen
Germany
www.basf.com/resins
The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.