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What is Zeise’s salt ? Discuss the structure and
bonding of Zeise’s salt ?
by BY P GHOSH on August 16, 2019 in HOME, INORGANIC, What is Zeise’s salt ? Discuss the structure and bonding of Zeise’s salt
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What Is Zeise’s Salt ? Discuss The Structure And Bonding  Of Zeise’s  Salt  ?

Platinum (Pt ) , a  4d transition metal, which forms  a large number of organo- metallic
compounds . Zeise’s salt is one of them. The salts containing the ion  [ C2H4PtCl3] -1 are
known as Zeise’s salt after the name of discover such salts may be K[C2H4PtCl3],
Na[C2H4PtCl3] , NH4[C2H4PtCl3] etc.
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Borazine or Borazole preparation

and its reactivity

What is Zeise’s salt ? Discuss the

structure and bonding of Zeise’s
?

Inductive effect and ퟷ�eld effect in

organic chemistry

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Lattice energy, Born-Lande equation

and Born-Haber cycle .

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Preparation of Zeise’s salt :   HOME

 ORGANIC
When platinum tetra chloride is react with ethanol an adduct is formed , which react with
 INORGANIC
KCl gives Zeise’s salt. The following two method for preparation of Zeise’s salt are shown
below,  CHEMISTRY IN MEDICINE

4

 5-DIMETHYL 4-NITRO ANILINE IS STRONGER BASE THAN 2

 6 TRI-NITRO PHENOL IS CALLED PICRIC ACID ?

 6-DIMETHYL 4-NITRO ANILINE AND O-CRESOL IS MORE

ACIDIC THAN 2

 6-DIMETHYL PHENOL?

 6-TRI-NITRO PHENOL MORE ACIDIC THAN PHENOL .

 ACTINIDE CONTRACTION-DEFINITION-CAUSES-
CONSEQUENCES IN CHEMISTRY

 BENZENE TO BENZOIC ACID-GATTERMANN-KOCH

REACTION

 BENZOIC ACID-BOILING POINT-STRENGTH-MORE ACIDIC

THAN ACETIC ACID.

 BORAZINE OR BORAZOLE PREPARATION AND ITS

REACTIVITY

 BORON NITRIDE PREPARATION USE AND COMPAIR WITH

GRAPHITE.
The nature of bonding in such oleퟷ�nic compound like Zeise’s salt is still imperfectly
understood, but it is clear that localized σ-bond between the metal atoms and carbon do not  CALCULATE THE NUMBER OF UNPAIRED ELECTRONS AND
LFSE OF [ CR( NH3)6 ]+3 ION .
exist.
 CALCULATE THE NUMBER OF UNPAIRED ELECTRONS AND
LFSE OF [PTCL6 ]–2 ION .
The is generally attributed to the interaction between π-electrons in the unsaturated
 CHELATE COMPLEX-DEFINITION-EXAMPLES-CHELATING
molecule and the hybrid orbitals of metal atom.  AND Π-ACID LIGAND’S .

 CHELATING EFFECT-EAN RULE-APPLICATION OF EAN RULE

Several oleퟷ�n complexes have been studied by X-ray diffraction method.
 CHEMICAL BONDING-DEFINITION-EXAMPLES AND
IMPORTANCE IN CHEMISTRY
In complexes such as [C2H4PtCl2]2 and [(C2H4)2RhCl]2 the coordinated double bond is
 CO-ORDINATE COVALENT BOND-DEFINITION-EXAMPLES-
normal to the coordination plane and similar in the case for [ C2H4PtCl3] -1 ion. FORMATION CONDITIONS.

 COMPLEX COMPOUNDS-DEFINITION-EXAMPLES-PERFECT-
IMPERFECT COMPLEX DEFINITION.

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 CONFORMATIONAL AND CONFIGURATIONAL ISOMERISM.

 COVALENT BOND-DEFINITION-EXAMPLES-FORMATION
ENERGY AND TYPES

 CR(CO)6 AND MN(CO) 6 +1 ARE REDUCED FROM THE

EXPECTED VALUE ?

 DEFINE FINKELSTEIN REACTION WITH EXAMPLES AND

STEREO CHEMISTRY OF FINKELSTEIN REACTIONS .

 DEFINITION OF MUTAROTATION AND HOW IT DEPENDS ON

TEMPERATURE

 DIBORANE PREPARATION AND ITS BONDING

 DITTE’S REACTION-APPLICATION-DEACON’S PROCESS IN

The bonding in Zeise’s salt can be explained by the molecular orbital (M.O) approach. The HALOGEN CHEMISTRY

theory assumes that the metal to oleퟷ�n bond consists of two parts.  GEOMETRICAL OR CIS-TRANS ISOMERISM AND
PROPERTIES OF GEOMETRICAL ISOMERISM.

(I)overlap of the π-electron density of the oleퟷ�n with a σ-type acceptor orbital on the metal  HALOGEN ELEMENTS-DEFINITION-PROPERTIES-
REACTIVITY AND USES.
atom. 
 HOMOTOPIC DIASTEREOTOPIC AND ENANTIOTOPIC.

 HOW STERIC INHIBITION OF RESONANCE INFLUENCE BOND

LENGTH

 HYDROGEN BOND AND ITS IMPORTANCE IN LIFE

 INORGANIC HOW WE DETERMINED FE +3 ION

COLOURIMETRICALLY ?

 INDUCTIVE EFFECT AND FIELD EFFECT IN ORGANIC

CHEMISTRY

 INERT PAIR EFFECT-DEFINITION-EXAMPLES-CAUSE AND

CONSEQUENCES

 IONIC BOND-DEFINITION-EXAMPLE-PROPERTIES AND

FORMATION CONDITION .

 LIGANDS-DEFINITION-EXAMPLES-TYPES IN CO-
ORDINATION CHEMISTRY .

 MORE STABLE STATES OF CU IS +2 WHILE THAT OF AU IS

 (II)A back bonding resulting from ៹�ow of electron density from ퟷ�lled metal dπ orbital  into +3 -EXPLAIN WHY?
antibonding vacant orbitals of C-atom .
 OPTICAL ISOMERISM ENANTIOMERS DIASTEREOMERS
AND OPTICAL ACTIVITY OF DISSYMMETRIC MOLECULE.

 PARACETAMOL-PARACETAMOL USED FOR-PARACETAMOL

SIDE EFFECTS AND PARACETAMOL MADE OF.

 PERICYCLIC REACTIONS-CYCLO ADDITION AND DIELS

ALDER REACTIONS .

 PHENOL IS ACIDIC IN NATURE-PHENOL TO SALICYLIC ACID

AND BENZENE CHANGE .

 PHENOL IS ACIDIC OR BASIC AND WHICH IS STRONGER

ACID PHENOL OR CRESOL ?

 PHYSICAL

 POLARIZABILITY-POLARIZING POWER-APPLICATION OF
FAJAN’S RULE

This view is similar to bonding in carbonyls , but some how different from that and this is  Q. WHAT IS LATTICE ENERGY ?

known a µ-bonding.  RACEMIC MODIFICATION AND EPIMERISATION

 SCHOTTEN BAUMANN REACTION-MECHANISM-

APPLICATION-SCHOTTEN BAUMANN REACTION-PHENOL-
Why the C –C oleퟷ�nic bond length in Zeise’s salt is greater than the C –C  bond in free ANILINE.
hydrocarbon ?
 SCHRODINGER WAVE EQUATION AND ITS SIGNIFICANCE.

 In Zeise’s salt back bonding also takes place from suitable ퟷ�lled metal dπ orbital into the  SIMPLE OR ROTATIONAL AXIS OF SYMMETRY PLANE OF
vacant antibonding π*orbital on the carbon atom. In the free C2H4 molecule, the   C –C bond SYMMETRY AND INVERSION OF CANE SUGAR

order should decrease .  STERIC INHIBITION OF RESONANCE AND ITS INFLUENCE

OF ON ACIDITY AND BASICITY.

As a consequence, the C –C bond length in  Zeise’s salt increases from free C2H4 molecule
 VALENCE BOND THEORY ( V.B.T ).
( 1.34 Å) to coordinated C2H4 molecule (1.4 -1.47 Å) .

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Why the ethylene molecule is perpendicular to the PtCl3 molecular plane in Zeise’s salt ?  WHAT IS ' IPSO SUBSTITUTION' REACTION AND WHAT IS
ELECTROPHILE ?
In Zeise’s salt the metal ion , Pt(II) contains three π-type ퟷ�lled d-orbital which are dxy, dyz,
 WHAT IS DOW PROCESS AND COMPARE THE BOILING
and dxz.  POINT OF ORTHO - META AND PARA DICHLORO BENZENE .

 WHAT IS E1CB REACTION MECHANISM

When the coordinated ethylene molecule lies perpendicular to the molecular plane , the
 WHAT IS GROVE’S PROCESS OR METHOD AND ITS
back bonding may take place either through dyz or dxz ퟷ�lled orbitals , but it may take place MECHANISM ?
only through dxy ퟷ�lled orbital.
 WHAT IS L S D AND ITS USE .

 WHAT IS N-BROMO SUCCINIMIDE OR NBS AND WHAT IS

When C2H4  molecule exists in the plane of the molecule . As a consequence, C2H4 THE USE OF N-BROMO SUCCINIMIDE OR NBS ?
molecule lies lies perpendicular to the PtCl3 molecular plane for better scope of back
 WHAT IS RASCHIG PROCESS AND WHY HALO ARENES CAN
bonding . NOT PREPARED FROM PHENOL ?

 WHAT IS SNI REACTION.

Why Cl – ion trans to the ethylene has the large Pt –Cl bond distance than the other two Pt –Cl
bond distance in Zeise’s salt?   WHAT IS SWARTS REACTION AND WHY NAF IS NOT USED
IN SWARTS REACTION ?
The above  fact can be explained with the help of trans orienting power of ligands. 
 WHAT IS URIC ACID ?

The metal oleퟷ�n bond has multiple bond character due to back bonding and due to this  WHAT IS ZEISE’S SALT ? DISCUSS THE STRUCTURE AND
BONDING OF ZEISE’S SALT ?
multiple bond character (π-bonding effect ) decreases the metal –carbon bond length.
 WHAT IS CARCINOGENICITY ?

As a result, the metal chlorine bond trans to the ethylene molecule weakens, that is, Pt –Cl  WHAT IS CHIRAL OR ASYMMETRIC CARBON ?

bond length increases.   WHAT IS ELIMINATION REACTION

 WHAT IS HYPER-CONJUGATION OR BAKER-NATHAN

But Pt –Cl bond character cis to C2H4 molecule is not affected due to this π-bonding. EFFECT AND ITS STABILITY

 WHAT IS PICRIC ACID AND WHY 2

Therefore , Pt –Cl distance trans to C2H4 is larger than the other two Pt –Cl bond distance .
 WHAT IS RESONANCE ? GIVE SIGNIFICANCE OF
RESONANCE AND RESONANCE ENERGY.
Is  the rotation of C2H4 molecule in Zeise’s salt hampering the stability of the complex ?
 WHAT IS SIGMATROPIC REARRANGEMENT AND WHAT IS
SUPRAFACIAL AND ANTARA FACIAL PROCESS ?
From bonding in Zeise’s salt it can be said that ethylene molecule can either lie on the same
plane to which the PtCl3 unit belongs on lie perpendicular to the plane of the molecule.  WHAT IS THE INCREASING ORDER OF ENERGY OF THE CT
BANDS OF HALIDES OF A METAL ?

 WHAT IS THERMODYNAMICALLY AND KINETICALLY

In each case back bonding is possible . In ퟷ�rst case back bonding takes place through ퟷ�lled CONTROLLED PRODUCT ?
dxy metal orbital and in the second case it may take place either through dyz or dxz metal
 WHICH ONE IS MORE REACTIVE BETWEEN VINYL BROMIDE
orbitals. AND ALLYL BROMIDE IN SN2 REACTION ?

 WHY IONIC BOND IS NON DIRECTIONAL BUT COVALENT

Since in the second case possibility of such back bonding is greater and hence the stability BOND IS DIRECTIONAL ?

is more .
 WHY MANGANESE DOES NOT FORM MONO NUCLEAR
CARBONYL COMPOUND BUT HYDRO DERIVATIVE OF SUCH
CARBONYL IS MONO MERIC – EXPLAIN ?
Experimental measurement has shown that stability difference is of the order of 5 – 6 kcal
per mole , that is, the energy barrier of C2H4 molecule is only 5 – 6 kcal per mole .  WHY 3

So it is clear from the above explanation that free rotation of C2H4 molecule is possible in  WHY CH3CL IS MORE ACTIVE THAN C6H5CL TOWARDS
Zeise’s salt . HYDROLYSIS AND WHAT IS ULMANN REACTION ?

Summary :  WHY CO IS A POOR LEWIS BASE TOWARDS H + BUT IT IS

AN EXCELLENT LEWIS BASE TOWARDS NI AND DEFINITION OF
SYNERGIC EFFECT
What is Zeise’s salt ? Discuss the structure and bonding  of Zeise’s  salt  ?
 Why the C –C ole nic bond length in Zeise’s salt is greater than the C –C  bond in free  WHY [FE(CN)6]4- IS DIAMAGNETIC WHERE AS [FE(H2O)6]+2
IS HIGHLY PARAMAGNETIC ?
hydrocarbon ?
 WHY ACETIC ACID IS MORE ACIDIC THAN PHENOL AND
Why the ethylene molecule is perpendicular to the PtCl3 molecular plane in Zeise’s  salt ? WHY PHENOL ARE MORE ACIDIC THAN ALIPHATIC ALCOHOL ?

Why Cl –  ion trans to the ethylene has the large Pt –Cl bond distance than the other two   WHY BENZYL CHLORIDE IS HIGHLY REACTIVE IN SN1
Pt –Cl bond distance in Zeise’s salt ? REACTION IN SPITE OF PRIMARY ALKYL HALIDE ?

 WHY BOILING POINT OF ALCOHOL IS HIGHER THAN ETHER

Click here :More stable states of Cu is +2 while that of Au is +3 -explain why? AND ALKANE ?

 WHY THE CO STRETCHING FREQUENCY OF METAL

COMPLEXES V(CO)6 -1

Tags # HOME # INORGANIC        WHY THE DIPOLE MOMENT OF CH3F IS LESS THAN CH3CL
ALTHOUGH ‘F’ IS MORE ELECTRONEGATIVE THAN ‘CL’ ?

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Author Image About BY P GHOSH  CHARGE TRANSFER( CT ) OR ELECTRON DONOR
ACCEPTOR( EDA) COMPLEXES AND THEIR PROPERTIES.
Soratemplates is a blogger resources site is a provider of high quality blogger template with premium
looking layout and robust design. The main mission of templatesyard is to provide the best quality  DIPOLE MOMENT BOND MOMENT GROUP MOMENT AND
INFLUENCE OF DIPOLE MOMENT
blogger templates.
 FRIEDEL-CRAFTS ALKYLATION REACTION- FRIEDEL
CRAFTS ALKYLATION OF BENZENE-ANISOLE-PHENOL AND
 NEWER ARTICLE OLDER ARTICLE  CHLORO BENZENE

Uric Acid And Cause Of Uric Acid Why CO Is A Poor Lewis Base Towards H + But It Is An  M.P AND DIPOLE MOMENT OF AN ORGANIC COMPOUND.
Excellent Lewis Base Towards Ni And De nition Of Synergic
 OPTICAL ACTIVITY OF SPIRANS AND BIPHENYL
Effect COMPOUNDS.

 PICRIC ACID OR 2
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NITRO PHENOL IS MORE VOLATILE THAN PARA NITRO PHENOL
?

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and bonding of Zeise’s salt ? WIKIPEDI A

Inductive effect and ퟷ�eld effect in organic

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