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Contact

Europe, Africa, West Asia


BASF Nederland B.V.
Resins & Additives

Innovatielaan 1
8466 SN Nijehaske
We create chemistry
that makes coatings
P.O. Box 390
8440 AJ Heerenveen
The Netherlands

Tel.: +31 51 3619-619


Fax: +31 51 3619-600 love resins and additives
resins@basf.com

BASF SE

67056 Ludwigshafen
Germany
www.basf.com/resins

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.

® = registered trademark of the BASF Group  2019


EDC 0115e
Table of contents
 2019 3

Table of contents

Market technology matrix 4 Radiation-curable systems 71


We create chemistry 8 Epoxy acrylates 82
Polyester acrylates 84
Water-based systems 11
Amine-modified polyether acrylates,
Colloidals and
polyether acrylates, and dual cure resins 86
non-cross-linking acrylic dispersions 20
Urethane acrylates 88
Explore our Non-cross-linking acrylic dispersions 22
portfolio online Unsaturated polyesters
Self-cross-linking acrylic dispersions 24
and UV specialties 90
www.basf.com/ OH-functional dispersions 26
UV monomers 92
resin-additive-search Polyurethane dispersions
Water-based UV resins 94
and PUD / acrylic hybrids 28
Amino resins 30
Polyisocyanates 32
Formulation additives 97
Epoxy resins and amine adducts 34 Rheology modifiers 106

Grinding resins, waxes, Defoamers 110


and cross-linker solutions 36 Dispersing agents 114
Wetting agents and surface modifiers 122
Solvent-based systems 39
Acrylic polyols, HPE, and catalyst 46 Performance additives 129
Amino resins and co-cross-linker 48 UV absorbers for water-based
Urea resins and polyvinyl chlorides 50 and solvent-based coatings 144

Polyisocyanates and cross-linker 52 HALS for water-based


and solvent-based coatings 146
Grinding resins, unsaturated
polyesters, and amine 54 Light stabilizer blends 148

Soft resins 56 Antioxidants and optical brighteners 150

Renewable systems 59
BASF’s Biomass balance apporach 60
Natural oil-based polyols 62
Properties of natural oil-based polyols 68
4 Market technology matrix
 2019
Market technology matrix
 2019 5

Our solutions for your requirements

Furniture Flooring Automotive Industrial


Interior
Product chemistry Brand name Page Economic Medium-quality High-quality Wood PVC / linoleum  Concrete Automotive Automotive Exterior
Car parts topcoats & Protective
furniture furniture furniture flooring / cork flooring flooring OEM refinish topcoats
primers

Water-based systems
Colloidals and non-cross-linking acrylic dispersions Joncryl® / Acronal® 20 1 1 - - - - - - - - - -

Non-cross-linking acrylic dispersions Joncryl®


22 1 1 - - - - - - 1 - 1 1

Self-cross-linking acrylic dispersions Joncryl  / Luhydran


® ®
24 1 1 1 1 1 1 - - - - - -

OH-functional dispersions Basonol® / Joncryl® / Luhydran® 26 - - 1 1 1 1 - - - 1 1 1

Polyurethane acrylic hybrids / polyurethane dispersions Joncryl® / Basonol® 28 - 1 1 1 1 1 - - 1 - 1 -

Amino resins Luwipal  / Plastopal


® ®
30 1 1 1 - - - 1 - - 1 1 -

Polyisocyanates Basonat ®
32 - 1 1 1 - 1 1 1 1 1 1 1

Epoxy resins 34 - - - - - 1 - - - - 1 1
Waterpoxy®
Amine adducts 34 - - - - - 1 - - - - 1 1

Grinding resins Joncryl® / Laropal® 36 1 1 1 - - 1 - 1 1 1 1 1

Waxes and cross-linker solutions Joncryl  / Zinc Oxide Solution


®
36 1 1 1 1 1 1 - - - - - -

Solvent-based systems
Acrylic polyols Joncryl® 46 - 1 1 1 - 1 - - - 1 1 1

Hyperbranched polyesters Basonol® HPE 46 - - - - - - 1 - - 1 1 1

Amino resins Luwipal  / Plastopal  / Larotact


® ® ®
48 1 1 1 1 - - 1 - - 1 1 -

Polyvinyl chlorides Laroflex ®


50 - - - - - - - - - - 1 1

Polyisocyanates Basonat ®
52 - 1 1 1 - 1 1 1 1 1 1 1

Amine Laromin® 54 - - - - - - - - - - 1 1

Grinding resins Laropal® 54 1 1 1 - - 1 - 1 1 1 1 1

Unsaturated polyesters Ludopal ®


54 - - - - - - - - 1 - 1 -

Acronal  / Joncryl  / 


® ®
Soft resins (acrylic resins, vinyl ethers, glycoluril) 56 - 1 1 - - - - - - - 1 1
Lutonal® / Plastigen® G ULF

Renewable systems
Natural oil-based polyols Sovermol® 64 - 1 1 1 1 1 - 1 1 1 1 1
6 Market technology matrix
 2019
Market technology matrix
 2019 7

Our solutions for your requirements

Furniture Flooring Automotive Industrial


Interior
Product chemistry Brand name Page Economic Medium-quality High-quality Wood PVC / linoleum Concrete Automotive Automotive Exterior
Car parts topcoats & Protective
furniture furniture furniture flooring / cork flooring flooring OEM refinish topcoats
primers

Radiation-curable systems
Epoxy acrylates 82 1 1 1 1 1 - - - 1 - 1 1

Polyester acrylates 84 1 1 1 1 1 - - - 1 - 1 -

Amine-modified polyether acrylates 86 1 1 1 1 1 - - - 1 - 1 -

Polyether acrylates and dual cure resins 86 1 1 1 1 1 - - - 1 - 1 -

Urethane acrylates Laromer® 88 1 1 1 1 1 - 1 1 1 1 1 -

Unsaturated polyesters 90 1 1 1 1 1 - - - 1 - 1 1

UV specialties 90 1 1 1 1 1 - - 1 1 1 1 1

UV monomers 92 1 1 1 1 1 - 1 1 1 1 1 1

Water-based UV resins 94 1 1 1 1 1 1 - - 1 1 1 -

Formulation additives
Solvent-based and solvent-free systems
Defoamers 112 1 1 1 1 1 1 1 1 1 1 1 1

Dispersing agents 118 1 1 1 1 1 1 1 1 1 1 1 1


Efka®
Rheology modifiers 108 1 1 1 - - - 1 1 1 1 1 1

Wetting agents and surface modifiers 124 1 1 1 1 1 1 1 1 1 1 1 1


Water-based systems
Defoamers FoamStar® 110 1 1 1 1 1 - 1 1 1 1 1 1

Dispersing agents Dispex  / Dispex Ultra


® ®
114 1 1 1 1 1 - 1 1 1 1 1 1

Rheology modifiers Rheovis ®


106 1 1 1 1 1 - 1 1 1 1 1 1

Wetting agents and surface modifiers Hydropalat ®


122 1 1 1 1 1 - 1 1 1 1 1 1

Performance additives
UV absorbers 144 1 1 1 1 1 1 1 1 1 1 - 1
Chimassorb® / Tinuvin® / 
HALS 146 1 1 1 1 1 1 1 1 1 1 - 1
Lignostab®
Light stabilizer blends 148 1 1 1 1 1 1 - - - - - -

Hindered phenolic primary antioxidants - - - - - - 1 - - 1 1 -

Thioether secondary antioxidants - - - - - - 1 - - 1 1 -


Irganox® / Irgafos®
Phosphite secondary antioxidants 150 - - - - - - 1 - - 1 1 -

Antioxidant blends - - - - - - 1 - - 1 1 -

Optical brighteners Tinopal ®


- - - - - - - - - - 1 -
8 We create chemistry
 2019

Find your perfect match

At BASF, we create chemistry. We offer tailor-made and sustainable solutions based


on our long-term technical expertise and market knowledge. As such, we can proudly
offer you a comprehensive portfolio of resins, formulation additives, light stabilizers,
antioxidants, and cross-linking agents for the formulation of industrial, automotive,
furniture, and flooring coating applications.

Your committed partner

Our goal is to understand the unique challenges faced by each industry as well as
the impact of the respective market trends. Our dedicated team works to develop
innovative, custom-made, and sustainable solutions to advance your formulations.

We constantly upgrade our assets and invest in additional capacities to fulfill


the growing demand for environmentally friendly technologies. Our leading-edge
competency in product safety and regulatory affairs helps you to comply with
increasing legal demands.

Worldwide close to our customers

In today’s global and rapidly changing business environment, a global footprint is a


key requirement in remaining competitive. With backward integrated production sites
across the world, we can deliver the high-quality products you need. This also helps
us to better understand your local market with an eye to research and development,
product supply, environmental concerns, and technical services.

Take a look at our far-reaching portfolio. In collaboration with our experts you will
surely find the perfect match of products to suit your needs. This brochure will give
you an overview of the comprehensive and steadily growing portfolio. Our recent
product launches are marked with NEW.
Water-based systems
Water-based
Bitte Kurzversion des Kapiteltitels systems
eintragen
 2019 1111
 2019

Water-based systems

The growing trend towards water-based systems is based on economic factors,


low-VOC demand, and health and safety requirements.

We are driving market conversion by setting new trends and industry standards
in terms of cost and performance.

Performance meets sustainability Broad formulation toolbox

In our view, finding the best match means delivering We provide a broad technology toolbox consisting of
high-performance for your formulation without several water-based technologies offering a variety of
harming the environment. For example, our products choices to match your specific requirements – ranging
make it possible to produce long-lasting and resilient from acrylic dispersions to polyurethane dispersions
coatings while, at the same time, reducing the output and polyurethane acrylic hybrids.
levels of volatile organic compounds (VOC).
Water-based systems
12 Water-based systems
 2019
Water-based systems
 2019 13

Acrylic dispersions
for water-based systems
Rheology profile Joncryl®

Resistant, long-lasting, and environmentally friendly Viscosity [mPa∙s]


Joncryl® dispersion (near-Newtonian)
Conventional acrylic dispersion (pseudoplastic)

Acronal® PRO, Joncryl®, and Luhydran® dispersions are the key product lines within
our comprehensive portfolio. They allow you to choose from a range of water-based
technologies and can be formulated according to the desired application method:
spraying, dipping, roller, and curtain coating, as well as manual applications such as
brushing and rolling.

Acronal® PRO acrylic dispersions Joncryl® acrylic dispersions Flow Spray / brush / roller


Shear rate [s-1]
Acronal® PRO is an innovative product line from BASF Most Joncryl® dispersions are characterized by the use
for anticorrosive metal coatings. of a low molecular weight acid-functional resin as a
polymeric emulsion stabilizer. Therefore, most Joncryl®
PRO stands for dispersions have a near-Newtonian rheology profile.
These products are especially suited for industrial
§§ Protection – offering high-performance corrosion
coating applications on metal, plastic, and wood. Acronal®, Luhydran®, and Joncryl® – particle morphologies
protection
§§ Professional – although the Acronal® PRO range
has primarily been developed for the anticorrosion
Luhydran® acrylic dispersions
professional industrial metal market, the products
may also be used in DIY applications These products have a long, reputable history of
success. They are surfactant-based, self-cross-linking,
New developments in the Acronal® PRO range offer or OH-functional dispersions, and particularly suitable
barrier- and corrosion-inhibiting properties with for interior wood applications and furniture foils and as
improved corrosion protection, early water resistance, co-binders in some exterior applications.
and good adhesion to ferrous, non-ferrous and
galvanized substrates. Homogeneous Core shell (inverse) Gradient Mixtures
Single-phase feed Sequential multifeed compositions Continuous change in feed Physical blend of two dispersions
composition (or potential secondary nucleation)
Water-based systems
14 Water-based systems
 2019
Water-based systems
 2019 15

Perfect match for interior


furniture and flooring applications

The interior wood furniture and flooring market is very diverse. It encompasses Selected recommendations Selected recommendations for medium-/
assembled contemporary furniture, cabinets, self-assembled flat-stock furniture for for economic flat-stock furniture high-quality furniture and flooring

home and office, as well as parquet and solid wood, ranging from factory-applied Colloidal Conventional RC

industrial to on-site professional or DIY applications. Self-cross-linking PUD Acrylic / PUD hybrid

Transfer, resolubility Chemical resistance /  Natural look Chemical resistance / 


scratch resistance scratch resistance
Joncryl® 1980 E
Joncryl® 661 Joncryl® 8226 Joncryl® 8331
Our goal of supporting you with our water-based No matter what the nature of your application, Joncryl® 663 Joncryl® 8322 Cost-effective Luhydran® A 875 S
dispersion technologies entails finding the best we create coating raw material solutions that meet Joncryl® 670 Joncryl® 1980 E Joncryl® 8322 Luhydran® A 849 S2
match of product properties – i.e. preserving the your needs regarding cost and performance while
beauty of wooden furniture and the environment conforming to the latest environmental regulations.
as well. Application methods and substrates vary enormously Joncryl® 8224 Joncryl® 8330
from country to country as a result of local preferences,
Our Joncryl® and Luhydran® self-cross-linking national regulations, and coating requirements.
dispersions allow the appearance of wood to We thus offer individual support for your needs with Cost-effective Low VOC Fast drying / blocking resistance Abrasion resistance

be modified – from a natural look to strong grain our water-based dispersions and system solutions Joncryl® 77-E Joncryl® 1915-E Joncryl® 8224 Joncryl® HYB 6336

enhancement. designed to match your targeted properties. Joncryl® 79 Joncryl® 8225 Joncryl® HYB 6430
Low VOC
Joncryl 8223
®
Joncryl® U 4190
Joncryl® 8225

A class of its own, Joncryl® 9500 series


Newly developed dispersions based on multiphase
technology, with ultrafine particle size.

Product Key properties

Excellent stain resistance in pigmented


Joncryl® 9500 systems, excellent adhesion, for DIY and
industrial use

Very good stain resistance in pigmented


Joncryl® 9502 systems, improved blocking resistance over
Joncryl® 9500

Universal self cross-linking acrylic, excellent


chemical and scratch resistance, high
Joncryl 9530
®
wet film transparency, excellent grain
enhancement
Water-based systems
16 Water-based systems
 2019
Water-based systems
 2019 17

Perfect match for


water-based metal coatings
1K acrylic dispersions for protective coatings
Portfolio snapshot

The biggest challenge within the industrial metal coatings industry today is providing
Primer / monocoat matt DTM / monocoat glossy

Product maturity
environmentally sustainable products that offer the perfect balance between coating
Joncryl®
properties and performance attributes. The range of acrylic emulsions that we offer PRO
1555
Joncryl® Joncryl® Acronal® Established
should be able to meet your needs. PRO
1532
PRO
1537
PRO
8977

Acronal® Acronal®
Joncryl® PRO Acronal® Acronal®
PRO 761 PRO PRO
PRO 763
(250–400 Growing
Customer support is well served with products applications while also providing the latitude to 1522 763 780 µm)
designed to attain high-performance in clear and optimize product performance attributes such as wet Acronal®
Joncryl® PRO
pigmented coatings. Our portfolio’s diversity of and dry adhesion, early water resistance, corrosion PRO 7600
(new)
1554
products allows the coatings manufacturer to design and chemical resistance, hardness, good intercoat (new) Acronal®
PRO
coatings for primer, direct to metal, and topcoat adhesion, and excellent exterior durability. 770
(new)
New

C2 C3 C4 C5

Higher corrosion protection


Multilayer Direct to metal (DTM)
Corrosion classification (according to DIN EN ISO 12944-1) based on dry film thickness of approx. 40 μm (DTM) and 80 μm (primer)

Topcoat Aesthetics (color, texture, gloss) +


25–80 µm weatherability + additional barrier

Enhance barrier to moisture and


Intermediate coat aggressive chemicals + build film thickness +
80 µm unit topcoat + primer Product (Primer) Attributes Product (DTM) Attributes

Acronal® PRO 770 (new) Superior performance Improved corrosion resistance and chemical
Active corrosion protection (barrier against
Primer oxygen, water + ions) + adhesion to metal Joncryl® PRO 1554 (new) resistance (new technology); improved wet
80 µm surface + provide surface for adhesion DTM coating High gloss, chemical + UV resistance adhesion
25–40 µm no anticorrosive pigments Workhorse, benchmark, robust, good
Acronal® PRO 761
application properties, good early water
Metal Metal Acronal® PRO 7600 (new) Good corrosion resistance and chemical
resistance, adhesion to galvanized steel Joncryl® PRO 1522
resistance
Universal, cost-effective; especially suited
Acronal® PRO 763
for thick layers (> 80 µm) Joncryl® PRO 1532 Fast drying, block resistance

Acronal® PRO 780 Improved corrosion resistance Joncryl® PRO 1537 Improved hardness vs. Joncryl® PRO 1532

Acronal® PRO 8977 Improved block resistance, harder High anti-blocking, good adhesion,
Joncryl® PRO 1555
fast drying
Water-based systems
18 Water-based systems
 2019
Water-based systems
 2019 19

Polyurethane dispersions (PUDs) Your best choice


and hybrid dispersions for 2K PU systems

Joncryl® and Basonol® PU polyurethane PUD (special properties) Joncryl® OH and Basonol® AC Basonat® polyisocyanates for
dispersion and Joncryl® HYB acrylic /  Drying process: phase separation OH-functional acrylic dispersions water-based systems
PUD hybrid dispersions

Joncryl® / Basonol® PUD and acrylic / PUD hybrid Besides the OH-functional primary dispersions Joncryl® Years ago it was unthinkable to use polyisocyanate
dispersions are manufactured using an NMP- and OH and Luhydran®, BASF has developed Basonol® AC, cross-linkers in water-based coatings.
NEP-free process, resulting in solvent-free products. a completely new class of core-shell, OH-functional Hydrophilic modifications of aliphatic polyisocyanates
Due to the chemical structure of phase-separated hard Hard phase dispersions with very low emulsifier content that are opened the field of 2K PU coatings to water-based
and soft domains, this product class exhibits a wide Rich in H-bonds especially suited for high-gloss 2K PU topcoats. applications.
variety of unique properties that can be tailored for and electrostatic They can compete with traditional secondary acrylic The Basonat® HW range allows the manufacturing of
different coating applications on wood, metal, and interactions: dispersions at a lower isocyanate demand. water-based 2K PU coatings with a sufficiently long pot
plastic. physical cross-linker life and a broad formulation latitude, with properties
close to those of solvent-based 2K coatings.
N-C-O-R-O
Soft phase The hydrophilic modified polyisocyanates from the
HO
(Mainly macrodiols) Basonat® HW range are emulsifiable in water, as
OH HO
C-N-R-N-C control of elastic supplied, or can be diluted with suitable solvents. For
properties example, they can be used together with OH-functional
acrylic dispersions and PUDs.
The low viscosity polyisocyanates from the Basonat® HA
range can be incorporated homogeneously into
secondary dispersions, like PUDs.

Advantages of PUDs
Synergistic
combination of the
Better-defined
water phase
“best of two worlds”
Mechanical properties
Film formation
Appearance
Hybrid technology

Fast drying and


recoating times
Low odor
Good hardness
development and
chemical resistance

Advantages of acrylics
Water-based systems
20 Water-based systems
 2019
Water-based systems
 2019 21

Joncryl® colloidals and Acronal®


non-cross-linking acrylic dispersions
1 Suited 2 Highly recommended

Solids by Viscosity Acid number on Coating layer Substrate


Product Appearance pH MFT [°C] Tg [°C] Key properties and applications
weight [%] [mPa·s] solids [mg KOH/g] Primer Topcoat Wood Metal Plastic Glass Concrete

Colloidals
Excellent penetration, minimal grain raising, excellent clarity and sandability,
Joncryl® 95-E Translucent dispersion 30.0 100 8.0 70 20 43 fast drying. Alkali-soluble dispersion for quick-drying interior stains, wood 2 - 2 - - - -
sealers

High viscosity at low solids content, high transfer with roller coaters, good
flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as
Joncryl® 661 Semi-translucent dispersion 44.0 60 2.1 154 - 70 2 - 2 - - - -
a thickener in various acrylic water-based paints, especially for roller coating
applications

High viscosity at low solids content, high transfer with roller coaters, good
flow, leveling, and good pigment wetting. Alkali-soluble dispersion for use as
Joncryl 663
®
Semi-translucent dispersion 40.0 450 6.2 131 - 30 2 - 2 - - - -
a thickener in various acrylic water-based paints, especially for roller coating
applications

High transfer with roller coaters, good flow, leveling, and good pigment
wetting. Alkali-soluble dispersion for use as thickener in various acrylic
Joncryl 670
®
NEW Semi-translucent dispersion 46.0 85 4.5 - 12 - 2 - 2 - - - -
water-based paints, especially for roller coating applications. Increased
solids content compared to Joncryl® 663

Non-cross-linking acrylic dispersions


Anticorrosion primer, topcoat: zero add-on of APEO, ecological, good,
corrosion category medium duty C2–C3, good adhesion and compatibility
Acronal PRO 761
®
White dispersion 50.0 325 9.3 < 20 22 ~ 20 2 1 - 2 1 - -
with anticorrosive pigments, good sandability. Anticorrosion primer, topcoat,
direct to metal

Silane-modified styrene acrylic dispersion. Universal, cost-effective product.


Good corrosion protection, good adhesion and compatibility with anticorrosive
Acronal® PRO 763 White dispersion 50.0 100–250 7–8 15 28 - pigments, corrosion category light to medium duty, C2–C3 for DFT 80 µm; 2 - - 2 - - -
heavy corrosion protection (C5M) with high film built possible (240–400 µm)
anticorrosion primer, topcoat, direct to metal

Superior performance, zero add-on of APEO and zinc, excellent anticorrosion


protection for both glossy and matt paints (zinc phosphates not necessary for
Acronal PRO 770
®
NEW White dispersion 50.0 100–400 7–8 7 19 - 2 2 - 2 - - -
good protection), excellent barrier to humidity, good adhesion, good early rain
resistance, corrosion category medium duty, C3–C4

Zero add-on of APEO and zinc, excellent anticorrosion protection at > 80 µm


Core dry film thickness, excellent barrier to humidity, good adhesion, good early rain
Acronal PRO 780
®
White dispersion 50.0 190 8.5 < 20 22 2 1 - 2 - - -
shell resistance, high pigmentability with anticorrosive pigments, corrosion category
medium duty, C3–C4. Anticorrosion primer, topcoat, direct to metal

Anticorrosion primer, topcoat: APEO-free direct plug-in of Acronal® PRO 760,


ecological, good, corrosion category medium duty C2–C3, good adhesion
Acronal PRO 7600X
®
NEW White emulsion 50.0 240 9.5 < 20 22 ~ 20 2 1 - 2 - - -
and compatibility with anticorrosive pigments good sandability. Anticorrosion
primer, topcoat, direct to metal

Anticorrosion primer, topcoat: zero add-on of APEO, good anticorrosion


protection, excellent block resistance, high pigmentability (PVC 35 %) with
Acronal® PRO 8977 White dispersion 50.0 200 9.5 - 37 ~ 36 2 1 - 2 1 - -
anticorrosive pigments, corrosion category medium duty, C2–C3. Anticorrosion
primer, topcoat, direct to metal
Water-based systems
22 Water-based systems
 2019
Water-based systems
 2019 23

Joncryl® non-cross-linking
acrylic dispersions
1 Suited 2 Highly recommended

Solids by Viscosity Acid number on Coating layer Substrate


Product Appearance pH MFT [°C] Tg [°C] Key properties and applications
weight [%] [mPa·s] solids [mg KOH/g] Primer Topcoat Wood Metal Plastic Glass Concrete

Non-cross-linking acrylic dispersions


Good balance of flexibility / hardness, excellent pigment wetting.
Joncryl® 77-E Semi-translucent dispersion 46.0 550 8.1 62 12 35 Medium-hard dispersion recommended as blending partner to improve 2 - 2 - - - -
flexibility and adhesion in combination with colloidal dispersions

High pigment-binding power, excellent cost performance, high-solid content.


Joncryl® 79 White dispersion 50.0 700–1,500 7.5–9.0 23 20 22 Excellent cost-performing dispersions for pigmented primers, furniture 2 - 2 - - - -
backings

Very good block resistance, excellent adhesion, low VOC, pigment-dispersing


Joncryl® 1915 Semi-translucent dispersion 44.0 700 8.5 68 <5 43 2 - 2 - - - -
capability. Dispersion for hardboard and other flat-stock coatings

Excellent adhesion to plastic substrates; fast hardness development, very


Joncryl® 8211 Translucent dispersion 44.0 150 7.6 26 57 60 2 1 1 1 2 - -
good weathering resistance

Good water resistance, good intercoat adhesion with 100% UV systems, good
Joncryl® 8223 Semi-translucent dispersion 30.0 250 8.2 100 <5 21 2 - 2 - - - -
pigment wetting, dispersion for economic industrial wood and board primers

Very fast drying, excellent block resistance and stackability, dispersion recom-
Joncryl® 8224 Translucent dispersion 45.0 70 7.7 53 10 - 2 2 2 - - - -
mended for primers and topcoats

Excellent clarity, very fast drying, good block resistance, good stackability.
Joncryl® 8225 Translucent dispersion 45.0 75 7.8 57 <5 - Low-VOC dispersion for use in fast industrially applied clear lacquers for 2 2 2 - 2 - -
furniture and flat-stock coatings

Excellent scratch resistance and block resistance, fast drying, good chemical
Joncryl® 8226 Semi-translucent dispersion 42.0 75 7.9 36 20 - resistance and clarity. Dispersion for industrial interior wood coatings on fast 1 2 2 - - - -
lines

Good isolating properties on tropical hardwoods and engineered wood types.


Joncryl® 8227 Semi-translucent dispersion 40.0 160 9.0 12 <0 7 Flexible dispersion for anti-bleeding industrial primer for tropical hardwoods 2 - 2 - - - -
and engineered wood

Low VOC, good appearance and grain enhancement, blending partner to


Joncryl® 8228 Semi-translucent dispersion 48.0 600 7.9 68 <5 <0 reduce solvent demand, dispersion for exterior and interior stains, high gloss 2 1 2 - - - -
brushing enamels, as well as industrial applied timber coatings

Excellent stain resistance in white pigmented formulations. Provides good


Joncryl® 9500 NEW White opaque dispersion 40.0 < 100 8.5 - 42 - adhesion to various substrates. Suitable both in industrial applications and for 2 2 2 1 1 - -
the DIY market

Corrosion protection without the use of active pigments at 30–40 µm dry film
Joncryl® PRO 1522 Translucent dispersion 45.0 400 9.0 - 26 34 thickness, high gloss, exterior durability and compatibility with anticorrosive - 2 - 2 - - -
pigments, corrosion category medium duty, C2–C3 topcoat, direct to metal

Good early water and UV resistance, excellent adhesion to various substrates,


Joncryl® PRO 1532 Semi-translucent dispersion 51.0 250 7.8 27 < 20 14 humidity and corrosion resistance properties, corrosion category light duty, 1 1 - 2 - - -
C1–C2 anticorrosion primer, topcoat

High Tg, good hardness development, good water and chemical resistance,
Joncryl® PRO 1537 Translucent dispersion 46.0 250 8.4 49 45 46 1 1 1 2 - - -
good adhesion; application: industrial and wood coating primer on primer

Improved corrosion resistance (at 30–40 µm dry film thickness) and chemical
Joncryl® PRO 1554 NEW Semi-translucent dispersion 41.5–44.0 250–1,750 7.5–8.9 30 25 - resistance (new technology); improved wet adhesion, high gloss, exterior - 2 - 2 - - -
durability, corrosion category medium duty, C2–C3

Very fast drying, excellent adhesion (also to non-ferrous), early water


Core
Joncryl® PRO 1555 Translucent dispersion 45.0 60 7.6 53 12 resistance, excellent block resistance, corrosion category light duty, C1–C2 1 1 1 2 - - -
shell
anticorrosion primer, topcoat
Water-based systems
24 Water-based systems
 2019
Water-based systems
 2019 25

Joncryl® and Luhydran®


self-cross-linking acrylic dispersions
1 Suited 2 Highly recommended

Solids by Viscosity Acid number on Coating layer Substrate


Product Appearance pH MFT [°C] Tg [°C] Key properties and applications
weight [%] [mPa·s] solids [mg KOH/g] Primer Topcoat Wood Metal Plastic Glass Concrete

Self-cross-linking acrylic dispersions


Core Good chemical resistance, good scratch and mar resistance, low VOC,
Joncryl® 1980-E Semi-translucent dispersion 39.0 150 8.6 18 56 1 2 2 1 - 1 -
shell natural look. Dispersion for interior wood applications

Universal use as 1K and 2K PU dispersion for clear and pigmented systems.


Core High chemical and scratch resistance. Good grain enhancement and dry
Joncryl 8310
®
White dispersion 42.0 100 7.0 - 44 2 2 2 1 2 1 -
shell film clarity. Primers and topcoats for medium- to high-quality 1K and 2K PU
furniture and flooring applications

Excellent adhesion to plastic substrates; high hardness, good blocking


Core
Joncryl® 8320 Semi-translucent dispersion 41 85 9.2 25 46 resistance and chemical resistance, excellent humidity resistance (without 2 2 1 1 2 1 -
shell
blushing)

High gloss, high hardness, fast drying and UV resistance, good chemical
Core
Joncryl® 8322 Semi-translucent dispersion 41.0 500 8.6 18 30 resistance and sandability; economical, good clarity; application: topcoat for 1 2 2 2 - 1 -
shell
wood and industrial coatings (corrosion category light duty, C1–C2)

Clear and pigmented coating; high clarity and chemical resistance, excellent
Core block and hardness development; blending partner for UV dispersions;
Joncryl 8330
®
Semi-translucent dispersion 38.0 50 8.1 25 33 1 2 2 1 - 1 -
shell application: topcoat for wood and industrial coatings (corrosion category light
duty, C1–C2)

Excellent chemical and scratch resistance, very good hot-block resistance,


Core
Joncryl® 8331 Semi-translucent dispersion 38.5 80 8.1 17 59 quick hardness development, excellent sandability. Dispersion developed for 1 2 2 1 - 1 -
shell
use in industrial wood coatings

Core Good scratch resistance, dispersion for interior with superior plasticizer and
Joncryl® 8333 White dispersion 45.0 250 7.2 24 58 1 2 2 1 - 1 -
shell hand cream resistance

Fast drying, good block resistance, good blending partner to reduce the
Core
Joncryl® 8336 Semi-translucent dispersion 40.0 75 8.0 25 <5 solvent demand, balanced chemical resistance. Dispersion for industrial 1 2 2 1 - 1 -
shell
applied clear and pigmented finishes for primer and topcoat

Excellent stain resistance, very good solvent resistance and excellent blocking
Core resistance, enabling IKEA R2 and DIN 68861-1B in pigmented formulations.
Joncryl® 9502 NEW White opaque dispersion 42 75 8 45 40 2 2 2 1 1 - -
shell Provides good grain enhancement (“Anfeuerung”) on different wood types as
clear coat

Universal self-cross-linking acrylic dispersion for interior wood coating.


Core
Joncryl® 9530 NEW Translucent dispersion 40.5 < 100 7.0 - 45 Provides high wet film clarity, excellent grain enhancement, chemical and 2 2 2 1 1 - -
shell
scratch resistance

High chemical resistance, excellent grain enhancement and scratch


Luhydran® A 849 S2 White dispersion 44.0 200 7.0 20 39 37 1 2 2 1 2 1 -
resistance. Second-generation dispersion for interior wood coatings

Good block resistance, clarity, film forming, sandability, excellent chemical,


Core
Luhydran® A 875 S White dispersion 44.0 60 7.0 21 60 plasticizer, and scratch resistance. All-round emulsion for industrial interior - 2 2 1 - 1 -
shell
wood coatings
Water-based systems
26 Water-based systems
 2019
Water-based systems
 2019 27

Basonol®, Joncryl®, and Luhydran®


OH-functional acrylic dispersions for
stoving and 2K PU applications 1 Suited 2 Highly recommended

Acid number OH number Coating layer Substrate


Solids by Viscosity
Product Appearance pH on solids MFT [°C] on solids Key properties and applications
weight [%] [mPa·s] Primer Topcoat Wood Metal Plastic Glass Concrete
[mg KOH/g] [mg KOH/g]

OH-functional dispersions
Dispersion for 2K PU high-performance, high-gloss topcoats; excellent
Basonol® AC 1120W NEW White dispersion 42.5 100 7 15 <5 120 compatibility with polyisocyanates, excellent gloss and leveling in combination 1 2 1 2 1 - -
with very good chemical resistance, good flexibility and scratch resistance

Universal use as 1K and 2K PU dispersion for clear and pigmented systems.


High chemical and scratch resistance. Good grain enhancement and dry
Joncryl® 8310 White dispersion 42.0 100 7.0 - 44 29 2 2 2 1 2 1 -
film clarity. Primers and topcoats for medium- to high-quality 1K and 2K PU
furniture and flooring applications

Rheology controlled acrylic dispersion for thermoset water-based industrial


metal and glass coatings. Thermosetting acrylic dispersion to be used for
general metal or stoving enamels. Good alternative to water-reducible and
Joncryl® OH 8300 Semi-translucent dispersion 43.5 280 9.6 60 < 15 42 1 2 - 2 - 2 -
solvent-based alkyd-melamine systems. Main applications are direct to metal
(DTM), metal topcoats, and glass coatings; very short pot life in combination
with free isocyanates

OH-functional dispersion (2K PU), excellent adhesion, resistance to water,


Joncryl® OH 8311 Translucent dispersion 42.0 40 7.6 - 50 120 1 2 2 1 1 1 -
chemicals, and solvents; application: topcoat for industrial and wood coating

OH-functional dispersion, long pot life up to 6 hours, excellent chemical


Joncryl® OH 8312 White dispersion 44.0 300 8.2 - 48 100 resistance, good scratch resistance, good hardness development, block 1 2 2 2 2 1 -
resistance, and adhesion; application: topcoat for industrial and wood coating

OH-functional dispersion, good chemical resistance, economical dispersion


Luhydran® S 938 T White dispersion 45.0 25 2.0 - 60 100 for furniture foils, heat-curable melamine coatings, and 2K PU wood and 1 2 2 1 1 1 -
industrial coatings (topcoat or direct to metal)

OH-functional dispersion, good pigment wetting, chemical resistance, and


Luhydran® S 939 T NEW Semi-translucent dispersion 45 < 100 3.0 - > 60 80 gloss. Suitable for furniture foils, heat curable melamine coatings, and 2K 1 2 1 1 - 1 -
wood and industrial coatings
Water-based systems
28 Water-based systems
 2019
Water-based systems
 2019 29

Joncryl® and Basonol® polyurethane


dispersions and PUD / acrylic hybrids
1 Suited 2 Highly recommended

Acid number Coating layer Substrate


Solids by Viscosity OH number on MFT
Product Appearance pH on solids Key properties and applications
weight [%] [mPa·s] solids [mg KOH/g] [°C] Primer Topcoat Wood Metal Plastic Glass Concrete
[mg KOH/g]

Polyurethane acrylic hybrid dispersions


Polyurethane acrylic hybrid dispersion, excellent clarity as well as scratch and
Joncryl® HYB 6336 Translucent dispersion 38.0 50 8.0 - 26 40 abrasion resistance, fast hardness development, good chemical resistance, 1 2 2 - 2 1 1
good grain enhancement

Solvent-free, polyurethane acrylic hybrid with excellent Taber® abrasion


resistance, fast hardness development, good chemical resistance. Hybrid for
Joncryl® HYB 6340 White dispersion 40.0 50 7.6 - 12 45 1 2 2 - - 1 1
high-quality water-based clear coats on wood for parquet flooring applications
and high-performance furniture topcoats

Polyurethane dispersions
Basonol® PU 1035 W is used in 1K stoving and 2K primer applications for
plastic and metal substrates; excellent adhesion to various substrates (plastic,
Basonol® PU 1035 W NEW Translucent dispersion ~ 43 ~ 35 6–8 35 - <0 e-coat, metal); excellent flexibility; formulation robustness; universal blending 2 - - 2 2 - -
partner for acrylic dispersions; zero add-on of NMP, NEP, and other organic
solvents

Solvent-free, aliphatic water-based polyurethane dispersion, very good abra-


sion resistance, good balance of film hardness, flexibility and toughness, good
Joncryl U 4190
®
Translucent dispersion 36.5 80 8.5 - - 23 - 2 2 1 2 2 1
chemical and water resistance, excellent adhesion to wood, metal, e-coat, and
various plastic substrates

Soft PUD with good adhesion on metal substrates, very elastic at good
Joncryl® U 4310 Semi-translucent dispersion 40.0 < 100 8.0 - - <2 toughness, high chemical resistance, heat resistant, high gloss, good barrier 1 - 1 1 - 2 -
to water and water steam; suitable for glass fiber sizing

Soft polyurethane dispersion, elastic behavior over a wide temperature range,


high gloss and good adhesion on wood, plastic (ABS/PC) and metal sub-
Joncryl U 4320
®
White dispersion 40.0 15–95 8.0 - - <0 1 1 1 2 - 2 1
strates, upon addition of polyisocyanates excellent resistance to boiling water;
suitable for blend with harder dispersions; suitable for fiber sizing

PUD especially developed for basecoats with improved drying speed; good
Joncryl® U 5168X NEW White dispersion 36.0 ~ 78 7.8 - - <5 2 2 - 2 2 2 -
pigment-wetting properties
Water-based systems
30 Water-based systems
 2019
Water-based systems
 2019 31

Luwipal® and Plastopal®


amino resins
1 Suited 2 Highly recommended

Free Substrate
Non-volatile at Viscosity at Temperature Acid
Product Type of product Solvent formalde- Key properties
2 h, 125 °C [%] 23 °C [mPa·s] reactivity reactivity Wood Metal Plastic Glass Concrete
hyde [%]

Melamine-formaldehyde resin / methanol-butanol-mixed-etherified
Mixed-etherified melamine resin, Methanol-butanol-mixed-etherified resin for water-based and solvent-based coatings;
Luwipal® 052 69 – 72 4,000–6,500 Butanol Medium - < 1.0 1 2 - 1 -
high methylolation degree high baking reactivity; for automotive application

Melamine-formaldehyde resins / methanol-etherified
For water-based coatings. Very high baking reactivity, for furniture foil and industrial
Luwipal® 063 Melamine resin, high imino content 68 – 72 500–800 Water High Low < 0.6 1 2 - 1 -
applications

Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for
Luwipal® 066 93 – 96 2,000–6,000 - Low High < 0.6 1 2 - 2 -
fully methyl-etherified furniture foil and coil-coating applications

Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for
Luwipal® 066 LF 93 – 96 2,000–6,000 - Low High < 0.3 1 2 - 2 -
fully methyl-etherified furniture foil and coil-coating applications: low formaldehyde content

Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for
Luwipal® 066 ULF 93 – 96 2,000–6,000 - Low High < 0.1 1 2 - 2 -
fully methyl-etherified furniture foil and coil-coating applications; no CMR labeling

Melamine resin, high etherification


Luwipal® 068 81 – 85 1,600–2,400 Water Medium Medium < 3.5 For water-based acid-curable coatings. High reactivity, for decorative foil applications 1 2 - 1 -
degree

Melamine resin, high etherification Methanol /  For solvent-based and water-based coatings. Medium to high reactivity, for furniture foil
Luwipal® 069 79 – 83 2,500–3,500 Medium Medium < 1.5 1 2 - 1 -
degree ethanol and industrial applications

Melamine resin, balanced For solvent-based and water-based coatings. High baking reactivity, for furniture foil,
Luwipal® 072 73 – 77 4,000–7,000 Isobutanol High - < 1.0 1 2 - 2 -
imino-methylolation degree coil, automotive and industrial applications

Melamine resin, balanced For water-based coatings. High baking reactivity, for furniture foil, coil, automotive and
Luwipal® 073 78 – 82 3,000–5,000 Water High Low < 0.5 1 2 - 2 -
imino-methylolation degree industrial applications

Melamine resin, balanced For water-based coatings. High baking reactivity, for furniture foil, coil, automotive and
Luwipal® 073 LF 78 – 82 3,000–5,000 Water High Low < 0.3 1 2 - 2 -
imino-methylolation degree industrial applications; low formaldehyde content

Carbamate resins
Carbamate resin /  Carbamate resin for water-based coatings; medium to high acid reactivity. For foil and
Plastopal® BTM N / A 2,500–3,700 Water Low Medium < 2.1 1 2 - 1 -
medium-etherified furniture coatings

Carbamate resin /  Carbamate resin for water-based coatings; medium to high acid reactivity. For foil and
Plastopal® BTW 75 – 79 1,000–1,500 Water Low Medium < 0.8 1 2 - 1 -
medium-etherified furniture coatings with lower formaldehyde content than Plastopal® BTM
Water-based systems
32 Water-based systems
 2019
Water-based systems
 2019 33

Basonat® polyisocyanates

Viscosity at 23 °C
Product Type of product Solids by weight [%] Solvent NCO [%] Key properties and applications
[mPa·s]

Low-viscous (NEW: available at < 0.1% residual diisocyanate)


Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 1000 HDI allophanate 100 900–1,500 - 21.0–23.0
water-based 2K PU wood coatings

Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 2000 HDI allophanate 100 500–900 - 18.5–21.5
water-based 2K PU wood coatings

Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 3000 HDI allophanate 100 200–400 - 19.0–20.0
water-based 2K PU wood coatings

Low-viscous trimer for high-solid 2K PU coatings without limitation in chemical resistance and reactivity. It can also be combined with water-emulsifiable Basonat® HW types and
Basonat® HI 2000 NG HDI isocyanurate low-viscous 100 900–1,500 - 22.5–23.5
secondary dispersions for water-based 2K PU wood coatings; NG: reduced color drift in formulations

Hydrophilic (NEW: available at < 0.1% residual diisocyanate)


Hydrophilically modified HDI Hydrophilic, fast-drying polyisocyanate for general use in water-based 2K PU coatings comprising primary or secondary dispersions. Enables low VOC systems providing excel-
Basonat® HW 1000 100 2,000–6,000 - 16.5–17.5
isocyanurate lent chemical resistance

Hydrophilically modified HDI


Basonat® HW 1180 PC 80 450–850 Propylene carbonate 13.2–14.0 Diluted version of Basonat® HW 1000 for faster incorporation in water-based 2K PU systems based on primary or secondary dispersions
isocyanurate

Hydrophilically modified HDI Easy-mixing version of Basonat® HW 1000 providing a combination of fast drying and easy mixing for water-based 2K PU systems in combination with primary and secondary
Basonat® HW 2000 100 1,500–3,000 - 17.5–18.5
isocyanurate dispersions

Hydrophilically modified HDI All-purpose, hydrophilic polyisocyanate for general use with primary and secondary dispersions in water-based 2K PU coatings for low VOC systems with balanced properties
Basonat® HW 2100 100 2,000–3,600 - 16.9–17.9
isocyanurate regarding miscibility, resistance, and reactivity

Hydrophilically modified HDI / IPDI 3-Methoxy 1-butyl


Basonat® HW 3280 MBA 80 800–1,400 11.5–12.5 Easy-mixing polyisocyanate for general use with improved physical-drying and hardness development in water-based systems
isocyanurate acetate

Hydrophilically modified HDI Easy emulsification in combination with high chemical resistance. New patented stabilization technology. Low solvent demand for hand mixing together with fast hardness
Basonat® HW 4000 100 3,000–3,500 - 18.5–19.5
isocyanurate development. Compatible with primary and secondary dispersions for use in DIY 2K PU floor coatings or high-quality furniture coatings
Water-based systems
34 Water-based systems
 2019
Water-based systems
 2019 35

Waterpoxy® epoxy resins


and amine adducts
1 Suited 2 Highly recommended

Hydrogen Substrate
Type of Solids by Viscosity High Specific gravity Epoxy
Product Appearance Key properties equivalent weight
product weight [%] [mPa·s] thickness [g/cm3] equivalent weight Wood Metal Plastic Glass Concrete
(HEW)

Epoxy resins
Particularly useful in the formulation of industrial maintenance and concrete
Emulsion of solid
protection coatings; offers combined with Waterpoxy® 751 as curing agent
Waterpoxy® 1422 epoxy resin in Milky emulsion 55 4,000 No 0.96 1,150 - 2 - 1 2
fast tack-free and curing times as well as good chemical resistance; improved
water
gloss and hardness compared to Waterpoxy® 1455

Particularly useful for formulating water-based coating systems, primers, and


Emulsion of solid protective coatings for concrete; produces as curing agent in combination
Waterpoxy® 1455 epoxy resin in Milky emulsion 56 3,500 No 1.1 1,035 with Waterpoxy® 751 excellent drying/curing characteristics combined with - 2 - 1 2
water very good protective performance; both resin and curing agent offer excellent
wetting properties enabling optimum pigment dispersion

Hydrogen Substrates
Type of Solids by Viscosity High Specific gravity Free amine Yellowing
Product Appearance Key properties equivalent weight
product weight [%] [mPa·s] thickness [g/cm3] content [%] resistance Wood Metal Plastic Glass Concrete
(HEW)

Amine adducts
Excellent wetting, flow, and resistivity properties, for concrete and metal
Water-based protection formulations (i.e. primers, protective coatings, self-leveling
Waterpoxy 751
®
Solution 59 11,750 Yes 1.09 ~ 0.2 High 225 - 2 1 1 2
amine adduct floorings); combined with Waterpoxy® 1455 / 1422, it offers very fast drying
speed and very long pot life

Curing agent solution; very low shrinkage properties makes it useful for
water-based epoxy self-leveling flooring with high thickness application; used
Water-based
Waterpoxy® 760 Solution 60 6,500 Yes 1.09 ~ 0.2 High in combination with standard liquid epoxy resin, it shows a definable end 210 - - - 1 2
amine adduct
of pot life and good chemical resistance; low temperatures do not limit the
application and curing behavior

Water-reducible epoxy curing agent for combination with emulsified epoxy


resins for heavy-duty industrial and maintenance coatings giving excellent
Water-based corrosion and chemical resistance; combinations with Waterpoxy® 1422
Waterpoxy® 801 Solution 60 700 No 1.08 <1 High 91 - 2 - 1 1
amine adduct produce formulations with a low solvent content offering long pot life but with
rapid-cure film properties that can be quickly sanded and recoated; other
suitable applications are automotive and marine coatings
Water-based systems
36 Water-based systems
 2019
Water-based systems
 2019 37

Joncryl® and Laropal® grinding resins,


waxes, and cross-linker solutions

Acid number on Molecular weight


Product Appearance Solids by weight [%] Viscosity [mPa·s] pH Tg [°C] Key properties and applications
solids [mg KOH/g] [g/mol]

Grinding resins
Joncryl® 8078 Clear liquid 32.0 1,750 8.3 224 8,500 101 Excellent pigment wetting, resolubility, compatibility, and rheology stability for pigment pastes

Joncryl® HPD 71-E Clear liquid 31.0 200 8.5 221 17,000 120 Excellent viscosity stability, pigment wetting, and color development

Excellent viscosity stability, pigment wetting, and color development.


Joncryl® HPD 96-E Clear liquid 31.0 2,000 8.5 233 16,500 105
Very-low VOC ammonia-neutralized resin solution for highly concentrated pigment dispersions

Excellent viscosity stability, pigment wetting, and color development.


Joncryl® HPD 296-E Clear liquid 35.5 500 8.1 141 11,500 15
Very-low VOC ammonia-neutralized resin solution for highly concentrated pigment dispersions

Joncryl® HPD 496-E NEW Clear liquid 34.5 500 8.5 178 5,500 58 Enables high-concentrated dispersions, excellent color development, low maintenance, pH-neutral

Excellent pigment wetting, broad compatibility.


Laropal® LR 9008 Yellowish liquid 35.0 2,000–15,000 7.5–8.5 - - -
Solution of a modified aldehyde resin for universal pigment dispersions

Melting point of wax


Product Type of product Appearance Solids by weight [%] Viscosity [mPa·s] pH Key properties and applications
[°C]

Waxes and cross-linker solutions


OH-functional dispersion, good pigment wetting, chemical resistance, and gloss. Suitable for furniture foils, heat curable melamine
Joncryl® Strip 2000 NEW Wax dispersion Semi-translucent dispersion 45 < 100 3.0 -
coatings, and 2K wood and industrial coatings

Joncryl® Wax 35 Additive Semi-translucent dispersion 34.5 25 9.8 130 Polyethylene wax to improve scratch resistance, slip, and block resistance

Water resistance, drying, hardness.


Zinc Oxide Solution #1 Additive Clear solution 25.0 5 11.4 -
Cross-linker for carboxy-functional acrylics to improve early resistance properties
Bitte Kurzversion desSolvent-based
Kapiteltitels eintragen
systems
 2019 39

Solvent-based systems
Solvent-based systems

Solvent-based systems represent the majority of applications in the coatings industry.


We offer a wide range of amino resins for high-solid performance and baking
reactivity, OH-functional acrylic copolymers, hyperbranched polyesters, hardeners,
and grinding resins for all solvent-based binder classes. Our high-quality products are
usable for 1K and 2K systems and fulfill the current VOC regulations.

Performance, however, is preeminent: Good adhesion, resistance to weathering,


yellowing, and chemicals; flexibility and economic cost in use, and especially
hardness and luster are among the hallmarks of these product ranges.

Our products cover a broad application window (especially temperature, humidity,


film thickness) and include applications for physical drying, low-bake systems, and
high-bake processes. They are usable for a majority of substrates and for matt
and high-gloss finishes.
40 Solvent-based systems
 2019
Solvent-based systems
 2019 41

Melamine curing 1K stoving technology is still a widely and surface hardness at a high flexibility with the poly­

Your best choice for cross-linkers and


used curing chemistry in a variety of coatings applications. ester’s typical reflow effect. Coatings cured with Basonol®
Automotive clear coats, pigmented industrial top coats, HPE show very robust performances at un­der­­cure
can and coil coatings, in each field of use the price/ tem­per­atures and increases final chemical resis­tances,

binders for 1K and 2K PU coatings

Solvent-based systems
per­for­mance behavior is still unbeatable compared to especially pancreatin, tree resin, and petrol resis­tances.
other curing technologies. Basonol® HPE can significantly The properties of the final film can be sig­nificantly superior
boost chemical and mechanical performances to a level to the pure acrylate system. BASF’s unique cross-linking
close to 2K Polyurethane coatings. Basonol® HPE as co-​ technology and the right choice of monomers to build up
binder in acrylate / melamine curing systems can improve the highly branched polyester pro­vides high weathering
the network density to increase chemical resistance, stability and reduced sensitivity to hydrolysis.
Polyisocyanates for conventional
and high-solid 2K PU coatings BASONOL HPE 1170B
®
BASONOL HPE 1170 B BASONOL HPE 1170 B
Acrylate 10% Basonol® HPE 1170 20% Basonol® HPE 1170 Acrylate 10% Basonol® HPE 1170 20% Basonol® HPE 1170
reference reference

PENDULUM HARDNESS [OSC] KOENIG

PENDULUM HARDNESS [OSC] KOENIG


120 160
With Basonat® we offer high-quality polyisocyanate Our new generation of isocyanurate grades 140
100
hardeners for high-performance 2K PU coatings. (Basonat® HI NG) combines this well-known technical 120
It is simply the ideal hardener for most conventional performance with very low yellowing in automotive refinish 80
100
and high-solid applications. Thanks to continuous formulations. As of 2019 we offer all Basonat HI, HA, and
60 80
optimization and development, BASF provides HW hardeners at residual diisocyanate levels of < 0.1%.
60
well-established market standards and fulfills the With Basionics® KAT1 we offer the perfect catalyst, 40
40
market’s highest performance requirements. which is tin-free and ideal for low-temperature curing. 20
20
Automotive stoving time window
0 0
10' 20' 30' 40' 50' 60' 80 89 100 109 120 132 143 157 168 180
STOVING TIME AT 100 °C [MIN] STOVING TEMPERATURE [°C]

§§ Slight increase of surface hardness at longer oven §§ 20% of Basonol® HPE 1170 B has significant impact
Basonol HPE hyperbranched polyesters
® drying time on surface hardness
§§ More hardness / reactivity at low temperatures
100 – 120 °C
For environmental and workers’ protection in 2K PU a complementing solution is needed to address a
coatings, low- to medium-solids solvent-based possible drop in curing speed and hampered hardness
systems can be substituted by high-solids solvent- and resistance of the cured film. Using Basonol® HPE as Daimler Etch Test – tree resin resistance and pancreatin
based systems. Two options for achieving high-solid a co-binder improves curing speed at increased pot life Tree resin resistance 30 32 34 36 38 40 42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 °C
content are reducing the molecular weight of polyols in systems based on low molecular weight polyacrylates Acrylic reference
and reducing the glass transition temperature. and polyisocyanates. The recommended dose rate is
+ 10% HPE 1170B
To leverage the full potential of these systems, 5–30% (solids on resin solids).
+ 20% HPE 1170B
+ 10% HPE 1265B
+ 20% HPE 1265B

Fields of application – main focus on high-solid 2K PU Pancreatin resistance 30 32 34 36 38 40 42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 °C


Acrylic reference
Performance level §§ Early block resistance, early handling + 10% HPE 1170B
+ 20% HPE 1170B
§§ Excellent weather resistance
+ 10% HPE 1265B
§§ Faster curing speed + 20% HPE 1265B
§§ Improved chemical resistance
+HPE
§§ Improved reflow behavior
§§ Improved final hardness Joncryl® OH-functional acrylic resins
§§ Increased pot life

Conventional 2K PU High-solid 2K PU §§ Minimal impact on VOC Joncryl® polyol grades are hydroxyfunctional acrylic chemistries to improve performance at reduced VOC
copolymers for solvent-based coatings. They can be levels. Basonol® HPE is an especially effective co-binder
used as binders for cross-linking with polyisocyanates for producing outstanding coating performances in
such as Basonat® or in combination with other binder low-VOC systems.
42 Solvent-based systems
 2019
Solvent-based systems
 2019 43

Select the right amino resin


for every challenge

Solvent-based systems
Luwipal® grades – Plastopal® grades – Luwipal® and Plastopal® grades / 
Melamine-formaldehyde Urea-formaldehyde resins non-volatile content (NVC)* versus reactivity**
and benzoguanamine resins
1 Methanol-etherified melamine resin 1 Benzoguanamine and mixed-etherified melamine resins 1 Butanol-etherified melamine resins 1 Urea resins

Applications for this class of products include baking Applications for this class of products include baking
finishes, acid-curing finishes, and physically drying finishes, acid-curing finishes, and physically drying NVC (%) NVC (%)
finishes. Both solvent-based and water-based systems finishes. Depending on resin structure, both solvent- 100 100
A B
may be formulated, depending on the resin structure. based and water-based systems can be formulated.
Luwipal® grades are the preferred choice wherever In contrast to melamine-formaldehyde resins, 80 80
the paint finish must provide resistance to weathering, Plastopal® grades are the preferred choice in cases
yellowing, and chemicals, and especially hardness and where the paint finish requires good adhesion, 1
1
luster. resistance to overbaking, flexibility, and economic 60 60

Melamine-formaldehyde resins in the coatings industry cost of use. 2


2
are condensation products consisting of melamine, Urea-formaldehyde resins for the coatings industry 40 40
formaldehyde, and an etherification alcohol. They are are condensation products consisting of urea,
distinguished by viscosity, molecular weight, degree formaldehyde, and an etherification alcohol. They are
of etherification, reactivity, and type of cutting solvent. distinguished by viscosity, molecular weight, degree 20 20

of etherification, reactivity, and type of cutting solvent. 3


3
Benzoguanamine-formaldehyde resins contain the BASF’s product range includes brittle cross-linkers that 0 0
raw material benzoguanamine instead of melamine. need an external co-reactant and plasticized products Low Medium High Low Medium High
Because of this aromatic ring, weather resistance to work as sole binders. Baking reactivity without catalyst Baking reactivity with maleic acid
and lightfastness are limited. However, Luwipal® B Carbamate resins are composed of a urethane
is characterized by high flexibility and resistance to group containing raw material, formaldehyde, and
chemicals. an etherification alcohol. Plastopal® BT grades are NVC (%) A To achieve high-solid coatings, highly etherified
used wherever lasting flexibility is required. 100 amino resins are most beneficial. At the same solids
C
content a partially etherified amino resin offers higher
80
baking reactivity. Superior performance in terms of
drying conditions is achieved with highly reactive
cross-linkers.
60
1
B Weak acids (e.g. maleic acid) used as a catalyst
2
40
enhance the baking reactivity of methylol groups in
amino resins and .

20 C Strong acids (e.g. sulfonic acid) boost the reactivity


3
of all functional groups. The addition of catalysts has an
0
effect on storage stability and needs separate lab work.
Low Medium High

Baking reactivity with sulfonic acid

* 2 g / 2 h / 125 °C (diluted to 250 m·Pas, ICI)


** Reactivity according to long-term experience (pendulum hardness, xylene resistance, etc.)
44 Solvent-based systems
 2019
Solvent-based systems
 2019 45

The grinding resin

Solvent-based systems
Compatibility Viscosity profiles
of Laropal® A 81 of Laropal® A 81 in various solvents

9,000
Cellulose nitrate 1
8,000
Ethyl cellulose 0
Laropal A 81 ®
7,000
Cellulose acetobutyrate 1

Laropal® A 81 has an excellent reputation as a Laropal® A 81 does not yellow, and is highly resistant Chlorinated rubber 1 6,000

Viscosity [mPa·s]
high-quality aldehyde grinding resin. Its outstanding to the effects of humidity and temperature. This means VC copolymers 1 5,000
compatibility with all the main binders and organic that it can be used for all outdoor applications in
solvents used in industrial coatings makes it the 1K acrylic, 2K PU, or stoving systems. Laropal® A 81 Acrylic resins 1 4,000
preferred solution for universal mixing systems and aldehyde resin by BASF is a world-class binder for Urea-formaldehyde resins 1
3,000
pigment pastes alike. producing highly compatible solvent-based pigment
Melamine-formaldehyde
pastes. resins 1 2,000
When combined with our Efka® dispersing agents,
Alkyd resins 1 1,000
pigment pastes with the following properties can be BASF’s universal Laropal® grinding resin is the market
created: high pigment loading, excellent color strength, standard for all state-of-the-art mixing systems. As well Epoxy resins 1 0
and good flow behavior combined with a high degree as increasing the efficiency of your mixing processes, 70 65 60 55 50
Hydrocarbon resins 1
of stability. this highly flexible product reduces inventory and saves Laropal® A 81 [%]

time, space, and money. 1 Compatible 0 Limited compatibility


Methoxy propyl acetate (MPA) MPA / Solvesso® 100
Solvesso® 100 Butyl acetate

Laropal® A-8L
One fits all –
Laropal A-8L is a liquid grinding resin. Since it is an
®
On top of that, easier handling is guaranteed since the Laropal®, the universal grinding resin for mixing systems
aldehyde-based resin, it is as universal as Laropal® dilution step can be skipped, no dust is released
A 81. Laropal® A-8L has been designed in such a way, during processing, and it is easy to pump. Without Laropal® With Laropal®
that, compared to pigment pastes based on Laropal®
A 81, significant lower VOCs can be reached (depending Pigment
on pigment).
4 pigments 4 pigments

Typical properties of Laropal® A 81 Solubility of Laropal® A 81


Pigment paste

16 pigment pastes 4 pigment pastes


Delivery form Solid / pellets Alcohols 1
Softening temperature 80–95 °C Esters 1
One fits all
Iodine color number ≤3 Ketones 1 with Laropal®

Acid value ≤ 3 mg KOH/g Aromatic hydrocarbons 1


Universal compatibility
Density at 20 °C ~ 1.11 g/cm³ Aliphatic hydrocarbons 0 with all binder systems

Hydroxyl value ~ 40 mg KOH/g


1 Soluble
Saponification value ~ 65 mg KOH/g 0 Solutions tend to separate at temperatures below 15 °C.
Adding 2–5% of an aromatic solvent produces stable solutions
Glass transition
~ 57 °C
temperature Tg
NC 1 Alkyd 2K PU 2 EP 3 Binder system NC 1 Alkyd 2K PU 2 EP 3

1
Nitrocellulose 2
Two-component polyurethane 3
Epoxy
46 Solvent-based systems
 2019
Solvent-based systems
 2019 47

Joncryl® acrylic polyols, Basonol® HPE,


Basionics® catalyst

Solvent-based systems
1 Suited 2 Highly recommended

OH number Substrate
Solids by Viscosity OH number
Product Appearance Solvent Tg [°C] on solids Key properties and applications
weight [%] [mPa·s] on solids [%] Wood Metal Plastic Glass Concrete
[mg KOH/g]

Acrylic polyols for conventional coatings


Fast drying, high hardness, low OH value. High equivalent weight for low NCO demand, can be used to
Joncryl® 804 Clear solid resin > 98.5 Solid - 70 1.3 45 formulate economical 2K PU coatings, solid form provides cost benefit and formulator versatility, can also 2 2 1 1 -
be used as a modifier

100% solid polyol used in both 2K PU and acid-curable coatings offering good chemical resistance and
Joncryl® 581 Clear solid resin 100.0 Solid - 62 4.7 155 2 2 1 1 -
hardness. Solid polyol suitable for high-quality furniture and floor coatings in solvent-based systems

Good outdoor durability, high gloss, and gloss retention. Conventional-solids workhorse polyol, very fast
Joncryl® 587 Clear solid resin 100.0 Solid - 60 2.8 94 drying with long pot life, and excellent UV and chemical resistance, solid form provides cost benefit and 2 2 1 1 -
formulator versatility

Acrylic polyol with good hardness, stain resistance, and pigment dispersibility, broad resin compatibility and
Joncryl® 552 Clear liquid 62.0 5,500 n-Butyl acetate 49 2.7 90 1 2 1 1 -
useful as a low-VOC modifier for office furniture and general metal coatings

Acrylic polyols for medium-solid coatings


Excellent early hardness development and fast drying time, excellent gloss and color retention, good chemi-
Joncryl® 909 Clear liquid 68.0 6,500 n-Butyl acetate 25 3.5 117 1 2 1 1 -
cal resistance and outstanding durability. For versatile 2K PU for industrial applications

Acrylic polyols for high-solid coatings


4.2% OH on solid resin, low-VOC capability, excellent flow and leveling, broad compatibility and excellent
Joncryl® 507 Clear liquid 80.0 4,000 Butyl acetate 7 4.2 145 1 2 1 1 -
outdoor durability. Non-HAPs application

Fast cure version of Joncryl® 507, with outstanding reactivity / pot life behavior. Low VOC polyol offering
Joncryl® 922 Clear liquid 80.0 5,500 Butyl acetate 7 4.2 145 1 2 1 1 -
good drying time and pot life characteristics; useful as a sole binder or a modifier for higher Tg polyols

Very soft and reactive polyol with high OH number to obtain a very good chemical resistance against several
solvents, used to plasticize and / or to reduce VOC in 2K PU coatings; as a sole binder it forms a rubber-like
Joncryl® 963 Clear liquid 100 7,500 - -63 3.9 130 1 2 2 1 -
coating with extremely high flexibility and very good adhesion on difficult substrates; good outdoor durability
with proper light stabilization

Hyperbranched polyesters
Hyperbranched polyester that shows low impact on VOC for high-solid coatings; significantly faster drying,
Basonol® HPE 1170 B Clear liquid 69–71 4,000 n-Butyl acetate 20 8.2 270 early hardness development, and cross-linking. Improved chemical resistance and reflow behavior for 2K 1 2 2 2 -
PU high-solid refinish clear coats and 2K PU high-solid topcoats, but also usable for conventional systems

Hyperbranched polyester as low OH value alternative with similar property profile as Basonol® HPE 1170
Basonol® HPE 1265 B Clear liquid 64–66 2,400 n-Butyl acetate 38 5.5 180 B, at slightly higher VOC. It shows fast curing speed with fast hardness development for early handling and 1 2 2 2 -
early polishing

Catalyst for 2K PU
Basionics® KAT 1 is a metal-free curing catalyst for polyurethane reactions. It is a low-viscous liquid with
ionic character displaying high catalytic activity at low temperatures and forced drying conditions. The
White to slightly yellow,
Basionics® Kat 1 > 97 500–2,000 - - - - catalyst is active in coatings formulations and adhesives. In conventional solvent-based and high-solid 1 2 2 1 1
clear to slightly turbid
formulations, the addition of Basionics® KAT 1 enhances the curing speed at lower temperature at a longer
pot life
48 Solvent-based systems
 2019
Solvent-based systems
 2019 49

Luwipal® amino resins


and Larotact® co-cross-linker

Solvent-based systems
1 Suited 2 Highly recommended

Free Substrate
Non-volatile at Viscosity at Temperature Acid
Product Type of product Solvent formalde- Key properties
2 h, 125 °C [%] 23 °C [mPa·s] reactivity reactivity Wood Metal Plastic Glass Concrete
hyde [%]

Co-cross-linker
Low-viscous and low-molecular-mass blocked isocyanate cross-linker. Deblocking and cross-linking start
at temperatures above 120 °C. No formaldehyde released during cross-linking. It does not cross-link with
Triazine derivative (melamine-based
Larotact® 150 10–50 n-Butanol - - - itself, making it an optimum cross-linker yielding an advantageous flexibility / hardness relation. Best use - 2 - 1 -
blocked isocyanate)
in combination with amino resins or alone. Preferred fields of application are automotive, industrial, and
coil-coating finishes

Melamine-formaldehyde resins / butanol-etherified
Butanol /  For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 012 Melamine resin, high imino content 56–60 600–1,000 Medium - < 0.5 - 2 - 1 -
xylene lower solids content than Luwipal® 016

Melamine resin, high MW /  For solvent-based, medium-solid automotive or industrial coatings with very high baking reactivity; fast
Luwipal® 014 50–54 600–1,000 Butanol High High < 1.0 - 2 - 1 -
high imino physical drying

Melamine resin, high MW /  i-Butanol-etherified resin; for solvent-based, medium-solid automotive or industrial coatings with very high
Luwipal® 015 52–55 1,300–2,000 Isobutanol High - < 0.5 - 2 - 1 -
high imino baking reactivity; fast physical drying

Butanol / 
Luwipal® 016 Melamine resin, high methylolation 72–75 6,000–10,000 Medium - < 0.4 For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity - 2 - 1 -
xylene

Melamine resin, high methylolation, For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 018 71–75 4,000–7,000 Butanol Medium - < 0.6 - 2 - 1 -
higher etherified standard for automotive clear-coat applications

Melamine resin, high methylolation, Butanol /  For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 018 BX 64–68 900–1,400 Medium - < 0.6 - 2 - 1 -
higher etherified xylene standard for automotive clear-coat applications; solvent cut butanol / xylene

Melamine resin, high methylolation, For solvent-based, medium-solid automotive or industrial coatings with medium to high baking reactivity;
Luwipal® 018 RF 68–72 3,000–6,000 Butanol Medium - < 0.4 - 2 - 1 -
higher etherified standard for automotive clear-coat applications; reduced formaldehyde content

For acid-curable solvent-based furniture and wood floor coatings with high reactivity and excellent chemical
Luwipal® 044 ULF Fully butyl-etherified melamine resin 94–97 2,000–5,000 - Low High < 0.1 2 2 - 1 -
resistance; no CMR labeling

Melamine-formaldehyde resins / methanol-butanol-mixed-etherified
Mixed-etherified melamine resin, Methanol-butanol-mixed-etherified resin for water-based and solvent-based coatings; high baking
Luwipal® 052 69–72 4,000–6,500 Butanol Medium - < 1.0 1 2 - 1 -
high methylolation degree reactivity; for automotive application

Melamine-formaldehyde resins / methanol-etherified
Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for furniture foil and
Luwipal® 066 93–96 2,000–6,000 - Low High < 0.6 1 2 - 2 -
fully methyl-etherified coil-coating applications

Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for furniture foil and
Luwipal® 066 LF 93–96 2,000–6,000 - Low High < 0.3 1 2 - 2 -
fully methyl-etherified coil-coating applications: low formaldehyde content

Hexa(methoxymethyl)-melamine, For solvent-based and water-based acid-curable coatings. Very high reactivity, for furniture foil and
Luwipal® 066 ULF 93–96 2,000–6,000 - Low High < 0.1 1 2 - 2 -
fully methyl-etherified coil-coating applications; no CMR labeling

Melamine resin, balanced For solvent-based and water-based coatings. High baking reactivity, for furniture foil, coil, automotive and
Luwipal® 072 73–77 4,000–7,000 Isobutanol High - < 1.0 1 2 - 2 -
imino-methylolation degree industrial applications

Benzoguanamine formaldehyde resin / n-butanol-etherified


Benzoguan amine resins, Benzoguanamine resin; for solvent-based coatings; medium to high baking reactivity. For coil and can
Luwipal® B 017 79–83 3,000–5,000 Butanol Medium - < 0.7 - 2 - 1 -
high methylolation degree coating primers
50 Solvent-based systems
 2019
Solvent-based systems
 2019 51

Plastopal® urea resins and


Laroflex® polyvinyl chlorides

Solvent-based systems
1 Suited 2 Highly recommended

Free
Non-volatile at 2 h, Viscosity at 23 °C Temperature Acid
Product Type of product Solvent formalde- Key properties Wood Metal Plastic Glass Concrete
125 °C [%] [mPa·s] reactivity reactivity
hyde [%]

Urea resins
Carbamate resin,  Carbamate resin for solvent-based coatings; medium to high acid reactivity. For wood and
Plastopal® BTB 59–62 1,600–2,400 Butanol Low Medium < 0.5 2 2 - 1 -
medium-etherified floor coatings, suitable as sole binder

Urea resin,
Plastopal® EBS 400 B 59–62 1,400–1,700 Butanol Low Medium < 0.8 Universal resin with low baking reactivity; for general wood and industrial applications 2 2 - 1 -
medium-etherified

Urea resin, i-Butanol-etherified resin with low baking reactivity; for general wood and industrial
Plastopal® EBS 400 I 59–62 1,400–1,700 Isobutanol Low Medium < 1.0 2 2 - 1 -
medium-etherified applications

Urea resin,
Plastopal® H73 IB 59–62 4,000–7,000 Isobutanol Medium High < 0.4 i-Butanol-etherified resin; high acid reactivity; for furniture, floor, and industrial coatings 2 2 - 1 -
highly etherified

Urea resin, Medium acid reactivity; low solvent content; high gloss; for furniture, floor, and industrial
Plastopal® H85 EB LF 83–88 3,000–6,000 Butanol / ethanol Low Medium < 0.3 2 2 - 1 -
medium-etherified coatings; low formaldehyde content

Plastopal® RH Urea resin, low-etherified 59–62 1,000–1,300 Butanol / xylene High Low < 0.6 Very high baking reactivity for industrial primers - 2 - 1 -

Viscosity [mPa·s] (20% solution Vicat softening Substrate


Product Physical form K value Key properties and applications
in toluene, 23 °C) temperature [°C] Wood Metal Plastic Glass Concrete

Polyvinyl chlorides
Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 15 Fine white powder 12–18 30 46–48 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 2 1 - 2
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics

Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 25 Fine white powder 20–26 35 48–52 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 2 1 - 2
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics

Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 35 Fine white powder 30–40 35 48–52 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 2 1 - 2
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics

Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
mineral substrates, as well as for printing inks (PVC / acrylic gravure inks) and road marking paints, resistant
Laroflex® MP 45 Fine white powder 40–50 35 48–52 - 2 1 - 2
to hydrolysis. Requires additional plastification using plasticizers or soft resins. Can be blended with alkyds
or acrylics

Chlorinated binder for the manufacture of physical drying coatings on iron and steel, non-ferrous metals,
Laroflex® MP 60 Fine white powder > 50 35 48–52 mineral substrates, as well as for printing inks and road marking paints, resistant to hydrolysis. Requires - 1 1 - 1
additional plastification using plasticizers or soft resins. Can be blended with alkyds or acrylics
52 Solvent-based systems
 2019
Solvent-based systems
 2019 53

Basonat® polyisocyanates
and Larotact® co-cross-linker

Solvent-based systems
Viscosity at
Product Type of product Solids by weight [%] NCO [%] Solvent Key properties and applications
23 °C [mPa·s]

Allophanates (NEW: available at < 0.1% residual diisocyanate)


Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 1000 HDI allophanate 100 900–1,500 21.0–23.0 -
water-based 2K PU wood coatings

Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 2000 HDI allophanate 100 500–900 18.5–21.5 -
water-based 2K PU wood coatings

Low-viscous polyisocyanates for high-solid solvent-based 2K PU coatings. It can also be combined with water-emulsifiable Basonat® HW types and secondary dispersions for
Basonat® HA 3000 HDI allophanate 100 200–400 19.0–20.0 -
water-based 2K PU wood coatings

Biurets
Basonat® HB 100 HDI biuret 100 2,500–4,000 22.0–23.0 - Basonat® HB polyisocyanates for general use 2K PU coatings such as general industry, high-performance wood coatings, automotive topcoats, especially plastic substrates

Methoxypropyl acetate /
Basonat® HB 175 MP/X HDI biuret 75 130–300 16.0–17.0 Basonat® HB polyisocyanates for general use 2K PU coatings such as general industry, high-performance wood coatings, automotive topcoats, especially plastic substrates
Xylene 1:1

Basonat® HB 275 B HDI biuret 75 100–180 16.0–17.0 n-Butyl acetate Basonat® HB polyisocyanates for general use 2K PU coatings such as general industry, high-performance wood coatings, automotive topcoats, especially plastic substrates

n-Butyl acetate / Biuret grades known as polyisocyanates for general use in 2K PU coatings; applications extend from automotive topcoats, especially for plastic substrates, to general industry and
Basonat® HB 475 B/X HDI biuret 75 100–250 16.0–17.0
Xylene 1:1 high-performance wood coatings

Isocyanurates (NEW: available at < 0.1% residual diisocyanate)


Solvent-free (allowing for Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coating. They are compatible and cross-linkable with most hydroxy-acrylic
Basonat® HI 100 NG HDI isocyanurate 100 2,500–4,000 21.5–22.5
broad range solvents) resins, e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations

Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coating. They are compatible and cross-linkable with most hydroxy-acrylic
Basonat® HI 145 B NG HDI isocyanurate 45 < 10 9.7–10.1 n-Butyl acetate
resins, e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations

Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coating. They are compatible and cross-linkable with most hydroxy-acrylic
Basonat® HI 152 B NG HDI isocyanurate 52 6–20 11–12 n-Butyl acetate
resins, e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations

Isocyanurate trimers known for low initial color, high weather resistance, high cross-link density, and perfect for high-performance 2K PU coatings, e.g. for 2K PU automotive OEM
Basonat® HI 172 S NG HDI isocyanurate 72 70–120 15.3–16.6 Solvesso® 100
and refinish; NG: reduced color drift in formulations

n-Butyl acetate / Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coatings; compatible and cross-linkable with most hydroxy-acrylic resins,
Basonat® HI 180 B/S NG HDI isocyanurate 80 130–250 16.9–18.3
Solvesso® 100 1:1 e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations

n-Butyl acetate / Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coatings; compatible and cross-linkable with most hydroxy-acrylic resins,
Basonat® HI 190 B/S NG HDI isocyanurate 90 450–600 19.3–20.3
Solvesso® 100 1:1 e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations

n-Butyl acetate / Isocyanurate trimers known for low initial color, high weather resistance, high cross-link density, and perfect for high-performance 2K PU coatings, e.g. for 2K PU automotive OEM
Basonat® HI 268 B/S NG HDI isocyanurate 68 39–55 14.5–15.5
Solvesso® 100 1:1 and refinish; NG: reduced color drift in formulations

Basonat® HI aliphatic polyisocyanates for highly cross-linked, lightfast, and weather-resistant 2K PU coatings; compatible and cross-linkable with most hydroxy-acrylic resins,
Basonat® HI 290 B NG HDI isocyanurate 90 400–600 19.3–20.3 n-Butyl acetate
e.g. Joncryl® grades and polyester resins containing hydroxyl groups; NG: reduced color drift in formulations

Low-viscous trimer for high-solid 2K PU coatings without limitation in chemical resistance and reactivity. It can also be combined with water-emulsifiable Basonat® HW types and
Basonat® HI 2000 NG HDI isocyanurate low-viscous 100 900–1,500 22.5–23.5 -
secondary dispersions for water-based 2K PU wood coatings; NG: reduced color drift in formulations

Blocked polyisocyanate-type co-cross-linker


Low-viscous and low-molecular-mass blocked isocyanate cross-linker. Deblocking and cross-linking start at temperatures above 120 °C. No formaldehyde release during
Triazine derivative (melamine-based
Larotact® 150 48–52 [105 °C] 10–50 - n-Butanol cross-linking. It does not cross-link with itself, making it an optimum cross-linker yielding an advantageous flexibility / hardness relation. Best use in combination with amino resins
blocked isocyanate)
or alone. Preferred fields of application are automotive, industrial, and coil-coating finishes
54 Solvent-based systems
 2019
Solvent-based systems
 2019 55

Laropal® grinding resins, Ludopal®


unsaturated polyesters, Laromin® amine

Solvent-based systems
1 Suited 2 Highly recommended

Solids by weight Viscosity at 25 °C Flash point OH number on Iodine color


Product Type of resin Physical form Tg [°C] Key properties and applications
[%] [mPa·s] [°C] solids [mg KOH/g] number

Grinding resins
Condensation product of urea with Excellent compatibility with common coating resins. Excellent solubility. Good pigment wetting. Improves hardness, gloss,
Laropal® A 81 Solid 100 - - 57 40 ≤3
aliphatic aldehydes and adhesion. Resistance to yellowing. Used as grinding resin or co-binder

Condensation product of urea with Excellent compatibility and solubility with common coating resins. Good pigment wetting. Improves hardness, gloss, and
Laropal® A 101 Solid 100 - - 73 35 ≤5
aliphatic aldehydes adhesion. Resistance to yellowing. Used as grinding resin or co-binder

Condensation product of urea with Excellent compatibility and solubility with common coating resins. Good pigment wetting. Improves gloss, and adhesion.
Laropal® A-8L Liquid 78–83 7,000–15,000 49.5 – 8 90 ≤ 50
aliphatic aldehydes Resistance to yellowing. Used as grinding resin

Solids by weight Viscosity at 23 °C Acid number on Refractive index Substrate


Product Physical form Key properties and applications
[%] [mPa·s] solids [mg KOH/g] at 20 °C Wood Metal Plastic Glass Concrete

Unsaturated polyesters
Unsaturated polyester resin for the formulation of sandable and polishable coatings and surfacers for wood
Ludopal® P 6 Solution in styrene 64–67 900–1,200 29–33 1.531–1.534 2 1 1 - -
and metal, dissolved in styrene. Suitable for gelcoats

Unsaturated polyester resin for the formulation of sandable and polishable coatings and surfacers for wood
Ludopal® U 150 Solution in styrene 64–67 900–1,100 27–31 1.524–1.527 2 1 1 - -
and metal, dissolved in styrene. Suitable for gelcoats

Hydrogen Substrate
Solids by weight Viscosity at 23 °C
Product Physical form Water content [%] equivalent weight Key properties and applications
[%] [mPa·s] Wood Metal Plastic Glass Concrete
(HEW)

Amine
Laromin® C 260 is mainly used to harden low viscosity liquid epoxy resins for low-solvent or solvent-free
coatings, construction trade, or marine coatings. Combinations of Laromin® C 260 with solid epoxy resins
Laromin® C 260 Liquid 99 6–10 < 0.2 27 - 2 1 - 2
and solvents are used as hardeners for industrial and anticorrosion coatings. It can also be used for curing
concrete topping, self-leveling concrete, repair mortars, as well as highly filled wearing surfaces
56 Solvent-based systems
 2019
Solvent-based systems
 2019 57

Soft resins

Solvent-based systems
1 Suited 2 Highly recommended

Solids by Viscosity at 23 °C Flash point Iodine color Substrate


Product Physical form Tg [°C] Key properties and applications
weight [%] [mPa·s] [°C] number Wood Metal Plastic Glass Concrete

Acrylic resins
130–200 Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Acronal® 4 F Liquid 99.0 150 –40 0–1 1 1 1 - 1
(50% in ethyl acetate) binders for coatings with good flexibility and excellent adhesion

Acronal® 4 L approx. Polymer of butyl acrylate, dissolved in acetate; soft acrylic resin, resistant to light and aging, for plasticizing
Solution in ethyl acetate 50.0 1,600–2,600 –6 –40 - 1 1 1 - 1
50% in ethyl acetate cellulose nitrate and chlorine-containing binders for coatings with good flexibility and excellent adhesion

Acronal® 500 LC Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Solution in ethyl acetate 40.0 9,000–14,000 (25 1/s) –4 - - 1 1 1 - 1
40% in ethyl acetate binders for coatings with good flexibility and excellent adhesion

Copolymer of vinyl isobutyl ether and n-butyl acrylate, dissolved in ethyl acetate; soft acrylic resin, resistant
Acronal® 700 L approx.
Solution in ethyl acetate 51.0 500–800 –4 - 0–2 to light and aging, for plasticizing cellulose nitrate and chlorine-containing binders for coatings with good 1 1 1 - 1
50% in ethyl acetate
flexibility and excellent adhesion

Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Acronal® 9020
Solution in o-xylene 65.0 1,000–2,500 34 - 0–1 binders for coatings with good flexibility and excellent adhesion. Main application: plastification of PVDF 1 1 1 - 1
65%ig in o-xylene
for coil coatings

Soft acrylic resin, resistant to light and aging, for plasticizing cellulose nitrate and chlorine-containing
Acronal® LR 8820 Liquid 98.5 20,000–50,000 (25 1/s) 109 –45 - - 1 1 - 1
binders for coatings with good flexibility and excellent adhesion

Compatible with many other resin systems, used as modifying resin to confer flexibility and improves
Joncryl® 611 Solid 99.0 150 (40% in toluene) - - 1 1 - - -
adhesion. Product is soluble in alcohols, aldehydes, ketones, and aromatic hydrocarbons

Solids by Viscosity at 23 °C Flash point Iodine color Substrate


Product Type of resin Physical form Tg [°C] Key properties and applications
weight [%] [Pa·s] [°C] number Wood Metal Plastic Glass Concrete

Vinyl ethers
Lutonal® A 25 Poly(vinyl ethyl ether) Liquid > 90 2.5–6.0 (100 1/s) > 55 –43 0–15 Plasticizing soft resin, i.e. for cellulose nitrate coatings. It also acts as an adhesion promoter 1 1 1 1 -

Lutonal A 50 app.
®
Plasticizing soft resin, i.e. for cellulose nitrate coatings. It also acts as an adhesion promoter.
Poly(vinyl ethyl ether) Solution 50 5–20 (25 1/s) 9 –30 0–4 1 1 1 1 -
50% in ethanol 50% solution in ethanol

Lutonal® I 60
Poly(vinyl isobutyl ether) Solution 35 0.3–4.5 (100 1/s) 26 –27 0–8 Plasticizing soft resin. It also acts as an adhesion promoter. 35% solution in white spirit 1 1 1 1 -
35% in white spirit

Lutonal® I 60 app. 1.0–6.0 (Brookfield


Poly(vinyl isobutyl ether) Solution 50 –21 –27 0–8 Plasticizing soft resin. It also acts as an adhesion promoter. 50% solution in light naphta 1 1 1 1 -
50% in light naphta RV, Sp. 5, 20 1/s)

Lutonal® M 40, Plasticizing soft resin, i.e. for cellulose nitrate coatings. It also acts as an adhesion promoter.
Poly(vinyl methyl ether) Solution 70 50–250 (25 1/s) 11 –49 0–15 1 2 1 1 -
45% in o-xylene Used as co-binder for anti-fouling coatings. 70% solution in ethanol

Non-volatile at 2 h, Viscosity at 23 °C Flash point Iodine color Substrate


Product Type of product Solvent Key properties
125 °C [%] [mPa·s] [°C] number Wood Metal Plastic Glass Concrete

Glycoluril
Plastigen® G ULF Glycoluril resin 93–96 900–1,400 Solution in n-butanol 77 < 400 Hazen Carbamide soft resin, as adhesion promoter and plasticizing resin for solvent-based coatings 1 1 1 1 -
Bitte Kurzversion des Kapiteltitels
Renewable
eintragen
5959
systems
 2019  2019

Renewable systems

The coatings market is at a turning point: Efficient production is meant to go hand in

Renewable systems
hand with ever better performance. At the same time, applied coatings must meet the
increasing demand for health-friendly and resource-saving solutions. The paints and
coatings industry can profit from these trends by delivering products that offer high-
performance while consuming fewer resources and causing less emissions. Adding
value with more sustainable solutions will most likely become a key growth driver.

We at BASF can help you meet these future demands. Discover our advanced
renewable solutions to set your products apart from the competition!
60 Renewable systems
 2019
Renewable systems
 2019 61

Saving fossil resources and reducing


CO2 emissions

BASF’s biomass balance approach


Consumers are increasingly aware of sustainability, a trend that is reflected in
purchase decisions. Market research shows that significant numbers of consumers
favor products manufactured by companies that actively conserve resources, save

Renewable systems
costs, and safeguard human well-being and the environment. This demand can be
expected to keep growing long into the future.

The coatings industry can benefit from the trend by Surprise your customers with added
delivering products that offer outstanding performance ecological benefit!
while consuming fewer resources and causing less
emissions. §§ Drives the use of sustainable renewable feedstock

With the biomass balance approach, BASF offers you §§ Saves fossil resources and reduces greenhouse gas
more sustainable resins and additives while maintaining emissions
the same product performance as ever. §§ Independently certified by third party
§§ Same product quality and properties
In this approach, the fossil resources are replaced
by sustainable biomass such as bio-naphtha or biogas
already at the beginning of the production process. If you are interested in our sustainable solutions, please
In a calculatory process certified by a third party, the contact us – our experts will be glad to advise you.
applied share of renewable resources is then virtually
allocated to the new product line. According to this
calculation, up to 100 % of the fossil resources Read more about biomass balance at
can be replaced by renewable raw materials. basf.com/biomassbalance

Almost all our resins can be manufactured according to


the biomass balance approach.
62 Renewable systems
 2019
Renewable systems
 2019 63

Your best choice for natural oil polyols

Sovermol® – a chemical hybrid Polyether

Hydrolysis stability
Natural oil polyols are polyfunctional alcohols based on renewable raw materials like
rapeseed oil, castor oil, soybean oil, and palm kernel oil. The practical advantages of Sovermol® polyether / polyester
these products include good adhesion, excellent workability, and good weathering

Renewable systems
Hydrophobic properties
properties. They can also be used on a wide variety of different substrates.
Hydrolysis stability

Polyols based on natural oils have a very pronounced The modular system of our Sovermol® product group
hydrophobic character. For this reason, oleochemical includes other important features, such as being 100% Hydrophobic properties
polyols create significantly less carbon dioxide by virtue solid, good gloss development, and good pigment-​
of the side reaction of the isocyanate. In high humidity wetting characteristics. The latest generation of BASF Hydrolysis stability
and high temperature conditions, these special polyols Sovermol® products combines sustainability with
are able to create networks without bubbles or foam performance, thus meeting the requirements of today’s
formation. Besides good hydrophobicity, polyols producers and consumers. Hardness can be regulated
based on oleochemicals exhibit excellent hydrolysis without using plasticizers and the group features Hydrophobic properties
resistance, chemical resistance, and UV resistance, excellent UV stability and long-term weathering
as well as low viscosity. This latter characteristic is performance. Some markets where Sovermol® is being
especially important in spraying applications. used include concrete flooring, wind blades, pipeline Polyester
coatings, protective coatings, and adhesives.
64 Renewable systems
 2019
Renewable systems
 2019 65

Sovermol® natural oil-based polyols


(1/2)
1 Suited 2 Highly recommended

Medium OH Medium Substrate


Renewable raw Medium OH
Product Type of product Functionality equivalent viscosity Key properties and applications
material content value Wood Metal Plastic Glass Concrete
[weight] [mPa·s]

Natural oil-based polyols


Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve-
Sovermol® 45 Branched polyether - 4.0 98 570 3,000 ment of glass transition temperature Tg; high cross-linking density; hydrophilic; improvement of chemical 1 1 1 1 2
resistance

Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve-
ment of glass transition temperature; high cross-linking density, hydrophilic; improvement of chemical
Sovermol® 100 Branched polyether - 3.0 64 880 6,000

Renewable systems
1 2 1 1 2
resistance; drinking and potable water application possible upon product-specific confirmation according
to local legislation

Copolyol for flooring (combined with Sovermol® 750 UV stable), adhesives, and casting materials; improve-
ment of glass transition temperature; high cross-linking density, hydrophilic; improvement of chemical
Sovermol® 100 N NEW Branched polyether - 3.0 65 860 5,900 1 2 1 1 2
resistance; drinking and potable water application possible upon product-specific confirmation according to
local legislation (N: different production site)

Branched polyether /  Drinking and potable water application possible upon product-specific confirmation according to local
Sovermol® 320 80–100% 2.8 180 310 1,000 1 2 1 1 2
polyester legislation; high shore D hardness (D ~ 80); good mechanical properties

Branched polyether /  Polyol for UV-stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 80);
Sovermol® 750 65–80% 3.0 178 315 1,100 [20 °C] 1 2 1 1 2
polyester hydrophobic; high saponification stability; excellent chemical resistance; hydrolysis stable; high-Tg polyol

Branched polyether /  High shore D hardness (D ~ 90); hydrophobic; high saponification stability; excellent chemical resistance;
Sovermol® 760 65–80% 3.5 145 390 2,300 1 1 1 1 2
polyester hydrolysis stable; extremely high-Tg polyol; high heat resistance

Branched polyether /  Polyol for UV-stable and weathering-resistant coatings and floorings; high shore D hardness (D ~ 90);
Sovermol® 780 50–65% 3.0 110 510 2,300 [20 °C] 1 2 1 2 2
polyester hydrophobic; excellent chemical resistance; hydrolysis stable; high-Tg polyol

Branched polyether / 
Sovermol® 805 65–80% 3.5 330 170 3,500 Universal polyol; excellent impact resistance; shore D hardness (D ~ 70) 2 2 2 1 2
polyester

Branched polyether / 
Sovermol® 810 65–80% 3.3 244 230 900 Polyol for encapsulation systems; hydrolysis stable; hydrophobic; low viscosity; high filler content possible 2 1 1 1 2
polyester

Branched polyether /  Low-viscous universal polyol binder for pigment pastes and crack-bridging flooring; good chemical resis­
Sovermol® 815 80–100% 3.5 260 215 1,600 2 1 1 1 2
polyester tance, hydrophobic, good elastic, memory effect

Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; excellent flexibility at
Sovermol® 818 Fatty acid polyester 80–100% 2.6 238 236 750 2 2 2 1 2
temperatures below 0 °C; good bonding properties

Low-viscous universal polyol; extremely hydrophobic; good self-leveling properties; good bonding
Sovermol® 819 Fatty acid polyester 80–100% 2.6 234 240 850 2 2 2 1 2
properties
66 Renewable systems
 2019
Renewable systems
 2019 67

Sovermol® natural oil-based polyols


(2/2)
1 Suited 2 Highly recommended

Medium OH Medium Substrate


Renewable raw Medium OH
Product Type of product Functionality equivalent viscosity Key properties and applications
material content value Wood Metal Plastic Glass Concrete
[weight] [mPa·s]

Natural oil-based polyols


Low-viscous universal workhorse polyol; extremely hydrophobic; good self-leveling properties; good
Branched oleochemical
Sovermol® 830 80–100% 2.6 233 241 875 bonding properties; drinking and potable water application possible upon product-specific confirmation 2 2 2 2 2
polyether / polyester
according to local legislation

Gel time prolonger; reactive diluent; hydrophobic; good adhesive properties on metal surfaces; contains
Sovermol® 860 Aliphatic polyol 80–100% 2.5 270 210 530 [20 °C] 2 2 1 1 2
epoxy groups (Ep-O = 0.3 to 1.4%)

Renewable systems
Sovermol® 908 Aliphatic dimer alcohol 80–100% 2.0 272 206 2,300 Crack-bridging coatings; good saponification stability; hard elastic performance; hydrophobic 1 1 1 1 2

Slightly branched Hydrophobic; plasticizer for polyol; soft elastic performance; drinking and potable water application possible
Sovermol® 1005 80–100% 2.2 460 122 800 [20 °C] 2 2 1 1 2
aliphatic diol upon product-specific confirmation according to local legislation

Soft elastic performance; drinking and potable water application possible upon product-specific
Sovermol® 1014 Aliphatic triol 80–100% 2.5 350 160 700 2 2 1 1 2
confirmation according to local legislation

Fatty acid polyester Ep content Non-reactive diluent; VOC-free acc. to 2004/42/EU; UV-stable performance; plasticizer for polyols and
Sovermol® 1055 80–100% - EEW = 333 15 [20 °C] 1 1 1 1 2
with epoxy groups 4.6–5.0% epoxy resins

Sovermol® 1058 Fatty acid polyester 80–100% - - - 5 [20 °C] Non-reactive diluent; VOC-free acc. to 2004/42/EU; hydrophobic; plasticizer for polyols 1 1 1 1 2

Branched polyether /  High-performance polyol for coatings, putties, and adhesives, low viscosity; extremely hydrophobic;
Sovermol® 1092 65–80% 2.8 198 283 800 2 2 1 1 2
polyester hardness similar to epoxy systems; hard elastic performance; good self-leveling properties

Branched polyether / 
Sovermol® 1093 65–80% 2.8 245 229 2,500 Polyol; high hardness; hydrophobic performance; hard elastic; water repellency 2 2 2 1 2
polyester

Slightly branched
Sovermol® 1102 80–100% 2.1 245 230 400 [20 °C] Universal copolyol; gel time prolonger; reactive diluent hydrophobic; UV-stable; soft elastic performance 1 2 1 1 2
polyether / polyester

Sovermol® 1140 Fatty acid polyester 80–100% 2.7 267 210 1,000 Universal polyol for adhesives; gel time prolonger; hard flexible performance; hydrophobic 1 1 1 1 2
68 Renewable systems
 2019
Renewable systems
 2019 69

Properties of Sovermol®
natural oil-based polyols
After stoichiometric cross-linking with MDI polymer
(NCO = 31%, functionality = 2.4)

Gel time ASTM D Shore hardness A / D (EN ISO 868) ISO 527-3 Type 5 ISO 527-3 Type 5 ISO 34-1 DIN EN ISO 604 DIN EN ISO 178 DIN 53453 DIN 53754
Product 2471-88 (30 g mass) Tensile strength Tear resistance Compression Bending strength Impact resistance Abrasion
[h:min] 1st day 2nd day 14th day 28th day Elongation [%]
[MPa] [N/mm] strength [MPa] [MPa] [mJ/mm²] [mg/1,000 R]
Sovermol® 100 / 
0:20 100 / 77 100 / 77 100 / 80 100 / 80 n.m. n.m. n.m. n.m. 107 2 n.m.
Sovermol® 100 N

Sovermol® 320 0:46 71 / 22 98 / 64 100 / 81 100 / 83 30 4 30 n.m. 36 12 n.m.

Sovermol® 750 0:38 100 / 74 100 / 80 100 / 86 100 / 87 45 3 9 36 53 6 34

Renewable systems
Sovermol® 760 0:19 100 / 86 100 / 88 100 / 90 100 / 90 42 1 6 45 57 4 15

Sovermol® 780 0:22 100 / 89 100 / 90 100 / 91 100 / 91 58 0 4 45 85 6 61

Sovermol 805
®
0:47 75 / 30 86 / 42 98 / 64 98 / 69 17 65 88 n.m. 8 121 68

Sovermol 810
®
0:55 77 / 32 86 / 42 98 / 66 98 / 67 18 39 60 n.m. 10 34 79

Sovermol 815
®
1:00 83 / 39 92 / 52 99 / 75 99 / 77 21 34 70 n.m. 22 24 28

Sovermol 818
®
1:24 60 / 18 78 / 31 94 / 50 96 / 60 18 58 64 n.m. 6 113 77

Sovermol 819
®
0:59 69 / 24 85 / 39 96 / 62 97 / 64 18 66 70 n.m. 7 107 88

Sovermol 830
®
0:55 70 / 25 85 / 39 96 / 63 100 / 65 19 65 73 13 6 126 42

Sovermol® 860 6:10 n.m. n.m. 85 / n.m. 97 / 62 13 17 48 n.m. 6 9 100

Sovermol® 908 0:12 66 / 24 78 / 34 84 / 40 84 / 42 14 122 38 n.m. 1 96 n.m.

Sovermol® 1005 1:47 n.m. 4 / n.m. 22 / n.m. 38 / 10 1 24 3 n.m. 0.3 n.m. n.m.

Sovermol® 1014 1:35 50 / 17 62 / 24 67 / 26 67 / 26 3 59 6 n.m. 1 3 7

Sovermol® 1092 1:09 90 / 45 97 / 65 100 / 84 100 / 86 39 3 21 31 43 34 61

Sovermol 1093
®
0:59 96 / 60 n.m. 100 / 87 100 / 87 43 4 25 n.m. 54 34 n.m.

Sovermol 1102
®
3:15 n.m. 39 / 10 89 / 45 94 / 56 13 52 47 n.m. 2 38 75

Sovermol 1140
®
6:07 n.m. 50 / n.m. 98 / 61 99 / 69 10 1 14 9 16 10 n.m.

n.m. = not measured


Bitte Kurzversion des Kapiteltitels
Radiation-curable
eintragen
systems
7171
 2019  2019

Radiation-curable systems

BASF is the first choice for high-performance radiation-curable resins. Our Laromer®
range enables you to create coatings as well as printing formulations tailored to your
needs. Your challenges are our challenges, and constantly spur us on to improve
our product portfolio with innovative new solutions for your coating and printing
formulations.

With our continuous high focus on research and development, investments in assets
and people, and our close interaction with formulators and machine manufacturers,
we are shaping the future of radiation-curable resins – for example with our water-

Radiation-curable systems
based UV resins.

Oligomers Monomers

Our extensive portfolio of oligomers, our strong Reactive diluents are key ingredients in most UV and
technical center, and our passionate team of experts EB formulations for matching the viscosity to a wide
are dedicated to fulfilling your requirements for variety of application conditions. Additionally, they
state-of-the-art UV and EB formulations. We offer a influence performance properties like reactivity,
broad portfolio of oligomers including UV 100% and hardness, and adhesion. BASF offers a broad portfolio
UV waterborne resins. of high-quality monomers for the coating and printing
industries.
72 Radiation-curable systems
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Radiation-curable systems
 2019 73

Discover new possibilities

UV LED curing Corrosion protection


1 Good 2 Very good 3 Excellent

UV LED curing is continuing to make significant inroads A high-performance UV coating needs to meet other Anti-
Product Type Viscosity (23.0 °C) Product Type Adhesion
into traditional UV curing markets used to work with prerequisites besides adhesion to the metal, e.g. good corrosion
mercury lamps as radiation source until now. UV LED Amine-modified anticorrosion properties. That’s why we offer UV resins Adhesion
Laromer® PO 8996 0.05 – 0.09 Pa·s Laromer® PA 9083 3 1
radiation sources, apart from their considerably longer polyether acrylate that can be used in combination with acidic adhesion promoter
service life than mercury lamps, do not emit infrared promoters and low-shrinkage, hydrophobic UV diluents.
radiation evolving as heat. As a consequence, heat-​​ Amine-modified Since the cross-linking of UV coatings is done at room
Laromer® PO 9144 0.10 – 0.20 Pa·s Laromer® TBCH Diluent 3 2
polyether acrylate
sensitive substrates like plastic films in packaging or temperature, UV technology is also very economical.
wood in furniture applications can be processed without Amine-modified
any dif­fi­culties caused by heating in contrast to mercury Laromer® PO 94 F 0.45 – 0.75 Pa·s
polyether acrylate Laromer® LR 8887 Diluent 3 3
lamps.
Amine-modified
Laromer® PO 9137 0.50 – 0.90 Pa·s Anticorrosion
polyether acrylate Laromer® UP 9151
However, due to the quasi-monochromatic emission resin
2 3
of commercial UV LED radiation sources in the wave­
Amine-modified
length range of 360–410 nm, the number of suitable Laromer® PO 9067 0.50 – 0.90 Pa·s
polyether acrylate
photoinitiators, absorbing this red-shifted UV radiation
is rather limited; particularly photoinitiators with proper Laromer® PO 9139
Amine-modified
2.0 – 6.0 Pa·s
surface cure are missing. This lack of surface cure for polyether acrylate
UV LED formulations triggered by oxygen inhibition

Radiation-curable systems
requires the use of highly reactive monomer and Laromer® PE 8981 Polyester acrylate 4.0 – 14.0 Pa·s
oligomer acrylates to compensate these surface cure
deficiencies. A dedicated range of monomer and Modified epoxy
Laromer® LR 9019 12.0 – 20.0 Pa·s
oligomer acrylates with a very fast UV cure response is acrylate
available, covering beyond printing and packaging
markets also furniture and flooring as well as automo-
tive and industrial applications.
74 Radiation-curable systems
 2019
Radiation-curable systems
 2019 75

Enabling durable coatings

Abrasion resistance (Taber®1 Abraser) Scratch resistance Weather resistance Adhesion

Abrasion resistance is of utmost importance in the Many different applications require a highly scratch-re- The weather resistance properties of UV and EB Recently, there has been a strong interest in using UV
world of high-quality flooring products. Product sistant coating to assure a long service life. Examples coatings open up a wide range of outdoor ​ and EB curable technology to coat metal and plastic
selection can sometimes be test-method-dependent include high-performance automotive clear coats and applications. The key to formulating such weather-re- substrates. These non-absorbing substrates require
and a close and specific match is often needed. plastics coatings as well as furniture and flooring sistant coatings is the use of aliphatic urethane careful selection of radiation-curable raw materials to
For each test method, we offer the optimal solution. coatings. Highly scratch-resistant surfaces can be acrylates in combination with a suitable photoinitiator. ensure that the coatings formulation achieves the
achieved via two alternative routes: through resins with To achieve the best possible weather resistance, we necessary adhesion performance. This can be
either high functionality or nano-modification. offer the Tinuvin® product range (UV absorbers and achieved by employing dual cure resins, film shrinkage
HALS). control, substrate wetting optimization, or an acidic
adhesion promoter.

1 Good 2 Very good 3 Excellent

S 33 /  Falling CS 10 /  Scratch Hard- / scratch-


Product Product Key features Product Flexible Product Metal Plastics Wood
S 42 sand CS 17 resistance resistant

Radiation-curable systems
Laromer® PE 56 F - 1 3 Laromer® UA 8987 N 2 High functionality Laromer® UA 8987 N 2 - Laromer® UA 9059 - - 3

Laromer® PE 9032 - 2 2 Laromer® UA 9048 3 High functionality Laromer® UA 9048 3 - Laromer® PA 9083 3 2 -

Laromer® UA 9065 - 2 - Laromer® UA 9136 3 High functionality Laromer® UA 9050 3 - Laromer® PR 9000 1 3 2

Laromer® UA 9033 N - 3 - Laromer® UA 9050 3 High functionality Laromer® UA 19 T - 2 Laromer® UA 9033 N 2 2 2

Laromer® PR 9052 3 - - Laromer® UA 9047 3 High functionality Laromer® UA 9033 N - 3 Laromer® UA 9072 2 2 2

Laromer® TMPTA 3 1 3 Laromer® TMPTA 2 High functionality Laromer® UA 9089 - 3 Laromer® PR 9013 1 1 2

Laromer® DPGDA 1 3 3 Laromer® UA 9136 3 - Laromer® TBCH 3 3 -

Laromer® LR 8887 - 3 1 Laromer® UA 9134 Aqua 2 - Laromer® LR 8887 2 2 2

Laromer® PE 9123 - 3 - Laromer® UA 9147 Aqua 2 - Laromer® POEA 2 2 2

Laromer® PE 9121 - 2 - Laromer® UA 8949 Aqua - 3

® = Registered trademark of Taber Acquisitions Corporation


1 
76 Radiation-curable systems
 2019
PO 9139
Radiation-curable systems
 2019 77
130

PO 9137
120

UV resins
110
Viscosity – reactivity

100 100

UA 9112 Aqua PO 77 F UA 9050


90 90

UA 9005 Aqua
80 80
UA 9149 Aqua
PO 94 F LR 9019 PE 9079

PE 55 Aqua
70 70

UA 9065

UA 9134 Aqua PO 8997


EA 9124 EA 9143
UA 9135 Aqua
60 60
UA 9147 Aqua

Radiation-curable systems
PO 9067 LR 9023

EA 8765 R PE 56 F
50 50
PE 55 F
UA 9154 Aqua PO 84 F EA 9138 PE 9084

PO 8996
UA 8983 Aqua PE 22 Aqua PE 8981 PE 9032
40 40
UA 9095 Aqua PR 9058 UA 9136
PO 9007 EA 9082
EA 9145 PE 9074
UA 8949 Aqua LR 8986 UA 9059 Aqua PE 9004
30 30
PO 9144 UA 9033 N
PE 9123 UA 9048 UA 9073
PE 9045 PE 9121
PR 9052
EA 9097
PO 83 F
20 PO 9034 UA 9047 20
UA 8987 N UP 9118
PE 46 T PE 9142
PR 9119
PO 8967
Reactivity [m/min]

PE 9128 PE 8800
UP 35 D
10 10
UP 9151
PO 43 F
UP 9096 UP 9115 EA 9101 PR 8985
UA 19 T
LR 8863 PE 8907 PE 9126 UA 9072
PO 33 F GPTA UA 9089 PR 9013
PO 9102
UA 9030
0 0
PPTTA
10 55 100 550 1,000 5,500 10,000 50,500 100,000 550,000 1,000,000

Viscosity at 23 °C [mPa·s]

1 Epoxy acrylates 1 Water-based products 1 Polyether acrylates 1 Unsaturated polyesters All products were cured with 1 UV lamp 120 W/cm. Photoinitiator for water-based and amine-modified products 4% 1-hydroxycyclohexyl phenyl ketone /
1 Polyester acrylates 1 Urethane acrylates 1 Amine-modified polyether acrylates 1 Special radiation-curable products benzophenone (1:1), all others 4% 1-hydroxycyclohexyl phenyl ketone
Film thickness: 25 µm
78 Radiation-curable systems
 2019
Radiation-curable systems
 2019 79

UV resins
Hardness – flexibility

10 10
UA 9072

UA 9030

9 9
UA 9059 Aqua
UA 9073
UA 9033 N

UA 9089 UA 8983 Aqua


8 8
UA 9065
UA 8949 Aqua
UA 19 T UA 9154 Aqua

7 PE 55 Aqua 7
PE 9126

PE 8907 PE 9142

PE 9074
6 PE 9045 6
PE 56 F PE 9004

Radiation-curable systems
PE 8981
PE 55 F
UA 9149 Aqua
UA 9095 Aqua
PE 9084 PE 46 T
PE 9128 PO 9102 UP 9115 PE 22 Aqua
5 PO 77 F PE 9079 PE 9032 5
PE 9123 EA 9101 EA 9097
PE 9121 UP 35 D
UA 8987 N
EA 8765 R PO 9067
LR 9023 UA 9005 Aqua
PO 84 F
4 4
LR 9019 PO 9034
PO 94 F PO 8997 PO 83 F PE 8800
PO 9137
PO 9007 PR 9058 EA 9145
PO 8996 LR 8986
PO 9139 UA 9147 Aqua
PO 9144 UP 9096 PO 43 F
3 EA 9138 3
UP 9151
EA 9143 EA 9082
EA 9124

UA 9047 PO 8967
UA 9134 Aqua
GPTA
2 2
UP 9118 UA 9135 Aqua
UA 9112 Aqua
Erichsen cupping [mm]

PO 33 F LR 8863

PR 9013
PPTTA
1 PR 8985 1

UA 9048 UA 9050
PR 9119
UA 9136
PR 9052

0 0
20 40 60 80 100 120 140 160

Pendulum hardness [oscil.]

1 Epoxy acrylates 1 Water-based products 1 Polyether acrylates 1 Unsaturated polyesters All products were cured with 1 UV lamp 120 W/cm. Photoinitiator for water-based and amine-modified products 4% 1-hydroxycyclohexyl phenyl ketone / 
1 Polyester acrylates 1 Urethane acrylates 1 Amine-modified polyether acrylates 1 Special radiation-curable products benzophenone (1:1), all others 4% 1-hydroxycyclohexyl phenyl ketone
Film thickness: 25 µm
80 Radiation-curable systems
 2019
Radiation-curable systems
 2019 81

Functional monomers in formulation

Viscosity – reactivity Hardness – flexibility

PPTTA PPTTA

LR 8863 (TMPEOTA) LR 8863 (TMPEOTA)

GPTA GPTA

TMPTA TMPTA

HDDA HDDA

TPGDA TPGDA

Radiation-curable systems
DPGDA DPGDA

PO 9102 PO 9102

POEA POEA

LR 8887 LR 8887

TBCH TBCH

8,000 6,000 4,000 2,000 0 5 10 15 20 25 60 40 20 0 2 4 6 8

Viscosity at 23 °C [mPa·s] Reactivity [m/min] Pendulum hardness [oscil.] Erichsen indentation [mm]

Formulation: 70 parts Laromer® PE 56 F, 30 parts monomer, 4 parts 1-hydroxycyclohexyl phenyl ketone / benzophenone (1:1) Formulation: 70 parts Laromer® PE 56 F, 30 parts monomer, 4 parts 1-hydroxycyclohexyl phenyl ketone / benzophenone (1:1)
Film thickness: 25 µm Film thickness: 25 µm
82 Radiation-curable systems
 2019
Radiation-curable systems
 2019 83

Laromer® epoxy acrylates

Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Epoxy acrylates
Laromer® EA 8765 R Aliphatic - 0.6–1.2 2.0 330 1 3 3 1 Partially water-soluble, flexible, highly reactive 1 2 1 1 1 1 1 -

Laromer® EA 9082 Aromatic TPGDA [30%] 6.0–9.8 2.0 158 4 2 2 4 Standard epoxy acrylate, low viscosity 1 2 1 1 3 1 1 1

Low viscosity, balanced mechanical profile, good


Laromer® EA 9097 Aromatic TPGDA [40%] 1.5–3.0 2.1 157 4 2 2 4 1 2 1 1 1 1 1 1
chemical resistance

Soybean oil
Laromer® EA 9101 - 13.0–20.0 3.8 3.5 1 3 1 1 Flexibilizing co-resin, outstanding pigment wetting 1 2 1 1 3 1 1 1
acrylate

Laromer® EA 9124 Aromatic HDDA [20%] 7.0–15.0 2.0 181 4 1 2 4 Standard epoxy acrylate with good adhesion 1 - 1 1 3 1 1 1

Laromer EA 9138
®
Aromatic TPGDA [25%] 10.0–20.0 2.0 176 4 2 2 4 Standard epoxy acrylate, medium viscosity 1 - 1 1 3 1 1 1

Laromer® EA 9143 Aromatic GPTA [25%] 35.0–55.0 2.3 175 4 2 2 4 Standard epoxy acrylate, high viscosity 1 2 1 1 3 1 1 1

Laromer® EA 9145 Aromatic DPGDA [30%] 4.0–6.5 2.0 159 4 2 2 4 Standard epoxy acrylate, low viscosity 1 2 1 1 3 1 1 -

Low viscosity epoxy acrylate, good chemical


Laromer® LR 8986 Aromatic - 3.0–6.0 2.4 170 4 3 2 4 1 2 1 1 1 1 1 3
resistance, high hardness

Highly reactive, good chemical resistance, UV LED


Laromer® LR 9019 Aromatic - 12.0–20.0 2.4 175 3 3 4 4 1 2 1 3 - 1 - 3

Radiation-curable systems
curing

Highly reactive, good chemical resistance; diluted


Laromer® LR 9023 Aromatic DPGDA [15%] 2.0–5.0 2.3 150 3 2 3 4 1 2 1 3 - 1 - 3
version of Laromer® LR 9019, UV LED curing

1 Low 2 Medium 3 Good 4 Excellent 1 Notified


2 Please contact your local sales representative for further information
3F  or further regulatory information, please contact ED-PSR@basf.com
- Currently no notification
84 Radiation-curable systems
 2019
Radiation-curable systems
 2019 85

Laromer® polyester acrylates

Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Polyester acrylates
Well-balanced properties with high toughness; diluted version of
Laromer® PE 46 T 2.0–2.5 2.5 60 2 2 2 3 1 2 1 1 1 1 1 1
Laromer® PE 56 F

Laromer® PE 55 F 25.0–45.0 2.6 70 2 3 3 3 Well-balanced properties with high toughness 1 2 1 1 1 1 1 1

Well-balanced properties with high toughness. Improved


Laromer® PE 56 F 20.0–40.0 2.8 70 2 3 3 3 compatibility with reactive diluents (versus Laromer® PE 55 F), 1 2 1 1 1 1 1 1
abrasion-resistant

Laromer® PE 8800 4.0–8.0 2.6 80 3 2 2 4 Hard and good chemical resistance 1 2 1 3 1 1 - 1

Laromer® PE 8907 0.5–2.0 2.0 120 1 4 2 3 Highly flexible, use in combination with hard, less flexible binders 1 - 1 3 - - - -

Laromer® PE 8981 4.0–14.0 2.9 80 1 3 4 3 Highly reactive and flexible, UV LED curing 1 - 1 3 - 1 3 1

Tough with good adhesion, good chemical resistance, high


Laromer® PE 9004 20.0–50.0 2.5 60 2 3 3 3 1 - 1 3 - 1 - 1
abrasion resistance

Laromer® PE 9032 15.0–25.0 2.7 50 2 3 3 3 Abrasion-resistant in parquet applications (falling sand) 1 - - 3 - 1 - 3

Tough with good adhesion, good chemical resistance; diluted


Laromer® PE 9045 2.0–7.0 2.9 60 2 3 3 3 1 - 1 3 - 1 - 1
version of Laromer® LR 9004

Radiation-curable systems
Tough, chemical-resistant; abrasion-resistant in parquet
Laromer® PE 9074 7.0–13.0 2.3 50 2 3 3 3 1 2 1 3 - 1 3 1
applications (falling sand), low yellowing

Tough, chemical-resistant; abrasion-resistant in parquet


Laromer® PE 9079 2.0–4.0 [60 °C] 3.3 60 2 3 3 3 applications (falling sand), high viscosity version of 1 2 1 3 - 1 3 1
Laromer® PE 9074

Tough, chemical-resistant; abrasion-resistant in parquet


Laromer® PE 9084 16.0–26.0 3.0 70 2 3 3 3 applications (falling sand), medium viscosity version of 1 2 1 3 - 1 3 1
Laromer® PE 9074

Laromer® PE 9121 7.0–13.0 4.2 44 2 3 3 3 Low yellowing, good abrasion resistance (falling sand) 1 - 1 3 3 - - 1

Balanced properties, low yellowing, good abrasion resistance


Laromer® PE 9123 2.0–5.0 3.2 50 1 3 2 3 1 - 1 3 1 - - -
(falling sand)

Specially dedicated for PVC flooring: combines superior adhesion


Laromer® PE 9126 8.0–16.0 3.2 68 1 4 1 4 onto flexible substrate with very good chemical resistance against 1 - - - - - - -
medical stains

Laromer® PE 9128 2.0–5.0 1.9 84 1 3 2 3 Free of diluents, low viscosity, flexible 1 2 1 3 - 1 3 3

Can be used for topcoat formulations onto wood, paper, and


Laromer® PE 9142 10.0–30.0 2.8 80 2 2 1 4 1 - - - - - - -
plastic substrates

1 Low 2 Medium 3 Good 4 Excellent 1 Notified


2 Please contact your local sales representative for further information
3F  or further regulatory information, please contact ED-PSR@basf.com
- Currently no notification
86 Radiation-curable systems
 2019
Radiation-curable systems
 2019 87

Laromer® amine-modified polyether


acrylates, polyether acrylates, and dual
cure resins
Type of thinner Viscosity at Amine value Functionality Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
[content] 23 °C [Pa·s] [mg KOH/g] calculated resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Amine-modified polyether acrylates


Laromer® PO 77 F None 1.0–3.0 36 2.5 1 3 3 3 Highly reactive all-round resin, UV LED curing 1 2 1 3 - 1 - 1

Good chemical resistance, low viscosity, UV LED


Laromer® PO 83 F None 0.09–0.13 25 2.6 2 2 3 3 1 2 1 3 - 1 - 3
curing

Reactive, excellent pigment wetting, excellent


Laromer® PO 84 F None 0.4–0.7 35 2.6 2 2 3 3 1 2 1 3 1 3 1 1
leveling, UV LED curing

Highly reactive, good chemical resistance, UV LED


Laromer® PO 94 F None 0.3–0.6 39 2.6 2 3 4 4 1 2 1 1 1 1 1 1
curing

Laromer® PO 8996 None 0.05–0.09 25 2.6 2 2 3 3 Reactive, low color and viscosity, UV LED curing 1 2 1 3 - 3 3 1

Highly reactive, low color and viscosity, UV LED


Laromer® PO 8997 None 0.3–0.5 36 2.6 2 2 4 3 1 - 1 1 - 1 1 3
curing

Laromer® PO 9067 None 0.4–0.7 34 2.6 2 2 3 3 Reactive, good substrate wetting, UV LED curing 1 - 1 1 - 1 - 3

Laromer PO 9137
®
NEW None 0.5–0.9 88 2.4 2 2 4 3 Outstanding reactivity, UV LED applications 1 - 3 3 - - - 1

Laromer® PO 9139 NEW None 2.5–8.0 88 3.3 3 2 4 3 Outstanding reactivity, UV LED applications 1 - 3 3 - - - -

Radiation-curable systems
Laromer® PO 9144 NEW None 0.1–0.3 - 2.6 2 2 3 3 Low viscosity with good reactivity 1 - 1 1 - 1 1 1

Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Type of resin Hardness Elasticity Reactivity Key properties
[content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Polyether acrylates
Alkoxylated TMP
Laromer® PO 33 F None 0.07–0.13 2.7 30 3 1 1 3 Low yellowing, low odor, reactive diluent 1 2 1 3 - 3 1 3
triacrylate

Laromer® PO 43 F - None 0.2–0.4 2.2 100 3 2 2 3 Chemical resistance, all-round resin 1 2 1 1 1 1 1 1

Chemical resistance, all-round resin; low-viscosity


Laromer® PO 8967 - None 0.12–0.19 2.3 50 3 2 2 3 1 2 1 1 1 1 1 1
version of Laromer® PO 43 F

Laromer® PO 9007 - None 0.8–1.5 3.0 130 3 2 3 4 Lowest amount of extractables, scratch-resistant 1 2 1 3 1 1 1 1

Laromer PO 9034
®
- None 0.35–0.6 2.6 58 1 4 2 2 Partially water-soluble, adjustable to spray viscosity 1 2 1 1 1 1 1 1

Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Type of resin Hardness Elasticity Reactivity Key properties
23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Dual cure resin


Aliphatic urethane Contains 14–15 wt% NCO- and UV-reactive groups within one
Laromer® PR 9000 1.0–1.4 2.0 + 2.0 NCO - 2 1 1 2 1 2 1 1 1 1 - 1
acrylate molecule, good adhesion

1 Low 2 Medium 3 Good 4 Excellent 1 Notified


2 Please contact your local sales representative for further information
3F  or further regulatory information, please contact ED-PSR@basf.com
- Currently no notification
88 Radiation-curable systems
 2019
Radiation-curable systems
 2019 89

Laromer® urethane acrylates

Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Urethane acrylates
Elastic, low yellowing, flexible at low temperatures,
Laromer® UA 19 T Aliphatic TPGDA [35%] 14.0–32.0 2.9 10 2 3 1 1 1 2 1 1 1 1 1 3
weathering-resistant

Scratch- and weathering-resistant, for outdoor


Laromer® UA 8987 N Aliphatic HDDA [30%] 4.0–6.0 2.4 11 3 2 2 3 1 2 3 3 - 1 - 1
applications, low yellowing

Laromer® LR
Laromer® UA 9030 Aliphatic 80.0–150.0 2.2 12 1 4 1 1 Highly elastic, low yellowing, good adhesion 1 - 1 1 1 1 1 3
8887 [30%]

Highly elastic, reactive, good adhesion, low


Laromer® LR
Laromer® UA 9033 N Aliphatic 8.0–21.0 2.8 6 1 4 3 2 shrinkage, low yellowing, abrasion-resistant, 1 - 1 1 1 1 - 3
8887 [30%]
weathering-resistant

Physical drying, best performance when cured at


Laromer® UA 9047 Aliphatic BuAc [30%] 2.0–7.0 3.5 30 3 2 1 4 high temperature, good adhesion, low shrinkage, 1 2 3 3 - 1 - 1
good weathering resistance

Excellent scratch and abrasion resistance,


Laromer® UA 9048 Aliphatic DPGDA [25%] 10.0–20.0 7.5 10 4 1 3 4 highly functional, very high chemical resistance, 1 2 3 - 1 1 - -
weathering-resistant

Lowest yellowing, excellent scratch resistance,

Radiation-curable systems
Laromer® UA 9050 Aliphatic BuAc [20%] 1.5–5.0 8.3 10 4 1 3 4 monomer-free (solvent-based) version of 1 2 3 3 1 1 - -
Laromer® UA 9048

Very reactive, very flexible, very good abrasion


Laromer® UA 9065 Aromatic DPGDA [35%] 7.0–9.0 3.5 5 2 4 4 2 1 - 3 3 - - - -
resistance (falling sand)

2.0–15.0 Extremely flexible and tough, best strain-stress


Laromer® UA 9072 Aliphatic TBCH [30%] 2.9 6 1 4 1 2 1 - 3 3 1 1 - -
[60 °C] behavior, high viscosity, very good adhesion

2.0–15.0
Laromer® UA 9073 Aromatic - 2.0 9 2 3 2 2 Flexible and tough with high viscosity 1 2 1 1 1 1 1 3
[60 °C]

High elasticity, excellent PVC adhesion and


Laromer® UA 9089 Aliphatic - 10.0–30.0 2.0 3 2 3 2 2 1 2 1 1 1 1 1 1
weathering resistance, low yellowing

Excellent scratch resistance, high reactivity, very


high chemical resistance, weathering-resistant,
Laromer UA 9136
®
NEW Aliphatic HDDA [20%] 3.0–6.0 7.0 17 4 1 3 4 1 - - 3 - - - -
good adhesion to various plastic and inorganic
substrates

1 Low 2 Medium 3 Good 4 Excellent 1 Notified


2 Please contact your local sales representative for further information
3F  or further regulatory information, please contact ED-PSR@basf.com
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90 Radiation-curable systems
 2019
Radiation-curable systems
 2019 91

Laromer® unsaturated polyesters


and UV specialties

Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Unsaturated polyesters
Unsaturated
Laromer® UP 35 D DPGDA [45%] 3.0–6.0 3.5 11 2 3 2 3 Good adhesion and good sanding properties 1 2 1 1 1 1 1 -
polyester

Unsaturated Good leveling, good adhesion, free of stenomeric


Laromer® UP 9096 GPTA [60%] 5.0–10.0 4.8 26 2 2 2 3 1 2 1 1 1 1 1 1
polyester diluent

Unsaturated Balanced mechanical profile, good sanding and


Laromer® UP 9115 TPGDA [38%] 13.0–19.0 3.5 8 2 3 2 3 1 2 1 1 3 1 3 1
polyester adhesion

Unsaturated DPGDA / TMPTA
Laromer® UP 9118 26.0–31.0 4.5 7 3 1 3 3 Hard, good chemical resistance 1 2 1 1 3 1 1 -
polyester [42%]

Unsaturated Monomer mix


Laromer® UP 9151 NEW 30.0–65.0 - 14 2 2 1 2 Good corrosion resistance on metal 1 - 1 1 3 1 1 1
polyester [42%]

Type of Type of thinner Viscosity at Functionality Hydroxy value Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Hardness Elasticity Reactivity Key properties
resin [content] 23 °C [Pa·s] calculated [mg KOH/g] resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Radiation-curable systems
UV specialties
Adhesion Acidic adhesion promoter; co-binder to increase
Laromer® PA 9083 - 1.2–3.5 1.0 - - - - - 1 2 1 3 1 1 1 1
promoter adhesion on metal and plastic

Inert resin Excellent pigment-wetting properties, low shrink-


Laromer® PR 8985 - 60–80 1.5 25 3 1 1 2 1 2 1 3 - 3 1 1
solution age; more hydrophobic than Laromer® PR 9013

Excellent pigment-wetting properties, low shrink-


Inert resin
Laromer® PR 9013 - 45–70 1.5 25 3 1 1 2 age; less hydrophobic than Laromer® PR 8985, 1 2 1 1 1 1 1 1
solution
good adhesion

Polyester Abrasion-resistant in flooring application (S42,


Laromer® PR 9052 TMPTA [60%] 4.0–8.0 6.0 - 3 1 2 3 1 2 1 1 1 1 1 1
resin S33), hard, scratch-resistant

Aromatic; Excellent pigment wetting, good flow behavior


Laromer® PR 9058 - 3.0–6.0 2.3 170 3 2 3 3 1 2 1 1 3 1 1 1
modified even at high filler content

Polyester Very good scratch and chemical resistance, easy


Laromer® PR 9119 TMPTA [62%] 5.0–8.0 5.5 18 3 1 2 3 1 2 1 1 3 1 1 1
resin to matt

1 Low 2 Medium 3 Good 4 Excellent 1 Notified


2 Please contact your local sales representative for further information
3F  or further regulatory information, please contact ED-PSR@basf.com
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92 Radiation-curable systems
 2019
Radiation-curable systems
 2019 93

Laromer® UV monomers

Viscosity Molecular
Density APHA color Europe Japan China Canada Korea USA Australia Philippines
Product Chemical name Structure at 23 °C Stenomeric weight CAS number
[g/cm3] [Pt-Co] REACH ENCS IECSC DSL ECL TSCA AICS PICCS
[mPa·s] [g/mol]

UV monomers

Dipropylene glycol
Laromer® DPGDA ~8 Yes 1.05 242 57472-68-1 Max. 150 1 2 1 1 1 1 1 -
diacrylate

Propoxylated (3.8) glycerol


Laromer® GPTA 70–120 No 1.08 475 52408-84-1 Max. 150 1 2 1 1 1 1 1 1
triacrylate

Laromer® HDDA Hexanediol diacrylate ~6 Yes 1.02 226 13048-33-4 Max. 150 1 2 1 1 1 1 1 1

Laromer® LR 8863 Ethoxylated (3.0) trimethyl


50–100 No 1.10 428 28961-43-5 Max. 100 1 2 1 1 1 1 1 1
(TMPEOTA) propane triacrylate

Radiation-curable systems
Laromer® LR 8887 Trimethylolpropane formal
~ 40 Yes 1.09 200 66492-51-1 Max. 200 1 - 1 1 1 1 1 1
(CTFA) monoacrylate

Laromer® PO 9102 Propoxylated (2.0)


10–20 No 1.01 328 84170-74-1 Max. 200 1 2 1 1 1 1 1 1
(PONPGDA) neopentyl glycol diacrylate

Laromer® POEA Phenoxyethyl acrylate ~8 Yes 1.10 192 48145-04-6 Max. 250 1 - 1 1 1 1 1 1

Ethoxylated (5.0)
Laromer® PPTTA pentaerythritol 130–190 No 1.14 572 51728-26-8 Max. 100 1 2 1 3 1 1 1 1
tetraacrylate

4-t-Butylcyclohexyl
Laromer® TBCH ~9 Yes 0.94 210 84100-23-2 Max. 100 1 2 1 3 1 1 1 -
acrylate

Trimethylolpropane
Laromer® TMPTA ~ 130 Yes 1.10 296 15625-89-5 Max. 150 1 2 1 1 1 1 1 1
triacrylate

Tripropylene glycol
Laromer® TPGDA ~ 11 Yes 1.04 300 42978-66-5 Max. 150 1 2 1 1 1 1 1 1
diacrylate

1 Notified 2 Please contact your local sales 3F


 or further regulatory information, - Currently no notification
representative for further information please contact ED-PSR@basf.com
94 Radiation-curable systems
 2019
Radiation-curable systems
 2019 95

Laromer® water-based UV resins

Solid content Viscosity at Functionality Chemical Europe Japan China Canada Korea USA Australia Philippines
Product Type of resin pH value Hardness Elasticity Reactivity Key properties
[%] 23 °C [Pa·s] calculated resistance REACH ENCS IECSC DSL ECL TSCA AICS PICCS

Water-based UV resins
Polyester acrylate Hard, chemical resistance, good sanding proper-
Laromer® PE 22 Aqua 48–52 0.15–0.5 3.6 4–6 2 2 2 4 1 - 1 3 3 1 - 1
emulsion ties, easy to matt

Polyester acrylate
Laromer® PE 55 Aqua 48–52 0.25–0.65 3.7 4–6 2 3 3 3 Tough, easy to matt, adhesion to PVC 1 2 1 3 3 1 1 1
emulsion

Aliphatic
Good grain enhancement, good chemical and
Laromer® UA 8949 Aqua urethane acrylate 38–42 0.015–0.18 2.7 7–9 2 3 2 4 1 2 3 3 - 1 3 -
weathering resistance
dispersion

Aromatic
Laromer® UA 8983 Aqua urethane acrylate 38–42 0.05–0.3 1.6 6–8 2 4 2 2 Excellent physical drying properties 1 2 - 3 - 1 - 1
dispersion

Aromatic
Laromer® UA 9005 Aqua urethane acrylate 38–42 0.02–0.25 5.2 7–9 4 2 2 4 Excellent scratch and chemical resistance 1 2 3 1 3 1 - 3
dispersion

Aliphatic Excellent adhesion on wood, very flexible, excellent


Laromer® UA 9059 Aqua 68–72 6.0–11.0 2.0 6.5–8.0 1 4 3 1 1 - 3 3 1 1 - -
urethane acrylate coin-test results

Urethane acrylate Good all-round properties, adhesion to PVC, low

Radiation-curable systems
Laromer® UA 9095 Aqua 37–39 0.01–0.5 3.8 7.3–8.3 4 2 2 3 1 - - 3 - 1 - -
dispersion yellowing

Outstanding through curing properties in pigment-


Urethane acrylate
Laromer® UA 9112 Aqua NEW ~ 40 0.01–0.15 3.1 7–8 4 2 4 3 ed coatings, good resistance prior to UV curing, 1 - - - - - - -
dispersion
good adhesion on various substrates

Offers a very high chemical resistance, good


Aliphatic physical drying properties and low yellowing.
Laromer® UA 9134 Aqua NEW urethane acrylate 38–41 0.005–0.35 4.9 7–8 4 2 2 4 Coatings based on Laromer® UA 9134 are very 1 - - 3 - - - -
dispersion suitable where high resistance (e.g. coffee) in clear
or white pigmented systems is required

Very high chemical resistance, good physical dry-


Aliphatic ing properties and free of stenomeric monomers.
Laromer® UA 9135 Aqua NEW urethane acrylate 38–41 0.01–0.6 3.9 7–8.5 4 2 2 4 Coatings based on Laromer® UA 9135 Aqua are 1 - - - - - - -
dispersion very suitable where high resistances e.g. coffee in
clear or white pigmented systems is required

Very fast water release with high resistance


Aliphatic
in clear coatings. Good viscosity stability in
Laromer UA 9147 Aqua
®
NEW urethane acrylate 37–40 0.05–0.5 4.7 7–8 4 2 2 4 1 - - 3 - - - -
formulated coatings. Good compatibility with other
dispersion
dispersions

Aromatic Very fast water release with high resistance in


Laromer® UA 9149 Aqua NEW urethane acrylate 38–41 0.01–0.38 5.0 7–8.5 4 2 4 4 off-white coatings with good physical drying and 1 - 3 3 - 1 - -
dispersion adhesion on melamine substrates

Urethane acrylate Fast-drying dispersion with high wet film transpar-


Laromer® UA 9154 Aqua NEW 35–38 0.05–1.2 2.6 7–8 2 3 4 2 1 - - - - - - -
dispersion ency and good compatibility with other dispersions

1 Low 2 Medium 3 Good 4 Excellent 1 Notified


2 Please contact your local sales representative for further information
3F  or further regulatory information, please contact ED-PSR@basf.com
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Water-based systems
Bitte Kurzversion des Kapiteltitels
We create
We chemistry
create chemistry
that makes
Formulation
eintragen
that coatings
additives
makes coatings
love resins
loveand
resins
additives 9797
and additives

Solvent-based systems
Formulation additives

BASF is a premier provider of formulation additives for the paints and coatings
industry. With a full complement of respected brands and a broad technology base

Bio-based systems
of dispersing agents, wetting agents and surface modifiers, defoamers, and rheology
modifiers, our unique portfolio helps to enable performance-driven products which
meet the latest and most stringent environmental regulations.

Efka® Hydropalat®

Radiation-curable systems
The Efka® brand offers a broad selection of Under the Hydropalat® brand, BASF presents a
dispersing agents, wetting agents and surface selection of substrate wetting, colorant compatibilizing,
modifiers, defoamers, and rheology modifiers for flow control, and slip agents for water-based industrial
non-aqueous formulations. and automotive coatings.

Dispex® and Dispex® Ultra Rheovis®

Providing a range of standard and highly efficient The long-established Rheovis® range comprises
dispersing agents for aqueous systems and for a broad portfolio of synthetic rheology modifiers for
universal pigment concentrates, the Dispex® and aqueous systems, including non-ionic associative
Dispex® Ultra brands portfolio includes polymeric, (HEUR / HMPE), anionic associative (HASE), and
oligomeric, and surfactant-based dispersing agents. non-associative thickener (ASE) technologies.

Formulation additives
Foamaster® and FoamStar®

Offering an outstanding selection of defoamer


technologies for aqueous systems, the familiar
Foamaster® and FoamStar® brands present
products based on mineral oils or native oils
as well as specialty-emulsion defoamers and
organosilicone, silicone-free, and star-polymer-
based defoamers.

Performance additives
98 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 99

Dispersing agents

Solid particles such as pigments and fillers are BASF’s knowledge of pigment chemistry and surface BASF offers a full range of dispersing agents for all prepared that are designed to optimally fit pigment
important components of paints and coatings and treatments combined with our know-how about paints and coatings formulations containing highly and resin chemistry.
need to be dispersed and stabilized well in the dispersing agents and their technology enables us efficient solutions for aqueous, solvent-based, high-​
formulations to assure consistent color, quality, to find optimum solutions for our customers and their solid, or 100% solids systems and for pigment As illustrated, dispersing agents designed with CFRP
and durability. formulation challenges. concentrates. The broad technology portfolio includes consist of two defined blocks that are produced by
Highly specialized additives are needed to wet, polymeric, oligomeric, and surfactant-based dispersing sequential polymerization of monomers or monomer
disperse, and stabilize dry pigment powders in liquid Favored properties agents. mixtures. Typically, a longer stabilizer block is
formulations. Dispersing agents represent an essential synthesized first, which has to be compatible with the
component of most paint and coating formulations. BASF’s dispersing agents product range relevant paint systems. The anchoring block contains
Their specialized function ensures color strength, for water-based systems functional groups which interact strongly with the
gloss, viscosity stability, and prevents sedimentation of pigment surface to allow for efficient and stable
Advanced 
particles. Today, high-quality coatings of high brilliance Low-molecular Oligomeric High-molecular
high-molecular adsorption. For demanding applications like organic
weight dispersants weight
and color strength are characterized by a perfect dispersants (FAME) dispersants
weight pigments, the anchoring block typically contains aminic
dispersants
pigment dispersion, optimal pigment particle size, and Primary particles Aggregates Agglomerates groups, which can optionally be modified further.
long-term stabilization of the dispersed particles in the Dispex® AA Dispex® Ultra PA
Dispex® Ultra FA Dispex® Ultra FA
Favored energy state Dispex® CX Dispex® Ultra PX
formulation.

BASF’s dispersing agents product range A-Block is resin- and solvent-specific


Higher
for solvent-based systems (incl. 100% systems) Compatible with paint system,
e.g. resins and solvents
B-Block is pigment-specific
Anchoring onto pigment
Advanced 
Low-molecular Oligomeric High-molecular
high-molecular Structure of dispersing agents designed with CFRP technology
weight dispersants weight
weight
dispersants (FAME) dispersants
dispersants
BASF recently developed a new dispersant “toolbox”
Dispex® Ultra FA Efka® PA that was developed to formulate a complete set of
Efka FA
®
Efka PX
®
Efka® FA Efka® PU
label-free universal colorants. Universal pigment
concentrates can be used to tint aqueous and
Lower
Especially, the award-winning controlled free radical solvent-based paints and coatings. This is achieved
Particle size
polymerization (CFRP) allows for higher efficiency and with “universal” dispersing additives, which are often
Viscosity Photo stability Strength Opacity broader compatibility, which creates optimal rheology based on low molecular weight or oligomeric type
and improved coloristics. Benefits are outstanding dispersing agents.

Formulation additives
§§ Optimum properties at low particle size viscosity reduction, enhanced gloss, increased color All toolbox products comply with the major ecolabel
§§ Energy required to mill down pigment intensity, and hiding power. standards. Based on innovative new chemistry,
§§ Stabilization required to keep particles apart a combination of amine- and acid-functional
Efka® PX and Dispex® Ultra PX grades are very polymers was found that provides universal affinity
Dry pigments Need for dispersion, whereby optimum properties of a pigment are achieved
versatile and powerful product groups for sol- to pigment surfaces (FAME technology). With this
at low particle size vent-based and aqueous applications, respectively. set of dispersants it is possible to formulate inorganic
Although non-controlled free-radical polymerization pigments at high pigment loading while also achieving
can lead to good dispersing agents, polymers with excellent results with organic pigments and carbon
Key benefits for your formulation a highly defined architecture can be more efficient, blacks. The products carry no, or only mild, labeling,
resulting in improved colorant stability and broader which allows the formulator their use in label-free
§§ Shorter dispersion time §§ Improved tone development system compatibilities. colorant formulations at a maximum concentration of 10%,
§§ Enhanced gloss §§ Prevention of flooding and floating This exact degree of control in polymer synthesis is provided no other components with similar labeling are
created by the award-winning controlled free radical used.
§§ Increased color strength and hiding power §§ Prevention of flocculation
polymerization (CFRP) technology. It enables the
§§ Reduced viscosities §§ Prevention of settling of pigments and fillers precise design of polymer structures. With the CFRP For all dispersing additives BASF experts have worked
technology, well-defined block copolymers can be out guide formulas for a variety of pigments in order to
support formulators and developers.
100 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 101

Wetting agents and surface modifiers

Wetting agents and surface modifiers are essential BASF Formulation Additives offers a broad portfolio Fluorinated polyacrylates are a very versatile class of Fluorinated polyacrylate
components of modern paints and coatings. They of wetting agents and surface modifiers for water-​ interfacially active additives. They are widely used in at the liquid / air interface
provide a formulation with adequate wetting properties, based and solvent-based systems based on various the coating industry as flow and leveling agents. Pure
enhance different component compatibility, and chemistries. polyacrylate copolymers are highly appreciated for their Illustration of fluorinated polyacrylate at the liquid / air
improve the surface of a coating. Our broad portfolio flow performance, although they do not significantly interface. The block copolymer arrangement makes
of wetting agents and surface modifiers offers highly reduce the surface tension of a formulation. However, maximum use of the fluorinated side chains.
effective products for almost every paint and coating Product a straight polyacrylate cannot solve problems like
Chemistry Characteristics
range
system. cratering, poor substrate wetting, and other problems
Most coating systems need good flow and leveling related to surface tension. Fluorinated polyacrylates
in order to have a smooth appearance. A flat and Alkoxylated Low-foaming substrate wetting
have been developed as a result. These polyacrylates
even surface will give a higher gloss and is therefore Hydropalat® with fluorinated side chains can lower the surface
surfactant agents for waterborne applications
eye-catching. As shown, wetting agents and surface tension of a formulation. They combine excellent flow
modifiers can have a strong influence on coating and leveling with anti-cratering and good wetting
properties like substrate wetting, slip, flow, and leveling. behavior.
Substrate wetting agents with
Efka® Silicone
generally very low static surface
Hydropalat® surfactants In comparison to organo-modified silicones and
tension
Controlling coating effects straight polyacrylates, fluorocarbon-modified
polyacrylates have clear advantages with respect
Several coating effects such as substrate wetting, flow to flow, substrate wetting, and fish-eye resistance. Statistical copolymer
and leveling, surface slip, and defoaming are controlled Cost-effective substrate wetting On the other hand, polysiloxanes can provide
Hydropalat® Sulfosuccinates agents with excellent dynamic
by wetting agents and surface modifiers. strong surface slip and anti-blocking effects and
surface tension reduction Fluorinated side chains
reduce surface tension.
Defoaming / deairation Slip / hydrophobization Leveling The newest generation of fluorinated acrylates are
block copolymers with fluorinated side chains. These
High-performance acrylate unique products are made via controlled free radical
Efka® (Fluorinated)
leveling agents for waterborne
Hydropalat® polyacrylates
and solvent-based applications polymerization (CFRP), which allows the synthesis of
block copolymer structures and to concentrate the
Coating Flow fluorinated side chains in one polymer block only.
Such an arrangement makes best use of the
Defoaming wetting agents based on
Star-shaped fluorinated side chains and guarantees maximum Polyacrylate backbone

Formulation additives
Hydropalat® star-shaped polymers for excellent
Substrate wetting polymers effectiveness with respect to substrate wetting and
dynamic surface tension reduction
anti-cratering behavior.
Substrate Block copolymer
102 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 103

Defoamers

For paint manufacturers and applicators, foam control All defoamers are characterized by a certain balance BASF Formulation Additives offers a broad selection A very special defoaming technology is our award-
is one of the major tasks to ensure a smooth and even between compatibility and incompatibility in a given of defoamer technologies to the paint and coatings winning FoamStar® series. The FoamStar® polymer
appearance of the paint film. Thus, high-performing system. On the one hand, the active ingredient in the market. The portfolio ranges from standard mineral is a hyper-branched polymer with a 3D star-shaped
defoamers are needed to prevent the formation of defoamer must be almost insoluble in the paint oil defoamer technologies to aqueous emulsion structure, containing hydrophilic as well as hydrophobic
bubbles in liquid paints. They reduce foam and avoid formulation. A defoamer must form small defoamer defoamers and up to our innovative FoamStar® elements.
foam formation during the production, application, droplets which are able to migrate into the foam technology. Unlike conventional mineral oil and silicone defoamers,
and transport of paint formulations. lamellae. In order to ensure long-term defoaming Today, most defoamers are sophisticated formulations the FoamStar® molecule defoams on a molecular level.
Especially in industrial surroundings, foam is a very efficiency the defoamer droplets have to be stable designed to fit together with paint and coating formula- It acts as a unique surfactant interacting with the
undesirable phenomenon that can emerge during in the system and should not dissolve upon storage. tions in the best possible way. Usually the formulations foam-stabilizing surfactants and destabilizes the foam
dispersing processes, pumping, stirring operations, are based on raw materials with a low surface tension bubbles. When combined with conventional defoamer
or while applying paints. This foam can, for example, On the other hand, no surface defects such as craters such as silicone, mineral oils, fatty acids, and fluorocar- types it yields faster bubble-break times and improves
increase the production time, create difficulties in filling should be generated in the final paint film due to bons. the overall efficiency. Bubble-break time is the time in
vessels, reduce the efficiency of many high-speed defoamer incompatibility. The defoamer must therefore seconds needed to break all macro bubbles in a paint
operations, and promote surface defects like craters, be sufficiently compatible with the binder. Thus, every film; the shorter the time the better the defoamer.
fish eyes, pinholes, and weak points in the dried film. defoamer is formulated on a tightrope between
compatibility and targeted incompatibility.
In order to explain the working mechanism of
defoamers, there is no single overarching defoamer Product range Chemistry Characteristics
theory in the scientific literature. However, for aqueous
systems all theories have some explanations and
prerequisites in common. It is generally accepted that
Foamaster®
a defoamer active should:
MO Mineral oil Macro foam, universal
§§ Possess a “controlled incompatibility” with the
formulation to be defoamed. This “controlled NO Natural oil Renewable, low S-VOC
incompatibility” must remain even after long-term FDA, better odor,
WO White oil
storage low fogging
§§ Have a low surface tension
FoamStar®
§§ Exhibit a de-wetting effect
Universal, easy

Formulation additives
§§ Have the capability to penetrate into the foam ED Emulsion defoamers
to incorporate
lamellae and to spread effectively on the liquid / 
High efficiency,
gas interface PB Polymer-based
no silicone

Silicone-based High gloss, industrial,


SI
defoamers printing inks

Star polymer-based High efficiency,


ST
defoamers fast foam knock down

Efka®
Polymer-based High efficiency,
PB
defoamers no silicone

Silicone-based High efficiency,


SI
defoamers high gloss
The FoamStar® star-shaped polymer
104 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 105

Rheology modifiers

Rheological modifiers are key ingredients in paints and Rheology modifiers from BASF reduce dripping and BASF offers nearly all commercially used classes of characteristic properties. The table below highlights
coatings as they help control the coating application spattering of paint during roller or brush application. synthetic rheology modifiers for water-based paints the benefits and areas of use of each product class.
and the final appearance. Without these special Sag resistance of paint is improved by a rapid but and coatings. Each product class has its own
additives, such media would be as “runny” as water. controlled viscosity increase after application.
During application, paints would spatter in all During transport and storage of the paint, rheology
directions, have little hiding power, and exhibit a modifiers prevent sedimentation of the pigments Polyurethanes, polyethers Acrylics
Property / influence on
much shorter shelf life. Rheology modifiers enable within a formulation. Rheology modifiers ensure (Rheovis® PU, Rheovis® PE) (Rheovis® AS, Rheovis® HS)
formulators to adjust the flow behavior of paints and that the end product achieves the desired balance
Low shear viscosity Medium contribution High contribution
coatings. That way, painters benefit from improved between consistency, durability, and good application
viscosity and application characteristics. properties. High contribution (high film thickness by roller /
High shear viscosity Low contribution, less impact on film thickness
brush application)
Viscosity [mPa·s] Spattering Improves spattering Low effect
105
Storage
104 Gloss Low to no effect Matting effect possible
10 3

Sag, leveling Influence of surfactants Low to high, must be tested in each case Hardly any (AS), moderate (HS)
102
Stirring
10 Painting Low to no tendency to syneresis
Syneresis Tendency to syneresis
depending on type
1
0.01 0.1 1 102 103 104
Good to moderate effect
Scrub and wash resistance Very good effect
depending on type
Brookfield Stormer ICI Shear rate [s-1]
Controlled stress rheometer

Viscosity profile and shear rates at different application scenarios including corresponding measurement equipment
Especially our Rheovis® PU and PE series of The rheological behavior of aqueous paints and
associative thickeners represent a class of coatings can be rendered either more Newtonian
BASF offers six classes of The naming of our products corresponds ground-breaking materials based primarily on hydro- (brush, roll-on, curtain coating) or more pseudoplastic
rheology modifiers for paints to their chemical composition and shear phobically modified polyether and polyurethane (sprayable) in nature to ensure optimized application
and coatings profile derivatives. properties.
With these rheology modifiers, it is possible to create

Formulation additives
§§ Alkali swellable emulsions (ASE) a wide variety of rheological profiles, imparting superb
Rheology modifiers
§§ Hydrophobically modified alkali swellable emulsions attributes to a broad range of water-based paints and
(HASE) coatings.
Rheovis® HS 1xxx Associative acrylic (HASE)
§§ Hydrophobically modified polyurethanes (HEUR)
Rheovis® AS 1xxx Non-associative acrylic (ASE)
§§ Hydrophobically modified polyethers (HMPE) Key benefits for your formulation
§§ Attapulgites (inorganic rheology modifiers) Rheovis® PE 1xxx Associative polyether (HMPE) §§ Broad rheology profile §§ Low impact on water uptake
§§ Castor oil and wax-based thixotropes §§ Highly efficient across many resin types §§ Low impact on water whitening
Rheovis® PU 1xxx Associative polyurethane (HEUR)
§§ pH-independent §§ Excellent leveling
Attagel® Organoclay types §§ Improved wash and scrub resistance §§ Reduced spattering

Efka® RM 1xxx Rheology modifiers for solvent-based

11xx = low shear 12xx = mid shear 13xx = high shear 19xx = solids
106 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 107

Rheovis® rheology modifiers

Recommended Recommended for


Viscosity VOC content Furniture
Product name Description Solids [%] for low-VOC Tin-free Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[mPa·s] [%] and flooring
paints* systems systems systems

Rheology modifiers designed to be used in water-based systems


Non-associative pure acrylic thickener; highly efficient
low-shear thickener; high shear thinning, anti-sagging, and
Non-associative thickener: anionic
Rheovis® AS 1130 30 ~5 < 0.005 1 1 1 - - anti-settling; used in pigment and filler slurries but also 1 1 1
polyacrylate copolymer (ASE)
highly successful in industrial and automotive formulations
for spray applications

Associative thickener: anionic Acrylic thickener with associative thickening; thixotropic


Rheovis® HS 1162 polyacrylate copolymer, 35 < 50 < 0.005 1 1 1 - - flow behavior; low water uptake; no impact on wet adhesion 1 - 1
hydrophobically modified (HASE) even after long water contact

Associative thickener: anionic Acrylic thickener with associative thickening; low-shear


Rheovis® HS 1169 polyacrylate copolymer, 30 < 50 < 0.1 1 1 1 - - thickener; spray applications; less water uptake; elongation 1 1 -
hydrophobically modified (HASE) of open time

Associative thickener: anionic Acrylic thickener with associative thickening; mid-shear


Rheovis® HS 1212 polyacrylate copolymer, 40 ~5 < 0.5 1 1 1 - - thickener; improves flow; excellent efficiency; all-round - - 1
hydrophobically modified (HASE) product which can be used in most paint systems

Acrylic thickener with pronounced high-shear behavior


Associative thickener: anionic
for many aqueous paint and coating systems; excellent
Rheovis® HS 1303 EB NEW polyacrylate copolymer, 25 < 50 < 0.1 1 1 1 - - - - 1
Newtonian flow behavior; especially suited for wood
hydrophobically modified (HASE)
coatings for brush and roller applications

Associative thickener: hydrophobically


Rheovis® PE 1330 30 ~ 4,500 < 0.1 1 1 1 - - Excellent high-shear thickener; imparts excellent flow - 1 1
modified polyether (HMPE)

Associative thickener: hydrophobically Next-generation strong low-shear thickener with excellent


Rheovis® PU 1191 30 ~ 2,800 <1 1 1 1 - - 1 1 -
modified ethoxylated urethane (HEUR) performance and easy handling; strong pseudoplasticity

Associative thickener: hydrophobically Next-generation VOC-free mid-shear rheology modifier with


Rheovis® PU 1291 45 ~ 3,000 < 0.1 1 1 1 - - 1 1 -
modified ethoxylated urethane (HEUR) excellent ICI thickening and easy handling

Associative thickener: hydrophobically Next-generation high-shear thickener; ultra-efficient,


Rheovis® PU 1331 18 ~ 4,500 < 0.1 1 1 1 - - - 1 1
modified ethoxylated urethane (HEUR) best-in-class ICI performance

Formulation additives
All products except Rheovis® PU 1214 and Rheovis® PU 1250 comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
108 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 109

Efka® rheology modifiers

Recommended Recommended for


Viscosity VOC content Furniture
Product name Description Solids [%] for low-VOC Tin-free Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[mPa·s] [%] and flooring
paints* systems systems systems

Rheology modifiers designed to be used in solvent-based systems


Pre-activated polyamide wax thickener; excellent anti-
Efka® RM 1463 Polyamide wax 20 Paste 80 - 1 - 1 - sagging and anti-settling properties for solvent-based - 1 1
industrial, architectural, heavy-duty, and marine coatings

Pre-activated polyamide wax thickener; excellent anti-


sagging and anti-settling properties for solvent-based OEM
Efka RM 1469
®
Polyamide wax 20 Paste 80 - 1 - 1 - 1 1 -
and refinish as well as for wood coatings; minimum effect
on color and gloss

Anti-settling and anti-hard-caking agent for solvent-based


systems; hard paste type of polyethylene wax dispersed
Efka RM 1506
®
Polyamide wax 24 Paste 76 - 1 - 1 - - 1 1
in xylene; well suited for most solvent-based systems in
dipping, spraying, and aerosol applications

Provides excellent sag resistance for non-aqueous


Efka® RM 1900 Modified hydrogenated castor oil 100 Powder < 0.1 - 1 - 1 1 - 1 -
formulations; higher temperature stability

Provides excellent sag resistance for non-aqueous


Efka® RM 1920 Hydrogenated castor oil 100 Powder < 0.1 - 1 - 1 1 - 1 -
formulations; standard thixotropy

Formulation additives
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
110 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 111

FoamStar® defoamers

Recommended Recommended for


VOC content Silicone Furniture
Product name Description Incorporation Dosage [%] Solids for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[%] containing and flooring
systems* systems systems systems

Defoamers designed to be used in water-based systems


High-performance, ultra low SVOC silicone
emulsion defoamer for premium water-based
FoamStar ED 2522
®
Emulsion defoamers Grinding stage / let-down 0.1–1.0 ~ 20 < 0.1 1 1 - - 1 - 1 1
paints, clear coats, and inks; excellent storage
stability; extremely low-SVOC content

Ultra low SVOC, emulsion defoamer for medium


FoamStar® ED 2523 Emulsion defoamers Grinding stage / let-down 0.2 –0.6 ~ 27 < 0.1 1 1 - - 1 - - 1
to high PVC coatings

100%-active-content defoamer for non-


Modified pigmented and low-pigmented aqueous
FoamStar® SI 2210 polydimethylsiloxane-based Grinding stage / let-down 0.1–0.5 100 < 0.5 1 1 - 1 1 coatings and UV-curable systems; provides - 1 1
defoamers a strong spontaneous defoaming effect;
outstanding long-term defoaming persistency

Modified Highly effective defoamer for aqueous pigment


FoamStar® SI 2216 polydimethylsiloxane-based Grinding stage 0.05–1.5 100 < 0.5 1 1 - - 1 concentrates and systems with high surfactant 1 1 -
defoamers content

Modified Highly effective defoamer for aqueous pigment


FoamStar® SI 2240 NEW polydimethylsiloxane-based Grinding stage / let-down 0.1–0.5 100 < 0.1 1 1 - - 1 concentrates and systems with high surfactant - 1 1
defoamers content

Defoamer for water-based coatings and


Modified
pigment concentrates where high-shear
FoamStar SI 2250
®
polydimethylsiloxane-based Grinding stage 0.1–0.3 100 <1 1 1 - - 1 1 1 1
processing or application exists; most effective
defoamers
in the range

Modified Easy to incorporate, high-shear stable defoam-


FoamStar® SI 2280 polydimethylsiloxane-based Grinding stage / let-down 0.1–1.0 100 < 0.5 1 1 - - 1 er; recommended for water-based paints and 1 1 1
defoamers pigment concentrates

Highly effective deaerator and defoamer for


aqueous spray coating applications; effectively
Modified
removes micro-foam from water-based
FoamStar® SI 2299 NEW polydimethylsiloxane-based Grinding stage / let-down 0.1–1.5 100 < 0.1 1 1 - - 1 - 1 1
spray coatings; remains persistent over
defoamers
longer storage periods; offers an outstanding

Formulation additives
combination of effectiveness and compatibility

Remains persistent over longer storage


Star polymer-based
FoamStar® ST 2400 Grinding stage / let-down 0.25–0.5 100 <1 1 1 - - - periods; offers an outstanding combination of 1 - -
defoamers
effectiveness and compatibility

Silicone-based defoamer for high-quality water-


Star polymer-based
FoamStar® ST 2438 Grinding stage / let-down 0.25–0.5 100 < 0.5 1 1 - - 1 based paints, delivering excellent long-term 1 1 1
defoamers
persistency and foam knock down

Silicone-free defoamer, especially suitable


Star polymer-based for aqueous wood, industrial and automotive
FoamStar ST 2454
®
Grinding stage / let-down 0.2–0.7 100 0.5 1 1 - - 1 1 1 -
defoamers coatings; outstanding long-term stability, highly
efficient in PUR emulsions

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
112 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 113

Efka® defoamers

Recommended Recommended for


VOC content Silicone Furniture
Product name Description Incorporation Dosage [%] Solids for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[%] containing and flooring
systems* systems systems systems

Defoamers designed to be used in non-aqueous systems


Solvent-based solution of Silicone-free air-release agent for non-aqueous
Efka® PB 2001 defoaming substances, Before or after processing 0.05–0.5 26 74 - - 1 1 - coatings such as epoxy, polyurethane, or UPE 1 1 -
silicone-free systems

Silicone-free defoamer for broad use in


Solvent-based solution of
solvent-based systems; well suited for clear
Efka PB 2010
®
defoaming substances, Before or after processing 0.1–0.7 - ~ 80 - - 1 1 - 1 1 1
systems due to the improved compatibility
silicone-free
when compared to Efka® PB 2020

Solvent-based solution of Acid-cured and NC-curtain coating systems,


Efka® PB 2020 defoaming substances, Before or after processing 0.1–0.7 - ~ 80 - - 1 1 - unsaturated polyesters and gelcoats; broad use 1 1 1
silicone-free silicone-free defoamer

Solvent-based solution of
Unsaturated polyester, epoxy, and polyurethane
Efka® PB 2720 defoaming substances, Before or after processing 0.1–10.0 - ~ 60 - - 1 1 - - 1 1
systems
silicone-free

Ultra low-VOC defoamer and de-aerator for


high-solid and solvent-free formulations;
Blend of foam-destroying
Efka® PB 2744 Before or after processing 0.2–1.5 100 < 0.1 1 - 1 1 1 excellent efficiency; improves leveling and - 1 -
substances with silicone
imparts surface smoothness; excellent long-
term persistency

Solvent-based solution Silicone-based highly efficient air-release agent


of defoaming substances with excellent compatibility with non-aqueous
Efka® SI 2008 Before or after processing 0.3–1.0 - 99 - - 1 1 1 1 1 -
with modified silicone coatings such as epoxy, polyurethane, or UPE
compounds systems

Solvent-based solution
of defoaming substances Polyurethane curtain coatings and stoving
Efka SI 2022
®
Before or after processing 0.1–1.0 - > 90 - - 1 - 1 - 1 1
with modified silicone enamels
compounds

Solvent-based solution
of defoaming substances Physically drying systems and medium- to
Efka SI 2035
®
End of processing 0.5–1.0 - > 95 - - 1 1 1 - 1 1
with modified silicone long-oil air-drying alkyds

Formulation additives
compounds

Solvent-based solution
of defoaming substances Solvent-based industrial finishes, including
Efka® SI 2040 End of processing 0.1–0.7 - > 95 - - 1 - 1 1 1 1
with modified silicone roller, brush, and airless spray applications
compounds

Solvent-based solution
UV-curing and EBC systems; highly effective
of defoaming substances
Efka SI 2721
®
Before or after processing 0.5–1.0 - > 95 - - - 1 1 defoaming in clear and matted systems; - - 1
with modified silicone
defoaming substances in 2-ethylhexyl acrylate
compounds

Solvent-free solution of
Solvent-free epoxy and polyurethane systems,
defoaming substances
Efka SI 2723
®
Prior to processing 0.5–1.5 - < 25 - - 1 1 1 low odor, high-solid 2-pack systems and - 1 1
with modified silicone
solvent-free radiation-curing systems
compounds

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
114 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 115

Dispex® and Dispex® Ultra


dispersing agents

Recommended Recommended for


Amine number Acid value VOC content Furniture
Product name Description Solids [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[mg KOH/g] [mg KOH/g] [%] and flooring
systems* systems systems systems

Anionic dispersing agents based on polyacrylic acid


Standard dispersing agent for inorganic fillers and pigments;
Ammonium polyacrylate
Dispex® AA 4040 45 - - < 0.1 1 1 - - low polydispersity leading to efficient dispersing properties and 1 - -
(co-)polymer
liquefying effect

Standard dispersing agent for inorganic fillers and pigments;


Sodium polyacrylate
Dispex® AA 4140 43 - - < 0.1 1 1 - - low polydispersity leading to efficient dispersing properties and - - 1
(co-)polymer
liquefying effect

Ammonium polyacrylate For inorganic pigments and extenders; more hydrophobic than
Dispex® CX 4240 40 - - < 0.1 1 1 - - - - 1
(co-)polymer Dispex® AA 4040

Low molecular weight dispersing agents mainly designed for water-based systems, surfactant-like types
Wetting and dispersing agent for aqueous formulations; suitable
Dispex® Ultra FA 4416 Mixture of surfactants 75 - - <2 - 1 - - - 1 -
for organic and inorganic pigments and pigment concentrates

Universal dispersing agent for inorganic fillers and pigments;


Fatty acid modified emulsi- also suitable as codispersing agent with high molecular
Dispex Ultra FA 4420
®
100 35 22 <1 1 1 1 1 - - 1
fier (FAME) weight dispersing agents; will improve compatibility and color
acceptance of universal colorants in base paints

Universal, non-ionic wetting and dispersing agent; powerful


Modified fatty alcohol
Dispex® Ultra FA 4480 80 - - < 0.1 1 1 - - alternative to APEOs; improves gloss development, color 1 1 1
ethoxylate
intensity, and color acceptance

Universal, anionic wetting and dispersing agent; especially


Dispex® Ultra FA 4483 Phosphoric acid ester 30 - 25 < 0.1 1 1 - - 1 1 1
suitable for inorganic pigment concentrates

High molecular weight dispersing agents


Water-based industrial and automotive coatings,
Modified polyacrylate
Dispex® Ultra PA 4550 50 27 - <1 1 1 - - pH-independent, broad compatibility; suitable for making 1 1 -
polymer
resin-containing and resin-free pigment concentrates

High-performance wetting and dispersing agent; specifically

Formulation additives
Dispex® Ultra PX 4275 Copolymer 37.5 - - < 0.5 1 1 - - designed for semi-gloss and high-gloss paint formulations and 1 1 1
pigment concentrates

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
116 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 117

Dispex® Ultra dispersing agents

Recommended Recommended for


Amine number Acid value VOC content Furniture
Product name Description Solids [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[mg KOH/g] [mg KOH/g] [%] and flooring
systems* systems systems systems

High molecular weight dispersing agents


Blend of amine- and Universal wetting and dispersing agent; improves gloss
Dispex® Ultra PX 4525 92 16 33 <1 1 1 - - - 1 1
acid-functional polymers development, color intensity, and color acceptance

VOC-free dispersing agent for water-based systems with


Acrylic block copolymer
benchmark performance in inorganic pigments; excellent overall
made by controlled free
Dispex® Ultra PX 4575 40 32 - < 0.1 1 1 - - performance for organic pigments; broad compatibility towards 1 1 1
radical polymerization
different resin systems; designed for colorants but well suited
(CFRP)
for grinds into primers, gloss, and semi-gloss paints

Acrylic block copolymer


High-end water-based coatings, industrial and automotive; broad
made by controlled free
Dispex Ultra PX 4585
®
50 20 - < 0.1 1 1 - - compatibility with different binder systems; pH-independent; 1 1 1
radical polymerization
suitable for making resin-free pigment concentrates
(CFRP)

Formulation additives
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
118 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 119

Efka® dispersing agents

Recommended Recommended for


Amine number Acid value VOC content Furniture
Product name Description Solids [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[mg KOH/g] [mg KOH/g] [%] and flooring
systems* systems systems systems

Low molecular weight dispersing agents mainly designed for solvent-based systems, conventional types
Surface-active anionic Anti-settling agent for non-aqueous systems; provides good
Efka® FA 4600 35.5 - - 27.5 - - 1 - - 1 -
compounds anti-settling properties in polar systems

Blend of fatty alcohol Anti-settling agent for non-aqueous systems; good anti-settling
Efka® FA 4601 47 - - 16 - - 1 - - 1 -
sulfates properties for medium-polar systems

Hydroxyl functional
Efka® FA 4608 unsaturated modified 100 85 - <1 1 - 1 - Solvent-based systems including low to polar solvents - 1 -
carboxylic acid

Copolymeric wetting and dispersing agent; strong reduction of


Solution of a copolymer
Efka® FA 4609 52 - 50 48 - - 1 1 mill base viscosity; high pigment and filler loading; increased 1 1 1
with acidic groups
hiding power

Solvent-free wetting and dispersing agent; strong reduction of


Copolymer with acidic
Efka® FA 4611 NEW 100 - 129 < 2.5 1 - 1 1 mill base viscosity; high pigment and filler loading; increased 1 1 1
groups
hiding power

Dispersing agent for inorganic pigments; suitable for all types of


Efka® FA 4620 Acidic polyether 100 - 290 < 2.5 - 1 1 1 industrial coatings, especially TiO2; dispersion of extenders and - 1 -
fillers in composite formulations (SMC+BMC)

High molecular weight dispersing agents


Industrial coatings, transportation topcoats; excellent (viscosity
Modified polyacrylate
Efka® PA 4401 50 50 - 50 - - 1 - depression) for industrial colorants (pigment pastes) in 1 - -
polymer
combination with grinding resins such as Laropal® A 81

Modified polyacrylate For industrial colorants (pigment pastes) in combination with


Efka® PA 4403 55 35 - 45 - - 1 - 1 - -
polymer grinding resins such as Laropal® A 81

Modified polyurethane General industrial coatings, wood coatings for stabilization of


Efka® PU 4010 51 6 12 49 - - 1 1 - 1 1
polymer TiO2, and matting agents

Modified polyurethane
Efka® PU 4046 40 19 - 60 - - 1 1 General industrial coatings 1 - 1
polymer

Formulation additives
Modified polyurethane High-quality industrial finishes including automotive OEM and
Efka® PU 4047 35 17 - 65 - - 1 1 - 1 1
polymer refinish

Second generation of
High-quality industrial, automotive, and refinish applications,
Efka® PU 4061 modified polyurethane 30 8 - 70 - - 1 - 1 - -
strong viscosity-depressing properties
polymer

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
120 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 121

Efka® dispersing agents

Recommended Recommended for


Amine number Acid value VOC content Furniture
Product name Description Solids [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
[mg KOH/g] [mg KOH/g] [%] and flooring
systems* systems systems systems

High molecular weight dispersing agents


Polymeric dispersing agent for the deflocculation of inorganic
Modified polyurethane
Efka® PU 4063 45 10 - 55 - - 1 1 and organic pigments in high-quality solvent-based pigment 1 1 1
polymer
pastes

Acrylic block copolymer High-quality solvent-based industrial and automotive coatings;


made by controlled free setting new standards as a dispersing agent for resin-free
Efka PX 4310
®
50 19 - 50 - - 1 - 1 1 -
radical polymerization pigment pastes for coil coatings and dispersing agent for carbon
(CFRP) blacks giving extremely high jetness

Acrylic block copolymer


Solvent-based industrial coatings; excellent (broad compatibility)
made by controlled free
Efka PX 4330
®
70 28 - 30 - - 1 - for industrial colorants (pigment pastes) in combination with - 1 1
radical polymerization
grinding resins such as Laropal® A 81
(CFRP)

Acrylic block copolymer


Solvent-based high-end applications, industrial, automotive
made by controlled free
Efka® PX 4340 55 4 - 45 - - 1 - systems; good performance in CAB-modified systems but also 1 - -
radical polymerization
with 2-pack PUR and 2-pack epoxies
(CFRP)

Acrylic block copolymer Highly efficient dispersing agent for ß- and ε-blue
made by controlled free Cu-phthalocyanine pigments and pigment green; high gloss
Efka PX 4350
®
51 12 - 49 - - 1 - 1 1 -
radical polymerization due to excellent compatibility; for high-quality solvent-based
(CFRP) industrial and automotive coatings

Acrylic block copolymer


Dispersing agent for high-performance pigments especially
made by controlled free
Efka PX 4701
®
100 40 - < 2.5 - - 1 1 for energy-curable systems; especially for UV inkjets; also for - 1 1
radical polymerization
solvent-based applications, both mild-solvent and strong-solvent
(CFRP)

Acrylic block copolymer


Solvent-free dispersing agent well suited for solvent-based
made by controlled free
Efka® PX 4703 NEW 100 56 - < 2.6 1 - 1 1 resin-free (RFPC) and resin-containing pigment concentrates - 1 1
radical polymerization
(RCPC) in a wide range of applications
(CFRP)

Dispersing agent for high-quality solvent-based industrial and


automotive coatings; suitable for high-performance organic
Efka® PX 4753 NEW Advanced polymer 51 12 - 49

Formulation additives
- - 1 - 1 1 1
pigments incl. α-blue Cu-phthalocyanine pigments; high gloss
due to excellent compatibility; tin-free

Highly efficient dispersing agent for organic pigments and


carbon-blacks; creates lower pigment paste viscosities at very
Efka® PX 4780 NEW Advanced polymer 100 20 - < 2.5 1 - 1 1 low levels of addition; suitable for industrial and automotive 1 1 1
coatings especially where a resin-matrix reactive dispersant is
desired

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
122 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 123

Hydropalat® wetting agents


and surface modifiers

Recommended Recommended for


Silicone Furniture
Product name Description Dosage [%] Solids [%] VOC content [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
containing and flooring
systems* systems systems systems

Substrate wetting agents


Low-foaming wetting agent for aqueous
Hydropalat® WE 3120 Alkoxylated surfactants 0.5–5.0 > 99.5 < 0.5 1 1 - - - formulations; excellent reduction of dynamic 1 1 1
surface tension

Non-volatile low-foaming wetting agent for


Hydropalat® WE 3197 Alkoxylated surfactants 0.5–5.0 > 97 <3 1 1 - - - aqueous formulations; excellent substrate 1 1 1
wetting

Silicone surfactant with strong reduction of


surface tension in aqueous formulations;
Hydropalat WE 3220
®
Silicone surfactants 0.1–0.5 87.5 12.5 - 1 - 1 1 1 1 1
excellent substrate and anti-crater additive with
good recoatability

Silicone surfactant in dipropylene glycol


monomethyl ether with strong reduction of
Hydropalat® WE 3221 Silicone surfactants 0.2–1.0 45 55 - 1 - - 1 surface tension in aqueous formulations; 1 1 1
excellent substrate and anti-crater additive with
good recoatability

Non-ionic wetting agent for aqueous


Hydropalat® WE 3322 Star-shaped polymers 0.1–1.0 100 <3 1 1 - - - formulations with pronounced defoaming 1 1 1
characteristics; excellent anti-cratering additive

Fluorocarbon-modified polyacrylate; excellent


substrate wetting, leveling, and anti-cratering;
Hydropalat® WE 3370 Fluorinated polyacrylates 0.5–1.5 60 < 10 - 1 - - - 1 1 1
problem solver in water-based systems, against
sissing and has pronounced effect on leveling

Highly efficient sulfosuccinate wetting agent;


Hydropalat® WE 3475 Sulfosuccinates 0.1–1.0 75 ~6 - 1 - - - strong reduction of dynamic surface tension; - - 1
standard product used in overprint varnishes

Excellent surface-leveling and substrate-


wetting agent; avoids side effects like cratering,
Hydropalat WE 3500
®
Fluorinated polyacrylates 0.1–0.75 60 < 20 - 1 - - - 1 1 1
foam stabilization, and effects on intercoat
adhesion

Formulation additives
Highly effective, low-foaming, substrate-wetting
Hydropalat® WE 3650 Modified alkoxylates 0.5–2.0 > 96 < 0.5 1 1 - - - 1 1 1
agent for water-based coatings

Non-ionic wetting agent for aqueous


formulations with excellent wetting and
Hydropalat® WE 3694 Alkoxylated surfactants 0.2–2.0 > 85 < 15 1 1 - - - 1 1 1
emulsification properties; low foaming and low
surface tension

Slip and leveling agents


Aqueous dispersion of an ultra-high Strong slip and anti-blocking additive for
Hydropalat® SL 3682 0.05–2.0 65 <1 1 1 - - 1 - 1 1
molecular weight silicone aqueous systems; good compatibility properties

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
124 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 125

Efka® wetting agents


and surface modifiers

Recommended Recommended for


Silicone Furniture
Product name Description Dosage [%] Solids [%] VOC content [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
containing and flooring
systems* systems systems systems

Flow and leveling agents


Silicone- and solvent-free flow and leveling
Efka® FL 3740 Copolyacrylates 0.2–1.0 > 95 < 0.5 1 - 1 1 - agent with air-release properties for non- 1 - -
aqueous coatings

Silicone- and solvent-free flow and leveling


Efka® FL 3741 Copolyacrylates 0.2–1.0 > 95 < 0.5 1 - 1 1 - agent with air-release properties; excellent - 1 1
compatibility

Fluorocarbon-modified polyacrylate; leveling


Efka® FL 3772 Fluorinated polyacrylates 0.5–2.0 60 40 - 1 1 - - and anti-cratering; can be used in both water- - 1 1
and solvent-based systems

Fluorocarbon-modified polyacrylate; solvent-


based systems, coil coatings, OEM, and
Efka® FL 3777 Fluorinated polyacrylates 0.5–2.0 70 30 - - 1 - - 1 1 -
industrial coatings; excellent combination of
low foam, substrate wetting, and leveling

Acrylic polymer; solvent-based systems,


coil coatings, OEM, and industrial coatings;
Efka FL 3778
®
Copolyacrylates 0.5–2.0 70 30 - - 1 1 - 1 1 -
excellent combination of low foam, substrate
wetting, and leveling

Formulation additives
All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
126 Formulation additives
We create chemistry that makes coatings love resins and additives
Formulation additives
We create chemistry that makes coatings love resins and additives 127

Efka® wetting agents


and surface modifiers

Recommended Recommended for


Silicone Furniture
Product name Description Dosage [%] Solids [%] VOC content [%] for low-VOC Water-based Solvent-based Solvent-free Features and benefits Automotive Industrial
containing and flooring
systems* systems systems systems

Slip and leveling agents


Organically modified polysiloxane; improved slip
Efka® SL 3030 Modified polysiloxanes 0.1–0.3 52 48 - 1 1 - 1 1 1 1
and mar resistance, very compatible

Organically modified polysiloxane; solvent-


Efka® SL 3031 Modified polysiloxanes 0.1–0.3 52 48 - - 1 - 1 based metal, wood, and paper coatings - 1 1
including UV-cured

Organically modified polysiloxane; improved


Efka® SL 3033 Modified polysiloxanes 0.1–1.0 15 85 - - 1 1 1 surface flow, excellent compatibility in clear 1 1 1
coats

Fluorocarbon-modified polysiloxane; strong


Efka® SL 3034 Modified polysiloxanes 0.05–0.2 52 48 - 1 1 - 1 1 1 1
substrate wetting and anti-cratering

Organically modified polysiloxane; solvent-


Efka® SL 3035 Modified polysiloxanes 0.1–0.5 52 48 - 1 1 - 1 and water-based coatings, stoving enamels, 1 1 1
unsaturated PE including UV-cured

Broad spectrum and efficient flow and slip


Efka® SL 3210 Modified polysiloxanes 0.1–0.3 100 <1 1 1 1 1 1 - - 1
enhancer; economic solutions

Solvent-free modified polysiloxane; solvent-


Efka® SL 3236 Modified polysiloxanes 0.04–0.4 100 <1 1 - 1 1 1 based wood finishes, industrial coatings, and 1 1 1
solvent-free floor coatings

Solvent-free modified polysiloxane; similar


Efka® SL 3239 Modified polysiloxanes 0.05–0.5 100 <1 1 - 1 1 1 to Efka® SL 3236 but stronger defoaming 1 1 -
properties

Highly effective solvent-free slip additive and


Efka® SL 3258 Modified polysiloxanes 0.05–1.0 > 95 < 0.5 1 1 1 1 1 leveling agent for non-aqueous coatings and - 1 1
UV systems

Organically modified polysiloxane; strong slip


Efka® SL 3299 Modified polysiloxanes 0.05–3.0 100 <1 1 1 1 1 1 and surface smoothness effect for high-gloss 1 1 1
industrial coatings

Formulation additives
Polysiloxane-modified with unsaturated
Efka® SL 3883 Reactive polysiloxanes 0.2–1.0 70 30 - - 1 1 1 terminal groups; UV-curing systems for wood, - - 1
plastic, and paper coatings

All products comply with APEO-free claims. APEO has not been intentionally added. * Recommended for low-VOC paints and coatings if VOC content < 1%. Measurements done according to the EU Ecolabel 2014/312/EU
Product may comprise minor traces as ubiquitously occurring impurities cannot be excluded. for indoor and outdoor paints and varnishes. For products with a VOC level above 15% the value is based on calculation according to recipe.
The data in the product selector table is a first recommendation. Suitability of a product should always be checked in the actual paint, coating, or ink.
Bitte Kurzversion des Kapiteltitels
We create
We chemistry
create chemistry
that makes
Performance
eintragen
that coatings
additives
makes coatings
love resins
loveand
resins
additives 129
129
and additives

Performance additives

Organic coatings and inks with aesthetical, protective, and other functional properties
are exposed to a variety of environmental and artificial factors such as solar radiation,
humidity, temperature change, microbiological attack, air pollutants, and many more.

In order to assure that coatings will maintain their beautiful appearance, we offer the
most comprehensive portfolio of stabilizers and other performance additives: UV
absorbers (UVA) and hindered amine light stabilizers (HALS) for effective stabilization
against the detrimental effects of light and weathering, as well as phenolic and
non-phenolic antioxidants against thermally induced degradation during production,
processing, and service life. The product range is completed with optical brighteners.

Performance additives
130 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 131

Your best choice for light stabilizers


and other performance additives
UVA (UV absorbers) and HALS (hindered amine light stabilizers) products are
available under the brand names Chimassorb®, Tinuvin®, and Lignostab®.

BP UVA based on 2-hydroxy-benzophenone are HALS are mainly derivatives of 2,2,6,6-tetramethyl Tinuvin® DW range Irganox® and Irgafos®
mainly used in applications where low to medium piperidine (TMP). They act as radical scavengers and
protection is required. inhibit the photo-oxidative degradation of polymers. The Tinuvin® DW range is based on aqueous Irganox® and Irgafos® antioxidants (AO) protect
preparations of light stabilizers designed for coatings, plastics, and fibers against thermal
BTZ UVA based on 2-(2-hydroxyphenyl)-benzotriazole water-based coatings and inks. degradation during processing, production, and
show a broader spectral coverage combined with a service life. Irganox® comprises a complete range of
better photopermanence than BP and are used in Tinuvin® blends AO based on sterically hindered phenols or thioethers,
various applications such as plastics, textiles, and as well as blends of different AO classes. Irgafos® are
coatings. They fulfill medium (industrial / architectural /  Tinuvin® 5000 blends are liquids based on synergistic so-called secondary AO process stabilizers based on
wood) to high-end (automotive) protection requirements. combinations of UVA and HALS, thereby combining phosphite chemistry.
easy handling with excellent compatibility and solubility
HPT UVA based on 2-hydroxyphenyl-s-triazine exhibit in most organic solvents, resins, and binder systems. Tinopal®
superior photopermanence and heat stability and a
higher extinction coefficient compared to BTZ and BP. Lignostab® Tinopal® optical brighteners (fluorescent whitening
HPT also show excellent chemical resistance. agents) are designed to brighten coatings or to mask
In contrast to BP and BTZ, mono-resorcinyl-triazines Lignostab® are lignin-stabilizing additives for wood yellowing. Tinopal® can also be used as a marker
do not interact with certain metal ions (e.g. catalysts pretreatment that engender color retention and where fluorescence is employed to detect film voids
or production-related impurities) or with strong alkali. improved durability. or for registration and identification purposes.
HPT is the UVA class of choice for applications
involving high baking temperatures and / or extreme
environmental conditions.

Performance additives
132 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 133

Background of light
and heat stabilization
How UV radiation and heat promote degradation of organic substrates.

Light- or heat-induced oxidation of organic materials Photo-oxidation in the presence of light and oxygen Mechanism of light and / or thermally induced oxidation
is a complex radical process involving initiation, is the prevailing mechanism under interior and ambient
propagation, chain branching, and autocatalytic conditions. The main consequence is discoloration
1 3 4
chain and termination reactions. Both initiation steps of the substrate (i.e. yellowing) or fading of colorants h·ѵ R•
generate free radicals (R•) to enter this cyclic process. (e.g. in wall paints or inks). Under exterior weathering CH CH* O2

conditions – water being the decisive factor – ∆T ROO •


P-H P-H
The predominant initiation mechanism under normal photo-oxidation leads to photodegradation resulting CH POO •
2 P•
service life conditions of polymers is light-induced in additional surface defects of the coating including RO • + • OH
PO • + • OH
oxidation, so-called photo-oxidation. The initiation loss of gloss, cracking, chalking, etc. 6
reaction is photolysis whereby a chromophore ROOH 5 P-H
POOH
CH (= UV-absorbing molecule or moiety) absorbs Heat exposure such as that encountered during
radiation energy (h•ѵ). The absorbed energy leads to processing steps like synthesis, mixing, extrusion,
the formation of an excited state CH* (higher energy curing, or during the high-temperature-baking CH = chromophore = UV-absorbing molecule R• = free radicals P-H = polymer
level). CH* molecules are highly reactive and can cycles of coatings is the main cause of yellowing,
subsequently form free radicals (R•) through hemolytic embrittlement, or loss of other mechanical properties
bond cleavage . Under high temperature conditions such as tensile strength in organic substrates. In order
heat can accelerate the oxidation – so-called thermal to protect organic substrates against harmful UV Overview of existing light and heat stabilizer technologies
oxidation – through radical breakdown reactions radiation and subsequent photo-oxidation followed
and initiate the formation of free radicals (R•). This by photo-degradation, the use of appropriate light
Mode of Usage Protects Protects
heat-induced initiation step can occur during high- stabilizers such as UV absorbers (UVA) and free-radical Product class
action area
Prevents
what? against
Chemical classes
temperature processing, production, and service life. scavengers such as hindered amine light stabilizers
(HALS) is necessary. UV absorbers filter out harmful Deeper
Photo-
The free radicals (R•) generated during photo- and UV light, thereby protecting the resin, the substrate UV coating Yellowing, 2-hydroxyphenyl-benzophenones (BP),
Converts UV Interior / oxidation
thermal oxidation can subsequently react with oxygen underneath, and the colorants in coatings and inks absorbers layers, blistering, 2-(2-hydroxyphenyl)-benzotriazoles (BTZ),
light into heat exterior and
(UVA) substrate loss of adhesion 2-hydroxyphenyl-s-triazines (HPT)
(O2) to form peroxy radicals (ROO•) 4 , which can against color changes. HALS trap free radicals once degradation
underneath
further attack the polymer (P-H) whereby unstable they are formed and are effective in preventing surface
hydroperoxides (ROOH) 5 are formed. These defects such as loss of gloss, cracking, and chalking. Surface
hydroperoxides fragment due to UV radiation and /  While HALS are, technically speaking, a distinct class defects, loss
Coating
Hindered amine of mechanical
or heat and form additional free radicals 6 . As the of antioxidant or free-radical scavenger, the term Deactivation Photo- surface,
light stabilizers Exterior properties, loss Tetramethyl piperidine derivatives
process continues, more and more molecular bonds antioxidant or AO generally refers to additives that are of free radicals degradation pigments
(HALS) of water
in coatings
break – a process that is autocatalytic in nature and primarily used as heat stabilizers. Today, the most Radical impermeability,
is known as autoxidation. commonly used AOs are based on sterically hindered scavengers pigment fading
phenol, thioether, or phosphite chemistries. Yellowing,
Sterically hindered phenols,
Deactivation Interior / Thermal embrittlement,
Antioxidants Coating phosphites,
of free radicals exterior oxidation loss of mechanical
thioethers
properties

Performance additives
134 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 135

UV absorbers

Tinuvin® and Chimassorb® UV absorbers (UVA) prevent the degradation of both The required concentration of UVA Mode of action of 2-(2-hydroxyphenyl)-
coatings and substrates by filtering out harmful UV radiation during the photolysis for effective protection depends on benzotriazole (BTZ) and
the dry film thickness of the coating 2-hydroxyphenyl-s-triazine (HPT) UV
cycle before subsequent photo-oxidation can take place. and the absorption coefficient of the absorbers
choosen UVA

UVA concentration based on


Dry film thickness 1 2
binder solids (% w/w)
Today, 2-hydroxyphenyl-benzophenones (BP), According to the Lambert Beer law, the absorbance A, HO R 1
H-O - R1
+
N h·ѵ N
2-(2-hydroxyphenyl)-benzotriazoles (BTZ), and i.e. the filter effect of a coating, is in linear relationship 10–20 µm 8–4 BTZ N N
2-hydroxyphenyl-s-triazines (HPT) are the most widely to the UVA concentration (c), the film thickness (= light N ΔT
R3 R3 N
used UVA for coatings and inks. UV absorbers work by path length d), and the extinction coefficient ε. Thus R 1
R2
R1
R2

converting absorbed light energy (h•ѵ) into heat. First the Lambert Beer law allows the amount of UVA
the UVA chromophore CH absorbs radiation energy needed for proper light protection to be calculated for 20–40 µm 4–2 -
HO O
(h•ѵ) and becomes an energy-enriched excited-state a given film thickness d. Increased c or d results in HPT h·ѵ
H +
R2 N N R2 R2 N N R2
CH*, which causes an electronic rearrangement, e.g. increased filter effect and therefore increased protection ΔT
N N
a reversible intramolecular proton transfer. The CH* against harmful UV radiation. In addition, the law also
40–80 µm 2–1 R3 R3 R3
is then deactivated by a radiationless release of heat infers that the filter effect is strongly influenced by R3

energy (ΔT) and reverts to its original form (ground coating thickness; the thinner the coating, the more
state). UVA are necessary. Hence UVA on their own are
insufficient for protecting the surface of a coating itself
The main criteria for selecting UVA are their specific (where thickness d approaches 0). It follows, then, that General structures of 2-hydroxyphenyl-benzophenone (BP), 2-(2-hydroxyphenyl)-
photo-physical (primary) and physical (secondary) UVA cannot effectively prevent the formation of surface benzotriazole (BTZ), and 2-hydroxyphenyl-s-triazine (HPT) UV absorbers
properties. Photo-physical properties of UVA are defects resulting from photo-degradation under exterior
absorbance A (= measure of the filter effect of a UVA conditions. For exterior conditions the combination of
at a certain wavelength) and the extinction coefficient UVA and HALS creates synergistic effects producing R1

ε, which is a molecule-specific constant that indicates excellent protection against surface defects and H
O O HO R1
the efficiency of the filter effect of a chromophore. The discoloration. For interior conditions, the use of UVA HO
N
absorbance A is a direct measure of the filter effect and alone is normally sufficient for preventing both the N R2 N N R2
is in inverse logarithmic relation to the transmittance T colorant fading of coatings and inks as well as the R1 R
3 N N
R2
(= amount of light penetrating through a coating /  yellowing of resins. R3 R3
plastic). The absorbance A and the transmittance T ​ BP BTZ HPT
of UVA depend both on the chemical class and the Photo-permanence (i.e. physical / chemical loss of UVA
molecular weight. The UV absorption spectra of during service life) and heat stability (i.e. low volatility)
Tinuvin® UV absorbers and of blends thereof, as well are basic requirements for UVA efficacy in the final
of the Chimassorb® UVA are shown on pages application.
140 / 141. Lambert Beer law

Transmittance T decreases exponentially,


absorbance A increases directly proportional to 1
T

Performance additives
§§ Chromophore concentration c
§§ Light path length or film thickness d
§§ Extinction coefficient ε
136 Performance additives
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Performance additives
We create chemistry that makes coatings love resins and additives 137

UV-VIS absorbance spectra


of UV absorbers
2-(2-hydroxyphenyl)-benzotriazole (BTZ) 2-hydroxyphenyl-s-triazine (HPT)

1.50 2.5
Spectra were recorded with 1.0 Spectra were recorded with
20 mg/l in toluene, path = 1 cm 20 mg/l in toluene, path = 1 cm
1.25 Spectra were recorded with
20 mg/l in toluene, path = 1 cm 1.6 2.0
0.8 Spectra were recorded with
1.00 20 mg/l in toluene, path = 1 cm
1.2 1.5

Absorbance [AU]
Absorbance [AU]
Absorbance [AU]

Absorbance [AU]

0.6
0.75

0.8 1.0
0.4
0.50

0.4 0.5
0.25 0.2

0 0
0 0
290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430
Wavelength [nm] Wavelength [nm] Wavelength [nm] Wavelength [nm]

Tinuvin® 326 Tinuvin® Carboprotect® Tinuvin® 900 Tinuvin® 384-2 Tinuvin® 928 Tinuvin® 400 Tinuvin® 405 Tinuvin® 460 Tinuvin® 477 Tinuvin® 479

2-hydroxy-benzophenone (BP) 2-(2-hydroxyphenyl)-benzotriazole (BTZ) Tinuvin® 5000 series

1.0 1.0
1.5 1.5
Spectra were recorded with Spectra were recorded with Spectra were recorded with Spectra were recorded with
20 mg/l in toluene, path = 1 cm 20 mg/l in toluene, path = 1 cm 40 mg/l in toluene, path = 1 cm 40 mg/l in toluene, path = 1 cm
1.25 1.25
0.8 0.8

1.0 1.0

Absorbance [AU]
Absorbance [AU]

Absorbance [AU]
Absorbance [AU]

0.6 0.6

0.75 0.75

0.4 0.4
0.5 0.5

0.2 0.2 0.25 0.25

0 0
0 0
290 310 330 350 370 390 410 430 290 310 330 350 370 390 410 430
290 310 330 350 370 390 410 430 280 300 320 340 360 380 400
Wavelength [nm] Wavelength [nm]
Wavelength [nm] Wavelength [nm]

Performance additives
Chimassorb® 81 Tinuvin® 171 Tinuvin® 99-2 Tinuvin® 1130 Tinuvin® 5248 Tinuvin® 5251 Tinuvin® 5050 Tinuvin® 5060 Tinuvin® 5151
138 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 139

Tinuvin® DW (N) Optical brighteners

The Tinuvin® DW (N) range is based on aqueous preparations of light stabilizers Tinopal® fluorescent optical brighteners (OB) are designed to brighten or enhance
designed for all water-based applications. Based on novel encapsulated additive the appearance of coatings, adhesives, and sealants by producing a perceived
technology (NEAT), Tinuvin® DW (N) has low viscosity, is solvent-free, storage- and “whitening” effect and also serve to mask yellowing.
sedimentation-stable, and has no EUH 208 label.
1.00
Tinopal® NFW Liquid

0.80

Tinuvin® DW (N) comprises a range of selected BTZ This allows to add them at the end of the production Tinopal®
and HPT UVA as well as HALS preparations. These process under normal stirring conditions without

Rel. intensity
0.60

light stabilizer preparations are based on a proprietary specific equipment and / or dispersing aids, e.g. Tinopal® can also be used where fluorescence can
encapsulation technique where active agents are emulsifiers or cosolvent. provide a mean to determine film thickness, and 0.40
essentially dissolved in an acrylic copolymer matrix. After being incorporated into the liquid paint they for registration and identification purposes, e.g.
The NEAT-based preparations exhibit excellent do not impair paint properties and storage stability. in adhesives and sealants as a fluorescent tracer 0.20
long-term storage stability without any sedimentation The Tinuvin® DW (N) range fully maintains dry film in in-line assurance inspections. OB are dyes that
or phase separation in their delivery form. The absence properties such as inherent color, gloss, and trans­ work by re-emitting light through the mechanism 0
of EUH 208 label and of co-solvents make them the parency. Other properties such as water permeability of fluorescence. They absorb light in the ultraviolet 275 325 375 425 475 525 575 625
Wavelength [nm]
ideal choice for low to zero VOC applications. They are and blocking resistance, hardness, and scratch region of the electromagnetic spectrum (usually
Fluorescence min / max Absorption min / max
easy to incorporate and homogeneously disperse into resistance are not affected. 340–370 nm), and emit light in the blue region
1.00
water and / or water-based paints. (typically 420–470 nm). Tinopal® OB CO

0.80
The Tinopal® range is available in a powder form that
is soluble in solvent or water and as a solution for
direct use in various applications. Due to the limited 0.60

Rel. intensity
Tinuvin® 5000 series photostability of optical brighteners, which can result
in yellowish degradation products, their use for 0.40

exterior applications is not recommended.


0.20

The Tinuvin® 5000 series and other Tinuvin® blends offer synergistic combinations 1.00 0
Tinopal® SFP
of UVA and HALS against surface defects while also maintaining color and gloss 275 325 375 425 475 525 575 625
Wavelength [nm]
retention in coating applications. 0.80 Fluorescence min / max Absorption min / max

1.00
Tinopal® SFP
Rel. intensity
0.60
The Tinuvin® 5000 series is attractive for its combination them particularly suitable for coatings exposed to high 0.80
of easy handling with its excellent compatibility and baking temperatures and / or extreme environmental
0.40
solubility in most solvent-based coating systems. conditions. Furthermore, they are not sensitive

Rel. intensity
0.60
The Tinuvin® 5000 family matches all performance to high pH and certain metal ions, i.e. there is no
requirements for architectural, industrial, and formation of colored complexes. Blends containing 0.20 0.40
automotive applications. The broad UV absorbance N-OR HALS are especially suitable for oxidative curing

Performance additives
of BTZ-based blends makes them suitable for a and acid-catalyzed systems. The non-basic character 0.20
0
wide range of coatings on wood, plastic, and metal prevents potential interactions with acidic paint
275 325 375 425 475 525 575 625
substrates. HPT-based blends show high thermal ingredients such as catalysts, biocides, and pigments. Wavelength [nm] 0
stability and superior photopermanence, which makes 275 325 375 425 475 525 575 625
Fluorescence min / max Absorption min / max Wavelength [nm]

Fluorescence min / max Absorption min / max


140 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 141

Hindered Amine Light Stabilizers


(HALS)
Typical HALS structures Influence of HALS basicity vs.
Hindered amine light stabilizers (HALS) are mainly derivatives of 2,2,6,6-tetramethyl N-substituent
piperidine (TMP). They act as radical scavengers in the autoxidation cycle and inhibit
the photo-oxidative degradation of polymers.
R3
R N H pkb ~ 4–5 Tinuvin® 770 DF
HN

N N
R1 N O (CH2)8 O N R1 R2
N R
2
N N R N CH3 pkb ~ 5–6 Tinuvin® 292
The mode of action of HALS is largely independent surfactants, catalysts, or certain acid-treated pigments, O O
of the applied film thickness, which in turn means which can result in limited formulation stability
that they can also act at the coating surface where or the deactivation of HALS or of other additives. N N
R N (CH2)2 OR pkb ~ 7–8 Tinuvin® 622 SF
only minor protection is provided by a UVA (see Furthermore, basic HALS can interfere with the R 1
R1
Lambert Beer law). In clear coats they protect against curing process of acid-catalyzed or oxidation-based A B
surface defects such as loss of gloss or cracking, curing systems. Because non-basic N-OR HALS do
whereas in pigmented coatings they prevent chalking not interact, they are the products of choice for all R N OR pkb ~ 8–10 Tinuvin® 123
Tinuvin® 152
and discoloration. Such surface defects eventually applications where traditional basic HALS fail. Typical structures of hindered amine light stabilizers (HALS) Tinuvin® 249
lead to substrate erosion due to increased water A: linked by diester; B: linked by triazine ring
Tinuvin® 5100
permeability and the loss of physical and protective The usage amount of UVA and HALS strongly
properties. Today, a large variety of HALS utilizing depends on the concentration of pigments (acting as
mono-, di-, or oligo-functional TMP are available; their UV screeners) and the final thickness of the coating.
wide range of physical and chemical properties enable Clear coatings require higher amounts of UVA
Denisov cycle
them to fulfill the multiple requirements of the coatings (and lower dose levels of HALS) whereas opaque
and plastics industries. pigmented coatings require higher amounts of HALS
(and lower UVA dose levels). Typical usage amounts
1 2 R• 3
According to the “Denisov cycle” the mode of action are listed in the table below. The usage amount of UVA
of HALS is a cyclic regenerative process. In the in pigmented coatings depends on the pigments used.
h·ѵ, O2
presence of oxygen (O2) and UV radiation (h•ѵ), the The lightfastness or weather stability of some organic N R N O• N OR
HALS compound is converted into the corresponding pigments can be improved by addition of UVA,
nitroxyl radical NO• as an active species that traps free whereas for inorganic pigments the use of UVA can be
RO• radicals through the formation of an aminoether dispensed with. R'OH + R=O R'OO •
N-OR structure. N-OR interacts with ROO• forming
intermediates, which then decompose into harmless
Typical UVA and HALS use levels
decomposition products, thereby reforming the active
species NO•. The cyclic nature of the stabilization Mode of action of hindered amine light stabilizers (HALS)
according to the Denisov cycle
process along with the regeneration of the active
Pigmentation Active UVA [%]1 Active HALS [%]2
species explains the high and long-term efficiency
of HALS.
Clear 1–2 1
Besides solubility and compatibility, the first selection
criteria for HALS is their basicity. The basicity of
HALS is governed by the substitution pattern on the Semi-transparent 1–2 1–2
piperidine nitrogen: H or alkyl-substituted HALS are

Performance additives
basic, whereas aminoether-(N-OR)-functionalized
HALS are considered as non-basic. Basic HALS Opaque 0–1 1–2
are highly efficient and long-term stable; they can,
however, undergo acid / base interactions with certain 1
% active UVA on binder solids (DFT ~ 40 µm)
formulation components such as biocides, 2
% active HALS on binder solids (does not depend on DFT)
142 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 143

Antioxidants (AO)
AO structures

AO prevent thermally induced oxidation of polymers in coatings during heat exposure, Hindered phenol AO Phosphite AO Thioether AO

processing, and curing or baking at high temperatures, as well as during their service R2
OH
R1
R2
S(R)2
life. Irganox® and Irgafos® denote different primary sterically hindered phenolic AO R3 O P(R)3-x

and secondary thioether or phosphite AO, respectively. R3 R1 x

Mechanism of AO
Unlike HALS, AO are a non-regenerative reaction Hindered phenol AO
mechanism, which in turn means that both primary and Hindered phenol AO
§§ activity over broad temperature range (RT to melt)
secondary AO are essentially consumed and rendered
ineffective after reaction. Conversely, HALS are usually §§ improve long-term thermal stability OH O• O O O
R2 R1 R2 R1 R2 R1 R2 R1 R2 R1
not effective in preventing thermal degradation but do §§ non-regenerative mechanism, consumption during + ROO· + ROO·
have the advantage that the regenerative nature of reaction • - ROR3
HALS allows them to function over much longer time R3 R 3
OOR O
R3 R3
p-Benzoquinone
scales. This makes them well suited as light stabilizers,
although some oligo-functional HALS can also Phosphite AO
be effective heat stabilizers under long-term and Phosphite AO Thioether AO
§§ phosphites are processing stabilizers
moderately low heat exposure conditions.
§§ stable against hydrolysis R2
R 2

Primary AO such as the sterically hindered phenols §§ no colored reaction products R3 O P + ROOH R3 O P=O + ROH S(R)2 + ROOH (R)2S=O + ROH
deactivate free radicals (RO•) formed during thermal
R1 3 R1 3
oxidation and interrupt breakdown reactions via a
kinetic mechanism. Primary AO work by donating Thioether AO
hydrogen atoms to preferably oxygen-centered radicals
§§ thiosynergists “like it hot”
(RO•, ROO•), thereby interrupting the autoxidation
§§ rate of ROOH decomposition increases with ΔT Effective use temperatures for the different classes of stabilizers
process. Phenolic AO are multipurpose products for
a broad temperature range and are mainly used to §§ designed to protect against high-temperature aging Long-term thermal stability (LTTS) Melt processing stability
increase the long-term thermal stability of various
coatings or plastics.
Oligomeric HALS Hindered amines
Secondary phosphite AO decompose peroxides
§§ HALS with AO properties
(ROOH) formed during the autoxidation process
§§ work up to 120 °C Thiosynergists
and extend the performance of primary AO through
synergistic effects. §§ stable against light, migration, and extraction
Today, hydrolytically stable phosphites and divalent Hindered phenols
§§ regenerative mechanism in contrast to AO
sulfur compounds are the most widely used secondary
AO. Applications include heat stabilization during Phosphites
synthesis, processing, mixing, extrusion, and curing
of coatings that are baked or cured at relatively high
0 50 100 150 200 250 300

Performance additives
temperatures (e.g. coil coatings and powder coatings).
°C
Solid Melt
144 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 145

Tinuvin® UV absorbers for water-based


and solvent-based coatings

Molecular Automotive and Furniture


Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications
weight [g/mol] transportation and flooring

Water-based UV absorbers
Tinuvin® 400-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture 1 1 1 1 Blue-shifted UVA for water-based high-performance applications, excellent spectral coverage in combination with Tinuvin® 479-DW

Tinuvin® 477-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture - 1 1 1 Red-shifted UVA for high-performance water-based wood coatings

UVA with extremely high extinction coefficient, for highest durability requirements in water-based clear coats, specifically suited for thin
Tinuvin® 479-DW (N) Hydroxyphenyltriazine Liquid 20% active - Mixture 1 1 - 1
film applications

Tinuvin® 1130 Benzotriazole Liquid - Mixture 1 1 1 1 UVA for medium-performance solvent-based and water-based coatings (may require addition of cosolvent)

Tinuvin® 9945-DW (N) Benzotriazole Liquid 45% active - Mixture - 1 1 1 Multipurpose UVA for medium to high durability requirements for water-based formulations

Solvent-based UV absorbers
Benzophenone (BP)
Chimassorb® 81 (ED) Benzophenone Solid 47–51 326 - 1 1 1 UVA for moderate durability requirements; mass stabilization of gel coats
Benzotriazole (BTZ)
Tinuvin® 99-2 Benzotriazole Liquid 95% in MPA** - 452 - 1 1 1 UVA for medium-performance solvent-based coatings

Tinuvin® 326 Benzotriazole Solid 138–142 316 - 1 1 1 Chlorinated red-shifted UVA, allows < 1% transmittance up to 370 nm; limited solubility in organic solvents

Tinuvin® 384-2 Benzotriazole Liquid 95% in MPA** - 452 1 1 - - Multipurpose UVA for medium to high durability requirements, minimum color impact in refinish clear coat applications

Tinuvin 900
®
Benzotriazole Solid 138–142 448 1 1 - - UVA for medium to high durability requirements in powder and coil coating applications, limited solubility in organic solvents

Tinuvin 928
®
Benzotriazole Solid 109–113 442 1 1 - - UVA for medium to high durability requirements in powder and coil coating applications, excellent solubility in organic solvents

Tinuvin® 1130 Benzotriazole Liquid - Mixture 1 1 1 1 UVA for medium-performance solvent-based and water-based coatings (may require addition of cosolvent)

Very red-shifted UVA for protection of aromatic epoxy systems, especially recommended for carbon or glass fiber reinforced composites;
Tinuvin® Carboprotect® Benzotriazole Solid 132–136 560 1 1 - -
allows < 1% transmittance up to 420 nm
Tris-ResorcinylTriazine (TRT), high photo- and thermal-permanence
Tinuvin® 460 Tris-Resorcinyltriazine Solid 97–101 630 - 1 - - Red-shifted UVA with extremely high extinction coefficient, allows ~ 1% transmittance up to 370 nm, limited solubility in organic solvents

Tinuvin® 477 Tris-Resorcinyltriazine Liquid 80% in MPA** - Mixture - 1 1 1 Red-shifted UVA with high extinction coefficient, for high durability wood coating requirements, allows < 1% transmittance up to 370 nm
HydroxyPhenylTriazine (HPT), best photo- and thermal-permanence, no interaction with amines, strong alkali, or any metal catalysts
Liquid 85% in Blue-shifted UVA for high durability requirements in clear coat applications including UV-curing systems, excellent spectral coverage in
Tinuvin® 400 Hydroxyphenyltriazine - 647 1 1 1 1
1-methoxypropan-2-ol combination with Tinuvin® 479

Tinuvin® 405 Hydroxyphenyltriazine Solid 73–77 584 1 1 - - Blue-shifted UVA for high durability requirements in powder clear coats, excellent spectral coverage in combination with Tinuvin® 479

UVA with extremely high extinction coefficient, for highest durability requirements in clear coats, powder coatings, or UV-curing systems,
Tinuvin® 479 Hydroxyphenyltriazine Solid 39–43* 678 1 1 1 1
specifically suited for thin film applications

Performance additives
* Tg [°C]
** 1-methoxy-2-propyl acetate
146 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 147

Tinuvin® HALS for water-based


and solvent-based coatings

Molecular Automotive and Furniture


Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications
weight [g/mol] transportation and flooring

Non-basic HALS for water-based coatings


Tinuvin® 123-DW (N) N-OR HALS Liquid 30% active - - 1 1 1 1 Non-basic HALS for waterborne formulations, no interaction with sensitive dispersions

Basic HALS for water-based coatings


Multipurpose basic HALS for various applications, use in water-based coatings may require addition of cosolvents, may interact with
Tinuvin® 292 N-alkyl HALS Liquid - 509 / 370 1 1 1 1
sensitive dispersion binders

Multipurpose basic HALS for color-sensitive applications such as refinish coatings, use in water-based coatings may require addition of
Tinuvin® 292 HP N-alkyl HALS Liquid - 509 / 370 1 - - -
cosolvents, may interact with sensitive dispersion binders

Basic HALS for solvent-based coatings


Tinuvin® 111 FDL N-alkyl / N-R HALS Solid - - - 1 - - HALS blend for powder-coating applications with triboelectric charging activity

Multipurpose basic HALS for various applications, use in water-based coatings may require addition of cosolvents, may interact with
Tinuvin® 292 N-alkyl HALS Liquid - 509 / 370 1 1 1 1
sensitive dispersion binders

Multipurpose basic HALS for color-sensitive applications such as refinish coatings, use in water-based coatings may require addition of
Tinuvin® 292 HP N-alkyl HALS Liquid - 509 / 370 1 - - -
cosolvents, may interact with sensitive dispersion binders

Tinuvin® 770 DF (ED) N-H HALS Solid 81–85 480 - 1 - - HALS suitable for powder-coating applications

Non-basic HALS for solvent-based coatings


Tinuvin® 123 N-OR HALS Liquid - 737 1 1 1 - Non-basic HALS for acid-catalyzed and oxidative curing coatings, improves yellowing resistance in direct-fired gas ovens

Tinuvin® 152 N-OR HALS Solid 72–76 757 1 1 - - Non-migrating, reactable low basic HALS for polar solvent-based coatings over plastic substrates (e.g. polycarbonate, ABS substrate)

Non-basic HALS, no exudation from solvent-based polar coatings, low viscosity and very low inherent color; use in water-based coatings
Tinuvin® 249 Non-basic HALS Liquid - 482 1 1 1 -
may require addition of cosolvents

Tinuvin® 622 SF Oligomeric N-R HALS Solid - 3,100–4,000 - 1 - - Low-basic HALS for powder-coating applications with very good antioxidant properties, limited solubility in organic solvents

Tinuvin® 5100 N-OR HALS Liquid - 737 - 1 1 1 Non-basic HALS for oxidative curing coatings

Molecular Automotive and Furniture


Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications
weight [g/mol] transportation and flooring

HALS for wood color protection


Lignostab® 1198 Lignin stabilizer Solid 66–70 172 - - 1 1 Lignin stabilizer for wood impregnation

Lignostab 1198 L
®
Lignin stabilizer Liquid 20% in water - 172 - - 1 1 Lignin stabilizer solution for wood impregnation

Performance additives
148 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 149

Tinuvin® light stabilizer blends

Molecular Automotive and Furniture


Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications
weight [g/mol] transportation and flooring

Light stabilizer blends


Tinuvin® 111 FDL N-alkyl / N-R HALS Solid - - - 1 - - HALS blend for powder-coating applications with triboelectric charging activity

Tinuvin® 5050 BTZ / N-alkyl HALS Liquid - Mixture - 1 1 1 UVA / HALS blend for solvent-based applications

Tinuvin 5060
®
BTZ / N-OR HALS Liquid - Mixture - 1 1 1 UVA / non-basic HALS blend for solvent-based oxidative curing coatings

Tinuvin 5151
®
BTZ / N-alkyl HALS Liquid - Mixture 1 1 1 1 UVA / HALS blend for solvent-based coatings, use in water-based coatings may require addition of cosolvent

Tinuvin® 5248 HPT / N-alkyl HALS Liquid - Mixture 1 1 - 1 UVA / HALS blend for high-performance solvent-based applications

Tinuvin® 5251 HPT / N-alkyl HALS Liquid - Mixture 1 1 - 1 UVA / HALS blend for high-performance solvent-based applications

Tinuvin® 5333-DW (N) UVA / HALS Liquid 40% active - - - 1 1 1 High-performance UVA / non-basic HALS blend for water-based applications with broad spectral coverage

Tinuvin B 75 (ED)
®
AO / N-alkyl HALS / UVA Liquid - Mixture - - 1 - Stabilizer blend for furniture and flooring applications

Performance additives
150 Performance additives
We create chemistry that makes coatings love resins and additives
Performance additives
We create chemistry that makes coatings love resins and additives 151

Irgafos® and Irganox® antioxidants


and Tinopal® optical brighteners

Molecular Automotive and Furniture and


Product Chemistry Physical form Melting point [°C] Industrial Architectural Key properties and applications
weight [g/mol] transportation flooring

Hindered phenolic (primary antioxidants)


Irganox® 245 (ED) Phenol Solid 76–79 587 1 1 - - AO for solvent-based and powder-coating applications

Irganox® 245-DW Phenol Liquid 40% active - 587 - 1 - - AO for water-based coating applications

Irganox 1010 (ED)


®
Phenol Solid 110–125 1,178 1 1 - - AO for solvent-based and powder-coating applications, not to be used in direct fired gas ovens

Irganox 1035
®
Phenol Solid 63–78 643 - 1 - - AO for solvent-based coating applications

Irganox® 1076 (ED) Phenol Solid 50–55 531 1 1 - - AO for solvent-based and powder-coating applications

Irganox® 1135 Phenol Liquid - 390 1 1 - - AO for all solvent-based applications

Irganox® 1425 Calcium phosphonate Solid > 260 695 - 1 - - Stabilizer for synthesis of polyester resins

Phosphite (secondary antioxidants)


Irgafos® 126 (ED) Phosphite Solid 160–175 604 1 1 - - AO for solvent-based and powder-coating applications, prevents yellowing in direct gas fired ovens

Irgafos® 168 (ED) Phosphite Solid 183–186 647 1 1 - - AO for solvent-based and powder-coating applications, prevents yellowing in direct gas fired ovens

Thioether (secondary antioxidant)


Irganox® PS 802 Thioether Solid 50–55 683 - 1 - - Thiosynergist suitable when high-temperature aging is required, needs combination with primary AO

Antioxidant blends
Irganox® B 225 (ED) Phenol / phosphite Solid > 100 - - 1 - - AO blend for powder-coating applications

Irganox B 900
®
Phenol / phosphite Solid 59–61 - 1 1 - - AO blend for powder-coating applications

Optical brighteners
Tinopal® NFW LIQ Biphenyl-stilbene Liquid 20% active - 563 - 1 - 1 Liquid optical brightener for water-based white and pastel-tone paints, clear coats, overprint varnishes

Tinopal® OB CO Benzoxazole Solid 196–203 431 - 1 - 1 Solid optical brightener for solvent-based white and pastel-tone paints, clear coats, overprint varnishes

Tinopal SFP
®
Triazine-stilbene Solid - 1,305 - 1 - 1 Water-soluble optical brightener for photographic color developer baths or as fluorescent tracers

Performance additives
Contacts
Contact
Worldwide
Europe, Africa, West Asia
BASF Nederland B.V.
Asia North America
Resins & Additives
BASF (China) Co., Ltd. BASF Corporation
Innovatielaan
No. 1
300, Jiangxinsha Road, 24710 West Eleven Mile Road
8466 SN Shanghai
Pudong, Nijehaske200137 Southfield, Mi 48034
P.O. China
P.R. Box 390 USA
8440 AJ Heerenveen
The Netherlands
Phone: +86-21-2039-5213 US and Canada:
dispersions-asiapacific@basf.com Phone: +1-800-231-7868
Tel.: +31 51 3619-619 dpsolutions@basf.com
Fax: +31 51 3619-600
Mexico:
resins@basf.com Phone: +52-55-5325-2600
contactoed@basf.com

Europe, Africa, West Asia South America

BASF SE BASF S.A.


Resins & Additives Av. das Nações Unidas 14171,
E-EDE/R – J550 Cond. Rochavera
67056 Ludwigshafen T. Crystal
Germany 04794-000 São Paulo, SP
Brazil
resins@basf.com
Phone: +55-11-2039-2735-2735

BASF SE

67056 Ludwigshafen
Germany
www.basf.com/resins

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.

®= Registered trademark of the BASF Group


® = registered trademark of the BASF Group
Res022019PSG
EDC 0115e

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