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2g

n Na CO = =0.0188 mol
2 3
106 g / mol
n HCl =0.2× V
−¿( Hydrochloricacid dissociation)¿
+¿+Cl(aq) ¿
HC l(aq) + H 2 O(l) → H 3 O(aq)
2−¿( Dissolution∈ aqueous solution) ¿
+¿+CO3 (aq) ¿
Na2 CO 3(s ) → 2 Na(aq )
−¿+ H O ¿
2 (l)
2−¿⇌ H CO3(aq ) ¿
+ ¿+CO 3(aq ) ¿
H 3 O(aq)

CO 2−¿
3
¿
H 3 O+ ¿¿ H CO−¿¿
3

I 0.0188 0.2V 0
C -0.2V -0.2V +0.2V
E 0.0188-0.2V 0 0.2V

Set pH = 10 from the laboratory.


pH= pKa¿

10=−log ( 4.7 ×10¿¿−11)+log ( 0.0188−0.2


0.2 V
V
)¿
Showing complete working

10=10.32+ log ( 0.0188−0.2


0.2V
V
)=−0.32
0.0188−0.2 V
=10−0.32=0.4786
0.2V
Solving gives v = 63.57 mL = 63.6 mL (3 sig figs)

H2O

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