Concrete SDS 2018

INVENTORY OF HAZARDOUS
CHEMICALS FOR SDS BOOKS

Page COMMON NAME, HAZARDOUS CHEMICAL
3 Concrete - 2255 White Concrete Curing Compound

5 Concrete - 3405 Hot applied joint sealer
7 Concrete - ACHRO KURE WB
11 Concrete - ACRY-LOK
13 Concrete - AKKRO- 7T
23 Concrete - Backer Rod, CERA-ROD
25 Concrete - Blastglass
27 Concrete - Cold applied joint sealer - #158
29 Concrete - Concrete & Sand Mixes
35 Concrete - Concrete Cure & Sealer CS-309
37 Concrete - Concrete cure/hardner MED-CURE
39 Concrete - Concrete Finisher Gray
53 Concrete - Concrete form release agent
55 Concrete - Concrete Sealer - TIAH
57 Concrete - Crafco Joint sealer
Concrete - Crystalline Silica in the form of Quartz -
63 TCC/various grades
71 Concrete - ET-HP epoxy-tie adhesive
81 Concrete - Federal White Cement, Portland Cement
93 Concrete - Fibre Expansion Joint
95 Concrete - Foam Expansion Joint
97 Concrete - Gray Iron Castings
103 Concrete - Hi-Spec hot applied joint sealant
105 Concrete - Hydrochloric acid
113 Concrete - KURE N SEAL
119 Concrete - L&M Everbond
125 Concrete - Masonry cements
131 Concrete - Mel Roi waterproofing membrane
133 Concrete - Portland cement - Holcim
139 Concrete - Portland cement - Lafarge
151 Concrete - Quikrete Products
161 Concrete - Silica Sand
171 Concrete - Silicone Joint Sealant 888
Page 1 of 516
I
197 Concrete - Spec Mix, Masonry Cement Mortars

207 Concrete - Spec Mix, Portland Lime & Sand Mortars
217 Concrete - SpecPoxy 3000 FS
239 Concrete - Speed Crete Red Line
257 Concrete - Stamped & Curbing, 1100 Clear Series Cure
259 Concrete - Stamped & Curbing, ANTI-HYDRO Cure
Concrete - Stamped & Curbing, Decra Seal Water based
263 concrete sealer
Concrete - Stamped & Curbing, Decra Seal Solvent based
265 concrete sealer
267 Concrete - Stamped & Curbing, E-Con
273 Concrete - Stamped & Curbing, Eucon 1037
283 Concrete - Stamped & Curbing, Evapre
285 Concrete - Stamped & Curbing, MasterKure CC 250SB
295 Concrete - Stamped & Curbing, Mineral Spirits
305 Concrete - Stamped & Curbing, Sika-Rugasol-S Retardant

313 Concrete - Stamped & Curbing, Sika-SikaFilm
321 Concrete - Stamped & Curbing, Solomon colorings
329 Concrete - Stamped & Curbing, TK-00 Solvent
335 Concrete - Stamped & Curbing, VOCOMP-20 Cure
337 Concrete - Stamped, Brickform Antique Release
347 Concrete - Stamped, Brickform Color Hardeners
357 Concrete - Stamped, Brickform Liquid Color
367 Concrete - Stamped, Brickform Liquid Release
377 Concrete - Stamped, Legacy Accent Colour Release
395 Concrete - Stamped~ Perma-Cast Antiquing Release
401 Concrete - Striping - Mineral Spirits
413 Concrete - Striping - Primer 94 - surface primer for tape or
431 Concrete - Striping - Stripe-Off
437 Concrete - Striping - Traffic Marking Paint, Solvent-Blue
453 Concrete - Striping - Traffic Marking Paint, Solvent-Red
469 Concrete - Striping - Traffic Marking Paint, Solvent-White
485 Concrete - Striping - Traffic Marking Paint, Solvent-Yellow
501 Concrete - Styrofoam
511 Concrete - Vermiculite Masonary Insulation
Page 2 of 516
W. R. MEADOWS,"
SAFETYDATA SHEET
Product: 2255-WHITE Part Number: 3122550

Manufacturer: W. R. MEADOWS,INC. Address: 300 Industrial Drive
Hampshire, Illinois 60140
Telephone: (847) 214-2100 In case of emergency, dial (800} 424-9300 (CHEMTREC}
4/12/2016
HMIS HAZARD STATEMENTS

Flammable Liquid/Vapor.
!Health! I1 I Harmful if inhaled. Causes skin/eye/respiratory irritation.
IFlammability I I2 I May be fatal if ingested and enters airway.
IReactivity I Io I Prolonged/repeated contact may cause organ damage.
IPersonal Protection I I I PRECAUTIONARY STATEMENTS
Avoid direct contact.
Avoid of inhalation of mists/vapors.
Keep containers closed when not in use/ Avoid ignition sources.
Store in well-ventilated location. For outdoor use or in well-ventilated locations.
Wear appropriate personal protective equipment.
SARA Vapor Pressure LEL

Chemical Name: CAS Number % by Weight 313 Imm Hg@20°Cl .l@1rn
l. Light Aromatic Naphtha 64742-95-6 10-15 No 2.1 1
2. Titanium Dioxide 13463-67-7 1-5 No N/A N/A
3. 1,2,4-Trimethyl benzene 95-63-6 1-5 Yes N/A 0.9
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA} and 40 CFR
Part 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA 313." N/A: Not Applicable
EYE CONTACT: Immediately flush eyes with water for fifteen minutes. If symptoms persist, seek medical attention.
SKIN CONTACT: Remove contaminated shoes/clothing. Wipe excess from skin and wash with soap if available. Seek medical attention if irritation
persists. Do not use clothing until thoroughly decontaminated.
INHALATION: Remove victim to fresh air and treat symptomatically. Seek medical attention if symptoms persist.
INGESTION: Do not induce vomiting. If vomiting spontaneously occurs, keep the victim's head below the hips to prevent lung aspiration. Seek
immediate medical attention.
FLASHPOINT: 110 degrees F Method 1010

EXTINGUISHING MEDIA: Water fog, foam, dry chemical, or carbon dioxide.
CHEMICAL/COMBUSTION HAZARDS: Carbon dioxide, carbon monoxide, and incomplete combustion products.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Personal protective equipment should include helmet, face shield,
bunker coat, gloves, rubber boots, and a positive pressure NIOSH-approved self-contained breathing apparatus.
product from freezing. Keep away from ignition so

~: ~Ul'Sirl~~fsR~f!!~~leRijlf~j~JI'.
Chemical Name: PEL PELLCEILING PELLSTEL SKIN TWA TLVLCEILING TLVLSTEL SKIN
1. Light Aromatic Naphtha N/E N/E N/E N/E N/E N/E N/E N/E
2. Titanium Dioxide* N/A N/A N/A N/A N/A N/A N/A N/A
3. 1,2,4-Trimethyl benzene 25 ppm N/E N/E N/E 25 ppm N/E N/E N/E
This material is in solution. No exposure is anticipated unless the product is dried/abraded. N/E = Not Established
Page 3 of 516
SAFETYDATA SHEET
Date of Preparation: 4/12/16 Page 2 of 2 3122550
Section 8 continued
ENGINEERING CONTROLS: Use with adequate ventilation. Use explosion proof equipment as required.
PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical-resistant gloves.
EYE CONTACT: Direct contact may cause mild to moderate irritation. Product vapors/mists may also cause irritation.
SKIN CONTACT: Direct contact may result in mild to moderate irritation.
INHALATION: Exposure may produce irritation of the throat, respiratory tract, and other mucous membranes. Exposure to excessive vapor
concentrations may cause signs of transient central nervous system depression (headache, drowsiness, loss of coordination, and fatigue). Repeated
and/or prolonged occupational exposures may result in permanent damage and can be potentially fatal.
INGESTION: Not expected to be an exposure pathway under normal use conditions.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include pain, tearing, redness, and swelling. Symptoms of skin irritation include reddening,
swelling, and rash. Symptoms of respiratory irritation include runny nose, coughing, chest discomfort, shortness of breath, reduced lung
function, and symptoms of central nervous system depression. Symptoms of gastrointestinal irritation include sore throat, abdominal pain, nausea,
vomiting, and diarrhea.
AGGRAVATED MEDICAL CONDITIONS: Skin, eye, and respiratory disorders may be aggravated by product exposure.
OTHER HEALTH EFFECTS: May cause liver abnormalities and may be harmful to the human fetus.
.. " . ~
HAZARDOUS/NON-HAZARDOUS MATERIAL: Non-hazardous by ground transportation.

UN NUMBER: None. HAZARD CLASS: None. PACKING GROUP: None.
UN PROPER SHIPPING NAME: Not regulated.
ENVIRONMENTAL HAZARDS: Not applicable.
BULK TRANSPORTATION INFORMATION: NA 1993, Combustible Liquid, N.O.S. (Aromatic Naphtha, 1,2,4-Trimethylbenzene), 111
SPECIAL PRECAUTIONS: Protect product from freezing.
PREPARED BY: Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However, we make no
warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We
assume no responsibility for injury from the use of this product described herein.
Page 4 of 516
W. R. MEADOWS,
SAFETYDATA SHEET
Product: 3405 REGULAR (LOW SULFUR) Part Number: 4215000

Manufacturer: W.R. Meadows®, Inc. Address: 300 Industrial Drive
(847) 214-2100 In case of emergency, dial (800) 424-9300 (CHEMTREC)
9/9/2014
Hot-A lied Joint Sealant

I Health I 111 WARNING!
I Flammability I 111 Causes skin irritation.
I Reactivity I 101 PRECAUTIONARY STATEMENTS
IPersonal Protection I I I Avoid direct contact with heated material.
Avoid inhalation of fumes.
% by SARA Vapor Pressure LEL

Chemical Name: CAS Number Weight 313 (mm Hg@20°Cl .l..@1i:Q
1. Petroleum Asphalt 8052-42-4 50-55 No N/A N/A
2. Petroleum Oil Base Stock 64742-65-0 5-10 No N/A 0.9
3. Limestone 1317-65-3 25-30 No N/A N/A
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA)and 40
CFR Part 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA 313." N/A = Not Applicable
__
...
__-:.a11:s~•~ll!fNf:11:111e~s~~1r-
,
EYE CONTACT: Not expected to be an exposure route as supplied. If contact with molten material occurs, seek immediate medical
attention.
SKIN CONTACT: Wash affected areas with soap and water if available. If contact with hot, molten material occurs cool affected area
with water. Do not attempt to remove congealed solid. Do not use petroleum solvents to remove solids adhered to skin. Seek
INHALATION: Not expected to be an exposure route as supplied. If irritation occurs due to exposure to fumes produced by hot molten
product, move victim from exposure source and treat symptomatically. If symptoms persist, seek medical attention.
INGESTION: Not expected to be an exposure source.
- -..- :~JMIJ!S~D!S1$:il~aiJf-.11t~
,~ _--
FLASHPOINT: Not applicable; product is a solid.
EXTINGUISHING MEDIA: Water fog, foam, dry chemical.
CHEMICAL/COMBUSTION HAZARDS: Oxides and compounds of nitrogen/sulfur, carbon monoxide/dioxide, and incomplete combustion
products.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Hot material may spatter if hit by a direct stream of
Prevent job-site damage.
OSHA ACGIH
Chemical Name: PEL PEL/CEILING PEL/STEL SKIN TLV TLV/CEILING TLV /STEL SKIN
3 3
1. Petroleum Asphalt S mg/m * N/E N/E No 0.5 mg/m * N/E N/E N/E
3
2. Petroleum Oil Base Stock N/E N/E N/E No 5 mg/m + N/E N/E N/E
3. Limestone N/A N/A N/A No N/A N/A N/A N/A
*: Asphalt Fumes +: Mineral Oil Mist in Air N/E: Not Established
ENGINEERING CONTROLS: None required under normal use conditions.
PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical resistant gloves.
Page 5 of 516
SAFETYDATA SHEET
EYE CONTACT: Direct contact may cause mild irritation. Contact with heated material may cause severe burns.
SKIN CONTACT: Direct contact may cause slight skin irritation. Contact with heated material may cause severe burns.
INHALATION: Not anticipated to be an exposure route. Heated material may emit fumes. Exposure to fumes may result in respiratory
irritation.
INGESTION: Not anticipated to be an exposure route.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness
and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory
irritation include runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function.
AGGRAVATED MEDICAL CONDITIONS: Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHER HEALTH EFFECTS: ACGIH Classifies asphalt as Not Classifiable as a Human Carcinogen; A4.
". :l!i =-·
1
_l!;It!lE 7
0~1?~
DEGRADABILITY: N/E
HAZARDOUS/NON-HAZARDOUS MATERIAL: Not regulated by DOT.

UN NUMBER: None. HAZARD CLASS: N/A PACKING GROUP: N/A
UN PROPER SHIPPING NAME: N/A
ENVIRONMENTAL HAZARDS: None recognized.
BULK TRANSPORTATION INFORMATION: None.
SPECIAL PRECAUTIONS: None.
Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However, we
make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the
use thereof We assume no responsibility for injuryfrom the use of this product described herein.
Page 6 of 516
Page: 1 of 3
SAFETY DATA SHEET Process Time: 2:29 pm
Date Revised: 5/24/10 Date Printed: 4/1/15
SECTION 1 - IDENTIFICATION
MANUFACTURER: SIERRA CORP/TK PRODUCTS EMERGENCYPHONE: 1-800-424-9300

ADDRESS 11400 WEST 47TH STREET INFORMATION PHONE: ( 952) 938-7 223
MINNETONKA, MN 55343 NAME OF PREPARER: Safety Director
PRODUCT NAME: ACHRO KURE WB
PRODUCT CODE: TK-AK-2WB
SECTION 2 - HAZARDS IDENTIFICATION
HAZARD RISK CLASSIFICATION
SIGNAL WORD:
PICTOGRAM:
HAZARD CLASS HAZARD CATEGORY
HAZARD STATEMENTS:
H303 May be harmful if swallowed
PRECAUTIONARY STATEMENTS:
PREVENTION:
RESPONSE:
P30l+P312 If swallowed: Call a Poison Center/ doctor if you feel unwell.
P330 Rinse mouth.
STORAGE:
DISPOSAL:
SECTION 3 - COMPOSITION/INFORMATIONON INGREDIENTS

WEIGHT EXPOSURE LIMITS
COMPONENT CAS NUMBER PERCENT OSHA PEL ACGIH TLV OTHER
*** NO REPORTABLE QUANTITIES OF HAZARDOUS INGREDIENTS ARE PRESENT***
PRIMARY ROUTES OF EXPOSURE:

Skin contact.
EFFECTS OF ACUTE EXPOSURE:
EYES: Direct contact with eyes may cause irritation.
SKIN: Prolonged or repeated contact may cause irritation.INHALATION: Inhalation of vapor or mist can cause
irritation of nose, throat and lungs and lead to headaches and nausea.
INGESTION: Not an anticipated route of exposure. Small amounts are not expected to be harmful.
CHRONIC HEALTH EFFECTS:
No anticipated chronic effects.MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
No known effects on other illnesses.
SECTION 4 - FIRST AID MEASURES

EYES: Flush with large amounts of water for 15 minutes, lifting upper and lower eyelids. If irritation persists seek
medical attention.
SKIN CONTACT: Wash contaminated area with soap and water. Remove and launder contaminated clothing.
INGESTION: If a large amount is ingested, give water or milk and induce vomitting. Seek medical attention.
INHALATION: Remove victim to fresh air and provide oxygen if breathing is difficult. If breathing has stopped
administer artificial respiration. Seek medical attention if condition persists.
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA==========
Page 7 of 516
Page: 2 of 3

FLASH POINT: No flash METHODUSED: n/a
FLAMMABLELilrrTS IN AIR BY VOLUME- LOWER: n/a UPPER: n/a
EXTINGUISHING MEDIA:
This material will not burn in its liquid state unless heated above its flash point. Dried films may burn and can be
extinguished by water spray, foam, dry chemical or carbon dioxide.
SPECIAL FIREFIGHTING PROCEDURES:

Persons exposed to products of combustion should wear self-contained breathing apparatus and full protective equipment.
Isolate danger area, keep unauthorized personnel out.
UNUSUAL FIRE AND EXPLOSION HAZARDS:

There is the possibility of pressure buildup in closed containers when heated. Water spray may be used to cool these
containers.
SECTION 6 - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Do not let uncured· spilled or leaking material enter watercourse. May be toxic to aquatic life. Absorb with oil-dri or
similar inert material. Sweep or scrape up and containerize. Rinse affected area thoroughly with water. Wear
appropriate protective equipment.
SECTION 7 - HANDLING AND STORAGE

HANDLING INFORMATION:
Employees who come in contact with this material must be trained in accordance to 1910.1200 of the Hazard Communicatin
Standard. Wear chemical resistant gloves and protective clothing to minimize contact. The use of respiratory
protection is advised when spraying because of mist and dust overspray.
STORAGE INFORMATION:
Keep from freezing; material may coagulate. The minimum recommended storage temperature is 34F/1C, the maximum
recommended storage temperature is 120F/49C. Keep away from incompatable materials (see section 10). Keep containers
tightly closed. It is advised that material be used within 1 year of manufacture, rotate stock.
OTHER PRECAUTIONS:
All empty containers should be disposed of in an evironmentally safe manner in accordance with all governmental
regulations.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

RESPIRATORY PROTECTION:
No special requirements under normal use conditions. In confined areas, or ares with poor ventilation, engineering
controls should be used to minimize exposure. Use NIOSH/MSHA approved respirator if conditions warrant.
VENTILATION:
General room ventilation is adequate.
PROTECTIVE GLOVES:
Prevent prolonged or repeated contact by wearing chemical resistant gloves and other appropriate protective clothing.
Launder contaminated clothing before reuse.
EYE PROTECTION:
Wear safety glasses to reduce eye contact potential. Chemical safety goggles (ANSI Z87.l or approved equivalent) are
appropriate if splashing is likely. Eye washes must be available where eye contact can occur.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
A source of clean water should be available for flushing eyes and skin. Showers should be available if larger spills
are possible.
WORK/HYGIENIC PRACTICES:
Efforts should be made to minimize contact and spills. Always wash hands before eating, drinking, or smoking. Clean up
spills promptly. Follow OSHA and company guidlines.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Liquid COLOR: Various colors
ODOR: Amine or ammonia odor SOLUBILITY IN WATER: Dilutable
SPECIFIC GRAVITY (H20=1): 1.01 VAPOR DENSITY: Heavier than air.
BOILING RANGE: EVAPORATION RATE: Slower than nBuAc
COATING V.O.C.: 172 g/1 (1. 44 lb/gl )
SECTION 10 - STABILITY AND REACTIVITY DATA

STABILITY:
Page 8 of 516
Page: 3 of 3

Stable under normal conditions and handling.
CONDITIONS TO AVOID:
None known
INCOMPATIBILITY (MATERIALS TO AVOID):
None known. Materials which are not cornpatable with water or ordinary organics will not be cornpatable with this
material.
HAZARDOUSDECOMPOSITION OR BYPRODUCTS:
Combustion may liberate toxic byproducts such as carbon dioxide, and carbon monoxide, various oxides of carbon and
nitrogen. Thermal decomposition may liberate acrylic monomers and ammonia.
HAZARDOUSPOLYMERIZATION:
Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION

SENSITIZATION:
None known.
CARCINOGENICITY:
There is no data available to indicate any components present at greater than 0.1% may present a carcinogenic hazard.
REPRODUCTIVE TOXICITY:
There is no data available to indicate any components present at greater than 0.1% may present reproductive toxicity.
TERATOGENICITY (BIRTH DEFECTS):
There is no data available to indicate any components present at greater than 0.1% may cause birth defects.
MUTAGENICITY:
There is no data to indicate that any component present at greater than 0.1% will alter DNA.
SECTION 12 - ECOLOGICAL INFORMATION

ENVIRONMENTALDATA:
Contains ammonia or amines which may be toxic to aquatic life.
SECTION 13 - DISPOSAL CONSIDERATIONS

This product does not meet the definition of hazardous waste under the U.S. EPA Hazardous Waste Regulations 40 CFR 261,
however, state and local regulations may be more restrictive. Coagulate the emulsion by the stepwise addition of ferric
chloride and lime. Remove the clear supernatant and flush to a chemical sewer. Incinerate liquid and contaminated
solids in accordance with local, state, and federal regulations.
SECTION 14 - TRANSPORT INFORMATION

SHIPPING NAME:
Not regulated.
=============SECTION 15 - REGULATORYINFORMATION
All ingredients of this product are listed, or are excluded from listing, on the US Toxic Subatances Control Act (TSCA)
chemical substance inventory.
This product does not contain a chemical subject to the reporting requirements of SARA Title III, Section 313 (40CFR
372) above de minimis concentrations.
STATE SPECIFIC REQUIREMENTS:

This product does not contain a chemical known to the state of California to cause cancer, birth defects or reproductive
harm, subject to the requirements of California Proposition 65.
STATE LISTED COMPONENTS CAS NUMBER STATE CODE
=============SECTION 16 - OTHER INFORMATION

REVISION DATE: 05/24/10
IMIS CODES: H F R p
2 0 0 B
Page 9 of 516
Page 10 of 516
SAFETYDATA SHEET
Product: ACRY-LOK™ BONDING AGENT Part Number: 3620000

Telephone: (847) 214-2100 In case of emergency, dial (800) 424-9300 (CHEMTREC)
Revision Date: 9/9/2014
Product Use: Adhesive/Glue
=~=::=---=- _ """,c=,=,,
r=,y=_-
=-=~=-·.~=-~---
u=·=: =_, _,,_=-

IHealth I 111 WARNING!
I Flammability I Io I May cause skin, eye, respiratory irritation.
IReactivity I Io I PRECAUTIONARY STATEMENTS
IPersonal Protection I I I Avoid direct contact
Avoid inhalation of mists/aerosols.
J1i #~~ili!-~•Cf ,~_
Chemical Name: CAS Number % by Weight 313 (mm Hg@20°C\ 1@1ffi
1. Acrylic Polymers N/E 45-50 No N/A N/A
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA)and 40 CFR
Part 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA313." N/A: Not Applicable N/E: Not Established
EVE CONTACT: Immediately flush eyes with large quantities of water for fifteen (15) minutes. If irritation persists, seek medical attention.
SKIN CONTACT: Wash skin with mild soap and water. Remove contaminated clothing. Launder before reuse. If irritation develops/persists, seek
medical attention.
INHALATION: Remove victim from exposure source and into fresh air. Treat symptomatically. If symptoms persist, seek medical attention.
INGESTION: Give victim one to two glasses of water or milk to drink. Do not induce vomiting. Seek medical attention.
'c~~ -
emical or carbon dioxide.

noxide, carbon dioxide, and incomplete combustion products.
ENT: Self-contained breathing apparatus and full fire fighting pr
~~f!NJL -rl~B~ ---In
rized personnel. Dike contain spilled material. Remove spill sour
laced in marked, sealed containers for disposal. Prevent spilled
HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS AND MATERIALS TO AVOID: None recognized.
HAZARDOUS DECOMPOSITION PRODUCTS: None recognized.
Page 11 of 516
EYE CONTACT: Direct contact may result in mild to moderate irritation.
SKIN CONTACT: Direct contact may result in mild irritation.
INHALATION: Inhalation of mists/aerosols may result in mild irritation.
swelling, rash, and redness. Symptoms of respiratory irritation include runny nose, sore throat, coughing, chest discomfort, shortness of breath,
and reduced lung function.
AGGRAVATED MEDICAL CONDITIONS: None recognized.
OTHER HEALTH EFFECTS: None recognized.
HAZARDOUS/NON-HAZARDOUS MATERIAL: Non-hazardous.

UN PROPER SHIPPING NAME: None.
ENVIRONMENTAL HAZARDS: None.
BULK TRANSPORTATION INFORMATION: Not regulated by DOT.
Dave Carey
warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof We
assume no responsibility for injuryfrom the use of this product described herein.
Page 12 of 516
Version: 2.0
EUCLW CHEMICAL
SAFETY DATA SHEET

11.Identification
Material name: AKKRO-?T
Material: TL6201555
Recommended use and restriction on use

Recommended use: Additive
Restrictions on use: Not known.
Manufacturer/Importer/Supplier/Distributor Information
Euclid Admixture Canada Inc.
2835 Grand-Allee
Saint Hubert QC J4T 2R4
CA
Contact person: EH&S Department

Telephone: (450)465-2233
Emergency telephone number: 1-800--424-9300 (US); 1-613-996-6666 (Canada)
/2.Hazard(s) identification
Hazard Classification
Not classified
Label Elements
Hazard Symbol: No symbol
Signal Word: No signal word.
Hazard Statement: not applicable
Precautionary not applicable

Statement:
Other hazards which do not None.

result in GHS classification:
13.Composition/information on ingredients
Mixtures
Chemical Identity GAS number Content in percent(%)'
Ammonium hydroxide 1336-21-6 0.1 -1%

* All concentrations are percent by weight unless ingredient 1sa gas. Gas concentrations are-in percent by volume.
14.First-aid measures
Ingestion: Rinse mouth thoroughly.
Inhalation: Move to fresh air.

1/10
000000007540
Page 13 of 516
Version: 2.0
EUCLID CHEMICAL
Skin Contact: Remove contaminated clothing and wash the skin thoroughly with soap and
water after work.
Eye contact: Rinse immediately with plenty of water.
Most important symptoms/effects, acute and delayed
Symptoms: May cause skin and eye irritation.
Indication of immediate medical attention and special treatment needed
Treatment: Get medical attention if symptoms occur.
Is.Fire-fighting measures
General Fire Hazards: No unusual fire or explosion hazards noted.
Suitable (and unsuitable) extinguishing media
Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical:
Special protective equipment and precautions for firefighters
Special fire fighting No data available.

procedures:
Special protective equipment Self-contained breathing apparatus and full protective clothing must be
for fire-fighters: worn in case of fire.
Is.Accidental release measures

Personal precautions, No data available.
protective equipment and
emergency procedures:
Methods and material for Dam and absorb spillages with sand, earth or other non-combustible
containment and cleaning material. Collect spillage in containers, seal securely and deliver for
up: disposal according to local regulations.
Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.
Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe
to do so. Do not contaminate water sources or sewer. Environmental
manager must be informed of all major spillages.
2/10
000000007540
Page 14 of 516
Version: 2.0
E\JCUO CHEMICAL
17.Handling and storage

Precautions for safe handling: Provide adequate ventilation. Wear appropriate personal protective
equipment. Observe good industrial hygiene practices. Provide adequate
ventilation. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices.
Conditions for safe storage, Store away from incompatible materials. Store in original tightly closed
inctuding any container.
incompatibilities:
Is.Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity type Exposure Limit Values Source
Ammonium hydroxide STEL 35 ppm US. ACGIH Threshold Limit Values

(2011)
TWA 25 ppm US. ACGIH Threshold Limit Values
(2011)
PEL 50 ppm 35 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000)
(02 2006)
Appropriate Engineering Observe good industrial hygiene practices. Observe occupational exposure
Controls limits and minimize the risk of inhalation of vapors and mist. Mechanical
ventilation or local exhaust ventilation may be required.
Individual protection measures, such as personal protective equipment
General information: Use personal protective equipment as required.
Eye/face protection: Wear goggles/face shield.
Skin Protection
Hand Protection: Use suitable protective gloves if risk of skin contact.
Other: No data available.
Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.
Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated
footwear that cannot be cleaned.
19.Physical and chemical properties
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Version: 2.0
EUCLID CHEMICAL
Appearance
Physical state: liquid
Form: liquid
Color: Off-white
Odor: Mild
Odor threshold: No data available.
pH: 9 -10
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: No data available.
Evaporation rate: Slower than Ether
Flammability (solid, gas): No
Upper/lower limit on flammability or explosive limits
Flammability limit - upper(%): No data available.
Flammability limit - lower(%): No data available.
Explosive limit - upper(%): No data available.
Explosive limit - lower(%): No data available.
Vapor pressure: No data available.
Vapor density: Vapors are heavier than air and may travel along the floor and
in the bottom of containers.
Relative density: 1.1
Solubility(ies)
Solubility in water: Soluble
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.
110.
Stability and reactivity
Reactivity: No data available.
Chemical Stability: Material is stable under normal conditions.
Possibility of hazardous No data available.

reactions:
Conditions to avoid: Avoid heat or contamination.
Incompatible Materials: Strong acids. Strong bases.
Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.
111.
Toxicological information
Information on likely routes of exposure

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000000007540
Page 16 of 516
Version: 2.0
EUCUD CHEMICAL
Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise.
Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and
mucus membranes.
Skin Contact: Moderately irritating to skin with prolonged exposure.
Eye contact: Eye contact is possible and should be avoided.
Information on toxicological effects
Acute toxicity (list all possible routes of exposure)
Oral
Product: No data available.
Dermal
Inhalation
Repeated dose toxicity

Skin Corrosion/Irritation
Serious Eye Damage/Eye Irritation

Specified substance(s):
Ammonium hydroxide Severely Irritating
Respiratory or Skin Sensitization

Carcinogenicity
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified
US. National Toxicology Program (NTP) Report on Carcinogens:

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

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000000007540
Page 17 of 516
Version: 2.0
EUCUG CHEMICAL
Germ Cell Mutagenicity
In vitro
In vivo
Reproductive toxicity
Specific Target Organ Toxicity - Single Exposure

Specific Target Organ Toxicity - Repeated Exposure

Aspiration Hazard
other effects: No data available.
j12.Ecological information
Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Ammonium hydroxide LC 50 (Western mosquitofish (Gambusia affinis), 96 h): 15 mg/I Mortality
Aquatic Invertebrates
Ammonium hydroxide LC 50 (Water flea (Daph nia magna), 25 h): 60 mg/I Mortality
LC 50 (Water flea (Ceriodaphnia dubia), 48 h): > 0 - 10 mg/I Mortality
Chronic hazards to the aquatic environment:
Fish
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Page 18 of 516
Version: 2.0
EUCL10 CHEMICAL
Toxicity to Aquatic Plants

Persistence and Degradability
Biodegradation
BOD/COD Ratio
Bioaccumulative Potential
Bioconcentration Factor (BCF)
Partition Coefficient n-octanol I water (log Kow)

Mobility in Soil: No data available.
Other Adverse Effects: No data available.
113.Disposal considerations
Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in
accordance with applicable laws and regulations, and product
characteristics at time of disposal.
Contaminated Packaging: No data available.
114.Transport information
TDG:
Not Regulated
CFR / DOT:
Not Regulated
IMDG:
Not Regulated
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000000007540
Page 19 of 516
Version: 2.0
EUCUP CHEMICAL
l1s.Regulatory information
US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

None present or none present in regulated quantities.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Chemical Identity OSHA hazard(s)
Formaldehyde Acute toxicity
Skin irritation
Skin sensitization
Flammability
respiratory tract irritation
Respiratory sensitization
Cancer
Eye irritation
CERCLA Hazardous Substance List (40 CFR 302.4):

Chemical Identity Reportable quantity
Ammonium hydroxide 1000 lbs.
Formaldehyde 100 lbs.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Not listed.
SARA 302 Extremely Hazardous Substance

Reportable
Chemical Identity quantity Threshold Planning Quantity
Formaldehyde 100 lbs. 500 lbs.
SARA 304 Emergency Release Notification

Ammonium hydroxide 1000 lbs.
Formaldehyde 100 lbs.
SARA 311/312 Hazardous Chemical

Chemical Identity Threshold Planning Quantity
Formaldehyde 500lbs
Ammonium hydroxide 500 lbs
SARA 313 (TRI Reporting)

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Formaldehyde 15000 lbs
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000000007540
Page 20 of 516
Version: 2.0
EUCUD CHEMICAL
US State Regulations
US. California Proposition 65

This product contains chemical(s) known to the State of California to cause cancer and/or to
cause birth defects or other reproductive harm.
US. New Jersey Worker and Community Right-to-Know Act

No ingredient regulated by NJ Right-to-Know Law present.
US. Massachusetts RTK - Substance List

Chemical Identity
Formaldehyde
US. Pennsylvania RTK - Hazardous Substances

No ingredient regulated by PA Right-to-Know Law present.
US. Rhode Island RTK

No ingredient regulated by RI Right-to-Know Law present.
Other Regulations:
Regulatory VOC (less water 10 g/1

and exempt solvent):
VOC Method 310: 0.00 %
Inventory Status:
Australia AICS: One or more components in this product are
not listed on or exempt from the Inventory.
Canada DSL Inventory List: All components in this product are listed on or
exempt from the Inventory.
EINECS, ELINCS or NLP: One or more components in this product are

Japan (ENCS) List: One or more components in this product are

China Inv. Existing Chemical Substances: One or more components in this product are
Korea Existing Chemicals Inv. (KECI): One or more components in this product are
Canada NDSL Inventory: One or more components in this product are

Philippines PICCS: One or more components in this product are

New Zealand Inventory of Chemicals: One or more components in this product are
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Page 21 of 516
Version: 2.0
EUCLJP CHEMICAL
Japan ISHL Listing: One or more components in this product are

Japan Pharmacopoeia Listing: One or more components in this product are

US TSCA Inventory: All components in this product are listed on or

16.0ther information, including date of preparation or last revision
Version#: 2.0
Further Information: No data available.
Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard
information herein is offered solely for the consideration of the user, subject
to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
10/10
000000007540
Page 22 of 516
W. R. MEADOWS,,
SAFETYDATA SHEET
Page 1 of 2
Product: CERA-ROD- Part Number: 4680500

Product Use:
as non-hazardous per OSHA 1910.1200. Cera-Rod is

an "article," a manufactured item that is formed to a specific shape
nufacture that does not release or result in exposure to a hazardous
% by Weight
of the Superfund Amendments and

R Part 373.65) are identified under
EYE CONTACT: Flush eyes with water to remove particles

SKIN CONTACT: Flush with water to remove particles. Wash affected areas with soap and water if available.
INHALATION: Not expected to be an exposure route.
C. ~-.J!i
1!l~t(ijlR~. -
FLASHPOINT: Not Applicable
CHEMICAL/COMBUSTION HAZARDS: Carbon monoxide, carbon dioxide, and incomplete combustion products.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Use appropriate respiratory protection .
~~
..~it"p~~;,,,,,,,,-i®lll&il'QC. ._iE~B~t?i~
SPILL OR LEAK PROCEDURES: Not applicable. Product is a solid.
SAFE HANDLING PROCEDURES: No special requirements.
Chemi
1. None
ENGINEER!
EYE CONTACT: Direct contact may cause mechanical irritation.

SKIN CONTACT: Direct contact may cause slight mechanical skin irritation.
INHALATION: Not anticipated to be an exposure route.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include
redness and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
OTHER HEALTH EFFECTS: None recognized
Page 23 of 516
SAFETYDATA SHEET

UN NUMBER: None HAZARD CLASS: N/A PACKING GROUP: N/A
Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However,
we make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained
from the use thereof We assume no responsibility for injuryfrom the use of this product described herein.
Page 24 of 516
g/assAdvantage
Safety Data Sheet Innovation and Recycling At Its Best
Product Name: Blastglass®

Manufactured By: Glass Advantage, Inc. Address: 230 15 th Street NW, West Fargo, ND 58078
Phone: 701-277-9200 Fax: 701-364-1281
Product Use: Glass media abrasive for wet or dry blasting
Crushed glass (glass sand) is not classified as a hazardous material by the criteria of the OSHA Hazard
Communication Standard, Title 29, Code of Federal Regulations, Section 1910.1200, Hazard Communication.
Contains no free (or crystalline) silica; all components are amorphous/non-crystalline.
Nuisance dust concern
Chemical Name: 100% Soda-Lime Silicon Dioxide Glass CAS Number: 65997-17-3
Known As: Crushed Glass Media
Inhalation: If product is inhaled, move to fresh air and contact a physician. Dust in excess of recommended
exposure limits may result in respiratory tract irritation.
Ingestion: Product is not hazardous if ingested, however consult a physician if a large amount is ingested.
Eyes: Flush thoroughly with water and contact physician if irritation persists.
Skin Contact: No known hazards, however, washing a~er contact is advised.
Non-flammable, non-combustible, non-hazardous, inorganic material.
Spills: Sweep up and discard; avoid excessive dusting. This material is not a SARA Title III reportable substance.
Respiratory: If dust concentrations exceed recommended Permissible Exposure Limits, use NIOSH-approved
respirators.
Ventilation: Local exhaust.
Precautions: Spillage may result in slippery conditions.

When transferring material, care should be taken to avoid dusting.
Nuisance Dust (total): ACGIH 10 mg/m 3 TLV (units) depends upon particle size
Nuisance Dust (respirable): OSHA PEL 5 mg/m 3 depends upon particle size
Carcinogenity:
NTP: Not listed IARC Monographs: Not Listed OSHA Regulation: Not Listed
Routes of Entry:
Lungs (breathing): Yes Ingestion: No Skin: No
Health Hazard (acute & chronic): Dust in excess of recommended exposure limits may result in irritation to the
respiratory tract.
Respiratory Protection: If dust concentrations exceed recommended Permissible Exposure Limits, use NIOSH-
approved respirators.
Eye Protection: NIOSH-approved safety glasses or goggles (tight fitting recommended)
Ventilation: Local Exhaust Protective Gloves: Not required
Other Protective Clothing or Equipment: None required
Appearance: Solid, transparent, colored particle Odor: Odorless Odor Threshold: N/A
Melting Point: 726°C (1340°F) Boiling Point: N/ A Freezing Point: N/A
Vapor Pressure: N/A Vapor Density: N/A Evaporation Rate: N/ A
Solubility in Water: Insoluble % Volatile by Volume: N/A Specific Gravity: 2.5
pH: N/A Flash Point: N/A Flammability: N/ A
Stability: Material is stable Incombatibilities: Hydrofluoric Acid

Hazardous Polymerization: Will not occur Hazardous Decomposition Products: None
Toxicity: N/ A
Ecological Concerns: N/A
Page 25 of 516
Waste Disposal Method: Dispose in approved landfill in accordance with federal, state and local regulations.
This material is not a SARA Title III reportable substance.
DOT Identification: Not regulated by DOT
Abbreviation References:
N/ A = Not Applicable
mg/m3 = Milligrams per cubic meter
TLV = Threshold limit value
NIOSH = National Institute of Safety & Health
OSHA= Occupational Safety & Health Administration
CAS = Chemical Abstracts Service
ACGIH: American Conference of Government Industrial Hygienists
SARA Title III = Emergency Planning and Community Right-to-Know Act
DOT = Department of Transporatation
August 6, 2015
This information is furnished without warranty, representation, inducement, or license of any kind, except that it is accurate to the best of
Glass Advantage Inc's knowledge or obtained from sources believed by Glass Advantage Inc to be accurate, and Glass Advantage Inc does
not assume any legal responsibility for use or reliance upon same. Customers are encouraged to conduct their own tests, read the product
label, and obtain data for sources, which they know to be reliable before using any product.
Page 26 of 516
W R. MEADOWS,,
SAFETYDATA SHEET
Page 1 of 2
Product: #158 Part Number: 4230000

11/5/2015
· Sealer
a!!i~a•••nilllm~l:l~N'
HA RD STATEMENTS
HMIS WARNING!
I Health I 11 I Flammable Liquid and vapor.
IFlammability I I2 I Causes skin, eye, respiratory irritation.
IReactivity I Io I Suspected of causing genetic defects.
I Personal Protection I I I Causes damage to liver, kidneys, lungs, and blood.
Harmful if inhaled.
May be fatal if ingested and enters airway.
PRECAUTIONARY STATEMENTS
Use only in well-ventilated areas.
Avoid breathing vapors and direct contact.
Store in well-ventilated location.
Keep away from ignition sources.
Control vapors in confined spaces utilizing mechanical ventilation.
-1\~~=-" ..... -
Chemical Name: CAS Number % by Weight 313 (mm Hg@20°C) ~
1. Xylene 1330-20-7 1-5 Yes 6.6 1.1
2. Light Aromatic Naphtha 64742-95-6 25-30 No <10@ 25°C 0.9
4. Petroleum Oil 64742-65-0 5-10 No N/A N/A
5. 1,2,4-Trimethylbenzene 95-63-6 5-10 Yes N/A 0.9
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA) and 40 CFR
.: GQ'il~~WNmiPlJI~GEiQ:'
EYE CONTACT: Move victim from exposure source and into fresh air. Flush eyes with water for Fifteen (15) minutes. Product is thick and may be
difficult to remove. If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water. Product may be difficult to remove. Do not use petroleum solvents.
INHALATION: If respiratory symptoms develop move victim from exposure source and into fresh air. If symptoms persist, seek medical attention.
INGESTION: Not anticipated to be an exposure route. If ingested, do not induce vomiting. Dilute by giving victim w.:iter or milk. Seek immediate
medical attention.
FLASHPOINT: 103 degrees F

CHEMICAL/COMBUSTION HAZARDS: Oxides/compounds of nitrogen/sulfur. carbon dioxide, carbon monoxide, and incomplete combustion
products.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid direct contact. Use of eye protection and chemical-resistant gloves is recommended.
Res irato rotection ma be re uired if excessive va or concentrations are resent.
SAFE STORAGE: Keep containers closed when not in use. Store away from ignition sources.
Page 27 of 516
SAFETYDATA SHEET
C
Chemical Name: PEL PELLCEILING PELLSTEL SKIN TWA TLVLCEILING TLVLSTEL SKIN
1. Xylene 100 ppm N/E N/E N/E 100 ppm N/E 150 ppm N/E
3. Petroleum Asphalt 3 3
5 mg/m ' N/E N/E N/E 5 mg/m ' N/E N/E N/E
3
4. Petroleum Oil 5 mg/m + N/E N/E N/E 5 mg/m 3+ N/E 10 mg/m 3+ N/E
5. 1,2,4-Trimethylbenzene 25 ppm N/E N/E No 25 ppm N/E N/E No
•: Asphalt Fumes +: Petroleum Oil mist in air N/E: Not Established
ENGINEERINGCONTROLS: Use with adequate ventilation. Use explosion-proof equipment.
PERSONALPROTECTIVEEQUIPMENT: Safety glasses, chemical-resistant gloves.
~:~4:ll =
-- -======'"" -~~ :JAillttll~1~-

EvE CONTACT: Direct contact may result in moderate irritation. Product vapors/mists may also cause irritation.
SKIN CONTACT: Direct contact may cause mild skin irritation. Prolonged/repeated contact may result in skin irritation/dermatitis.
INHALATION: Exposure to excessive vapor concentrations may result in transient central nervous system depression (headache, fatigue,
drowsiness, loss of coordination). Intentional misuse by deliberately concentrating/inhaling vapors may be harmful or fatal.
Repeated/prolonged occupational exposures to solvents may cause permanent brain and nervous system damage.
INGESTION: Not anticipated to be an exposure route. Ingestion will cause irritation of the digestive tract.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory irritation include
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function. Symptoms of transient central nervous
system depression include: headache, fatigue, drowsiness, dizziness, and loss of coordination.
AGGRAVATEDMEDICAL CONDITIONS: Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHER HEALTHEFFECTS:Xylene and Aromatic Naphtha have been shown to cause the following effects in laboratory animals: liver/kidney
effects, blood abnormalities, effects on the spleen, testes, nervous system, adrenals, cardiovascular system, and harm to the fetus. The relevance
to humans is uncertain.
HAZARDOUS/NON-HAZARDOUSMATERIAL: Not Regulated by domestic ground shipment.

UN NUMBER: None HAZARDCLASS:None PACKINGGROUP: None
UN PROPERSHIPPING NAME: Tars, Liquid
ENVIRONMENTAL HAZARDS:None recognized.
BULKTRANSPORTATIONINFORMATION: Not applicable. Product not supplied in bulk configuration.
SPECIALPRECAUTIONS: None.
Dave Carey
Page 28 of 516
SAFETY DATA SHEET: PACKAGED CONCRETEAND SAND MIXES REVISION DATE: 5/28/15 PAGE 1
SAFETYDATA SHEET
~olcim MATERIAL: PACKAGED CONCRETE AND SAND MIXES
Section 1- Product Identification

Product Identifier
Product Name: Packaged Concrete and Sand Mixes
Product Codes: Packaged Concrete Mix, Packaged Sand Mix
(This SOScovers several products. Individual constituents will vary.)
Synonyms: Concrete mix, sand mix
Product Form: Solid blend
Intended Use of Product: Packaged Concrete and Sand Mixes are used for masonry binders and creating cementitious building
materials.
Name, Address and Telephone of Responsible Party Emergency Contact Information:

Holcim (US) Inc. CHEMTREC:1-800-424-9300
24 Crosby Drive
Bedford, MA 01730
(888) 646-5246
Section 2 - Hazards Identification

Classification of the Substance or Mixture
Classification ( GHS-US)
Skin Corrosion 1B
Eye Damage 1
Skin Sensitizer 1B
Specific Target Organ Toxicity: Single Exposure (Lungs) 3
Label Elements
Hazard Pictograms
Signal Word Danger

Hazard Statements Causes severe skin burns and eye damage
May cause an allergic skin reaction
May cause respiratory irritation
Precautionary Statements
Prevention Do not breathe dust.
Wear protective gloves/protective clothing/eye protection/face protection
Wash thoroughly after handling.
Do not handle until all safety precautions have been read and understood.
Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a doctor.
If on skin: Take off immediately all contaminated clothing. Rinse skin with water. Wash
contaminated clothing before reuse.
If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center/doctor.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/state/national regulations.
Other Hazards Exposure may aggravate those with pre-existing eye, skin or respiratory conditions or illness.
Page 29 of 516
SAFETYDATA SHEET: PACKAGEDCONCRETEAND SAND MIXES REVISION DATE:S/28/15 PAGE2
Section 3 - Composition/Information on Ingredients
Component/Ingredient CAS# Percent Present (Range)
Portland cement 65997-15-1 10-20
Fly Ash* 68131-74-8 4-10
Sand (may be composed of varying granitic and silicate materials) None 0-82
Mineral aggregates None 0- 85
Nuisance Dusts (Particulates not otherwise regulated) None < 1- 5
Crystalline Silica (quartz - respirable) 68131-74-8 0 < 0.1
Other Components
Packaged Concrete and Sand Mixes are made primarily from materials mined from the earth. A chemical analysis of the material may reveal trace
amounts of naturally occurring but potentially harmful chemical compounds such as organic compounds, potassium and sodium compounds, and heavy
metals including cadmium, chromium (including hexavalent chromium), nickel and lead. See Section 16 for additional information.
* Fly ash is a by-product of coal combustion and is primarily composed of silicates and metallic oxides. The exact composition will vary depending on
the source of the coal.
Section 4 - First Aid Measures

Description of First Aid Measures
Eyes Rinse eyes and under lids cautiously with clean water for at least 15 minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.
Skin Remove contaminated clothing. Remove dry material from skin, but avoid creating dust. Wash
with plenty of water. If skin irritation occurs, get immediate medical advice/attention.
Inhalation Remove person to fresh air away from dust and keep comfortable for breathing. If coughing
persists, obtain medical attention.
Ingestion Do not induce vomiting. If subject is conscious, rinse the mouth with water to remove any
material and drink plenty of water to dilute any swallowed material. Do not give drink or
attempt to force water to an unconscious person. Get medical advice/attention.
Important Symptoms and Effects (Acute and Delayed)
Eyes Causes serious eye irritation and may scratch eye surface due to particle abrasion. May cause
chemical burns resulting in corneal damage.
Skin Causes skin irritation if exposed to moisture on skin creating redness, dryness and itching.
Extended exposure to wet material will result in chemical burns to skin, possibly severe.
Inhalation May irritate nose and throat if dust is inhaled. Prolonged or repeated inhalation of respirable
dust may lead to respiratory tract or lung damage.
Ingestion May cause irritation and burns of mouth, throat, stomach and digestive tract if swallowed.
Recommendations for Immediate Medical Care or Special Treatment
Seek immediate medical attention for inhalation of large quantities of dust or exposure of wet material over large areas of skin.
Seek immediate medical attention if material comes into contact with eyes and cannot be immediately removed.
Section 5 - Fire Fighting Measures

General Fire Hazards None. Material is not considered flammable or combustible.
Extinguishing Media Use water or water spray to extinguish any fires involving this material.
Extinguishing Media to Avoid None.
Hazards of Combustion None.
Fire Fighting Recommendations Firefighters should always wear full protective gear to fight any fire.
Refer to Section 9 for flammability information.
Section 6 - Accidental Release Measures

Precautions Avoid creating dust. Prevent material from entering sewers, drains, ditches or waterways.
Personal Protection Wear respiratory protection and protective eyewear/clothing to avoid eye or skin contact.
Emergency Procedures Ventilate area and avoid creating dust. Remove unnecessary persons from area.
Containment Procedures Barricade solid material to prevent additional spillage.
Clean Up Procedures Scoop or vacuum up spilled material while avoiding dust creation. Scoop up wet material and
place in approved container. Allow wet material to harden before disposal.
Page 30 of 516
SAFETY DATA SHEET: PACKAGED CONCRETE AND SAND MIXES REVISION DATE: 5/28/15 PAGE 3
- Section 7 - Handling and Storage

Safe Handling Practices Avoid contact with skin or eyes. Avoid breathing dust. Use only in well ventilated areas. Wear
appropriate personal protective equipment to prevent eye or skin contact and use respiratory
protection equipment if dusty or in poorly ventilated areas.
Safe Storage Measures Store in well-ventilated areas away from moisture and incompatible materials. If stored in
containers, keep containers closed when not in use.
Incompatible Materials Water/moisture exposure will cause material to generate heat. Keep away from fluoride
compounds, strong acids, aluminum, and oxidizers. Cement dissolves in hydrofluoric acid,
producing corrosive silicon tetrafluoride gas.
Section 8 - Exposure Controls & Personal Protection

Exposure Limits for Individual Components (T= Total Respirable, R=Respirable fraction, l=lnhalable-aerosol)
Component OSHA PEL ACGIH TLV NIOSH REL
Portland cement 15 mg/m3 (T); 5 mg/m3 (R) 1 mg/m3 (R) 10 mg/m3 (T); 5 mg/m3 (R)
Fly ash 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 (T); 3 mg/m3 (R) Not established
Mineral aggregates None None None
Nuisance Dusts (PNOR) 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 Not established
Crystalline Silica (Quartz) 10 mg/m3 (R) /(% SiO2 + 2) 0.025 mg/m3 (R) 0.05 mg/m3 (R)
30 mg/m3 (T) /(% SiO2 + 2)
Exposure Controls
Engineering Controls Use outdoors in well-ventilated areas; otherwise employ natural or mechanical ventilation to
maintain exposure within applicable limits.
Personal Protection Avoid contact with skin or eyes. Avoid creating or breathing dust.
Face and Eyes Safety glasses with side shields or protective goggles should be worn while using this product.
For extremely dusty conditions, non-vented goggles or goggles with indirect venting are
recommended. Avoid contact lens wear when using this product.
Body Long sleeved shirts and trousers should be worn while using this material. Wear water-proof
boots. If working in dusty conditions, impervious over garments are recommended.
Respiratory If exposure levels cannot be maintained below acceptable limits, suitable particulate-filtering
facemasks or respirators approved by MSHA/NIOSH should be worn in accordance with the
user's respiratory protection program and OSHA/MSHA guidelines.
Hands Protective gloves with wrist/arm cuffs should be worn to avoid direct contact with skin.
Section 9 - Physical and Chemical Properties

Physical State Solid mix, powder/granules Specific Gravity 3.1- 3.2
Appearance & Color Grey/tan/off-white mixture Flash Point/Method None. Not flammable.
Odor None Auto Ignition Temperature Not determined
pH >12 (in water) Lower Flammability Limit Not applicable
Boiling Point Not applicable Upper Flammability Limit Not applicable
Solubility (Water) Slight (<5%) Octanol/H2O Coefficient Not determined
Evap_oration Rate Not applicable Viscosity Not applicable
Melting Point Not determined Freezing Point Solid at room temperature
Vapor Density Not applicable Explosion Risk: Static Not considered a hazard
Vapor Pressure Not applicable Explosion Risk: Shock Not considered a hazard
Section 10 - Stability and Reactivity

Reactivity Reacts with water to create heat and calcium hydroxide.
Chemical Stability Stable at standard temperature and pressures.
Hazardous Reactions None. Hazardous polymerization will not occur.
Conditions to Avoid Moisture or wetting will cause exothermic heating as product cures.
Incompatible Materials Avoid contact with strong acids, oxidizers aluminum and ammonium salts.
Decomposition Hazards Reacts with water to form calcium hydroxide which can irritate/damage skin. Cement dissolves
in hydrofluoric acid, producing corrosive silicon tetrafluoride gas.
Page 31 of 516
SAFETYDATASHEET:PACKAGED
CONCRETE
AND SAND MIXES REVISIONDATE:S/28/15 PAGE4
- Section 11- Toxicological Information
Product: Packaged concrete and sand mixes
Acute Toxicity Not classified.
LDS0/LCS0 Data Not classified.
Skin Corrosion/Irritation Causes irritation or chemical burns if exposed to moisture on skin.
Critical Eye Damage/Irritation Causes serious eye injury due to chemical burns or mechanical irritation.
Respiratory or Skin Sensitization Not reported/no data available.
Germ Cell Mutagenicity Not reported/no data available.
Teratogenicity Not reported/no data available.
Carcinogenicity Material contains trace amounts of respirable crystalline silica, which may cause lung
cancer through repeated or prolonged exposure to dust.
Specific Organ Toxicity (Single Exposure) May cause respiratory irritation.
Specific Organ Toxicity (Repeated Exposure) May cause damage/disease to lungs through repeated or prolonged exposure.
Reproductive Toxicity Not reported/no data available.
Aspiration Respiratory Hazard Not reported/no data available.
Symptoms: Inhalation Coughing, sneezing, mucous discharge and dyspnea. Extended contact may lead to
chemical burns to mucous membranes.
Symptoms: Skin Contact Redness and itching. Extended contact may lead to chemical burns.
Symptoms: Eye Contact Redness and itching. Extended contact may lead to corneal abrasion/ulceration.
Symptoms: Ingestion Irritation and chemical burns of mouth and throat.
Other Toxicological Information No additional data available.
Components Toxicity Care: IARC Care: NTP Care: OSHA
Portland cement No data Not listed Not listed Not listed
(refer to Section 16 for more information)
Fly ash No data Not listed Not listed Not listed
Mineral aggregates No data Not listed Not listed Not listed
Nuisance dusts (PNOR) No data Not listed Not listed Not listed
Crystalline Silica (Quartz) Oral LOSORat >22,500 mg/kg Group 1 Known Not listed
(refer to Section 16 for more information) LCS0Carp >10,000 mg/L (72 hr)
Section 12 - Ecological Information

General Ecotoxicity Not classified.
Persistence and Degradability Not reported/no data available.
Bioaccumulation Potential Not reported/no data available.
Mobility in Soil to Groundwater Not reported/no data available.
Environmental Fate Not reported/no data available.
Other Environmental Avoid release to the environment. Prevent material from entering sewers, drains, ditches or
Precautions or Information waterways.
Section 13 - Disposal Considerations _

Disposal Methods Dispose as an inert, non-metallic mineral in accordance with applicable federal, state, and local
regulations.
Special Considerations Avoid creation or breathing dust during disposal. Avoid contact with skin and eyes. Refer to
Section 8 for personal protection measures.
Other Disposal Information Prevent material from entering sewers, drains, ditches or waterways.
Section 14 -Transport Information

Proper Shipping Name N/ A - not regulated.
Hazard Class N/A- not regulated.
UN Shipping ID Number N/ A - not regulated.
Packing Group N/A- not regulated.
Environmental/lMDG Codes N/A- not regulated.
Page 32 of 516
AND SAND MIXES
CONCRETE
SAFETYDATASHEET:PACKAGED REVISIONDATE:S/28/15 PAGE5
Section 15- Regulatory Information
Federal
This product contains one or more chemical components or ingredients that may require identification and/or reporting under SARA
Section 302, SARA Section 311/312/313, CERCLAand/or TSCA. An examination of the components of this product should be
conducted by a qualified environmental professional to determine if such identification or reporting is required by federal law.
• Components: Portland cement, Silica (Crystalline)
State
This product contains one or more chemical components or ingredients that are included or listed on the hazardous substances lists
for one or more of the following states: California, Maine, Minnesota, New Jersey, Pennsylvania and Rhode Island. An examination
of the components of this product should be conducted by a qualified environmental or safety and health professional to determine
the specific requirements for those states.
The state of California requires the following statement (Proposition 65) in regards to this material;
• WARNING! This product contains chemicals known to the state of California to cause cancer, birth defects or other
reproductive harm.
~ Section 16 - Other Information

Date of last revision: May 29, 2015 Prepared and reviewed by: Holcim (US) Inc. Occupational Safety & Health
Additional information regarding products containing portland cement:

Wet portland cement can cause caustic burns to unprotected skin, sometimes referred to as cement burns. Cement burns may
result in blisters, dead or hardened skin, or black or green skin. In severe cases, these burns may extend to the bone and cause
disfiguring scars or disability.
Employees cannot rely on pain or discomfort to alert them to cement burns because cement burns may not cause immediate pain or
discomfort. By the time an employee becomes aware of a cement burn, much damage has already been done. Accordingly, the
safest method to use portland cement is to avoid contact with exposed skin completely. Cement burns can get worse even after skin
contact with cement has ended. Any employee experiencing a cement burn is advised to see a health care professional immediately.
Skin contact with wet portland cement can also cause inflammation of the skin, referred to as dermatitis. Signs and symptoms of
dermatitis can include itching, redness, swelling, blisters, scaling, and other changes in the normal condition of the skin. Contact with
wet portland cement can cause a non-allergic form of dermatitis (called irritant contact dermatitis) which is related to the caustic,
abrasive, and drying properties of portland cement.
In addition, hexavalent chromium [Cr(VI)] which may be found in portland cement in trace amounts, can cause an allergic form of
dermatitis (allergic contact dermatitis, or ACD) in sensitized employees who work with wet portland cement. When an employee is
sensitized, that person's immune system overreacts to small amounts of Cr(VI), which can lead to severe inflammatory reactions
upon subsequent exposures. Sensitization may result from a single Cr(VI) exposure, from repeated exposures over the course of
months or years, or it may not occur at all. After an employee becomes sensitized, brief skin contact with very small amounts of
Cr(VI) can trigger ACD. ACD is long-lasting and employees can remain sensitized to Cr(VI) years after their exposure to portland
cement has ended. Medical tests (e.g. skin patch tests) are available that can confirm whether an employee has become dermally
sensitized to Cr(VI).
Employees who work with wet portland cement and experience skin problems, including seemingly minor ones, are advised to see a
health care professional for evaluation and treatment. In cement-related dermatitis, early diagnosis and treatment can help prevent
chronic skin problems.
Additional information regarding crystalline silica:

The major concern is silicosis, caused by the inhalation and retention of respirable (extremely small) crystalline silica dust particles.
Silicosis can exist in several forms. Chronic or ordinary silicosis (often referred to as simple silicosis) is the most common form of
silicosis, and can occur after many years of exposure to relatively low concentrations of airborne respirable crystalline silica dust.
Complicated silicosis or progressive massive fibrosis (PMF) may be associated with decreased lung function and may be disabling.
Advanced complicated silicosis or PMF may lead to death. Advanced complicated silicosis or PMF can result in heart disease
secondary to the lung disease. Acute silicosis can occur with exposures to very high concentrations of respirable crystalline silica
Page 33 of 516
SAFETYDATA SHEET: PACKAGEDCONCRETEAND SAND MIXES REVISION DATE: 5/28/15 PAGE6
over a very short time period, sometimes as short as a few months. The symptoms of acute silicosis include progressive shortness of
breath, fever, cough and weight loss. Acute silicosis can be fatal.
IARC: The overall IARC evaluation was that "crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (Group l)." The IARC evaluation noted that "carcinogenicity was not detected in all industrial
circumstances studies. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors
affecting its biological activity or distribution of its polymorphs."
NTP: The National Toxicology Program (NTP), in its Thirteenth Annual Report on Carcinogens, classified "silica, crystalline
(respirable)" as a known human carcinogen.
OSHA: Crystalline silica (quartz) is not regulated as a human carcinogen by the Occupational Safety and Health Administration.
Other important information:

While the information provided in this document is believed to provide a useful summary of the hazards of packaged concrete and
sand mixes, the information in this document cannot anticipate and provide all of the information that might be needed in every
situation. Inexperienced product users should obtain proper training before using this product.
The data furnished in this document do not address hazards that may be posed by other materials when mixed with packaged
concrete and sand mixes. Users should review other relevant safety data sheets before working with this product.
The information presented in the Safety Data Sheet is based on current knowledge and publications and is intended to describe the
product for the purposes of health, safety and environmental requirements only. It should not be interpreted as guaranteeing any
specific property of the product.
SELLER MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS
THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY HOLCIM (US) INC., EXCEPT
THAT THE PRODUCT SHALL CONFORM TO CONTRACTED SPECIFICATIONS.
--END OF SAFETY DATA SHEET--
Page 34 of 516
W R. MEADOWS,,
SAFETYDATA SHEET
uct:
1"rt>d CS-309™ OTC Part Number: 3518000
In case of emergency, dial (800) 424-9300 (CHEMTREC)

IHealth I 111 Danger!
IFlammability I 131 Highly flammable liquid and vapor.
IReactivity I 101 Harmful if Inhaled. Causes skin/eye/respiratory irritation.
IPersonal Protection I I I Prolonged/repeated exposure may cause organ damage.
May be fatal if ingested and enters airways.
Keep containers closed when not in use/avoid ignition sources.
Store in well-ventilated Location.
Wear appropriate Personal Protective Equipment.
Use only outdoors or in well-ventilated areas.
Vapor Pressure
Chemical Name: CAS Number 313 (mm Hg@20°Cl
1. Acetone 67-64-1 No 24 kPa
2. Proprietary Solvent Blend N/E 45-50 No N/E N/E
Under the reporting requirements of Section 313 of Title Ill of the 5uperfund Amendments and Reauthorization Act of 1966 (SARA)and 40 CFR
Part 372, chemicals listed on the 313 List CFRPart 373.65) are identified under the headin "SARA 313." N/E: Not Established
-- iliii!I -:~,[ii_fflf~ill!!N~ ~~-,
EYE CONTACT: If irritation or redness develops, move victim from exposure source and into fresh air. Flush eyes with water for fifteen (15)
minutes. If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water; remove contaminated shoes/clothing. If symptoms persist, seek medical
attention.
INHALATION: If respiratory symptoms develop, move victim from exposure source and into fresh air. If symptoms persist, seek medical
attention. If victim is not breathing, immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by
qualified personnel.
INGESTION: Dilute with liquid unless the victim is unconscious or very drowsy. Do not induce vomiting. If vomiting spontaneously occurs,
prevent lung aspiration. Seek immediate medical attention.
- - -
~~:a.:-;:,:;o=t/J:c:.liS:l=':"'J=:_i:::!,
Chemical Name: PEL PEL/STEL SKIN TWA TLV/CEILING TLV/STEL SKIN

1. Acetone 1000 ppm N/E Yes 500 ppm N/E 750 ppm Yes
2. Proprietary Solvent Blend N/E N/E N/E N/E N/E N/E N/E
N E: Not Established
Page 35 of 516
SAFETYDATA SHEET
SECTION8 continued
ENGINEERING CONTROLS:Use with adequate ventilation. Use explosion-proof equipment.
PERSONALPROTECTIVE EQUIPMENT:Safety glasses, chemical-resistant gloves.
EYECONTACT:Direct contact may cause mild to moderate irritation. Product vapors may also cause irritation.
SKINCONTACT:Direct contact may cause mild skin irr"itation. Prolonged/repeated contact may result in irritation/dermatitis.
INHALATION:Exposure may produce irritation to the nose, throat, respiratory tract, and other mucous membranes. Exposure to excessive
vapor concentrations may cause signs of transient central nervous system depression (headache, drowsiness, loss of coordination, and fatigue).
Repeated/prolonged occupational overexposures may result in permanent damage and can be potentially fatal.
INGESTION: This product is anticipated to be slightly toxic. If ingested and lung aspiration occurs, serious lung damage may result. Ingestion of
excessive quantities may result in symptoms of central nervous system depression.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include reddening,
swelling, rash, and redness. Symptoms of gastrointestinal irritation include abdominal pain, vomiting and diarrhea. Symptoms of respiratory
irritation include runny nose, sore throat, coughing, chest discomfort, shortness of breath, reduced lung function, and symptoms of central
nervous system depression.
AGGRAVATED
MEDICALCONDITIONS:Pre-existing skin, lung, liver, kidney, central nervous system, male reproductive, immune, and auditory
systems may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:Prolonged/repeated exposure may affect the central nervous system. Animal studies have shown fetal harm. The
relevance to humans is uncertain. Target organs include the kidneys, liver, spleen, adrenals, lungs, central nervous system, and cardio-
vascular system.
HAZARDOUS/NON-HAZARDOUS MATERIAL:Hazardous.
UN NUMBER: 1866 HAZARDCLASS:3 PACKINGGROUP: II
UN PROPERSHIPPINGNAME: Resin Solution.
ENVIRONMENTAL HAZARDS:Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
BULKTRANSPORTATION INFORMATION:Not applicable. Product not shipped in bulk configuration.
SPECIALPRECAUTIONS: Keep containers closed. Avoid ignition sources.
IT:::t;T
Dave Carey
Page 36 of 516
W. R.MEADOWS,,
SAFETYDATA SHEET
Product: MED-CURE™, DUST-GARD, CURE-HARD Part Number: 3310000

Ploduct Use: Concrete Hardener/Curing Aid

IFlammability I 101 Causesskin irritation.
IReactivity I 101 Causesserious eye irritation
IPersonal Protection I I I May cause respiratory irritation
Avoid breathin mists/sprays.
___ ~==-
"""!JJ=.ll3l:,::';~:ci:,l;:i:-~\-::i:l;aw""~_.

Chemical Name: CAS Number Weight 313 (mm Hg@20°CI ~
1. Sodium Silicate 1344-09-8 5-10 No <1 N/A
Under the reporting requirements of Section 313 ofTitle Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA)and 40
CFRPart 372 chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the headin "SARA 313." NA: Not A Jicable
~i~Bii~Jf,Jg
th water for fifteen (15) minutes. Seek prompt medical attention.
mild soap and water. Remove contaminated shoes/clothing. Seek prompt medical attention.
osure route as supplied. If respiratory symptoms develop, seek medical attention.
ictim is unconscious or very drowsy. Do not induce vomiting. If vomiting spontaneously occurs,
)~ ~~~~!
ical.
zed.
T: Use appropriate personal protective e ui ment.
~ .'.·•·
51~f4'111'lfilllllfjl
Dike and contain spilled materi
ntainers for proper disp
ACGIH
Chemical Name: PEL PEL/CEILING PEL/STEL SKIN TWA TLV/CEILING TLV/STEL SKIN
3 3
1. Sodium Silicate 2 mg/m N/E N/E No 2 mg/m N/E N/E N/E
ENGINEERING CONTROLS: None required under normal use conditions. N/E: Not Established
PERSONAL PROTECTIVE EQUIPMENT: Safet lasses, chemical resistant gloves.
-~~..... l,IJQi)tiJ:,lglvi~iil ..
TY: N/A % VOLATILE
70 ~:::~~::: % VOLATILE
STABILITY: Stable. HAZARDOUS POLYMERl2ATION: Will not occur.

CONDITIONS AND MATERIALS TO AVOID: Strong acids.
HAZARDOUS DECOMPOSITION PRODUCTS: None recognized
Page 37 of 516
EYE CONTACT: Direct contact may cause moderate to severe irritation. This product may cause corneal injury resulting in permanent
vision impairment/blindness.
SKIN CONTACT: Direct contact may cause moderate skin irritation. Prolonged contact may result in skin damage.
INHALATION: Not anticipated to be an exposure route. Inhalation of mists may cause moderate to severe respiratory tract irritation.
INGESTION: Not anticipated to be an exposure route. May cause severe irritation of the gastrointestional tract if ingested.
SIGNS AND SYMPTOMS: This product will cause moderate to severe irritation if direct contact occurs. Symptoms will vary from mild
irritation to severe burning based on product concentration and duration of exposure.
··,'/.~ "~ ·~

UN PROPER SHIPPING NAME: N/ A
SPECIALPRECAUTIONS: Prevent product from freezing.
Dave Carey
use thereof We assume no responsibility for injury from the use of this product described herein.
Page 38 of 516
Version: 1.0
EUCLIDCHEMICAL
SAFETY DATA SHEET

I1. Identification
Material name: CONCRETE FINISHER GRAY
Material: TR2107670501

Recommended use: Cement, Portland, chemicals
EUCLID CHEMICAL COMPANY
19218 REDWOOD ROAD
CLEVELAND OH 44110
us
Telephone: 216-531-9222
Emergency telephone number: 1-800-424-9300 (US); 1-613-996-6666 (Canada)
12.Hazard(s) identification
Health Hazards
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 1
Skin sensitizer Category 18
Carcinogenicity Category 1A
Specific Target Organ Toxicity - Category 3
Single Exposure
Unknown toxicity - Health

Acute toxicity, oral 91.73 %
Acute toxicity, dermal 92.23 %
Acute toxicity, inhalation, vapor 100 %
Acute toxicity, inhalation, dust or mist 100 %
Unknown toxicity - Environment

Acute hazards to the aquatic 99.5 %
environment
Chronic hazards to the aquatic 100 %
environment
Label Elements
Hazard Symbol:
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EUCLIDCHEMICAL
Signal Word: Danger
Hazard Statement: Causes skin irritation.

Causes serious eye damage.
May cause an allergic skin reaction.
May cause cancer.
May cause respiratory irritation.
Precautionary
Statement:
Prevention: Wash thoroughly after handling. Wear protective gloves/protective
clothing/eye protection/face protection. Avoid breathing
dust/fume/gas/mist/vapors/spray. Contaminated work clothing must not be
allowed out of the workplace. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Use
personal protective equipment as required. Use only outdoors or in a well-
ventilated area.
Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. IF ON
SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical
advice/attention. Immediately call a POISON CENTER/doctor. Specific
treatment {see this label). Wash contaminated clothing before reuse.
Storage: Store locked up. Store in well-ventilated place. Keep container tightly
closed.
Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
Other hazards which do not None.

result in GHS classification:
ja.Composition/information on ingredients
Mixtures
Chemical Identity CAS number Content in percent(%)*
Crystalline Silica (Quartz)/ 14808-60-7 60- 100%

Silica Sand
Portland cement 65997-15-1 15- 40%
Kaolin Clav 1332-58-7 1-5%
Calcium salt 7778-18-9 0.1 - 1%
Calcium stearate 1592-23-0 0.1 - 1%
• All concentrations are percent by weight unless ingredient Is a gas. Gas concentrations are 1npercent by volume.
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EUCLID CHEMICAL
/4. First-aid measures
Ingestion: Call a POISON CENTER/doctor/ .. ./if you feel unwell. Rinse mouth.
Skin Contact: Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash contaminated clothing
before reuse. Get medical attention.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Call a physician or poison control center
immediately.
Symptoms: Prolonged or repeated contact with skin may cause redness, itching,
irritation and eczema/chapping. Extreme irritation of eyes and mucous
membranes, including burning and tearing. Respiratory tract irritation.
Treatment: Symptoms may be delayed.
js.Fire-fighting measures

media:
media:
the chemical:

procedures:

Personal precautions, See Section 8 of the SOS for Personal Protective Equipment. Do not touch
protective equipment and damaged containers or spilled material unless wearing appropriate
emergency procedures: protective clothing. Keep unauthorized personnel away.
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EUCLIDCHEMICAL
Methods and material for Collect spillage in containers, seal securely and deliver for disposal
containment and cleaning according to local regulations.
up:
Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe lo do so.
j7.Handling and storage

Precautions for safe handling: Do not handle until all safely precautions have been read and understood.
Obtain special instructions before use. Use personal protective equipment
as required. Do not get in eyes. Wash hands thoroughly after handling.
Avoid contact with skin. Ventilate well, avoid breathing vapors. Use
approved respirator if air contamination is above accepted level. Use
mechanical ventilation in case of handling which causes formation of dust.
Conditions for safe storage, Store locked up.

including any
incompatibilities:
ja.Exposure controls/personal protection

Control Parameters
Chemical Identity type Exposure Limit Values Source

Crystalline Silica TWA 0.025 US. ACGIH Threshold Limit Values
(Quartz)/ Silica Sand - mg/m3 (2011)
Respirable fraction.
Crystalline Silica TWA 2.4 US. OSHA Table Z-3 (29 CFR
(Quartz)/ Silica Sand - millions of 1910.1000) (2000)
Respirable. particles
per cubic
foot of air
TWA 0.1 mg/m3 US. OSHA Table Z-3 (29 CFR
1910.1000) (2000)
Crystalline Silica TWA 0.3 mg/m3 US. OSHA Table Z-3 (29 CFR
(Quartz)/ Silica Sand - 1910.1000) (2000)
Total dust.
Portland cement - TWA 1 mg/m3 US. ACGIH Threshold Limit Values
Resoirable fraction. (2011)
Portland cement- Total PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
dust. Contaminants (29 CFR 1910.1000)
(02 2006)
Portland cement - PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Respirable fraction. Contaminants (29 CFR 1910.1000)
(02 2006)
Portland cement TWA 50 millions US. OSHA Table Z-3 (29 CFR
of particles 1910.1000) (2000)
per cubic
foot of air
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Kaolin Clay - TWA 2 mg/m3 US. ACGIH Threshold Limit Values

Respirable fraction. (2011)
PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000)
(02 2006)
Kaolin Clay-Total PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
(02 2006)
Calcium salt - lnhalable TWA 10 mg/m3 US. ACGIH Threshold Limit Values
fraction. (2011)
Calcium salt- Total PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
(02 2006)
Calcium salt - PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Respirable fraction. Contaminants (29 CFR 1910.1000)
(02 2006)
Calcium stearate TWA 10 mg/m3 US. ACGIH Threshold Limit Values
(2011)
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EUCLID CHEMICAL
Chemical name type Exposure Limit Values Source
Crystalline Silica TWA 0.025 Canada. British Columbia OELs.

(Quartz)/ Silica Sand - mg/m3 (Occupational Exposure Limits for
Respirable fraction. Chemical Substances, Occupational
Health and Safety Regulation 296/97,
as amended) (07 2007)
Crystalline Silica TWAEV 0.10 Canada. Ontario OELs. (Control of
(Quartz)/ Silica Sand - mg/m3 Exposure to Biological or Chemical
Resoirable. Agents) (11 2010)
Crystalline Silica TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of
(Quartz)/ Silica Sand - Labor - Regulation Respecting the
Respirable dust. Quality of the Work Environment) (12
2008)
Portland cement - TWA 10 mg/m3 Canada. British Columbia OELs.
Total dust. (Occupational Exposure Limits for
Chemical Substances, Occupational
Portland cement - TWA 3 mg/m3 Canada. British Columbia OELs.
Respirable fraction. (Occupational Exposure Limits for
Portland cement TWAEV 10 mg/m3 Canada. Ontario OELs. (Control of
Exposure to Biological or Chemical
Agents) (11 2010)
Portland cement - TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of
Total dust. Labor - Regulation Respecting the
Quality of the Work Environment) (12
2008)
Portland cement - TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of
Respirable dust. Labor - Regulation Respecting the
2008)
Kaolin Clay - TWA 2 mg/m3 Canada. British Columbia OELs.
Respirable. (Occupational Exposure Limits for
as amended) (07 2007}
Kaolin Clay - TWAEV 2 mg/m3 Canada. Ontario OELs. (Control of
Respirable fraction. Exposure to Biological or Chemical
Aaents) (11 2010)
Kaolin Clay - TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of
Respirable dust. Labor - Regulation Respecting the
2008)
Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required.

Controls Observe good industrial hygiene practices. Observe occupational exposure
limits and minimize the risk of inhalation of dust.
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EUCLID CHEMICAL
General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 1Oair changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level.
Eye/face protection: Wear a full-face respirator, if needed. Wear safety glasses with side shields
(or goggles) and a face shield.
Skin Protection
Other: Wear chemical-resistant gloves, footwear, and protective clothing

appropriate for the risk of exposure. Contact health and safety professional
or manufacturer for specific information.
local supervisor.
Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Do not get in eyes. Wash
contaminated clothing before reuse. Avoid contact with skin.
19.
Physical and chemical properties
Appearance
Physical state: solid
Form: Powder
Color: Gray
Odor: Odorless
pH: No data available.
Evaporation rate: No data available.
Explosive limit• upper(%): No data available.
Explosive limit - lower (%): No data available.
Vapor density: No data available.
Solubility(ies)
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EUCLIDCHEMICAL
Solubility in water: Miscible with water.

j10.Stability and reactivity

ReactiVity: No data available.
Possibility of Hazardous No data available.

Reactions:
Conditions to Avoid: Avoid heat or contamination.
Incompatible Materials: No data available.
]11. Toxicological information

mucus membranes.
Skin Contact: Causes skin irritation.
Eye contact: Causes serious eye damage.
Oral
Dermal
Inhalation

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Serious Eye DamagefEye Irritation

Calcium salt in vivo (Rabbit, 72 hrs): Not irritating

Carcinogenicity
Crystalline Silica Overall evaluation: Carcinogenic to humans.

(Quartz)/ Silica
Sand

Crystalline Silica Known To Be Human Carcinogen.
(Quartz)/ Silica
Sand

In vitro
In vivo


Aspiration Hazard
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Other effects: No data available.
j12. Ecological information
Ecotoxicity:
Fish
Calcium salt LC 50 (Fathead minnow (Pimephales promelas), 96 h): > 1,970 mg/I
Mortality
Calcium salt LC 50 (Water flea (Daphnia magna), 24 h): > 1,970 mg/I Mortality
LC 50 (Water flea (Ceriodaphnia dubia), 24 h): > 1,940 mg/I Mortality
Fish

Biodegradation
BOD/COD Ratio
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Partition Coefficient n-octanol / water (log Kow)

Mobility in Soil: No data available.
Other Adverse Effects: No data available.
113.Disposal considerations
114.
Transport information
TOG:
Not Regulated
CFR/ DOT:
Not Regulated
IMDG:
Not Regulated
115.Regulatory information



Hazard categories
Immediate (Acute) Health Hazards
Delayed (Chronic) Health Hazard
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EUCLIDCHEMICAL



Crystalline Silica (Quartz)/ S00lbs
Silica Sand
Portland cement S00lbs
Kaolin Clay S00lbs
Calcium salt S00lbs
Calcium stearate 500Ibs

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):

This product contains chemical(s) known to the State of California to cause cancer and/or to
cause birth defects or other reproductive harm.

Chemical Identity
Crystalline Silica (Quartz)/ Silica Sand
Portland cement
Kaolin Clay

Chemical Identity
Portland cement
Kaolin Clay

Chemical Identity
Portland cement
Kaolin Clay

Other Regulations:
Regulatory voe (less water O g/1

and exempt solvent):
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Version: 1.0
EUCLIDCHEMICAL
voe Method 310: 0.00 %
Inventory Status:
Australia AICS: One or more components in this product are
Canada DSL Inventory List: One or more components in this product are





New Zealand Inventory of Chemicals: One or more components in this product are


Version#: 1.0
13/14
000000007150
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Version: 1.0
EUCLID CHEMICAL
14/14
000000007150
Page 52 of 516
W R..MEADOWS"
SAFETYDATA SHEET
Page 1 of 2
Product: DUOGARD® Part Number: 3915000

9/9/2014
SARA Vapor Pressure

Chemical Name: CAS Number %by Weight 313 (mm Hg@20°Cl
1.None
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of
1966 (SARA) and 40 CFR Part 372, chemicals listed on the 313 List (40 CFR Part 373.65) are identified under the heading
"SARA 313."
'.;i~~q:~ ..~-:
Flush eyes with water for fifteen (15) minutes. If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water. Remove contaminated shoes/clothing. If symptoms
persist, seek medical attention.
INHALATION: Not expected to be an exposure route as supplied. If respiratory symptoms develop, seek
medical attention.
INGESTION: Dilute with liquid unless the victim is unconscious or very drowsy. Do not induce vomiting. If vomiting
spontaneously occurs, prevent lung aspiration. Seek immediate medical attention .
.=~
lrl!I~~ .
$tilG@ll!J!EX!Q;~
ater fog, foam, dry chemical, carbon dioxide.
HAZARDS: Carbon monoxide, carbon dioxide, and incomplete combustion products.
L PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Use appropriate personal protective
RES: Avoid direct contact. Dike and contain spilled material. Remove source of spill if safe to
d place clean-up material in sealed/marked containers for proper disposal. Clean-up
Chemical Name: PEL SKIN

1. None
BOILING POINT: N/E

... ,.
PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical-resistant gloves .
- -,·,~-~)
VAPOR DENSITY: N/A
pH LEVEL: N/ A
...
% VOLATILE BY WEIGHT: 100
EVAPORATION RATE: <1 (Ether=l)
WEIGHT PER GALLON: 7.25 PRODUCT APPEARANCE: Amber Liquid voe CONTENT: 82 g/L
~Ni*QJ~
~,~~
STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS AND MATERIALS TO AVOID: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and incomplete combustion products.
Page 53 of 516
Date of Preparation: 9/9/14 3915000
EYECONTACT:Direct contact may cause mild irritation.

SKINCONTACT:Direct contact may cause slight skin irritation. Prolonged/repeated contact may result in irritation.
INHALATION:Not anticipated to be an exposure route.
INGESTION:Not anticipated to be an exposure route.
SIGNSAND SYMPTOMS:Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation
include redness and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
Symptoms of respiratory irritation include ruynny nose, sore throat, coughing, chest discomfort, shortness of breath, and
reduced lung function.
AGGRAVATED
MEDICAL
CONDITIONS:
Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to
this product.
OTHERHEALTH
EFFECTS:None recognized.
DEGRADABILITV:
N/E BIOACCUMULATIVE
POTENTIAL:N/E
HAZARDOUS/NON-HAZARDOUS MATERIAL:Not regulated by DOT.

UN NUMBER: None. HAZARDCLASS:N/A PACKINGGROUP: N/A
UN PROPERSHIPPINGNAME: N/A
BULKTRANSPORTATIONINFORMATION:None.
SPECIALPRECAUTIONS: None recognized.
Dave Carey
Page 54 of 516
W R. MEADOWS.,
SAFETYDATA SHEET
Page 1 of 2
~ --·_:J)Aml!~ijJl1i~)~C
<:: ~"~--~ -
4
Product: TIAH® Part Number: 3521000

In case of emergency, dial (800) 424-9300 (CHEMTREC)

IFlammability I 121 Causes skin/eye irritation.
IReactivity I 101 Flammable liquid and vapor.
IPersonal Protection I I I Harmful if inhaled.
May be fatal if ingested and enters airway.
Use only in well-ventilated areas.
Control vapors in confined spaces utilizing mechanical ventilation.

Chemical Name: CAS Number % bl£Weight 313 {mm Hg@20°C} f.@1i:9.
1. Aromatic Naphtha 64742-95-6 50-55 No <10@ 25•c 0.9
2. Xylene 1330-20-7 1-5 Yes 6.6 1.1
3. 1,2,4-Trimethylbenzene 95-63-6 15-20 Yes N/E 0.9
4. Ethylene Glycol Monobutyl
Ether Acetate 112-07-2 1-5 Yes 0.29 0.50 @ 93°C
Part 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA 313." N/E: Not Established
- =,1q111~~D11E~[im
EYE CONTACT: Flush eyes with water for fifteen (15) minutes. If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water. Remove contaminated shoes/clothing. If symptoms persist, seek medical attention.
INHALATION: If respiratory symptoms develop move affected individual from exposure source and into fresh air. If symptoms persist, seek
medical attention.
~ ~i~liilFl,RElirl)~
~--::--:c- , _-
FLASHPOINT: 105 degrees F (Estimate)
PRECAUTIONS PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Use appropriate per
-iJl!Et/.lT~"f;iia:~CC:::~:::~"
ources. Dike and contain spill
marked containers for pro
OSHA ACGIH
Chemical Name: PEL PELLCEILING PEL[STEL SKIN TWA TLVLCEILING TLVLSTEL SKIN
1. Aromatic Naphtha N/E N/E N/E No N/E N/E N/E N/E
2. Xylene 100 ppm N/E N/E No 100 ppm N/E 150 ppm No
4. Ethylene Glycol Mono-
butyl Ether Acetate N/E N/E N/E N/E N/E N/E N/E Yes
N E: Not Established
Page 55 of 516
SAFETYDATA SHEET
Section 8 continued
ENGINEERING CONTROLS: Use with adequate ventilation. Use explosion-proof equipment.
PERSONAL PROTECTIVE EQUIPMENT: Safe lasses chemical-resistant loves.
TERIALS TO AVOID: Oxidizing agents, strong acids, and strong alkalies.

POSITION PRODUCTS: Carbon monoxide, carbon dioxide, and incom lete combustion products.
'.'
~DXtQOJgG(;
SKIN CONTACT: Direct contact may cause slight skin irritation. Prolonged/repeated contact may result in irritation/dermatitis.
INHALATION: Exposure may cause irritation of the nose, throat, respiratory tract, and other mucous membranes. Exposure to excessive vapor
concentrations may cause signs of transient central nervous system depression (headache, fatigue, drowsiness, dizziness, loss of coordination}.
INGESTION: May result in irritation of the gastrointestional tract. Ingestion of excessive quantities may result in symptoms of transient central
nervous system depression as noted above.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function. Symptoms of transient central nervous
system depression include: headache, fatigue, drowsiness, dizziness, and loss of coordination.
OTHER HEALTH EFFECTS: Ethylene Glycol Monobutyl Ether has been shown to cause the following effects in laboratory animals: Mild reversible
liver/kidney effects, blood abnormalities, cancer, and harm to the fetus. The relevance to humans is uncertain.
"[jJ ill
HAZARDOUS NON-HAZARDOUS MATERIAL: Not regulated by DOT (Domestic Land Transportation}.

Dave Carey
Page 56 of 516
SAFETY DATA SHEET
1. Identificatfon
Product identifier Crafco Roadsaver, Polyflex, Parking lot, Asphalt Rubber, DF, Superflex, Matrix Binder,
loop Detector, Pavement Joint Adhesive, Polyfiber, Fiber Asphalt, Marker Adhesive,
Quikstix, Asphalt Adhesive, PCF 100, High-Slope, QWIKSEAl, QWIKDOT
Other means of identification Not available.
Recommended use Pavement Crack and Joint Sealing and Preservation
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer: Crafco, Inc.
Address: 6165 West Detroit St.
Chandler, AZ 85226 USA
Contact Name: Jim Chehovits
Telephone: 602-276-0406
E-mail: jim.chehovits@crafco.com
CHEMT REC: 800-424-9300 (North America)
+ 1-703-527-3887 (International)
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.
*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".
label elements
Hazard symbol None.
Signal word Not applicable.
Hazard statement Not applicable.
Prevention Not applicable.
Response Not applicable.
Storage Not applicable.
Disposal Not applicable.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number 0/o
ASPHALT 8052-42-4 20 - 100
DISTILLATES (PETROLEUM), 64742-52-5 0 -40

HYDROTREATEDHEAVY
NAPHTHENIC
Other components below reportable levels 0 - 75
Composition comments * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First-aid measures
Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention, if needed. Call a physician if symptoms develop or persist.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothtng and shoes. Thoroughly wash (or discard) clothing and shoes
before reuse.
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen sos us
Page 57 of 516
4988 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 1/ 6
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO
NOT delay irrigation or attempt to remove the lens. Get medical attention if irritation develops and
persists.
Ingestion Rinse mouth. Do not induce vomiting. Do not use mouth-to-mouth method if victim ingested the
substance. Call a POISON CENTERor doctor/physician if you feel unwell.
Most important Not available.
symptoms/effects, acute and
delayed
Indication of immediate In case of ingestion, the decision of whether or not to induce vomiting should be made by the
medical attention and special attending physician. Certain pre-existing conditions may make workers particularly susceptible to
treatment needed the effects of this chemical: asthma, allergies, impaired pulmonary function.
General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance. Discard any shoes or clothing items that cannot
be decontaminated.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Addition of water or foam to the fire
may cause frothing.
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
Specific hazards arising from Fire may produce irritating, corrosive and/or toxic gases. Development of hazardous combustion
the chemical gases or vapours possible in the event of a fire. The following may develop: Acrolein.
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full
firefighters protective clothing including self contained breathing apparatus. Structural firefighters protective
clothing will only provide limited protection.
Fire-fighting In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective
equipment/instructions equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA. ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum
distance or use unmanned hose holders or monitor nozzles. In the event of fire, cool tanks with
water spray. By fire, toxic gases may be formed (COx, NOx). Keep run-off water out of sewers and
water sources. Dike for water control.
Specific methods In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with
water spray. Use water spray to cool unopened containers.
6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
protective equipment and clean-up. Ventilate closed spaces before entering them. Do not touch or walk through spilled
emergency procedures material.
Methods and materials for ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Dike far
containment and cleaning up ahead of spill for later disposal. Following product recovery, flush area with water.
Never return spills in original containers for re-use.

Environmental precautions Prevent further leakage or spillage if safe to do so. Runoff or release to sewer, waterway or ground
is forbidden.
7. Handling and storage

Precautions for safe handling The product is non-combustible. If heated, irritating vapors may be formed. Do not use in area~
without adequate ventilation. Wash hands thoroughly after handling. Wash hands after handling.
Observe good industrial hygiene practices.
Conditions for safe storage, Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in
including any a well-ventilated place. Keep the container tightly closed and dry. Store in a closed container away
incompatibilities from incompatible materials. Keep out of the reach of children.
8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form
DISTILLATES PEL 5 mg/m3 Mist.
(PETROLEUM),
HYDROTREATEDHEAVY
NAPHTHENIC (CAS
64742-52-5)
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDS US
4988 Page 58 of 516
Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 2/6
US. ACGIH Threshold limit Values
ASPHALT (CAS 8052-42-4) TWA 0.5 mg/m3 Inhalable fraction.
US. NIOSH: Pocket Guide to Chemical Hazards

ASPHALT (CAS 8052-42-4) Ceiling 5 mg/m3 Fume.

DISTILLATES STEL 10 mg/m3 Mist.
(PETROLEUM),
HYDROTREATEDHEAW
NAPHTHENIC (CAS
64742-52-5)
TWA 5 mg/m3 Mist.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should
controls be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable level. Ensure adequate
ventilation, especially in confined areas.
Eye/face protection Wear safety glasses; chemical goggles (if splashing is possible). Wear chemical goggles; face shield
(if handling molten material).
Hand protection Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style
gloves.
Other Wear suitable protective clothing and eye/face protection. Use of an impervious apron is
recommended.
Skin protection
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Thermal hazards During product use, there is a risk of thermal burns.

General hygiene When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Keep away from food
considerations and drink. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties

Appearance Solid.
Physical state Solid.
Form Solid.
Color Black. Dark brown
Odor Product is a black, semi-solid with a burnt tar odor.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 150 - 250 °F (65.56 - 121.11 °C) ASTM D36 Softening Point
Initial boiling point and > 800 °F (> 426.67 °C)
boiling range
Flash point > 400.0 °F (> 204.4 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - Not available.
upper(%)
Explosive limit - lower Not available.
(%)
Explosive limit - upper Not available.
(%)
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Page 59 of 516
4988 Version#: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 3/6
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature > 700 °F (> 371.11 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density Not Available
Percent volatile O%
Specific gravity 1 - 1.9
10. Stability and reactivity

Reactivity Not available.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Strong oxidizing agents.
Incompatible materials Incompatible with oxidizing agents.
Hazardous decomposition Upon decomposition, product emits acrid dense smoke with carbon dioxide, carbon monoxide, trace
products oxides of nitrogen and sulfur, and water.
11. Toxicological information

Ingestion May cause gastrointestinal discomfort if swallowed. Do not induce vomiting. Vomiting may
increase risk of product aspiration.
Inhalation May be harmful if inhaled. However, this product does not currently meet the criteria for
classification.
Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis,
Eye contact May be irritating to eyes.
Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Acute toxicity Not classified.
Skin corrosion/irritation Not classified. May cause defatting of the skin, but is neither an irritant nor a sensitizer.
Serious eye damage/eye Not classified.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not classified.
Skin sensitization Not classified.
Germ cell mutagenicity Non-mutagenic based on Modified Ames Assay.
Carcinogenicity This product is not considered to be a carcinogen by !ARC, ACGIH, NTP, or OSHA.
US, OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Contains no ingredient listed as toxic to reproduction
Specific target organ toxicity Not classified.
- single exposure
Specific target organ toxicity Not classified.
- repeated exposure
Aspiration hazard Not classified.
Chronic effects Prolonged or repeated contact may cause drying, cracking, or irritation of the skin.
12. Ecological information

Ecotoxicity This product has no known eco-toxicological effects. Not expected to be harmful to aquatic
organisms.
Persistence and degradability Not available.
Page 60 of 516
Bioaccumulative potential Not available.
Mobility in soil Not available.
Other adverse effects Not available.
13. Disposal considerations

Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.
When this product as supplied is to be discarded as waste, it does not meet the definition of a
RCRAwaste under 40 CFR 261.
Hazardous waste code Not applicable.
Waste from residues / Dispose of in accordance with local regulations.
unused products
Contaminated packaging Offer rinsed packaging material to local recycling facilities.
14. Transport information

DOT
Not regulated as dangerous goods.
IATA
IMDG
Transport in bulk according to Not available.
Annex II of MARPOL 73/78
and the IBC Code
Further information If the product is shipped at temperatures below 212°F (100°C), it is not regulated for transport by
ground, air or vessel. If shipped above 212 deg F: "UN3257, Elevated Temperature Liquid, n.o.s.
(Asphalt mixture), 9, PG III"
15. Regulatory information

US federal regulations All components are on the U.S. EPA TSCA Inventory List.
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Not listed.
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 No
Hazardous chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SOWA)
US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer.
Not regulated.
Not regulated.
Page 61 of 516
Not regulated.
Not regulated.
Not Listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
canada Domestic Substances List (DSL) Yes
canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Substances Yes
(EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision

Issue date 11-25-2013
Revision date 08-18-2015
Version# 08
Further information HMIS® is a registered trade and service mark of the NPCA.
References ACGIH
EPA: AQUIRE database
US. IARC Monographs on Occupational Exposures to Chemical Agents
HSDB® - Hazardous Substances Data Bank
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices
Disclaimer The information in the sheet was written based on the best knowledge and experience currentl)
available. The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
Revision Information Physical & Chemical Properties: Multiple Properties
Toxicological information: Acute toxicity
Toxicological information: Specific target organ toxicity - single exposure
Toxicological information: Specific target organ toxicity - repeated exposure
Toxicological information: Aspiration hazard
Toxicological information: Respiratory sensitization
Transport information: Further information
Regulatory Information: Risk Phrases - Class.
4988 Page 62 of 516
Version#: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 6/6
SAFETY DATA SHEET SDS No: 011-U-GHS
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name: Crystalline Silica in the form of Quartz - various grades
Synonyms: Quartz, Crystalline Silica, Silicon Dioxide
Relevant Identified Uses of the Substance or Mixture and Uses Advised Against:
Product Use: Various co=ercial and industrial uses
Manufacturer:
UNIMIN CORPORATION Emergency Telephone Number
258 Elm Street (203) 966-8880
New Canaan, CT 06840
Telephone Number for Information
(203) 966-8880
SDS Date of Preparation/Revision: April 2014
SECTION 2: HAZARDS IDENTIFICATION
GHS/ Hazcom 2012 Classification:
Physical: Health: Environmental

Not Hazardous Carcinogen Category lA Not Hazardous
Specific Target Organ Toxicity
(Repeated Exposure) Category 1
GHS/Hazcom 2012 Label:
DANGER
Statements of Hazard Prevention
May cause cancer by inhalation. Obtain special instructions before use.
Causes damage to lungs through prolonged or repeated Do not handle until all safety precautions have been read
exposure by inhalation and understood.
Response: Do not breathe dust.
If exposed or concerned: Get medical advice. Do not eat, drink or smoke when using this product.
Disposal: Wear protective gloves and safety glasses or goggles.
Dispose of contents/containers in accordance with local In case of inadequate ventilation wear respiratory
regulation. protection.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
CAS# Com anent Percentage

14808-60-7 Crystalline Silica in the form of Quartz 87 - 99.9%
SECTION 4: FIRST AID MEASURES
Gross Inhalation: Remove victim to fresh air. If breathing has stopped, perform artificial respiration. If breathing is difficult
have qualified personnel administer oxygen. Get prompt medical attention.
011-u-silica-ghs.doc Page 1 of8 Date Prepared: April 2015
Page 63 of 516
SDS No: 011-U-GHS
Skin Contact: No first aid should be needed since dermal contact with this product does not affect the skin. Wash exposed
skin with soap and water before breaks and at the end of the shift.
Eye Contact: Flush the eyes immediately with large amounts of running water, lifting the upper and lower lids occasionally.
If irritation persists or for imbedded foreign body, get immediate medical attention.
Ingestion: If large amounts are swallowed, get immediate medical attention.
Most Important Symptoms and Effects, Both Acute and Delayed: May cause eye irritation with redness and
tearing. Exposure to dust may cause mucous membrane and respiratory irritation, cough, sore throat, nasal congestion,
sneezing and shortness of breath. However, there may be no immediate signs or symptoms of exposure to hazardous
concentrations ofrespirable crystalline silica (quartz).
Indication of immediate medical attention and Special Treatment Needed: None required.
SECTION 5: FIREFIGHTING MEASURES
Suitable Extinguishing Media: This product will not burn but is compatible with all extinguishing media. Use any media
that is appropriate for the surrounding fire.
Specific Hazards Arising from the Chemical:

Unusual Fire and Explosion Hazards: Not flammable or combustible. Dry powders may accumulate static charge
in handling which can be a source of ignition for flammable atmospheres.
Hazardous Combustion Products: None.
Special Protective Equipment and Precautions for Fire-Fighters: None required with respect to this product.
Firefighters should always wear self-contained breathing apparatus for fires indoors or in confined areas.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective equipment.
Environmental Precautions: Report spills and releases as required to appropriate authorities.
Methods and Material for Containment/Cleanup: If uncontaminated, collect using dustless method (HEP A vacuum
or wet method) and place in appropriate container for use. If contaminated: a) use appropriate method for the nature of
contamination, and b) consider possible toxic or fire hazards associated with the contaminating substances. Collect for
appropriate disposal.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling: Do not breathe dust. Do not rely on your sight to determine if dust is in the air.
Silica may be in the air without a visible dust cloud. Use normal precautions against bag breakage or spills of bulk
material. Avoid creation ofrespirable dust. Use good housekeeping in storage and use areas to prevent accumulation
of dust in work area.
To reduce the risk of developing silicosis, lung cancer and other adverse health effects, the ACGIH recommends that the
industrial hygienist use every means available to keep exposures below the recommended TLV. NIOSH recommends
reducing airborne exposure levels as low as possible below NIOSH's recommended exposure limit, substituting less
hazardous materials when feasible, using appropriate respiratory protection when source controls cannot keep exposures
below the recommended limit and making medical examinations available to exposed workers.
Use adequate ventilation and dust collection. To minimize exposure, wear a respirator approved for silica dust when using,
handling, storing or disposing of this product or bag. Refer to the most recent government and local regulations when
selecting a respirator. Maintain, clean and fit test respirators in accordance with the most recent government and local
Page 2 of 8 Date Prepared: April 2015
Page 64 of 516
SDS No: 011-U-GHS
regulations. Maintain and test ventilation and dust collection equipment. Launder clothing that has become dusty. Empty
containers (bags, bulk containers, storage tanks, etc.) retain silica residue and must be handled in accordance with the
provisions of this Material Safety Data Sheet. WARN and TRAIN employees in accordance with state and federal
regulations.
WARN YOUR EMPLOYEES (AND YOUR CUSTOMERS AND USERS IN CASE OF RESALE) BY POSTING,
AND OTHER MEANS, OF THE HAZARDS AND OSHA AND ANY OTHER APPLICABLE REGULATORY
PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT OSHA
PRECAUTIONS.
Dust can accumulate electrostatic charges due to friction from transfer and mixing operations and cause an electrical spark
(ignition source) which can ignite flammable liquids and atmospheres. Provide adequate precautions when adding this
product to flammable and combustible mixtures like paints and coating, such as electrical grounding and bonding, inert
atmosphere or non-sparking tools. However, bonding and grounds may not eliminate the hazard for static accumulation.
See also American Society for Testing and Materials (ASTM) Standard Practice El 132-99a, "Standard Practice for Health
Requirements Relating to Occupational Exposure to Respirable Crystalline Silica".
Additional information on silica hazards and precautionary measures can be found at the following websites:
NIOSH Joint Campaign on Silicosis Prevention http://www.cdc.gov/niosh/topics/silica/default.html
OSHA Crystalline Silica Website http://www.osha.gov/dsg/topics/silicacr:ystalline/index.html
MSHA Silicosis Prevention Website http://www.msha.gov/S&HINFO/SILICO/SILICO.HTM
NI OSH Hazard Review - Health Effects of Occupational Exposure to Respirable Crystalline Silica Website
http:/ /www.cdc.gov/niosh/docs/2002-129 I
Conditions for Safe Storage, Including any Incompatibilities: Store in a dry location.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines:
Definitions:
NIOSH means National Institute for Occupational Safety and Health.
REL means the NIOSH Recommended Exposure Limit.
TL V means American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value.
TWA means time-weighted average.
OSHA PEL and MSHA Exposure Limit for Crystalline Silica, Quartz 10 mg/m 3
(Respirable measured as an 8-hour TWA) % Silica+ 2
TL V - 0.025 mg/m 3 8-hour TWA (respirable :fraction)
In 2006 the ACGIH lowered the TL V for Silica, Crystalline: a-Quartz and Cristobalite to 0.025 mg/m3 stating in the
Documentation of the TL V "Because the time between exposure and signs of fibrosis is characteristically very long, as much
as 30 to 40 years, the margin of safety for exposure to crystalline silica at the proposed TL V-TW A is not known precisely.
Given the observed association between silicosis and lung cancer, it is recommended that air concentrations be maintained as
far below the proposed TLV as prudent practices permit. The recommended TLV -TWA of 0.025 mg/m3, respirable
particulate mass, is intended to prevent pulmonary fibrosis that may be a risk factor for lung cancer. An A2, Suspected
Human Carcinogen, notation is based on the demonstrated association between lung cancer and the presence of silicosis."
The documentation further states "A lack of toxicological and industrial hygiene data does not permit the recommendation of
a TL V-STEL. However, it should be noted that high exposures of short duration to freshly fragmented crystalline particles do
produce an acute and rapidly progressive form of silicosis. The reader is encouraged to review the section on Excursion
Limits in the "Introduction to the Chemical Substances" of the current TL Vs® and BEis® book for guidance and control of
excursions above the TL V-TW A, even when the 8-hour TWA is within the recommended limits"
Page 3 of8 Date Prepared: April 2015
Page 65 of 516
SDS No: 011-U-GHS
NIOSH has issued its REL of 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m 3) as determined by a full
shift sample up to 10-hour working day, 40 hours per week. NIOSH has recommended that OSHA and MSHA adopt the
NIOSH REL as the OSHA PEL and the MSHA Exposure Limit. The 1974 NIOSH Criteria for a Recommended Standard for
Occupational Exposure to Crystalline Silica should be consulted for more detailed information. Additionally, NIOSH, In a
publication entitled NIOSH Hazard Review Health Effects of Occupational Exposure to Respirable Silica (April 2002),
NIOSH stated" ... that workers have a significant risk of developing chronic silicosis when they are exposed to respirable
crystalline silica over a working lifetime at the current Occupational Safety and Health Administration (OSHA) permissible
exposure limit (PEL), the Mine Safety and Health Administration (MSHA) PEL, or the National Institute for Occupational
Safety and Health (NIOSH) recommended exposure limit (REL) .... Current sampling and analytical methods used to
evaluate occupational exposure to respirable crystalline silica do not meet the accuracy criterion needed to quantify
exposures at concentrations below the NIOSH REL of 0.05 mg/m 3 as a time-weighted average (TWA) for up to a 10-hr
workday during a 40-hr workweek. Until improved sampling and analytical methods are developed for respirable crystalline
silica, NIOSH will continue to recommend an exposure limit of 0.05 mg/m 3 to reduce the risk of developing silicosis, lung
cancer, and other adverse health effects. NIOSH also recommends minimizing the risk of illness that remains for workers
exposed at the REL by substituting less hazardous materials for crystalline silica when feasible, by using appropriate
respiratory protection when source controls cannot keep exposures below the NIOSH REL, and by making medical
examinations available to exposed workers."
Crystalline silica exists in several forms, the most common of which are quartz (i.e. this product), trydimite and cristobalite,
with quartz being the most common form found in nature. If quartz is heated to more than 870°C, it can change form to
trydimite and if quartz is heated to more than 1450°C, it can change form to cristobalite.
Appropriate Engineering Controls: Use local exhaust as required to maintain exposures as far as possible below
applicable occupational exposure limits. See also ACGIH "Industrial Ventilation - A Manual for Recommended
Practice" (current edition). Control of exposure to dust must be accomplished as far as feasible by accepted engineering
control measures (for example, enclosure or confinement of the operation, general or local exhaust ventilation and
substitution ofless toxic materials).
Personal Protective Equipment:

Respiratory Protection: When effective engineering controls are not feasible, or while they are being implemented,
appropriate respiratory protection must be used. Use appropriate respiratory protection for respirable particulates based on
consideration of airborne workplace concentrations and duration of exposure arising from intended end use. Refer to the most
recent government and local standards.
Gloves: Protective gloves recommended.
Eye Protection: Safety glasses or goggles recommended.
Other Protective Equipment/Clothing: As appropriate for the work environment. Dusty clothing should be laundered
before reuse.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Form: Solid Annearance: White powder

Viscosity: Not applicable Odor: None
pH: Not applicable Odor Threshold: Not applicable
Boiling Point/Range: 4046°F I 2230°C Vapor Density: Not applicable
Melting point/freezing 2930°F I 1610°C Evaporation Rate: Not applicable
point:
Flammability (solid, gas): Fully oxidized, will not bum Partition coefficient (n- Not applicable
octanol/water):
Decomposition Not applicable Vapor Pressure: Not applicable
Temperature:
Flash Point: Not applicable Relative Density: 2.65
Lower Explosion Limit: Not applicable Solubilities: Insoluble in water
Page4 of8 Date Prepared: April 2015
Page 66 of 516
SDS No: 011-U-GHS
I Upper Explosion Limit: I Not applicable I Autoignition Temperature: I Will not burn
/ SECTION 10: STABILITY AND REACTIVITY
Reactivity: This product is not reactive under normal conditions of storage and use.
Chemical Stability: This product is stable at normal temperatures.
Possibility of Hazardous Reactions: None known
Conditions to Avoid: None known.
Incompatible Materials: Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, etc.
Hazardous Decomposition Products: Silica will dissolve in hydrofluoric acid producing a corrosive gas, silicon
tetrafluoride.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects
Potential Health Effects:
Inhalation: Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be
occurring. Inhalation of dust may have serious chronic health effects (see below Repeat Dose Toxicity.)
Skin Contact: No adverse effects expected.
Eye Contact: Contact may cause mechanical irritation and possible injury.
Ingestion: No adverse effects expected for normal, incidental ingestion.
Chronic Health Effects: See Repeat Dose Toxicity below with respect to silicosis, cancer status and other data with possible
relevance to human health.
Signs and Symptoms of Exposure: Exposure to dust may cause mucous membrane and respiratory irritation, cough, sore
throat, nasal congestion, sneezing and shortness of breath. However, there may be no immediate signs or symptoms of
exposure to hazardous concentrations ofrespirable crystalline silica (quartz). See Repeat Dose Toxicity below for symptoms
of silicosis. The absence of symptoms is not necessarily indicative of safe conditions.
Acute Toxicity Values: Silica: LD50 oral rat >22,500 mg/kg.
Skin Sensitization: Not a skin sensitizer in animals or humans.
Repeated Dose Toxicity:
Silicosis: Excessive inhalation ofrespirable crystalline silica dust may cause a progressive, disabling and sometimes
fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific
chest illness and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with
silicosis are predisposed to develop mycobacterial infections (tuberculous and non-tuberculous) and fungal
infections. Inhalation of air with a very high concentration of respirable silica dust can cause the most
serious forms of silicosis in a matter of months or a few years. Some epidemiologic studies have
concluded that there is significant risk of developing silicosis even at airborne exposure levels that are
equal to the recommended NIOSH REL, and ACGIH TL V.
Page 67 of 516
SDS No: 011-U-GHS
Other Data with Possible Relevance to Human Health:
There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with
an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder
manifested by fibrosis of the lungs, skin and other internal organs) rheumatoid arthritis, systemic lupus,
erythematosus, sarcoidosis, chronic bronchitis, chronic obstructive pulmonary disease (COPD),
emphysema, chronic kidney disease and end-stage renal disease.
For further information consult "Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic
Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine,
Volume 155, pages 761-768, 1997, and see also NIOSH Hazard Review- Health Effects of Occupational Exposure to
Respirable Crystalline Silica, April 2002 (see Section 7 for NIOSH Hazard Review Website).
Carcinogenicity: The International Agency for Research on Cancer has determined that crystalline silica is carcinogenic to
humans (Group 1 - carcinogenic to humans). Refer to IARC Monograph l00C, A Review of Human Carcinogens: Arsenic,
Fibres, and Dusts (published in 2011) in conjunction with the use of these materials. The National Toxicology Program
classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the Twelfth Report on Carcinogens
(2011 ). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
Developmental/ Reproductive Toxicity: No specific data is available, however, there is no evidence that silica exposure
has any effect on reproduction.
Genetic Toxicity: No specific data is available, however, there is no evidence that silica is a germ cell mutagen.
SECTION 12: ECOLOGICAL INFORMATION
Toxicity: Practically non-toxic to aquatic organisms. Silica: LC50 carp> 10,000 mg/L/72 hr.
Persistence and Degradability: Silica is not degradable.
Bioaccumulative Potential: Not expected to bioaccumulate.
Mobility in Soil: Not applicable.
Results of PBT and vPvB Assessment: None required.
Other Adverse Effects: None known
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Treatment Methods:

If uncontaminated, dispose as an inert, non-metallic mineral. If contaminated, dispose in accordance with all applicable local,
state/provincial and national/ federal regulations in light of the contamination present. Local regulations may be more
stringent than regional and national requirements. It is the responsibility of the waste generator to determine the toxicity and
physical characteristics of the material to determine the proper waste identification and disposal in compliance with
applicable regulations.
SECTION 14: TRANSPORT INFORMATION
Not regulated for transportation under IATA/ICAO, IMDG, US DOT, EU ADR, or Canadian TDG Regulations.
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code: None
SECTION 15: REGULATORY INFORMATION
Page 6 of 8 Date Prepared: April 2015
Page 68 of 516
SOS No: 011-U-GHS
SARA 311/312: Hazard Categories for SARA Section 311/312 Reporting: Chronic Health
SARA 313 This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under the
SARA Section 313 (40 CFR 372): None
CERCLA Section 103 Reportable Quantity: None
California Proposition 65: This product contains crystalline silica (respirable) which is known to the State of California to
cause cancer.
Toxic Substances Control Act: All of the components of this product are listed on the EPA TSCA Inventory or exempt
from premanufacture notification requirements.
EU Inventory: All of the components of this product are listed on the EINECS inventory or exempt from notification
requirements.
EU REACH Status: This substance is exempt from REACH registration.
Canadian Environmental Protection Act: All the components of this product are listed on the Canadian Domestic
Substances List or exempt from notification requirements.
Canadian WHMIS Classification: Class D, Division 2, Subdivision A (Very Toxic Material causing other Toxic Effects)
This SDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the SDS
contains all of the information required by the CPR.
Japan EITI: All of the components of this product are existing chemical substances as defrned in the Chemical Substance
Control Law.
Australian Inventory of Chemical Substances: All of the components of this product are listed on the AICS inventory or
exempt from notification requirements.
Australian National Occupational Health & Safety Commission Status: Hazardous according to the criteria of Australian
National Occupational Health & Safety Commission -Harmful (Xn) R48/20 Harmful: Danger of serious damage to health by
prolonged exposure by inhalation.
Korea: All of the components of this product are listed on the KECL inventory or exempt from notification requirements.
Philippines: All of the components of this product are listed on the PICCS inventory or exempt from notification
requirements.
New Zealand: All of the components of this product are listed on the HSNO inventory or exempt from notification
requirements.
China: All of the components of this product are listed on the IECSC inventory or exempt from notification requirements.
Taiwan: All of the components of this product are listed on the CSNN inventory or exempt from notification
requirements.
16: OTHER INFORMATION
NFP A Hazard Rating: Health: 1 Fire: 0 Reactivity: 0
HMIS Hazard Rating: Health:* Fire: 0 Reactivity: 0
Page 69 of 516
SDS No: 011-U-GHS
*Warning-Chronic health effect possible - inhalation of silica dust may cause lung injury/disease (silicosis). Take
appropriate measures to avoid breathing dust. See Section 3.
References:
Registry for Toxic Effects of Chemical Substances (RTECS), 2014
Patty's Industrial Hygiene and Toxicology
NIOSH Hazard Review - Health Effects of Occupational Exposure to Respirable Crystalline Silica, April 2002
NTP Twelfth Report on Carcinogens, 2011
IARC Monograph Volurnel00C, A Review of Human Carcinogens: Arsenic, Fibres, and Dusts (2011)
Hazardous Substances Data Bank (HSDB), 2014
Documentation of the TL V - Silica, Crystalline: a-Quartz and Cristobalite, American Conference of Governmental
Industrial Hygienists, 2006
SOS Date of Preparation/Revision: April 2014
Revision Summary: Conversion to US Hazcom2012 format- GHS Classification added.
The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in
combination with any other material or in any process. The information set forth herein is based on technical data the Unirnin
Corporation believes reliable. It is intended for use by persons having technical skill and at their own discretion and risk.
Since conditions of use are outside the control ofUnirnin Corporation, no warranties, expressed or implied, are made and no
liability is assumed in connection with any use of this information. Any use of these data and information must be
determined by the user to be in accordance with federal, state and local laws and regulations.
Page 70 of 516
ET-HP® Anchoring Adhesive
SAFETY DATA SHEET
1. Identification ·
Product Identification
Product Identifier: ET-HP (ET-HP22, ET-HP65, ETHP)
Recommended Use: Epoxy-Tie Adhesive
Use Restrictions: None Known.
Com any Identification -
Company: Simpson Strong-Tie Company Inc.
Address: 5956 W. Las Positas Blvd.
Pleasanton, CA 94588
Phone: 1-800-999-5099
Website: www.strongtie.com
Emergency: 1-800-535-5053 (US/Canada)
1-352-323-3500 (International)
For most current SDS, please visit our website at www.strongtie.com/sds
2. Hazard Identification -
General Information -
ET-HP Anchoring Adhesive is a two part system. The two parts of this product have been assessed according to GHS and are
classified below. The final hardened material is considered nonhazardous. Some hazards apply upon grinding or cutting
through hardened product.
Resin (white side) GHS Classification - ·
Physical Hazards: Not Classified.

Health Hazards: Skin Corrosion/Irritation Category 2
Serious Eye Damage/Irritation Category 2A
Sensitization, Skin Category 1
Germ Cell Mutagenicity Category 2
Environmental Hazards: Acute Aquatic Environmental Hazard Category 2
Chronic Aquatic Environmental Hazard Category 2
Signal Word: WARNING!

Hazard Statements: Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction.
Suspected of causing genetic defects. Toxic to aquatic life with long lasting effects.
Precautionary Statements:
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves/protective clothing/eye protection/face
protection. Contaminated work clothing must not be allowed out of the workplace. Avoid
breathing mist or vapor. Wash thoroughly after handling. Avoid release to the
environment.
Response: If exposed or concerned: Call a poison center/doctor. If on skin: Wash with plenty of
water. If skin irritation or rash occurs: Get medical advice/attention. Take off
contaminated clothing and wash before re-use. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical advice/attention. Collect Spillage.
Storage: Store locked up. Store in a well-ventilated place. Store between 45-90°F (7-32°C).
Disposal: Dispose of contents/container in accordance with local/regional/national/international
regulations.
Page 1 of 10
Page 71 of 516
ET-HP®Anchoring Adhesive
SAFETY DATA SHEET
Hardener (black side) GHS Classification
Physical Hazards: Not Classified.

Health Hazards: Skin Corrosion/Irritation Category 2
Serious Eye Damage/Irritation Category 1
Sensitization, Skin Category 1
Germ Cell Mutagenicity Category lA
Reproductive Toxicity (Fertility) Category 2
STOT, Repeated Exposure Category 2
(kidney, liver, nervous system, skin)
Environmental Hazards: Acute Aquatic Environmental Hazard Category 2
Chronic Aquatic Environmental Hazard Category 2
Signal Word: DANGER!

Hazard Statements: Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction.
Suspected of causing genetic defects. Suspected of damaging fertility. May cause damage
to organs (kidney, liver, nervous system, skin) through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
Prevention: Obtain special instructions before use. Wear protective gloves/protective clothing/eye
protection/face protection. Do not handle until all safety precautions have been read and
understood. Do not breathe mist or vapor. Wash thoroughly after handling. Contaminated
work clothing must not be allowed out of the workplace. Avoid release to the
environment.
Response: If exposed or concerned: Get medical advice/attention. If on skin (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or
rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it
before reuse. Ifin eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you
feel unwell. Collect Spillage.
Storage: Store locked up. Store in a well-ventilated place. Store between 45-90°F (7-32°C).
Disposal: Dispose of contents/container in accordance with local/regional/national/international
regulations.
Hazards Not Otherwise Classified (HNOC)
The above hazards are for the uncured components of ET-HP. Upon combination the components of ET-HP form an
innocuous solid which does not present any immediate hazards. Upon grinding or cutting the cured product the
following hazards may apply.
Health Hazards: Carcinogenicity Category lA

STOT, repeated exposure Category 2 (Lung)
Hazard Statements: May cause cancer. May cause damage to organs (Lung) through prolonged or repeated
exposure.
Precautionary Statements: Do not breathe dust.
3. Com osition Information

General Information
This product is a mixture. Hazardous ingredients for each component are listed below. May include other nonhazardous
ingredients. May include other trace ingredients, see Section 15.
ET-HJfi' Page 2 of 10
Page 72 of 516
SAFETY DATA SHEET
Resin (white side)
Bisphenol A/Epichlorohydrin 25068-38-6 40-60

Phenol, polymer with formaldehyde, glycidyl ether 28064-14-4 20-30
Butyl Glycidyl Ether 2426-08-6 1-10
Titanium Dioxide 13463-67-1 1-10
Hardener black side)
2-Piperazin-1-ylethylamine 140-31-8 5-15

4,4,'-isopropylidenediphenol 80-05-7 5-10
2,4,6-Tris-( dimethylaminomethyl)-phenol 90-72-2 1-10
.Nonylphenol 84852-15-3 1-10
Phenol 108-95-2 1-10
Crystalline Silica, Quartz 14808-60-7 5-10
diisopropyl-1, 1'-biphenyl 69009-90-1 1-10
m-Phenylenebis(methylarnine) 1477-55-0 1-10
4. First-Aid Measures
General Information
Provide general supportive measures and treat symptomatically. Symptoms may be delayed. Ensure that medical personnel
are aware of the material(s) involved, and take precautions to protect themselves. If exposed or concerned: Get medical
advice/attention. Wash contaminated clothing before reuse.
Routes of Ex osure
Eye Contact: Immediately flush eyes with plenty of cool water for at least 15 minutes while holding
the eyes open. Remove contact lenses if present and easy to do. If redness, burning,
blurred vision, or swelling persists, consult a physician.
Skin Contact: Remove contaminated clothing and product; wash affected area with soap and water. Do
not apply greases or ointments. If skin irritation persists consult a physician.
Ingestion: Rinse mouth immediately. Give large amounts of milk or water, if person is conscious.
Only induce vomiting at the instruction of medical personnel. Consult a physician.
Inhalation: Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient
continues to experience difficulty breathing, consult a physician.
Most Important Symptoms _
Irritant effects. May cause severe irritation or bums to the eyes, skin, gastrointestinal tract, and respiratory system Symptoms
may include stinging, tearing, redness, swelling, and blurred vision. May cause allergic skin reaction. Rash.
5. Fire-Fighting Measures -
Suitable Extinguishing Media: Extinguish with foam, carbon dioxide, dry powder, or water fog.
Additional Information: Do not use water jet as an extinguisher as this will spread the fire.
Hazards during Fire-Fighting: Hazardous decomposition products may occur when materials polymerize at
temperatures above 500° F (260°C). Irritating and toxic gases/fumes may be released
during a fire. Do not allow run-off from fire-fighting to enter drains or water courses.
Fire-Fighting Procedures: Use standard firefighting procedures and consider the hazards of other involved
materials. In case of fire and/or explosion do not breathe fumes. Self-contained breathing
apparatus and full protective clothing must be worn. Move containers from fire area if
you can do so without risk. Cool containers with flooding quantities of water until well
after fire is out. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply.
6. Accidental Release Measures

Personal Precautions
Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing
ET-HI'® Page 3 of 10
Page 73 of 516
SAFETY DATA SHEET
appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be
advised if significant spillages cannot be contained.
Clean-U Methods
Small spills: Wipe up with absorbent material (e.g. cloth, fleece). Place in leak-proof containers. Seal
tightly for proper disposal. Clean surface thoroughly.
Large spills: Stop the flow of material, if this is without risk. Dike far ahead of spill for later disposal.
Use a non-combustible material like vermiculite, sand or earth to soak up the product.
Place in leak-proof containers. Seal tightly for proper disposal. Following product
recovery, flush area with water. Prevent entry into waterways, sewer, basements or
confined areas.
Environmental Precautions
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further
leakage or spillage if safe to do so. ·
7. Handling and Storage

Handling _
Keep away from open flames, hot surfaces and sources of ignition. Wear appropriate personal protective equipment. When
using, do not eat, drink or smoke. Avoid contact with eyes, skin, and clothing. Pregnant women should not work with this
product if there is risk of exposure. Observe good industrial hygiene practices.
Stora e
Store in a closed container away from incompatible materials. Keep in original container. Keep container tightly closed. Store
in a dry place out of direct sunlight. Keep out of the reach of children. Store between 45-90°F (7-32°C). Keep away from heat
and sources of ignition. Store in a well-ventilated place. Store locked up.
8. Ex osure Controls / Personal Protection
Personal Protective E ui ment
Protective Measure: Wear appropriate personal protective equipment.
Eye Protection: Wear chemical splash goggles or safety glasses with side shield.
Hand Protection: Wear chemical-resistant gloves such as: Nitrile, neoprene, butyl.
Skin and Body Protection: Wear long sleeve shirts/long pants and other clothing as required to minimize contact.
Respirator Protection: The use of a respirator is not required during regular use of this product. If cutting or
grinding cured product the use of an approved respirator is reco=ended.
General Hygiene: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
Engineering Controls - -
When using indoors good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be
matched to conditions. Ready access to running water is required. Provide eyewash station.
Exposure Limits -
Ul
N-Butyl Glycidyl Ether 270 mg/m 3 30 mg/m 3 (Ceiling)
(2426-08-6) 3ppm
50ppm 5.6 ppm (Ceiling)
Titanium Dioxide 5 mg/m3(respirable)
10 mg/m 3 NIE
(13463-67-7) 15 mg/m 3(total dust)
Phenol* 19 mg/m 3 60 mg/m 3 ( Ceiling)
(CAS 108-95-2) 5ppm
5ppm 15.6 ppm (Ceiling)
Quartz 0.3 mg/m 3 (total dust)
0.025 mg/m 3 (respirable) 0.05 mg/m 3 (respirable)
(14808-60- 7) 0.1 mg/m 3 (respirable)
m-Phenylenebis(methylamine) *
(CAS 1477-55-0) NIE 0.1 mg/m 3 (Ceiling) 0.1 mg/m 3 (Ceiling)
*Skin Designation: Material can be absorbed through the skin.
ET-HJftl Page 4 of 10
Page 74 of 516
SAFETY DATA SHEET
Additional Information
After Cure: Product forms an innocuous solid. Processing after cure (grinding or cutting) may
produce dust containing compounds that present an inhalation hazard.
9. Physical and Chemical Properties
Property Resin Hardener
Physical State: Liquid, Paste Liquid, Paste
Color: White Black
Odor: Sweet Ammonia
pH: 6.9 10.2
Flammability limit- lower%: No data No data
Flammability limit- upper%: No data No data
Vapor Pressure: Non-volatile No data
Vapor Density: No data No data
Solubility: Insoluble in water Slightly soluble in water
Freezing/Melting Point: No data No data
Boiling Point: > 500 °P (>260 °C) No data
Flash Point: 250 °P (121 °C) Open Cup 225 °P (107 °C) Open Cup
Evaporation Rate: No data No data
Decomposition Temperature: No data No data
Specific Gravity: 1.19 at 72°P (22°C) 1.36 at 72°P (22°C)
voe (after cure): 3 g/L 3 g/L
Kow: No data No data
Viscosity: No data No data
10. Stabili and Reactivit
Resin (white side)
Reactivity: This product is stable and non-reactive under normal conditions.
Chemical Stability: Stable under normal storage conditions.
Condition to Avoid: High heat and open flame.
Substances to Avoid: Oxidizing agents, acids, organic bases, and amines
Hazardous Reactions: Hazardous polymerization does not occur.
Decomposition Products: Carbon dioxide, carbon monoxide, oxides of nitrogen, and other organic compounds.
Hardener (black side)
Reactivity: This product is stable and non-reactive under normal conditions.
Chemical Stability: Stable under normal storage conditions.
Condition to Avoid: High heat and open flame.
Substances to Avoid: Strong oxidizing agents. Peroxides. Phenols. Acids.
Hazardous Reactions: The product is stable if stored and handled as prescribed/indicated.
Decomposition Products: Carbon dioxide, carbon monoxide, oxides of nitrogen, and other organic compounds.
11. Toxicolo ical Information
Likely Routes of Ex osure ·
Ingestion: Causes digestive tract bums. Ingestion may cause irritation to the gastrointestinal tract.
Inhalation: If this material is heated or misted, coughing and mild, temporary irritation may occur.
Inhalation of dust from cutting/grinding cured product may irritate the respiratory tract.
Skin contact: Causes skin irritation. Causes severe skin bums. May cause an allergic skin reaction.
Eye contact: Causes serious eye irritation. Causes serious eye damage.
Information on Toxicological Effects
Acute toxicity: Occupational exposure to the substance or mixture may cause adverse effects.
0
:Prod-·
__ -:;;.-:.~-.,;.,=...,,..,,,.,=--~-T-
·=····"""<"""uC'"c-t....,.;-:-:"~=~....,.,,,...,,-~=~~~..,,....,..,..,.,.,,....._... e-st"".R~.
,_...,,
·"'.""esu1t'"""··-·-.-,,:-':r-·
Butyl Glycidyl Ether (2426-08-6)

Acute, Dermal, LC50 Rabbit 2520 µL/kg
Acute, Inhalation, LC50 Rat 1030 ppm, 8 hours
Acute, Oral, LD50 Rabbit 1660 ID g
ET-HJii> Page 5 of 10
Page 75 of 516
SAFETY DATA SHEET
®
.\> )~
Bisphenol NEpichlorohydrin (25068-38-6)

Acute, Dermal, LC50 Rat >2000 mg/kg
Acute, Oral, LD5 0 Rat >5000 mg/kg
2-Piperazin-1-ylethylamine (CAS 140-31-8)
Acute, Dermal, LD50 Rabbit 880 mg/kg
. 4,4,'-isopropylidenediphenol (CAS 80-05-7)
Rat 3300 mg/kg
Acute, Oral, LD50
Mouse 2500 mg/kg
Nonylphenol (CAS 84852-15-3)
Acute, Oral, LD50 Rat 1600 mg/kg
Phenol (CAS 108-95-2)
m-Phenylenebis(methylamine) (CAS 1477-55-0)
Acute, Dermal, LD50 Rabbit 2000mg/kg
Acute, Inhalation, LC50 Rat 700 ppm, 1 hour
Skin corrosion/irritation: Causes skin irritation. Causes skin burns.
Eye damage/eye irritation: Causes serious eye irritation. Causes serious eye damage.
Respiratory sensitization: No data available. ·
Skin sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: Contains a component that is suspected of causing genetic defects.
Carcinogenicity: Cured product contains Quartz and Titanium Dioxide, which are considered carcinogens
only in their inhalable form. Due to the nature of this product inhalation is highly
unlikely. Exposure to respirable Quartz and Titanium Dioxide is likely only when
grinding or cutting cured product, ensure good work practice and use of personal
protective equipment as needed to control exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60- 7) 1 Carcinogenic to humans.
Titanium Dioxide (13463-67-7) 2B Possibly Carcinogenic to humans.
Phenol (CAS 108-95-2) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
Reproductive toxicity: Suspected of damaging fertility.
Aspiration hazard: No data available.
Specific target organ toxicity:
Single exposure No data available.
Repeated exposure May cause damage to organs (kidney, Liver, Lung, nervous system, skin) through
prolongedor repeatedexposure.
lffilmflffiilli,,@iltlJ,
Toxicological, ecotoxicological, physical, and chemical properties may not have been fully investigated. Hazard data above is
estimated based on best available information. Some workers with pre-existing medical conditions such as: asthma, allergies,
or impaired pulmonary and/or liver functions, or who may be particularly susceptible to this material, may be affected by
exposure to this material.
12. Ecological Information
General Information
Information given is based on data on the components and the ecotoxicology of similar products. Product is classified as
toxic to aquatic life with long lasting effects. A void release to the environment.
ET-HF" Page 6 oflO
Page 76 of 516
SAFETY DATA SHEET
Supporting Data
Bisphenol A/Epichlorohydrin (25068-38-6)

Fish, LC50 Salmo Gairdneri 1.5 mg/1, 96 hours
A uatic, Crustacea, EC50 Da hnia Magna 2. 7 mg/1, 48 hours
Titanium dioxide (CAS 13463-67- 7)
Aquatic, Crustacea, EC50 Daphnia > 1000 mg/1, 48 hours
A uatic, Fish, LC50 Mummichog > 1000 mg/1, 96 hours
2-Piperazin-1-ylethylamine (140-31-8)
A uatic, Fish, LC50 Fathead Minnow 1950-2460 m /1, 96 hours
4,4,'-isopropylidenediphenol (CAS 80-05-7)
A uatic, Fish, LC50 Fathead Minnow 3.6-5.4 mg/1, 96 hours
Nonylphenol (CAS 84852-15-3)
Aquatic, Crustacea, EC50 Clam 0.0379 mg/1, 48 hours
A uatic, Fish, LC50 Winter Flounder 0.017 mg/1, 96 hours
Phenol (CAS 108-95-2)
Aquatic, Crustacea, EC50 Daphnia 4.7-6.4 mg/1, 48 hours
A uatic, Fish, LC50 Rainbow Trout 7. 7 mg/1, 96 hours
Persistence and degradability: No data available.
Bioaccumulative potential: No data available for this product.
Partition coefficient n-octanol / water (log Kow)
Phenol (108-95-2) 1.46
4,4,'-isopropylidenediphenol (80-05- 7) 3.32
Nonylphenol (25154-52-3) 5. 71
Mobility in soil: No data available.
Further Information
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption,
global warming potential) are expected from this product.
13. Disposal Consideration
Waste Disposal of Substance: Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds,
waterways or ditches with chemical or used container. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Container Disposal: Empty containers or liners may retain some product residues; follow label warnings even
after container is emptied. Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Disposal of Cured Product: Chip or grind off surface. Solid material does not need special disposal consideration.
14. Transportation Information -
Resin (white side) -
UN number: UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Bisphenol-A-Epichlorohydrin), 9, III, Marine Pollutant
Precautions: Marine Pollutant
Required Labels: 9
ERG Code (IATA): 9L
EmS (IMDG): F-A, S-F
Hardener (black side)
UN number: UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Nonylphenol), 9, III, Marine Pollutant
Precautions: Marine Pollutant
Required Labels: 9
ERG Code (IATA): 9L
EmS (IMDG): F-A, S-F
ET-HJfi' Page 7 of 10
Page 77 of 516
SAFETY DATA SHEET
Additional Information
Special precautions for user: Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
This substance/mixture is not intended to be transported in bulk
This information does not cover all specific regulatory or operational requirements of this product. The classifications for
transportation may vary by container volume or different regional or national regulations.
15. Re ulator Information
United States
Federal Regulations: This product is a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed.
4,4, '-isopropylidenediphenol (CAS 80-05- 7) LISTED
Phenol (CAS 108-95-2) LISTED
Resin Yes Yes No No

Hardener Yes Yes No No No
SARA 302 Extremely hazardous substance No

SARA 311/312 Hazardous chemical Yes
SARA 313 (TRI re ortin )
Phenol 108-95-2 1-10

4, 4, '-isopropylidenediphenol 80-05- 7 5-10
US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause
cancer, birth defects, or harm.
;.Co '"''n~iit' 'lation ·•.~'+;~litBiend (a i,,Y';,styffefc<;i<,Remark
Quartz (14808-60- 7) ACGIH 5-10 Carcinogenic
Carbon Black (1333-86-4) ACGIH < 0.1 Carcinogenic
Titanium dioxide (13463-67-7) ACGIH 1-10 Carcinogenic
2-Piperazin-1-ylethylamine
Listed Listed Listed
(CAS 140-31-8)
4,4,' -isopropylidenediphenol
Listed Listed Listed Listed
(CAS 80-05- 7)
m-Phenylenebis(methylamine)
Listed Listed
(CAS 1477-55-0)
Nonylphenol
Listed Listed
(CAS 84852-15-3)
Phenol (CAS 108-95-2) Listed Listed Listed Listed
Quartz (CAS 14808-60-7) Listed Listed
Butyl Glycidyl Ether
Listed Listed
(CAS 2426-08-6)
Titanium dioxide
Listed Listed
(CAS 13463-67-7
ET-HP Page 8 of 10
Page 78 of 516
SAFETY DATA SHEET
Canada
This product has been classified according to the hazard criteria of the CPR and the SDS contains all of the
information required by the CPR.
WHMIS Classification
(I)
Class D-2A: Material
Class E: Corrosive
Causing other toxic effects
International -
Australia Australian Inventory of Chemical Substances (AICS) No

Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
Inventory of Existing Chemical Substances in China (IECSC) Yes
European Inventory of Existing Commercial Chemical Substances (EINECS) No
Euro ean List of Notified Chemical Substances (ELIN CS) No
Inventory of Existing and New Chemical Substances (ENCS) No
Existing Chemicals List (ECL) No
Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) No
United States & Yes
Toxic Substances Control Act (TSCA) Inventory
Puerto Rico
16. Other Information

Date Prepared or Revised: September 2014
Supersedes: August 2013
Additional Resin (white side) Classifications -
NFP A Ratings HMIS Rating
PERSONALPROTECTION
Additional Hardener (black side) Classifications

NFP A Ratings HMIS Rating
H.AZARD
PHYSICAL
PROTECTION
PERSONAL
ET-HJiID Page 9 of 10
Page 79 of 516
SAFETY DATA SHEET
Abbreviations
ACGIH: American Conference of Governmental Industrial Hygienists

CASNo.: Chemical Abstract Service Registry Number
CERCLA: Comprehensive Environmental Response, Compensation and Liability Act (U.S. EPA)
CPR: Controlled Product Regulations (Canada)
DOT: Department of Transportation (U.S.)
EPA: Environmental Protection Agency (U.S.)
GHS: Globally Harmonized System of Classification and Labeling of Chemicals
HEPA: High-Efficiency Particulate Air
HMIS: Hazardous Materials Identification System
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods code
LPP: Limite Permisible Ponderado (Chile)
NIOSH: National Institute of Occupational Safety and Health (U.S.)
NFPA: National Fire Protection Association (US)
NTP: National Toxicology Program (US)
OSHA: Occupational Safety and Health Administration (U.S.)
PEL: Permissible Exposure Limit
SARA: Superfund Amendments and Reauthorization Act (U.S. BPA)
SDS: Safety Data Sheet
STEL: Short Term Exposure Limit (15 minute Time Weighted Average)
STOT: Specific Target Organ Toxicity (GHS Classification)
TLV: Threshold Limit Value
TSCA: Toxic Substances Control Act (U.S.)
TWA: Time Weighted Average (exposure for 8-hour workday)
U.S.: United States
voe: Volatile Organic Compounds
WHMIS: Canadian Workplace Hazardous Materials Information System
Disclaimer
This Safety Data Sheet (SDS) is prepared by Simpson Strong-Tie Co. in compliance with the requirements of OSHA
29 CFR Part 1910.1200. The information it contains is offered in good faith as accurate as of the date of this SDS.
This SDS is provided solely for the purpose of conveying health, safety, and environmental information. No
warranty, expressed or implied, is given. Health and Safety precautions may not be adequate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations.
© 2014 Simpson Strong-Tie Company Inc.
Internal
FOR INTERNAL USE ONLY

ET-HP Resin: XCOM3B-50% Cartridge ET-HP Hardener: XCOM3B - 50% Cartridge
ET-HpffJ Page 10 of 10
Page 80 of 516
Conforms to HazCom2012/United States FW FederalWhite Portland Cement
CEMENT
WHITE
FEDERAL
Cement
Safety Data Sheet Portland
Section1. Identification -
GHSproductidentifier: Portland Cement
Chemicalname: Calciumcompounds,calcium silicate compounds,and other calcium compoundscontaining iron and
aluminummakeup the majority of this product.
Othermeansof identification: Cement,hydrauliccement,masonrycement,silicate.
Relevantidentifiedusesof Building materials,construction, a basic ingredientin concrete.
the substanceor mixture
and usesadvisedagainst:
Supplier/Manufacturer: FederalWhite Cement I P.O.Box 1609 I Woodstock,Ontario I CanadaN4S0AB
Emergencytelephonenumber: Main Offices: (579)485-5410- 24 Hours I Website:federalwhitecement.com
Section2. HazardsIdentification
DANGER!Overexposureto portland cementcan causeserious, potentially irreversibleskin or eyedamagein the form of chemical(caustic)
burns, including third degreeburns. Thesameserious injury can occur if wet or moist skin has prolongedcontact exposureto dry portland
cement.
Portland cement is not classifiableas a humancarcinogen.
OSHA/HCSstatus: This materialis consideredhazardousby the OSHAHazardCommunicationStandard(29 CFR1910.1200).
Classificationof the - Category1
SKINCORROSION/IRRITATION
substanceor mixture:
- Category1
SERIOUSEYEDAMAGE/EYEIRRITATION
- Category1
SKINSENSITIZATION
SPECIFIC TARGETORGANTOXICITY(SINGLEEXPOSURE)
[Respiratorytract irritation] - Category3
GHSlabel elements
Hazardpictograms:
Signalword: Danger
Hazardstatements: Causessevereskin burns and eye damage.
May causean allergic skin reaction.
May causerespiratory irritation.
Precautionarystatements
Prevention: Wear protectivegloves.Weareye or face protection. Useonly outdoors or in a well-ventilatedarea.Avoid
breathingdust. Washhandsthoroughly after handling.Contaminatedwork clothing should not be allowed
out of the workplace.Causeseyeand skin burns. SeeSection 4 for additionaldetails. Maypresentrisk
of engulfment.SeeSection7 for additional details. Overexposureto wet cementcan causesevereskin
damagein the form of chemicalburns, includingthird degreeburns. The samesevereinjury can occur if
wet or moist skin is exposedto dry portland cement.Clothingwet with moisturefr001cementcan transmit
the causticeffects to the skin, causingchemicalburns. Portland cement causesskin burnswith little
warning; discomfort or pain cannot be relied uponto alert a personto a serious injury. Youmay not feel
pain or the severity of the burn until hours after the exposure.
Page 1 of 11
Page 81 of 516
Section2. HazardsIdentification- Continued F\V FederalWhite Portland Cement
MEDICALCONDITIONS WHICHMAYBEAGGRAVATED BYEXPOSURE: Contactwith wet cementmay

aggravateexisting skin conditions.Sensitivity to hexavalentchromiumcan be aggravatedby exposure.
Response: IF INHALED:Removevictim to fresh air and keepat rest in a position comfortablefor breathing.Prolonged
and repeatedinhalationof respirablecrystallinesilica-containingdust in excessof appropriateexposure
limits hascausedsilicosis, fibrosis or scar tissue formations in the lungs.Calla POISONCENTERor physi-
cian if you feel unwell. IF ONSKIN:Washwith plenty of pH neutralsoapandwater.Takeoff contaminated
clothing.Washcontaminatedclothing beforereuse.If skin irritation or rash occurs:get medicalattention.
Portlandcementmaycontaintrace amountsof hexavalentchromium.Hexavalentchromiumis associated
with al.lergicskin reactionswhich mayappearas contactdermatitisandskin ulcerations.Personsalready
sensitizedmay react to their first exposureto cement.Other individualsmaydevelopallergic dermatitis after
repeatedexposureto cement.Thesymptomsof allergicreactionsmayincludereddeningof the skin, rash,
and irritation. Symptomsof chronicexposureto wet cementmay includereddening,irritation, and eczema-
tous rashes.Drying,thickening,and crackingof the skin and nails mayalso occur. IF IN EYES:Rinsecau-
tiously with water for severalminutes.Removecontact lenses,if presentandeasyto do. Continuerinsing.
Exposureto dust maycauseimmediateor delayedirritation or inflammation.Eyecontactby larger amount
of dry poweror splashesof wet portlandcementmay causeeffects rangingfrom moderateeye irritation to
chemicalburns or blindness.Immediatelycall a POISONCENTERor physician.IF INGESTED: Irritating to
mouth,throat and stomach.Ingestionof largequantitiesmay causesevereirritation andchemicalburns
of the mouth,throat, stomachand digestivetract. Do not ingest portlandcement.Getimmediatemedical
attention.
Storage: Keepcontainertightly closed in a dry and well-ventilatedarea.
Disposal: Disposeof contentsand containerin accordancewith all local, regional,nationaland international
regulations.
Hazardsnot otherwiseclassified: Not applicable.
Section3. Composition/information
on ingredients _
Substance/mixture: Mixture
Chemicalname: Calciumcompounds,calciumsilicate compounds,and other calcium compoundscontainingiron and
aluminummakeup the majority of this product.
Othermeansof identification: Cement,hydrauliccement,portland cement,silicate
CASnumber/otheridentifiers
GASnumber: 65997-15-1
Productcode: Not available.
Ingredientname % GASnumber
Cement,portland, chemicals 100% 65997-15-1
The structureof Portlandcementmaycontainthe followingin someconcentrationranges:
Calciumoxide 0-4% 1305-78-8
Quartz 0-.5% 14808-60-7
Hexavalentchromium* 0-26 PPM 18540-29-9
Portlandcementalso containsgypsum,limestoneand magnesiumoxidein various

concentrations.However,becausethese componentsare notclassifiableas a hazardunder
Title 29 Codeof FederalRegulations1910.1200, they are not requiredto be listed in this section.
Gypsum 2-6% 13397-24-5
Limestone 0-5% 1317-65-3
Magnesiumoxide .5-2% 1309-48-4
Any concentrationshown as a rangeis to protect confidentiality or is dueto processvariation.
*Hexavalentchromium is includeddueto dermal sensitivity associatedwith the component.
Thereare no additional ingredients presentwhich, within the current knowledgeof the supplier and in the concentrationsapplicable,are classified as
hazardousto health or the environmentand hencerequire reporting in this section.
Occupationalexposurelimits, if available,are listed in Section 8.

Page 2 of 11
Page 82 of 516
FW FederalWhite Portland Cement
Section4. Firstaid measures -

-
-
Descriptionof necessaryfirst aid measures

Eyecontact: Getmedicalattention immediately.Call a poison centeror physician.Immediatelyflush eyeswith plenty of
water,occasionallylifting the upperand lower eyelids.Checkfor and removeany contact lenses.Continue
to rinsefor at least 20 minutes.Chemicalburns must be treatedpromptly by a physician.
Inhalation: Seekmedicalhelp if coughingor other symptomspersist. Inhalationof large amountsof portland cement
requiresimmediatemedicalattention. Calla poison centeror physician.Removevictim to fresh air and
keepat rest in a position comfortablefor breathing.If the individualis not breathing,if breathingis irregular
or if respiratoryarrest occurs, provideartificial respirationor oxygenby trained personnel.It may be
dangerousto the person providing aid to give mouth-to-mouthresuscitation.If unconscious,place in
recoveryposition and get medicalattention immediately.Maintainan openairway.
Skin contact: Getmedicalattention immediately.Heavyexposureto portland cementdust, wet concreteor associated
water requiresprompt attention. Quicklyremovecontaminatedclothing, shoes,and leathergoods such as
watchbandsand belts. Quicklyand gently blot or brush awayexcessportland cement.Immediatelywash
thoroughlywith lukewarm,gently flowing water and non-abrasivepH neutralsoap.Seekmedicalattention
for rashes,burns, irritation, dermatitis and prolongedunprotectedexposuresto wet cement,cement
mixturesor liquids from wet cement.Burnsshould be treatedas caustic burns. Portlandcementcauses
skin burnswith little warning. Discomfortor pain cannotbe relied uponto alert a personto a serious injury.
You maynot feel pain or the severity of the burn until hours after the exposure.Chemicalburns must be
treatedpromptly by a physician.In the eventof any complaintsor symptoms,avoidfurther exposure.
Ingestion: Getmedicalattention immediately.Call a poison centeror physician.Havevictim rinse mouth thoroughly
with water.DONOTINDUCEVOMITINGunlessdirectedto do so by medicalpersonnel.Removevictim to
fresh air and keepat rest in a position comfortablefor breathing.If materialhasbeenswallowedandthe
exposedpersonis conscious,give small quantitiesof waterto drink. Havevictim drink 60 to 240 ml (2 to
8 oz.) of water.Stop giving water if the exposedpersonfeels sick as vomiting may be dangerous.If
vomiting occurs,the headshould be kept low so that vomit doesnot enterthe lungs. Chemicalburns
must betreatedpromptly by a physician.Nevergive anythingby mouthto an unconsciousperson. If
unconscious,placein recoveryposition and get medicalattention immediately.Maintainan open airway.
Most importantsymptoms/effects,acute and delayedpotential acute health effects

Eyecontact: Causesseriouseyedamage.
Inhalation: Maycauserespiratory irritation.
Skin contact: Causessevereburns. May causean allergicskin reaction.
Ingestion: May causeburnsto mouth,throat and stomach.
signs/symptoms
Over-exposure
Eyecontact: Adversesymptomsmay includethe following: pain,wateringand redness
Inhalation: Adversesymptomsmay includethe following: respiratorytract irritation and coughing
Skin contact: Adversesymptomsmay includethe following: pain or irritation, rednessand blistering may occur, skin
burns, ulcerationand necrosismay occur
Ingestion: Adversesymptomsmay includethe following: stomachpains
Indicationof immediatemedicalattention and specialtreatment needed,if necessary

Notesto physician: Treatsymptomatically.Contactpoison treatmentspecialistimmediatelyif largequantitieshavebeen
ingestedor inhaled.
Specifictreatments: Not applicable.
Protectionof first-aiders: No action shall be taken involving any personalrisk or without suitabletraining. It maybe dangerousto the
personprovidingaid to give mouth-to-mouthresuscitation.Washcontaminatedclothing thoroughly with
water beforeremovingit, or weargloves.
See toxicological information (Section 11)
Page 3 of 11
Page 83 of 516
Section5. Fire-fightingmeasures _ - -
Extinguishing
media
Suitableextinguishingmedia: Usean extinguishingagentsuitablefor the surroundingfire.
Unsuitableextinguishingmedia: Do not usewaterjet or water-basedfire extinguishers.
Specifichazardsarisingfrom No specific fire or explosionhazard.
the chemical:
Hazardousthermal Decompositionproducts may includethe following materials:carbon dioxide,carbon monoxide,sulfur
decompositionproducts: oxidesand metal oxide/oxides
Specialprotectiveactionsfor Movecontainersfrom fire areaif this can be donewithout risk. Usewaterspray to keepfire-exposed
fire-fighters: containerscool.
Specialprotectiveequipment Fire-fightersshould wearappropriateprotectiveequipmentand self-containedbreathingapparatus(SCBA)
for fire-fighters: with a fullface-pieceoperatedin positive pressuremode.
Section6. Accidentalreleasemeasures ~ - -
Personalprecautions,protectiveequipmentandemergencyprocedures
Fornon-emergency
personnel: No action shall be taken involving any personalrisk or without suitabletraining. Evacuatesurrounding
areas.Keepunnecessaryand unprotectedpersonnelfrom entering. Do not touch or walk through spilled
material.Do not breathedust. Provideadequateventilation.Wearappropriaterespiratorwhenventilation is
inadequate.Put on appropriatepersonalprotectiveequipment.
Foremergencyresponders: For personalprotectiveclothing requirements,pleasesee Section8.
Environmental
precautions: Avoid dispersalof spilled materialand runoff and contact with soil, waterways,drains and sewers.Inform
the relevantauthorities if the product hasenteredthe environment,includingwaterways,soil or air.
Materialscan enter waterwaysthrough drainagesystems.
Methodsandmaterialsfor containmentandcleaningup
Smallspill: Movecontainersfrom spill area.Avoid dust generation.Do not dry sweep.Vacuumdust with equipment
fitted with a HEPAfilter and placein a closed,labeledwaste container.Placespilled material in a
designated,labeledwaste container.Disposeof waste materialby using a licensedwaste disposal
contractor.
Largespill: Movecontainersfrom spill area.Approachreleasefrom upwind. Prevententry into sewers,water courses,
basementsor confinedareas.Avoid dust generation.Do not dry sweep.Vacuumdust with equipmentfitted
with a HEPAfilter and placedust in a closed,labeledwaste container.Avoidcreating dusty conditions
and preventwind dispersal.Largespills to waterwaysmay be hazardousdueto alkalinity of the product.
Disposeof waste materialusing a licensedwaste disposalcontractor. Note:see Section 1 for emergency
contact informationand Section 13 for wastedisposal.
Section7. Handlingandstorage
Precautionsfor safe handling

Protectivemeasures: Put on appropriatepersonalprotectiveequipment(seeSection 8). Personswith a history of skin sensitiza-
tion problemsshould not be employedin any processin which this product is used.Avoid exposureby
obtainingand following specialinstructions beforeuse. Do not handleuntil all safety precautionshavebeen
readand understood.Do not get in eyesor on skin or clothing. Do not breathedust. Do not ingest. Useonly
with adequateventilation.Wearappropriaterespiratorwhen ventilation is inadequate.Keepin the original
containeror an approvedalternativemadefrom a compatiblematerialand keepthe containertightly closed
when not in use. Emptycontainersretain product residueand can be hazardous.Do not reusecontainer.
Adviceo~general Eating,drinking and smoking should be prohibited in areaswhere this materialis handled,stored and
occupationalhygiene: processed.Workersshould wash handsandface beforeeating, drinking and smoking. Remove
contaminatedclothing and protectiveequipmentbeforeenteringeating areas.Seealso Section8 for
additionalinformation on hygienemeasures.
Page4 of 11
Page 84 of 516
Section 7. Handlingand storage - Continued FW FederalWhite Portland Cement
Conditionsfor safe storage, A keyto using the product safely requiresthe userto recognizethat portland cementreacts chemically
includingany incompatibilities: with water to producecalcium hydroxidewhich can causeseverechemicalburns. Everyattempt should be
madeto avoidskin and eye contact with cement.Do not get portland cementinside boots, shoesor gloves.
Do not allow wet, saturatedclothingto remainagainstthe skin. Promptly removeclothing and shoesthat are
dusty or wet with cement mixtures. Launder/cleanclothing and shoes before reuse. Do not enter a confined
spacethat stores or contains portland cementunlessappropriateproceduresand protection are available.
Portland cementcan build up or adhereto the walls of a confined spaceand then releaseor fall suddenly
(engulfment).
controls/personprotection
Section8. Exposure al
Controlparameters
Occupationalexposurelimits
Ingredientname Exposurelimits
Cement, portland,chemicals ACGIHTLV (UnitedStates, 3/2012).
TWA:7 mg/m3 B hours. Form: Respirablefraction
NIOSHREL(UnitedStates, 6/2009).
TWA:5 mg/m3 70 hours. Form: Respirablefraction
TWA:70 mg/m3 70 hours. Form:Total
OSHAPEL(UnitedStates, 6/2010).
TWA:75 mg/m3 B hours. Form:Total dust
Calcium oxide ACGIHTLV (UnitedStates, 3/2012).

TWA:2 mg/m3 B hours.
TWA:2 mg/m3 70 hours.
OSHAPEL(United States, 6/2010).
TWA:5 mg/m3 B hours.
Limestone NIOSHREL(UnitedStates, 6/2009).

TWA:5 mg/m3 70 hours. Form: Respirablefraction
TWA:70 mg/m' 70 hours. Form:Total
TWA:75 mg/m3 B hours. Form:Total dust
Magnesiumoxide ACGIHTLV (UnitedStates, 3/2012).

TWA:70 mg/m' 8 hours. Form: lnhalablefraction
TWA:75 mg/m' B hours. Form:Total particulates
Quartz ACGIHTLV (UnitedStates, 3/2012).

TWA:0.025 mg/m3 8 hours. Form: Respirablefraction
TWA:0.05 mg/m3 70 hours. Form: respirabledust
OSHAPELZ-3 (United States, 9/2005).
TWA:70mg/m3 divided by %SiO, + 2: Respirable
TWA:30mg/m3 divided by %SiO, + 2: Total
Calcium sulfate (gypsum) ACGIHTLV (UnitedStates, 3/2012)

TWA:70 mg/m' B hours. Form: Respirablefraction
NIOSHREL(UnitedStates, 6/2009)
TWA5 mg/m3 B hours. Form:Respirablefraction
TWA70 mg/m' B hours. Form:Total dust
OSHAPELZ-1 (United States, 2/2006)
TWA5 mg/m3 8 hours. Form:Respirablefraction
TWA75 mg/m3 B hours. Form:Total dust
Page 5 of 11
Page 85 of 516
Section8. Exposurecontrols/personal
protection- Continued FW FederalWhite Portland Cement
Appropriateengineeringcontrols: Useonly with adequateventilation. If user operationsgeneratedust, use processenclosures,local

exhaustventilation or other engineeringcontrols to keepworker exposureto airbornecontaminants
belowany recommendedor statutory limits.
Environmentalexposurecontrols: Emissionsfrom ventilation or work processequipmentshould be checkedto ensurethey comply
with the requirementsof environmentalprotection legislation.
Individualprotectionmeasures
Hygienemeasures: Cleanwater should alwaysbe readilyavailablefor skin and (emergency)eyewashing.Periodicallywash
areascontactedby portland cementwith a pH neutralsoapand clean,uncontaminatedwater. If clothing
becomessaturatedwith portland cement,garmentsshould be removedand replacedwith clean,dry
clothing.
Eye/faceprotection: To preventeyecontact, wearsafety glasseswith side shields, safety gogglesor face shieldswhen handling
dust or wet cement.Wearingcontact lenseswhen working with cementis not recommended.
Skinprotection
Handprotection: Useimpervious,waterproof,abrasionand alkali-resistantgloves.Do not rely on barrier creamsin placeof
imperviousgloves.Do not get portland cementinsidegloves.
Bodyprotection: Useimpervious,waterproof,abrasionand alkali-resistantboots and protectivelong-sleevedand long-
leggedclothing to protect the skin from contactwith wet portland cement.To reducefoot and ankle
exposure,wear imperv·1ous boots that are high enoughto preventportland cementfrom getting inside
them. Do not get portland cementinsideboots, shoes,or gloves.Removeclothing and protective
equipmentthat becomessaturatedwith cementand immediatelywash exposedareasof the body.
Otherskin protection: Appropriatefootwear and anyadditionalskin protectionmeasuresshould be selectedbasedon the task
being performedandthe risks involved.Footwearand other gearto protect the skin should be approvedby
a specialistbefore handlingthis product.
Respiratoryprotection: Usea properlyfitted, particulatefilter respiratorcomplyingwith an approvedstandardif a risk assessment
indicatesthis is necessary.Respiratorselectionmust be basedon known or anticipatedexposurelevels,
the hazardsof the product, andassignedprotectionfactor of the selectedrespirator.
Section9. Physicalandchemicalproperties
Appearance
PhysicalState: Solid. [Powder.] Lowerand upperexplosive(flammable)limits:Not applicable.
Color: Grayor white. Vaporpressure: Not applicable.
Odor: Odorless. Vapordensity: Not applicable.
Odorthreshold: Not available. Relativedensity: 2.3 to 3.1
pH: >11.5[Cone.(%w/w): 1%] Solubility: Slightly soluble in water.
Melting point: Not available. Solubilityin water: 0.1 to 1%
Boilingpoint: >1000°C(>1832°F) Partitioncoefficient:n-octanol/water: Not applicable.
Flashpoint: Not flammable.Not combustible. Auto-ignitiontemperature: Not applicable.
Burningtime: Not available. Decomposition
temperature: Not available.
Burningrate: Not available. SADT: Not available.
Evaporationrate: Not applicable. Viscosity: Not applicable.
Flammability(solid, gas): Not applicable.
Section10. Stabilityandreactivity
Reactivity: Reactsslowly with water forming hydratedcompounds,releasingheatand producinga strong alkaline
solution until reactionis substantiallycomplete.
Chemicalstabitity: The product is stable.
Possibilityof hazardousreactions:Undernormal conditions of storageand use, hazardousreactionswill not occur.
Conditionsto avoid: No specific data.
Page 6 of 11
Page 86 of 516
Section10. Stability and reactivity- Continued F\V FederalWhite Portland Cement
Incompatiblematerials: Reactiveor incompatiblewith the following materials:oxidizingmaterials,acids,aluminumandammonium

salt. Portlandcementis highly alkalineand will reactwith acidsto producea violent, heat-generatingreac-
tion. Toxicgasesor vapors may be given off dependingon the acid involved.Reactswith acids,aluminum
metalsandammoniumsalts. Aluminumpowderand other alkali and alkalineearth elementswill react in wet
mortar or concrete,liberatinghydrogengas. Limestoneignites on contactwith fluorine and is incompatible
with acids,alum, ammoniumsalts, and magnesium.Silica reactsviolently with powerfuloxidizingagents
suchas fluorine, borontrifluoride, chlorinetrifluoride, manganesetrifluoride, andoxygendifluorideyielding
possiblefire and/orexplosions.Silicatesdissolvereadily in hydrofluoricacid producinga corrosivegas-
silicon tetrafluoride.
products:Undernormalconditionsof storageand use, hazardousdecompositionproductsshouldnot be produced.
Hazardousdecomposition
Section11. Toxicological
information
Informationon toxicologicaleffects
Acutetoxicity: PortlandCementLDS0/LCSO
= Not available
Irritation/Corrosion: Skin:Maycauseskin irritation. Maycauseserious burns in the presenceof moisture.

Eyes:Causesseriouseyedamage.Maycauseburns in the presenceof moisture.
Respiratory:Maycauserespiratorytract irritation.
Sensitization: Maycausesensitizationdueto the potentialpresenceof trace amountsof hexavalentchromium.
Mutagenicity: Thereare no dataavailable.
Carcinogenicity:
Classification
Product/ingredient
name OSHA IARC ACGIH NTP
Cement,portland, chemicals - - A4 -
Quartz - 1 AZ Knownto be a humancarcinogen.
Reproductive
toxicity: Thereare no dataavailable.
Teratogenicity: Thereare no dataavailable.
Specifictarget organtoxicity(singleexposure)
Name Category Routeof Exposure TargetOrgans
Calciumoxide Category3 Inhalationand skin contact Respiratorytract irritation, skin irritation

Cement,portland, chemicals Category3 Inhalationandskin contact Respiratorytract irritation, skin irritation
Specifictarget organtoxicity(repeatedexposure)
Name Category Routeof Exposure TargetOrgans
Quartz Category7 Inhalation Respiratorytract and kidneys
Aspirationhazard: Thereare no dataavailable.
Page 7 of 11
Page 87 of 516
Section11. Toxicologicalinformation- Continued .FW FederalWhite Portland Cement
Informationon the likely routesof exposure

Dermalcontact. Eyecontact. Inhalation.Ingestion.
Potentialacutehealtheffects: Eyecontact:Causesserious eyedamage.
Inhalation:May causerespiratory irritation.
Skincontact:Causessevereburns. Maycausean allergic skin reaction.
Ingestion:May causeburns to mouth, throat andstomach.
Symptomsrelatedto the Eyecontact:Adversesymptoms may includethe following: pain, watering,redness

physical,chemicaland Inhalation:Adversesymptomsmay includethe following: respiratorytract irritation, coughing
toxicologicalcharacteristics:
Skincontact:Adversesymptoms may includethe following: pain or irritation, redness,blistering may
occur,skin burns, ulcerationsand necrosismayoccur
Ingestion:Adversesymptomsmay includethe following: stomachpains
Delayedand immediate Shortterm exposure

effectsandalso chronic Potentialimmediateeffects: No known significant effects or critical hazards.
effectsfromshortand long Potentialdelayedeffects: No known significant effects or critical hazards.
term exposure: Longterm exposure
Potentialimmediateeffects: No knownsignificant effects or critical hazards.
Potentialdelayedeffects: No known significant effects or critical hazards.
Potentialchronichealtheffects: General:Repeatedor prolongedinhalationof dust may leadto chronic respiratory irritation. If sensitized
to hexavalentchromium,a severeallergic dermalreactionmay occur when subsequentlyexposedto very
low levels.
Carcinogenicity:Portlandcementis not classifiableas a humancarcinogen.Crystallinesilica is considered
a hazardby inhalation.IARChas classified crystallinesilica as a Group1 substance,carcinogenic
to humans.This classificationis basedon the findings of laboratoryanimalstudies (inhalationand
implantation)and epidemiologystudiesthat wereconsideredsufficient for carcinogenicity.Excessive
exposureto crystalline silica can causesilicosis, a non-cancerouslung disease.
Mutagenicity:No knownsignificant effects or critical hazards.
Teratogenicity:No knownsignificant effects or critical hazards.
Developmentaleffects:No known significant effects or critical hazards.
Fertilityeffects:No knownsignificant effects or critical hazards.
Numericalmeasuresof toxicity: Acutetoxicity estimates:Thereare no data available.
Section12. Ecologicalinformation ,
Toxicity
Product/ingredient
name Result Species Exposure
Calciumoxide ChronicNOEC100 mg/L Fish-Oreochromis niloticus-Juvenile 46 days
Freshwater (Fledgling,Hatchling,Weanling)
Persistenceand degradability: Thereare no data available.

Bioaccumulative
potential: Thereare no data available.
Mobilityin soil: Soil/waterpartition coefficient (Koc):Not available.
Otheradverseeffects: No knownsignificant effects or critical hazards.
Page B of 11
Page 88 of 516
FW' FederalWhite Portland Cement
Section13. Disposalconsiderations _ - _ _
Disposalmethods: Thegenerationof waste should be avoidedor minimizedwhereverpossible.Disposalof this product,
solutions andany by-productsshouldcomplywith the requirementsof environmentalprotection and waste
disposallegislationand any regionallocal authority requirements.Disposeof surplus and non-recyclable
productsvia a licensedwaste disposalcontractor.Untreatedwasteshouldnot be releasedto the sewer
unlessfully compliantwith the requirementsof all authoritieswith jurisdiction. Waste packagingshould be
recycled.Incinerationor landfill should only be consideredwhen recyclingis not feasible.This materialand
its containermust be disposedof in a safe manner.Careshould be takenwhenhandlingempty containers
that havenot beencleanedor rinsedout. Emptycontainersor liners mayretainsome product residues.
Avoiddispersalof spilled materialand runoff, and contact with soil, waterways,drains and sewers.
Section14. Transportinformation
DOTClassification IMDG IATA
UN number Not regulated. Not regulated. Not regulated.

UN propershippingname - - -
Transporthazardclass(es) - - -
Packinggroup - - -
Environmentalhazards None. None. None.
Additionalinformation - - -
Specialprecautionsfor user: Transportwithin user's premises:alwaystransport in closedcontainersthat are upright and secure.Ensure
that personstransporting the product know what to do in the eventof an accidentor spillage.
Transportin bulkaccording Not available.
to AnnexII of MARPOL73/78
andthe IBCCode:
Section15. Regulatoryinformation _
U.S. Federalregulations: TSCA6 final riskmanagement:Chromium,ion (Cr6+)
UnitedStatesinventory(TSCABb):Portlandcementsare consideredto be statutory mixtures underTSCA.
CAS65997-15-1is includedon the TSCAinventory.
CleanWater Act(CWA)307: Chromium,ion (Cr6+)
This product is not listed as a CERCLAsubstance.
CERCLA:
CleanAir ActSection112 (b): HazardousAir Pollutants(HA-Ps)- Not listed
CleanAir ActSection602: ClassI Substances- Not listed
- Not listed
CleanAir ActSection602: ClassII Substances
DEAList I Chemicals:(PrecursorChemicals)- Not listed
DEAList II Chemicals:(EssentialChemicals)- Not listed
Page 9 of 11
Page 89 of 516
Section15. Regulatoryinformation- Continued F\V FederalWhite Portland Cement
SARA311/312
Classification: Immediate(acute)healthhazard
Delayed(chronic)healthhazard
Composition/information
on ingredients
Name % Fire Suddenrelease Reactive Immediate(acute) Delayed(chronic)

hazard of pressure healthhazard healthhazard
Calciumoxide A-B No. No. No. Yes. No.
Quartz < 0.2 No. No. No. No. Yes.
Chromium,ion (Cr6+) < 0.1 No. No. No. Yes. Yes.
NickelCompounds < 0.1 No. No. No. Yes. Yes.
Lead(Organic& Inorganic) < 0.1 No. No. No. No. Yes.
SARA313
Productname GASnumber %
Form R-Reporting requirements Chromium,ion (Cr6+) 18540-29-9 < 0.1
Lead(Organicor Inorganic) - < 0.1
NickelCompounds - < 0.1
Suppliernotification Alternatively,if any of the compoundsare not present,state:

This product does not contain any constituentslisted under
SARATitle Ill Section313.
State regulations
Massachusetts: The following componentsare listed: cement,portland, chemicals,limestone
NewYork: Noneof the componentsare listed.
NewJersey: The following componentsare listed: cement,portland, chemicals,gypsum,limestone
Pennsylvania: The following componentsare listed: cement,portland, chemicals,gypsum,limestone
CaliforniaProp. 65
WARNING:This product containscrystalline silica and chemicals(trace metals)knownto the State of Californiato causecancer,birth defectsor
other reproductiveharm. Californialaw requiresthe abovewarning in the absenceof definitive testing to provethe definedrisks do not exist.
Ingredientname Cancer Reproductive No significant Maximumacceptable

risk level dosagelevel
Quartz Yes. No. No. No.
Chromium,ion (Cr6+) Yes. Yes. 0.001 µg/day (inhalation) 8.2 micrograms/day(ingestion)
NickelCompounds No. No. No. No.
Lead Yes. Yes. 15 µg/day (ingestion) 0.5 micrograms/day(inhalation)
Internationalregulations
Internationallists: CanadianDomesticSubstancesList (DSL):Portlandcementis includedon the DSL.
MexicoInventory(INSQ):All componentsare listed or exempted.
Page 10 of 11
Page 90 of 516
- -
Section16. Otherinformation _
History
Date of issue: 06/14/2017
Version: 3
RevisedSection(s): Not applicable.
Noticeto reader
While the information providedin this safety data sheet is believedto providea useful summary of the hazardsof portland cement as it is
commonly used, the sheet cannotanticipateand provide all of the information that might be neededin every situation. Inexperiencedproduct
usersshould obtain propertraining before using this product. In particular,the data furnished in this sheetdo not addresshazardsthat may be
posedby other materials mixedwith portland cementto produce portland cement products. Usersshould review other relevant materialsafety
datasheets before working with this portland cementor working on portland cementproducts, for example,portland cement concrete.
SELLERMAKESNOWARRANTY,EXPRESSOR IMPLIED,CONCERNING THEPRODUCT ORTHEMERCHANTABILITY OR FITNESSTHEREOF
FORANY PURPOSEORCONCERNING THEACCURACY OFANY INFORMATION PROVIDEDBYFederalWhite Cement,exceptthat the product
shall conform to contractedspecifications.The information providedhereinwas believedby the Federal White Cementto be accurateat the
time of preparation or preparedfrom sources believedto be reliable,but it is the responsibility of the userto investigateand understandother
pertinent sources of information to comply with all laws and proceduresapplicableto the safe handlingand use of product and to determinethe
suitability of the product for its intendeduse. Buyer'sexclusiveremedyshall be for damagesand no claim of any kind, whether as to product
deliveredor for non-deliveryof product, and whether basedon contract, breachof warranty, negligence,or otherwiseshall be greater in amount
than the purchaseprice of the quantity of product in respect of which damagesare claimed. In no event shall Sellerbe liable for incidental or
consequentialdamages,whether Buyer's claim is basedon contract, breachof warranty, negligenceor otherwise.
Abbreviations Preparedby:
ACGIH- AmericanConferenceof GovernmentalIndustrial Hygienists BernardJ. lgusky
CAS- ChemicalAbstract Service Director Logistics, Marketing & TechnicalServices
CERCLA- ComprehensiveEmergencyResponseand ComprehensiveLiability Act
CFR- Codeof FederalRegulations
ApprovedDate or RevisionDate:
DOT- Departmentof Transportation January4, 2018
GHS- Globally HarmonizedSystem
Date of PreviousSDS:
HEPA- High EfficiencyParticulateAir
August 7, 2017
IATA- InternationalAir TransportAssociation
IARC- InternationalAgencyfor Researchon Cancer
IMDG- InternationalMaritime DangerousGoods
NIOSH- National Institute of OccupationalSafety and Health
NOEC- No ObservedEffect Concentration
NTP- National ToxicologyProgram
OSHA- OccupationalSafety and Health Administration
PEL- Permissible ExposureLimit
REL- RecommendedExposureLimit
RO- ReportableQuantity
SARA- SuperfundAmendmentsand ReauthorizationAct
SOS- Safety DataSheet
TLV- Threshold Limit Value
TPQ- Threshold PlanningQuantity
TSCA- Toxic SubstancesControl Act
TWA- Time-WeightedAverage
UN- United Nations
Page 11 of 11
Page 91 of 516
Page 92 of 516
W. R.MEADOWS,i,
SAFETYDATA SHEET
Product: FIBREEXPANSIONJOINT Part Number: 1103360

Manufacturer: W. R. MEADOWS, INC. Address: 300 Industrial Drive
Product Use: Expansion Joint in Concrete Construction
HMIS
IHealth I 111 Product is classified as non-hazardous per OSHA 1910.1200. Fiber Expansion Joint is
I Flammability I 111 defined by OSHA as an "article." A manufactured item that is formed to a specific shape or
I Reactivity I 101 design during manufacture that does not release or result in exposure to a hazardous
I Personal Protection I I I chemical under normal use conditions.

Chemical Name: CASNumber % by Weight 313 (mm Hg@Z0"C) 1@M.'..g
Under the reporting requirements of Section 313 ofTitle Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA)and
40 CFRPart 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA 313." N/A = Not Applicable
EYECONTACT: Flush eyes with water to remove fibers

SKIN CONTACT: Flush with water to remove fibers. Wash affected areas with soap and water if available
INHALATION: Not expected to be an exposure route. If a dust exposure occurs, remove victim from exposure source and treat
symptomatically.
OSHA ACGIH
Chemical Name: PEL PEL/CEILING PEL/STEL SKIN TLV TLV/CEILING TLV/STEL SKIN
1. Petroleum Asphalt 5 mg/m 3 * N/E N/E No 0.5 mg/m *
3
N/E N/E N/E
ENGINEERINGCONTROLS; None required under normal use conditions.
PERSONALPROTECTIVEEQUIPMENT: Safety glasses, chemical-resistant gloves. N/E = Not Established *: Asphalt Fumes
STABILITY:Stable. HAZARDOUSPOLYMERIZATION: Will not occur.

CONDITIONS AND MATERIALSTO AVOID: None recognized.
HAZARDOUSDECOMPOSITION PRODUCTS: None recognized.
Page 93 of 516
SAFETYDATA SHEET
EYECONTACT: Direct contact may cause mild irritation.

SKIN CONTACT:Direct contact may cause slight skin irritation.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tear'lng, reddening, and swelling. Symptoms of skin ·irritation include redness
and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
AGGRAVATEDMEDICALCONDITIONS:None recognized.
OTHERHEALTHEFFECTS:Wood dust is listed by the IARCas a human carcinogen (Group 1)
HAZARDOUS/NON-HAZARDOUSMATERIAL: Not regulated by DOT.

UN NUMBER: None HAZARDCLASS:N/A PACKINGGROUP: N/A
ENVIRONMENTALHAZARDS: None recognized.
BULKTRANSPORTATIONINFORMATION: None.
Dave Carey
Page 94 of 516
W. R. MEADOWS.,
SAFETYDATA SHEET
Product: Deck-O-Foam® Expansion Joint Part Number: 4610000

Product Use:
ss11e as non-hazardous per OSHA 1910.1200. Deck-0-Foam is

SHA as an "article." A manufactured item that is formed to a specific shape or
g manufacture that does not release or result in exposure to a hazardous
er normal use conditions.
a.:~~t,.1;~1G_~
"-~------
Weight 313 (mm Hg@20°Cl .l@M:Q
Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA) and 40 CFR
OSHA ACGIH
PEL/CEILING PEL/STEL TLV TLV/CEILING TLV/STEL
ormal use conditions.

ed under normal conditions of use.
JjJ~itl8XSJ
VAPOR DENSITY: N A
pH LEVEL: N/ A
EYE CONTACT: No adverse e ects with normal pro uct use.

SKIN CONTACT: No adverse effects with normal product use.
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
Page 95 of 516
SAFETYDATA SHEET

BULKTRANSPORTATION INFORMATION:None.
Dave Carey
Page 96 of 516
SAFETY DATA SHEET (SDS)
GRAY IRON CASTINGS

© 2013 American Foundry Society
SDS SC-000-041 Rev. 12
DATE ISSUED
Meets the Requirements of OSHA Standard 29 CFR 1910.1200 Hazard
Communfcation and EPA Supplier Notification Requirements under Section 10/13
313 of the Emergency Planning and Community Right-to-Know Act.
SECTION 1-PRODUCT IDENTIFICATION & COMPANY INFORMATION

PRODUCT NAME
GRAY IRON CASTINGS
OTHER DESIGNATIONS: ASTM (American Society for Testing & Materials) Specification No's., (ACI (Alloy Casting Institute) Alloy Designations-
Grades)
ASTM: A48, A74, A126, A159, A278, A319, A667, A748, A823, A942
PRODUCT IDENTIFICATION (Label Identifier)
Gray Iron
MANUFACTURER'S NAME STREET ADDRESS
Neenah Foundry Company 2121 Brooks St
EMERGENCY TELEPHONE NO. MAILING ADDRESS
CHEMTREC: (800) 424-9300
TELEPHONE NO. CITY, STATE, ZIP CODE, COUNTRY
920.729.3679 or 920.729.3850 Neenah, WI 54956 USA
FAX NO. E-MAIL ADDRESS/WEBSITE
920.729.3661 http://www.nfco.com/
RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Solid casting; no restrictions
SECTION 2-HAZARD IDENTIFICATION
CLASSIFICATION
Castings are metallic articles that do not present hazards in their original form.
OTHER INFORMATION
1. Grinding castings that have not been cleaned or that contain embedded sand may generate significant amounts
of dust containing crystalline silica.
2. Fumes from hot processes may contain other compounds with different exposure limits. Dust or fumes
generated by machining, grinding, welding or thermal cutting of the casting may produce airborne contaminants.
Consult Sections 3 & 8 for further information.
SECTION 3-COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME/COMMON NAME/SYNONYM Wt% CAS NUMBER

Carbon (C) 2.5-4.0 7440-44-0
Chromium (Cr) 0.01-1.5 7440-47-3
Copper (Cu) 0.01-1.00 7440-50-8
Iron (Fe) 86.3-96.2 7439-89-6
Manganese (Mn) 0.2-1.1 7439-96-5
Nickel (Ni) 0.01-1.5 7440-02-0
Silicon (Si) 1.0-3.5 7440-21-3
Tin (Sn) 0.1-0.15 7440-31-5
Gray Iron Castings (SOS SC-000-041 Rev 12) Page 1 of6
Page 97 of 516
SECTION 4-FIRST AID MEASURES
EYE CONTACT: Not applicable
SKIN CONTACT: No special requirements
INGESTION: Not applicable
INHALATION: Not applicable
SECTION 5-FIREFIGHTING MEASURES
FLAMMABLE PROPERTIES: Not applicable
EXTINGUISHING MEDIA: Not applicable
PROTECTION OF FIREFIGHTERS: Not applicable
RECOMMENDED STORAGE
No special requirements
PROCEDURES FOR HANDLING
Proper hand and foot protection is recommended.
-
SECTION 8-EXPOSURE CONTROLS/ PERSONAL PROTECTION -
ENGINEERING CONTROLS
None Required. There are no health hazards from castings in solid form.
ACGIHTLV OSHA PEL
SUBSTANCE mg/m 3 ma/m
3
Carbon (C) NIE NIE

Chromium (Cr) 0.5 1
Copper (Cu) 1 1
Iron (Fe) NIE NIE
Manganese (Mn) 0.02 (R); 0.1 (I) 5 (C)
Nickel (Ni) 1.5 (I) 1
Silicon (Si)
Total dust NIE 15
Respirable dust NIE 5
Tin (Sn) 2 2
SUPPLEMENTAL INFORMATION
Grinding castings that have not been cleaned or that contain embedded sand may generate significant amounts of
dust containing crystalline silica.
Fumes from hot processes may contain other compounds with different exposure limits than those listed above.
Dust or fumes generated by machining, grinding, welding or thermal cutting of the casting may produce airborne
contaminants. Exposure limits for the most common contaminants are offered as reference. Please consult a
competent person for guidance on exposure assessment and controls.
In particular, Hexavalent Chromium is an OSHA Expanded Health Standard; refer to OSHA 29 CFR
1910.1026-Chromium (VI) for complete requirements.
Gray Iron Castings (SDS SC-000-041 Rev 12) Page 2 of6
Page 98 of 516
ACGIH TLV OSHA PEL
3 3
SUBSTANCE mg/m mg/m
Chromium Compounds (as Cr)
Chromium (II) inorganic compounds NIE 0.5
Chromium (Ill) inorganic compounds 0.5 0,5
Chromium (VI) inorganic compounds, certain water insoluble 0.01 0,005
Chromium (VI) Inorganic compounds, water soluble 0.05 0.005
Chromium (VI) all forms and compounds NIE 0.005
Copper Compounds (as Cu)
Fume, as Cu 0.2 0.1
Dusts and mists, as Cu 1 1
Iron Compounds
Iron oxide (Fe203) fume NIE 10
Iron oxide (Fe203) 5 (R) NIE
Nickel Compounds (as Ni)
Insoluble, inorganic compounds 0.2(1) 1
Soluble, inorganic compounds 0.1(1) 1
Nickel oxide 0.2(1) 1
Tin compounds (as Sn)
Tin Oxide & Inorganic compounds, except SnH 4 · 2 NIE
Inorganic compounds, except oxides, as Sn NIE 2
Tin Oxides, as Sn 2 NIE
TERMS
All exposure limits referenced above are 8 hour time weighted averages [rWA) unless otherwise noted.
NIE= None Established
C= Ceiling
I= lnhalablefraction
R= Resplrablefraction
TLV= Threshold Limit Value/American Conferenceof IndustrialHygienists (ACGIH)
PEL= PermissibleExposure Limit/ OSHA
3
mg/m = milligramsper cubic meter
PERSONAL PROTECTION:
Proper hand and foot protection is recommended.
SECTION 9-PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE /PHYSICAL STATE
Solid, silver gray in color
ODOR/ODOR THRESHOLD VAPOR DENSITY
None Not applicable
MEL TING POINT/FREEZING POINT SPECIFIC GRAVITY (relative density)
3
Approximately 2350°F ( 1300°C) 7.85 glcm for iron
BOILING POINT VAPOR PRESSURE
5000°F (2750°C) for iron Not applicable
FLASH POINT EVAPORATION RATE
Not applicable for solid castings Not applicable
FLAMMABILITY SOLUBILITY IN WATER
Not flammable Insoluble
UPPER AND LOWER FLAMMABILITY LIMITS pH
Not applicable for solid castings Not applicable
AUTO IGNITION TEMPERATURE VISCOSITY
Not applicable Not applicable
Page 99 of 516
DECOMPOSITION TEMPERATURE PARTITION COEFFICIENT
CHEMICAL STABILITY
Stable
CONDITIONS TO AVOID
None
REACTIVITY INCOMPATIBLE MATERIALS
Not reactive None
HAZARDOUS DECOMPOSITION PRODUCTS POSSIBILITY OF HAZARDOUS REACTIONS
None Not applicable
SECTION 11-TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
EYE CONTACT: None
SKIN: None
INGESTION: None
INHALATION: None
Carcinogen Classification of Ingredients
INGREDIENT OSHA NTP IARC TARGET ORGAN
Nickel (metal) NL K 2B Lung, Nose
TERMS
OSHA-Occupational Safety & Health Administration
Y =
Listed as a Human Carcinogen
NTP-Natlonal Toxicology Program
K =
Known to be a Human Carcinogen
R =
Reasonably Anticipated to be a Human Carcinogen (RAHC)
!ARC-International Agency for Research on Cancer
1 =
Carcinogen to Humans
=
2A Probably Carcinogenic to Humans
=
2B Possibly Carcinogenic to Humans
3 = Unclassifiable as to Carcinogenicity in Humans
4 = Probably not Carcinogenic to Humans
Other
NL =
Not Listed
SECTION 12-ECOLOGICAL INFORMATION
ECOTOXICITY PERSISTENCE AND DEGRADABILITY
BIOACCUMULATION POTENTIAL MOBILITY IN SOIL
OTHER ADVERSE EFFECTS
Not applicable
US DEPARTMENT OF TRANSPORTATION CANADIAN TRANSPORTATION OF DANGEROUS

(DOT)-HMR (Hazardous Materials Registration) GOODS (TDG)
Not Regulated Not regulated
UN SHIPPING NAME UN NUMBER
Not regulated Not regulated
Page 100 of 516

TRANSPORT HAZARD CLASS PACKING GROUP
Not regulated Not regulated
ENVIRONMENTAL HAZARDS LABEL(S) REQUIRED?
None No
TRANSPORT IN BULK SPECIAL SHIPPING INFORMATION
- - >"' ""''"'
*-""
- SECTION 15-REGULATORY INFORMAJ110N - -
- -
US-OSHA (Hazard Communication Standard)
Reference 29 CFR 1910.1200 and 1910.1000. A finished casting is an article as defined in the OSHA Hazard
Communication Standard 29CFR 1910.1200 (c). Dust or fumes generated by cleaning, machining, grinding, or
welding of the casting may produce airborne contaminants, such as chromium, copper, iron, manganese, nickel,
silicon, tin and silica.
For hexavalent chromium references see 29 CFR 1910.1026.
US-EPA (Toxic Substances Control Act-TSCA)
All components of these products are on the TSCA inventory list or are excluded from listing.
US-EPA (SARA Title Ill)
Releases to the environment of Chromium, Copper, Manganese and Nickel, may be subject to reporting under
Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 72.
CANADA-WHMIS (Workplace Hazardous Materials Information System)
This SOS has been prepared according to the hazard criteria of the Controlled Product Regulations (CPR) and the
SOS contains the information required by the CPR.
CANADA DSL (Domestic Substance List) Inventory Status
All components of these products are on the DSL Inventory.
CEPA {Canadian Environmental Protection Act)
Chromium and nickel are on the CEPA Priorities Substances Lists
EINECS No. (European Inventory of Existing Commercial Chemical Substances)
All components of these products are on the EINECS list.
RoHS (Restriction of Certain Hazardous Substances) Compliance
Castings comply with RoHS
CALIFORNIA PROPOSITION 65 Compliance
WARNING: This product contains or produces chemicals known to the State of California to cause cancer and
birth defects (or other reproductive harm). (California Health & Safety Code 25248.5 et seq.)
US STATE REGULATORY INFORMATION
Some of the components listed In Section 3 may be covered under specific state regulations.
SECTION 16-OTHER INFORMATION
SDS SHEET PREPARED BY DATE
American Foundry Society, Inc. 10/13
Occupational Safety & Health Committee (10-Q)
NOTE:
This data and label information is offered in good faith as typical values and not as a product specification. No
warranty either expressed or implied is hereby made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review the recommendations in
specific context of the intended use and determine if they are appropriate.
Page 101 of 516

Page 102 of 516
W. R. MEADOWS,"
SAFETYDATA SHEET
Product: HI-SPEC®JOINT SEALING COMPOUND Part Number: 4210000

9/9/2014
Hot-A lied Joint Sealant
HMIS
I Health I 111
I Flammability I 111 Causes skin irritation.
IReactivity I 101 Heated material will cause burns.
IPersonal Protection I I I PRECAUTIONARY STATEMENTS
Avoid direct contact with heated material.
Avoid inhalation of fumes.
~-g,~f~ltm1!~~~~tlmlii1tSW '
Chemical Name: CAS Number Weight 313 (mm Hg@2D'Cl ~
1. Petroleum Asphalt 8052-42-4 50-55 No N/ A N/ A
2. Petroleum Oil Base Stock 64742-65-0 10-15 No N/A 0.9
3. Limestone 1317-65-3 25-30 No N/A N/A
Part 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA 313." N/A = Not Applicob/e
-=-~
---""-
===-'=
~=---;"-~--,·.~·;,J~llBfflll/~f~,t~iitl&~-
EYE CONTACT: Not expected to be an exposure route as supplied. If contact with molten material occurs, seek immediate medical attention.
SKIN CONTACT: Wash affected areas with soap and water if available. If contact with hot molten material occurs, cool affected area with water.
Do not attempt to remove congealed solid. Do not use petroleum solvents to remove solids adhered to skin. Seek immediate medical attention.
INHALATION: Not expected to be an exposure route as supplied. If irritation occurs due to exposure to fumes produced by hot molten product,
move victim from exposure source and treat symptomatically. If symptoms persist, seek medical attention.
plete combustion product

ect stream of water. Use
w material to cool and
A
Chemical Name: PEL PEL[CEILING PEL[STEL SKIN TLV TLV [CEILING TLV[STEL SKIN
3 3
1. Petroleum Asphalt 5 mg/m * N/E N/E No 0.5 mg/m * N/E N/E N/E
3
2. Petroleum Oil Base Stock N/E N/E N/E No 5 mg/m + N/E N/E N/E
3. Limestone N/A N/A N/A No N/A N/A N/A N/A
*: Asphalt Fumes +: Mineral Oil Mist in Air N/E: Not Established

PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical resistant loves.
,:W;,s~q,_
BOILING POINT: N/A VAPOR DENSI : % VOLATILE BYVOLUME: N/A
EVAPORATION RATE: N/A pH LEVEL: N/ A % VOLATILE BYWEIGHT: N/ A
WEIGHT PER GALLON: N/ A PRODUCTAPPEARANCE: Black solid voe CONTENT: N/A
Page 103 of 516

SAFETYDATA SHEET
9/9/14 4210000
HAZARDOUSPOLYMERIZATION:
Will not occur.
CONDITIONSAND MATERIALS
TO AVOID: None recognized.
HAZARDOUSDECOMPOSITION PRODUCTS:None recognized.
EYECONTACT:Direct contact may cause mild irritation. Contact with heated material may cause severe burns.
SKINCONTACT:Direct contact may cause slight skin irritation. Contact with heated material may cause severe burns.
INHALATION:Not anticipated to be an exposure route. Heated material may emit fumes. Exposure to fumes may result in respiratory irritation.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function.
AGGRAVATED MEDICALCONDITIONS:Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:ACGIH classifies asphalt as Not Classifiable as a Human Carcinogen; A4.

BULKTRANSPORTATION INFORMATION: None.
PREPAREDBY: Dave Care
Page 104 of 516

Thermo Fisher
SCIENTIFIC
SAFETY DATA SHEET

Creation Date 24-Aug-2009 Revision Date 18-Jan-2018 Revision Number 5
Product Name Hydrochloric acid
Cat No.: A481-212; A481-212LC; S71942SC; S71943; S71943ND; S80036;

S80038; SA49
Synonyms Muriatic acid; Hydrogen chloride; HCI (Technical/Certified ACS Plus/Optima/NF/FCC)
Recommended Use Laboratory chemicals.

Uses advised against Not for food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Company
Fisher Scientific
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Emergency Telephone Number

CHEMTREC®, Inside the USA: 800-424-9300
CHEMTREC®, Outside the USA: 001-703-527-3887
1 1:;:•~•1..,.,i,iJli,1ma1111}f~~l:(if~~:1im}:,,i~11~1t!n
i~:t2~f~\h.111i:~;::~~'.;:r.::~'1l''~fiLl{\;~~;~:•
,:~);:~•'.';t,l:i:!,~);~ ;:·.,1
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Corrosive to metals Category 1

Skin Corrosion/irritation Category 1 8
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.
Label Elements
Signal Word
Danger
Hazard Statements
May be corrosive to metals
Causes severe skin burns and eye damage
Page 1 / 8
Page 105 of 516

Hydrochloric acid Revision Date 18-Jan-2018
Prevention
Do not breathe dusUfume/gas/misUvapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Use only outdoors or in a well-ventilated area
Keep only in original container
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Spills
Absorb spillage to prevent material damage
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Store in corrosive resistant polypropylene container with a resistant inliner
Store in a dry place
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
Comoonent CAS-No Weiaht%

Water 7732-18-5 62-65
Hydrochloric acid 7647-01-0 35-38
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.
Inhalation Move to fresh air. ff breathing is difficult, give oxygen. Do not use mouth-to-mouth method if
victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory medical device. Immediate
medical attention is required.
Page 2 /8
Page 106 of 516

Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately.
Most important symptoms and Causes burns by all exposure routes. Product is a corrosive material. Use of gastric
effects lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should
be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue
and danger of perforation
Notes to Physician Treat symptomatically
Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Unsuitable Extinguishing Media No information available
Flash Point No information available

Method - No information available
Autoignition Temperature No information available

Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical

Corrosive Material. Causes burns by all exposure routes. Thermal decomposition can lead to release of irritating gases and vapors.
Hazardous Combustion Products

Hydrogen chloride gas
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Health Flammability Instability Physical hazards

3 0 0 N/A
Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to
safe areas. Keep people away from and upwind of spill/leak. Do not get in eyes, on skin, or
on clothing.
Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological
information.
Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Up
I
Handling Wear personal protective equipment. Do not breathe vapors or spray mist. Do not get in
eyes, on skin, or on clothing. Do not ingest.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area.
Exposure Guidelines
Page 3 / 8
Page 107 of 516

Component ACGIHTLV OSHA PEL NIOSH IDLH Mexico OEL lTWAl

Hydrochloric acid Ceiling: 2 ppm Ceiling: 5 ppm IDLH: 50 ppm Ceiling: 5 ppm
Ceiling: 7 mg/m3 Ceiling: 5 ppm Ceiling: 7 mg/m 3
(Vacated) Celling: 5 ppm Ceiling: 7 mg/m3
(Vacated) Ceiling: 7 mg/m 3
A CGIH - American Conference of Governmental Industrial Hygienists

OSHA - Occupational Safety and Health Administration
N/OSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Physical State Liquid

Appearance Colorless
Odor pungent
Odor Threshold No information available
pH < 1
Melting Point/Range -35 °C / -31 °F
Boiling Point/Range 57 °C / 135 °F @ 760 mmHg
Flash Point No information available
Evaporation Rate No information available
Flammability (solid,gas) Not applicable
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure 125 mbar @ 20 °C
Vapor Density 1.27
Specific Gravity 1.18
Solubility Soluble in water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity 1.8 mPa.s@ 15°C
Molecular Formula HCI.H2O
Molecular Weight 55.55
I:
Reactive Hazard None known, based on information available
Page 418
Page 108 of 516

Stability Stable under normal conditions.
Conditions to Avoid Incompatible products. Excess heat.
Incompatible Materials Metals, Strong oxidizing agents, Bases, sodium hypochlorite, Amines, Fluorine, Cyanides,
Alkaline
Hazardous Decomposition Products Hydrogen chloride gas
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions Contact with metals may evolve flammable hydrogen gas.
Acute Toxicity
Product Information
Oral LD50 Based on ATE data, the classification criteria are not met. ATE> 2000 mg/kg.
Dermal LD50 Based on A TE data, the classification criteria are not met. ATE > 2000 mg/kg.
VaporLC50 Based on ATE data, the classification criteria are not met. ATE > 20 mg/I.
C omponen ti nf orma fron
Component LD50 Oral LD50 Dermal LC50 Inhalation
Water - Not listed Not listed
Hydrochloric acid 238 - 277 mg/kg ( Rat ) > 5010 mg/kg ( Rabbit ) 1.68 mg/L ( Rat ) 1 h
Toxicologically Synergistic No information available

Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation Causes burns by all exposure routes
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component I CAS-No I !ARC I NTP I ACGIH I OSHA I Mexico I

Water I 7732-18-5 I Not listed I Not listed I Not listed I Not listed I Not listed I
Hydrochloric acid I 7647-01-0 I Not listed I Not listed I Not listed I Not listed I Not listed I
/ARC: (International Agency for Research on Cancer) /ARC: (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 2A - Probably Carcinogenic to Humans
Group 28 - Possibly Carcinogenic to Humans
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system

STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
delayed Possible perforation of stomach or esophagus should be investigated: Ingestion causes
severe swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Page 5 / 8
Page 109 of 516

Other Adverse Effects The toxicological properties have not been fully investigated.
Ecotoxicity
Do not empty into drains. Large amounts will affect pH and harm aquatic organisms.
Comoonent Freshwater Alaae Freshwater Fish Microtox Water Flea

Hydrochloric acid - 282 mg/L LC50 96 h
Gambusia affinis
- 56mg/L EC50 72h Daphnia
mg/L LC50 48 h Leucscus

idus
Persistence and Degradability Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility.
Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
DOT
UN-No UN1789
Proper Shipping Name HYDROCHLORIC ACID
Hazard Class 8
Packing Group fl
TDG
UN-No UN1789
Proper Shipping Name HYDROCHLORIC ACID
Hazard Class 8
Packing Group ll
IATA
UN-No UN1789
Proper Shipping Name Hydrochloric acid
Hazard Class 8
Packing Group II
IMDG/IMO
UN-No UN1789
Proper Shipping Name Hydrochloric acid
Hazard Class 8
Packing Group ll
Comoonent TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL
Water X X - 231-791-2 - X - X X X
Hvdrochloric acid X X - 231-595-7 - X X X X X
Legend:
X-Listed
E - Indicates a substance that is the subject of a Section S(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section S(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered
to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
Page 6 / 8
Page 110 of 516

T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(8}.
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b) Not applicable
SARA 313
SARA 313 - Threshold
Component
I CAS-No
I Weight%
Values%
Hydrochloric acid I 7647-01-0 I 35-38 1.0
SARA 3111312 Hazard Categories See section 2 for more information
CWA Clean Water Act

Component CWA - Hazardous CWA - Reportable CWA -Toxic Pollutants CWA - Priority Pollutants
Substances Quantities
H drochloric acid X 5000Ib
Clean Air Act

Com onent HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors
H drochloric acid X
OSHA Occupational Safety and Health Administration

Not applicable
Com onent Specifically RegulatedChemicals Highly Hazardous Chemicals

H drochloric acid TQ: 5000 lb
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)
HazardousSubstances RQs CERCLA EHS RQs

5000Ib 5000Ib
California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know

Requ Ia fions
Comoonent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Water - - X - -
Hvdrochloric acid X X X X X
U.S. Department of Transportation
Reportable Quantity (RQ): Y

DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security

This product contains the following DHS chemicals:
Component DHS Chemical Facilitv Anti-Terrorism Standard

Hydrochloric acid 0 lb STQ (anhydrous); 11250 lb STQ (37% concentration or
greater)
Other International Regulations
Page 7 I 8
Page 111 of 516

Mexico - Grade No information available
Prepared By Regulatory Affairs

Thermo Fisher Scientific
Email: EMSDS.RA@lhermofisher.com
Creation Date 24-Aug-2009

Revision Date 18-Jan-2018
Print Date 18-Jan-2018
Revision Summary SOS sections updated. 2. 3. 11.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of 5D5
Page 8 / 8
Page 112 of 516

BASF
The Chemical Company
Safety Data Sheet

KURE N SEAL 30
Revision date: 2009/09/14 Page: 1/6
Version: 1.0 (30367869/SDS GEN CNEN)
1. Product and Company Identification
Company 24 Hour Emergency Response Information

BASF CANADA CANUTEC (reverse charges): (613) 996-6666
100 Milverton Drive BASF HOTLINE (800) 454-COPE (2673)
Mississauga, ON L5R 4H1
2. Hazards Identification
Emergency overview
FLAMMABLE.
State of matter: liquid

Colour: clear
Odour: strong
Potential health effects
Irritation / corrosion:
Not irritating to eyes and skin. The product has not been tested. The statement has been derived from the
properties of the individual components.
Chronic toxicity:
Repeated dose toxicity: Repeated exposures may cause adverse effects on the brain, as seen in animal
studies.
3. Composition / Information on Ingredients
CAS Number Content (WIW) Hazardous ingredients

64742-95-6 >= 60.0 - <= 100.0 % solvent naphtha
General advice:
First aid personnel should pay attention to their own safety. Remove contaminated clothing.
Page 113 of 516

Safety Data Sheet
KURE N SEAL 30
Version: 1.0 (30367869/SDS GEN CA/EN)
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.
If on skin:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances should organic
solvent be used. If irritation develops, seek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye
specialist.
If swallowed:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting unless
told to by a poison control center or doctor.
Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions.
5. Fire-Fighting Measures
Flash point: 37.78 °C
Suitable extinguishing media:

foam, water spray, dry extinguishing media, carbon dioxide
Unsuitable extinguishing media for safety reasons:

water jet
Hazards during fire-fighting:

carbon monoxide, carbon dioxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
Protective equipment for fire-fighting:

Wear a self-contained breathing apparatus.
Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations.
Personal precautions:
Use personal protective clothing. Do not breathe vapour/aerosol/spray mists. Sources of ignition should be kept
well clear. Handle in accordance with good building materials hygiene and safety practice.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Cleanup:
For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of contaminated
material as prescribed.
For large amounts: Pump off product.
Handling
General advice:
Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skill contact. No special measures necessary
provided product is used correctly.
Page 114 of 516

Safety Data Sheet
KURE N SEAL 30
Protection against fire and explosion:
Keep away from heat. Prevent electrostatic charge - sources of ignition should be kept well dear - fire
extinguishers should be kept handy.
Storage
General advice:
Keep only in the original container in a cool, well-ventilated place. Protect from direct sunlight.
Storage incompatibility:
General advice: Segregate from metals. Segregate from lyes. Segregate from oxidants. Segregate from foods
and animal feeds.
8. Exposure Controls and Personal Protection
Personal protective equipment

Respiratory protection:
When workers are facing concentrations above the occupational exposure limits they must use appropriate
certified respirators.
Hand protection:
Wear chemical resistant protective gloves., Manufacturer's directions for use should be observed because of
great diversity of types.
Eye protection:
Tightly fitting safety goggles (chemical goggles).
Body protection:
Body protection must be chosen based on level of activity and exposure.
General safety and hygiene measures:

Avoid contact with the skin, eyes and clothing. In order to prevent contamination while handling, closed working
clothes and working gloves should be used. Handle in accordance with good building materials hygiene and
safety practice. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks
and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied.
Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).
Form: liquid
Odour: strong, solvent-like
Odour threshold: No data available.
Colour: clear
pH value: not applicable
Unspecified
Vapour pressure: No data available.
Density: 0.91 g/cm3 ( 20 °C)
Vapour density: Heavier than air.
Partitioning coefficient n- No data available.
octanol/water (log Pow):
Viscosity, dynamic: No data available.
Solubility in water: slightly soluble
Page 115 of 516

Safety Data Sheet
KURE N SEAL 30
10. Stability and Reactivity
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous reactions:
The product is stable if stored and handled as prescribed/indicated.
Decomposition products:
Thermal decomposition products: carbon oxides
Oxidizing properties:
Based on its structural properties the product is not classified as oxidizing.
Acute toxicity
Information on: solvent naphtha

Assessment of acute toxicity:
Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by
inhalation. The product has not been tested. The statement has been derived from products of a similar
structure and composition.
Oral:
No data available.
Inhalation:
No data available.
Dermal:
No data available.
Irritation I corrosion

Assessment of irritating effects:
Not irritating to the eyes. Not irritating to the skin. The product has not been tested. The statement has been
derived from products of a similar structure and composition.

Other adverse effects:
Ecological data are not available.
Waste disposal of substance:

Do not discharge substance/product into sewer system. Dispose of in accordance with local authority
regulations.
Page 116 of 516

Safety Data Sheet
KURE N SEAL 30
Container disposal:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after
being thoroughly cleaned.
14. Transport Information
Land transport
TOG
Hazard class: 3
Packing group: Ill
ID number: UN 1263
Hazard label: 3
Proper shipping name: PAINT
Sea transport
IMDG
Hazard class: 3
Packing group: Ill
ID number: UN 1263
Hazard label: 3
Marine pollutant: NO
Air transport
IATNICAO
Hazard class: 3
Packing group: Ill
ID number: UN 1263
Hazard label: 3
15. Regulatory Information
Federal Regulations
Registration status:
Chemical DSL, CA released / listed
WHMIS classification: B2: Flammable Liquid
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR
AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
Page 117 of 516

Safety Data Sheet
KURE N SEAL 30
BASF supports worldwide Responsible Care® initiatives. We value the health and safety of our employees,
customers, suppliers and neighbors, and the protection of the environment. Our comm ltment to Responsible
Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible
fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our
products, and minimizing the impact of our operations on society and the environment during production,
storage, transport, use and disposal of our products.
Local Contact lnfonnation

BASF Construction Chemicals
bcc_prps@basf.com
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE
RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR
PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR
IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR
PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION
SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT
INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE
DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR
TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT
THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE
GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS,
DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED
AT YOUR RISK.
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR
THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF SPARKS LLC
HEREUNDER ARE GIVEN GRATIS AND BASF SPARKS LLC ASSUMES NO OBLIGATION OR LIABILITY
FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL
SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR
THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF POLYURETHANE
FOAM ENTERPRISES LLC HEREUNDER ARE GIVEN GRATIS AND BASF POLYURETHANE FOAM
ENTERPRISES LLC ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA
AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT
YOUR RISK.
END OF DATA SHEET
Page 118 of 516

SAFETY DATA SHEET
LA.Tl CRETE
1. Identification
Product identifier L&M Everbond
Recommended use Bonding agent.
Company Name LATICRETE International
Address 1 Laticrete Park, N
Bethany, CT 06524
Telephone (203)-393-0010
Contact person Steve Fine
Website www.laticrete.corn
Emergency phone number Call CHEMTREC day or night
USA/Canada - 1.800.424.9300
Mexico - 1.800.681.9531
Outside USA/Canada
1.703.527 .3887
Health hazards Serious eye damage/eye irritation Category 2A
Label elements
Signal word Warning

Hazard statement Causes serious eye irritation.
Precautionary statement
Prevention Wash thoroughly after handling. Wear protective gloves/eye protection/face protection.
Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Nbt classified.
classified (HNOC)
Mixtures
Chemical name CAS number %
Polyethylene glycol octylphenyl 9036-19-5 0.5 - 2.5

ether
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Inhalation No specific first aid measures noted.
Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.
L&M Everbond sos us

921641 Version#: 01 Revision date: - Issue date: 11-August-2014 1/ 6
Page 119 of 516

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention.
Ingestion Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content
doesn't get into the lungs. Get medical attention if any discomfort continues.
Most important Irritation of eyes.
delayed
Indication of immediate Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide.
media
Specific hazards arising from By heating and fire, irritating vapors/gases may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace.
Fire-fighting Move containers from fire area if you can do so without risk. Use water spray to cool unopened
equipment/instructions containers.
General fire hazards No unusual fire or explosion hazards noted.

Personal precautions, Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
protective equipment and clean-up. Do not touch damaged containers or spilled material unless wearing appropriate
emergency procedures protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant
spillages cannot be contained.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. For waste disposal, see Section 13 of the SDS.
Environmental precautions Avoid release to the environment. Do not discharge into drains, water courses or onto the ground.
Environmental manager must be informed of all major releases.

Precautions for safe handling Do not breathe mist. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Keep container tightly closed. Store in a cool and well-ventilated place. Store away from
including any incompatibilities incompatible materials (See Section 10).

Occupational exposure limits No exposure limits noted for ingredient(s).
Appropriate engineering Provide eyewash station.
controls
Eye/face protection Wear safety glasses with side shields (or goggles). Face-shield.
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
L&M Everbond SDS US

921641 Version#: 01 Revision date: - Issue date: 11-August-2014 2/6
Page 120 of 516

General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

Appearance White liquid.
Physical state Liquid.
Form Liquid.
Color White.
Odor Odorless.
pH 9.5
Melting point/freezing point Not applicable.
Initial boiling point and boiling Not applicable.
range
Flash point Non flammable.
Evaporation rate Not applicable.
Flammability (solid, gas) Not applicable.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower(%) Not available.
Explosive limit - upper(%) Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density 1.12
Solubility(ies)
Solubility (water) Completely soluble.
Partition coefficient No data available.
(n-octanol/water)
Auto-ignition temperature Not available.

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Possibility of hazardous Will not occur.
reactions
Conditions to avoid Heat, flames and sparks. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Carbon oxides.
products

Ingestion Ingestion may cause irritation and malaise.
Inhalation No inhalation hazard under normal conditions. High mist concentrations may cause irritation of
respiratory tract.
Skin contact May cause skin irritation on prolonged or repeated contact.
Eye contact Causes serious eye irritation.
L&M Everbond sos us

921641 Version #: 01 Revision date: - Issue date: 11-August-2014 3/6
Page 121 of 516

Symptoms related to the Irritation of eyes.
Acute toxicity May cause discomfort if swallowed.
Skin corrosion/irritation May cause skin irritation on prolonged or repeated contact.
Serious eye damage/eye Causes severe eye irritation.
irritation
Respiratory sensitization No data available.
Skin sensitization Not a skin sensitizer.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity No data available.
Specific target organ toxicity - No data available.
single exposure
repeated exposure
Aspiration hazard No data available.
Chronic effects No data available.
Further information Not available.

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Polyethylene glycol octylphenyl ether (CAS 9036-19-5)
Aquatic
Algae IC50 Algae 5000 mg/I, 16 hours
Crustacea EC50 Water flea (Daphnia magna) 18 - 26 mg/I, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) 4 - 8.9 mg/I, 96 hours
Persistence and degradability No data available.

Bioaccumulative potential No data available.
Mobility in soil No data available.
Mobility in general The product is soluble in water.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
L&M Everbond sos us

Page 122 of 516

DOT
IATA
IMDG
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Not regulated.
Not listed.
Not listed.
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA313 (TRI reporting)
Not regulated.

Not regulated.
Not regulated.
(SDWA)
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
Not regulated.
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
Not regulated.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
L&M Everbond sos us
Page 123 of 516

Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) Yes
(PICCS)
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
country(s).

Issue date 11-August-2014
Revision date
Version# 01
NFPA ratings
References HSDB® - Hazardous Substances Data Bank

Registry of Toxic Effects of Chemical Substances (RTE CS)
Disclaimer The information in this (M)SDS was obtained from sources which we believe are reliable but
cannot guarantee. Additionally, your use of this information is beyond our control and may be
beyond our knowledge. Therefore, the information is provided without any representation or
warranty express or implied.
L&M Everbond sos us

Page 124 of 516

SAFETYDATASHEET:MASONRYMORTARAND STUCCOCEMENTS REVISIONDATE:5/4/lS PAGE1
SAFETYDATA SHEET
~olcim MATERIAL: MASONRY MORTAR AND STUCCO CEMENTS

Product Identifier
Product Name: Masonry Mortar and Stucco Cements
Product Codes: Holcim Mortamix Masonry Cement, Holcim Mortar Cement, Holcim Cement-Lime, Holcim Morta mix Rainbow
Custom Color Masonry Cement, Holcim Rainbow Custom Color Cement-Lime, Holcim Custom Stucco. (This SOScovers many
products. Individual constituents will vary.)
Synonyms: Masonry Cement Type 0, N, Sand M. Cement-Lime Type 0, N, Sand M. Mortar Cement Type S, Stucco Cement.
Product Form: Solid / powder
Intended Use of Product: Masonry mortar and stucco cements are cementitious binders used for masonry, exterior and interior
stucco, and other building and construction applications.

24 Crosby Drive
Bedford, MA 01730
(888) 646-5246

Classification (GHS-US)
Skin Corrosion 1B
Eye Damage 1
Skin Sensitizer 1B
Specific Target Organ Toxicity Single Exposure 3
Label Elements
Hazard Pictograms
Signal Word Danger

If on skin: Take off immediately all contaminated clothing. Rinse skin with water. Wash
Oth,Q,;Hazards Exposure may aggravate those with pre-existing eye, skin or respiratory conditions or illness.
Page 125 of 516

SAFETYDATASHEET:MASONRYMORTARAND STUCCOCEMENTS REVISIONDATE:S/4/lS PAGE2
Portland cement 65997-15-1 0-100
Limestone (calcium carbonate) 1317-65-3 0 - 60
Hydrated lime (calcium magnesium hydroxide) 39445-23-3 0 - 55
Magnesium oxide 1309-48-4 0-10
Calcium oxide 1305-78-8 30 - 70
Gypsum (calcium sulfate) 13397-24-5 2-7
Red pigment (hematite) 1317-60-8 0-10
Red pigment (iron oxide) 1309-37-1 0-10
Yellow pigment 51274-00-1 0 -10
Black pigment 12227-89-3 0-10
Ochre 1343-81-3 0-10
Crystalline Silica (Quartz) 14808-60-7 0 -< 1
Other Components
Masonry mortar and stucco cement is made from materials mined from the earth and processed using energy provided by fuels. Additional materials,
such as fly ash, kiln dust and slag may also be introduced into the cement manufacturing process. A chemical analysis of this product may reveal trace
amounts of naturally occurring but potentially harmful chemical compounds such as free crystalline silica, organic compounds, potassium and sodium
compounds, heavy metals including cadmium, chromium (including hexavalent chromium), nickel and lead. Other trace constituents may include
calcium oxide {also known as free lime or quick lime) and organic compounds from grinding aids such as amine acetate salts, glycols and 1,2-
ethanediol.
Section 4- First Aid Measures


RefeF to Section 9 for flammability information.
Page 126 of 516

SAFETY DATA SHEET: MASONRY MORTAR AND STUCCO CEMENTS REVISION DATE: S/4/lS PAGE 3
Section 6 - Accidental Release Measures -

Section 7 - Handling and Storage

compounds, strong acids and oxidizers. Cement dissolves in hydrofluoric acid, producing
corrosive silicon tetrafluoride gas.
Section 8 - Exposure ControJs & Personal Protection -

Exposure Limits for Individual Components (T= Total Respirable [PNOC/PNOR], R=Respirable fraction, l=lnhalable-aerosol)
Hydrated lime 15 mg/m3 (T); 5 mg/m3 (R) 5 mg/m3 5 mg/m3
Magnesium oxide 15 mg/m3 10 mg/m3 (I) Not established
Calcium oxide 5 mg/m3 2 mg/m3 2 mg/m3
Gypsum (Calcium Sulfate) 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 (T) 10 mg/m3 (T); 5 mg/m3 (R)
Limestone (Calcium Carbonate) 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 10 mg/m3 (T); 5 mg/m3 (R)
Red pigment (hematite) 10 mg/m3 5 mg/m3 5 mg/m3
Red pigment (iron oxide) 10 mg/m3 5 mg/m3 5 mg/m3
Yellow pigment 10 mg/m3 5 mg/m3 5 mg/m3
Black pigment 10 mg/m3 5 mg/m3 5 mg/m3
Ochre 10 mg/m3 5 mg/m3 Not established
30 mg/m3 (T) /(% SiO2 + 2)
Exposure Controls
user's respiratory protection program and OSHA/MS HA guidelines.
Page 127 of 516

SAFETYDATASHEET:MASONRYMORTARAND STUCCOCEMENTS REVISIONDATE:5/4/lS PAGE4
Section 9 - Physical and Chemical Properties ~
Physical State Solid, powder Specific Gravity 2.8-3.0

Appearance & Color Grey, buff or colored powder Flash Point/Method None. Not flammable.
B.oiling Point Not applicable Upper Flammability Limit Not applicable
Solubility (Water) Negligible (<1%) Octanol/H2O Coefficient Not determined
Evaporation Rate Not applicable Viscosity Not applicable
Section 10- Stability and Reactivity
Reactivity Reacts with water to create heat and calcium hydroxide.
Incompatible Materials Avoid contact with strong acids, oxidizers and ammonium salts.
Section 11-Toxicological Information ~
Product: Blended hydraulic cement
Carcinogenicity Material contains trace amounts of crystalline silica, which may cause lung cancer
through repeated or prolonged exposure to dust.
Specific Organ Toxicity (Single Exposure) May cause respiratory irritation.
chemical burns.
Portland cement {also see Section 16) No data Not listed Not listed Not listed
Hydrated lime Oral LOSORat 7340 mg/kg Not listed Not listed Not listed
Magnesium oxide Oral LOSORat 810 mg/kg Not listed Not listed Not listed
Calcium oxide Oral LOSORat 500 mg/kg Not listed Not listed Not listed
Gypsum (Calcium Sulfate) Oral LOSORat >2000 mg/kg Not listed Not listed Not listed
Limestone (Calcium carbonate) Oral LOSORat 6450 mg/kg Not listed Not listed Not listed
Red pigment (hematite) Oral LOSORat >10000 mg/kg Group 3 Not listed Not listed
Red pigment (iron oxide) Oral LOSORat >10000 mg/kg Group 3 Not listed Not listed
Yellow pigment Oral LOSORat >10000 mg/kg Not listed Not listed Not listed
Black pigment Oral LOSORat >10000 mg/kg Not listed Not listed Not listed
Ochre Oral LOSORat >10000 mg/kg Not listed Not listed Not listed
Crystalline Silica (Quartz) {also see Section 16) Oral LOSORat >22,500 mg/kg Group 1 Known Not listed
LCSOCarp >10,000 mg/L (72 hr)
Page 128 of 516

SAFETYDATASHEET:MASONRYMORTARAND STUCCOCEMENTS REVISIONDATE:S/4/lS PAGES

Section 13- Disposal Considerations -
regulations.
Special Considerations Avoid creating or breathing dust during disposal. Avoid contact with skin and eyes.
Proper Shipping Name N/ A- not regulated.
UN Shipping ID Number N/ A - not regulated.
Packing Group N/A - not regulated.
Section 15- Regulatory Information
Federal
• Components: Portland cement, Silica (Crystalline), Iron oxide
State
for one or more of the following states: California, Maine, Minnesota, New Jersey, Pennsylvania and Rhode Island. An exam in at ion
• Components: Portland cement, Limestone (calcium carbonate), Gypsum (calcium sulfate), Silica (Crystalline), Iron oxide
The state of California requires the following statement (Proposition 65) in regards to this material:
reproductive harm.
Section 16 - Other Information

Additional information regarding products containing portland cement:

result in blisters, dead or hardened skin, or black or green skin. In severe cases, these burns may extend to the bone and ca use
Page 129 of 516

SAFETYDATA SHEET: MASONRY MORTAR AND STUCCOCEMENTS REVISIONDATE:5/4/15 PAGE6

!ARC:The overall IARC evaluation was that "crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (Group 1)." The !ARC evaluation noted that "carcinogenicity was not detected in all industrial
NTP: The National Toxicology Program {NTP), in its Thirteenth Annual Report on Carcinogens, classified "silica, crystalline

While the information provided in this document is believed to provide a useful summary of the hazards of masonry mortar and
stucco cement, the information in this document cannot anticipate and provide all of the information that might be needed in every
situation. Inexperienced product users should obtain proper training before using this product.
The data furnished in this document do not address hazards that may be posed by other materials when mixed with masonry mortar
and stucco cement. Users should review other relevant safety data sheets before working with this product.
SELLERMAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS
--END OF SAFETYDATA SHEET--
Page 130 of 516

W. R. MEADOWS
..
SAFETYDATA SHEET
Page 1 of 2
Product: MEL-ROL ® Waterproofing Membrane Part Number: 5110060

Hampshire, Illinois 60140'
9/9/2014
Water roofin Membrane
__
~fil$f§'I.Q))t~:2:ttfl~~JIP~1t:l~t~Mlie~~;g1il _
Product is classified as non-hazardous per OSHA 1910.1200. Mel-Roi is
defined by OSHA as an "article." A manufactured item that is formed to a specific shape or
design during manufacture that does not release or result in exposure to a hazardous
nder normal use conditions.

Weight 313 (mm Hg@20°Cl 24°
55-60 No N/A N/A
Ill of the Superfund Amendments and Reauthorization Act o
ified under the headin "SARA 313."
]fflJS;itll~]E!~IEEP,~ltES~=-::
}
EYE CONTACT: Not expected to be an exposure route.
SKIN CONTACT: Wash affected areas with soap and water if available.
INHALATION: Not expected to be an exposure route.
FLASHPOINT: Not applicable; product is a solid.

CHEMICAL/COMBUSTION HAZARDS: Oxides and compounds of nitrogen/sulfur.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Use
Asphalt
CONTRO
halt Fumes
EYE CONTACT: Direct contact may cause mild irritation.

SKIN CONTACT: Direct contact may cause slight skin irritation.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include
redness and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
Page 131 of 516

SAFETYDATA SHEET
Page 2 of 2 5112060
.~ ,', J~l11t<;e:6ffi;::
DEGRADABILITY: N/E BIOACCUMULATIVE POTENTIAL: N/E
FECTS: None Reco nized

UN NUMBER: None HAZARD CLASS: N/A PACKING GROUP: N/A
Dave Carey
Page 132 of 516

DATASHEET:PORTLANDCEMENT
SAFETY REVISIONDATE:5/2/15 PAGE 1
SAFETYDATA SHEET
~olcim PORTLANDCEMENT
MATERIAL:

Product Identifier
Prod.Yet Name: Portland Cement
Product Codes: Portland Cement Type I, IA, 11,IIA, Ill, IIIA, IV, IVA, V, VA, White Cement, CSAType GU, MS, HE, LH, HS.
This SDScovers many products. Individual constituents will vary.
Synonyms: Cement, cement powder, portland cement, hydraulic cement
Product Form: Solid/ powder
Intended Use of Product: Portland cement is used as a binder in combination with water and aggregates to form concrete. It is also
used as a component of masonry mortar and other building and construction materials.

24 Crosby Drive
Bedford, MA 01730
(888) 646-5246

Skin Corrosion 1B
Eye Damage 1
Skin Sensitizer 1B
Specific Target Organ Toxicity: Single Exposure (Lungs) 3
Label Elements
Hazard Pictograms
Signal Word Danger

If on skin:Take off immediately all contaminated clothing. Rinse skin with water. Wash
Other Hazards Exposure may aggravate those with pre-existing eye, skin or respiratory conditions or illness.
Page 133 of 516

SAFETY DATA SHEET: PORTLAND CEMENT REVISION DATE: S/2/lS PAGE2
Portland cement 65997-15-1 100
Tricalcium silicate 12168-85-3 20- 70
Dicalcium silicate 10034-77-2 10- 60
Tetracalcium aluminoferrrite 12068-35-8 5 -15
Gypsum (Calcium Sulfate) 13397-24-5 2-10
Tri-calcium Aluminate 12042-78-3 1-15
Limestone (Calcium Carbonate) 1317-65-3 0-20
Magnesium oxide 1309-48-4 < 1- 4
Nuisance Dusts (Particulates not otherwise regulated) None < 1- 5
Crystalline Silica (Quartz) 14808-60-7 0-<1
Other Components
Cement is made from materials mined from the earth and processed using energy provided by fuels. Additional materials, such as fly ash, kiln dust and
slag may also be introduced into the cement manufacturing process. A chemical analysis of cement may reveal trace amounts of naturally occurring but
potentially harmful chemical compounds such as free crystalline silica, organic compounds, potassium and sodium compounds, heavy metals including
cadmium, chromium (including hexavalent chromium), nickel and lead. Other trace constituents may include calcium oxide (also known as free lime or
quick lime) and organic compounds from grinding aids such as amine acetate salts, glycols and 1,2-ethanediol.
Section 4 - first Aid Measures


Refer to Section 9 for flammability information.
Page 134 of 516

SAFETY DATA SHEET: PORTLAND CEMENT REVISION DATE: S/2/lS PAGE3
Section 6 - Accidental Release Measures

Section 7 - Handling and Storage
compounds, strong acids, alkalines, and oxidizers. Cement dissolves in hydrofluoric acid,
producing corrosive silicon tetrafluoride gas.
Section 8 - Exposure Controls & Personal Protection
Exposure Limits for Individual Components (T= Total Respirable [PNOC/PNOR], R=Respirable fraction, l=lnhalable-aerosol)
Tricalcium silicate 15 mg/m3 (T); 5 mg/m3 (R) Not listed 10 mg/m3 (T); 5 mg/m3 (R)
Dicalcium silicate 15 mg/m3 (T); 5 mg/m3 (R) Not listed 10 mg/m3 (T); 5 mg/m3 (R)
Tetracalcium aluminoferrite 15 mg/m3 (T); 5 mg/m3 (R) Not listed 10 mg/m3 (T); 5 mg/m3 (R)
Gypsum (Calcium Sulfate) 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 (T) 10 mg/m3 (T); 5 mg/m3 (R)
Tri-calcium Aluminate 15 mg/m3 (T); 5 mg/m3 (R) Not listed 10 mg/m3 (T); 5 mg/m3 (R)
Limestone (Calcium Carbonate) 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 10 mg/m3 (T); 5 mg/m3 (R)
Magnesium oxide 15 mg/m3 10 mg/m3 (I) Not established
Nuisance Dusts (PNOR) 15 mg/m3 (T); 5 mg/m3 (R) 10 mg/m3 Not established
30 mg/m3 (T) /(% SiO2 + 2)
Exposure Controls
user's respiratory protection program and OSHA/MSHA guidelines.
Section 9 - Physical and Chemical Properties
Physical State Solid, powder Specific Gravity 3.1- 3.2
Appearance & Color Grey/off-white powder Flash Point/Method None. Not flammable.
Boiling Point Not applicable Upper Flammability Limit Not applicable
Solubility (Water) Slight (<5%) Octanol/H2O Coefficient Not determined
Evaporation Rate Not applicable Viscosity Not applicable
Page 135 of 516

SAFETYDATASHEET: PORTLANDCEMENT REVISIONDATE:5/2/15 PAGE4
Section 10 - Stability and Reactivity
Reactivity Reacts with water creating heat and calcium hydroxide.
Incompatible Materials Avoid contact with strong acids, oxidizers, aluminum and ammonium salts.
Section 11 - Toxicological Information

Product: Portland cement
Carcinogenicity Material contains trace amounts of crystalline silica, which may cause lung cancer
through repeated or prolonged exposure to dust.
Specific Organ Toxicity (Single Exposure) Not reported/no data available.
chemical burns.
Portland cement No data Not listed Not listed Not listed
(refer to Section 16 for more information)
Tricalcium silicate No data Not listed Not listed Not listed
Dicalcium silicate No data Not listed Not listed Not listed
Tetracalcium aluminoferrite No data Not listed Not listed Not listed
Gypsum (Calcium Sulfate) Oral LOSORat >2000 mg/kg Not listed Not listed Not listed
Tri-calcium Aluminate No data Not listed Not listed Not listed
Limestone (Calcium carbonate) Oral LOSORat 6450 mg/kg Not listed Not listed Not listed
Magnesium oxide Oral LOSORat 810 mg/kg Not listed Not listed Not listed
Nuisance Dusts (PNOR) No data Not listed Not listed Not listed
Crystalline Silica (Quartz) Oral LOSORat >22,500 mg/kg Group 1 Known Not listed
(refer to Section 16 for more information) LCSOCarp >10,000 mg/L (72 hr)

Page 136 of 516

SAFETYDATASHEET:PORTLANDCEMENT REVISIONDATE:S/2/lS PAGES
Section 13 - Disposal Considerations

regulations.
Special Considerations Avoid creation or breathing dust during disposal. Avoid contact with skin and eyes. Refer to
Section 8 for personal protection measures.

Proper Shipping Name N/A- not regulated.
UN Shipping ID Number N/ A- not regulated.
Packing Group N/ A- not regulated.
Section 15 - Regulatory Information

Federal
State
for one or more of the following states: California, Maine, Minnesota, New Jersey, Pennsylvania and Rhode Island. An examination
• Components: Portland cement, Limestone (calcium carbonate), Gypsum (calcium sulfate), Silica (Crystalline)
The state of California requires the following statement (Proposition 65) in regards to this material:
reproductive harm.
Section 16 - Other Information

Additional information regarding portland cement:

result in blisters, dead or hardened skin, or black or green skin. In severe cases, these burns may extend to the bone and cause
Page 137 of 516

SAFETY DATA SHEET: PORTLAND CEMENT REVISION DATE: S/2/lS PAGE 6

IARC: The overall lARC evaluation was that "crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (Group l)." The IARC evaluation noted that "carcinogenicity was not detected in all industrial
NTP: The National Toxicology Program (NTP), in its Thirteenth Annual Report on Carcinogens, classified "silica, crystalline

While the information provided in this document is believed to provide a useful summary of the hazards of portland cement, the
information in this document cannot anticipate and provide all of the information that might be needed in every situation.
Inexperienced product users should obtain proper training before using this product.
The data furnished in this document do not address hazards that may be posed by other materials when mixed with portland
cement. Users should review other relevant safety data sheets before working with this product.
SELLERMAKES NO WARRANTY, EXPRESSEDOR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS
--END OF SAFETY DATA SHEET--
Page 138 of 516

Lafarge Portland Cement (cement)
Safety Data Sheet
according to Federal Register/ Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 04/23/2015 Date of issue: 03/01/2014 Supersedes Date: 03/01/2014 Version: 2.0
SECTION 1: IDENTIFICATION
Product Identifier
Product Name: Lafarge Portland Cement (cement)
Synonyms: Cement, Portland Cement, Hydraulic Cement, Oil Well Cement, Trinity® White Cement, Antique White Cement, Portland
Limestone Cement, Portland Cement Type I, IA, IE, II, 1/11,IIA, II L.A., Ill, IIIA, IV, IVA, V, VA, 10, 20, 30, 40, SO,GU, GUL, MS, MH, HE,
LH, HS, OWH, OWG Cement, OW Class G HSR, lnfiniCem™
Note: This SOScovers many types of Portland cement. Individual composition of hazardous constituents will vary between types of
Portland cement.
Intended Use of the Product
Cement is used as a binder in concrete and mortars that are widely used in construction. Cement is distributed in bags, totes and
bulk shipment.
Name, Address, and Telephone of the Responsible Party
Company
Lafarge North America Inc.
8700 West Bryn Mawr Avenue, Suite 300
Chicago, IL 60631
Information: 773-372-1000 (9am to 5pm CST)
email: SDSinfo@Lafarge.com
Website: www.lafarge-na.com
Emergency Telephone Number
Emergency number : 1-800-451-8346 (3E Hotline)
SECTION 2: HAZARDS IDENTIFICATION
Skin Corr. lC H314
Eye Dam. 1 H318
Skin Sens. 1 H317
Care. lA H350
STOTSE 3 H335
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US}
GHSOS GHS07 GHSOB
Signal Word (GHS-US) Danger

Hazard Statements (GHS-US) H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H335 - May cause respiratory irritation
H350 - May cause cancer (Inhalation)
Precautionary Statements (GHS-US) P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P260 - Do not breathe dust.
P264 - Wash hands, forearms, and exposed areas thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves, protective clothing, face protection, eye protection.
P301+P330+P331- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361 +P353+P352 - IF ON SKIN (or hair): Remove/Take off immediately all
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Safety Data Sheet
contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water.
P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTERor doctor/physician.
P321- Specific treatment (see Section 4).
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P405 - Store locked up.
P501- Dispose of contents/container according to local, regional, state, national, territorial,
provincial, and international regulations.
Other Hazards
Other Hazards Not Contributing to the Classification: Inhalation can cause serious, potentially irreversible lung/respiratory tract
tissue damage due to chemical (caustic) burns, including third degree burns. Individuals with lung disease (e.g. bronchitis,
emphysema, COPD, pulmonary disease) or sensitivity to hexavalent chromium can be aggravated by exposure.
Unknown Acute Toxicity {GHS-US) Not available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Name Product identifier % (w/w) Classification (GHS-US)
Cement, portland, chemicals (CAS No) 65997-15-1 100 Skin lrrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
STOTSE3, H335
Limestone (CAS No) 1317-65-3 0-15 Not classified
Gypsum (Ca(SO4).2H2O) (CAS No) 13397-24-5 2-10 Not classified
Calcium oxide (CAS No) 1305-78-8 0-5 Skin Corr. lC, H314
Eye Dam. 1, H318
STOTSE 3, H335
Magnesium oxide (MgO) (CAS No) 1309-48-4 0-4 Not classified
Quartz (CAS No) 14808-60-7 0- 0.2 Care. lA, H350
STOTSE3, H335
STOT RE 1, H372
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Keep at rest and in a position comfortable for
breathing. If you feel unwell, seek medical advice.
Skin Contact: Remove contaminated clothing. Immediately flush skin with plenty of water for at least 60 minutes. Immediately call a
POISON CENTERor doctor/physician.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for
at least 60 minutes. Immediately call a POISON CENTERor doctor/physician.
Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTERor doctor/physician.
Most Important Symptoms and Effects Both Acute and Delayed
General: Corrosive to eyes, respiratory system and skin. Exposure may produce an allergic reaction.
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Inhalation: The three types of silicosis include: 1) Simple chronic silicosis - which results from long-term exposure (more than 20
years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirab le
crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic
obstructive pulmonary disease (COPD); 2) Accelerated silicosis - occurs after exposure to larger amounts of respirable crystalline
silica over a shorter period of time (5-15 years); 3) Acute silicosis - results from short-term exposure to very large amounts of
respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood
oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis. Progressive
massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive
fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to
respirable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several
autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis and
diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic
kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Corrosive to the respiratory tract.
Skin Contact: Cement may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Exposure of sufficient duration to wet
cement, or to dry cement on moist areas of the body, can cause serious, potentially irreversible damage to skin, eye, respiratory and
digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be hazardous even if there is no
pain or discomfort. Cement is capable of causing dermatitis by irritation and allergy. Skin affected by dermatitis may include
symptoms such as, redness, itching, rash, scaling, and cracking. Irritant dermatitis is caused by the physical properties of cement
including alkalinity and abrasion. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in
cement. The reaction can range from a mild rash to severe skin ulcers. Persons already sensitized may react to the first contact with
cement. Others may develop allergic dermatitis after years of repeated contact with cement.
Eye Contact: Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of dry
powder or with wet cement can cause moderate eye irritation, chemical burns and blindness. Eye exposures require immediate first
aid and medical attention to prevent significant damage to the eye.
Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract.
Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung disease.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention.
SECTION5: FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not flammable.
Explosion Hazard: Product is not explosive.
Reactivity: Wet cement is alkaline and is incompatible with acids, ammonium salts and aluminum metal. Cement dissolves in
hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide.
Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen
difluoride.
Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Do not get water inside containers. Do not apply water stream directly at source of leak.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: None.
Reference to Other Sections
Refer to section 9 for flammability properties.
SECTION6: ACCIDENTALRELEASEMEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Do not breathe dust. Do not get in eyes, on skin, or on clothing.
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
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For Emergency Personnel

Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area.
Prevent entry to sewers and public waters.
Methods and Material for Containment and Cleaning Up
For Containment: Place spilled material into a container. Avoid actions that cause the cement to become airborne. Avoid inhalation
of cement and contact with skin. Wear appropriate protective equipment as described in Section 8. Scrape wet cement and place in
container. Allow material to dry or solidify before disposal. Do not wash cement down sewage and drainage systems or into bodies
of water (e.g. streams).
Methods for Cleaning Up: Avoid actions that cause dust to become airborne during clean-up such as dry sweeping or using
compressed air. Use HEPA vacuum or thoroughly wet with water to clean-up dust. Use PPEdescribed in Section 8.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13.
SECTION7: HANDLING AND STORAGE
Precautions for Safe Handling
Additional Hazards When Processed: Keep bulk and bagged cement dry until used. Stack bagged material in a secure manner to
prevent falling. Bagged cement is heavy and poses risks such as sprains and strains to the back, arms, shoulders and legs during
lifting and mixing. Handle with care and use appropriate control measures. Engulfment hazard. To prevent burial or suffocation, do
not enter a confined space, such as a silo, bin, bulk truck, or other storage container or vessel that stores or contains cement.
Cement can buildup or adhere to the walls of a confined space. The cement can release, collapse or fall unexpectedly. Properly
ground all pneumatic conveyance systems. The potential exists for static build-up and static discharge when moving cement
powders through a plastic, non-conductive, or non-grounded pneumatic conveyance system. The static discharge may result in
damage to equipment and injury to workers. Cutting, crushing or grinding hardened cement, concrete or other crystalline silica-
bearing materials will release respirable crystalline silica. Use all appropriate measures of dust control or suppression, and Personal
Protective Equipment (PPE)described in Section 8 below.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work. Wash contaminated clothing before
reuse.
Conditions for Safe Storage, Including Any Incompatibilities
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use.
Incompatible Materials: Wet cement is alkaline and is incompatible with acids, ammonium salts and aluminum metal. Cement
dissolves in hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium
hydroxide. Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and
oxygen difluoride.
Storage Temperature: Unlimited
Specific End Use(s) Cement is used as a binder in concrete and mortars that are widely used in construction. Cement is distributed
in bags, totes and bulk shipment.
SECTION8: EXPOSURECONTROLS/PERSONALPROTECTION
Control Parameters
Mexico OEL TWA (mg/m') 10 mg/m 3

Mexico OEL STEL(mg/m') 20 mg/m'
USA OSHA OSHA PEL(TWA) (mg/m 3 ) S mg/m'
USA NIOSH NIOSH REL(TWA) (mg/m 3 ) S mg/m 3
Alberta OEL TWA (mg/m 3 ) 10 mg/m 3
British Columbia OEL STEL(mg/m 3 ) 20 mg/m'
British Columbia OEL TWA (mg/m 3 ) 3 mg/m'
New Brunswick OEL TWA (mg/m 3 ) 10 mg/m 3
Nunavut OELTWA (mg/m 3 ) 10 mg/m' (total mass)
Northwest Territories OEL TWA (mg/m') 10 mg/m' (total mass)
Quebec VEMP (mg/m') 10 mg/m 3 (Limestone, containing no Asbestos and <1% Crystalline silica)
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Saskatchewan OEL STEL(mg/m 3 ) 20 mg/m 3

Saskatchewan OELTWA (mg/m 3 ) 10 mg/m 3
Yukon OEL STEL(mg/m 3 ) 20 mg/m 3
Yukon OELTWA (mg/m 3 ) 10 mg/m 3
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Mexico OELTWA (mg/m 3 ) 10 mg/m 3
Mexico OEL STEL(mg/m 3 ) 20 mg/m 3
USAACGIH ACGIH TWA (mg/m 3 ) 1 mg/m 3
USA OSHA OSHA PEL(TWA) (mg/m 3 ) 5 mg/m 3
USA NIOSH NIOSH REL(TWA) (mg/m 3 ) 5 mg/m 3
USAIDLH US IDLH (mg/m 3 ) 5000 mg/m 3
Alberta OELTWA (mg/m 3 ) 10 mg/m 3
British Columbia OELTWA (mg/m 3 ) 3 mg/m 3 (particulate matter containing no Asbestos and <1% Crystalline
silica)
Manitoba OELTWA (mg/m 3 ) 1 mg/m 3 (particulate matter containing no Asbestos and <1% Crystalline
silica)
New Brunswick OELTWA (mg/m 3 ) 10 mg/m 3
Newfoundland & Labrador OELTWA (mg/m 3 ) 1 mg/m 3 (particulate matter containing no Asbestos and <1% Crystalline
silica)
Nova Scotia OELTWA (mg/m 3 ) 1 mg/m 3 (particulate matter containing no Asbestos and <1% Crystalline
silica)
Nunavut OELTWA (mg/m 3 ) 10 mg/m 3 (total mass)
Northwest Territories OELTWA (mg/m 3 ) 10 mg/m 3 (total mass)
Ontario OELTWA (mg/m 3 ) 1 mg/m 3 (containing no Asbestos and <1% Crystalline silica)
Prince Edward Island OELTWA (mg/m 3 ) 1 mg/m 3 (particulate matter containing no Asbestos and <1% Crystalline
silica)
Quebec VEMP (mg/m 3 ) 5 mg/m 3 (containing no Asbestos and <1% Crystalline silica)
Saskatchewan OELTWA (mg/m 3 ) 10 mg/m 3
Yukon OELSTEL(mg/m 3 ) 20 mg/m 3
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Mexico OELTWA (mg/m ) 10 mg/m 3
USA OSHA OSHA PEL (TWA) (mg/m 3 ) S mg/m 3
USA NIOSH NIOSH REL(TWA) (mg/m 3 ) S mg/m 3
Alberta OELTWA (mg/m 3 ) 10 mg/m 3
British Columbia OELSTEL(mg/m 3 ) 20 mg/m 3
British Columbia OELTWA (mg/m 3 ) 3 mg/m 3
Manitoba OELTWA (mg/m 3 ) 10 mg/m 3
Newfoundland & Labrador OELTWA (mg/m 3 ) 10 mg/m 3
Nova Scotia OELTWA (mg/m 3 ) 10 mg/m 3
Nunavut OELTWA (mg/m 3 ) 10 mg/m 3 (total mass)
Northwest Territories OELTWA (mg/m 3 ) 10 mg/m 3 (total mass)
Ontario OELTWA (mg/m 3 ) 10 mg/m 3
Prince Edward Island OELTWA (mg/m 3 ) 10 mg/m 3
Quebec VEMP (mg/m 3 ) 5 mg/m 3 (containing no Asbestos and <1% Crystalline silica)
Saskatchewan OELTWA (mg/m ) 3
10 mg/m 3
Yukon OELSTEL(mg/m 3 ) 20 mg/m 3
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,,;,•s
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Mexico OEL TWA (mg/m 3 ) 2 mg/m 3
USA OSHA OSHA PEL (TWA) (mg/m 3 ) 5 mg/m 3
USA NIOSH NIOSH REL(TWA) (mg/m 3 ) 2 mg/m 3
British Columbia OEL TWA (mg/m 3 ) 2 mg/m 3
Manitoba OEL TWA (mg/m 3 ) 2 mg/m 3
Newfoundland & Labrador OEL TWA (mg/m 3 ) 2 mg/m 3
Nova Scotia OEL TWA (mg/m 3 ) 2 mg/m 3
Nunavut OEL STEL(mg/m 3 ) 4 mg/m 3
Nunavut OEL TWA (mg/m 3 ) 2 mg/m 3
Northwest Territories OEL STEL(mg/m 3 ) 4 mg/m 3
Northwest Territories OEL TWA (mg/m 3 ) 2 mg/m 3
Ontario OEL TWA (mg/m 3 ) 2 mg/m 3
Prince Edward Island OEL TWA (mg/m 3 ) 2 mg/m 3
Quebec VEMP (mg/m 3 ) 2 mg/m 3
Saskatchewan OEL TWA (mg/m 3 ) 2 mg/m 3
Yukon OEL TWA (mg/m 3 ) 2 mg/m 3
Magi1~iU1D'.oxide·JMiOJ:D.3os'.'48c4J!i'titJ
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, ssii,,)(;,~)' ·. Ii({) ·.>;;c~./; ,f~)z!~
Mexico OEL TWA (mg/m 3 ) 10 mg/m 3
3
USA OSHA OSHA PEL (TWA) (mg/m ) 15 mg/m 3

British Columbia OEL STEL(mg/m 3 ) 10 mg/m 3
British Columbia OEL TWA (mg/m 3 ) 3 mg/m 3
Manitoba OEL TWA (mg/m 3 ) 10 mg/m 3
Newfoundland & Labrador OEL TWA (mg/m 3 ) 10 mg/m 3
Nova Scotia OEL TWA (mg/m 3 ) 10 mg/m 3
Nunavut OEL STEL(mg/m 3 ) 20 mg/m 3
Nunavut OEL TWA (mg/m 3 ) 10 mg/m 3
Northwest Territories OEL STEL(mg/m 3 ) 20 mg/m 3
Northwest Territories OEL TWA (mg/m 3 ) 10 mg/m 3
Ontario OEL TWA (mg/m 3 ) 10 mg/m 3
Prince Edward Island OEL TWA (mg/m 3 ) 10 mg/m 3
Quebec VEMP (mg/m 3 ) 10 mg/m 3
Saskatchewan OEL TWA (mg/m 3 ) 10 mg/m 3
Yukon OEL TWA (mg/m 3 ) 10 mg/m 3
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Mexico OEL TWA (mg/m ) 0.1 mg/m 3
USAACGIH ACGIH TWA (mg/m 3 ) 0.025 mg/m 3

3
USA OSHA OSHA PEL(STEL)(mg/m ) 250 mppcf/%SiO2+5, 10mg/m 3/%SiO2+2
3
USA NIOSH NIOSH REL(TWA) (mg/m ) 0.05 mg/m 3
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USAIDLH US IDLH (mg/m 3 ) SO mg/m 3

Alberta OELTWA (mg/m 3 ) 0.025 mg/m 3
British Columbia OELTWA (mg/m 3 ) 0.025 mg/m 3
Manitoba OELTWA (mg/m 3 ) 0.025 mg/m 3
New Brunswick OELTWA (mg/m 3 ) 0.1 mg/m 3
Newfoundland & Labrador OELTWA (mg/m 3 ) 0.025 mg/m 3
Nova Scotia OELTWA (mg/m 3 ) 0.025 mg/m 3
Nunavut OELTWA (mg/m 3 ) 0.3 mg/m 3 (total mass)
Northwest Territories OEL TWA (mg/m 3 ) 0.3 mg/m 3 (total mass)
Ontario OEL TWA (mg/m 3 ) 0.10 mg/m 3 (designated substances regulation)
Prince Edward Island OELTWA (mg/m 3 ) 0.025 mg/m 3
Quebec VEMP (mg/m 3 ) 0.1 mg/m 3
Saskatchewan OELTWA (mg/m 3 ) 0.05 mg/m 3
Yukon OELTWA (mg/m 3 ) 300 particle/ml
Exposure Controls
Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Use local exhaust or general dilution ventilation or other suppression methods to maintain dust levels
below exposure limits. Power equipment should be equipped with proper dust collection devices.
Personal Protective Equipment: Gloves. In case of dust production: protective goggles. Dust formation: dust mask.
Materials for Protective Clothing: Chemically resistant materials and fabrics.

Hand Protection: Wear gloves impervious to water to prevent skin contact. Do not rely on barrier creams, in place of impervious
gloves.
Eye Protection: Wear ANSI approved glasses or safety goggles when handling dust to prevent contact with eyes. Wearing contact
lenses when using Limestone and Dolomite, under dusty conditions, is not recommended.
Skin and Body Protection: Wear gloves, boot covers and protective clothing impervious to water to prevent skin contact. Do not rely
on barrier creams, in place of impervious gloves.
Respiratory Protection: Wear a NIOSH approved respirator that is properly fitted and is in good condition when exposed to dust
above exposure limits.
Other Information: When using, do not eat, drink or smoke
SECTION9: PHYSICALAND CHEMICALPROPERTIES
Information on Basic Physical and Chemical Properties
Physical State Solid
Appearance Gray, off white or white powder
Odor Odorless
Odor Threshold Not available
pH 12 - 13 (in water)
Relative Evaporation Rate (butylacetate=l) Not available
Melting Point Not available
Freezing Point Not available
Boiling Point > 1000 °C (> 1832 °F)
Flash Point Not available
Auto-ignition Temperature Not available
Decomposition Temperature Not available
Flammability (solid, gas) Not available
Lower Flammable Limit Not available
Upper Flammable Limit Not available
Vapor Pressure Not available
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Relative Vapor Density at 20 •c Not available

Relative Density/Specific Gravity 3.15
Solubility Water: 0.1 - 1 % (slightly soluble)
Partition coefficient: n-octanol/water Not available
Viscosity Not available
Explosion Data - Sensitivity to Mechanical Impact Not expected to present an explosion hazard due to mechanical impact.
Explosion Data - Sensitivity to Static Discharge Not expected to present an explosion hazard due to static discharge.
SECTION 10: STABILITYAND REACTIVITY
Reactivity: Wet cement is alkaline and is incompatible with acids, ammonium salts and aluminum metal. Cement dissolves in
hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide.
Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen
difluoride.
Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Extremely high or low temperatures. Incompatible materials.
Incompatible Materials: Acids. Ammonium salts. Aluminum. Hydrofluoric acid. Water. Oxidizers.
Hazardous Decomposition Products: None known.
SECTION 11: TOXICOLOGICALINFORMATION
Information on Toxicological Effects - Product
Acute Toxicity: Not classified
LDS0 and LCS0 Data: Not available
Skin Corrosion/Irritation: Causes severe skin burns and eye damage. (pH: 12 - 13 (in water))
Serious Eye Damage/Irritation: Causes serious eye damage. (pH: 12 - 13 (in water))
Respiratory or Skin Sensitization: May cause an allergic skin reaction.
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not available
Carcinogenicity: May cause cancer (Inhalation).
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation.
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: The three types of silicosis include: 1) Simple chronic silicosis - which results from long-term
exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked
by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may
resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis - occurs after exposure to larger amounts of
respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis - results from short-term exposure to very
large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of
breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple
silicosis. Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form.
Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show
that exposure to respirable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased
incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid
arthritis and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of
chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Corrosive to the respiratory
tract.
Symptoms/Injuries After Skin Contact: Cement may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Exposure of
sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious, potentially irreversible damage to
skin, eye, respiratory and digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be
hazardous even if there is no pain or discomfort. Cement is capable of causing dermatitis by irritation and allergy. Skin affected by
dermatitis may include symptoms such as, redness, itching, rash, scaling, and cracking. Irritant dermatitis is caused by the physical
properties of cement including alkalinity and abrasion. Allergic contact dermatitis is caused by sensitization to hexavalent chromium
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(chromate) present in cement. The reaction can range from a mild rash to severe skin ulcers. Persons already sensitized may react to
the first contact with cement. Others may develop allergic dermatitis after years of repeated contact with cement.
Symptoms/Injuries After Eye Contact: Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with
large amounts of dry powder or with wet cement can cause moderate eye irritation, chemical burns and blindness. Eye exposures
require immediate first aid and medical attention to prevent significant damage to the eye.
Symptoms/Injuries After Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract.
Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung disease.
Information on Toxicological Effects - lngredient{s)
LOSOand LCSOData:
ATE CLP (oral)

'.ctuaffz.11Mios~~1)C.'>
LOSOOral Rat
f1-1Bos-.60:11·.•t
'Qoarfi
IARC Group
National Toxicity Program (NTP) Status Known Human Carcinogens.
SECTION12: ECOLOGICALINFORMATION
Toxicity Not classified
13os:7s-sftf:
:.it:i11i:ll1ttl'ioxiaef
LCS0 Fish 1 1070 mg/I (Exposure time: 96 h - Species: Cyprinus carpio [static])
Persistence and Degradability Not available
·••Calclun'I
o,tide{1305~78-8)•
BCFfish 1
Mobility in Soil Not available
Other Adverse Effects Not available
SECTION13: DISPOSALCONSIDERATIONS
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, state, national, provincial,
territorial and international regulations.
Additional Information: If discarded in its purchased form, this product would not be a hazardous waste either by listing or
characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a
material containing the product or derived from the product should be classified as a hazardous waste.
SECTION14: TRANSPORTINFORMATION
14.1 In Accordance with DOT Not regulated for transport
14.2 In Accordance with IMDG Not regulated for transport
14.3 In Accordance with IATA Not regulated for transport
14.4 In Accordance with TDG Not regulated for transport
SECTION15: REGULATORYINFORMATION
Listed on the United States TSCA (Toxic Substances Control Act) inventory
04/23/2015 EN (English US) 9/11
Page 147 of 516

Safety Data Sheet
Jersey - Right to Know Hazardous Substance List

nsylvania - RTK Ri ht to Know List
RTK- U.S. - Massachusetts - Right To Know List

RTK - U.S. - New Jersey - Right to Know Hazardous Substance List
RTK - U.S. - Penns lvania - RTK (Right to Know) List
Gwsu
...
RTK - U.S. - Pennsylvania - RTK (Right to Know) List
i'>caldum''oxide·'(il30~1S::sflllllf:lS,,
.tviagnesiLt~]g~f1ijMgO) 1t!'.•.{
(130948~lli'¼f.!f:!\i1!
1 1

iXliiwL,;;
ciua~;(l.4$~66:;7~;.c;.
·•:<p: ;:J::(;r{'.· 1

RTK- U.S. - Pennsylvania - RTK (Right to Know) List
rrosive Material
Listed on the Canadian DSL estic Sub

Listed on the Canadian Ingredient Disclosure List
Listed on the Canadian DSL (Domestic Substances List) inventory.

WHMIS Classification Class E - Corrosive Material
04/23/2015 EN {English US) 10/11
Page 148 of 516

Safety Data Sheet
Listed on the Canadian

iiu~~ {ltl~~7)1°0::c:
Listed on the Canadian DSL (Domestic Substances List) inventory.
WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)and the SDS
contains all of the information required by CPR.
SECTION16: OTHER INFORMATION, INCLUDING DATE OF PREPARATIONOR LASTREVISION
Revision date 04/23/2015
Other Information This document has been prepared in accordance with the SDSrequirements of the OSHA
Hazard Communication Standard 29 CFR1910.1200.
GHS Full Text Phrases:
Care. lA Carcinogenicity Category lA
Eye Dam. 1 Serious eye damage/eye irritation Category 1
Skin Corr. lC Skin corrosion/irritation Category lC
Skin lrrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOTSE 3 Specific target organ toxicity (single exposure) Category 3
H314 Causes severe skin burns and eye damage
H31S Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H33S May cause respiratory irritation
H3S0 May cause cancer
H372 Causes damage to organs through prolonged or repeated exposure
Party Responsible for the Preparation of This Document
Lafarge North America Inc.
+l 773-372-1000 (9am to 5pm CST)
An electronic version of this SDS is available at: www.Jafarge-na.com under the Sustainability and Products sections. Please direct any
inquiries regarding the content of this SDS to SDSinfo@Lafarge.com.
Lafarge North America Inc. {LNA}believes the information contained herein is accurate; however, LNA makes no guarantees with
respect to such accuracy and assumes no liability in connection with the use of the information contained herein which is not intended
to be and should not be construed as legal advice or as insuring compliance with any federal, state or local laws or regulations. Any
party using this product should review all such Jaws, rules, or regulations prior to use, including but not limited to US and Canada
Federal, Provincial and State regulations.
NO WARRANTY IS MADE, EXPRESSOR IMPLIED,OF MERCHANTABILITY,FITNESSFORA PARTICULARPURPOSE,OR OTHERWISE.
North America GHS US 2012 & WHMIS
04/23/2015 EN (English US) 11/11
Page 149 of 516

Page 150 of 516
CEMENT & CONCRETE PRODUCTS""
C 1: Portland Cement Based Concrete Products

SAFETY DATA SHEET
(Complies with OSHA 29 CFR 1910.1200)
SECTION I: PRODUCT IDENTIFICATION
The QUIKRETE® Companies Emergency Telephone Number

5 Concourse Parkway, Suite 1900 INFOTRAC (800) 535-5053
Atlanta, GA 30328 Information Telephone Number
(800) 282-5828
SOS C1
Revision: Feb-18
QUIKRETE® Product Name Item #(s)

Fence Post Mix 1005
Fiber-Reinforced Concrete Mix 1006
Crack Resistant Concrete Mix 1006-80
Pro-Finish Crack Resistant Concrete Mix 1006-68
QUIKRETE 5000 Concrete Mix 1007
QUIKRETE 6000 Concrete Mix 1007
Pro-Finish QUIKRETE 5000 1007-85
Lightweight Concrete Mix 1008
Basic Concrete Mix 1015
Maximum Yield Concrete Mix 1100-80
Concrete Mix 1101-10, -20, -40, -60, -80, -90
Green Concrete Mix 1101-63, -73
B-Crete 1101-81
Red-E-Crete Concrete mix 1101-91, -87; 1141-62, -63, -92, -93, Bulk NR810035
Countertop Mix 1106-80
Form & Pour Concrete Mix 1120-80/NR810065
Form & Pour Concrete Mix MS 1120-80/NR810065
All-Star Concrete Mix 1121
Rip Rap 1129
Rip Rap Scrim 1134-80
Handicrete Concrete Mix 1141-59, -60, -80
RiteM ix Concrete 1171-60
Fiber Reinforced Deck Mix 1251-80, -81
All-Star Crack Resistant Concrete Mix 1470-03
All-Star 5000 Concrete Mix 1470-01
FlowCrete 5000 (Mix 801) 8080026/NR80026
Mix 801 Concrete Mix NR81001
Product Use: Portland cement-based, aggregated products for general construction
SDS Cl QUIKRETE Companies, LLC 2/7/2018
Page 1 of 10
Page 151 of 516

CEMEIVT & CONCRETE PRODUCTS""'
See most current revision of this document atwww.QUIKRETE.com.
SECTION II - HAZARD IDENTIFICATION
Hazard-determining components of labeling: Silica, Portland cement

2.1 Classification of the substance or mixture
Carcinogen - Category 1A
Skin Corrosion - Category 1B
Eye Damage - Category 1
Skin Sensitization - Category 1B
Specific Target Organ Toxicity Repeat Exposure - Category 1
Specific Target Organ Toxicity: Single Exposure - Category 3
2.2a Signal word DANGER!
2.2b Hazard Statements

May cause cancer through chronic inhalation
Causes severe skin burns and serious eye damage
Causes damage to lungs through prolonged or repeated inhalation
Harmful if swallowed.
2.2c Pictograms
2.2d Precautionary statements

Wear impervious gloves, such as nitrile. Wear eye protection, and protective clothing.
Do not eat, drink or smoke when using this product.
Use only in a well-ventilated area. Wear a NIOSH approved respirator (mask) such as N95 in poorly
ventilated areas, when used for extended periods, when use is frequent, or when permissible
exposure limits may be exceeded.
Do not breathe dust.
If swallowed: Rinse mouth. Do NOT induce vomiting.

Page 2 of 10
Page 152 of 516

DATASHEET
GHSSAFETY
\ ' .,j
If inhaled: Remove person to fresh air and keep comfortable for breathing.
easy to do. Continue rinsing.
If on skin (or hair): Remove immediately all contaminated clothing and wash before re-use. Rinse
skin or hair with water.
If significant skin irritation or rash occurs: get medical advice or attention.
Immediately seek medical advice or attention if symptoms are significant or persist.
Store in a well-ventilated place. Keep container tightly closed.

Dispose of contents/containers in accordance with all regulations.
2.3 Additional Information

The Portland cement in this product can cause serious, potentially irreversible damage to skin, eye,
respiratory and digestive tracts due to chemical (caustic) burns, including third degree burns.
Burns from Portland cement may not cause immediate pain or discomfort. You cannot rely on pain
to alert you to cement burns. Portland cement can cause dermatitis or sensitization. Therefore
precautions must be taken to prevent all contact with Portland cement. Cement burns can become
worse even after contact has ended. If there is contact with this product, immediately remove all
product from body and thoroughly rinse with water. If you experience or suspect a cement burn or
inflammation you should immediately see a health care professional.
Skin burns and irritation may be caused by brief exposure, though often are caused by extended
exposure of 15 minutes, an hour, or longer. Interaction of Portland cement with water or sweat
releases a caustic solution which produces the burns or irritation. Any extended exposure should be
treated as though a burn has occurred until determined otherwise.
Skin contact with Portland cement can also cause inflammation of the skin, referred to as dermatitis.
Signs and symptoms of dermatitis can include itching, redness, swelling, blisters, scaling, and other
changes in the normal condition of the skin. Signs and symptoms of burns include the above and
whitening, yellowing, blackening, peeling or cracking of skin.
The Portland cement in this product may cause allergic contact dermatitis in sensitized individuals.
This overreaction of the immune system can lead to severe inflammation. Sensitization may result
from a single exposure to the low levels of Cr (VI) in Portland cement or repeated exposures over
months or years. Sensitization is long lasting and, after sensitization, even very small quantities can
trigger the dermatitis. Sensitization is uncommon. Individuals who experience skin problems,
including seemingly minor ones, are advised to seek medical attention.
2.3a HNOC - Hazards not otherwise classified: Not applicable

2.3b Unknown Acute Toxicity: None
Page 3 of 10
Page 153 of 516

SECTION 111-HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous Components CAS No. % by Weight
Sand, Silica, Quartz 14808-60-7 60-100*
Portland Cement 65997 15 1 10-30*
Fly Ash 68131-7 4-8 5-1 0*
*The concentrations ranges are provided due to batch-to-batch variability.

None of the constituents of this material are of unknown toxicity.
SECTION IV - FIRST AID MEASURES

4.1 Description of the first-aid measures
General information:
After inhalation: Remove person to fresh air. If breathing is difficult, administer oxygen. If not
breathing, give artificial respiration. In case of unconsciousness, place patient stably in side position
for transportation.
After skin contact: Wash skin with cool water and pH-neutral soap or a mild detergent. If
significant skin irritation or rash occurs: get medical advice or attention.
After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
After swallowing: Do not induce vomiting. If conscious, have the victim drink plenty of water and
call a physician immediately. Never give anything by mouth to an unconscious person.
4.2 Most important symptoms/effects, acute and delayed

Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or
repeated inhalation. This product contains crystalline silica. Prolonged or repeated inhalation of
respirable silica from this product can cause silicosis.
Skin contact: Skin burns and irritation may be caused by brief exposure, though often are caused
by extended exposure of 15 minutes, an hour, or longer.
Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess
blinking and tear production, with marked redness and swelling of the conjunctiva.
Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea
or vomiting.
4.3 Indication of immediate medical attention and special treatment needed:

SECTION V - FIRE FIGHTING MEASURES
5.1 Flammability of the Product: Non-flammable and non-combustible

5.2 Suitable extinguishing agents: Treat for surrounding material
5.3 Special hazards arising from the substance or mixture: None
Page 4 of 10
Page 154 of 516

DATASHEET
GHSSAFETY
j
5.3a Products of Combustion: None

5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of
shocks
SECTION VI -ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures: Wear personal
protective equipment (See section VIII). Keep unprotected persons away.
6.2 Methods and material for containment and cleaning up:

Do not allow to enter sewers/ surface or ground water. Dispose of unwanted materials and
containers properly in accordance with all regulations.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE
7.1 Handling
Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. DO NOT
BREATHE DUST. In dusty environments, the use of an OSHA, MSHA or NIOSH approved
respirator and tight fitting goggles is recommended. Wear appropriate PPE (See section 8).Do not
mix with other chemical products, except as indicated by the manufacturer. Do not get in eyes, on
skin or clothing. Good housekeeping is important to prevent accumulation of dust.
7.2 Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep out of the reach of children. Keep container
tightly closed and prevent exposure to humidity. Do not allow water to contact the product until time
of use to preserve product utility.
SECTION VIII - EXPOSURE CONTROL MEASURES/ PERSONAL PROTECTION

8.1 Components with limit values that require monitoring at the workplace:
Hazardous Components CAS No. PEL (OSHA) TLV (ACGIH)
mg/M 3
mg/M3
Silica Sand, crystalline 14808-60-7 0.1 0.025 (resp)
Portland Cement 65997-15-1 5 (resp) 15 (total) 10 (resp)
Fly Ash 68131-74-8 N/A N/A
8.2 Exposure Controls

Use ventilation adequate to keep exposures below recommended exposure limits.
Page 5 of 10
Page 155 of 516

8.3 General protective and hygienic measures

Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated
clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin.
8.3a Personal protective equipment

Protection of hands:
Wear gloves of adequate length to offer appropriate skin protection from splashes. Nitrile, Butyl and
PVC gloves have been found to offer adequate protection for incidental contact. You cannot rely on
pain to alert you to cement burns. Portland cement can cause dermatitis or sensitization.
Eye protection:
Wear approved eye protection (properly fitted dust- or splash-proof chemical safety glasses.
Wear a NIOSH approved respirator (mask) such as N95 in poorly ventilated areas, when used for
extended periods, when use is frequent, or when permissible exposure limits may be exceeded.
Respirators should be selected by and used under the direction of a trained health and safety
professional, following requirements found in OSHA's respirator standard (29 CFR 1910.134) and
ANSI's standard for respiratory protection (Z88.2).
SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS
General Information
Appearance Form: Granular Solid
Color: Gray to gray-brown colored
Odor: None
pH-value at 20°c (68 °F): 13 (10%)
Boiling point/Boiling range: Not applicable
Flash point: Not applicable
Auto igniting: Product is not self-igniting
Vapor pressure at 21 °C (70°F) Not available
Density at 25°C (77 °F): 2.6 to 3.15
Solubility in / Miscibility with

Water: Insoluble
voe content: o g/L voe
SECTION X- STABILITY AND REACTIVITY
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal storage conditions. Keep in dry storage.
Page 6 of 10
Page 156 of 516

DATASHEET
GHSSAFETY
...j
10.3 Possibility of hazardous reaction

10.4 Thermal decomposition/ conditions to be avoided
No decomposition if used according to specifications.
10.5 Incompatible materials
Contact of silica with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese
trioxide, or oxygen difluoride may cause fires
10.6 Hazardous Decomposition or By-products
Silica will dissolve in Hydrofluoric Acid and produce a corrosive gas - silicon tetrafluoride.
SECTION XI - TOXICOLOGICAL INFORMATION

11.1 Exposure Routes: Skin contact, skin adsorption, eye contact, inhalation, or ingestion.
11.2 Symptoms related to physical/chemical/toxicological characteristics:

Inhalation: May cause respiratory tract irritation. Causes damage to organs through
prolonged or repeated exposure. This product contains crystalline silica. Prolonged or
repeated inhalation of respirable silica from this product can cause silicosis.
Skin contact: Causes severe skin burns. Handling can cause dry skin, discomfort, irritation,
and dermatitis. May cause sensitization by skin contact. Product becomes extremely alkaline
when exposed to moisture, and can cause alkali burns and affect the mucous membranes.
Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain,
excess blinking and tear production, with marked redness and swelling of the conjunctiva.
Ingestion: Harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or
vomiting.
11.3 Delayed, immediate and chronic effects of short-term and long-term exposure
Short Term
Skin Corrosion/Irritation: Causes severe skin burns.
Serious Eye Damage/Irritation: Causes severe eye damage.
Respiratory Sensitization: Not available
Skin Sensitization: May cause an allergic skin reaction.
Specific Target Organ Toxicity-Single Exposure: (Category 3) May cause respiratory
irritation.
Aspiration Hazard: Not available
Long Term
Carcinogenicity: May cause cancer through chronic inhalation.
Germ Cell Mutagenicity: Not available
Reproductive Toxicity: Not available
Page 7 of 10
Page 157 of 516

CEMENT & CONCRETE PRODUCTS"'
Specific Target Organ Toxicity- Repeated Exposure: (Category 1) Causes damage to lungs
through prolonged/repeated exposure
Synergistic/Antagonistic Effects: Not available.
SECTION XII- ECOLOGICAL INFORMATION

12.1 Ecotoxicity
May cause long-term adverse effects to the aquatic environment. Do not allow undiluted product or
large quantities of it to reach ground water, water course or sewage system. Must not reach bodies
of water or drainage ditch undiluted or un-neutralized
12.2 Persistence and degradability

No further relevant information available.
12.3 Bioaccumulative potential:

12.4 Mobility in soil

12.5 Other Adverse Effects

SECTION XIII - DISPOSAL CONSIDERATIONS

13.1 Waste Disposal Method
The packaging and material may be land filled; however, material should be covered to minimize
generation of airborne dust. This product is not classified as a hazardous waste under the authority
of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance
with local, state and federal regulations.
13.2 Other disposal considerations

Uncleaned packaging
Recommendation: Disposal must be made in accordance with local, state and federal regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.
SECTION XIV-TRANSPORT INFORMATION

DOT (U.S.) TDG (Canada)
UN-Number Not Regulated Not Regulated
UN proper shipping name Not Regulated Not Regulated
Transport Hazard Class(es) Not Regulated Not Regulated
Packing Group (if applicable) Not Regulated Not Regulated
Page 8 of 10
Page 158 of 516

CEMENT & CONCRETE PRODUCTS-
14.1 Environmental hazards:

Not Available
14.2 Transport in bulk according to Annex II of Marpol 73/78 and the IBC Code
Not available
14.3 Special precautions for user

SECTION XV - OTHER REGULATORY INFORMATION

15.1 Safety, Health and Environmental Regulations/Legislations specific for the chemical
Canada
WHMIS Classification: Considered to be a hazardous material under the Hazardous
Products Act as defined by the Hazardous Products Regulations and subject to the
requirements of Health Canada's Workplace Hazardous Material Information (WHMIS). This
document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and
the HPR.
15.2 US Federal Information
SARA 302/311 /312/313 Components

No chemicals in this material are subject to the reporting requirements of SARA Title 111,
Section 302, 311, 312 or 313.
RCRA: Crystalline silica (quartz) is not classified as a hazardous waste under the Resource
Conservation and Recovery Act, or its regulations, 40 CFR §261 et seq.
CERCLA: Crystalline silica (quartz) is not classified as a hazardous substance under
regulations of the Comprehensive Environmental Response Compensation and Liability Act
(CERCLA), 40 CFR §302.
Emergency Planning and Community Right to Know Act (SARA Title Ill): Crystalline
silica (quartz) is not an extremely hazardous substance under Section 302 and is not a toxic
chemical subject to the requirements of Section 313.
FDA: Silica is included in the list of substances that may be included in coatings used in food
contact surfaces, 21 CFR §175.300(b)(3)(xxvi).
NTP: Respirable crystalline silica, primarily quartz dusts occurring in industrial and
occupational settings, is classified as Known to be a Human Carcinogen.
OSHA Carcinogen: Crystalline silica (quartz) is not listed.
Page 9 of 10
Page 159 of 516

CEMENT & CONCRETE PRODUCTS,...
15.3 State Right to Know Laws

California Prop. 65 Components
A\ WARNING: This product can expose you to chemicals including crystalline silica which
is known to the State of California to cause cancer and hexavalent chromium compounds
which are known to the State of California to cause birth defects or other reproductive harm.
For more information go to www.P65Warninqs.ca.qov.
California Inhalation Reference Exposure Level (REL): California established a chronic
REL of 3 µg for silica (crystalline, respirable). A chronic REL is an airborne level of a
substance at or below which no adverse health effects are anticipated in individuals
indefinitely exposed to the substance at that level.
Massachusetts Toxic Use Reduction Act: Silica, crystalline (respirable size, <10 microns)
is "toxic" for purposes of the Massachusetts Toxic Use Reduction Act.
15.4 Global Inventories

DSL All components of this product are on the Canadian DSL list.
TSCA No.: Crystalline silica (quartz) appears on the EPA TSCA inventory under the CAS No.
14808-60-7. All constituents are listed in the TSCA inventory.
SECTION XVI - OTHER INFORMATION

Last Updated: February 7, 2018
NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee
or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and
disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products.
Prepared by The QUIKRETE Companies, LLC
End of SDS
Page 10 of 10
Page 160 of 516

U.S. SILICA COMPANY
SAFETY DATA SHEET
11.IDENTIFICATION
Product identifier: Silica Sand or Ground Silica; crystalline silica (quartz)
Product Name/Trade Names:

Sand and Ground Silica Sand (sold under various names: ASTM TESTING SANDS • GLASS
SAND• FILPRO® · FLINT SILICA• DM-SERIES • F-SERIES • FOUNDRY SANDS· FI-SERIES
H-SERIES • L-SERIES • N-SERIES • NJ SERIES• OK-SERIES· P-SERIES • T-SERIES •
hydraulic fracturing sand, all sizes• frac sand, all sizes• MIN-U-SIL® Fine Ground Silica• MYSTIC
WHITE®• #1 DRY· #1 SPECIAL· PENN SAND®• PRO WHITE®· SILURIAN®· Q-ROK® •
SIL-CO-SIL® Ground Silica • MICROSIL® • SUPERSIL® • MASON SAND • GS SERIES • PERSPEC
• proppant, all sizes • SHALE FRAC® - SERIES • KOSSE WHITE® • OTT A WA WHITE® •
OPTIJUMP® • LIGHTHOUSE TM
Chemical Name or Synonym:

Crystalline Silica (Quartz), Sand, Silica Sand, Flint, Ground Silica, Fine Ground Silica, Silica Flour.
Recommended use of the chemical and restrictions on use: (non-exhaustive list): brick, ceramics, foundry
castings, glass, grout, hydraulic fracturing sand, frac sand, proppant, mortar, paint and coatings, silicate
chemistry, silicone rubber, thermoset plastics.
Manufacturer:
U.S. Silica Company Phone: 800-243-7500
8490 Progress Drive, Suite 300 Emergency Phone: 301-682-0600
Frederick, MD 21701 Fax: 301-682-0690
U.S.A.
I2. HAZARD(S) IDENTIFICATION
Classification:
Ph sical Health
Not Hazardous Carcinogen Category lA
ific Tar et Or · ·
DANGER
May cause cancer by inhalation. Prevention
Causes damage to lungs through prolonged or Obtain special instructions before use.
repeated exposure by inhalation. Do not handle until all safety precautions have
Response: been read and understood.
If exposed or concerned: Get medical advice. Do not breathe dust.
Disposal: Do not eat, drink or smoke when using this
Dispose of contents/containers in accordance with product.
local regulation Wear protective gloves and safety glasses or
goggles.
In case of inadequate ventilation wear respiratory
protection.
Page 161 of 516

U.S. SILICA COMPANY
Safety Data Sheet
Silica Sand or Ground Silica Page 2 of9
13.COMPOSITION I INFORMATION ON INGREDIENTS
nent CASNo. Percent

Crystalline Silica ( 14808-60-7 95-99.9
I4. FIRST-AID MEASURES
Inhalation: First aid is not generally required. If irritation develops from breathing dust, move the person from
the overexposure and seek medical attention if needed.
Skin contact: First aid is not required.
Eye contact: Wash immediately with plenty of water. Do not rub eyes. If irritation persists, seek medical
attention.
Ingestion: First aid is not required.
Most important symptoms/effects, acute and delayed: Particulates may cause abrasive eye injury. Inhalation
of dust may cause respiratory tract irritation. Symptoms of exposure may include cough, sore throat, nasal
congestion, sneezing, wheezing and shortness of breath. Prolonged inhalation ofrespirable crystalline
silica above certain concentrations may cause lung diseases, including silicosis and lung cancer.
Indication of immediate medical attention and special treatment, if necessary: Immediate medical
attention is not required.
1 s. FIRE-FIGHTING MEASURES
Suitable (and unsuitable) extinguishing media: Use extinguishing media appropriate for surrounding fire.
Specific hazards arising from the chemical: Product is not flammable, combustible or explosive.
Special protective equipment and precautions for fire-fighters: None required.
I6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures: Wear appropriate protective
clothing and respiratory protection (see Section 8). Avoid generating airborne dust during clean-up.
Environmental precautions: No specific precautions. Report releases to regulatory authorities if required by

local, state and federal regulations.
Methods and materials for containment and cleaning up: Avoid dry sweeping. Do not use compressed air
to clean spilled sand or ground silica. Use water spraying/flushing or ventilated or HEPA filtered vacuum
cleaning system, or wet before sweeping. Dispose of in closed containers.
I7. HANDLING AND STORAGE
Precautions for safe handling:

Avoid generating dust. Do not breathe dust. Do not rely on your sight to determine if dust is in the air.
Respirable crystalline silica dust may be in the air without a visible dust cloud. Use adequate exhaust
Page 162 of 516

U.S. SILICA COMPANY
Safety Data Sheet
ventilation and dust collection to reduce respirable crystalline silica dust levels to below the pennissible
exposure limit ("PEL"). Maintain and test ventilation and dust collection equipment. Use all available work
practices to control dust exposures, such as water sprays. Practice good housekeeping. Do not permit dust to
collect on walls, floors, sills, ledges, machinery, or equipment. Keep airborne dust concentrations below
permissible exposure limits.
Where necessary to reduce exposures below the PEL or other applicable limit (if lower than the PEL), wear a
respirator approved for silica containing dust when using, handling, storing or disposing of this product or bag.
See Section 8, for further information on respirators. Do not alter the respirator. Do not wear a tight-fitting
respirator with facial hair such as a beard or mustache that prevents a good face to face piece seal between the
respirator and face. Maintain, clean, and fit test respirators in accordance with applicable standards. Wash or
vacuum clothing that has become dusty.
Participate in training, exposure monitoring, and health surveillance programs to monitor any potential adverse
health effects that may be caused by breathing respirable crystalline silica. The OSHA Hazard Communication
Standard, 29 CPR Sections 1910.1200, 1915.1200, 1917.28, 1918.90, 1926.59 and 1928.21, and state and local
worker or community "right-to-know" laws and regulations should be strictly followed.
Conditions for safe storage, including any incompatibilities: Use dust collection to trap dust produced
during loading and unloading. Keep containers closed and store bags to avoid accidental tearing, breaking, or
bursting.
s. EXPOSURE
1 CONTROLS I PERSONAL PROTECTION
Exposuregm "deIines:
Component OSHA PEL ACGIHTLV NIOSHREL
10 mg/m3
Crystalline Silica (quartz) %SiO2 + 2 TWA 0.025 mg/m3 TWA 0.05 mg/m3 TWA
(respirable dust) (respirable dust) (respirable dust)
30mg/m3
%SiO 2 + 2 TWA
(total dust)
If crystalline silica (quartz) is heated to more than 870°C, quartz can change to a form of crystalline silica
known as tridymite; if crystalline silica (quartz) is heated to more than 1470°C, quartz can change to a fonn of
crystalline silica known as cristobalite. The OSHA PEL for crystalline silica as tridymite or cristobalite is one-
half of the OSHA PEL for crystalline silica (quartz).
Appropriate engineering controls: Use adequate general or local exhaust ventilation to maintain
concentrations in the workplace below the applicable exposure limits listed above.
Respiratory protection: If it is not possible to reduce airborne exposure levels to below the OSHA PEL or
other applicable limit with ventilation, use the table below to assist you in selecting respirators that will reduce
personal exposures to below the OSHA PEL. This table is part of the NIOSH Respirator Selection Logic, 2004,
Chapter III, Table 1, "Particulate Respirators". The full document can be found at
www.cdc.gov/niosh/npptl/topics/respirators; the user of this MSDS is directed to that site for information
concerning respirator selection and use. The assigned protection factor (APP) is the maximum anticipated level
Page 163 of 516

U.S. SILICA COMP ANY
Safety Data Sheet
of protection provided by each type of respirator worn in accordance with an adequate respiratory protection
program. For example, an APP of 10 means that the respirator should reduce the airborne concentration of a
particulate by a factor of 10, so that if the workplace concentration of a particulate was 150 ug/m3, then a
respirator with an APP of 10 should reduce the concentration of particulate to 15 ug/m3. In using chemical
cartridges, consideration must be given to selection of the correct cartridge for the chemical exposure and the
maximum use concentration for the cartridge. In additional a cartridge change-out schedule must be developed
based on the concentrations in the workplace.
Assigned Type of Respirator

1 (Use only NIOSH-certified respirators)
protection factor
10 Any air-purifying elastomeric half-mask respirator equipped with appropriate type of
particulate filter. 2
Appropriate filtering facepiece respirator. 2 ' 3
Any air-purifying full facepiece respirator equipped with appropriate type of particulate filter. 2
Any negative pressure (demand) supplied-air respirator equipped with a half-mask.
25 Any powered air-purifying respirator equipped with a hood or helmet and a high efficiency
(HEPA) filter.
Any continuous flow supplied-air respirator equipped with a hood or helmet.
50 Any air-purifying full facepiece respirator equipped with N-100, R-100, or P-100 filter(s).
Any powered air-purifying respirator equipped with a tight-fitting facepiece (half or full
facepiece) and a high-efficiency filter.
Any negative pressure (demand) supplied-air respirator equipped with a full facepiece.
Any continuous flow supplied-air respirator equipped with a tight-fitting facepiece (half or full
facepiece).
Any negative pressure (demand) self-contained respirator equinned with a full facepiece.
1,000 pressure-demand supplied-air respirator equipped with a half-mask.
1. The protection offered by a given respirator is contingent upon (1) the respirator user adhering to complete program
requirements (such as the ones required by OSHA in 29CFR1910.134), (2) the use ofNIOSH-certified respirators in their
approved configuration, and (3) individual fit testing to rule out those respirators that cannot achieve a good fit on
individual workers.
2. Appropriate means that the filter medium will provide protection against the particulate in question.
3. An APF of 10 can only be achieved if the respirator is qualitatively or quantitatively fit tested on individual workers.
Skin protection: Maintain good industrial hygiene. Protection recollllllended for workers suffering from
dermatitis or sensitive skin.
Eye protection: Safety glasses with side shields or goggles recollllllended if eye contact is anticipated.
Other: None known.
I9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance (physical state, color, etc.): White or tan sand: granular, crushed or ground to a powder.
Odor: None.
Odor threshold: Not determined
Va or ressure: Not a
Page 164 of 516

Safety Data Sheet
Partition coefficient: n-octanol/water: Not Auto-ignition temperature: Not detennined

applicable
Decomposition temperature: Not detennined Viscosity: Not applicable
Flammability (solid, 2as): Not applicable
110.
STABILITY AND REACTIVITY
Reactivity: Not reactive under normal conditions of use.

Chemical stability: Stable
Possibility of hazardous reactions: Contact with powerful oxidizing agents, such as fluorine, chlorine
trifluoride and oxygen difluoride, may cause fires.
Conditions to avoid: Avoid generation of dust in handling and use.
and
Incompatible materials: Powerful oxidizers such as fluorine, chlorine trifluoride, and oxygen difluoride
hydrofluoric acid.
Hazardous decomposition products: Silica will dissolve in hydrofluoric acid and produce a corrosive
gas, silicon tetrafluoride.
111.
TOXICOLOGICAL INFORMATION
Acute effects of exposure:

Inhalation: Inhalation of dust may cause respiratory tract irritation. Symptoms of exposure may include
cough, sore throat, nasal congestion, sneezing, wheezing and shortness of breath.
throat.
Ingestion: Ingestion in an unlikely route of exposure. If dust is swallowed, it may irritate the mouth and
Skin contact: No adverse effects are expected.
Eye contact: Particulates may cause abrasive injury.
Chronic effects: Prolonged inhalation of respirable crystalline silica may cause lung disease, silicosis, lung
cancer and other effects as indicated below.
The method of exposure that can lead to the adverse health effects described below is inhalation.
A. SILICOSIS
Silicosis can exist in several forms, chronic (or ordinary), accelerated, or acute:
to
Chronic or Ordinary Silicosis is the most common form of silicosis, and can occur after many years ( 10
20 or more) of prolonged repeated inhalation of relatively low levels of airborne respirable crystalline silica
dust. It is further defmed as either simple or complicated silicosis. Simple silicosis is characterized by lung
lesions (shown as radiographic opacities) less than 1 centimeter in diameter, primarily in the upper lung
zones. Often, simple silicosis is not associated with symptoms, detectable changes in lung function or disability.
Simple silicosis may be progressive and may develop into complicated silicosis or progressive massive fibrosis
greater
(PMF). Complicated silicosis or PMF is characterized by lung lesions (shown as radiographic opacities)
or PMF symptoms, if present, are shortness of breath and
than 1 centimeter in diameter. Complicated silicosis
cough. Complicated silicosis or PMF may be associated with decreased lung function and may be disabling.
result
Advanced complicated silicosis or PMF may lead to death. Advanced complicated silicosis or PMF can
in heart disease secondary to the lung disease (cor pumonale).
Accelerated Silicosis can occur with prolonged repeated inhalation of high concentrations of respirable
crystalline silica over a relatively short period; the lung lesions can appear within five (5) years of initial
exposure. Progression can be rapid. Accelerated silicosis is similar to chronic or ordinary silicosis, except
Page 165 of 516

Safety Data Sheet
that lung lesions appear earlier and progression is more rapid.
Acute Silicosis can occur after the repeated inhalation of very high concentrations of respirable crystalline
silica over a short time period, sometimes as short as a few months. The symptoms of acute silicosis
include progressive shortness of breath, fever, cough, weakness and weight loss. Acute silicosis is fatal.
B.CANCER
IARC - The International Agency for Research on Cancer ("IARC") concluded that "crystalline silica in the
form of quartz or cristobalite dust is carcinogenic to humans (Group I)". For further information on the
IARC evaluation, see IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Volume
l00C,"A Review of Human Carcinogens: Arsenic, Metals, Fibres and Dusts" (2011).
NTP classifies "Silica, Crystalline (respirable size)" as Known to be a human carcinogen.
C. AUTOIMMUNE DISEASES
Several studies have reported excess cases of several autoimmune disorders -- scleroderma, systemic lupus
erythematosus, rheumatoid arthritis -- among silica-exposed workers.
D. TUBERCULOSIS
Individuals with silicosis are at increased risk to develop pulmonary tuberculosis, if exposed to tuberculosis
bacteria. Individuals with chronic silicosis have a three-fold higher risk of contracting tuberculosis than similar
individuals without silicosis.
E. KIDNEY DISEASE
Several studies have reported excess cases of kidney diseases, including end stage renal disease, among silica-
exposed workers. For additional information on the subject, the following may be consulted: "Kidney Disease
and Silicosis", Nephron, Volume 85, pp. 14-19 (2000).
F. NON-MALIGNANT RESPIRATORY DISEASES

The reader is referred to Section 3 .5 of the NIOSH Special Hazard Review cited below for information
concerning the association between exposure to crystalline silica and chronic bronchitis, emphysema and
small airways disease. There are studies that disclose an association between dusts found in various mining
occupations and non-malignant respiratory diseases, particularly among smokers. It is unclear whether the
observed associations exist only with underlying silicosis, only among smokers, or result from exposure to
mineral dusts generally (independent of the presence or absence of crystalline silica, or the level of crystalline
silica in the dust).
Sources of information:
The NIOSH Hazard Review - Occupational, Effects of Occupational, Exposure to Respirable
Crystalline Silica published in April 2002 summarizes and discusses the medical and epidemiological
literature on the health risks and diseases associated with occupational exposures to respirable crystalline silica.
The NIOSH Hazard Review is available from NIOSH - Publications Dissemination, 4676 Columbia Parkway,
Cincinnati, OH 45226, or through the NIOSH web site, www.cdc.gov/niosh/topics/silica, then click on the link
"NIOSH Hazard Review: Health Effects of Occupational Exposure to Respirable Crystalline Silica".
For a more recent review of the health effects of respirable crystalline silica, the reader may consult Fishman 's
Pulmonmy Diseases and Disorders, Fourth Edition, Chapter 57. "Coal Workers' Lung Diseases and Silicosis".
Finally, the US Occupational Safety and Health Administration (OSHA) published a summary ofrespirable
crystalline silica health effects in connection with OSHA's Proposed Rule regarding occupational exposure to
Page 166 of 516

Safety Data Sheet
respirable crystalline silica. The summary was published in the September 12, 2013 Federal Register, which
can be found at www.federalregister.gov/articles/2013/09/12/2013-20997 /occupational-exposure-to-respirable-
crystalline-silica.
Numerical measures of toxicity:

Crystalline Silica (quartz): LD50 oral rat >22,500 mg/kg
I12. ECOLOGICAL INFORMATION
Ecotoxicity: Crystalline silica (quartz) is not known to be ecotoxic.

Persistence and degradability: Silica is not degradable.
Bioaccumulative potential: Silica is not bioaccumulative.
Mobility in soil: Silica is not mobile in soil.
Other adverse effects: No data available
j 13. DISPOSAL CONSIDERATIONS
Discard any product, residue, disposable container or liner in full compliance with national regulations.
j 14. TRANSPORT INFORMATION
UN number: None
UN proper shipping name: Not regulated
Transport hazard classes(es): None
Packing group, if applicable: None
Environmental hazards: None
Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not determined
Special precautions: None known.
I1s. REGULATORY INFORMATION
UNITED STATES {FEDERAL AND STATE)
TSCA Status: Crystalline silica (quartz) appears on the EPA TSCA inventory under the GAS No.
14808-60-7.
RCRA: This product is not classified as a hazardous waste under the Resource Conservation and Recovery Act,
or its regulations, 40 CFR §261 et seq.
CERCLA: Crystalline silica (quartz) is not classified as a hazardous substance under regulations
of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), 40
CFR§302.
Emergency Planning and Community Right to Know Act (SARA Title III): This product contains the following
chemicals subject to SARA 302 or SARA 313 reporting: None above the de minim us concentrations.
Clean Air Act: Crystalline silica (quartz) mined and processed by U.S. Silica Company is not
processed with or does not contain any Class I or Class II ozone depleting substances.
Page 167 of 516

Safety Data Sheet
California Proposition 65: Crystalline silica (airborne particles of respirable size) is classified as a substance
known to the State of California to be a carcinogen.
California fuhalation Reference Exposure Level (REL): California established a chronic non-cancer effect REL
of 3 µg for silica (crystalline, respirable ). A chronic REL is an airborne level of a substance at or below which
no non-cancer health effects are anticipated in individuals indefinitely exposed to the substance at that level.
Massachusetts Toxic Use Reduction Act: Silica, crystalline (respirable size, <10 microns) is
"toxic" for purposes of the Massachusetts Toxic Use Reduction Act.
Pennsylvania Worker and Community Right to Know Act: Quartz is a hazardous substance under
the Act, but it is not a special hazardous substance or an environmental hazardous substance.
Texas Commission on Environmental Quality: The Texas CEQ has established chronic and acute Reference
Values and short term and long term Effects Screening Levels for crystalline silica (quartz). The information
can be accessed through www.tceq.texas.gov.
CANADA
Domestic Substances List: U. S. Silica Company products, as naturally occurring substances, are
on the Canadian DSL.
WHMIS Classification: D2A
OTHER NATIONAL INVENTORIES
Australian Inventory of Chemical Substances (AICS): All of the components of this product are
listed on the AICS inventory or exempt from notification requirements.
China: Silica is listed on the IECSC inventory or exempt from notification requirements.
Japan Ministry of International Trade and Industry (MITD: All of the components of this product
are existing chemical substances as defined in the Chemical Substance Control Law Registry
Number 1-548.
Korea Existing Chemicals Inventory (KECI) (set up under the Toxic Chemical Control Law):
Listed on the ECL with registry number 9212-5667.
New Zealand: Silica is listed on the HSNO inventory or exempt from notification requirements.
Philippines Inventory of Chemicals and Chemical Substances (PICCS): Listed for PICCS.
Taiwan: Silica is listed on the CSNN inventory or exempt from notification requirements.
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U.S. SILICA COMPANY
Safety Data Sheet
j 16. OTHER INFORMATION
Date of preparation/revision: February 10, 2015
Hazardous Material Information System (HMIS):

Health*
Flammability 0
Physical Hazard 0
Protective Equipment E
* For further information on health effects, see Sections 2, 8 and 11 of this MSDS.
National Fire Protection Association (NFPA):

Health 0
Flammability 0
Instability 0
Web Sites with Information about Effects of Crystalline Silica Exposure:
The U. S. Silica Company web site will provide updated links to OSHA and NIOSH web sites addressing
crystalline silica issues: www.ussilica.com, click on "Info Center", then click on "Health & Safety".
The U.S. National Institute for Occupational Safety and Health (NIOSH) and Occupational Safety and Health
Administration (OSHA) maintain sites with information about crystalline silica and its potential health effects.
For NIOSH, http://www.cdc.gov/niosh/topics/silica; for OSHA,
http://www. osha. gov/ dsg/topics/ silicacrystalline/index.
The IARC Monograph that includes crystalline silica, Volume 100C, can be accessed in PDF form
at the IARC web site, http://monographs.iarc.fr/ENG/Monographs/PDFs/index.php.
U. S. Silica Company Disclaimer

The information and recommendations contained herein are based upon data believed to be up to-
date and correct. However, no guarantee or warranty of any kind, express or implied, is made with
respect to the information contained herein. We accept no responsibility and disclaim all liability for any
harmful effects that may be caused by purchase, resale, use or exposure to our silica. Customers and
users of silica must comply with all applicable health and safety laws, regulations, and orders. In
particular, they are under an obligation to carry out a risk assessment for the particular work places and
to take adequate risk management measures in accordance with the national implementation legislation
of EU Directives 89/391 and 98/24.
Page 169 of 516

Page 170 of 516
SAFETY DATA SHEET
DOWSILTM 888 Silicone Joint Sealant
Version Revision Date: SDS Number: Date of last issue: 04/28/2017

6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014
SECTION 1. IDENTIFICATION
Product name DOWS ILTM 888 Silicone Joint Sealant
Product code 04104518
Manufacturer or supplier's details

Company Identification THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND Ml 48674-0000
UNITED STATES
Telephone 800-258-2436
24-Hour Emergency Contact Chemtrec +1 800-424-9300
Local Emergency Number 800-424-9300
E-mail address SDSQuestion@dow.com

Recommended use of the chemical and restrictions on use
Recommended use Construction materials and additives
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200

Eye irritation Category 2A
Reproductive toxicity Category 2
GHS label elements

Hazard pictograms
Signal Word Warning
Hazard Statements H319 Causes serious eye irritation.

H361fd Suspected of damaging fertility. Suspected of damaging
the unborn child.
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
1./25
Page 171 of 516
SAFETY DATA SHEET
DOWSIL TM 888 Silicone Joint Sealant
Version Revision Date: SOS Number: Date of last issue: 04/28/2017

6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/ Mixture Mixture
Chemical nature Silicone

Sealant
Hazardous ingredients
Chemical name. !I:.. ' 1:>-
,--
.,..,..:
_:_'crlC",·
,-,~, c_, _
,,,: CA&No. ./' .· :--;~
Concentratiori(%'WJw:Jli ' I
Limestone 1317-65-3 >= 46 - <= 57
Methylvinyl bis(N-ethylacetamido )silane 87855-59-2 >= 0.8 - <= 3
Dimethyl, methylhydrogen siloxane, dehy- 68952-53-4 >= 0.9 - <= 2.2
drogenated, reaction with hydroxydiethyla-
mine
Maonesium carbonate 546-93-0 >= 0.9 - <= 1.2
Quartz 14808-60-7 >= 0.33 - <= 0.41
Titanium dioxide 13463-67-7 >= 0.26 - <= 0.35
N-ethylacetamide 625-50-3 >= 0.1 - <= 0.4
Octamethylcyclotetrasiloxane 556-67-2 >= 0.19- <= 0.26
Impurities in methylvinylbis(N- Not Assigned >= 0.05 - <= 0.2
ethylacetamido )silane
SECTION 4. FIRST AID MEASURES
General advice In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
If inhaled If inhaled, remove to fresh air.

Get medical attention.
In case of skin contact In case of contact, immediately flush skin with plenty of water.
2125
Page 172 of 516
SAFETY DATA SHEET

Remove contaminated clothing and shoes.

Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
If swallowed If swallowed, DO NOT induce vomiting.

Rinse mouth thoroughly with water.
Most important symptoms Causes serious eye irritation.

and effects, both acute and Suspected of damaging fertility. Suspected of damaging the
delayed unborn child.
Protection of first-aiders First Aid responders should pay attention to self-protection,

and use the recommended personal protective equipment
when the potential for exposure exists.
Notes to physician Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Water spray

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing None known.

media
Specific hazards during fire Exposure to combustion products may be a hazard to health.
ighting
Hazardous combustion prod- Carbon oxides

ucts Metal oxides
Silicon oxides
Formaldehyde
Nitrogen oxides (NOx)
Specific extinguishing meth- Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.
3/25
Page 173 of 516
SAFETY DATA SHEET
DOWSIL rM 888 Silicone Joint Sealant

SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- Use personal protective equipment.

tive equipment and emer- Follow safe handling advice and personal protective
gency procedures equipment recommendations.
Environmental precautions Discharge into the environment must be avoided.

Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for Soak up with inert absorbent material.

containment and cleaning up For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SOS provide information regarding
certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures See Engineering measures under EXPOSURE

CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation Use only with adequate ventilation.
dvice on safe handling Do not get on skin or clothing.

Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety
practice, based on the results of the workplace exposure
assessment
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage Keep in properly labeled containers.

Store in accordance with the particular national regulations.
Materials to avoid Do not store with the following product types:

Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Page 174 of 516

SAFETY DATA SHEET

(Form of ters /Permissible

exposure) concentration
Limestone 1317-65-3 TWA (total 15 mg/m 3 OSHA Z-1
dust)
TWA (respir- 5 mg/m 3 OSHA Z-1
able fraction)
TWA (Res- 5 mg/m 3 NIOSH REL
pirable) (Calcium carbo-
nate)
TWA (total) 10 mg/m 3 NIOSH REL
(Calcium carbo-
nate)
Magnesium carbonate 546-93-0 TWA (Res- 5 mg/m 3 NIOSH REL
pirable)
TWA (total) 10 mq/m 3 NIOSH REL
TWA (total 15 mg/m 3 OSHA Z-1
dust)
TWA (respir- 5 mg/m 3 OSHA Z-1
able fraction)
Quartz 14808-60-7 TWA (respir- 10 mg/m3 OSHA Z-3
able) I %SiO2+2
TWA (respir- 250 mppcf OSHAZ-3
able) I %SiO2+5
TWA (Res- 0.025 mg/m 3 ACGIH
pirable frac- (Silica)
tion)
TWA (Res- 0.05 mg/m 3 NIOSH REL
pirable dust) (Silica)
TWA (Res- 0.05 mg/m 3 OSHA Z-1
pirable dust)
Titanium dioxide 13463-67-7 TWA (total 15 mg/m 3 OSHA Z-1
dust)
TWA 10 mg/m 3 ACGIH
(Titanium dioxide)
Octamethylcyclotetrasiloxane 556-67-2 TWA 10 oom US WEEL
Hazardous components without workplace control parameters
Ingredients CAS-No.
Methylvinyl bis(N- 87855-59-2
ethylacetamido )silane
Dimethyl, methylhydrogen 68952-53-4
siloxane, dehydrogenated,
reaction with hydroxydiethyla-
mine
N-ethylacetamide 625-50-3
Impurities in methylvinylbis(N- Not Assigned
ethvlacetamido )silane
These substance(s) are inextricably bound in the product and therefore do not contribute
to a dust inhalation hazard.
Quartz
Titanium dioxide
5/25
Page 175 of 516
SAFETY DATA SHEET

Engineering measures Processing may form hazardous compounds (see section

10).
Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.

Respiratory protection General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Hand protection
Material Chemical-resistant gloves
Remarks Choose gloves to protect hands against chemicals depending

on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection Wear the following personal protective equipment:

Safety goggles
Skin and body protection Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
These precautions are for room temperature handling. Use at
elevated temperature or aerosol/spray applications may
require added precautions.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance paste
6125
Page 176 of 516
SAFETY DATA SHEET
DOWSIL ™ 888 Silicone Joint Sealant

Color gray
Odor Fishy
Odor Threshold No data available
pH Not applicable
Melting point/freezing point No data available
Initial boiling point and boiling Not applicable

range
Flash point 100 °C

Method: closed cup
Evaporation rate Not applicable
Flammability (solid, gas) Not classified as a flammability hazard
Self-ignition The substance or mixture is not classified as pyrophoric. The

substance or mixture is not classified as self heating.
Upper explosion limit/ Upper No data available

flammability limit
Lower explosion limit/ Lower No data available

flammability limit
Vapor pressure Not applicable
Relative vapor density No data available
Solubility(ies)
Water solubility No data available
Partition coefficient: n- No data available

octanol/water
Autoignition temperature No data available
Decomposition temperature No data available
Viscosity
Viscosity, dynamic Not applicable
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
7125
Page 177 of 516
SAFETY DATA SHEET

SECTION 10. STABILITY AND REACTIVITY
Reactivity Not classified as a reactivity hazard.
Chemical stability Stable under normal conditions.
Possibility of hazardous reac- Use at elevated temperatures may form highly hazardous
tions compounds.
Can react with strong oxidizing agents.
Hazardous decomposition products will be formed at elevated
temperatures.
Conditions to avoid None known.
Incompatible materials Oxidizing agents
Hazardous decomposition products

Thermal decomposition Formaldehyde
SECTION 11. TOXICOLOGICAL INFORMATION

Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Ingredients:
Limestone:
r
cute oral toxicity LD50 (Rat): > 2,000 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity
Methylvinyl bis(N-ethylacetamido)silane:
cute oral toxicity Acute toxicity estimate: 500 mg/kg
Method: Expert judgment
cute dermal toxicity LD50 (Rat): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: On basis of test data.
Magnesium carbonate:
lfAcute
oral toxicity LD50 (Rat): > 2,000 mg/kg
_. 8 I 25
Page 178 of 516
SAFETY DATA SHEET

Method: OECD Test Guideline 420

icity
Quartz:
Ircute oral toxicity LD50 (Rat): > 5,000 mg/kg
Titanium dioxide:
cute inhalation toxicity LC50 (Rat): > 6.82 mg/I

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity
N-ethylacetamide:
cute oral toxicity LD50 (Rat): 3,950 mg/kg
Remarks: Based on data from similar materials
cute inhalation toxicity LC0 (Rat): 2.19 mg/I

Exposure time: 8 h
Test atmosphere: vapor
Octamethylcyclotetrasiloxane:
icity
cute inhalation toxicity LC50 (Rat): 2975 ppm

Exposure time: 4 h
Test atmosphere: vapor
Assessment: The substance or mixture has no acute inhala-
tion toxicity
cute dermal toxicity LD50 (Rabbit): > 2.5 ml/kg

toxicity
Impurities in methylvinylbis(N-ethylacetamido)silane:
cute oral toxicity Acute toxicity estimate: 500 mg/kg
Method: Expert judgment
cute dermal toxicity LD50 (Rat): > 2,000 mg/kg

toxicity
9/25
Page 179 of 516
SAFETY DATA SHEET

II
Skin corrosion/irritation
Ingredients:
Species: Rabbit
Result: No skin irritation
Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction with hydroxydiethylamine:

Result: Skin irritation
IIRemarks: Based on data from similar materials
Method: EPISKIN Human Skin Model Test
IIResult: No skin irritation
Titanium dioxide:
Species: Rabbit
II
N-ethylacetamide:
Species: Rabbit
Species: Rabbit
Species: Rabbit
Serious eye damage/eye irritation

Causes serious eye irritation.
Ingredients:
Species: Rabbit
Result: Irreversible effects on the eye
IIRemarks: On basis of test data.
10 /25
Page 180 of 516
SAFETY DATA SHEET


Result: Irritation to eyes, reversing within 21 days
II
Species: Rabbit
Result: No eye irritation
Titanium dioxide:
Species: Rabbit
II
N-ethylacetam ide:
Species: Rabbit
Species: Rabbit
Impurities in methylvinylbis(N-ethylacetam ido )silane:

Species: Rabbit
Result: Irreversible effects on the eye
Skin sensitization
Respiratory sensitization
Ingredients:
ssessment: Does not cause skin sensitization.
Test Type: Buehler Test

Species: Guinea pig
Result: negative
Titanium dioxide:
T est Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
II
Species: Mouse
11/25
Page 181 of 516
SAFETY DATA SHEET

IIResult: negative
N-ethylacetamide:
Test Type: lntracutaneous test
Species: Guinea pig
Result: negative
Test Type: Maximization Test

Species: Guinea pig
Result: negative
Test Type: Buehler Test

Species: Guinea pig
Result: negative
Germ cell mutagenicity

Ingredients:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Test Type: Bacterial reverse mutation assay (AMES)

Result: negative
Genotoxicity in vitro Test Type: In vitro mammalian cell gene mutation test
Result: negative
Titanium dioxide:
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo Test Type: In vivo micronucleus test

Species: Mouse
12/25
Page 182 of 516
SAFETY DATA SHEET

II
N-ethylacetamide:
Result: negative

Result: negative
Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: lntraperitoneal injection
Result: negative
Result: negative
Test Type: Mutagenicity (in vitro mammalian cytogenetic test)

Result: negative
Test Type: Chromosome aberration test in vitro

Result: negative
Test Type: In vitro sister chromatid exchange assay in mam-

malian cells
Result: negative
Test Type: DNA damage and repair, unscheduled DNA syn-

thesis in mammalian cells (in vitro)
Result: negative
Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Rat
Application Route: inhalation (vapor)
Result: negative
Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Rat
Application Route: Ingestion
Result: negative
Germ cell mutagenicity - Animal testing did not show any mutagenic effects.
ssessment
13125.
Page 183 of 516
SAFETY DATA SHEET

Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Test Type: Bacterial reverse mutation assay (AMES)

Result: negative
Carcinogenicity
Ingredients:
Species: Mouse
pplication Route: Ingestion
Exposure time: 18 Months
Result: negative
Quartz:
Species: Humans
pplication Route: inhalation (dusUmisUfume)
Result: positive
Remarks: IARC: (International Agency for Research on Cancer)
These substance(s) are inextricably bound in the product and therefore do not contribute to a
dust inhalation hazard.
Carcinogenicity - Assess- Positive evidence from human epidemiological studies (inhala-

ment tion)
Titanium dioxide:
Species: Rat
pplication Route: inhalation {dusUmisUfume)
Result: positive
Remarks: The mechanism or mode of action may not be relevant in humans.
These substance(s) are inextricably bound in the product and therefore do not contribute to a
dust inhalation hazard.
Carcinogenicity - Assess- Limited evidence of carcinogenicity in inhalation studies with

ment animals.
N-ethylacetamide:
Species: Mouse
pplication Route: inhalation (vapor)
Result: negative
14./25. ____
Page 184 of 516
SAFETY DATA SHEET

IARC Group 1: Carcinogenic to humans
Quartz 14808-60-7
Group 2B: Possibly carcinogenic to humans
Titanium dioxide 13463-67-7
OSHA No component of this product present at levels greater than or

equal to 0.1 % is on OSHA's list of regulated carcinogens.
NTP Known to be human carcinogen
Quartz 14808-60-7
Suspected of damaging fertility. Suspected of damaging the unborn child.
Ingredients:
Effects on fertility Species: Rat, male
Symptoms: Effects on fertility.
Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.
Effects on fertility Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Result: negative
Effects on fetal development Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Result: negative
N-ethylacetamide:
Effects on fetal development Test Type: Embryo-fetal development
Species: Mouse
Result: positive
15125
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SAFETY DATA SHEET

Reproductive toxicity - As- Some evidence of adverse effects on development, based on
II
sessment
animal experiments.
Effects on fertility Test Type: Two-generation reproduction toxicity study

Species: Rat, male and female
Effects on fetal development Test Type: Prenatal development toxicity study (teratogenicity)
Species: Rabbit
Symptoms: No effects on fetal development.
Impurities in methylvinylbis(N-ethylacetamido )silane:

Effects on fertility Species: Rat, male
STOT-single exposure
STOT-repeated exposure
Ingredients:
Quartz:
outes of exposure: inhalation (dust/mist/fume)
arget Organs: Lungs
ssessment: Shown to produce significant health effects in animals at concentrations of 0.02
mg/l/6h/d or less.
~
Routes of exposure: Ingestion
ssessment: No significant health effects observed in animals at concentrations of 100 mg/kg
bw or less.
Routes of exposure: inhalation (vapor)

ssessment: No significant health effects observed in animals at concentrations of 1 mg/1/6h/d or
less.

ssessment: No significant health effects observed in animals at concentrations of 200 mg/kg
16125
Page 186 of 516
SAFETY DATA SHEET

Ilbw or less.
Ingredients:
pecies: Rat
OAEL: 124 - 127 mg/kg
xposure time: 90 Days
~
Quartz:
Species: Humans
LOAEL: 0.053 mg/m 3
pplication Route: Inhalation
Remarks: These substance(s) are inextricably bound in the product and therefore do not
contribute to a dust inhalation hazard.
Titanium dioxide:
Species: Rat
NOAEL: 24,000 mg/kg
Exposure time: 28 Days
Species: Rat
NOAEL: 10 mg/m 3
pplication Route: inhalation {dusUmisUfume)
Exposure time: 2 y
Remarks: These substance(s) are inextricably bound in the product and therefore do not
contribute to a dust inhalation hazard.
N-ethylacetamide:
Species: Rabbit
NOAEL: 0.09 mg/I
LOAEL: 0.36 mg/I
Species: Rat
Species: Rat
Species: Rabbit
pplication Route: Skin contact
17/25
Page 187 of 516
SAFETY DATA SHEET

II
Aspiration toxicity
Further information
Ingredients:
Remarks: Results from a 2 year repeated vapor inhalation exposure study to rats of octamethyl-
cyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of female an i-
mals. This finding occurred at the highest exposure dose (700 ppm) only. Studies to date have
not demonstrated if these effects occur through pathways that are relevant to humans. Repeated
exposure in rats to D4 resulted in protoporphyrin accumulation in the liver. Without knowledge of
he specific mechanism leading to the protoporphyrin accumulation the relevance of this finding
o humans is unknown.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Limestone:
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 10,000 mg/I
Exposure time: 96 h
oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 1,000 mg/I
aquatic invertebrates Exposure time: 48 h
Toxicity to algae EC50 (Desmodesmus subspicatus (green algae)): > 200 mg/I
Exposure time: 72 h
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/I
Exposure time: 96 h
NOEC (Oncorhynchus mykiss (rainbow trout)): 50 mg/I

Exposure time: 96 h
LC50 (Danie rerio (zebra fish)):> 100 mg/I

Exposure time: 96 h
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 69 mg/I
Toxicity to algae EC50 (Pseudokirchneriella subcapitata (green algae)):> 100

mg/I
Exposure time: 72 h
18125
Page 188 of 516
SAFETY DATA SHEET

NOEC (Pseudokirchneriella subcapitata (green algae)): 100

mg/I
Exposure time: 72 h
Ecotoxicology Assessment
1rcute aquatic toxicity No toxicity at the limit of solubility.
Toxicity to fish LC50 (Pimephales promelas (fathead minnow)): 2,120 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 490 - 1,127 mg/I
Toxicity to algae ErC50 (Desmodesmus subspicatus (green algae)):> 100 mg/I

Exposure time: 72 h
Toxicity to microorganisms EC50: > 900 mg/I

Exposure time: 3 h
Quartz:
rcute aquatic toxicity No toxicity at the limit of solubility.
rhronic aquatic toxicity No toxicity at the limit of solubility.
Titanium dioxide:
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 100 mg/I
Toxicity to algae EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/I
Exposure time: 72 h
Toxicity to microorganisms EC50: > 1,000 mg/I

Exposure time: 3 h
N-ethylacetamide:
IIToxicity to fish LC50 (Leuciscus idus (Golden orfe)): 3,390 mg/I
19 / 25
Page 189 of 516
SAFETY DATA SHEET

Exposure time: 96 h
Method: DIN 38412
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 580 mg/I
Method: DIN 38412
Toxicity to algae EC50 (Desmodesmus subspicatus (green algae)):> 500 mg/I

Exposure time: 96 h
Toxicity to microorganisms EC10 (Pseudomonas putida): > 10,000 mg/I

Exposure time: 17 h
Method: DIN 38 412 Part 8
Toxicity to fish LC50 (Cyprinodon variegatus (sheepshead minnow)):>
0.0063 mg/I
Exposure time: 336 h
Remarks: No toxicity at the limit of solubility.
Toxicity to daphnia and other EC50 (Mysidopsis bahia (opossum shrimp)):> 0.0091 mg/I
Toxicity to algae ErC50 (Pseudokirchneriella subcapitata (green algae)):>

0.022 mg/I
Exposure time: 72 h
Toxicity to fish (Chronic toxic- NOEC (Oncorhynchus mykiss (rainbow trout)): >= 0.0044 mg/I
ity) Remarks: On basis of test data.
No toxicity at the limit of solubility.
Toxicity to daphnia and other NOEC (Daphnia magna (Water flea)): >= 0.0079 mg/I
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Remarks: On basis of test data.
No toxicity at the limit of solubility.
"Chronic aquatic toxicity May cause long lasting harmful effects to aquatic life.
Persistence and degradability
Ingredients:
Biodegradability Result: Not readily biodegradable.
II Biodegradation: 62.66 %
Method: OECD Test Guideline 301 B
Page 190 of 516

SAFETY DATA SHEET

II
II
N-ethylacetam ide:
Biodegradability Result: Inherently biodegradable.

Biodegradation: 100 %
Exposure time: 6 d
Biodegradation: 3.7 %
Exposure time: 28 d
Stability in water Degradation half life: 69.3 - 144 h (24.6 °C) pH: 7
Bioaccumulative potential
Ingredients:
Bioaccumulation Species: Pimephales promelas (fathead minnow)
Bioconcentration factor (BCF): 12,400
Partition coefficient: n- log Pow: 6.48 (25.1 °C)

octanol/water
Mobility in soil
No data available
Other adverse effects
Ingredients:
Results of PBT and vPvB Remarks: Octamethylcyclotetrasiloxane (D4) meets the cur-
assessment rent REACh Annex XIII criteria for PBT and vPvB. In Canada,
D4 has been assessed and deemed to meet the PiT criteria.
However, D4 does not behave similarly to known PBT /vPvB
substances. The weight of scientific evidence from field stud-
ies shows that D4 is not biomagnifying in aquatic and terres-
trial food webs. D4 in air will degrade by reaction with naturally
occurring hydroxyl radicals in the atmosphere. Any D4 in air
that does not degrade by reaction with hydroxyl radicals is not
expected to deposit from the air to water, to land, or to living
organisms.
21 /25
Page 191 of 516
SAFETY DATA SHEET

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Resource Conservation and This product has been evaluated for RCRA characteristics
Recovery Act (RCRA) and does not meet the criteria of hazardous waste if discarded
in its purchased form.
Waste from residues Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken to an approved waste

If not otherwise specified: Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
IMDG-Code
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49CFR
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity

c6mponerit:aR.O
·. <. :: '':',,,;' '·
1~i
,.lti§:. ,
100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
II
SARA 311/312 Hazards Serious eye damage or eye irritation
22)25.
Page 192 of 516
SAFETY DATA SHEET

SARA 313 This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title Ill, Section 313.
Pennsylvania Right To Know

Limestone 1317-65-3
Dimethyl siloxane, hydroxy-terminated 70131-67-8
Aluminum oxide 1344-28-1
Cobalt titanite green spinel 68186-85-6
C.I. Pigment Yellow 119 68187-51-9
Aluminium 7429-90-5
California Prop. 65
WARNING: This product can expose you to chemicals including Cobalt titanite green spinel,
which is/are known to the State of California to cause cancer. For more information go to
11www.P65Warnings.ca.gov.
California Permissible Exposure Limits for Chemical Contaminants
Limestone 1317-65-3
California Regulated Carcinogens
II Quartz 14808-60-7
The ingredients of this product are reported in the following inventories:
NZloC All ingredients listed or exempt.
TSCA All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.
AICS All ingredients listed or exempt.
ENCS/ISHL Consult your local Dow Chemical office.
REACH For purchases from Dow Chemical EU legal entities, all

ingredients are currently pre/registered or exempt under
REACH. Please refer to section 1 for recommended uses. For
purchases from non-EU Dow Chemical legal entities with the
intention to export into EEA please contact your DC
representative/local office.
IECSC One or more components of this product may not be listed on

the IECSC inventory, but this component(s) is (are) registered
with volume limitation under Dow Chemical entity in China.
Consult your local Dow Chemical office.
PICCS Consult your local Dow Chemical office.
DSL All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).
TCSI All ingredients listed or exempt.
23125
Page 193 of 516
SAFETY DATA SHEET

SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS®IV:
Flammability
£
ai
Q)
I
HMIS® ratings are based on a 0-4 rating

scale, with O representing minimal ha-
zards or risks, and 4 representing signifi-
Special hazard.
cant hazards or risks. The "*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.
Full text of other abbreviations

ACGIH USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL USA. NIOSH Recommended Exposure Limits
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
OSHA Z-3 USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
ACGIH /TWA 8-hour, time-weighted average
NIOSH REL/ TWA Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
OSHA Z-1 /TWA 8-hour time weighted average
OSHA Z-3 / TWA 8-hour time weighted average
US WEEL/TWA Time weighted average
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with xo/oresponse; EHS - Extremely Ha-
zardous Substance; ELx - Loading rate associated with xo/oresponse; EmS - Emergency Sche-
dule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated
with xo/ogrowth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System;
IARC - International Agency for Research on Cancer; IATA - International Air Transport Associa-
tion; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous
Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Avia-
tion Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - Interna-
tional Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Ko-
Page 194 of 516

SAFETY DATA SHEET
DOWSILTM 888 Silicone Joint Sealant

rea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50
- Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Conven-
tion for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration;
n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Ob-
served (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR -
No Observable Effect Loading Rate; NTP - National Toxicology Program; NZloC - New Zealand
Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development;
OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative
and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances;
(Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Re-
covery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RO -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SOS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative
Sources of key data used to Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/
Revision Date 10/20/2017
Items where changes have been made to the previous version are highlighted in the body of this
document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SOS and may not be valid when the
SOS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SDS material in the user's end product, if applicable.
US/ Z8
25/25
Page 195 of 516
Page 196 of 516
SPEC MIX, Inc.

1230 Eagan Industrial Rd. Ste 160
Eagan, MN 55121
Emergency Telephone Number (800) 535-5053

Information Telephone Number (888) 773-2649
Revised: Apr-17
SDSSM1
Spec Mix® Product Name Item #(s)
a. Masonry Cement & Sand Mortar (MC-01)
b. Masonry Cement & Sand Mortar - Type M (MC-02)
c. Masonry Cement & Sand Mortar - Type S (MC-03)
d. Masonry Cement & Sand Mortar - Type N (MC-04)
e. Masonry Cement & Sand Mortar - Color (MC-05)
f. Integral Water Repellent Mortar (IWR)-Type M (IW-01)
g. Integral Water Repellent Mortar (IWR) - Type S (IW-01)
h. Integral Water Repellent Mortar (IWR) - Type N (IW-01)
i. Integral Water Repellent Mortar (IWR) - Color (IW-05)
j. Set Accelerated Mortar - Type M (SA-01)
k. Set Accelerated Mortar - Type S (SA-01)
I. Set Accelerated Mortar - Type N (SA-01)
m. Set Accelerated Mortar - Color (SA-05)
n. Set Delayed Mortar - Type M (SD-01)
o. Set Delayed Mortar - Type S (SD-01)
p. Set Delayed Mortar - Type N (SD-01)
q. Set Delayed Mortar - Color (SD-05)
Product Use: Mortars for construction with block, brick, veneer stones, etc.

Skin Sensitization .,..Category 1B
Page 1 of 10
SPEC MIX, Inc. !123:0 Eagan b1dustrlal Bd. Suite um, Eagan, MN 55!!2:t T BlUU77:S.2H9 F 65!1.!4/5#.53:Hi
Page 197 of 516


2.2c Pictograms

Wear protective gloves, eye protection, and protective clothing.
Use in a well-ventilated area.

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
If on skin (or hair): Remove immediately all contaminated clothing and wash before re-use. Rinse skin
or hair with water.

2.3 Additional Information Precautions must be observed because burns occur with little
warning -- little heat is sensed.

2.3C WHMIS Classification
Class D2B - Skin/Eye Irritant
Page 2 of 10
SPEC MIX, Inc. 1230 Eagan Industrial lh:1. Suite HHI, Eagan, MN 55121 T 883.773.2&49 F 651.454.5315
Page 198 of 516

Class D2A - Chronic Toxic Effects - Carcinogen
Class E - Corrosive Material
2.3d Label Elements According To WHMIS
Hazard Symbols
Cf)
Signal Word
DANGER!
SECTION Ill - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous ComQonents CAS No. % by Weight
Portland Cement 65997 151 10-30*
Lime 01305-62-0 5-10%
Pulverized Limestone 01317-65-3 5-10%


for transportation.
After skin contact: Wash skin with cool water and pH-neutral soap or a mild detergent. If significant
skin irritation or rash occurs: get medical advice or attention.
After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
After swallowing: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a
physician immediately. Never give anything by mouth to an unconscious person.

Skin contact: Causes skin irritation. Handling can cause dry skin,. discomfort, irritation, and
dermatitis. May cause sensitization by skin contact. Product becomes extremely alkaline when
Page 3 of 10
Page 199 of 516

exposed to moisture, and can cause alkali burns and affect the mucous membranes. Precautions must
be observed because burns occur with little warning -- little heat is sensed.
Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva.
Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or
vomiting.


5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of shocks
SECTION VI - ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures: Wear personal protective
equipment (See section VIII). Keep unprotected persons away.

7 .1 Handling
BREATHE DUST. In dusty environments, the use of an OSHA, MSHA or NIOSH approved respirator
and tight fitting goggles is recommended. Wear appropriate PPE (See section 8). Do not mix with
other chemical products, except as indicated by the manufacturer. Do not get in eyes, on skin or
clothing. Good housekeeping is important to prevent accumulation of dust.
7.2 Storage
Page 4 of 10
SPEC M ll, Inc. 1230 Eagan Industrial Rd. Suite HHJ, t:avan, MN 55121 l' 888.773.2649 F 651.454.531!:i
Page 200 of 516

Further information about storage conditions: Keep out of the reach of children. Keep container tightly
closed and prevent exposure to humidity. Do not allow water to contact the product until time of use
to preserve product utility.
SECTION VIII - EXPOSURE CONTROL MEASURES/ PERSONAL PROTECTION

Hazardous Components CAS No. PEL (OSHA} TLV (ACGIH}
mg/M 3
mg/M 3
Silica Sand, crystalline 14808-60-7 0.1 0.025 (resp)
Portland Cement 65997-15-1 5 (resp) 15 (total} 10 (resp)
Lime 01305-62-0 5 5
Pulverized Limestone 01317-65-3 5 (resp} 15 (total} 10 (resp}



PVC gloves have been found to offer adequate protection for incidental contact. Precautions must be
observed because burns occur with little warning -- little heat is sensed.
Eye protection:
A NIOSH-approved dust mask or filtering face piece is recommended in poorly ventilated areas or
when permissible exposure limits may be exceeded. Respirators should be selected by and used
under the direction of a trained health and safety professional, following requirements found in OSHA's
respirator standard (29 CFR 1910.134) and ANSI's standard for respiratory protection (288.2).
General Information
Odor: None
pH-value at 20°c (68 °F}: 13 (10%}
Page 5 of 10
Page 201 of 516

Vapor pressure at 21°c (70°F) Not available
Density at 25°C (77 °F): 2.6 to 3.15
SolubiUty in / Miscibility with
Water: Insoluble
voe content: 0 g/LVOC
10.1 Reactivity
10.4 Thermal decomposition/ conditions to be avoided
SECTION XI - TOXICOLOGICAL INFORMATION

Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged
or repeated exposure. This product contains crystalline silica. Prolonged or repeated
inhalation of respirable silica from this product can cause silicosis.
Skin contact: Causes skin irritation. Handling can cause dry skin, discomfort, irritation, and
exposed to moisture, and can cause alkali burns and affect the mucous membranes.
vomiting.
Page 6 of 10
SPEC MIX, Inc. H!Bll Eag:an Industrial IHI. Suite 160, Eagan, MN 5!tt2'.f if 888.773.2549 f 651.:454.5315
Page 202 of 516

Short Term
Specific Target Organ Toxicity-Single Exposure: (Category 1) Causes respiratory irritation.
Long Term
Synergistic/ Antagonistic Effects: Not available.
SECTION XII - ECOLOGICAL INFORMATION
12.1 Ecotoxicity
large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of
water or drainage ditch undiluted or un-neutralized




SECTION XIII - DISPOSAL CONSIDERATIONS

generation of airborne dust. This product is not classified as a hazardous waste under the authority of
the RCRA {40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance with local,
state and federal regulations.
Page 7 of 10
SftEC MIX, lnll. Easan tn!llustrlal
:112.SD 1111.Suite urn, Eagan, lMI\I 55:112;1 T 888,717:3.H\49 F 65:11.454.53\15
Page 203 of 516

Uncleaned packaging recommendation: Disposal must be made in accordance with local, state and
federal regulations.
SECTION XIV - TRANSPORT INFORMATION

DOT (U.S.) TOG (Canada)

Not Available
Not available

SECTION XV- OTHER REGULATORY INFORMATION
Canada
WHMIS Classification: Considered to be a hazardous material under the Hazardous Products
Act as defined by the Controlled Products Regulations and subject to the requirements of
Health Canada's Workplace Hazardous Material Information (WHMIS). This document complies
with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR.

SARA 302/311/312/313 Components
No chemicals in this material are subject to the reporting requirements of SARA Title Ill, Section
302,311,312 or 313.
of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA}, 40
CFR §302.
Page 8 of 10
SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite HHI, Eagan, MN 55121 T BBB.773.2649 F 651.4154.5315
Page 204 of 516

Emergency Planning and Community Right to Know Act (SARA Title Ill): Crystalline silica
(quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical
subject to the requirements of Section 313.
NTP: Respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational
settings, is classified as Known to be a Human Carcinogen.

WARNING: This product contains chemicals known to the State of California to cause cancer
and birth defects or other reproductive harm.
California Inhalation Reference Exposure Level (REL): California established a chronic REL of 3
µg for silica (crystalline, respirable). A chronic REL is an airborne level of a substance at or
below which no adverse health effects are anticipated in individuals indefinitely exposed to the
substance at that level.

15.5 NFPA Ratings
_.. NFPA Rating Explanation Guide _..

HEALTHHAZARD HAZARD
FLAMMABILITY
3 ~ Can Ci!IUH lletil)U11.

or-p,{tr~n•nttnJ ...ry
2 i=cCari cause
1tttnl)<)~ty
incapacitation or
~sidual .injury
1 "'Can ~~e ~1snl1-e,mt
irritation
Cl"" Nohaurrd
AlK. =Afkalirw
ftCltl :si,A,clcll,c ..~.,..,.
4"'M""1-..•Jilodo.01t
.._.._
.....,...""'111$~-~~•'3
COf\ =Com:15m :;J""M•)'...-1>IOllkl:1'1thlgh.
t11fllPl'ffllUmor11hock
OX ,.OxklWng ~ .. ~,;,l-,,,m,.\<::wJ
~ .. ~IU;{jo;ll(:tlvc,
--·
ch#n91>-lrtnigh
w d :=1:r:.:~
mR~viol,e,nijyQ!"
~r
,.,~ .......w
't"'NICW' ... •lt)t-11ta.l:1£,o,~ffi!lh
.... l'flp&fllbll'l>:lifl'IJ!l-
wox. fl:~~1w1ywlth umu,411b:lc,
water and oxidi.zM
SPECIAL HAZARD INSTABILITYHAZARD

Last Updated: April 19, 2017
Page 9 of 10
Page 205 of 516

NOTE: The information and recommendations contained herein are based upon data believed to be
correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to
the information contained herein. We accept no responsibility and disclaim all liability for any harmful
effects which may be caused by exposure to silica contained in our products.
Prepared by SPEC MIX, Inc.
Phone(888}773-2649
www.SPECMIX.com
End ofSDS
Page 10 of 10
SPEC MIX, Inn. i23ll Eagan Industrial Rd. Suite HHI, Eagan, MN 5l.U21f cf 888.:'1?13.2649 F 651.454.5315
Page 206 of 516

SPEC MIX, Inc.

1230 Eagan Industrial Rd. Ste 160
Eagan, MN 55121
Emergency Telephone Number (800) 535-5053

Information Telephone Number (888) 773-2649
Revised: Apr-17
SDSSM4
Spec Mix®Product Name Item #(s)
a. Portland Lime & Sand Mortar (PL-01)
b. Portland Lime & Sand Mortar - Type M (PL-02)
c. Portland Lime & Sand Mortar - Type S (PL-03)
d. Portland Lime & Sand Mortar - Type N (PL-04)
e. Portland Lime & Sand Mortar - Color (PL-05)
f. Integral Water Repellent Mortar (IWR) - Type M (IW-01)
g. Integral Water Repellent Mortar (IWR) - Type S (IW-01)
h. Integral Water Repellent Mortar (IWR) - Type N (IW-01)
i. Integral Water Repellent Mortar (IWR) - Color (IW-05)
j. Tuckpoint Mortar (TP-01)
k. Tuckpoint Mortar - Color (TP-05)
I. Set Accelerated Mortar - Type M (SA-01)
m. Set Accelerated Mortar - Type S (SA-01)
n. Set Accelerated Mortar - Type N (SA-01)
o. Set Accelerated Mortar - Color (SA-05)
p. Set Delayed Mortar - Type M (SD-01)
q. Set Delayed Mortar - Type S (SD-01)
r. Set Delayed Mortar - Type N (SD-01)
s. Set Delayed Mortar - Color (SD-05)
t. Underground Utility Mortar (UG-01)
u. Underground Utility Mortar - Color (UG-05)
v. Adhered Veneer Mortar (VM-01)
w. Adhered Veneer Mortar - Color (VM-05)
x. Building Stone Mortar (SM-01)
y. Building Stone Mortar - Color (SM-05)
z. Setting Bed Mortar (SB-01)
aa. Setting Bed Mortar - Color (SB-05)
Product Use: Mortars for construction with block, brick, veneer stones, etc.
Page 1 of 10
SPEC MIX, Inc. 1230 Eagan lnilustriaJ 'Rd. Sui'.tie 1611, Eagan, :!VIN55121:1 if Bll\B.1'77'3.12649 F 11511.ill'Sl.5315
Page 207 of 516


Skin Sensitization - Category 1B

2.2c Pictograms

Wear protective gloves, eye protection, and protective clothing.
Use in a well-ventilated area.

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
If on skin (or hair): Remove immediately all contaminated clothing and wash before re-use. Rinse skin
or hair with water.
Page 2 of 10
SPEC MIX:, Inc. !1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 ii' BBB.:773.2649 IE fl51.i454.5315
Page 208 of 516

2.3 Additional Information Precautions must be observed because burns occur with little
warning -- little heat is sensed.

2.3C WHMIS Classification
Class D2B - Skin/Eye Irritant
Class D2A - Chronic Toxic Effects - Carcinogen
Class E - Corrosive Material
2.3d Label Elements According To WHMIS
Hazard Symbols
Cf)
Signal Word
DANGER!
SECTION Ill - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous Components CAS No. % by Weight
Portland Cement 65997 151 10-30*
Lime 01305-62-0 5-10*
May Contain
Inorganic Pigment Non-Hazardous 0-5


for transportation.
Page 3 of 10
Page 209 of 516

After skin contact: Wash skin with cool water and pH-neutral soap or a mild detergent. If significant
skin irritation or rash occurs: get medical advice or attention.
After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
After swallowing: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a
physician immediately. Never give anything by mouth to an unconscious person.

exposed to moisture, and can cause alkali burns and affect the mucous membranes. Precautions must
be observed because burns occur with little warning -- little heat is sensed.
Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva.
Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or
vomiting.


5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of shocks
SECTION VI -ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures: Wear personal protective
equipment (See section VIII). Keep unprotected persons away.

Page 4 of 10
C
SPEC MIX, Inc. 1230 Eagan lntlustrlal IHI. Suite 160, Eagan, MIii 55121 T BBl'L:773.2649 F 65:1.!454.53115
Page 210 of 516

7 .1 Handling
BREATHE DUST. In dusty environments, the use of an OSHA, MSHA or NIOSH approved respirator
and tight fitting goggles is recommended. Wear appropriate PPE (See section 8). Do not mix with
other chemical products, except as indicated by the manufacturer. Do not get in eyes, on skin or
clothing. Good housekeeping is important to prevent accumulation of dust.
7.2 Storage
Further information about storage conditions: Keep out of the reach of children. Keep container tightly
closed and prevent exposure to humidity. Do not allow water to contact the product until time of use
to preserve product utility.
SECTION VIII - EXPOSURE CONTROL MEASURES / PERSONAL PROTECTION

Hazardous Components CAS No. PEL (OSHA} TLV (ACGIH}
mg/M 3
mg/M 3
Silica Sand, crystalline 14808-60-7 0.1 0.025 (resp}
Portland Cement 65997-15-1 5 (resp} 15 (total} 10 (resp}
Lime 01305-62-0 5 5
Pulverized Limestone 01317-65-3 5 (resp} 15 (total} 10 (resp)



PVC gloves have been found to offer adequate protection for incidental contact. Precautions must be
observed because burns occur with little warning -- little heat is sensed.
Eye protection:
Page 5 of 10
Page 211 of 516

A NIOSH-approved dust mask or filtering face piece is recommended in poorly ventilated areas or
when permissible exposure limits may be exceeded. Respirators should be selected by and used
under the direction of a trained health and safety professional, following requirements found in OSHA's
respirator standard (29 CFR 1910.134) and ANSI's standard for respiratory protection (288.2).
General Information
Odor: None
pH-value at 20°C (68 °F): 13 (10%)
Vapor pressure at 21 °c (70°F) Not available
Density at 25°C (77 °F): 2.6 to 3.15
Solubility in / Miscibility with
Water: Insoluble
voe content: o g/L voe
10.1 Reactivity


10.4 Thermal decomposition / conditions to be avoided



SECTION XI -TOXICOLOGICAL INFORMATION
Page 6 of 10
Page 212 of 516


Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged
or repeated exposure. This product contains crystalline silica. Prolonged or repeated
inhalation of respirable silica from this product can cause silicosis.
exposed to moisture, and can cause alkali burns and affect the mucous membranes.
vomiting.
Short Term
Specific Target Organ Toxicity-Single Exposure: (Category 1) Causes respiratory irritation.
long Term
Synergistic/Antagonistic Effects: Not available.
SECTION XII - ECOLOGICAL INFORMATION
12.1 Ecotoxicity
large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of
water or drainage ditch undiluted or un-neutralized

Page 7 of 10
Page 213 of 516



SECTION XIII- DISPOSAL CONSIDERATIONS

generation of airborne dust. This product is not classified as a hazardous waste under the authority of
the RCRA (40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance with local,
state and federal regulations.

Uncleaned packaging recommendation: Disposal must be made in accordance with local, state and
federal regulations.
SECTION XIV-TRANSPORT INFORMATION

DOT (U.S.) TDG (Canada)

Not Available
Not available

SECTION XV- OTHER REGULATORY INFORMATION
Page 8 of 10
,,SPEC MIX:, Inc. H!30 Eagan fntlustrlal lh:I. Suite 1611, Eagan, MN 55Utf T 8BB.1i73.2649 fi 65cf.454i.53U
Page 214 of 516

Canada
WHMIS Classification: Considered to be a hazardous material under the Hazardous Products
Act as defined by the Controlled Products Regulations and subject to the requirements of
Health Canada's Workplace Hazardous Material Information (WHMIS). This document complies
with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR.

SARA 302/311 /312/313 Components
No chemicals in this material are subject to the reporting requirements of SARA Title Ill, Section
302,311,312 or 313.
of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), 40
CFR §302.
Emergency Planning and Community Right to Know Act (SARA Title Ill): Crystalline silica
(quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical
subject to the requirements of Section 313.
NTP: Respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational
settings, is classified as Known to be a Human Carcinogen.

WARNING: This product contains chemicals known to the State of California to cause cancer
and birth defects or other reproductive harm.
California Inhalation Reference Exposure Level (REL): California established a chronic REL of 3
1-'9for silica (crystalline, respirable). A chronic REL is an airborne level of a substance at or
below which no adverse health effects are anticipated in individuals indefinitely exposed to the
substance at that level.

15.5 NFPA Ratings
Page 9 of 10
Page 215 of 516

CtNFPA Rating Explanation Guide C,
HEALTHHAZARD FtA.MMABIUTYHAZARD
4- = Can be fe:thaJ
-3 ,:-.C~n Cllf.418 1iot!'riOU:1.
~ ~f!'l,sllfl#nl ~UfY
2= Can call-se
l!Pmf)Ot~ry
inc~pa~t:ation ~
ro:skiuaJloju,y
1 .. ,C-,itn c~~II;' ~~t1iH'ilA1nl
irribtion
011a:No-h.u:.ard
ALK =AlbUno 4"'M•t"'"'#'>~•t

ro(>~i'>'M 1:(>~.P#"'iJ.•N>:fli
N:iD t1111Aciclic caOO~r-11.1.U11>11e
COO.. c;;.o~•lvil- :;)1«1!,ll;q.,11,plod,i,, .. th~
OX 1mO.ddlzi1TS t,o;~urco.'•ho,r;k
, .... ~fffitd,cim~o;::!11
._.. "' ~lO~V(l. ('h3tl5'9'41thlu~
W "=1:r::~r
.. R:•~,;t,;;..,,.il;Jl•~cn
pt,lte,.._,.,..
1"'mp,,t,mvno-tir9o:
1..,No""11(ly:11.t,lll:Qk;.~
t .. mpo,'ldutco""""'"k•
11rOX:~~1vtdywatt tH:t"'tlll~
watr!f" Bfld. oxidb:in O.;,.Sl<NJ~
SPECIAL HAZARD INSTABIUTYHAZARD

Last Updated: April 19, 2017
NOTE: The information and recommendations contained herein are based upon data believed to be
correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to
the information contained herein. We accept no responsibility and disclaim all liability for any harmful
effects which may be caused by exposure to silica contained in our products.
Prepared by SPEC MIX, Inc.
Phone(888)773-2649
www.SPECMIX.com
End ofSDS
Page 10 of 10
'
.SPECMIX, Inn. 12.30 Eagan lntlustr!at Rd. Suite urn, Eagan, MN 55112.1 T BBB.778..2649 It 651.454.5315
Page 216 of 516

Safety Data Sheet SPE Solution to Service
Version 1 pg. 1
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
1.1 Trade Name (as labeled): SpecPoxy 3000 FS Part A

Synonyms: N/A
GAS No: Mixture
1.2 Product Use: Epoxy bonding gel
1.3 Company Name: SpecChem
Company Address: 1511 Baltimore Ave; Suite 600
Company Address Cont: Kansas City, MO 64108
Business Phone: (816) 968-5600
Website: www.specchemllc.com
1.4 Emergency Telephone Number: Chemtrec: (800) 424-9300
Date of Current Revision: April 30, 2015
Date of Last Revision: February 26, 2007
EMERGENCY OVERVIEW: This product is a white gelled liquid with a characteristic odor.
Health Hazards: May cause skin and eye irritation. Contact with skin may cause allergic reaction.
Flammability Hazards: This product is a non-flammable liquid.
Reactivity Hazards: None.
Environmental Hazards: The environmental effects of this product have not been investigated,
however release may cause long term adverse environmental effects.
US DOT Symbols: Not Regulated
EU and GHS Symbols:
Signal Word: Warning
2.1 EU Labeling and Classification:

This product meets the definition of a hazardous substance or preparation as defined by the
European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent
Directives.
EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC:
Index Number:
500-033-5 is listed in Annex I 603-07 4-00-8
215-279-6 is not listed in Annex I
Substances not listed either individually or in group entries must be self classified.
Components Contributing to Classification: Bisphenol A Diglycidyl Ether Resin, Calcium

Carbonate
2.2 Label Elements:
GHS Hazard Classifications: Skin Irritation Category 2
Skin Sensitization Category 1
Page 217 of 516

Safety Data Sheet
Version 1 pg.2
Eye Irritant Category 2

Chronic Aquatic Toxicity Category 2
Hazard Statements: H315 Causes skin irritation
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting
effects
Precautionary Statements: P280 Wear protective gloves/eye
protection/face protection.
P264 Wash thoroughly after handling.
P261 Avoid breathing
dust/fume/gas/mist/vapours/spray.
P272 Contaminated clothing should not be
allowed out of the workplace.
P273 Avoid release to the environment.
Response Statements: P302+P352 IF ON SKIN: Wash with plenty of
water.
P305+P351+P338 IF IN EYES: Rinse
cautiously with water for several minutes.
Remove contact lenses, if present and easy to
do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical
advice/attention.
P337 +P311 If eye irritation persists: Get
medical advice/attention.
P362+P364 Take off contaminated clothing and
wash it before reuse.
P391 Collect spillage.
Storage Statements: P405 Store locked up.
Disposal Statements: P501 Dispose of contents/container in accordance
with local/regional/national/international regulations.
2.3 Health Hazards or Risks From Exposure:
Symptoms of Overexposure by Route of Exposure:
The most significant routes of overexposure for this product are by contact with skin or eyes. The
symptoms of overexposure are described in the following paragraphs.
Acute:
Inhalation: May cause respiratory tract irritation. May cause headaches, drowsiness, or dizziness.
Skin Contact: May be irritating to skin. Contact with skin may cause allergic reaction.
Eye Contact: May cause irritation to the eyes.
Ingestion: May be harmful if swallowed. May cause nausea or diarrhea.
Chronic: Not known.
Target Organs:
Acute: Skin, Eyes
Chronic: Not known.
SECTION 3- COMPOSITION/ INFORMATION ON INGREDIENTS
Page 218 of 516

Safety Data Sheet SPEC Solution to Service
Version 1 pg.3
Hazardous Ingredients WT% CAS No. EINECS No. Hazard Classification

Calcium Carbonate 50-60% 1317-65-3 215-279-6 Skin lrrit. 3, Eye lrrit. 2B
Bisphenol A Diglycidyl Ether _ % _ _ Skin lrrit. 2, Skin Sens. 1, Eye lrrit. 2, Aquatic
40 45 25068 38 6 500-033-5
Resin Chronic 2
Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1 % for carcinogens, reproductive toxins, or
res irato sensitizers .
Note: All WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format.
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250:2000
4.1 Description of First Aid Measures:
Eye Contact: If product enters the eyes, flush with plenty of water or eye wash
solution for several minutes. Remove contacts if present and easy to
do. Seek medical attention if irritation persists.
Skin Contact: Wash skin thoroughly with soap and water after handling. Seek medical
attention if irritation develops and persists.
Inhalation: If breathing becomes difficult, remove victim to fresh air. If necessary,
use artificial respiration to support vital functions. Seek medical
attention.
Ingestion: If product is swallowed, call physician or poison center immediately. If
professional advice is not available, do not induce vomiting. Never
induce vomiting or give dilutents (milk or water) to someone who is
unconscious, having convulsions, or who cannot swallow. Seek medical
advice. Take a copy of the label and/or SOS with the victim to the health
professional.
Medical Conditions
Generally Aggravated
By Exposure: Pre-existing skin, respiratory system or eye problems may be
aggravated by prolonged contact.
4.2 Symptoms and Effects Both Acute and Delayed: Exposure to the eyes may cause irritation.
4.3 Recommendations to Physicians: Treat symptoms and eliminate overexposure.
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Fire Extinguishing Materials:
Use the following fire extinguishing materials: Water Spray: Yes

Foam: Yes
Halon: Yes
Carbon Dioxide: Yes
Dry Chemical: Yes
Other: Any "C" Class
Page 219 of 516

Version 1 pg.4
5.2 Unusual Fire and Explosion Hazards:

Irritating and toxic fumes may be produced at high temperatures. Use of water may result if
the formation of a toxic aqueous solution. Do not allow run-off from fire fighting to enter
drains or water courses.
Explosive Sensitivity to Mechanical Impact: No

Explosive Sensitivity to Static Discharge: No
5.3 Special Fire-Fighting Procedures:

• Incipient fire responders should wear eye protection.
• Structural firefighters must wear Self-Contained Breathing
• Apparatus (SCBA) and full protective equipment.
• Isolate materials not yet involved in the fire and protect personnel.
• Move containers from fire area if this can be done without risk; otherwise, cool with carefully
applied water spray.
• If possible, prevent run-off water from entering storm drains, bodies of water, or other
environmentally sensitive areas.
NFPA RATING SYSTEM HMIS RATING SYSTEM

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
Flammability
Health Reactivity PHYSICAL HAZARD {YELLOW) 0
PROTECTIVE EQUIPMENT
RESPIRATORY BODY
Other
SeeSect6 See Sect
8
For Routine lndusltial Use and HandlingA pllcations

Hazard Scale: O= Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe •=Chronic Hazard
SECTION 6-ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)
6.1 Personal Precautions, Protective Equipment and Emergency Procedures:

Use cautious judgment when cleaning up spill. Wear suitable protective clothing, gloves, and eye/face
protection.
6.2 Environmental Precautions:

Construct a dike to prevent spreading. Keep out of sewers, storm drains, surface waters, and soils.
6.3 Spill and Leak Response:
Page 220 of 516

Version 1 pg. 5
Small Spills:
• Collect material via broom or mop. Place in tightly sealed containers for proper disposal.
• Approach spill areas with caution.
• If liquid was introduced, create a dike or trench to contain material.
• Soak up with absorbent material such as clay, sand or other suitable non-reactive material.
Large Spills:
• Place in leak-proof containers. Seal tightly for proper disposal.
• Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal
regulations and those of Canada and its Provinces, those of Australia, Japan and EU
Member States (see Section 13, Disposal Considerations).
7 .1 Precautions for Safe Handling:

To prevent eye contact under the foreseeable conditions of use, wear appropriate safety eyewear.
When handling, do not eat, drink, or smoke. Wash thoroughly after handling. Do not handle or store
near heat, sparks, or flame.
7 .2 Storage and Handling Practices:
Keep away from incompatible materials. Keep container closed when not in use and store in well
ventilated area.
7 .3 Specific Uses:
Epoxy.
SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION

8.1 Exposure Parameters:
Ingredients CAS No. OSHA PEL NIOSH PEL

Bisphenol A Diglycidyl Ether Resin 25068-38-6 Not Listed Not Listed
TWA 5 mg/m3 (resp) Not ListedTWA 5 mg/m3 (resp
Calcium Carbonate 1317-65-3
TWA 15 m /m3 total TWA 10 m /m3 total
8.2 Exposure Controls:

Ventilation and Engineering Controls: Use with adequate ventilation to ensure
exposure levels are maintained below the limits
provided above.
The following information on appropriate Personal Protective Equipment is provided to assist
employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), or
standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye
protection}, and those of Japan. Please reference applicable regulations and standards for relevant
details.
Respiratory Protection: Not required for properly ventilated areas.

Maintain airborne contaminant concentrations
below guidelines listed above, if applicable. If
necessary, use only respiratory protection
Page 221 of 516

Safety Data Sheet
Version 1 pg.6
authorized in the U.S. Federal OSHA

Respiratory Protection Standard {29 CFR
1910.134), equivalent U.S. State standards,
Canadian CSA Standard Z94.4-93, the
European Standard EN 149, or EU member
states.
Eye Protection: Safety glasses or goggles are required.
If necessary, refer to U.S. OSHA 29 CFR
1910.133, Canadian Standards, and the
European Standard EN 166, Australian
Standards, or relevant Japanese Standards.
Hand Protection: Chemical resistant gloves are required to
prevent skin contact.
1910.138, the European Standard DIN EN 374,
the appropriate Standards of Canada, Australian
Body Protection: Use body protect appropriate to task being
performed.
If necessary, refer to appropriate Standards of
Canada, or appropriate standards of the EU,
Australian Standards, or relevant Japanese
Standards. If a hazard of injury to the feet exists
due to falling objects, rolling objects, where
objects may pierce the soles of the feet or where
employee's feet may be exposed to electrical
hazards, use foot protection, as described in
U.S. OSHA 29 CFR 1910.136.
9.1 Information on Basic Physical and Chemical Properties:

Appearance (Physical State and Color): White gelled liquid
Odor: Characteristic Odor
Odor Threshold: No data available
pH: No data available
Melting/Freezing Point: No data available
Boiling Point: 300°F ( 149.89°C)
Flash Point: 200°F (93°C)
Evaporation Rate: No data available
Flammability (Solid; Gas): Not applicable
Upper/Lower Flammability or Explosion Limits: No data available
Vapor Pressure (mm Hg@ 20°c (68° F): 11 mm Hg 100° F
Vapor Density: Heavier than air
Relative Density: No data available
Specific Gravity: >1.2
Solubility in Water: Not miscible
Page 222 of 516

Version 1 pg. 7
Weight per Gallon: No data available

Partition Coefficient (n-octanol/water): No data available
Auto-Ignition Temperature: No data available
Decomposition Temperature: No data available
Viscosity: No data available
9.2 Other Information: No data available
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity: This product is not reactive.

10.2 Stability: Stable under conditions of normal storage and use.
10.3 Possibility of Hazardous Reactions: Will not occur.
10.4 Conditions to Avoid: Heat, open flame or other sources of ignition.
10.5 Incompatible Substances: Strong oxidizing agents.
10.6 Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide and other decomposition
products can occur during combustion if not use according to specifications.
SECTION 11 -TOXICOLOGY INFORMATION

11.1 Information on Toxicological Effects:
Toxicit Data:
Bisphenol A Diglycidyl
25068-38-6 LOSOOral - Rat 13,600 mg/kg
Ether Resin
Suspected Cancer Agent: Ingredients within this product are not found on one or more of
the following lists: FEDERAL OSHA Z LIST, NTP, IARC, or
CAL/OSHA and therefore are not considered to be cancer-
causing agents by these agencies.
lrritancy: Skin, eye irritant.
Sensitization to the Product: This product is not expected to cause skin sensitization.
Germ Cell Mutagenicity: This product does not contain ingredients that are suspected
to be a germ cell mutagenic.
Reproductive Toxicity: No data available.
SECTION 12- ECOLOGICAL INFORMATION
12.1 Toxicity:
Bisphenol A Diglycidyl LC50 - Rainbow Trout
25068-38-6
Ether Resin EC50-AI ae
12.2 Persistence and Degradability: No specific data available on this product.

12.3 Bioaccumulative Potential: No specific data available on this product.
12.4 Mobility in Soil: No specific data available on this product.
12.5 Results of PBT and vPvB Assessment: No specific data available on this product.
12.6 Other Adverse Effects: No data available
12.7 Water Endangerment Class: At present, there are no ecotoxicological assessments
for this product.
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Safety Data Sheet
Version 1 pg.8
SECTION 13- DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods: Waste disposal must be in accordance with

appropriate U.S. Federal, State, and local
regulations, those of Australia, EU Member
States and Japan.
13.2 EU Waste Code: Not determined
SECTION 14 -TRANSPORTATION INFORMATION
14.1 U.S. Department of Transportation (DOT) Shipping Regulations:

This product is classified (per 49 CFR 172. 101) by the U.S. Department of Transportation, as follows.
UN Identification Number: Not Regulated
Proper Shipping Name: None
Hazard Class Number and Description: None
Packing Group: None
DOT Label(s) Required: None
North American Emergency Response
Guidebook Number: None
14.2 Environmental Hazards:
Marine Pollutant: The components of this product are designated by the
Department of Transportation to be Marine Pollutants
(49 CFR 172.101, Appendix B).
14.3 Special Precaution for User: None
14.4 International Air Transport Association
Shipping Information {IATA): This product is considered as dangerous goods.
14.5 International Maritime Organization
Shipping Information {IMO):
UN Identification Number: Not regulated
Proper Shipping Name: None
Hazard Class Number and Description: None
Packing Group: None
EMS-No: None
SECTION 15- REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations Specific for the Substance or Mixture:
United States Regulations:
U.S. SARA Reporting Requirements:
The components of this product are subject to the reporting requirements of Sections 302, 304, and 313 of
Title Ill of the Superfund Amendments and Reauthorization Act.
Page 224 of 516

Safety Data Sheet SPEC
Version 1 pg.9
U.S. SARA 311/312:

Acute Health: Yes; Chronic Health: No; Fire: No; Reactivity; No
U.S. CERCLA Reportable Quantity:
Not Applicable
U.S. TSCA Inventory Status:
The components of this product are listed on the TSCA Inventory or are exempted from listing.
Other U.S. Federal Regulations:
None known
California Safe Drinking Water and Toxic Enforcement Act (Proposition 66):
This product does not contain ingredients on the Proposition 65 Lists.
15.2 Canadian Regulations:

Canadian DSL/NDSL Inventory Status:
Components are DSL Listed, NDSL Listed and/or are exempt from listing
Other Canadian Regulations:
Not applicable
Canadian Environmental Protection Act (CEPA) Priorities Substances Lists:
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
(I)uct
Canadian WHMIS Classification and Symbols:
is Class D2A, Vecy Toxic Matecial, pe, WHMIS Contmlled Product Regulations.
15.3 European Economic Community Information:

This product meets the definition of a hazardous substance or preparation as defined by the European
Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. See Section
2 for Details.
Chemical Safety Assessment:
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
15.4 Australian Information for Product:
Components of this product are listed on the International Chemical Inventory list.
15.5 Japanese Information for Product:
Japanese Minister of International Trade and Industry {MITI) Status: The components of this product are not
listed as Class I specified Chemical Substances, Class II Specified Chemical Substances, or Designated
Chemical Substances by the Japanese MITI.
15.6 International Chemical Inventories:
Listing of the components on individual country Chemical Inventories is as follows:
Australian Inventory of Chemical Substances {AICS): Listed
Korean Existing Chemicals List (ECL): Listed
Japanese Existing National Inventory of Chemical Substances (ENCS): Listed
Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed
U.S. TSCA: Listed
SECTION 16 - OTHER INFORMATION
Prepared By: Chris Eigbrett (MSDS to GHS Compliance)
Page 225 of 516

Safety Data Sheet
Version 1 pg. 10
Date of Printing: April 30, 2015
The information contained herein is believed to be accurate but is not warranted to be so. Data and
calculations are based on information furnished by the manufacturer of the product and manufacturers of
the components of the product. Users are advised to confirm in advance of the need that information is
current, applicable and suited to the circumstances of use. This safety sheet cannot cover all possible
situations which the user may experience during processing. Each aspect of your operation should be
examined to determine if, or where, additional precautions may be necessary. All health and safety
information contained in this bulletin should be provided to your employees or customers. SpecChem
assumes no responsibility for injury to vendee or third party person proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, SpecChem
assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety
procedures are followed. Compliance with all applicable federal, state, and local laws and local regulations
remains the responsibility of the user.
END OF SDS SHEET
Page 226 of 516

Version 1 pg. 1
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
1.1 Trade Name (as labeled): SpecPoxy 3000 FS Part B

Synonyms: N/A
CAS No: Mixture
1.2 Product Use: Epoxy bonding adhesive
1.3 Company Name: SpecChem
Company Address: 1511 Baltimore Ave; Suite 600
Company Address Cont: Kansas City, MO 64108
Business Phone: (816) 968-5600
Website: www.specchemllc.com
1.4 Emergency Telephone Number: Chemtrec: (800) 424-9300
Date of Current Revision: April 30, 2015
Date of Last Revision: February 26, 2007
EMERGENCY OVERVIEW: This product is a black gelled liquid with a characteristic odor.
Health Hazards: May cause skin, eye and respiratory system irritation. Inhalation may cause
drowsiness or dizziness. Contact with skin may cause allergic reaction.
Flammability Hazards: This product is a non-flammable liquid.
Reactivity Hazards: None.
Environmental Hazards: The environmental effects of this product have not been investigated,
however release may cause long term adverse environmental effects.
US DOT Symbols:
EU and GHS Symbols:
Signal Word: Danger
2.1 EU Labeling and Classification:

This product meets the definition of a hazardous substance or preparation as defined by the
European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent
Directives.
EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC:
Index Number:
203-865-4 is listed in Annex I 612-058-00-X
205-411-0 is listed in Annex 1612-105-00-4
203-867-5 is listed in Annex I 603-194-00-0
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Safety Data Sheet SPECC Solution to Service
Version 1 pg.2

Substances not listed either individually or in group entries must be self classified.
Components Contributing to Classification: All Ingredients

2.2 Label Elements:
GHS Hazard Classifications: Skin Sensitization Category 1
Skin Corrosive Category 1B
Acute Toxicity Category 4 (Oral)
Acute Toxicity Category 4 (Dermal)
Reproductive Toxicity Category 1B
Chronic Aquatic Toxicity Category 2
Hazard Statements: H314 Causes severe skin burns and eye
damage
H302 Harmful if swallowed
H312 Harmful in contact with skin
H361 Suspected of damaging fertility or the
unborn child
H411 Very toxic to aquatic life with long lasting
effects
Precautionary Statements: P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions
have been read and understood.
P260 Do not breathe dusts or mists.
P272 Contaminated work clothing should not be
allowed out of the workplace.
P280 Wear protective gloves/eye
protection/face protection.
P264 Wash thoroughly after handling.
P261 Avoid breathing
dusUfume/gas/misUvapours/spray.
H270 Do not eat, drink or smoke when using
this product.
Response Statements: P301+P330+P331 IF SWALLOWED: Rinse
mouth. Do NOT induce vomiting
P303+P361+P353 IF ON SKIN (or hair): Take
off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse
cautiously with water for several minutes.
Remove contact lenses, if present and easy to
do. Continue rinsing.
P302+P352 IF ON SKIN: Wash with plenty of
water.
P321 Specific treatment (see supplemental first
aid instructions on this label).
Page 228 of 516

Version 1 pg.3
P332+P313 If skin irritation occurs: Get medical

advice/attention.
P363 Wash contaminated clothing before
reuse.
P304+P340 IF INHALED: Remove person to
fresh air and keep comfortable for breathing.
P330 Rinse mouth.
P308+P313 IF exposed or concerned: Get
medical advice/attention.
P310 Immediately call a POISON
CENTER/doctor if you feel unwell.
Storage Statements: P405 Store locked up.
Disposal Statements: P501 Dispose of contents/container in accordance
with local/regional/national/international regulations.
2.3 Health Hazards or Risks From Exposure:
Symptoms of Overexposure by Route of Exposure:
The most significant routes of overexposure for this product are by contact with skin or eyes. The
symptoms of overexposure are described in the following paragraphs.
Acute:
Inhalation: May cause respiratory tract irritation. May cause headaches, drowsiness, or dizziness.
Skin Contact: A single prolonged exposure may result in the absorption of harmful amounts. May cause
burns or redness. Contact with skin may cause allergic reaction.
Eye Contact: Corrosive material may cause irritation with possible burns and tissue damage.
Ingestion: Harmful if swallowed. May cause nausea and diarrhea.
Chronic: Repeated exposure may cause skin dryness or cracking.
Target Organs:
Acute: Skin, Eyes
Chronic: Skin.
SECTION 3- COMPOSITION/ INFORMATION ON INGREDIENTS
Hazardous Ingredients WT% CAS No. EINECS No. Hazard Classification

Calcium Carbonate 50-60% 1317-65-3 215-279-6 Skin lrrit. 3, Eye lrrit. 2B
Acute Tax. 4 (oral), Skin Corr, 1B, Reproductiv
4-Nonylphenol 10-15% 84852-15-3 284-325-5
T ox.2, A uatic Acute 1, A uatic Ch ran .1
4-tert-butylphenol 10-15% 98-54-4 202-679-0 Skin lrrit. 2, Eye Dam. 1, Repr. 2
2 ,2'-iminodiethylamine Acute Tax. 4 (Oral), Acute Tax. 4 (Dermal), Ski
3-5% 111-40-0 203-865-4
dieth lenetriamine Corr. 1B, Skin Sens. 1
Acute Tax. 4 (Oral), Acute Tax. 4 (Dermal), Ski
2-piperazin-1-ylethylamine 3-5% 140-31-8 205-411-0
Corr. 1B, Skin Sens. 1, A uatic Chronic 3
2-(2-am inoethylamino )ethanol
3-5% 111-41-1 203-867-5 Skin Corr. 1B, Skin Sens. 1, Repr. 1B
AEEA
Bis[(dimethylamino)methyl]phenol 1-3% 71074-89-0 275-162-0 Skin Corr, 1B
2,4,6-tris(dimethylaminomethyl)phenol 1-3% 90-72-2 202-013-9 Acute Tax. 4(Oral), Skin lrrit.2, Eye lrrit.2
Balanceof other ingredientsare non-hazardousor less than 1% in concentration(or 0.1% for carcinogens,reproductivetoxins, or respi
sensitizers .
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Safety Data Sheet
Version 1 pg.4
Note: All WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format.
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250:2000
4.1 Description of First Aid Measures:
Eye Contact: If product enters the eyes, flush with plenty of water or eye wash
solution for several minutes. Remove contacts if present and easy to
do. Seek medical attention if irritation persists.
Skin Contact: Wash skin thoroughly with soap and water after handling. Seek medical
attention if irritation develops and persists.
Inhalation: If breathing becomes difficult, remove victim to fresh air. If necessary,
use artificial respiration to support vital functions. Seek medical
attention.
Ingestion: If product is swallowed, call physician or poison center immediately. If
professional advice is not available, do not induce vomiting. Never
induce vomiting or give dilutents (milk or water) to someone who is
unconscious, having convulsions, or who cannot swallow. Seek medical
advice. Take a copy of the label and/or SOS with the victim to the health
professional.
Medical Conditions
Generally Aggravated
By Exposure: Pre-existing skin, respiratory system or eye problems may be
aggravated by prolonged contact.
4.2 Symptoms and Effects Both Acute and Delayed: Exposure to skin and eyes may cause burns
or redness.
4.3 Recommendations to Physicians: Treat symptoms and eliminate overexposure.
5.1 Fire Extinguishing Materials:
Use the following fire extinguishing materials: Water Spray: Yes

Foam: Yes
Halon: Yes
Carbon Dioxide: Yes
Dry Chemical: Yes
Other: Any "C" Class
5.2 Unusual Fire and Explosion Hazards:
Irritating and toxic fumes may be produced at high temperatures. Use of water may result if
the formation of a toxic aqueous solution. Do not allow run-off from fire fighting to enter
drains or water courses.
Page 230 of 516

Version 1 pg. 5
Explosive Sensitivity to Mechanical Impact: No

Explosive Sensitivity to Static Discharge: No
5.3 Special Fire-Fighting Procedures:

• Incipient fire responders should wear eye protection.
• Structural firefighters must wear Self-Contained Breathing
• Apparatus (SCBA) and full protective equipment.
• Isolate materials not yet involved in the fire and protect personnel.
• Move containers from fire area if this can be done without risk; otherwise, cool with carefully
applied water spray.
• If possible, prevent run-off water from entering storm drains, bodies of water, or other
environmentally sensitive areas.
NFPA RATING SYSTEM HMIS RATING SYSTEM

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
Flammability
Health Reacti PHYSICAL HAZARD (YELLOW) 0
PROTECTIVE EQUIPMENT
RESPIRATORY BODY
Other See Sect

See Sect 8
8
For Routine Industrial Use and Handling Applications

Hazard Scale: o = Minimum 1 = Sli9hl 2 = Moderate 3 = Serious 4 = Severe •=Chronic Hazard
SECTION 6-ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)
6.1 Personal Precautions, Protective Equipment and Emergency Procedures:

Use cautious judgment when cleaning up spill. Wear suitable protective clothing, gloves, and eye/face
protection.
6.2 Environmental Precautions:

Construct a dike to prevent spreading. Keep out of sewers, storm drains, surface waters, and soils.
6.3 Spill and Leak Response:
Small Spills:
• Collect material via broom or mop. Place in tightly sealed containers for proper disposal.
• Approach spill areas with caution.
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Safety Data Sheet
Version 1 pg.6
• If liquid was introduced, create a dike or trench to contain material.

• Soak up with absorbent material such as clay, sand or other suitable non-reactive material.
Large Spills:
• Place in leak-proof containers. Seal tightly for proper disposal.
• Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal
regulations and those of Canada and its Provinces, those of Australia, Japan and EU
Member States (see Section 13, Disposal Considerations).
7.1 Precautions for Safe Handling:

To prevent eye contact under the foreseeable conditions of use, wear appropriate safety eyewear.
When handling, do not eat, drink, or smoke. Wash thoroughly after handling. Do not handle or store
near heat, sparks, or flame.
7.2 Storage and Handling Practices:
Keep away from incompatible materials. Keep container closed when not in use and store in well
ventilated area.
7.3 Specific Uses:

Epoxy bonding gel.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Exposure Parameters:
Ingredients CAS No. OSHA PEL NIOSH PEL

Calcium Carbonate TWA 5 mg/m3 (resp) TWA 5 mg/m3 (resp)
1317-65-3
TWA 15 m /m3 total TWA 10 mg/m3 total
4-Nonylphenol 84852-15-3 Not Listed Not Listed
4-tert-butylphenol 98-54-4 Not Listed Not Listed
2,2'-iminodiethylamine
140-31-8 Not Listed Not Listed
diethylenetriamine
2-(2-aminoethylamino )ethanol
111-41-1 Not Listed Not Listed
AEEA
Bis[( dimethylamino )methyl]phenol 71074-89-0 Not Listed Not Listed
2 ,4,6-tris( dimethylaminomethyl)phenol 90-72-2 Not Listed Not Listed
8.2 Exposure Controls:

Ventilation and Engineering Controls: Use with adequate ventilation to ensure
exposure levels are maintained below the limits
provided above.
The following information on appropriate Personal Protective Equipment is provided to assist
employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), or
standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye
protection), and those of Japan. Please reference applicable regulations and standards for relevant
details.
Page 232 of 516

Version 1 pg. 7
Respiratory Protection: Not required for properly ventilated areas.

Maintain airborne contaminant concentrations
below guidelines listed above, if applicable. If
necessary, use only respiratory protection
authorized in the U.S. Federal OSHA
Respiratory Protection Standard (29 CFR
1910.134), equivalent U.S. State standards,
Canadian CSA Standard Z94.4-93, the
European Standard EN149, or EU member
states.
Eye Protection: Safety glasses or goggles are required.
1910.133, Canadian Standards, and the
European Standard EN166, Australian
Hand Protection: Chemical resistant gloves are required to
prevent skin contact.
1910.138, the European Standard DIN EN 37 4,
the appropriate Standards of Canada, Australian
Body Protection: Use body protect appropriate to task being
performed.
If necessary, refer to appropriate Standards of
Canada, or appropriate standards of the EU,
Australian Standards, or relevant Japanese
Standards. If a hazard of injury to the feet exists
due to falling objects, rolling objects, where
objects may pierce the soles of the feet or where
employee's feet may be exposed to electrical
hazards, use foot protection, as described in
U.S. OSHA29 CFR 1910.136.
9.1 Information on Basic Physical and Chemical Properties:

Appearance (Physical State and Color): White gelled liquid
Odor: Characteristic
Odor Threshold: No data available
pH: No data available
Melting/Freezing Point: No data available
Boiling Point: 300°F (148.9°C)
Flash Point: 200°F (93°C)
Evaporation Rate: No data available
Flammability (Solid; Gas): Not applicable
Upper/Lower Flammability or Explosion Limits: No data available
Page 233 of 516

Safety Data Sheet
Version 1 pg.8
Vapor Pressure (mm Hg @20°C (68° F): 11mm Hg 100° F

Vapor Density: No data available
Relative Density: No data available
Specific Gravity: 1.2
Solubility in Water: Not miscible
Weight per Gallon: No data available
Partition Coefficient (n-octanol/water): No data available
Auto-Ignition Temperature: No data available
Decomposition Temperature: No data available
Viscosity: No data available
9.2 Other Information: No data available
10.1 Reactivity: This product is not reactive.

10.2 Stability: Stable under conditions of normal storage and use.
10.3 Possibility of Hazardous Reactions: Will not occur.
10.4 Conditions to Avoid: Heat, open flame or other sources of ignition.
10.5 Incompatible Substances: Strong oxidizing agents.
10.6 Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide and other decomposition
products can occur during combustion if not use according to specifications.
SECTION 11 -TOXICOLOGY INFORMATION

11.1 Information on Toxicological Effects:
Toxicity Data:
4-Nonylphenol 84852-15-3 LD50 Oral-Rat 1,412 mg/kg
4-tert-butylphenol 98-54-4 LD50 Oral-Rat > 2,000 mg/kg
2,2'-iminodiethylamine LD50 Oral-Rat 0.3 mg/I- 4h
111-40-0
d iethylenetriam ine LD50 Dermal-Rabbit 1,090 mQ/kQ
LD50 Oral-Rat 2,097 mg/I- 4h
2-piperazin-1-ylethylamine 140-31-8
LD50 Dermal-Rabbit 866 mg/kg
Suspected Cancer Agent: Ingredients within this product are not found on one or more of
the following lists: FEDERAL OSHA Z LIST, NTP, IARC, or
CAL/OSHA and therefore are considered to be cancer-causing
agents by these agencies.
lrritancy: Skin, eye and respiratory irritant.
Sensitization to the Product: This product is not expected to cause skin sensitization.
Germ Cell Mutagenicity: This product does not contain ingredients that are suspected
to be a germ cell mutagenic.
Reproductive Toxicity: This product is expected to be a human reproductive toxicant.
SECTION 12- ECOLOGICAL INFORMATION
12.1 Toxicity:
Page 234 of 516

Version 1 pg.9
LC50 - Leoomis macrochirus 0.209 mq/I -96h

4-Nonylphenol 84852-15-3
EC50-Alqae 0.33 mq/I- 72h
LC50 - Fathead Minnow 5.14 mQ/I- 96h
4-tert-butylphenol 98-54-4
EC50 - Water flea 4.8 mg/I - 72h
2,2'-iminodiethylamine 1,014 mg/I- 96h
111-40-0 LC50-Guppy
diethylenetriamine
12.2 Persistence and Degradability: No specific data available on this product.

12.3 Bioaccumulative Potential: No specific data available on this product.
12.4 Mobility in Soil: No specific data available on this product.
12.5 Results of PBT and vPvB Assessment: No specific data available on this product.
12.6 Other Adverse Effects: No data available
12.7 Water Endangerment Class: At present, there are no ecotoxicological assessments
for this product.
13.1 Waste Treatment Methods: Waste disposal must be in accordance with

appropriate U.S. Federal, State, and local
regulations, those of Australia, EU Member
States and Japan.
13.2 EU Waste Code: Not determined
SECTION 14 -TRANSPORTATION INFORMATION
14.1 U.S. Department of Transportation (DOT) Shipping Regulations:

This product is classified (per 49 CFR 172. 101) by the U.S. Department of Transportation, as follows.
UN Identification Number: UN2815
Proper Shipping Name: N-Aminoethylpiperazine
Hazard Class Number and Description: Class 8 - Corrosive substances
Packing Group: Ill
DOT Label(s) Required: Corrosive substances
North American Emergency Response
Guidebook Number: 153
14.2 Environmental Hazards:
Marine Pollutant: The components of this product are designated by the
Department of Transportation to be Marine Pollutants
(49 CFR 172.101, Appendix B).
14.3 Special Precaution for User: None
14.4 International Air Transport Association
Shipping Information (IATA): This product is considered as dangerous goods.
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Safety Data Sheet
Version 1 pg. 10
14.5 International Maritime Organization

Shipping Information (IMO):
UN Identification Number: UN2815
Proper Shipping Name: N-Aminoethylpiperazine
Hazard Class Number and Description: Class 8 - Corrosive substances
Packing Group: Ill
EMS-No: F-A-S-B
15.1 Safety, Health and Environmental Regulations Specific for the Substance or Mixture:
United States Regulations:
U.S. SARA Reporting Requirements:
The components of this product are not subject to the reporting requirements of Sections 302, 304, and 313
of Title Ill of the Superfund Amendments and Reauthorization Act.
U.S. SARA 311/312:
Acute Health: Yes; Chronic Health: Yes; Fire: No; Reactivity; No
U.S. CERCLA Reportable Quantity:
Not Applicable
U.S. TSCA Inventory Status:
The components of this product are listed on the TSCA Inventory or are exempted from listing.
Other U.S. Federal Regulations:
None known
California Safe Drinking Water and Toxic Enforcement Act (Proposition 66):
This product does not contain ingredients on the Proposition 65 Lists.
15.2 Canadian Regulations:
Canadian DSL/NDSL Inventory Status:
Components are DSL Listed, NDSL Listed and/or are exempt from listing
Other Canadian Regulations:
Not applicable
Canadian Environmental Protection Act (CEPA) Priorities Substances Lists:
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
(J)uct
Canadian WHMIS Classification and Symbols:
is Class D2A, Very Tmdc Material, per WHMIS Controlled Product Regulations.
15.3 European Economic Community Information:

This product meets the definition of a hazardous substance or preparation as defined by the European
Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. See Section
2 for Details.
Chemical Safety Assessment:
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
15.4 Australian Information for Product:
Components of this product are listed on the International Chemical Inventory list.
15.5 Japanese Information for Product:
Page 236 of 516

Version 1 pg. 11
Japanese Minister of International Trade and Industry (MITI) Status: The components of this product are not
listed as Class I specified Chemical Substances, Class II Specified Chemical Substances, or Designated
Chemical Substances by the Japanese MITI.
15.6 International Chemical Inventories:
Listing of the components on individual country Chemical Inventories is as follows:
Australian Inventory of Chemical Substances (AICS): Listed
Korean Existing Chemicals List (ECL): Listed
Japanese Existing National Inventory of Chemical Substances (ENCS): Listed
Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed
U.S. TSCA: Listed
Prepared By: Chris Eigbrett (MSDS to GHS Compliance)

Date of Printing: April 30, 2015
The information contained herein is believed to be accurate but is not warranted to be so. Data and
calculations are based on information furnished by the manufacturer of the product and manufacturers of
the components of the product. Users are advised to confirm in advance of the need that information is
current, applicable and suited to the circumstances of use. This safety sheet cannot cover all possible
situations which the user may experience during processing. Each aspect of your operation should be
examined to determine if, or where, additional precautions may be necessary. All health and safety
information contained in this bulletin should be provided to your employees or customers. SpecChem
assumes no responsibility for injury to vendee or third party person proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, SpecChem
assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety
procedures are followed. Compliance with all applicable federal, state, and local laws and local regulations
remains the responsibility of the user.
END OF SDS SHEET
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SAFETY DATA SHEET

J1.Identification
Material name: SPEED CRETE RED LINE
Material: TR5101650

Recommended use: Cement, Portland, chemicals
19218 REDWOOD ROAD
CLEVELAND OH 44110
us
Telephone: 216-531-9222
J2.Hazard(s) identification
Health Hazards
Skin Corrosion/Irritation Category 2
Skin sensitizer Category 1
1
Specific Target Organ Toxicity - Category 3 ·
Single Exposure
Specific Target Organ Toxicity - Category 11·
Repeated Exposure
Target Organs
1. Respiratory tract irritation.
2. Lung
Unknown toxicity - Health

Acute toxicity, oral 92.52 %
Acute toxicity, dermal 92.68 %
Acute toxicity, inhalation, vapor 100 %
Acute toxicity, inhalation, dust 100 %
or mist
Environmental Hazards
Acute hazards to the aquatic Category 3
environment
Unknown toxi.Gity- Environment

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Acute hazards to the aquatic 99.5 %

environment
Chronic hazards to the aquatic 100 %
environment
Label Elements
Hazard Symbol:
Signal Word: Danger
Hazard Statement: Causes skin irritation.

Causes serious eye damage.
May cause cancer.
Causes damage to organs through prolonged or repeated exposure.
Harmful to aquatic life.
Precautionary
Statements
Prevention: Wash thoroughly after handling. Wear protective gloves/protective

clothing/eye protection/face protection. Contaminated work clothing should
not be allowed out of the workplace. Obtain special instructions before use.
Use personal protective equipment as required. Use only outdoors or in a
well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Do
not eat, drink or smoke when using this product. Avoid release to the
environment.
Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. IF ON
SKIN: Wash with plenty of water/ ... If skin irritation or rash occurs: Get
medical advice/attention. Immediately call a POISON CENTER/doctor/ ...
Specific treatment (see this label). Wash contaminated clothing before
reuse.
Storage: Store locked up. Store in a well-ventilated place. Keep container tightly
closed.
Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
Hazard(s) not otherwise None.

classified (HNOC):
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13.
Composition/information on ingredients
Mixtures
Chemical Identity GAS number Content in percent(%)*
Portland cement 65997-15-1 50 - <100%

Crystalline Silica (Quartz)/ 14808-60-7 20- <50%
Silica Sand
Gypsum (Calcium Sulfate) 10034-76-1 10- <20%
Kaolin Clav 1332-58-7 5- <10%
Ammonium Chloride 12125-02-9 0.1-<1%
Titanium dioxide 13463-67-7 0.1-<1%
* All concentrations are percent by weight unless ingredient 1sa gas. Gas concentrations are in percent by volume.
Ingestion: Call a POISON CENTRE/doctor/ if you feel unwell. Rinse mouth.
Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated shoes.
Immediately remove contaminated clothing and shoes and wash skin with
soap and plenty of water. If skin irritation or an allergic skin reaction
develops, get medical attention.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Call a physician or poison control center
immediately.
Symptoms: Prolonged or repeated contact with skin may cause redness, itching,
irritation and eczema/chapping. Extreme irritation of eyes and mucous
membranes, including burning and tearing. Respiratory tract irritation.
Treatment: Symptoms may be delayed.

media:
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media:
the chemical:

procedures:
for fire-fighters: worn in case offire.
js.Accidental release measures

Personal precautions, See Section 8 of the SOS for Personal Protective Equipment. Do not touch
protective equipment and damaged containers or spilled material unless wearing appropriate
emergency procedures: protective clothing. Keep unauthorized personnel away.
Methods and material for Collect spillage in containers, seal securely and deliver for disposal
containment and cleaning according to local regulations.
up:
to do so. Do not contaminate water sources or sewer.
j7.Handling and storage

Precautions for safe handling: Do not handle until all safety precautions have been read and understood.
Obtain special instructions before use. Use personal protective equipment
as required. Do not get in eyes. Wash hands thoroughly after handling.
Avoid contact with skin. Avoid contact with eyes, skin, and clothing.
Ventilate well, avoid breathing vapors. Use approved respirator if air
contamination is above accepted level. Use mechanical ventilation in case
of handling which causes formation of dust.
Conditions for safe storage, Store locked up.

including any
incompatibilities:
js.Exposure controls/personal protection
Control Parameters
0 ccupa f 1onaIE xposure L"1m1ts
.
Chemical Identity Type ExposureLimitValues Source

Portland cement - Respirable TWA 1 mg/m3 US. ACGIH Threshold Limit Values (2011)
fraction.
Portland cement - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000\ (02 2006)
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Portland cement - Respirable PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
fraction. Contaminants (29 CFR 1910.1000) (02 2006)
Portland cement TWA 50 millions of US. OSHA Table Z-3 (29 CFR 1910.1000)
particles per (2000)
cubic foot of
air
Crystalline Silica (Quartz)/ TWA D.025 mg/m3 US. ACGIH Threshold Limit Values (2011)
Silica Sand - Respirable
fraction.
Crystalline Silica (Quartz)/ TWA 2.4 millions US. OSHA Table Z-3 (29 CFR 1910.1000)
Silica Sand - Respirable. of particles (2000)
per cubic foot
of air
TWA D.1 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000)
(2000)
Crystalline Silica (Quartz)/ TWA D.05 mg/m3 US. OSHA Specifically Regulated Substances
Silica Sand - Resoirable dust. /29 CFR 1910.1001-1053) /03 2016)
OSHA_AC D.025 mg/m3 US. OSHA Specifically Regulated Substances
T (29 CFR 1910.1001-1053) (03 2016)
Crystalline Silica (Quartz)/ PEL 0.05 mg/m3 US. OSHA Table Z-1 Limits for Air
Silica Sand - Resoirable dust. Contaminants /29 CFR 1910.1000) /03 2016)
Gypsum (Calcium Sulfate) - TWA 10 mg/m3 US. ACGIH Threshold Limit Values (2011)
lnhalable fraction.
Gypsum (Calcium Sulfate) - PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Total dust. Contaminants /29 CFR 1910.1000) /02 2006)
Respirable fraction. Contaminants (29 CFR 191D.1000) /02 2006)
Contaminants /29 CFR 1910.1 ODD)/02 2006)
Total dust. Contaminants (29 CFR 191D.1ODD)(02 2006)
Kaolin Clay - Respirable TWA 2 mg/m3 US. ACGIH Threshold Limit Values (2011)
fraction.
Contaminants /29 CFR 1910.1000\ /02 2006)
Kaolin Clay - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 191D.1000\ (02 2006\
TWA 50 millions of US. OSHA Table Z-3 (29 CFR 1910.1000) (03
particles per 2016)
cubic foot of
air
Kaolin Clay - Respirable TWA 15 millions of US. OSHA Table Z-3 (29 CFR 1910.1000) (03
fraction. particles per 2016)
cubic fool of
air
TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03
2016)
Kaolin Clay - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03
2016)
Ammonium Chloride - Fume. TWA 10 ma/m3 US. ACGIH Threshold Limit Values (2011)
STEL 20 mg/m3 US. ACGIH Threshold Limit Values (2011)
Ammonium Chloride - Total TWA 50 millions of US. OSHA Table Z-3 (29 CFR 1910.1000) (03
dust. particles per 2016)
cubic foot of
air
Ammonium Chloride - TWA 15 millions of US. OSHA Table Z-3 (29 CFR 1910.1000) (03
Respirable fraction. particles per 2016)
cubic foot of
air
TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03
2016)
Ammonium Chloride - Total TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03
dust. 2016)
Titanium dioxide TWA 10 ma/m3 US. ACGIH Threshold Limit Values (2011)
Titanium dioxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants /29 CFR 1910.1000\ /02 2006)
Titanium dioxide - Respirable TWA 15 millions of US. OSHA Table Z-3 /29 CFR 1910.1000) (03
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fraction. particles per 2016)

cubic foot of
air
Titanium dioxide - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03
2016)
Titanium dioxide - Respirable TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03
fraction. 2016)
Titanium dioxide - Total dust. TWA 50 millions of US. OSHA Table Z-3 (29 CFR 1910.1000) (03
particles per 2016)
cubic foot of
air
Chemical name Type Exposure Limit Values Source
Portland cement - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational
Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Portland cement - Respirable TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational
fraction. Exposure Limits for Chemical Substances,
296/97, as amended) /07 2007)
Portland cement - Respirable TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Bioloaical or Chemical Aaents) /06 2015)
Portland cement - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor-
Regulation Respecting the Quality of the Work
Environment) /12 2008)
Portland cement - Respirable TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
dust. Regulation Respecting the Quality of the Work
Crystalline Silica (Quartz)/ TWA 0.025 mg/m3 Canada. British Columbia OELs. (Occupational
Silica Sand - Respirable Exposure Limits for Chemical Substances,
fraction. Occupational Health and Safety Regulation
296/97, as amended) /07 2007)
Crystalline Silica (Quartz)/ TWA 0.10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
Silica Sand - Respirable Biological or Chemical Agents) (06 2015)
fraction.
Crystalline Silica (Quartz)/ TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Silica Sand - Respirable dust. Regulation Respecting the Quality of the Work
Environment) (12 2008)
Gypsum (Calcium Sulfate) - STEL 20 mg/m3 Canada. British Columbia OELs. (Occupational
Total dust. Exposure Limits for Chemical Substances,
296/97, as amended) /07 2007)
TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational
296/97, as amended) /07 2007)
Gypsum (Calcium Sulfate) - TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational
Respirable fraction. Exposure Limits for Chemical Substances,
296/97, as amended) (07 2007)
Gypsum (Calcium Sulfate) - TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational
lnhalable Exposure Limits for Chemical Substances,
296/97, as amended) /07 2007)
Gypsum (Calcium Sulfate) - TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
lnhalable fraction. Bioloaical or Chemical Aoents) /11 2010)
Gypsum (Calcium Sulfate) - TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Total dust. Regulation Respecting the Quality of the Work
TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
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Gypsum (Calcium Sulfate) - TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Respirable dust. Regulation Respecting the Quality of the Work
5 mg/m3 Canada. Quebec OE Ls. (Ministry of Labor -
TWA
Kaolin Clay - Respirable. TWA 2 mg/m3 Canada. British Columbia OELs. (Occupational
296/97, as amended) /07 2007)
Kaolin Clay - Respirable TWA 2 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Bioloaical or Chemical Aaents) (11 2010)
Kaolin Clay - Respirable dust. TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational
296/97, as amended) /07 2007)
Titanium dioxide - Respirable TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational
fraction. Exposure Limits for Chemical Substances,
296/97, as amended) (07 2007)
Titanium dioxide TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
Biolociical or Chemical Aaents) /11 201 O)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required.

Controls Observe good industrial hygiene practices. Observe occupational exposure
limits and minimize the risk of inhalation of dust.
General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level.
Eyelface protection: Wear a full-face respirator, if needed. Wear safety glasses with side shields
(or goggles) and a face shield.
Skin Protection
Other: Wear chemical-resistant gloves, footwear, and protective clothing

appropriate for the risk of exposure. Contact health and safety professional
or manufacturer for specific information.
local supervisor.
Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Do not get in eyes. Wash
contaminated clothing before reuse. Avoid contact with skin. Contaminated
work clothing should not be allowed out of the workplace.
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\s.Physical and chemical properties

Appearance
Physical state: solid
Form: Powder
Color: Gray
Odor: Odorless
pH: No data available.
Evaporation rate: No data available.
Vapor density: No data available.
Solubility(ies)
Solubility in water: Miscible with water.

\10. Stability and reactivity

reactions:
Incompatible Materials: No data available.
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111.Toxicological information

mucus membranes.
Skin Contact: Causes skin irritation. May cause an allergic skin reaction.
Eye contact: Causes serious eye damage.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation: No data available.
Skin Contact: No data available.
Eye contact: No data available.
Ingestion: No data available.
Oral
Product: Not classified for acute toxicity based on available data.
Kaolin Clay LD 50 (Rat):> 5,000 mg/kg
Ammonium Chloride LD 50 (Rat): 1,410 mg/kg
Titanium dioxide LD 50 (Rat): > 5,000 mg/kg
Dermal
Kaolin Clay LD 50 (Rat): > 5,000 mg/kg
Ammonium Chloride LD 50 (Rat):> 2,000 mg/kg
Inhalation
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Titanium dioxide LC 50 (Rat): 3.43 mg/I

Ammonium Chloride in vivo (Rabbit): Irritating Experimental result, Not specified
Titanium dioxide in vivo (Rabbit): Not irritant Experimental result, Supporting study

Titanium dioxide Rabbit, 24 hrs: Not irritating

Carcinogenicity
Crystalline Silica Overall evaluation: Carcinogenic to humans.

(Quartz)/ Silica
Sand
Titanium dioxide Overall evaluation: Possibly carcinogenic to humans.

Crystalline Silica Known To Be Human Carcinogen.
(Quartz)/ Silica
Sand

Crystalline Silica
(Quartz)/ Silica Cancer
Sand
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In vitro
In vivo


Target Organs
Specific Target Organ Toxicity - Single Exposure: Respiratory tract irritation.
Specific Target Organ Toxicity - Repeated Exposure: Lung
Aspiration Hazard
I12. Ecological information
Ecotoxicity:
Fish
Ammonium Chloride LC 50 (Fathead minnow (Pimephales promelas), 96 h): 0.207 - 0.304 mg/I
Mortality
Ammonium Chloride LC 50 (Water flea (Ceriodaphnia dubia), 48 h): 0.86 - 1.18 mg/I Mortality
Titanium dioxide EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/I Intoxication
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Fish
Specified substance(s ):
Ammonium Chloride NOAEL (Pimephales promelas, 28 d): 11.8 mg/I Experimental result, Key
study

Biodegradation
BOD/COD Ratio
Partition Coefficient n-octanol / water (log Kow)

Other adverse effects: Harmful to aquatic organisms.
113.
Disposal considerations

114.
TOG:
Not Regulated
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CFR / DOT:
Not Regulated
IMDG:
Not Regulated
l1s.Regulatory information

Chemical Identity OSHA hazard(s)
Crystalline Silica kidney effects
(Quartz)/ Silica Sand lung effects
immune system effects
Cancer

Ammonium Chloride 5000 lbs.
Hazard categories
Immediate (Acute) Health Hazards
Delayed (Chronic) Health Hazard
Skin sensitizer
Carcinogenicity
Specific Target Organ Toxicity- Single Exposure
Specific Target Organ Toxicity- Repeated Exposure


Ammonium Chloride 5000 lbs.
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Portland cement 10000 lbs
Crystalline Silica (Quartz)/ 10000 lbs
Silica Sand
Gypsum (Calcium Sulfate) 10000Ibs
Kaolin Clay 10000Ibs
Ammonium Chloride 10000Ibs
Titanium dioxide 10000Ibs

Clean Water Act Section 311 Hazardous Substances (40 CFR 117 .3)

This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth
Crystalline Silica (Quartz)/ Carcinogenic. 09 2011
Silica Sand
Titanium dioxide Carcinogenic. 09 2011

Chemical Identity
Portland cement
Gypsum (Calcium Sulfate)
Kaolin Clay

Chemical Identity
Portland cement
Kaolin Clay

Chemical Identity
Portland cement
Kaolin Clay
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Chemical Identity
Portland cement
Kaolin Clay
International regulations
Montreal protocol
not applicable
Stockholm convention
not applicable
Rotterdam convention
not applicable
Kyoto protocol
not applicable
voe:
Regulatory voe (less water and 0 g/1
exempt solvent)
voe Method 310 0.00 %
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Inventory Status:
Australia AICS: All components in this product are listed on or





New Zealand Inventory of Chemicals: All components in this product are listed on or


Mexico INSQ: One or more components in this product are

Ontario Inventory: One or more components in this product are

Taiwan Chemical Substance Inventory: One or more components in this product are
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W. R. MEADOWS,
SAFETYDATA SHEET
Page 1 of 2
Product: 1100 Part Number: 3011000

Manufacturer: W. R. MEADOWS, INC. Address: 300 Industrial Drive
12/26/2017
HAZARD STATEMENTS
HMIS WARNING!
I Health I 11 I May cause skin irritation.
IFlammability I Io I May cause eye irritation.
IReactivity I Io I May cause respiratory irritation.
I Personal Protection I I I PRECAUTIONARY STATEMENTS
Avoid of inhalation of mists/vapors.

Chemical Name: CAS Number % by Weight 313 Imm Hg@20°C) ~
1. Light Aromatic Naphtha 64742-95-6 5-10 No 2.1 1
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA) and 40 CFR
,l!>.~~1l,~ ~..~ J1p]fffl~ii1,~%~r1\1'1~ .-:::,_
EYE CONTACT: Immediately flush eyes with water for fifteen minutes. If symptoms persist, seek medical attention.
SKIN CONTACT: Remove contaminated shoes/clothing. Wipe excess from skin and wash with soap if available. Seek medical attention if irritation
persists. Do not use clothing until throughly decontaminated.
INHALATION: Remove victim to fresh air and treat symptomatically. Seek medical attention if symptoms persist.
INGESTION: Do not induce vomiting. If vomiting spontaneously occurs, keep the victim's head below the hips to prevent lung aspiration. Seek
FLASHPOINT: >210°F
CHEMICAL/COMBUSTION HAZARDS: Carbon dioxide, carbon monoxide, and incomplete combustion products.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Personal protective equipment should include helmet, face shield,
bunker coat, gloves, rubber boots, and a positive pressure NIOSH-approved self-contained breathing apparatus.
,1:1~~~~~&:tiidiiliitiliJ:t~~Mii~ ·
rized personnel from spill area. Wear appr
free product and soak up residue with an
OSHA ACGIH
N/E: Not Established
BOILING POINT: 212°F VAPOR DENSITY:> 1 (Air=l) % VOLATILE BY VOLUME: 85

EVAPORATION RATE: <1 (Ether =1) pH LEVEL: 8.80 % VOLATILE BY WEIGHT: 84
WEIGHT PER GALLON: 8.33 PRODUCT APPEARANCE: Tan Liquid voeCONTENT: 278 g/L
Page 257 of 516

1dizingagents.
ecognized.
-- •~1:lt:O~~.
SKIN CONTACT: Direct contact may result in mild to moderate irritatioll.
INHALATION: Not expected to be an exposure pathway under normal use conditions.
INGESTION: Not expected to be an exposure pathway under normal use conditions.
swelling, and rash. Symptoms of respiratory irritation include runny nose, coughing, chest discomfort, shortness of breath, and reduced lung
function. Symptoms of gastrointestinal irritation include sore throat, abdominal pain, nausea, vomiting, and diarrhea.
HAZARDOUS NON-HAZARDOUS MATERIAL: Non-hazardous.

UN PROPER SHIPPING NAME: Not regulated.
ENVIRONMENTAL HAZARDS: Not applicable.
BULK TRANSPORTATION INFORMATION: Not regulated when shipped in bulk configuration.
SPECIAL PRECAUTIONS: Protect reduct from freezin .
Dave Carey
Page 258 of 516

SAFETY DATA SHEET (SDS) ANTI-HYDRO INTERNATIONAL, INC.
PRODUCT: "ANTI-HYDRO"" DATE ISSUED: May 1, 2015; PAGE:1 of 3
PRODUCT NAME: "ANTI-HYDRO"" EMERGENCY PHONE: 1(800) 424-9300 (CHEMTREC)
SYNONYM: Concrete Admixture, Aqueous PHONE FOR INFORMATION: 1(908) 284-9000
USAGE: Portland Cement Waterproofing & Set Accelerating COMPANY: Anti-Hydro International, Inc.
PACKAGING:¼, 1, 5 or 55 gallon containers 45 River Road, Flemington, NJ 08822
SECTION 2 - HAZARD($) IDENTIFICATION
EMERGENCY OVERVIEW: WARNING!Material is a slightly turbid, pinkish aqueous mixture with slight odor. May irritate eye, skin or
upper respiratory tract (see SECTION4of the SOS).Take proper measures for personal protections and hygiene, housekeeping,
storage and handling, including exposure controls (see SECTION7 and SECTION8 of the SOS).
Major Route(s) of Entry: Eye(s), Skin, Inhalation (mist), Ingestion.
GLOBALLY HARMONIZED SYSTEM (GHS)
Eye Irritation - Category 2A; Skin corrosion/irritation - Category 3
CLASSIFICATION:
classified (not classified as a carcinogen by NTP, IARC, or OSHA).
Carcinogenicity: Not ,.,,,
PICTOGRAM/SYMBOL: <,.f)GHS07 Exclamation mark {H316; 319) SIGNAL WORD: WARNING!

GHS STATEMENTS
Health Hazards: H316 Causes mild skin irritation; H319 Causes serious eye irritation.
General: P1O2 Keep out of reach of children.
Prevention: P2O2 Do not handle until all safety precautions have been read and understood; P264 Wash hands thoroughly after
handling; P28O Wear protective gloves/protective clothing/eye protection/face protection.
Response: P3O2 + P352 IF ON SKIN: wash with plenty of soap and water; P321 Specific treatment (see First Aid information in
SECTION4 of the SOS); P332 + P313 IF skin irritation occurs: Get medical advice/attention; P362 Take off contaminated clothing and
wash before reuse. P3O5+P351+P338 IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing; P337 + P313 IF eye irritation persists: Get medical advice/attention. P33O + P331 IF SWALLOWED:
Rinse mouth. Do NOT induce vomiting; P314 Get medical advice/attention if you feel unwell. P3O4 +P34O IF INHALED: Remove
victim to fresh air and Keep at rest in a position comfortable for breathing; P314 Get medical advice/attention if you feel unwell.
Storage: P4O3 + P235 Store in a well-ventilated place. Keep cool; P4O2 + P4O4 Store in a dry place. Store in a closed container.
Disposal: P5O1 Dispose of contents and container in accordance with applicable local, regional, national, and/or international
regulations.
HAZARDS NOTOTHERWISE CLASSIFIED (HNOC): None identified. TOXICOLOGY INFORMATION: See SECTION11 of the sos.
NoTE:This Safety Data Sheet information is compiled from component manufacturers' SOS and/or test data.
SECTION 3 - COMPOSITION/ INFORMATION ON INGRDIENTS
The specific chemical identity and/or exact percentage (concentration) of the "Anti-Hydro"" mixer composition has been withheld
as a proprietary trade secret. The mixture contains aqueous solution of calcium chloride, CAS# 10043-52-4 as a component and
may contain some impurities, e.g. potassium chloride CAS#7447-40-7, sodium chloride CAS#7647-14-5. All other mixture
components are non- or less hazardous and/or below the cut-off limits.
SECTION 4 - FIRST AID MEASURES (Continued on Page 2 of 3)
EYE CONTACT: If in eyes, immediately rinse eyes cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If irritation occurs, get medical advice/attention.
SKIN CONTACT: If on skin, wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. Specific Treatment: Wash with lots of clean and cool water.
INHALATION: Avoid inhalation of vapor, spray or mist. If inhalation occurs and adverse effects result, move person to fresh air and
keep comfortable for breathing. Get medical advice/attention immediately if you feel unwell.
INGESTION: If swallowed, rinse mouth. If exposed person is conscious, give small quantities of water to drink. Do NOT induce
vomiting. Get medical advice/attention immediately if you feel unwell.
MOST IMPORTANT SYMPTOMS/EFFECTS (ACUTE AND DELAYED)
Eye- May cause serious eye irritation, corneal eye pain, redness and/or acute corneal thickening or whitening.
Skin- Skin exposure may cause slight irritation, redness, itching, and swelling. May cause more severe response if skin is damp,
abraded (scratched or cut), or covered.
Inhalation (Breathing) - Inhaling mist, spray, or vapor may cause irritation to upper respiratory tract (nose and throat).
Ingestion (Swallowing) - Consumption of large amount of solids/liquid causes nausea, vomiting, and increased thirst.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting or compromised skin, eye and respiratory conditions.
INTERACTION WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY: None known.
PROTECTION OF TREATING PERSONNEL: If potential for exposure exists refer to SECTION 8 for specific measures.
Notes to Physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to
S082193 7/16 Page 1 of 3
Page 259 of 516

PRODUCT: "ANTI-HYDRO"" DATE ISSUED: May 1, 2015; PAGE:2 of 3
SECTION 4- FIRST AID MEASURES (Continued from Page 1 of 3)

be kept under medical surveillance for 48 hours.
SECTION 5- FIRE-FIGHTING MEASURES
FLASHPOINT:Not applicable FIREHAZARD:This material does not burn.
FLAMMABLE LIMITS(in Air% by Vol): LEL (Lower): Not applicable; UEL (Upper): Not applicable
EXTINGUISHING MEDIA: Use extinguishing agents appropriate for surrounding fire.
FIREFIGHTING PROCEDURE: Keep unnecessary people away, isolate hazard area and deny entry. This material does not burn. Fight fire
for other material that is burning. Water should be applied in large quantities as fine spray. Wear NIOSH approved positive-
pressure self-contained breathing apparatus operated in pressure demand mode. Wear protective firefighting clothing (includes
firefighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during firefighting operations.
HAZARDOUS COMBUSTION PRODUCT: Decomposes on heating generating hydrogen chloride gas and oxides of calcium.
SECTION 6- ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Spilled material may
cause a slipping hazard on some surfaces. Use appropriate safety equipment. For additional information, refer to SECTION 8,
Exposure Controls and Personal Protection. Refer to SECTION 7, Handling, for additional precautions.
METHODS ANDMATERIALS FORCONTAINMENT ANDCLEANING UP: Small and large spills: Contain spilled material if possible. Absorb with
materials such as sand. Collect in suitable and properly labeled containers. Flush residue with plenty of water. See SECTION 13,
Disposal considerations, for additional information.
ENVIRONMENTAL PRECAUTIONS: Prevent large spills from entering into soil, ditches, sewers, waterways and/or groundwater. See
SECTION 12, Ecological Information.

HANDLING: Avoid contact with eyes, skin, and clothing. Do not swallow or inhale. Wash hands thoroughly after handling. Wear
personal protective equipment as described below in Exposure Controls/Personal Protection SECTION 8. Keep container closed when
not in use. Do not smoke, eat and/or drink in the work area.
STORAGE: Store in a dry, cool and well ventilated place, away from incompatible substances (see SECTION 10 of the SDS),children,
food items, animals and vegetation. Keep container closed.
SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION
EYE PROTECTION: Wear chemical safety goggles and/or a face-shield when needed to prevent eye and skin contact.
SKIN/HAND PROTECTION: Use chemically resistant rubber gloves (Neoprene, PVC, and Nitrile/butadiene). Wear long-sleeve garments,
work boots and apron.
INHALATION: In misty conditions, wear approved breathing mask or particulate respirator.
ENGINEERING CONTROLS: Use local exhaust ventilation, or other engineering controls to maintain airborne exposure within limits
OTHER PROTECTIVE MEASURES: Safety shower or eye wash station. Use good personal hygiene. Do not eat, drink or smoke in the area.
Wash hands after the use. Keep away from children, animal, food and vegetation.
SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Slightly turbid, pinkish, aqueous liquid mixer ODOR: Slight Odor ODOR THRESHOLD: Not Applicable
pH: Neutral/slightly acidic (7 -5) SOLUBILITY: Readily dispersible in water.
SPECIFICGRAVITY (H20=1): Approx.1.22 VISCOSITY: 2 - 7 cp@ 77°C (25 °C)
VAPORPRESSURE: 9 - 15 mm Hg @ 77°C (25 °C) VAPOR DENSITY (Air=l): No Data
HYGROSCOPIC: Yes voeCONTENT: o g/I (less water)
EVAPORATION RATE(Ether=l): No Data FREEZING POINT:Approx. -46° F (-43° C)
BOILING POINT: 230° - 252° F (110° - 122° C) FLAMMABILITY: Not Flammable
Non: The above information is typical for this family of materials/components and may vary under actual conditions.
SECTION 10 • STABILITY AND REACTIVITY
CHEMICAL STABILITY:Stable at normal temperatures and pressures. REACTIVITY: Hygroscopic
POSSIBILITY OFHAZARDOUS REACTIONS: No information available. CONDITIONS TOAVOID: None known.
INCOMPATIBILITIES/MATERIALS TO AVOID: Avoid contact with alkalis, acids, reducing agents, combustible material, organic material,
bromide trifluoride, 2-furan percarboxylic acid, zinc. Catalyzes exothermic polymerization of methyl vinyl ether.
HAZARDOUS DECOMPOSITION PRODUCTS: Formed under fire conditions: hydrogen chloride gas, calcium oxide
HAZARDOUS POLYMERIZATION: Will not occur at normal temperatures and pressures.
SECTION 11 - TOXICOLOGICAL INFORMATION (Continued on Page 3 of 3)

Tox1c1TY: Acute-For liquid calcium chloride, Oral LDSOI2282 mg/kg- estimate (ATE); Dermal LDSODermal- 6013 mg/kg- estimate
(ATE). Chronic- Not toxic.
EFFECTS OFEXPOSURE: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet.
S082193 7/16 Page1 of 3
Page 260 of 516

PRODUCT:"ANTI-HYDRO"" DATE ISSUED: May 1, 2015; PAGE:3 of 3
SECTION 11 - TOXICOLOGICAL INFORMATION (Continued from Page 2 of 3)
Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Ingestion: Can result in nausea,
vomiting, diarrhea, and abdominal pain. Eye contact: Irritation. Skin contact: Result in mild irritation. Inhalation: Mists or aerosols
may produce respiratory irritation. Sensitization- Not sensitizing.
CARCINOGENICITY: Not classified as a carcinogen per GHS, NTP, IARC, OSHA criteria. Also see SECTION 2 of the sos.
MUTAGENICITY: No mutagenic effect.
Eco TOXICITY: Aquatic: Material is practically non-toxic to aquatic organisms on an acute basis
ENVIRONMENTAL FATE:Biodegradation: Not subject to biodegradation; Bio concentration: Not expected; Persistence: Readily
dissociates; Bioaccumulation: Readily dissociates; Mobility in Soil: Readily dissociates (Typical for this family of materials/major
components).
SECTION 13- DISPOSAL CONSIDERATION
WASTEDISPOSAL METHOD:Dispose of content and container in accordance with applicable local, regional, national, and/or
international regulations. Reuse or reprocess the content if possible.
SECTION 14-TRANSPORTATION INFORMATION
U.S. DOT: Not regulated (49 CFR 172.101).
CANADIAN TRANSPORTATION OFDANGEROUS GOODS(TDG): Not regulated
MARITIMETRANSPORT (IMO/IMDG): Not regulated
IATA/ICAO DGR INFORMATION: Not dangerous material or substance.
U.S. REGULATIONS
OSHA: This document may be used to comply with OSHA's Hazardous Communication Standard, 29 CFR 1910.1200. Considered
hazardous based on the criteria "Irritant"; 29 CFR 1910.119: Not regulated.
CERCLA:Sections 102a/103 Hazardous Substances (40 CFR 302.4): Not regulated
SARA EHS Chemical: 40 CFR355.30: Not regulated
EPCRA: Section 311/312 Hazard (40 CFR370.10): Acute Health Hazard; Section 313 (40 CFR372.65): To the best of our knowledge,
this product does not contain chemicals at levels which require reporting under this statute.
HMIS: Health-1; Flammability-0; Reactivity-0; Protection- See SECTION 8; (O=Minimal, l=Slight, 2=Moderate, 3=Serious, 4=Severe)
NFPA: Health-1; Flammability-0; Reactivity-0; Special- See SECTION 5; (Scale 0-4)
NATIONAL INVENTORY STATUS
U.S. TSCA Inventory Status: All components are listed or exempt. TSCA 12(b): Not subject to export notification.
Canadian Chemical Inventory: All components of this product are listed on either the DSL or the NDSL.
WHMIS Classifications: WHMIS: D-1B (immediate and serious toxic effects).
STATEREGULATIONS:
California Proposition 65: Not listed, but it may contain impurities/trace elements known to the State of California to cause cancer
or reproductive toxicity as listed under Proposition 65 State Drinking Water and Toxic Enforcement Act.
DISCLAIMER: This product is for professional use only. The information contained herein was obtained from sources which Anti-hydro
International, Inc. believes are reliable. However Anti-Hydro International, Inc. does not warrant or assume any liability whatsoever
for the accuracy or completeness of information contained herein. Some information presented and conclusions drawn herein are
from sources other than direct test data on the substance itself Final determination of suitability of this product or any material is
the sole responsibility of the user. This product or any material may present unknown health and/or fire hazards and should be used
with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. This
disclaimer may not be detached from this MSDS. Any copying and redistribution of this MSDS shall also include copying and
redistribution of this disclaimer.
DATEISSUED: May 1, 2015 (Total Pages: 3).
SD821937/16 Page1 of 3
Page 261 of 516

Page 262 of 516
W. R. MEADOWS.,,
SAFETYDATA SHEET
'-~~~L
Product: DECRA-SEAL- W/B Part Number: 3465000

Telephone: (847) 214-2100 In case of emergency, dial (800} 424-9300 (CHEMTREC}
Product Use: Concrete Sealer
.~~!~~!~~(;;)~~
IHealth I 11 I WARNING!
IFlammability I Io I Skin and respiratory irritant.
I Reactivity I Io I May cause an allergic skin reaction.
IPersonal Protection I I I May cause damage to liver and kidneys.
Avoid direct contact/breathing mists.
_Jlllllil;J:~~~~~,\"
Chemical Name: CAS Number Weight 313 (mm Hg@20°C\ (@li:Q
1. N-Methyl Pyrolidone 872-50-4 1-5 N/E 0.29 1.2
2. Ethylene Glycol Monobutyl Ether 111-76-2 1-5 Yes 0.66 1.1
Under the reporting requirements of Section 313 ofTitle Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA} and 40
CFR Part 372, chemicals listed on the 313 List (40 CFRPart 373.65} are identified under the heading "SARA 313."
;,:,1111;1-~~i~EliU:~ '·~ ~-,, ·
EYE CONTACT: Direct contact may result in mild to moderate irritation. Corneal injury is unlikely.
SKIN CONTACT: Direct contact may cause mild skin irritation. Prolonged/repeated contact may result in skin irritation and dermatitis.
INHALATION: Exposure to mists/sprays may cause irritation of the respiratory tract.
INGESTION: Not anticipated to be an exposure route. If ingested irritation of the gastrointestinal tract may occur. Signs of central
nervous
system depression (headache, fatigue, drowsiness, dizziness, and loss of coordination} may occur.
1. N-Methyl Pyrolidone N/E N/E N/E No 100 ppm N/E N/E No
2. Ethylene Glycol Monobutyl Ether 50 ppm N/E N/E Yes 20 ppm N/E N/E Yes
ENGINEERING CONTROLS: None required under normal conditions of use.
::'~~~•~IIJl!;_ -
BOILING POINT: 212° F (for water} VAPOR DENSITY:> 1 (air=l} % VOLATILE BY VOLUME: N/E
EVAPORATION RATE: <1 (ether=l) pH LEVEL: 8.24 % VOLATILE BY WEIGHT: N/E
WEIGHT PER GALLON: 8.60 PRODUCT APPEARANCE: Opaque liquid voe CONTENT: 204 g/L
Page 263 of 516

SAFETYDATA SHEET
EYECONTACT:Flush eyes with water for fifteen minutes. If irritation persists, seek medical attention.
SKINCONTACT:Remove contaminated clothing/shoes. Cleanse affected areas with mild soap and water. If irritation persists, seek medical
attention.
INHALATION:Remove victim from exposure source. Treat symptomatically.
INGESTION:Dilute with two glasses of water unless the victim is unconscious or very drowsy. If vomiting spontaneously occurs, keep the
victim's head below the hips to prevent lung aspiration. Seek immediate medical attention.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include pain, tearing, reddening, and swelling. Symptoms of skin irritation include reddening,
swelling, rash, and redness. Symptoms of respiratory irritation include runny nose, sore throat, coughing, chest discomfort, shortness of breath,
and reduced lung function. Symptoms of gastrointestinal irritation include sore throat, abdominal pain, nausea, vomiting, and diarrhea.
AGGRAVATEDMEDICALCONDITIONS:Pre-existing liver, kidney, and lung conditions may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:Target organs include lungs, liver, and kidneys. Ethylene Glycol Monobutyl Ether has been shown to cause cancer in
in laboratory animals. The relevance of this finding to humans is uncertain.
HAZARDOUS/NON-HAZARDOUS MATERIAL:Non-hazardous.
UN NUMBER: None. HAZARDCLASS:None. PACKINGGROUP: None.
UN PROPERSHIPPINGNAME: None.
BULKTRANSPORTATION INFORMATION:Not applicable. Product is not shipped in bulk configuration.
SPECIALPRECAUTIONS:None recognized.
Page 264 of 516

W R. MEADOWS,,.
SAFETYDATA SHEET
~ ]L
Product: DECRA-SEAL™S/B Part Number: 3565000
Product Use: Ac lie Cure/Seal for Decorative Concrete
":,c1~!~lF
HMlS AZARD STATEMENTS
Warning!
IHealth I 111 Flammable liquid and vapor.
IFlammability I 121 Harmful if inhaled.
IReactivity I 101 Causes skin/eye/respiratory irritation.
IPersonal Protection I I I Prolonged/repeated exposure may cause organ damage.
May be fatal if ingested and enters airways.
Keep containers closed when not in use. Avoid ignition sources.
Wear appropriate Personal Protective Equipment.
Use onl outdoors or in well-ventilated areas.

Chemical Name: CAS Number Weight 313 Imm Hg@20°Cl i@lW
1. Light Aromatic Naphtha 64742-95-6 45-50 No <10@ 25°C 0.9
2. Xylene 1330-20-7 10-15 Yes 6.6 1.1
3. 1,2,4-Trimethylbenzene 95-63-6 10-15 Yes N/E 0.9
4. Ethylene Glycol Monomethyl Ether Acetate 108-65-6 1-5 Yes 3.7 1.5
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA)and 40
CFR Part 372, chemicals listed on the 313 List (40 CFR Part 373.65) are identified under the heading "SARA 313." N/E: Not Established
-· -•~~~.
" j~~i.~~~nnrm
EYE CONTACT: If irritation or redness develops, move victim from exposure source and into fresh air. Flush eyes with water for fifteen
(15) minutes, If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water. Remove contaminated shoes/clothing. If symptoms persist, seek medical
attention.
INHALATION: If respiratory symptoms develop, move victim from exposure source and into fresh air. If symptoms persist, seek medical
attention. If victim is not breathing, begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified
personnel.
FLASHPOINT: 105 degrees F (Estimate)

EXTINGUISHING MEDIA; Wilter fog, foam, dry chemical, or carbon dioxide.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Personal protective equipment should include helmet, face
shield, bunker coat, gloves, rubber boots, and a positive pressure NIOSH-approved self-contained breathing apparatus.
- • . ·. ' ⇒ 'timij~"-
SPI LL OR LEAK PROCEDURES: Avoid direct contact. Dike and contain spilled material. Remove source of spill if safe to do so. Evacuate all
non-essential personnel from immediate area. Remove/extinguish ignition sources. A vapor-suppressing foam may be used to reduce vapor
generation. Absorb with non-combustible absorbent and place in sealed containers for disposal. Control run-off and prevent from entering
..-
waterways, sewers, etc .... Use non-sparking tools to collect spilled material as well as contaminated absorbent .
•~••■• -:Qin:::
SAFE HANDLING PROCEDURES: Avoid direct contact. Use adequate grounding when decanting.
".~.
SAFE STORAGE: Keep containers closed when not in use. Keep away from ignition sources.
Page 265 of 516

SAFETYDATA SHEET
OSHA ACGIH
Chemical Name: PEL PEL[CEILING PELLSTEL SKIN TWA TLV [CEILING TLVLSTEL SKIN
1. Light Aromatic Naphtha N/E N/E N/E N/E N/E N/E N/E No
2. Xylene 100 ppm N/E N/E No 100 ppm N/E 150 ppm No
4. Cumene SO ppm N/E N/E YES SOppm N/E N/E Yes
5. Ethylene Glycol Monomethyl Ether Acetate N/E N/E N/E N/E N/E N/E N/E Yes
ENGINEERING CONTROLS: Use with adequate ventilation. Use explosion-proof equipment.
PERSONAL PROTECTIVE EQUIPMENT: Safet lasses chemical-resistant loves.
EYE CONTACT: Direct contact may cause mild to moderate irritation. Product vapors may a so cause irritation.
SKIN CONTACT: Direct contact may cause mild skin irritation. Prolonged/repeated contact may result in irritation/dermatitis.
INHALATION: Exposure may produce irritation to the nose, throat, respiratory tract, and other mucous membranes. Exposure to excessive
vapor concentrations may cause signs of transient central nervous system depression (headache, drowsiness, loss of coordination and
fatigue). Repeated/prolonged occupational overexposures may result in permanent damage and can be potentially fatal.
INGESTION: This product is anticipated to be slightly toxic. If ingested and lung aspiration occurs, serious lung damage may result. Ingestion
of excessive quantities may result in symptoms of central nervous system depression.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include reddening,
swelling, rash, and redness. Symptoms of gastrointestinal irritation include abdominal pain, vomiting and diarrhea. Symptoms of respiratory
irritation include runny nose, sore throat, coughing, chest discomfort, shortness of breath, reduced lung function, and symptoms of central
nervous system depression.
OTHER HEALTH EFFECTS: Based on the presence of component 4, chronic overexposure may cause damage to red blood cells and kidneys.
Component 5 has been shown to have reversible liver and kidney effects on laboratory animals. Component 5 has also been shown to cause
harm to the fetus in laborator animal studies. The relevance to humans is uncertain.
HAZARDOUS/NON-HAZARDOUS MATERIAL: Combustible Liquid. Not regulated by domestic ground transportation.

UN NUMBER: None. HAZARD CLASS: None. PACKING GROUP: N/A
UN PROPER SHIPPING NAME: None.
ENVIRONMENT.Mc HAZARDS: Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
BULK TRANSPORTATION INFORMATION: Not applicable. Product not shipped in bulk configuration.
SPECIAL PRECAUTIONS: Keep containers closed. Avoid ignition sources.
~•~--,~ =====
=intft .. ".I·""
The information contained herein is based on the data available to us and is believed to be correct. However, we make no warranty,
expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof We assume no responsibility
for injury from the use of this product described herein.
Page 266 of 516

SAFETY DATA SHEET
·1111111mmmm:
mmimmmm· immmmmm
:m11mm111m1:
•tj!>
1. Identification
Product identifier L&M E-Con
Recommended use Curing compound.
Company Name LATICRETE International
Address 1 Laticrete Park, N
Bethany, CT 06524
Telephone (203)-393-0010
Contact person Steve Fine
Website www.laticrete.com
Emergency phone number Call CHEMTREC day or night
USA/Canada - 1.800.424.9300
Mexico - 1.800.681.9531
Outside USA/Canada
1.703.527.3887
Health hazards Not classified.
Label elements
Hazard symbol None.
Signal word None.
Hazard statement None.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response No specific first aid measures noted.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise None known.
classified (HNOC)
Mixtures
Composition comments The components are not hazardous or are below required disclosure limits.
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical
attention if any discomfort continues.
Skin contact Wash skin with soap and water. Get medical attention if symptoms occur.
Eye contact Flush eyes thoroughly with water for at least 15 minutes. Get medical attention if symptoms
persist.
Ingestion Rinse mouth. Do not induce vomiting. Get medical attention if any discomfort continues.
Most important Symptoms include redness, itching and pain.
delayed
L&M E-Con sos us

921646 Version#: 01 Revision date: - Issue date: 11-August-2014 1/ 6
Page 267 of 516

Indication of immediate Treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
media
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire-fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk. Use water spray to cool unopened containers.
General fire hazards No unusual fire or explosion hazards noted.

Personal precautions, Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation.
protective equipment and Local authorities should be advised if significant spillages cannot be contained.
emergency procedures
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. For waste disposal, see Section 13 of the SOS.
Environmental precautions Environmental manager must be informed of all major releases.

Precautions for safe handling Do not breathe mist or vapor. Do not get in eyes, on skin, on clothing. Use with adequate
ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices.
Conditions for safe storage, Keep container tightly closed. Store in a cool and well-ventilated place.
including any incompatibilities

Occupational exposure limits No exposure limits noted for ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
adequate ventilation and minimize the risk of inhalation of vapors.
Eye/face protection Risk of contact: Wear approved safety glasses or goggles.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Rubber gloves are recommended.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

Appearance
L&M E-Con sos us

Page 268 of 516

Form Liquid.
Color Pink.
Odor Not available.
pH 7.2
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
(%)
Flammability limit - upper Not available.
(%)
Vapor pressure Not available.
Vapor density Not available.
Solubility(ies)
Solubility (water) Completely soluble.
Partition coefficient Not available.
( n-octanol/water)

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Possibility of hazardous Will not occur.
reactions
Conditions to avoid Heat, flames and sparks.
Incompatible materials Oxidizing agents.
Hazardous decomposition Carbon dioxide (CO2). Carbon monoxide.
products

Ingestion May cause discomfort if swallowed.
Inhalation In high concentrations, vapors may be irritating to the respiratory system.
Skin contact May cause skin irritation.
Eye contact May cause eye irritation.
Symptoms related to the Symptoms include redness, itching and pain.

Acute toxicity May cause discomfort if swallowed.
Skin corrosion/irritation May cause skin irritation on prolonged or repeated contact.
Serious eye damage/eye May cause eye irritation on direct contact.
irritation
L&M E-Con SDS US
Page 269 of 516

Respiratory sensitization No data available.
Skin sensitization Not a skin sensitizer.
Germ cell mutagenicity No data available.
Carcinogenicity Not classifiable as to carcinogenicity to humans.
Not listed.
Reproductive toxicity No data available.
single exposure
repeated exposure
Aspiration hazard Not classified.
Chronic effects No data available.

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data available.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Mobility in general The product is soluble in water.
Other adverse effects Not available.

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues/ unused Dispose of in accordance with local regulations.
products
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

DOT
IATA
IMDG
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
Not regulated.
Not listed.
Not listed.
L&M E-Con SDS US
Page 270 of 516

Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Not regulated.
Not regulated.
(SOWA)
US state regulations This product does not contain a chemical known to the State of California to cause cancer birth
US. Massachusetts RTK • Substance List
Not regulated.
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
Not regulated.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.

Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No

(PICCS)
•A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
country(s).

Issue date 1t-August-2014
Revision date
Version# 01
L&M E-Con SDS US

Page 271 of 516

NFPA ratings
References HSDB® - Hazardous Substances Data Bank

Registry of Toxic Effects of Chemical Substances (RTECS)
Disclaimer The information in this (M)SDS was obtained from sources which we believe are reliable but
cannot guarantee. Additionally, your use of this information is beyond our control and may be
beyond our knowledge. Therefore, the information is provided without any representation or
warranty express or implied.
L&M E-Con sos us

Page 272 of 516

Version: 3.0
EUCUD CHEMICAL
SAFETY DATA SHEET

11.Identification
Material name: EUCON 1037 - BULK GALLONS
Material: 01OB 99

Recommended use: Additive
19218 REDWOOD ROAD
CLEVELAND OH 44110
us
Telephone: 216-531-9222
12.Hazard(s) identification
Not classified
Label Elements
Hazard Symbol: No symbol
Signal Word: No signal word.
Hazard Statement: not applicable
Precautionary not applicable

Statements
Hazard(s) not otherwise None.

classified (HNOC):
13.Composition/information on ingredients
Mixtures
Composition Comments: The components are not hazardous or are below required disclosure limits.
1/10
800000050126
Page 273 of 516

Version: 3.0
EUCL1D CHEMICAL
Ingestion: Rinse mouth thoroughly.
Skin Contact: Remove contaminated clothing and wash the skin thoroughly with soap and
water after work.
Eye contact: Rinse immediately with plenty of water.
Symptoms: May cause skin and eye irritation.
Treatment: Get medical attention if symptoms occur.

media:
media:
the chemical:

procedures:

Personal precautions, No data available.
protective equipment and
emergency procedures:
Methods and material for Dam and absorb spillages with sand, earth or other non-combustible
containment and cleaning material. Collect spillage in containers, seal securely and deliver for
up: disposal according to local regulations.
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EUCLID CHEMICAL
to do so. Do not contaminate water sources or sewer. Environmental
manager must be informed of all major spillages.
17.Handling and storage

Precautions for safe handling: Provide adequate ventilation. Wear appropriate personal protective
equipment. Observe good industrial hygiene practices. Provide adequate
ventilation. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices.
Conditions for safe storage, Store away from incompatible materials. Store in original tightly closed
including any container.
incompatibilities:
la.Exposure controls/personal protection

Control Parameters
None of the components have assigned exposure limits.
Appropriate Engineering Observe good industrial hygiene practices. Observe occupational exposure
Controls limits and minimize the risk of inhalation of vapors and mist. Mechanical
ventilation or local exhaust ventilation may be required.
General information: Use personal protective equipment as required.
Eye/face protection: Wear goggles/face shield.
Skin Protection
Other: No data available.
local supervisor.
Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated
footwear that cannot be cleaned.
Is.Physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
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Color: Brown
Odor: Mild
pH: 7.0
Flash Point: > 93 °C > 200 °F
Evaporation rate: Slower than Ether
Vapor density: Vapors are heavier than air and may travel along the floor and
in the bottom of containers.
Relative density: 1 .19
Solubility(ies)
Solubility in water: Soluble

!10. Stability and reactivity

reactions:
Incompatible Materials: Strong acids. Strong bases.
111.
Toxicological information

mucus membranes.
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Skin Contact: Moderately irritating to skin with prolonged exposure.
Eye contact: Eye contact is possible and should be avoided.
Inhalation: No data available.
Skin Contact: No data available.
Eye contact: No data available.
Ingestion: No data available.
Oral
Dermal
Inhalation



Carcinogenicity


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In vitro
In vivo


Aspiration Hazard
112.
Ecological information
Ecotoxicity:
Fish
Fish


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Biodegradation
BOD/COD Ratio
Partition Coefficient n-octanol I water (log Kow)

Other adverse effects: No data available.
113.
Disposal considerations

114.
TDG:
Not Regulated
CFR / DOT:
Not Regulated
IMDG:
Not Regulated
j1s.Regulatory information

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Hazard categories
Not listed.




Clean Water Act Section 311 Hazardous Substances (40 CFR 117 .3)

No ingredient regulated by CA Prop 65 present.

No ingredient regulated by NJ Right-to-Know Law present.

No ingredient regulated by MA Right-to-Know Law present.

No ingredient regulated by PA Right-to-Know Law present.

International regulations
Montreal protocol
not applicable
Stockholm convention
not applicable
Rotterdam convention
not applicable
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EUCUD CHEMICAL
Kyoto protocol
not applicable
voe:
Regulatory VOC (less water and 0 g/1
exempt solvent)
voe Method 31 o 0.00 %
Inventory Status:
Australia AICS: All components in this product are listed on or


China Inv. Existing Chemical Substances: All components in this product are listed on or
Korea Existing Chemicals Inv. (KECI): All components in this product are listed on or

Philippines PICCS: All components in this product are listed on or


New Zealand Inventory of Chemicals: All components in this product are listed on or


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Version#: 3.0
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WR. MEADOWS,.
SAFETYDATA SHEET
Page 1 of 2
Product: EVAPRE™ Part Number: 3061000

Product Use: Surface Retarder
I 111 Warning!
ability I 101 May cause skin irritation.
ivityl 101 PRECAUTIONARY STATEMENTS
na I Protection I I I Avoid direct contact.
%by SARA
Chemical Name: CAS Number Weight 313
e reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reautho SARA) and
FR Part 373.65) are identified under the heading"
EYE CONTACT: Flus eyes wit water or ifteen 15 minutes. If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water. Remove contaminated shoes/clothing. If symptoms persist, seek
medical attention.
INHALATION: Not expected to be an exposure route as supplied. If respiratory symptoms develop, seek medical attention.
rt~r$~1Pr
•:-~~
mical, carbon dioxide.
oxide, carbon dioxide, and incomplete combustion products.
NT: Avoid sm
. Dike and co
arked contai

CONDITIONS AND MATERIALS TO AVOID: Strong oxidizing agents.
Page 283 of 516

SAFETYDATA SHEET
Date of Preparation: 9/9/14 Page 2 of 2
EYE CONTACT: Direct contact may cause mild irritation.

SKIN CONTACT: Direct contact may cause slight skin irritation. Prolonged/repeated contact may result in irritation.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness
and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory irritation
include runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function.
OTHER HEALTH EFFECTS: None reco nized.
=-~~~-
~- ~.
~.~;;::·
""'~""'-:;;;;:'"'",.i:;-:-:½;~:::-5:EC::~=_;:~~~~- =
~~~~cc.=.=:a'!~Q:-::R:-:;;l\?l"!".Sfl.:,;:;it:~;[~.
DEGRADABILITY: N/E
HAZARDOUS NON-HAZARDOUS MATERIAL: Not regulated by DOT.

SPECIAL PRECAUTIONS: None recognized.
Dave Carey
Page 284 of 516

Cl•BASF
We create chemistry
Safety Data Sheet

MasterKure CC 250S8
Revision date : 2015/07/13 Page: 1/10
1. Identification
Product identifier used on the label
MasterKure CC 250S8
Recommended use of the chemical and restriction on use
Recommended use*: for industrial and professional users
is not part of
* The "Recommended use" identified for this product is provided solely to comply with a Federal requirement and
specification. The terms of this Safety Data Sheet (SOS) do not create or infer any warranty, express or
the seller's published
implied, including by incorporation into or reference in the seller's sales agreement.
Company:
BASF Canada Inc.
100 Milverton Drive
Mississauga, ON L5R 4H1, CANADA
Telephone: +1289360-1300
Emergency telephone number
CANUTEC (reverse charges): (613) 996-6666

BASF HOTLINE: (800) 454-COPE (2673)
Other means of identification

Chemical family: No data available.
2. Hazards Identification
According to Hazardous Products Regulations (HPR) (SOR/2015-17)
Classification of the product
Flam. Liq. 3 Flammable liquids

Skin Corr./lrrit. 2 Skin corrosion/irritation
Eye Dam./lrrit. 2A Serious eye damage/eye irritation
Muta. 1B Germ cell mutagenicity
Care. 1B Carcinogenicity
Repr. 2 (fertility) Reproductive toxicity
STOT SE 3 (Vapours may cause Specific target organ toxicity - single exposure
drowsiness and
dizziness.)
Page 285 of 516

Safety Data Sheet
MasterKure CC 25058
STOT SE 3 (irritating to Specific target organ toxicity - single exposure
respiratory system)
STOT RE 1 Specific target organ toxicity - repeated
exposure
Aquatic Acute 2 Hazardous to the aquatic environment - acute
Aquatic Chronic 2 Hazardous to the aquatic environment - chronic
Label elements
Signal Word:
Danger
Hazard Statement:
H226 Flammable liquid and vapour.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H335 May cause respiratory irritation.
H361 Suspected of damaging fertility.
H350 May cause cancer.
H340 May cause genetic defects.
H372 Causes damage to organs (Central nervous system) through prolonged
or repeated exposure.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements (Prevention):

P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P271 Use only outdoors or in a well-ventilated area.
P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P260 Do not breathe dust/gas/mist/vapours.
P202 Do not handle until all safety precautions have been read and
understood.
P243 Take precautionary measures against static discharge.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P270 Do not eat, drink or smoke when using this product.
P264 Wash with plenty of water and soap thoroughly after handling.
P240 Ground/bond container and receiving equipment.
P242 Use only non-sparking tools.
Precautionary Statements (Response):
Page 286 of 516

Safety Data Sheet
MasterKure CC 2505B
P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.
P362 + P364 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for
extinction.
Precautionary Statements (Storage):

P233 Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.
Hazards not otherwise classified
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
3. Composition / Information on Ingredients
According to Hazardous Products Regulations (HPR) (SOR/2015-17)
CAS Number Weight% Chemical name

8052-41-3 >= 20.0 - < 50.0% Stoddard solvent
64742-95-6 >= 20.0 - < 25.0% solvent naphtha
95-63-6 >= 15.0 - < 20.0% 1,2,4-trimethylbenzene
64742-82-1 >= 7.0 - < 15.0% Naphtha (petroleum), hydrodesulfurized heavy
108-67-8 >= 1.0 - < 3.0% rnesitylene
1330-20-7 >= 0.3 - < 3.0% Xylene
25340-17-4 >= 0.3 - < 1.0% Benzene, diethyl-
25550-14-5 >= 0.3 - < 3.0% ethyltoluene
91-20-3 >= 0.1 - < 1.0% naphthalene
25551-13-7 >= 0.0 - < 5.0% Benzene, trimethyl-
Description of first aid measures
General advice:
First aid personnel should pay attention to their own safety. Immediately remove contaminated
clothing.
Page 287 of 516

Safety Data Sheet
MasterKure CC 250S8
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
If on skin:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances
should organic solvent be used. If irritation develops, seek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
If swallowed:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
Hazards: No applicable information available.
Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:

foam, water spray, dry powder, carbon dioxide
Unsuitable extinguishing media for safety reasons:

water jet
Special hazards arising from the substance or mixture

Hazards during fire-fighting:
carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
Advice for fire-fighters

Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire,
keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do
not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed
of in accordance with official regulations.
Page 288 of 516

Safety Data Sheet
MasterKure CC 2505B
Personal precautions, protective equipment and emergency procedures

Do not breathe vapour/aerosol/spray mists. Wear eye/face protection. If exposed to high vapour
concentration, leave area immediately. Use personal protective clothing. Handle in accordance with
good building materials hygiene and safety practice.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods and material for containment and cleaning up

For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of
contaminated material as prescribed.
For large amounts: Pump off product.
Precautions for safe handling

Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures
necessary provided product is used correctly.
Conditions for safe storage, including any incompatibilities

No applicable information available.
Suitable materials for containers: High density polyethylene (HOPE)
Further information on storage conditions: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Protect from direct sunlight.
Protect from temperatures below: 5 °C
The packed product must be protected from temperatures below the indicated one.
8. Exposure Controls/Personal Protection
Components with occupational exposure limits

naphthalene OSHA PEL PEL 10 ppm 50 mg/m3 ; STEL value 15 ppm
75 mg/m3 ; TWA value 10 ppm 50 mg/m3 ;
ACGIH TLV TWA value 10 ppm ; STEL value 15 ppm ;
Skin Designation ;
The substance can be absorbed through the skin.
1,2,4-trimethylbenzene OSHA PEL TWA value 25 ppm 125 mg/m3

ACGIH TLV TWA value 25 ppm
mesitylene OSHA PEL TWA value 25 ppm 125 mg/m3

ACGIH TLV TWA value 25 ppm
Xylene OSHA PEL PEL 100 ppm 435 mg/m3 ; STEL value 150
ppm 655 mg/m3 ; TWA value 100 ppm 435
mg/m3 ;
ACGIH TLV TWA value 100 ppm ; STEL value 150 ppm ;
Page 289 of 516

Safety Data Sheet
MasterKure CC 2505B
Stoddard solvent OSHA PEL PEL 500 ppm 2,900 mg/m3 ;
ACGIH TLV TWA value 100 ppm ;
Benzene, trimethyl- OSHA PEL TWA value 25 ppm 125 mg/m3

Naphtha (petroleum), OSHA PEL PEL 500 ppm 2,900 mg/m3 ; PEL 100 ppm
hydrodesulfurized heavy 400 mg/m3 ; TWA value 100 ppm 400 mg/m3
Advice on system design:


When workers are facing concentrations above the occupational exposure limits they must use
appropriate certified respirators.
Hand protection:
Wear chemical resistant protective gloves., Manufacturer's directions for use should be observed
because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (chemical goggles).
Body protection:
Body protection must be chosen based on level of activity and exposure.
General safety and hygiene measures:

Do not inhale gases/vapours/aerosols. Avoid contact with the skin, eyes and clothing. Avoid
exposure - obtain special instructions before use. Handle in accordance with good building materials
hygiene and safety practice. Wearing of closed work clothing is recommended. When using, do not
eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be
inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).
Form: liquid
Odour: solvent-like
Odour threshold: No applicable information available.
Colour: clear
pH value: The product has not been tested.
Melting point: No applicable information available.
Boiling point: 137.22-171.11 °C
Sublimation No applicable information available.
temperature:
Flash point: 42.78 °C (ASTM D3278)
Flammability: not determined
Lower explosion limit: 0.9 %(V)
Upper explosion limit: 7.0 %(V)
Vapour pressure: The product has not been tested.
Density: 0.9046 g/cm3
( 20 °C)
Relative density: No applicable information available.
Page 290 of 516

Safety Data Sheet
MasterKure CC 2505B
Bulk density: not applicable
Vapour density: Heavier than air.
Partitioning coefficient n- not applicable
octanol/water (log Pow):
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Viscosity, dynamic: No applicable information available.
Viscosity, kinematic: 37 mm2/s
( 40 °C)
Solubility in water: insoluble
Solubility (quantitative): No applicable information available.
Solubility (qualitative): No applicable information available.
Evaporation rate: No applicable information available.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Oxidizing properties:
Based on its structural properties the product is not classified as oxidizing.
Chemical stability
Possibility of hazardous reactions

Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
oxidizing agents
Hazardous decomposition products
Decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: No applicable information available.
Page 291 of 516

Safety Data Sheet
MasterKure CC 25058
Oral
Inhalation
Dermal
Assessment other acute effects

Assessment of STOT single:
A single exposure may have relevant toxic effects on organs. Causes temporary irritation of the
respiratory tract. Possible narcotic effects (drowsiness or dizziness).
Irritation / corrosion
Assessment of irritating effects: Eye contact causes irritation. Skin contact causes irritation.
Sensitization
Assessment of sensitization: No applicable information available.
Aspiration Hazard
Aspiration hazard May be harmful if swallowed and enters airways.
Chronic Toxicity/Effects

Assessment of repeated dose toxicity: Repeated exposure to small quantities may affect certain
organs.
Carcinogenicity
Information on: ethylbenzene

Assessment of carcinogenicity: Indication of possible carcinogenic effect in animal tests. The effect is
caused by an animal specific mechanism that has no human counter part. A clear indication of an
increased risk of cancer in humans has so far not been shown. /ARC (International Agency for
Research on Cancer) has classified this substance as group 28 (The agent is possibly carcinogenic
to humans).
/ARC (International Agency for Research on Cancer) has classified this substance as group 28 (The
agent is possibly carcinogenic to humans). NTP listed carcinogen
Information on: Naphtha (petroleum}, hydrodesulfurized heavy

Assessment of carcinogenicity: The substance caused cancer in animal studies. The product has not
been tested. The statement has been derived from the properties of the individual components.
Information on: naphthalene

Assessment of carcinogenicity: In Jong-term studies in rats and mice in which the substance was
given by inhalation, a carcinogenic effect was observed. EU-classification The substance was
classified as a group 3 carcinogen by the German MAK-Commission (substances for which a
suspicion of a carcinogenic potential exists). /ARC (International Agency for Research on Cancer)
has classified this substance as group 28 (The agent is possibly carcinogenic to humans).
/ARC (International Agency for Research on Cancer) has classified this substance as group 28 (The
agent is possibly carcinogenic to humans).
Page 292 of 516

Safety Data Sheet
MasterKure CC 2505B
Other Information
The product has not been tested. The statement has been derived from the properties of the
individual components.
Symptoms of Exposure
The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11.
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
Acutely toxic for aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
Additional information
Other ecotoxicological advice:

Do not discharge product into the environment without control. The product has not been tested. The
statements on ecotoxicology have been derived from the properties of the individual components.
Waste disposal of substance:

Dispose of in accordance with national, state and local regulations. Residues should be disposed of
in the same manner as the substance/product. Do not discharge into drains/surface
waters/groundwater.
Container disposal:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
14. Transport Information
Land transport
TOG
Hazard class: 3
Packing group: Ill
ID number: UN 1263
Hazard label: 3
Sea transport
IMDG
Hazard class: 3
Packing group: Ill
ID number: UN 1263
Page 293 of 516

Safety Data Sheet
MasterKure CC 2505B
Hazard label: 3
Marine pollutant: NO
Air transport
IATA/ICAO
Hazard class: 3
Packing group: Ill
ID number: UN 1263
Hazard label: 3
15. Regulatory Information
Federal Regulations
Registration status:
Chemical DSL, CA released; restriction on use/ listed
CEPA, Significant New Activity Restriction (SNAc)

Not for use in products designed to be used by children under the age of 7.
SNAc 12541
SDS Prepared by:

BASF NA Product Regulations
SOS Prepared on: 2015/07/13
We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.
END OF DATA SHEET
Page 294 of 516

SAFETY DAT A SHEET
MINERAL SPIRITS RULE 66 (<8% AROMATICS)

Product ID: AA100901
Revised: 10-01-2013
Replaces: 09-07-2011
1. IDENTIFICATION
Product Name: MINERAL SPIRITS RULE 66 (<8% AROMATICS)

Synonyms: Mineral Spirits 75
CAS Number: MIXTURE
Recommended Use: No data available.
Restrictions on Use: No data available.
Hydrite Chemical Co. EMERGENCY RESPONSE NUMBERS:
300 N. Patrick Blvd. 24 Hour Emergency#: (414) 277-1311
Brookfield, WI 53008-0948 CHEMTREC Emergency #: (800) 424-9300
(262) 792-1450
2. HAZARD S IDENTIFICATION
Signal Word: Danger

GHS Classification: Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Carcinogenicity Category 2
Specific Target Organ Systemic Toxicity (STOT) - Repeated Exposure
Category 2
Flammable Liquid Category 3
Acute Toxicity - Inhalation Vapour Category 3
Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 3
Hazard Statements: Flammable liquid and vapour.
Causes skin irritation.
Toxic if inhaled.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May cause damage to organs (nervous and respiratory system) through
prolonged or repeated exposure (by inhalation).
Prevention: Obtain special instructions before use.
Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
Ground and bond container and receiving equipment.
Use explosion-proof electrical, ventilating, and lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust, fume, gas, mist, vapors or spray.
Use only outdoors or in a well-ventilated area.
Page 1 of 9
Page 295 of 516

ProductID:AA100901
Wear gloves, eye and face protection and protective clothing.
Use personal protective equipment as required.
Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water.
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice or attention.
Call a POISON CENTER or doctor if you feel unwell.
Get medical advice or attention if you feel unwell.
Specific treatment (see First Aid on SDS or on this label).
If skin irritation occurs: Get medical advice or attention.
If eye irritation persists: Get medical advice or attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use appropriate extinguishing media - See Section 5 on SDS.
Storage: Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store in a secure manner.
Disposal: Dispose of in accordance with local, regional and international regulations.
Hazards Not Otherwise Classified: Chronic effects of ingestion and subsequent aspiration into the
lungs may cause pneumatocele (lung cavity) formation and
chronic lung dysfunction. May cause damage to the following
organs: kidneys, lungs, liver, mucous membranes, upper
respiratory tract, skin, CNS, eye, lens or cornea. May be harmful
or fatal if swallowed and enters airways. Breathing high
concentrations can cause irregular heartbeats which may be
fatal.
. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS Number % by Wt.

Distillates, Petroleum, Hydrotreated Light 64742-47-8 < = 100 %
Cumene 98-82-8 < 1.0 %
Note: This product may be composed, in whole or in part, of any the following refinery streams: Distillates
(petroleum), hydrotreated light (CAS No. 64742-47-8). Heavy hydrodesulfurized naphtha (petroleum)
(CAS No. 64742-82-1).
4. FIRST-AID MEASURES
Eye Contact: If in eyes: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids
open. Tilt head to avoid contaminating unaffected eye. Get immediate medical attention. Remove contact lens if
easy to do. Do not use eye ointment.
Skin Contact: If on skin: Immediately flush skin with plenty of water while removing contaminated clothing and
shoes. Do not reuse clothing or shoes until cleaned. If irritation develops or persists, get medical attention. If skin
surface is not damaged, wash thoroughly with soap and water. If skin surface is damaged, apply a clean
dressing and seek medical attention. Do not use ointments. Discard contaminated leather articles such as shoes
and belt.
Inhalation: If inhaled: Remove to fresh air. If breathing is difficult, administer oxygen. If not breathing, give
artificial respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY.
Ingestion: If swallowed: Call a physician immediately. DO NOT induce vomiting unless directed to do so by a
physician. Never give anything by mouth to an unconscious person. If vomiting occurs spontaneously, keep head
Page: 2 of 9
Page 296 of 516

below hips to prevent aspiration of liquid into the lungs. If victim is drowsy or unconscious, place on the left side
with head down. Do not leave victim unattended.
Note to Physicians:
Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty in
breathing develops, evaluate for upper respiratory tract inflammation, bronchitis, and pneumonitis. Administer
supplemental oxygen with assisted ventilation, as required. If ingested, this material presents a significant
aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated
charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by
placement of the body in a Trendelenburg and left lateral decubitus position.
Most Important Symptoms/Effects:
Eye Contact: Causes moderate irritation. This product can cause transient, mild eye irritation with short-term
contact with liquid sprays or mists. Symptoms may include: stinging. watering. redness. swelling.
Skin Contact: Causes moderate irritation. This product can cause mild, transient skin irritation with short-term
exposure. The degree of irritation will depend on the amount of material that is applied to the skin and the speed
and thoroughness that it is removed. Symptoms may include: redness. itching. burning. Prolonged and repeated
contact with skin can cause defatting and drying of the skin which may result in skin irritation and dermatitis.
Skin Absorption: No data available.
Inhalation: Causes moderate irritation. Vapors or mists may irritate: throat. lungs. respiratory tract. May cause:
central nervous system depression. nausea. headache. dizziness. fatigue. drowsiness. unconsciousness.
Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal.
Ingestion: Causes moderate irritation. May cause irritation of the: mouth. throat. esophagus. It can be readily
absorbed by the stomach and intestinal tract. Symptoms may include: burning sensation. nausea. vomiting.
dizziness. staggering gait. drowsiness. unconsciousness. delirium. other central nervous system effects. Due to
its light viscosity, there is a danger of aspiration into the lungs during vomiting. Aspiration can result in severe
lung damage or death.
5. FIRE-FIGHTING MEASURES
Extinguishing Media: Water spray. Water fog. Foam. Dry chemical. Carbon dioxide. Water fog and spray are
effective in cooling containers and adjacent structures but might cause frothing and/or may not achieve
extinquishment. DO NOT USE: Direct water stream.
Fire Fighting Methods: Evacuate area of unprotected personnel. Wear protective clothing including NIOSH-
approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and
decomposition products. Use water spray to cool fire-exposed containers and disperse vapors. Avoid water
accumulation. Product may reignite and burn on the water's surface. If container is not properly cooled, it can
rupture in the heat of a fire. Do not use direct water stream. May spread fire. Run-off from fire control may cause
pollution.
Fire and Explosion Hazards: FLAMMABLE LIQUID. Vapors are heavier than air. Vapors may settle in low or
confined areas, or travel long distances along the ground or surface to an ignition source where they may ignite,
flashback, or explode. Keep away from heat, sparks, flames or other sources of ignition (e.g., static electricity,
pilot lights, mechanical/electrical equipment). PROCESS HAZARD: Sudden release of hot organic chemical
vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of
air into hot equipment under a vacuum, may result in ignitions without the presence of obvious ignition sources.
Published "autoignition" or "ignition" temperature values cannot be treated as safe operating temperatures in
chemical processes without analysis of the actual process conditions. Any use of this product in elevated-
temperature processes should be thoroughly evaluated to establish and maintain safe operating conditions.
Hazardous Combustion Products: Carbon oxides. Products of incomplete combustion. Smoke. Fumes.
II6. ACCIDENTAi:.. RELEASE MEASURES
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ProductID:AA100901
Spill Clean-Up Procedures: FLAMMABLE LIQUID. Eliminate all sources of ignition. Evacuate unprotected
personnel from area. Maintain adequate ventilation. Follow personal protective equipment recommendations
found in Section 8. Never exceed any occupational exposure limit. Shut off source of leak if safe to do so. A
vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor, but may not prevent
ignition in closed spaces. Use non-sparking tools and equipment. Contain spill, place into dn..imsfor proper
disposal. Soak up residue with non-flammable absorbent material. DO NOT use sawdust or other cellulose-type
material. Place in non-leaking containers for immediate disposal. Avoid direct discharge to sewers and surface
waters. Notify authorities if entry occurs. Prevent entry into basements, low areas, or confined areas. Flush
remaining area with water to remove trace residue and dispose of properly.
NDLING AND STORAGE
Handling: Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Do not swallow. Avoid
breathing vapors, mists, or dust. Do not eat, drink, or smoke in work area. Wash thoroughly after handling.
Empty containers retain product residue (vapor, dust, or liquid) and can be dangerous. DO NOT pressurize, cut,
weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other
source of ignition. They may explode and cause injury or death. Use appropriate grounding and bonding
practices. Always open containers slowly to allow any excess pressure to vent.
Storage: FLAMMABLE LIQUID. Store in a cool, well ventilated area away from all sources of ignition and out of
direct sunlight. Store in a dry location away from heat. Keep away from incompatible materials. Keep containers
tightly closed. Do not store in unlabeled or mislabeled containers. Static electricity may accumulate and create a
fire hazard. Ground fixed equipment. Bond and ground transfer containers and equipment. See Section 10 for
incompatible materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OSHA Exposure Guidelines:

Component Limits
Cumene 50 ppm TWA; 245 mg/m3 TWA; (Skin)
ACGIH Exposure Guidelines:
Component Limits
Distillates, Petroleum, Hydrotreated 200 mg/m3 TWA (application restricted to conditions in which there are
Light negligible aerosol exposures); (Skin)
Cumene 50 ppm TWA
Note:
* MANUFACTURER RECOMMENDED EXPOSURE LIMIT: TWA of 100 ppm for Petroleum Distillate - Stoddard
Solvent. S = Skin notation.
Engineering Controls: Local exhaust ventilation, process enclosures, or other engineering controls are
imperative when handling or using this product to avoid overexposure. Use explosion-proof ventilation
equipment. Maintain adequate ventilation. Do not use in closed or confined spaces. Avoid creating dust or mist.
Keep levels below exposure limits. To determine exposure levels, monitoring should be performed regularly.
Eye/Face Protection: Wear safety glasses with side shields while handling this product. Wear additional eye
protection such as chemical safety goggles when the possibility exists for eye contact with splashing or spraying
liquid, or airborne material. Do not wear contact lenses.
Skin Protection: Prevent contact with this product. Wear gloves and protective clothing depending on condition
of use. Protective gloves: Chemical-resistant. Viton (R). Heavy nitrile rubber.
Respiratory Protection: Respiratory protection must be worn if ventilation does not eliminate symptoms or keep
levels below recommended exposure limits. If exposure limits are exceeded, wear: NIOSH-Approved respirator.
NIOSH-Approved air-purifying respirator with: Organic vapor cartridge. NIOSH-Approved Supplied Air Respirator
(SAR). NIOSH-Approved self-contained breathing apparatus. DO NOT exceed limits established by the
respirator manufacturer. All respiratory protection programs must comply with OSHA 29 CFR 1910.134 and ANSI
Page: 4 of9
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Z88.2 requirements and must be followed whenever workplace conditions require a respirator's use. NIOSH-
Approved organic respirator. NIOSH-Approved positive pressure supplied air respirator.
Other Protective Equipment: Eye-wash station. Safety shower. Rubber apron. Rubber boots. Protective
clothing.
General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work shift.
Good manufacturing practices require gross amounts of any chemical be removed from skin as soon as practical,
especially before eating or smoking.
ND CHEMICAL PROPERTIES
Physical State: Liquid.

Color: Transparent. Colorless.
Odor: Characteristic hydrocarbon solvent odor.
Odor Threshold: N.D.
pH: N.A.
Freezing Point (deg. F): N.D.
Melting Point (deg. F): N.D.
Initial Boiling Point or Boiling Range: 315 - 394 °F
Flash Point: 110 °F
Flash Point Method: TCC. ASTM D 56.
Evaporation Rate (nBuAc = 1): N.D.
Flammability (solid, gas): N.D.
Lower Explosion Limit: - 0.5 %
Upper Explosion Limit: - 6 %
Vapor Pressure (mm Hg): 2@ 20 C
Vapor Density (air=1): > 1
Specific Gravity or Relative Density: 0.78
Solubility in Water: Very slightly soluble in cold water (< 0.1 % w/w)
Partition Coefficient (n-octanol/water): N.D.
Autoignition Temperature: No Data
Decomposition Temperature: N.D.
Viscosity: N.D.
% Volatile (wt%): 100
voe (wt%): 1oo
voe (lbs/gal): 783 g/I (w/v)
Fire Point: N.D.
II10. STABILITY AND REACTIVITY

Chemical Stability: Stable under normal conditions.
Possibility of Hazardous Reactions: Hazard.9us polymerization will not occur under normal conditions.
Conditions to Avoid: Avoid contact with heat, sparks, electric arcs, other hot surfaces, and open flames. Avoid
other ignition sources. Keep away from strong oxidizing conditions and agents.
Incompatible Materials: Strong oxidizing agents. Strong acids. Strong alkalies.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Smoke. Fumes. Unburned
hydrocarbons.
II11. TOXICOLOGICAL INFORMATION

Component Oral LD50 Dermal LD50 Inhalation LC50
Disti+lmes, Petroleum, Hydrotreated Rat: > 5000 mg/kg Rabbit: > 2000 mg/kg 4H Rat: > 5.2 mg/L
Page: 5 of9
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Light
Cumene Rat: 1400 mg/kg Rabbit: 12,300 µL/kg No Data
Acute Toxicity Estimate (ATE):
Inhalation Vapor: 5.2261 mg/L
Routes of Exposure: Eyes. Skin. Inhalation. Ingestion. Absorption.
Eye Contact: Causes moderate irritation. This product can cause transient, mild eye irritation with short-term
contact with liquid sprays or mists. Symptoms may include: stinging. watering. redness. swelling.
Skin Contact: Causes moderate irritation. This product can cause mild, transient skin irritation with short-term
exposure. The degree of irritation will depend on the amount of material that is applied to the skin and the speed
and thoroughness that it is removed. Symptoms may include: redness. itching. burning. Prolonged and repeated
contact with skin can cause defatting and drying of the skin which may result in skin irritation and dermatitis.
Skin Absorption: No data available.
Inhalation: Causes moderate irritation. Vapors or mists may irritate: throat. lungs. respiratory tract. May cause:
central nervous system depression. nausea. headache. dizziness. fatigue. drowsiness. unconsciousness.
Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal.
Ingestion: Causes moderate irritation. May cause irritation of the: mouth. throat. esophagus. It can be readily
absorbed by the stomach and intestinal tract. Symptoms may include: burning sensation. nausea. vomiting.
dizziness. staggering gait. drowsiness. unconsciousness. delirium. other central nervous system effects. Due to
its light viscosity, there is a danger of aspiration into the lungs during vomiting. Aspiration can result in severe
lung damage or death.
Medical Conditions Aggravated by Exposure to Product: Skin disorders. Respiratory system disorders. Liver
disorders. Kidney disorders. Central nervous system disorders.
Other: Chronic effects of ingestion and subsequent aspiration into the lungs may cause pneumatocele (lung
cavity) formation and chronic lung dysfunction. Reports have associated repeated and prolonged occupational
overexposure to solvents with irreversible brain and nervous system damage (sometimes referred to as "Solvent
or Painter's Syndrome").
Cancer Information:
This product contains 0.1 % or more of the following chemicals listed by NTP, IARC or OSHA as known or
possible carcinogens:
Cumene
Distillates (petroleum), hydrotreated light:
IRRITATION:
Primary dermal irritation studies (four hour exposure) in rabbits utilizing mineral spirits containing less than 2%
aromatics resulted in slight to moderate skin irritation. In humans, mineral spirits have produced slight to
moderate skin irritation particularly with evaporation from the skin is prevented. Animal studies have
demonstrated that mineral spirits produced mild respiratory tract irritation at elevated concentrations. Also,
sensory respiratory tract irritation was evident by reduced breathing rates in the test animals in certain stidies.
SENSITIZATION:
In animal studies utilizing mineral spirits containing up to 18%, aromatics skin sensitive is not evident.
REPEAT DOSE/TARGET ORGAN TOXICITY:
The most common effects observed in repeated dose animal studies with mineral spirits are kidney changes that
are consistent with an alpha 2u-globulin-medicated process that is not regarded as relevant to humans. The
kidney damage occured only in male rats and appeared to involve both the tubules and glomerull. Certain
studies have reported effects in the liver as well as hematological or urine chemistry changes. In general, these
effects have not to been shown to be dose-related.
NERVOUS SYSTEM EFFECTS:
In animal studeis utilizing mineral spirits containing up to 22% aromatics indicated that the acute central nervous
system effects are reversible. Based on exisiting animal studies, the potential for persistent effects is not clear. In
certain repeated dose animal studies have changes were reported in behavior, neurochemistry and sensory
evoked potentials which may be irreversible. Repeated exposure to elevated concentrations of hydrocarbon
Page: 6 of9
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solvents can produce a variety of transient CNS effects (e.g., dizziness, headache, narcosis, etc.).
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
There were no treatment-related effects on pregnancy rate, mortality or gross post mortem observations in
animal studies utilizing mineral spirits containing less than 2% aromatics.
GENOTOXICITY:
In vivo and in vitro studies on mineral spirits containing up to 22% aromatics indicate that these products are not
genotoxic.
CARCINOGENICITY:
The National Toxicology Program (NTP) conducted two-year carcinogenicity studies in rats and mice with
Stoddard Solvent IIC (less than 2% aromatics). The studies indicated that there was some evidience of
carcinogenic activity in male rats (adrenal medulla neoplasms and renal tubule adenoma) but no evidence of
carcinogenic activity in female rats. Further, there was equivocal evidence of carcinogenic activity in female mice
(hepatocellular adenoma) but no evidence of carcinogenic activity in male mice. A low carcinogenic potential is
suggested by a lack of genotoxic potential identified in in vivo and in vitro genetic toxicity tests (with and without
metabolic activation).
Trimethylbenzenes, all isomers:
Studies of Workers:
Levels of total hydrocarbon vapors present in the breathing atmosphere of these workers
ranged from 10 to 60 ppm. The TCLo for humans is 10 ppm, with somnolence and
respiratory tract irritation noted.
Studies in Laboratory Animals:
In inhalation studies with rats, four of ten animals died after exposures of 2400 ppm for 24
hours. An oral dose of 5 ml/kg resulted in death in one of ten rats. Minimum lethal
intraperitoneal doses were 1.5 to 2.0 ml/kg in rats and 1.13 to 12 ml/kg in guinea pigs.
Mesitylene (1, 3, 5 Trimethylbenzene) inhalation at concentrations of 1.5, 3.0, and 6.0 mg/L
for six hours was associated with dose-related changes in white blood cell counts in rats. No
significant effects on the complete blood count were noted with six hours per day exposure
for five weeks, but elevations of alkaline phosphatase and SGOT were observed. Central
nervous system depression and ataxia were noted in rats exposed to 5,100 to 9,180 ppm for
two hours.
Cumene:
Effects from Acute Exposure:
Overexposure to cumene may cause upper respiratory tract irritation and severe CNS
depression.
Effects from Prolonged or Repeated Exposure:
Studies in laboratory animals indicate evidence of adverse effects on the kidney and adrenal
glands following high level exposure. The relevance of these findings to humans is not clear
at this time. IARC has classified cumene as "possibly carcinogenic to humans" (Group 2B).
12. ECOLOGICAL INFORMATION
Ecotoxicological Information: This mixture contains components that are potentially toxic to freshwater and
saltwater ecosystems.
Chemical Fate Information: This product will normally float on water. Components will evaporate rapidly. This
material may be harmful to aquatic organisms and may cause long term adverse effects in the aquatic
environment. The octanol-water partition coefficient (log Kow) for this product is expected to be in the range of
2.1 to 5.
~ 13. DISPOSAL CONSIDERATIONS

Hazardous Waste Number: D001 and D018
Disposal Method: Dispose of in a permitted hazardous waste management facility following all local, state and
federal regulations. Reclaim (recycle) solvent. Regulations may vary in different locations. Waste characterizations
and compliance with applicable laws are the responsibility solely of the waste generator. DO NOT pressurize, cut,
Page: 7 of 9
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weld, solder, drill, grind or expose empty containers to heat, flame, sparks or other sources of ignition. Since
emptied containers retain product residue, follow label warnings even after container is emptied.
II14. TRANSPORT INFORMATION

DOT (Department of Transportation):
Identification Number: UN1268

Proper Shipping Name: PETROLEUM DISTILLATES, N.O.S. (NAPHTHA SOLVENT)
Hazard Class: 3
Packing Group: Ill
Label Required: FLAMMABLE
Reportable Quantity (RQ): 5000# (Cumene)
1115.
REGULATORY INFORMATION
TSCA Inventory Status: All components of this product are on the TSCA Inventory or are exempt from TSCA
Inventory requirements.
SARA Title Ill Section 311/312 Category Hazards:
Immediate (Acute) Delayed (Chronic) Fire Hazard Pressure Release Reactive
Yes Yes Yes No No
Regulated Components: CAS CERCLA SARA SARA U.S. WI Prop
Component Number RQ EHS 313 HAP HAP 65
Cumene 98-82-8 Yes No Yes Yes Yes Yes
*Prop 65 - May Contain the Following Trace Components:
Ethylbenzene
Benzene
Toluene
Naphthalene
Clean Water Act:
This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of
1990 (OPA). Discharge or spills which produce a visible sheen on waters of the United States, their adjoining
shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center
at (800)424-8802.
1116.
OTHER INFORMATION
Hazard Rating System

Health: 1*
Flammability: 2
Reactivity: 0
* = Chronic Health Hazard
NFPA Rating System
Health: 1
Flammability: 2
Reactivity: 0
Special Hazard: None
MSDS Abbreviations
N.A. = Not Applicable
N.D. = Not Determined
HAP = Hazardous Air Pollutant
voe = Volatile Organic Compound
C = Ceiling Limit
Page: 8 of9
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N.E./Not Estab. = Not Established
MSDS Prepared by: CSH
Reason for Revision: New format.
Revised: 10-01-2013
Replaces: 09-07-2011
The data in this Safety Data Sheet relates to the specific material designated and does not relate to its use
in combination with any other material or process. The data contained is believed to be correct. However,
since conditions of use are outside our control it should not be taken as warranty or representation for
which HYDRITE CHEMICAL CO. assumes legal responsibility. This information is provided solely for your
consideration, investigation, and verification.
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Page 304 of 516
A Safety Data Sheet
Revision Date 11/11/2013 Print Date 11/22/2013
1. Identification
Product name Sika® Rugasol® S
Supplier Sika Corporation
Address 201 Polito Avenue

Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone (201) 933-8800
Telefax (201) 804-1076
Emergency telephone CHEMTREC: 800-424-9300

INTERNATIONAL: 703-527-3887
ehs@sika-corp.com
Recommended use of the For further information, refer to the product technical data
chemical and restrictions on sheet.
use
2. Hazards identification
GHS Classification
Not a hazardous substance or mixture.
GHS Label element

See Section 11 for more detailed information on health effects and symptoms.
There are no ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence
require reporting in this section.
4. First aid measures
If inhaled Move to fresh air.
In case of skin contact Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
In case of eye contact Flush eyes with water as a precaution.
1/8
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£ Safety Data Sheet
Remove contact lenses.

Keep eye wide open while rinsing.
If swallowed Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Most important symptoms No known significant effects or hazards.

and effects, both acute and
delayed
See Section 11 for more detailed information on health effects
and symptoms.
Protection of first-aiders No hazards which require special first aid measures.
Notes to physician Treat symptomatically.
Suitable extinguishing media Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Specific extinguishing Collect contaminated fire extinguishing water separately. This

methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
for fire-fighters
Environmental precautions Local authorities should be advised if significant spillages

Methods and materials for Wipe up with absorbent material (e.g. cloth, fleece).
containment and cleaning up Keep in suitable, closed containers for disposal.
Advice on safe handling For personal protection see section 8.

No special handling advice required.
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage Keep container tightly closed in a dry and well-ventilated
place.
Store in accordance with local regulations.
Materials to avoid no data available
Page 306 of 516

A Safety Data Sheet
Contains no substances with occupational exposure limit values.
Engineering measures Use of adequate ventilation should be sufficient to control

worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any
recommended or statutory limits.

Respiratory protection Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk
assessment indicates this is necessary.
The filter class for the respirator must be suitable for the
maximum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when handling
the product. If this concentration is exceeded, self-contained
breathing apparatus must be used.
Hand protection
Remarks Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary.
Eye protection Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.
Skin and body protection Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to
the specific work-place.
Hygiene measures Wash hands before breaks and immediately after handling the
product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Appearance liquid
Color green
Odor characteristic
Odor Threshold no data available
Flash point ca.> 212 °F (> 100 °C)
Ignition temperature not applicable
Decomposition temperature no data available
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.A. Safety Data Sheet
Lower explosion limit (Vol%) no data available
Upper explosion limit (Vol%) no data available
Flammability (solid, gas) no data available
Oxidizing properties no data available
Autoignition temperature no data available
pH ca. 6.5
at
73 °F (23 °C)
Melting point/range / no data available

Freezing point
Boiling point/boiling range no data available
Vapor pressure no data available
Density ca.1.09 g/cm3

at 73 °F (23 °C)
Water solubility Note: completely soluble
Partition coefficient: n- no data available

octanol/water
Viscosity, dynamic no data available
Viscosity, kinematic ca.> 20.5 mm2/s

at 104 °F (40 °C)
Relative vapor density no data available
Evaporation rate no data available
Burning rate no data available
Volatile organic compounds < 10 g/1

(VOC) content
Reactivity No dangerous reaction known under conditions of normal use.
Chemical stability The product is chemically stable.
Possibility of hazardous Stable under recommended storage conditions.

reactions
Conditions to avoid no data available
Incompatible materials no data available
Page 308 of 516

A Safety Data Sheet
Acute toxicity
Product
Acute oral toxicity no data available
Acute inhalation toxicity no data available
Acute dermal toxicity no data available
Product
no data available

Product
no data available

Product
no data available

Product
Mutagenicity no data available
Carcinogenicity
Product
Carcinogenicity : no data available
IARC not applicable

NTP not applicable
Reproductive Toxicity/Fertility
Product
Reproductive toxicity : no data available
Reproductive Toxicity/Development/T eratogenicity

Product
Teratogenicity no data available
$TOT-single exposure
Product
Assessment: no data available
5/8
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.A. Safety Data Sheet
Product
Aspiration toxicity
Product
no data available
Other information Do not empty into drains; dispose of this material and its
container in a safe way.
Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal methods
Waste from residues Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

DOT
Not dangerous goods
IATA
Not dangerous goods
IMDG
Not dangerous goods
Special precautions for user

no data available
not applicable
TSCA list All chemical substances in this product are either listed on the
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Page 310 of 516

A Safety Data Sheet
exemption.

This material does not contain any components with a CERCLA RQ.
SARA304 Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : No SARA Hazards
SARA302 SARA 302: No chemicals in this material are subject to the

reporting requirements of SARA Title 111,
Section 302.
SARA 313 SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title 111,
Section 313.
Clean Air Act
Ozone-Depletion This product neither contains, nor was manufactured with a

Potential Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A+ B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
California Prop 65 This product does not contain any chemicals known to the State
of California to cause cancer, birth, or any other reproductive
defects.
16. Other information
HMIS Classification
Personal Protection 0
718
Page 311 of 516

,A_ Safety Data Sheet
Caution: HMIS® rating is based on a 0-4 rating scale, with O representing minimal hazards or
risks, and 4 representing significant hazards or risks. Although HMIS® rating is not required
on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® rating
is to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the
National Paint & Coatings Association (NPCA}. Please note HMIS® attempts to convey full
health warning information to all employees.
Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika
Corporation ("Sika") product identified and described herein. This information is not intended
to address, nor does it address the use or application of the identified Sika product in
combination with any other material, product or process. All of the information set forth herein
is based on technical data regarding the identified product that Sika believes to be reliable as
of the date hereof. Prior to each use of any Sika product, the user must always read and
follow the warnings and instructions on the product's current Product Data Sheet, product
label and Safety Data Sheet for each Sika product, which are available at web site and/or
telephone number listed in Section 1 of this SOS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY

ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT
BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON
ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201-933-8800.
Material number: 188659
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A Safety Data Sheet
1. Identification
Product name SikaFitm®
Supplier Sika Corporation
Address 201 Polito Avenue

Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone (201) 933-8800
Telefax (201) 804-1076
Emergency telephone CHEMTREC: 800-424-9300

INTERNATIONAL: 703-527-3887
ehs@sika-corp.com
Recommended use of the For further information, refer to the product technical data
chemical and restrictions on sheet.
use
2. Hazards identification
GHS Classification
GHS Label element

See Section 11 for more detailed information on health effects and symptoms.
There are no ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence
require reporting in this section.
4. First aid measures
If inhaled Move to fresh air.
In case of skin contact Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
In case of eye contact Flush eyes with water as a precaution.
1/8
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£. Safety Data Sheet
Remove contact lenses.

Keep eye wide open while rinsing.
If swallowed Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Most important symptoms No known significant effects or hazards.

and effects, both acute and
delayed
See Section 11 for more detailed information on health effects
and symptoms.
Protection of first-aiders No hazards which require special first aid measures.
Notes to physician Treat symptomatically.
Suitable extinguishing media Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Specific extinguishing Collect contaminated fire extinguishing water separately. This

methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
for fire-fighters
Environmental precautions Local authorities should be advised if significant spillages

Methods and materials for Wipe up with absorbent material (e.g. cloth, fleece).
containment and cleaning up Keep in suitable, closed containers for disposal.
Advice on safe handling For personal protection see section 8.

No special handling advice required.
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage Keep container tightly closed in a dry and well-ventilated
place.
Store in accordance with local regulations.
Materials to avoid no data available
. 218
Page 314 of 516

A Safety Data Sheet
Contains no substances with occupational exposure limit values.
Engineering measures Use of adequate ventilation should be sufficient to control

worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any
recommended or statutory limits.

Respiratory protection Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk
assessment indicates this is necessary.
The filter class for the respirator must be suitable for the
maximum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when handling
the product. If this concentration is exceeded, self-contained
breathing apparatus must be used.
Hand protection
Remarks Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary.
Eye protection Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.
Skin and body protection Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to
the specific work-place.
Hygiene measures Wash hands before breaks and immediately after handling the
product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Appearance liquid
Color orange
Odor characteristic
Odor Threshold no data available
Flash point ca.> 212 °F (> 100 °C)
Ignition temperature not applicable
Decomposition temperature no data available
.3/8
Page 315 of 516

Lower explosion limit (Vol%) no data available
Upper explosion limit (Vol%) no data available
Flammability (solid, gas) no data available
Oxidizing properties no data available
Autoignition temperature no data available
pH ca. 7.5
at
73 °F (23 °C)
Melting point/range / no data available

Freezing point
Boiling point/boiling range no data available
Vapor pressure no data available
Density ca.1 g/cm3

at 73 °F (23 °C)
Water solubility Note: dispersible
Partition coefficient: n- no data available

octanol/water
Viscosity, dynamic no data available
Viscosity, kinematic ca.> 20.5 mm2/s

at 104°F(40°C)
Relative vapor density no data available
Evaporation rate no data available
Burning rate no data available
Volatile organic compounds < 15 g/1

(VOC) content
Reactivity No dangerous reaction known under conditions of normal use.
Chemical stability The product is chemically stable.
Possibility of hazardous Stable under recommended storage conditions.

reactions
Conditions to avoid no data available
Incompatible materials no data available
Page 316 of 516

Print Date 11/11/2013
Acute toxicity
Product
Acute oral toxicity no data available
Acute inhalation toxicity no data available
Acute dermal toxicity no data available
Product
no data available

Product
no data available

Product
no data available

Product
Mutagenicity no data available
Carcinogenicity
Product
Carcinogenicity : no data available
IARC not applicable

NTP not applicable
Reproductive Toxicity/Fertility
Product
Reproductive toxicity : no data available
Reproductive Toxicity/Development/Teratogenicity
Product
T eratogenicity no data available
$TOT-single exposure
Product
5/8
Page 317 of 516

Print Date 11/11/2013
Product
Aspiration toxicity
Product
no data available
Other information Do not empty into drains; dispose of this material and its
container in a safe way.
Avoid dispersal of spilled material and runoff and contact
Disposal methods
Waste from residues Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

DOT
Not dangerous goods
IATA
Not dangerous goods
IMDG
Not dangerous goods
Special precautions for user

no data available
not applicable
TSCA list All chemical substances in this product are either listed on the
Page 318 of 516

A Safety Data Sheet
exemption.

This material does not contain any components with a CERCLA RO.
SARA304 Reportable Quantity

This material does not contain any components with a section 304 EHS RO.
SARA 311/312 Hazards : No SARA Hazards
SARA302 SARA 302: No chemicals in this material are subject to the

reporting requirements of SARA Title 111,
Section 302.
SARA 313 SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title 111,
Section 313.
Clean Air Act
Ozone-Depletion This product neither contains, nor was manufactured with a

Potential Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A+ B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61 ).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
California Prop 65 WARNING! This product contains a chemical known in the

State of California to cause cancer.
WARNING: This product contains a chemical known in the
State of California to cause birth defects or other reproductive
harm.
16. Other information
HMIS Classification
Personal Protection 0
718
Page 319 of 516

Caution: HMIS® rating is based on a 0-4 rating scale, with O representing minimal hazards or
risks, and 4 representing significant hazards or risks. Although HMIS® rating is not required
on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® rating
is to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the
National Paint & Coatings Association (NPCA). Please note HMIS® attempts to convey full
health warning information to all employees.
Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika
Corporation ("Sika") product identified and described herein. This information is not intended
to address, nor does it address the use or application of the identified Sika product in
combination with any other material, product or process. All of the information set forth herein
is based on technical data regarding the identified product that Sika believes to be reliable as
of the date hereof. Prior to each use of any Sika product, the user must always read and
follow the warnings and instructions on the product's current Product Data Sheet, product
label and Safety Data Sheet for each Sika product, which are available at web site and/or
telephone number listed in Section 1 of this SOS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY

ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT
BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON
ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201-933-8800.
Material number: 107602
Page 320 of 516

SOLOMON SAFETY DATA SHEET
COLORS, INC.
Issue Date 19-May-2015 Revision Date 19-May-2015 Version 1
CP DRY BLENDS CP Dry Blends
Product identifier
Product Name CP Dry Blends

Product Code CP DRY BLENDS

Recommended Use Coloring agent for Concrete.
Uses advised against No information available

Supplier Address Manufacturer Address
Solomon Colors, Inc. Solomon Colors, Inc.
4050 Color Plant Road 4050 Color Plant Road
Springfield, IL 62702 Springfield, IL 62702
Company Phone Number 800-624-0261 (US & Canada); 217-522-3112 (Outside North America)
24 Hour Emergency Phone Number 800--373-7542
Classification
OSHA Regulatory Status

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.122)
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Emeraencv Overview
The product contains no substances which at their given concentration, are considered to be hazardous to health
~ppearance Powder Physical state Powder Odor Odorless
Other Information
Chemical Name CAS No. Wei ht-% Trade Secret

Red Iron Oxide 1309-37-1 0-90
CP DRY BLENDS 1/ 8 CP Dry Blends
Page 321 of 516

Black Iron Oxide 1317-61-9 0-90
Yellow·lron Oxide 51274-00-1 0-90
•The exact percentage (concentration) of composition has been withheld as a trade secret.
General advice In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible).
Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. (Get medical attention immediately if irritation
persists.).
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. In the case of skin irritation or allergic reactions see a physician.
Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
Ingestion Clean mouth with water. Remove from exposure, lie down. Do not induce vomiting without
medical advice. Consult a physician if necessary.
Symptoms· No information available.
Note to physicians Treat symptomatically.
Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical

No information available.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters

protective gear.
Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Avoid creating dust. Evacuate personnel to safe areas.
CP DRY BLENDS 2/8 CP Dry Blends
Page 322 of 516

Environmental precautions See Section 12 for additional ecological information.
Methods for containment Vacuum or sweep up material and place in a designated labeled waste container. Prevent
further leakage or spillage if safe to do so. Prevent dust cloud.
Methods for cleaning up With clean shovel place material into clean, dry container and cover loosely; move
containers from spill area. Take up with sand, earth or other non-combustible absorbent
material. Use personal protective equipment as required.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials Strong oxidizing agents. Strong acids.
Control parameters
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies. The TWA limits are set
for Iron or Iron Oxide fumes. The Iron Oxide pigments do not contain any Iron or Iron Oxide
fumes.
Chemical Name ACGIHTLV OSHA PEL NIOSH IDLH
Red Iron Oxide TWA: 5 mglm 3 respirable fraction TWA: 10 mg/m3 fume lDLH: 2500 mglm3 Fe dust and
1309-37-1 TWA: 15 mglm 3 total dust fume
TWA: 5 mglm' respirable fraction TWA: 5 mgim' Fe dust and fume
(vacated) TWA: 10 mglm3 fume
and total dust Iron oxide
(vacated} TWA: 5 mg/m3 respirable
fraction regulated under Rouge
Appropriate engmeermg controls
Engineering Controls Showers

Eyewash stations
Ventilation systems.
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles).
Skin and body protection Wear protective gloves and protective clothing. Protective shoes or boots.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended. Wash face, hands and any exposed
skin thoroughly after handling. Do not eat, drink or smoke when using this product.
Page 323 of 516

Information on basic physical and chemical properties
Physical state Powder

Appearance Powder Odor Odorless
Color Red Odor threshold Not applicable
Property Values Remarks • Method

pH 3.0-8.D
Melting point/freezing point >1000°C (1832°F)
Boiling point I boiling range No information available
Flash point No information available
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure No information available
Vapor density No information available
Specific Gravity 4.0- 5.0
Water solubility Insoluble
Solubility in other solvents No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available
Other Information
Softening point No information available

Molecular weight No information available
VOC Content(%) No information available
Density No information available
Bulk density No information available
Reactivity
No data available
Chemical stability
Stable under normal conditions.
Possibility of Hazardous Reactions

None under normal processing.
Hazardous polymerization None under normal processing.
Conditions to avoid
Extremes of temperature and direct sunlight.
Strong oxidizing agents. Strong acids.
Hazardous Decomposition Products

None known based on information supplied.
Page 324 of 516

Product Information Product does not present an acute toxicity hazard based on known or supplied information
Inhalation May cause irritation of respiratory tract.
Eye contact May cause mechanical irritation (abrasion).
Skin Contact May cause mechanical irritation (abrasion).
Ingestion No known effect based on information supplied.
!Chemical Name Oral LOSO Dermal LOSO Inhalation LC50

!Red Iron Oxide > 10000 mg/kg ( Rat ) - -
1309-37-1
Black Iron Oxide > 10000 mg/kg ( Rat ) - -
1317-61-9
Symptoms No information available.
Sensitization No information available.

Germ cell mutagenicity No information available.
Carcino enici No information available.
ACGIH IARC NTP OSHA
Red Iron Oxide Group3
1309-37-1
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 10326 mg/kg
Ecotoxicity

Bioaccumulation
Other adverse effects No known significant effects or critical hazards.
Page 325 of 516

Waste treatment methods
Disposal of wastes This material, as supplied, is not a hazardous waste according to state and federal
regulations (40 CFR 261 ). Disposal should be in accordance with applicable regional,
national and local laws and regulations.
Contaminated packaging Do not reuse container.
DOT Not regulated
TDG Not regulated
MEX Not regulated
ICAO(air} Not regulated
IATA Not regulated
IMDG Not regulated
RID Not regulated
ADR Not regulated
ADN Not regulated
Page 326 of 516

TSCA Complies
DSUNOSL Complies
EINECS/ELINCS Complies
ENCS Does not comply
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section B(b) Inventory
DSUNDSL - Canadian Domestic Substances LisUNon-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
SARA 313
not contain any
Section 313 of Title 1Hof the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does
are subject to the reporting requirements of the Act and Title 4D of the Code of Federal Regulations, Part 372
chemicals which
SARA 311!312 Hazard Categories

Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA {Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR
122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
and
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments
or state level
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional,
pertaining to releases of this material
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
NewJerse Massachusetts Penns lvania

Chemlcal Name
X X X
Red Iron Oxide
13D9-37-1
CP Dry Blends
CP DRY BLENDS 7/8
Page 327 of 516

Reactivity O Physical and Chemical HMIS Health hazards 1
Properties •
Flammability 0 Physical hazards 0 Personal protection X
Issue Date 19•May-2015

Revision Date 19-May-2015
Revision Note
No information available
The information provided In this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication, The information given is designed only as a guidance for safe handling, use, processing, storage,
materials or in any process, unless specified in the texl
End of Safety Data Sheet
Page 328 of 516

Page: 1 of 5
MANUFACTURER: SIERRA CORP/TK PRODUCTS EMERGENCYPHONE: 1-800-424-9300

ADDRESS 11400 WEST 47TH STREET INFORMATION PHONE: (952)938-7223
MINNETONKA, MN 55343 NAME OF PREPARER: Safety Director
PRODUCT NAME: SOLVENT
PRODUCT CODE: TK-00
HAZARD RISK CLASSIFICATION
SIGNAL WORD: DANGER
PICTOGRAM:
GHS02 - FLAME GHS07 - EXCLAMATION MARK GHS0B - HEALTH HAZARD GHS09 -
ENVIRONM ENT
HAZARD CLASS HAZARD CATEGORY
FLAMMABLELIQUIDS CATEGORY 3
ACUTE TOXICITY CATEGORY 4 DERMAL
ACUTE TOXICITY CATEGORY 4 INHALATION
ACUTE TOXICITY CATEGORY 5 ORAL
SKIN CORROSION/ CATEGORY 2
IRRITATION
SERIOUS EYE DAMAGE/ CATEGORY 2 AND 2A
EYE IRRITATION
CARCINOGENICITY CATEGORY 2
TOXIC TO SPECIFIC TARGET ORGAN CATEGORY 3
TOXICITY - SINGLE EXPOSURE
TOXIC TO SPECIFIC TARGET ORGAN CATEGORY 2
TOXICITY - REPEATED EXPOSURE
ASPIRATION HAZARD CATEGORY 1
HAZARDOUS TO THE AQUATIC ACUTE 3
ENVIRONMENT SHORT-TERM (ACUTE) HAZARDOUS TO THE AQUATIC CHRONIC 2
ENVIRONMENT LONG-TERM (CHRONIC)
HAZARD STATEMENTS:
H225 Highly flammable liquid and vapor
H304 May be fatal if swallowed or enters airways
H315 Causes skin irritation
H319 Causes serious eye irritation.
H335 May cause respiratory irritation
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated
exposure.
H411 Toxic to aquatic life with long lasting effects
PREVENTION:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and
understood.
P210 Keep away from heat/hot surfaces/sparks/open flames and other
sources of ignition. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
Page 329 of 516

Page: 2 of 5

P241 Use explosion-proof electrical/ ventilation/lighting/handling
equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharge.
P260 Do not breath dusts/fume/gas/mist/vapors or spray.
P264 Wash hands and any exposed area thoroughly after handling.
P270 Do not eat, drink or smoke while using this product.
P271 Use only outdoors or in well-ventilated area.
P281 Use appropriate personal protective impervious gloves/protective
clothing/ OSHA approved eye protection/ face protection.
RESPONSE:
P30l+P310 If swallowed: Immediately call a Poison Center/ doctor.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated
clothing. Rinse skin with water (or shower).
P304+P340 If inhaled: Remove person to fresh air and keep comfortable for
breathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P321 Specific treatment (see on this label)
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use carbon dioxide (CO2), powder, alcohol-
resistant foam to extinguish.
STORAGE:
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
DISPOSAL:
P501 Store separately. Dispose of contents/ container in accordance
with local/ regional/national /international regulations.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

WEIGHT EXPOSURE LIMITS
COMPONENT CAS NUMBER PERCENT OSHA PEL ACGIH TLV OTHER
+*A Xylene, mixed isomers 1330-20-7 84.75

100 PPM 100 PPM STEL 150 PPM
+*A Ethyl Benzene 100-41-4 15.00
100 PPM 100 PPM STEL 125 PPM
* Chemical{s) that are chronic health hazards. Refer to section 3 for further information.
+ Toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.
'Hazardous Air Pollutant established by the EPA as directed by the Clean Air Act of 1990.
PRIMARY ROUTES OF EXPOSURE:

Skin contact, eye contact, and inhalation.
EFFECTS OF ACUTE EXPOSURE:
EYES: Contact with eyes may cause irritation including burning, watering, and redness~
SKIN: Contact may cause mild skin irritation including redness, burning, and drying and cracking of skin. Continued exposure
may develop into dermatitis. Solvents can penetrate the skin and cause systematic effects similar to those under
inhalation symptoms.
Page 330 of 516

Page: 3 of 5

INHALATION: High vapor concentrations are irritating to the eyes and respiratory tract, may cause headaches,
dizziness, anesthesia, asthma, drowsiness, unconsciousness, and other central nervous system effects, and possibly
death.
INGESTION: Can cause gastrointestinal irritation, nausea, vornitting and diarrhea. Small amounts aspirated into the
respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury.
CHRONIC HEALTH EFFECTS:

Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage (Sometimes referred to as Solvent or Painter's Syndrome). Intentional misuse by deliberately
concentrating and inhaling this material may be harmful or fatal. Chronic exposure may also cause damage to the
respiratory system, lungs, eyes, skin, gastrointestinal tract, liver, spleen and kidneys. Repeated skin contact may
cause persistant irritation or dermatitis.
MEDICAL CONDITIONS GENERALLY AGGRAVATEDBY EXPOSURE:
Conditions aggrevated by exposure may include skin disorders, respiratory (asthma-like) disorders, and pre-existing
liver or kidney conditions.
SECTION 4 - FIRST AID 1'1EASURES

IF ON SKIN: Thoroughly wash exposed area with soap and water. Remove contaminated clothing. Launder contaminated
clothing before re-use. If irritation develops and persists, seek medical attention.
IF IN EYES: Flush with large amounts of water for 15 minutes, lifting upper and lower lids occasionally. If symptoms
persist, seek medical attention.
If SWALLOWED: Do not induce vomiting. Immediately administer 1-2 glasses of water and contact a physician, hospital
emergency room, or poison control center for further advice. Keep person warm, quiet and seek immediate medical
attention. Aspiration of material into lungs can cause severe lung damage. VOMITING CAN CAUSE CHEMICAL PNEUMONITIS
WHICH CAN BE FATAL.
INHALATION: Move affected individual to fresh air. If breathing is difficult, qualified personnel should administer
oxygen. If breathing has stopped give artificial respiration. If respiratory symptoms develop or persist, seek medical
attention.
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: 76 F METHOD USED: TCC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1 UPPER: 6.7
EXTINGUISHING MEDIA:
Foam, CO2, or dry chemical is recommended. Water spray is recommended to cool or protect exposed materials or
structures.
SPECIAL FIREFIGHTING PROCEDURES:

Persons exposed to products of combustion should wear self-contained breathing apparatus and full protective equipment.
Isolate danger area, keep unauthorized personnel out. Water may be ineffecive for extinguishment, unless used under
favorable conditions by experienced fire fighters. Carbon dioxide can displace oxygen, exercise caution when using CO2
in confined areas.
UNUSUAL FIRE J\ND EXPLOSION HAZARDS:

Vapors may be ignited by heat, sparks, flames, or other sources of ignition. Vapors are heavier than air and may travel
considerable distances to a source of ignition where they may cause a flashback or explosion. If container is not
properly cooled, it can rupture in the presence of excessive heat.
SECTION 6 - ACCIDENTAL RELEASE 1'1EASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Keep all sources of ignition and hot metal surfaces away from spill/release. Use explosion-proof non-sparking
equipment. Stay upwind from area. Isolate danger and keep unauthorized personnel out. Stop source of release if
possible with minimal risk. Wear appropriate protective equipment including respiratory protection. Prevent spill from
entering sewers, storm drains, or any other unauthorized treatment drainage systems and natural waterways by diking
ahead of the spill. Spilled material may be absorbed with an appropriate spill kit. Notify fire authorities and
appropriate federal, state, and local agencies if required.

HANDLING INFORMATION:
Employees who come in contact with this material must be trained in accordance to 1910.1200 of the Hazard Communication
Page 331 of 516

Page: 4 of 5
SAFETY DATA SHEET ProcessTime: 3:16 pm

Standard.
Open container slowly to relieve any pressure. Bond and ground all equipment when transferring from one vessel to
another. Static charge can accumulate by flow or agitation. Ignition can occur by static discharage. The use of
explosion proof equipment is recommended and may be required. The use of respiratory protection is advised when
concentrations exceed any established exposure limits and in confined spaces. Use good industrial and personal hygiene
practice, wash thoroughly after handling, and do not wear contaminated clothing.
STORAGE INFORMATION:
Keep containers tightly closed. Use and store material in cool, dry, well-ventilated areas away from heat, direct
sunlight, hot metal surfaces, and all sources of ignition. Post "No smoking or open flame" sign. Store only in
approved containers. Keep away from incompatible materials (see section 10). Protect containers against physical
damage. Indoor storage should meet OSHA standards and appropriate fire codes.
OTHER PRECAUTIONS:
"Empty" containers retain residue, liquid and vapor, and may be dangerous. Do not cut, weld, pressurize, solder, drill,
grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may expode and cause severe
personal injury or death. All containers should be disposed of in an environmentally safe manner in accordance with all
government regulations.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

RESPIRATORY PROTECTION:
Engineering or administrative controls should be implemented to. reduce exposure. A NIOSH/MSHA approved respirator with
an organic vapor cartridge should be used under conditions where airborne concentrations are expected to exceed exposure
limits (See Section 2). Use a positive pressure air supplied respirator if there is potential for uncontrolled release,
exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate
protection.
VENTILATION:
If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure
limits, additional ventilation or exhaust systems may be required. Where explosive mixtures may be present, electrical
systems safe for such locations must be used.
PROTECTIVE GLOVES:
Prevent prolonged or repeated contact by wearing gloves impervious to solvents and other appr'opriate protective
clothing. Launder contaminated clothing before reuse.
EYE PROTECTION:
Wear safety glasses to reduce eye contact potential. Chemical safety goggles (ANSI Z87.l or approved equivalent) are
appropriate if splashing is likely. Eye washes must be available where eye contact can occur.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
A source of clean water should be available for flushing eyes and skin. Showers should be available if larger spills
are possible.
WORK/HYGIENIC PRACTICES:
Efforts should be made to minimize contact and spills. Always wash hands before eating, drinking, or smoking. Clean up
spills promptly. Follow OSHA and company guidlines.

PHYSICAL STATE: Liquid COLOR: Clear(Water white)
ODOR: Hydrocarbon odor SOLUBILITY IN WATER: Insoluble/Negligible
SPECIFIC GRAVITY (H20=1): .87 VAPOR DENSITY: Heavier than air.
BOILING RANGE: 277 F EVAPORATION RATE: Slower than nBuAc
COATING V.O.C.: 868 g/1 (7.25 lb/gl I
SECTION 10 - STABILITY AND REACTIVITY DATA

STABILITY:
Stable under normal conditions and handling.
CONDITIONS TO AVOID:
All possible sources of ignition.
INCOMPATIBILITY (MATERIALS TO AVOID):
Avoid exposure to strong oxidizing agents and reducing agents.
HAZARDOUSDECOMPOSITION OR BYPRODUCTS:
Combustion may liberate toxic byproducts such as carbon dioxide, carbon monoxide, various oxides of carbon and nitrogen.
HAZARDOUS POLYMERIZATION:
Will not occur.
Page 332 of 516

Page: 5 of 5

SECTION 11 - TOXICOLOGICAL INFORMATION
SENSITIZATION:
None known.
CARCINOGENICITY:
There is no data available to indicate any components present at greater than 0.1% may present a carcinogenic hazard.
REPRODUCTIVE TOXICITY:
There is no data available to indicate any components present at greater than 0.1% may present reproductive toxicity.
TERATOGENICITY (BIRTH DEFECTS):
There is no data available to indicate any components present at greater than 0.1% may cause birth defects.
MUTAGENICITY:
There is no data to indicate that any component present at greater than 0.1% will alter DNA.

ENVIRONMENTALDATA:
Although no information is available for this specific product mixture, individual components may by themselves may have
ecological affects. Trimethylbenzene is a marine pollutant under 49 CFR 172.101.

This product is considered a RCRA hazardous waste due to the characterisic(s) of D00l (ignitability). Waste is subject
to the land disposal restrictions in 40 CFR 268.40 and may require treatment standards. Consult state and local
regulations to determine whether they are more stringent than the federal requirements.
Container contents should be completely used and containers empty prior to discarding. Container rinsate could be
considered a RCRA hazardous waste and must be discarded in compliance with all applicable regulations. Larger empty
containers, such as drums, should be returned to a professional drum reconditioner. To assure proper disposal of
smaller empty containers, consult with state and local regulations and disposal authorities.
SECTION 14 - TRANSPORT INFORMATION

SHIPPING NAME:
UN1307, Xylenes, 3, III
=============SECTION 15 - REGULATORY INFORMATION
All ingredients of this product are listed, or are excluded from listing, on the US Toxic Subatances Control Act (TSCA)
chemical substance inventory.
This product does contain a chemical(s) subject to the reporting requirements of SARA Title III, Section 313 (40CFR
372). See section 2.
STATE SPECIFIC REQUIREMENTS:

This product does not contain a chemical known to the state of California to cause cancer, birth defects or reproductive
harm, subject to the requirements of 1
California Proposition 65.
STATE LISTED COMPONENTS CAS NUMBER STATE CODE

Ethyl Benzene 100-41-4 CA,NJ,PA
Trimethylbenzene 95-63-6 CA,MA,MN,NJ,PA
=============SECTION 16 - OTHER INFORMATION

REVISION DATE: 05/11/11
HM:IS CODES: H F R p
2 * 3 0 G
Page 333 of 516

Page 334 of 516
W. R. MEADOWS~
SAFETYDATA SHEET
Page 1 of 2
Product: VOCOMP®-20 Part Number: 3420000

Product Use: Concrete Curing/Sealing Compound
2Jli-~!iH 51;~~~-l!J;!Nl~~-MJ:lsllfe\liw~,t
I Health I 111 WARNING!
I Flammability I IOI Causes skin irritation.
I Reactivity I 101 PRECAUTIONARY STATEMENTS
-5 No <1
uperfund Amendments and Reauthorization Act of 1966 (SARA)
tified under the heading "SARA 313."
•·
~.e~t~~511ffil111111p-1tf!!p1:10,t!(_
oms persist, seek medical attention.
e contaminated shoes/clothing. If symptoms persist, seek m
piratory symptoms develop, seek medical attention.
drowsy. Do not induce vomiting. If vomiting spontaneously
EDIA: Water fog, foam, dry chemical.

BUSTION HAZARDS: Carbon monoxide, carbon dioxide, and incomplete combustion products.
ERSONAL PROTECTIVE EQUIPMENT: Use appropriate personal rotective e ui ment.
-~ -, fJEtiil:(~
SPILL OR LEAK PROCEDURES: Avoid direct contact. Dike and contain spilled material. Remove source of spill if safe to do so. Apply absorbent
and place clean-up material in sealed/marked containers for proper disposal. Clean-up materials will be classified as non-hazardous waste.
- -,:.~~~Nff~Jl!AGE4~~-
SAFE HANDLING PROCEDURES: Avoid direct contact.
SAFE STORAGE: Prevent product from freezing.
:1;~-,•~~•rco~~~
,_. OSHA
__~
rR~!l>.,flfMG#&~~~½~'8'j~i1~1~~~i~m\~~~~~F-
1
ACGIH
1. Propylene Glycol
Phenyl Ether N/E N/E N/E No N/E N/E N/E N/E
,,~M-1llliflllffl~I~lleS..::~-
-'. _=:__
VAPOR DENSITY: N/A % VOLATILE BY VOLUME:
pH LEVEL: 9.4 % VOLATILE BY WEIGHT: 80
PRODUCT APPEARANCE: Opaque Liquid voeCONTENT: 20 g/L
-
- ~ )kl iiE~Cifi
o

CONDITIONS AND MATERIALS TO AVOID: None recognized.
Page 335 of 516

SAFETYDATA SHEET
EYE CONTACT: Direct contact may cause mild to moderate irritation.

SKIN CONTACT: Direct contact may cause slight skin irritation. Prolonged/repeated contact may result in irritation.
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of resp"iratory "irdtation include
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function.

SPECIAL PRECAUTIONS: Prevent product from freezing.
Dave Carey
Page 336 of 516

SAFETY DATA SHEET
Issue Date 29-May-2015 Revision Date 02-Jun-2015 Version 1
RA Brickform Antique Release
Product identifier
Product Name Brickform Antique Release

Product Code RA
Synonyms 100,175,200,300,325,350,375,400,425,500,515,525,550,575,600,615,625,700,
810,815,820,825, 1010, 1015, 1045, 1050, 1055, 1065, 1075, 1080,00

Recommended Use Restricted to professional users.
Uses advised against Consumer use

24 Hour Emergency Phone Number 800-373-7542
Classification

Label elements
Emeraencv Overview
~ppearance Powder Physical state Powder Odor Odorless
Other Information
RA 1/9 Brickform Antique Release
Page 337 of 516

Synonyms 100,175,200,300,325,350,375,400,425,500,515,525,550,575,600,615,625,700,
810,815,820,825, 1010, 1015, 1045, 1050, 1055, 1065,1075, 1080,00.
Chemical Name CAS No. Weight-% Trade Secret

Inorganic Filler Proprietary 0-25 *
Proprietary Release Agent Proprietary 0-25 *
Yellow Iron Oxide 51274-00-1 0-15 *
Red Iron Oxide 1309-37-1 0-15 *
Chrome Oxide 1308-38-9 0-15 *
Black Iron Oxide 1317-61-9 0-15 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Skin Contact Wash skin with soap and water.
Inhalation Remove to fresh air.
Ingestion Clean mouth with water and drink afterwards plenty of water.


Explosion data

protective gear.
Page 338 of 516

Personal precautions Ensure adequate ventilation, especially in confined areas. Use personal protective
equipment as required.
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Incompatible materials None known based on information supplied.
Page 339 of 516

Control parameters
exposure limits established b>vthe reqion soecific reaulator, bo d"Ies.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Inorganic Filler TWA: 2 mg/m3 particulate matter TWA: 15 mg/m3 total dust TWA: 1O mg/m3 total dust
containing no asbes1os and <1% TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust
crystalline silica, respirable fraction (vacated) TWA: 10 mg/m 3 total dust
(vacated) TWA: 5 mg/m 3 respirable
fraction
Proprietary Release Agent TWA: 10 mg/m3 except stearates - -
of toxic metals
Red Iron Oxide TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m3 fume IDLH: 2500 mg/m 3 Fe dust and
1309-37-1 TWA: 15 mg/m3 total dust fume
TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 Fe dust and fume
(vacated) TWA: 10 mg/m 3 fume
Chrome Oxide TWA: 0.5 mg/m 3 Cr TWA: 0.5 mg/m 3 Cr IDLH: 25 mg/m 3 Cr(III)
1308-38-9 (vacated) TWA: 0.5 mg/m3 Cr TWA: 0.5 mg/m3 Cr
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d
962 (11th Cir., 1992).
Appropriate engineering controls

Eyewash stations
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

Color Light Amber to Black Odor threshold No information available

pH No information available
Melting point/freezing point No information available
Boiling point / boiling range No information available
Page 340 of 516

Specific Gravity No information available
Water solubility No information available
other Information

VOC Content (%) No information available
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.

Conditions to avoid

Page 341 of 516

Product Information No data available
Inhalation No data available.
Eye contact No data available.
Skin Contact No data available.
Ingestion No data available.
Chemical Name Oral LOSO Dermal LOSO Inhalation LCSO

Proprietary Release Agent > 10 g/kg (Rat) - -
Red Iron Oxide > 10000 mg/kg ( Rat ) - -
1309-37-1
1317-61-9

CarcmoaemcItv
. . ·t No .1nJiorma f10n ava1·1a ble.
Chemical Name ACGIH IARC NTP OSHA
Red Iron Oxide - Group 3 - -
1309-37-1
Chrome Oxide - Group 3 - -
1308-38-9
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
/ARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X-Present
STOT • single exposure No information available.
Target Organ Effects Eyes, lungs, Lymphatic System, Respiratory system, Skin.
Numerical measures of toxicity • Product Information
ATEmix (dermal) 601 mg/kg
Page 342 of 516

Ecotoxicity

Bioaccumulation
Other adverse effects No information available
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Chemical Name California Hazardous Waste Status

Chrome Oxide Toxic
1308-38-9 Corrosive
lanitable
DOT Not regulated
Page 343 of 516

TSCA Complies
DSUNDSL Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA- United States Toxic Substances Control Act Section 8(b) Inventory
DSUNDSL - Canadian Domestic Substances List/Non-Domestic Substances List
SARA 313
Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 · Threshold Values%

Chrome Oxide - 1308-38-9 1.0
SARA 311/312 Hazard Categories
Fire hazard No
Reactive Hazard No
CWA (Clean Water Act)
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Chrome Oxide - X - -
1308-38-9
CERCLA
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
Chemical Name New Jersey Massachusetts Pennsylvania

Inorganic Filler X X X
Red Iron Oxide X X X

1309-37-1
Chrome Oxide X X X
1308-38-9
Page 344 of 516

NFPA Reactivity 0 Physical and Chemical HMIS Health hazards 0
Properties -
Issue Date 29-May-2015

Revision Date 02-Jun-2015
Revision Note
materials or in any process, unless specified in the text.
Page 345 of 516

Page 346 of 516
SAFETY DATA SHEET
Issue Date 07-May-2015 Revision Date 07-May-2015 Version 1
CH Color Hardeners
Product identifier
Product Name Color Hardeners

Product Code CH


Classification

Specific target organ toxicity (repeated Category 2
exposure)
Label elements
Erner enc Overview

Danger
Hazard statements
May cause cancer
May cause damage to organs through prolonged or repeated exposure
Corrosive
CH 1/ 9 Color Hardeners
Page 347 of 516

Overexposure to dust can cause chronic lung injury. Acute silicosis may develop in a short timewith heavy exposure. Silicosis can
be progressive and may cause death.
ppearance Grey or colored powder Physical state Powder Odor No information availabl
Precautionary Statements• Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Precautionary Statements • Response

IF exposed or concerned: Get medical advice/attention
Precautionary Statements • Storage

Store locked up
Precautionary Statements • Disposal

Other Information

QUARTZ 14808-60-7 35- 70 *
Portland Cement 65997-15-1 20-40 *
Yellow Iron Oxide 51274-00-1 1- 5 *
Titanium Dioxide 13463-67-7 1- 5 *
Red Iron Oxide 1309-37-1 1- 5 *
Black Iron Oxide 1317-61-9 1- 5 *
General advice In case of accident or unwellness, seek medical advice irrrnediately (show directions for
continue flushing for at least 15 minutes. If symptoms persist, call a physician.
clothes and shoes. If skin irritation persists, call a physician.
CH 2/9 Color Hardeners
Page 348 of 516

Ingestion Rinse mouth. Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Call a physician immediately.
Most important symptoms and effects. both acute and delayed


Explosion data

protective gear.
Personal precautions Ensure adequate ventilation, especially in confined areas.
Methods for containment Vacuum or sweep up material and place in a designated labeled waste container.
containers from spill area.
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Do not
eat, drink or smoke when using this product.
Page 349 of 516

Control parameters
Exoosure Guide ines

ChemicalName ACGIHTLV OSHA PEL NIOSH IDLH
QUARTZ TWA: 0.025 mg/m3 respirable (vacated) TWA: 0.1 mg/m 3 IDLH: 50 mg/m 3 respirable dust
14808-60-7 fraction respirable dust TWA: 0.05 mg/m 3 respirable dust
(30)/(%SiO2 + 2) mg/m 3 TWA
total dust
(250)/(%SiO2 + 5) mppcfTWA
respirable fraction
(10)/(%SiO2 + 2) mg/m3 TWA
respirable fraction
Portland Cement TWA: 1 mg/m 3 particulate matter TWA: 15 mg/m 3 total dust IDLH: 5000 mg/m 3
65997-15-1 containing no asbestos and <1% TWA: 5 mg/m3 respirable fraction TWA: 10 mg/ms total dust
crystalline silica, respirable fraction (vacated) TWA: 10 mg/m 3 total dust TWA: 5 mg/m3 respirable dust
fraction
TWA: 50 mppcf <1% Crystalline
silica
Titanium Dioxide TWA: 10 mg/m 3 TWA: 15 mg/m 3 total dust IDLH: 5000 mg/m 3
13463-67-7 (vacated) TWA: 10 mg/m 3 total dust
Red Iron Oxide TWA: 5 mg/m 3 respirable fraction TWA: 10 mg/m3 fume IDLH: 2500 mg/m 3 Fe dust and
1309-37-1 TWA: 15 mg/m 3 total dust fume
(vacated) TWA: 5 mg/m3 respirable

Eyewash stations
Skin and body protection Wear protective gloves and protective clothing.

Appearance Grey or colored powder Odor No information available
Color No information available Odor threshold No information available

Boiling point/ boiling range No information available
Page 350 of 516

Other Information

Reactivity
No data available
Chemical stability

Conditions to avoid

Page 351 of 516

Chemical Name Oral LDS0 Dermal LDS0 Inhalation LCS0

QUARTZ = 500 mg/kg ( Rat ) - -
14808-60-7
Titanium Dioxide > 10000 mg/kg ( Rat ) - -
13463-67-7
1309-37-1
1317-61-9

C arcmoaemcI
. . ·ttv No 1n
. Jiorma f10nava1·1a ble.
QUARTZ A2 Group 1 Known X
14808-60-7
rrnanium Dioxide - Group 2B - X
13463-67-7
1309-37-1
ATEmix(oral) 5119 mg/kg
Ecotoxicity

Bioaccumulation
Page 352 of 516

regulations.
DOT Not regulated
Page 353 of 516

TSCA Complies
DSUNDSL Complies
IECSC Complies
KECL Complies
PICCS Does not comply
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8{b) Inventory
DSUNDSL - Canadian Domestic Substances List/Non-DomesticSubstances List
PIGGS - Philippines Inventory of Chemicals and Chemical Substances
SARA313
Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Fire hazard No
Reactive Hazard No

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act ( 40 CFR 122.21 and 40
CFR 122.42)
CERCLA
Chemical Name California Proposition 65

QUARTZ- 14808-60-7 Carcinogen
Titanium Dioxide - 13463-67-7 Carcinogen

QUARTZ X X X
14808-60-7
Portland Cement X X X
65997-15-1
Titanium Dioxide X X X
13463-67-7
1309-37-1
Page 354 of 516

Properties -

Revision Date 07-May-2015
Revision Note
Page 355 of 516

Page 356 of 516
SAFETY DATA SHEET
Issue Date 19-Feb-2016 Revision Date 19-Feb-2016 Version 1
BRICKFORM LC BRICKFORM Liquid Color
Product identifier
Product Name BRICKFORM Liquid Color

Product Code BRICKFORM LC

Recommended Use Coloring agent for Concrete.

Classification

Label etements
Emeroencv Overview
Annearance Viscous Phvsical state Liouid Odor Characteristic
Precautionary Statements • Prevention

Precautionary Statements • Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact tenses, if present and easy to do. Continue rinsing
BRICKFORM LC 1/ 9 BRICKFORM Liquid Color
Page 357 of 516

May cause eye irritation. May cause: tearing, redness, discomfort.
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove!Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Precautionary Statements - Storage

Store in accordance with local regulations
Precautionary Statements - Disposal

Other Information
Chemical Name CAS No. Weiaht-% Trade Secret

Red Iron Oxide 1309-37-1 0-65 *
Proprietary Dispersant Proprietary 1 -10 *
continue flushing for at least 15 minutes. (Get medical attention immediately if irritation
persists.).
clothes and shoes. In the case of skin irritation or allergic reactions see a physician.
Ingestion Clean mouth with water. Remove from exposure, lie down. Do not induce vomiting without
medical advice. Consult a physician if necessary.
BRICKFORM LC 2/9 BRICKFORM Liquid Color
Page 358 of 516


Explosion data

protective gear.
Avoid creating dust. Evacuate personnel to safe areas.
Methods for containment Vacuum or sweep up material and place in a designated labeled waste container. Prevent
further leakage or spillage if safe to do so. Prevent dust cloud.
containers from spill area. Take up with sand, earth or other non-combustible absorbent
material. Use personal protective equipment as required.
Storage Conditions Keep from freezing. Keep cool. Protect from sunlight. Store at temperatures not exceeding
80 °C/ 176 °F.
Incompatible materials Strong oxidizing agents. Strong acids.
Page 359 of 516

Control parameters
exposure limits established by the region specific regulatory bodies. The TWA limits are set
for Iron or Iron Oxide fumes. The Iron Oxide pigments do not contain any Iron or Iron Oxide
fumes.
Red Iron Oxide TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m 3 fume IDLH: 2500 mg/m 3 Fe dust and
fraction reaulated under Rouae

Eyewash stations
Skin and body protection Wear protective gloves and protective clothing. Protective shoes or boots.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended. Wash face, hands and any exposed
skin thoroughly after handling. Do not eat, drink or smoke when using this product.
Physical state Liquid

Appearance Viscous Odor Characteristic
Color Light Amber to Black Odor threshold Not applicable

pH 8.0 - 10.0
Boiling point I boiling range No information available
Specific Gravity 4.0 - 5.0
Page 360 of 516

Other Information

Reactivity
No data available
Chemical stability
Hazardous polymerization None under normal processing.
Conditions to avoid
Strong oxidizing agents. Strong acids.
Page 361 of 516

Product Information Product does not present an acute toxicity hazard based on known or supplied information.
Dried product might be harmful if inhaled.
Inhalation May cause irritation of respiratory tract.
Eye contact May cause mechanical irritation (abrasion).
Skin Contact May cause mechanical irritation (abrasion).
Ingestion No known effect based on information supplied.

1309-37-1
1317-61-9

Carcino enicit No information available.
ACGIH IARC NTP OSHA
Red Iron Oxide Group 3
1309-37-1
Ecotoxicity

No information available:
Bioaccumulation
Page 362 of 516

Disposal of wastes This material, as supplied, is not a hazardous waste according to state and federal
regulations (40 CFR 261 ). Disposal should be in accordance with applicable regional,
national and local laws and regulations.
DOT Not regulated
TDG Not regulated
MEX Not regulated
ICAO {air) Not regulated
IATA Not regulated
IMDG Not regulated
RID Not regulated
ADR Not regulated
ADN Not regulated
Page 363 of 516

TSCA Complies
DSUNDSL Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
SARA 313

Fire hazard No
Reactive Hazard No
CWA /Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
Chemical Name NewJerse Massachusetts Penns lvania

1309-37-1
Page 364 of 516

Properties -
Issue Date 19-Feb-2016

Revision Date 19-Feb-2016
Revision Note
Page 365 of 516

Page 366 of 516
SAFETY DATA SHEET
Issue Date 01-May-2015 Revision Date 29-Apr-2015 Version 1
LR Liquid Release
Product identifier
Product Name Liquid Release

Product Code LR


Classification

Germ cell mutagenicity Category 1B

Carcinogenicity Category 1B
Aspiration toxicity Category 1
Label elements
Erner enc Overview

Danger
Hazard statements
Causes serious eye irritation
May cause drowsiness or dizziness
Harmful if inhaled
Causes skin irritation
May cause cancer
May cause damage to organs through prolonged or repeated exposure
May be harmful if swallowed and enters airways
LR 1 / 10 Liquid Release
Page 367 of 516

ppearance No information available Ph sical state No information available Odor No information availabl
Precautionary Statements - Prevention

Wear eye/face protection
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Precautionary Statements - Response

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Rinse mouth
Do NOT induce vomiting

Store locked up

other Information
• May be harmful in contact with skin
• Toxic to aquatic life with long lasting effects
Chemical Name CAS No. Weiaht-% Trade Secret

Naphtha (petroleum), heavy alkylate 64741-65-7 60-100 *
Amyl acetate 628-63-7 1-5 *
Page 368 of 516

Eye contact Do not rub affected area. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Skin Contact Wash off immediately with soap and plenty of water. In the case of skin irritation or allergic
reactions see a physician.
Inhalation Move to fresh air in case of accidental inhalation of vapors or decomposition products. If
breathing is irregular or stopped, administer artificial respiration. If symptoms persist, call a
physician.
Ingestion If swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label.

Dry chemical, Carbon Dioxide, Foam, Sand.

Explosion data

Wear self contained breathing apparatus for fire fighting if necessary.
Personal precautions. protective equipment and emergency procedures
Ensure adequate ventilation, especially in confined areas.
Other Information ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded.
LR 3/10 LiquidRelease
Page 369 of 516

Methods for containment Prevent further leakage or spillage if safe to do so. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and place in container for disposal according to local/ national regulations (see Section 13).
Methods for cleaning up Use clean non-sparking tools to collect absorbed material. Ground and bond containers
when transferring material. Dike to collect large liquid spills.
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protective equipment as required. Keep away from heat, sparks, flame and other sources of
ignition (i.e., pilot lights, electric motors and static electricity). Use spark-proof tools and
explosion-proof equipment. All equipment used when handling the product must be
grounded. Never pierce, drill, grind, cut, saw or weld any empty container.
Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity). Keep container tightly closed in a dry and well-ventilated
place. Do not store near combustible materials. Use spark-proof tools and explosion-proof
equipment.
Incompatible materials Strong oxidizing agents.
Page 370 of 516

Control parameters
Exoosure G uidelines
Amyl acetate STEL: 100 ppm TWA: 100 ppm IDLH: 1000 ppm
628-63-7 TWA: 50 ppm TWA: 525 mg/m3 TWA: 100 ppm
(vacated) TWA: 100 ppm TWA: 525 mg/m3
(vacated) TWA: 525 mg/m 3
N/OSH /DLH Immediately Dangerous to Life or Health
962 (11th Cir., 1992).

Eyewash stations
General Hygiene Considerations Do not eat, drink or smoke when using this product. Handle in accordance with good
industrial hygiene and safety practice.
Physical state No information available

Appearance No information available Odor No information available
Color No information available Odor threshold No information available

BoHing point/ boiling range 161.6 °C / 322 °F
Flash point 80 °C I 176 °F
Page 371 of 516

Other Information

Reactivity
No data available
Chemical stability

Conditions to avoid
Strong oxidizing agents.

LR 6/10 Liquid Release
Page 372 of 516

Product Information May be harmful by inhalation, ingestion, or skin absorption
Inhalation Avoid breathing vapors or mists. Harmful by inhalation.
Eye contact Avoid contact with eyes. Contact with eyes may cause irritation.
Skin Contact Prolonged contact may cause redness and irritation.
Ingestion May be harmful if swallowed.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Naphtha (petroleum), heavy alkylate > 7000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.04 mg/L ( Rat) 4 h
64741-65-7
Amyl acetate > 1600 mg/kg ( Rat ) - -
628-63-7

Carcinogenicity No information available.
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin.
Ecotoxicity
Chemical Name AIQae/aQuatic plants Fish Crustacea

Naphtha (petroleum), heavy alkylate 30000: 72 h Pseudokirchneriella - 2: 48 h Mysidopsis bahia mg/L
64741-65-7 subcapitata mg/L EC50 LC50
Amyl acetate - 650: 96 h Lepomis macrochirus -
628-63-7 mg/L LC50 static

Bioaccumulation
Page 373 of 516

regulations.

Amyl acetate Toxic
628-63-7 I nitable
DOT Not regulated

UN/ID no. UN 1268
Proper shipping name Petroleum Distillates
Hazard Class 3
Packing Group Ill
Emergency Response Guide 128
Number
Page 374 of 516

TSCA Complies
DSUNDSL Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
TSCA - United States Toxic Substances Cor'ltrol Act Section 8(b) Inventory
SARA313

Fire hazard No
Reactive Hazard No
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA · Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA • Hazardous
Amyl acetate 50001b - - X
628-63-7
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

Amyl acetate 50001b - RO 5000 lb final RO
628-63-7 RO 2270 kg final RO
Chemical Name New Jersev Massachusetts I Pennsvlvania

Amyl acetate X X X
628-63-7 I
LR 9/10 Liquid Release
Page 375 of 516

Properties -

Revision Date 29-Apr-2015
Revision Note
Page 376 of 516

Lr?.
SAFETY DATA SHEET
1:_t_
,./T~®DECORATIVE
vv CONCRETE
SYSTEMS
A ptVISION OF SOLOMONCOLORS, INC,
RA_L. Accent-Colour Release
Product identifier
Product Name Accent-Colour Release

Product Code RA_L.
Synonyms 101, 103, 104, 105, 121, 122, 124


Classification

!Acute toxicity - Oral No evidence of adverse effects from available data.

!Acute toxicity - Dermal May cause mechanical irritation, soiling and skin drying. No cases of sensitization in
humans have been reported.
!Acute toxicity - Inhalation (Dusts/Mists Temporary discomfort to upper respiratory tract may occur due to mechanical irritation
when exposures are well above the occupational exposure limit.
Carcinoqenicitv Cateqorv 2
Label elements
Erner enc Overview

arning
Hazard statements
Harmful if inhaled
Suspected of causing cancer
RA_L. 1/9 Accent-Colour Release
Page 377 of 516

ppearance Powder Physical state Powder Odor Odorless

Do not eat, drink or smoke when using this product

IF ON SKIN (or hair): Remove!Take off immediately all contaminated clothing. Rinse skin with water/shower
If skin irritation or rash occurs: Get medical advice/attention
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
No known significant effects or critical hazards.

Store in accordance with local regulations

Other Information
Synonyms 101,103,104,105,121,122,124.
Chemical Name
Yellow Iron Oxide
CAS No.
51274-00-1
Weight-%
0-15 .
Trade Secret
Titanium Dioxide
Red Iron Oxide
13463-67-7
1309-37-1
0-14
0-15
*
.
...
Inorganic Filler Proprietary 0-25 *
Chrome Oxide 1308-38-9 0-15
Black Iron Oxide 1317-61-9 0-15
Proprietary Release AQent Proprietary 0-25
Cobalt Blue 1345-16-0 0-15 *
Page 378 of 516



Explosion data

protective gear.
Page 379 of 516

Control parameters
"de I"
Exoosure G u1 mes
Titanium Dioxide TWA: 10 mg/m 3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
13463--67-7 (vacated) TWA: 1O mg/m 3 total dust
Red Iron Oxide TWA: 5 mg/m 3 respirable fraction TWA: 10 mg/m 3 fume IDLH: 2500 mg/m 3 Fe dust and
(vacated) TWA: 1O mg/m 3 fume
Inorganic Filler TWA: 2 mg/m3 particulate matter TWA: 15 mg/m 3 total dust TWA: 1O mg/m 3 total dust
containing no asbestos and <1% TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust
crystalline silica, respirable fraction (vacated) TWA: 10 mg/m 3 total dust
fraction
Chrome Oxide TWA: 0.5 mg/m 3 Cr TWA: 0.5 mg/m 3 Cr IDLH: 25 mg/m 3 Cr(III)
1308-38-9 (vacated) TWA: 0.5 mg/m 3 Cr TWA: 0.5 mg/m 3 Cr
Proprietary Release Agent TWA: 10 mg/m 3 except stearates - -
of toxic metals
Cobalt Blue TWA: 0.02 mg/m3 Co TWA: 1 - -
1345-16-0 mg/m 3 respirable fraction
..
Other Information Vacated limits revoked by the Court of Appeals dec1s1onIn AFL-CIO v. OSHA, 965 F.2d
962 (11th Cir., 1992).

Eyewash stations
Page 380 of 516



Boiling point/ boiling range No information available
Other Information

Reactivity
No data available
Chemical stability

Conditions to avoid

RA_L. 5/9 Accent-ColourRelease
Page 381 of 516

ChemicalName Oral LDS0 DermalLDS0 InhalationLCS0

rritanium Dioxide > 10000 mg/kg ( Rat ) - -
13463-67-7
1309-37-1
1317-61-9
Proprietary Release Agent >10g/kg (Rat) - -

Carcinoaenicitv No information available.
ChemicalName ACGIH IARC NTP OSHA
Titanium Dioxide - Group 2B - X
13463-67-7
1309-37-1
1308-38-9
Cobalt Blue A3 Group 2B - X
1345-16-0
ACG/H (American Conference of Governmental lndustr,a/ Hygienists)
X-Present
Page 382 of 516

Ecotoxicity

Bioaccumulation
regulations.

Chrome Oxide Toxic
1308-38-9 Corrosive
Ignitable
Cobalt Blue Toxic
1345-16-0
DOT Not regulated
Page 383 of 516

TSCA Complies
DSUNDSL Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
SARA 313
Chemical Name SARA 313 - Threshold Values%

Chrome Oxide - 1308-38-9 1.0
Cobalt Blue - 1345-16-0 0.1
Fire hazard No
Reactive Hazard No
CWA (Clean Water Act}
Chrome Oxide . X - -
1308-38-9
CERCLA
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65

Titanium Dioxide - 13463-67-7 Carcinogen

Titanium Dioxide X X X
13463-67-7
Page 384 of 516

1309-37-1
Chrome Oxide - X X X
1308-38-9
Cobalt Blue X - X
1345-16-0

Properties -

Revision Note
belief at the
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
is designed only as a guidance for safe handling, use, processing, storage,
date of its publication. The information given
with any other
relates only to the specific material designated and may not be valid for such material used in combination
Accent-Colour Release
RA_L. 9/9
Page 385 of 516

::/_.
~®DECORATIVE
l,{A./ CONCRETE
SAFETY DATA SHEET
SYSTEMS
. . :\:,~ DlVJSl_g~-?~-~OLO~b~- fOl:_OR!?, 'l"f~·
RA_L Accent~Colour Release
Product identifier
Product Name Accent~Colour Release

Product Code RA_L
Synonyms 102,106,107,108,109,110,111,112,113,114,115,116,117,118,119,120,123,125,
126,127, 128,00


Classification

Label elements
Emeraencv Overview
Appearance Powder Physical state Powder Odor Odorless
Other Information
RA_L 1/ 9 Accent~Colour Release
Page 386 of 516

Synonyms 102,106,107,108,109,110,111,112,113,114,115,116,117,118,119,120,123,125,
126, 127, 128, 00.

tnorganic Filler Proprietary 0-25 *
Proprietary Release Agent Proprietary 0-25 *
Red Iron Oxide 1309-37-1 0-15 *
Chrome Oxide 1308-38-9 0-15 *


Explosion data

and full
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)
protective gear.
RA_L 2/9 Accent-Colour Release
Page 387 of 516

Conditions for safe storage. including any incompatibilities
Page 388 of 516

Control parameters
.
exoosure limits establishe . soecI"tiIc reau Iator bo d.Ies.
d bv t he reaion
Inorganic Filler TWA: 2 mg/m3 particulate matter TWA: 15 mg/m3 total dust TWA: 10 mg/m3 total dust
containing no asbeslos and <1% TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust
crystalline silica, respirable fraction (vacated} TWA: 10 mg/m3 total dust
fraction
Proprietary Release Agent TWA: 10 mg/m3 except stearates - -
of toxic metals
Red Iron Oxide TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m3 fume IDLH: 2500 mg/m3 Fe dust and
(vacated) TWA: 10 mg/m3 fume
Chrome Oxide TWA: 0.5 mg/m3 Cr TWA: 0.5 mg/m3 Cr IDLH: 25 mg/m3 Cr(III)
1308-38-9 (vacated) TWA: 0.5 mg/m3 Cr TWA: 0.5 mg/m3 Cr
NIOSH IDLH Immediately Dangerous to Life or Health
962 (11th Cir., 1992).

Eyewash stations


Boiling point / boiling range No information available
Page 389 of 516

Other Information

Reactivity
No data available
Chemical stability

Conditions to avoid

Page 390 of 516


Proprietary Release Agent >10g/kg (Rat) - -

1309-37-1
1317-61-9

.
C arcmoaerncI. ·trv . forma f,on ava,·1a ble.
No ,n
1309-37-1
1308-38-9
ACGIH (American Conference of Governmental Industrial Hygienists)
X-Present
Page 391 of 516

Ecotoxicity

Bioaccumulation
regulations.

Chrome Oxide Toxic
1308-38-9 Corrosive
l;:initable
DOT Not regulated
Page 392 of 516

TSCA Complies
DSUNDSL Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
Legend:
SARA 313
Chemical Name SARA 313 • Threshold Values %

Chrome Oxide - 1308-38-9 1.0
Fire hazard No
Reactive Hazard No
CWA {Clean Water Act}
Chrome Oxide - X - -
1308-38-9
CERCLA


1309-37-1
Chrome Oxide X X X
1308-38-9
Page 393 of 516

Properties -

Revision Note
Page 394 of 516

BUTTERFIEL~ ~ Safety Data Sheet
Pe~fo~lffal(ae
E1til(ee~dCol(a~ete Perma-Cast® Antiquing Release
625 W. Illinois Ave., Aurora IL 60506
Ph.: (630) 906-1980 - Fax: (630) 906-1982
www.butterfieldcolor.com
STANDARD)
THIS SDS COMPLIESWITH 29 CFR1910.1200 (HAZARDCOMMUNICATION
Section 1 Identification
PRODUCT IDENTITY: Perma-Cast® Antiquing Release

PRODUCT USES: Bond breaker for stamping concrete
COMPANY IDENTITY: Butterfield Color
COMPANY ADDRESS: 625 W Illinois Ave.
COMPANY CITY: Aurora, IL 60506
COMPANY PHONE:1-630-906-1980
EMERGENCY PHONES: CHEMTREC: 1-800-424-9300 (USA)
CANUTEC: 1-613-996-6666 (CANADA)
Section 2, Hazard(s) identification
Danger
2.1 HAZARD STATEMENTS: (CAT= Hazard Category)

= = =
H100s General, H200s Physical, H300s Healtli, H400s =Environmental
H350 May cause cancer (Inhalation) (CAT:1)
H370 Causes damage to organs (lung/respiratory system) (CAT:1)
H303 May be harmful if swaTiowed. (CAT:5).
H313 May be harmful if contacted with skin.(CAT:5)
H320 Causes eye irritation. (CAT:2B)
H333 May be harmful if inhaled. (CA1:5)
2.2 PRECAUTIONARY STATEMENTS:

= =
P100s General, P200s Prevention, P300s =Response, P400s =Storage, P500s =Disposal
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P264 - Wash hands, forearms and face thoroughly after handling
P270 - Do not eat, drink or smoke when using fhis product
P405 - Store locked up
P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
P264 - Wash with soap & water tlioroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
1
SDS No. 101 - Perma-Cast® Antiquing Release
PLEASEENSURETHAT THIS SDS IS GIVENTO AND EXPLAINEDTO PEOPLE USINGTHIS PRODUCT

EMERGENCYINFORMATION:CALLCHEMTREC(800) 424-9300
Page 395 of 516

P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302+352 IF ON SKIN: Wash with soap & water.
P304+340 IF INHALED: Remove victim to fresh air & keep at rest in a position comfortable for breathing.
P305+351 +338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if
present & easy to do - Continue rinsing.
P308+P313 - If exposed or concerned: Get medical advice/attention
P309+311 If exposed or you feel unwell: Call a POISON CENTER or doctor/physician.
P332+313 If skin irritation occurs: Get medical advice/attention.
P337 +313 If eye irritation persists, get medical advice/attention.
P361- Remove/Take off immediatery all contaminated clothing.
P363 - Wash contaminated clothing before reuse.
P501 - Dispose of contents/container in accordance with local, regional, national and international
regulation.
SEE SECTIONS 8, 11 & 12 FOR TOXICOLOGICAL INFORMATION.
Section 3, Composition / Information on Ingredients

Mixture
MATERIAL CAS# EINECS# WT
Talc 14807-96-6 238-877-9 40-60%
Chlorite-group minerals 1318-59-8 215-285-9 5-20%
Iron Oxide 1332-37-2 215-570-8 2-10%
Quarts (impurity) 14808-60-7 215-683-2 0-3%
TRACE COMPONENTS: Trace ingredients (if any) are present in < 1% concentration. None of the trace
ingredients contribute significant aaditional hazards at the concentrations that may be present in this
product. Trade Secret Component is non-hazardous. All pertinent hazard information has been provided in
this document, per the requirements of the Federal Occupational Safety and Health Administration
Standard (29 CFR 1910.1200), U.S. State equivalents, and Canadian Razardous Materials Identification
System Standard (CPR 4).
Section 4, First Aid Measures

4.1 MOST IMPORTANT SYMPTOMS/EFFECTSI ACUTE & DELAYED:
See Section 11 for symptoms/effects, acute & de ayed.
4.2 GENERAL ADVICE:
First Aid responders should pay attention to self-protection and use the recommended protective clothing
(chemical resistant gloves, splash protection). If potential for exposure exists, refer to Section 8 for specific
personal protective equipment.
4.3 EYE CONT ACT:
If this product enters the eyes, open eyes while under gently running water. Use sufficient force to open
eyelids. "Roll" eyes to expose more surface. Minimum flushing's for f5 minutes. Seek immediate medical
attention.
4.4 SKIN CONTACT:
If the product contaminates the skin, wash with soapy water.
4.5 INHALATION:
After high vapor exposure, remove to fresh air.
4.6 SWALLOWING:
If swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. If professional advice is not available, give two glasses of water to drink. DO NOT
INDUCE VOMITING. Never induce vomiting or give liquids to someone who is unconscious, having
convulsions, or unable to swallow. Seek immediate medical attention.
4.7 NOTES TO PHYSICIAN:
There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms
and the clinical condition of the patient. Any material aspirated during vomiting may cause lung injury.
Therefore, emesis should not be induced mechanically or pharmacofogically. lf it is considered necessary
to evacuate the stomach contents, this should be done by means leasf likely to cause aspiration (such as:
Gastric lavage after endotracheal intubation).
2
SDS No. 101- Perma-Cast® Antiquing Release
PLEASEENSURE THAT THIS SDS IS GIVENTO AND EXPLAINEDTO PEOPLE USINGTHIS PRODUCT
Page 396 of 516

Section 5, Fire Fighting Measures
5.1 FIRE & EXPLOSION PREVENTIVE MEASURES:

The material is non-flammable and will not support combustion.
5.2 SUITABLE (& UNSUITABLE) EXTINGUISHING MEDIA:
NA.
5.3 SPECIAL PROTECTIVE EQUIPMENT & PRECAUTIONS FOR FIRE FIGHTERS:
NA.
5.4 SPECIFIC HAZARDS OF CHEMICAL & HAZARDOUS COMBUSTION PRODUCTS:
NA
Section 6, Accidental Release Measures
6.1 SPILL AND LEAK RESPONSE AND ENVIRONMENTAL PRECAUTIONS:

Isolate and contain spill. Avoid excessive dust generation and runoff into a sewer or waterway. Materials
can be collected and reused if possible. Place waste in a disposal container and dispose of in accordance
with local and state RCRA rules and regulation.
6.2 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, EMERGENCY PROCEDURES:
A disposal dusk mask can be used to prevent excessive dust accumulation.
6.3 ENVIRONMENTAL PRECAUTIONS:
NA.
6.4 METHODS AND MATERIAL FOR CONTAINMENT & CLEAN-UP:
Pick up material and reuse as needed.
Section 7, Handling and Storage
7.1 PRECAUTIONS FOR SAFE HANDLING:

Standard work gloves, disposable dust mask to control excessive dust.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
Store in a cool, dry location. Isolate from Fluorine, magnesium, acids, alum, ammonium salts.
Section 8, Exposure Controls/ Personal Protective Equipment
8.1 EXPOSURE LIMITS:

MATERIAL CAS# EINECS# TWA (OSHA) TLV (ACGIH)
Quarts (impurity) 14808-60-7 215-683-2 0.025 mg/m 3
3
Talc 14807-96-6 238-877-9 2 mglm
Iron 1332-37-2 215-168-2 10 mg/m 3
8.2 APPROPRIATE ENGINEERING CONTROLS:

RESPIRATORY EXPOSURE CONTROLS
Maintain airborne contaminant concentrations below exposure limits given above. If respiratory protection
is needed, use only protection authorized in 29 CFR 1910.134, European Standard EN 149, or applicable
State regulations.
EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS
NA.
VENTILATION
LOCAL EXHAUST: If Necessary MECHANICAL (GENERAL): If Necessary
SPECIAL: None OTHER: None
Please refer to ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most
recent edition, for details.
3
SOS No. 101- Perma-Cast® Antiquing Release
PLEASE ENSURETHAT THIS SOS IS GIVENTO AND EXPLAINEDTO PEOPLE USINGTHIS PRODUCT
Page 397 of 516

8.3 INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
Splash goggles or safety glasses.
HAND PROTECTION:
Use standard cloth work gloves.
BODY PROTECTION:
Use body protection appropriate for task. Coveralls, are generally acceptable, depending on the task.
WORK & HYGIENIC PRACTICES:
Provide readily accessible eye wash stations & safety showers. Wash at end of each shift & before
eating, smoking or using the toilet. Remove clothing that becomes contaminated.
Section 9, Physical & Chemical Properties
APPEARANCE: Color Pigmented Powder (Color Varies)

ODOR: No Odor
ODOR THRESHOLD: Not Available
pH (Neutrality): Not Available
MEL TING POINT/FREEZING POINT: Not Available
BOILING RANGE (IBP,50%,Dry Point): Not Applicable
FLASH POINT (TE:ST METHOD): Not Applicable
EVAPORATION RATE (n-Butyl Acetate=1): Not Applicable
FLAMMABILITY CLASSIFICATION: Not Applicable
LOWER FLAMMABLE LIMIT IN AIR ~% by vol): Not Applicable
UPPER FLAMMABLE LIMIT IN AIR (% by vol): Not Available
VAPOR PRESSURE (mm of Hg)@20 C Not Applicable
VAPOR DENSITY (air-1): Not Applicable
GRAVITY @ 68/68 F / 20/20 C:
DENSITY: Not Available
SPECIFIC GRAVITY (Water=1): Not Available
POUNDS/GALLON: Not Available
WATER SOLUBILITY: Insoluble
PARTITION COEFFICIENT (n-Octane/Water): Not Available
DENSITY: Not Available
DECOMPOSITION TEMPERATURE: Not Available
voes (>0.044 Lbs./Sg In) : Not Applicable
TOTALVOC'S (TVOC)*: Not Applicable
NONEXEMPT VOC'S (CVOC)*: Not Applicable
HAZARDOUS AIR POLLUTANTS (HAPS): Not Applicable
NONEXEMPT voe PRESSURE (mm of Hg @ 20 C) Not Applicable
VISCOSITY~ 20 C (ASTM D445): Not Applicable
* Using CARB"(California Air Resources Board Rules).
Section 10, Stability & Reactivity
10.1 REACTIVITY & CHEMICAL STABILITY:

10.2 POSSIBILITY OF HAZARDOUS REACTIONS & CONDITIONS TO AVOID:
NL.
10.3 INCOMPATIBLE MATERIALS:
Isolate from Fluorine, magnesium, acids, alum, ammonium salts,
10.4 HAZARDOUS DECOMPOSITION PRODUCTS:
NL.
10.5 HAZARDOUS POLYMERIZATION:
Will not occur.
4
PLEASE ENSURE THAT THIS SDS IS GIVENTO AND EXPLAINEDTO PEOPLE USINGTHIS PRODUCT
Page 398 of 516

Section 11, Toxicological Information
11.1 ACUTE HAZARDS

11.11 EYE & SKIN CONTACT:
Primary dust irritation to skin, and eyes.
Primary irritation to eyes, redness, tearing, blurred vision.
Wash thoroughly after handling with soap and water.
11.12 INHALATION:
Irritates respiratory tract.
11.13 SWALLOWING:
Harmful if swallowed. Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
11.2 SUBCHRONIC HAZARDS/CONDITIONS AGGRAVATED
CONDITIONS AGGRAVATED
NL
11.3 CHRONIC HAZARDS
11.31 NL
11.4 MAMMALIAN TOXICITY INFORMATION

MATERIAL CAS# EINECS# LOWEST KNOWN LETHAL DOSE DATA
LOWEST KNOWN LOSO(ORAL)
NL
Section 12, Ecological Information
12.1 ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL

CONTAMINATION.
12.2 EFFECT OF MATERIAL ON PLANTS AND ANIMALS:
NL.
12.3 EFFECT OF MATERIAL ON AQUATIC LIFE:
NL.
12.4 MOBILITY IN SOIL
Mobility of this material has not been determined.
12.5 DEGRADABIUTY
Will not degrade.
12.6 ACCUMULATION
Bioaccumulation of this product has not been determined.
Section 13, Disposal Considerations
Material may be picked up, reclaimed and reused.
Section 14, Transportation Information
MARINE POLLUTANT: No
DOTfTDG SHIP NAME: Non Regulated
DRUM LABEL: Non Regulated
IATA / ICAO: Non Regulated
IMO/ IMDG: Non Regulated
5
SDS No. 101 - Perma-Cast® Antiquing Release
PLEASE ENSURETHAT THIS SDS IS GIVENTO AND EXPLAINEDTO PEOPLE USING THIS PRODUCT
Page 399 of 516

Section 15, Regulatory Inforrnation
15.1 EPA REGULATION:

SARA SECTION 311/312 HAZARDS: Non Hazardous, No Sara Reportable
All components of this product are on the TSCA list.

SARA Title Ill Section 313 Supplier Notification
SARA TITLE Ill INGREDIENTS GAS# EINECS# WT% (REG.SECTION) RQ(LBS)

None Listed
15.2 STATE REGULATIONS:

CALIFORNIA SAFE DRINKING WATER & TOXIC ENFORCEMENT ACT (PROPOSITION 65):
This product contains is not listed.
15.3 INTERNATIONAL REGULATIONS
NA
15.4 CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
NA
Section 16, Other Information
16.1 HAZARD RATINGS:

HEAL TH (NFPA): 0, HEAL TH (HMIS): 0, FLAMMABILITY: 0, PHYSICAL HAZARD: 0
(Personal Protection Rating to be supplied by user based on use conditions.)
This information is intended solely for the use of individuals trained in the Nf='PA& HMIS hazard rating
systems.
16.2 EMPLOYEE TRAINING
Employees should be made aware of all hazards of this material (as stated in this SOS) before handling it.
16.3 SOS DATE: 5/29/15
Notice:
Butterfield Color expressly disclaims all express or implied warranties of merchantability and fitness for a particular
purpose with respect to the product or information provided herein, and shall under no circumstances be liable for
incidental or consequential damages.
All information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources.
While the information is believed to be accurate, we make no representations as to its accuracy or sufficiency.
Conditions of use are beyond our control, and therefore users are responsible for verifying the data under their own
operating conditions to determine whether the product is suitable for their particular purposes and they assume all
risks of their handling, and disposal of the product. Users also assume all risks in regards to the publication or use of,
or reliance upon information contained herein.
This infonmation relates only to the product designated herein, and does not relate to its use in combination with any
other material or process.
Prepared By: HS&E Compliance Resources
6
PLEASEENSURETHAT THIS SDS IS GIVENTO AND EXPLAINEDTO PEOPLE USINGTHIS PRODUCT

Page 400 of 516

Product Number 803 SAFETY DATA SHEET
Issuing Date No data available Revision Date 08-Nov-2013 Revision Number 1
The supplier identified below generated this SOS using the UL SOS template. UL did not test, certify, or approve the substance described in this SOS,
and all information in this SOS was provided by the supplier or was reproduced from pub/ical/y available regulatory data sources. UL makes no
representations or warranties regarding the completeness or accuracy of the information in this SOS and disclaims all liability in connection with the use of
this information or the substance described in this SOS. The layout, appearance and format of this SOS is© 2014 UL LLC. All rights reserved.
Product identifier
Product Name Mineral Spirits
Synonyms None
Recommended Use Paint Thinner (*Note Future CARB requirements: 2013 - 3 wt%)
Supplier Name Sunnyside Corporation

Supplier Address 225 Carpenter Avenue
Wheeling
IL
60090
us
Supplier Phone Number Phone:8003238611
Fax:8475419043
Supplier Email sscontact@sunnysidecorp.com

Emergency telephone number Chem Tree 8004249300
Classification
Cate o
Cate o 3
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1119374- Mineral Spirits Revision Date 08-Nov-2013
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Warning
Hazard State~
May be fatal if swallowed and enters airways
Flammable liquid and vapor
Appearance Clear Physical State Liquid Odor Petroleum distillate

Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge

None
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Do NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction

Store locked up
Store in a well-ventilated place. Keep cool

Not applicable
Unknown Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
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111937 4 - Mineral Spirits Revision Date 08-Nov-2013
Other information
Interactions with Other Chemicals

Chemical Name CAS No Weight-% Trade Secret

Solvent naphtha petroleum , medium aliphatic 64742-88-7 60 - 100
*The exact percentage(concentration)of composition has been withheld as a trade secret
First aid measures
General Advice Show this safety data sheet to the doctor in attendance.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. If eye irritation persists: Get medical advice/attention.
Skin Contact Wash skin with soap and water. Get medical attention if irritation develops and
persists. Take off contaminated clothing and wash before reuse.
Inhalation If symptoms persist, call a physician.
Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center
immediately.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take
precautions to protect themselves and prevent spread of contamination.
Most Important Symptoms and Difficulty in breathing. Dizziness.

Effects
Notes to Physician Treat symptomatically. Because of the danger of aspiration, emesis or gastric
lavage should not be employed unless the risk is justified by the presence of
additional toxic substances.
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Suitable Extinguishing Media

Use:. Dry chemical, CO2, water spray or regular foam.
Unsuitable Extinguishing Media

CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient.

Vapors can form explosive mixtures with air. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.).
Vapors may travel to source of ignition and flash back.
Uniform Fire Code Combustible Liquid: II
Hazardous Combustion Products

Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes.

protective gear.
Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Pay
attention to flashback. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Do not touch or walk
through spilled material.
Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces.
Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas.
Methods for Containment A vapor suppressing foam may be used to reduce vapors.
Methods for cleaning up Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal
binder, sawdust). Use clean non-sparking tools to collect absorbed material. Clean up
promptly by sweeping or vacuum. Keep in suitable, closed containers for disposal.
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Revision Date 08-Nov-2013
1119374- Mineral Spirits
Handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use grounding and
bonding connection when transferring this material to prevent static discharge, fire or
explosion. Use according to package label instructions. Use personal protection equipment.
Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment.
Avoid contact with skin, eyes or clothing. Avoid breathing vapors or mists.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture. Store locked up. Keep out of the reach of children. Store away from other
materials. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot
lights, electric motors and static electricity). Keep in properly labeled containers. Do not
store near combustible materials. Keep in an area equipped with sprinklers. Store in
accordance with the particular national regulations. Store in accordance with local
regulations.
Incompatible Products Strong oxidizing agents.
Control parameters
exposure limits established by the region specific regulatory bodies
Engineering Measures Showers

Eyewash stations
Ventilation systems
Eye/Face Protection Tight sealing safety goggles.
Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant
apron. Impervious gloves. Antistatic boots.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Contaminated work clothing should not be allowed out of
the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product.
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Physical and Chemical Properties
Physical State Liquid

Appearance Clear Odor Petroleum distillates
Color No information available Odor Threshold No information available
Property Values Remarks/ Method

pH UNKNOWN None known
Melting/ freezing point No data available None known
Boiling point/ boiling range 157 °C / 315 °F None known
Flash Point 42 C I 108 F None known
Evaporation Rate No data available None known
Flammability (solid, gas) No data available None known
Upper flammability limit No data available
Lower flammability limit No data available
Vapor pressure No data available None known
Vapor density No data available None known
Specific Gravity No data available None known
Water Solubility Insoluble in water None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive properties No data available
Oxidizing Properties No data available
Other Information
Softening Point No data available

VOC Content(%) No data available
Particle Size No data available
Particle Size Distribution
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111937 4 - Mineral Spirits
Reactivity
No data available.
Chemical stability

Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks.

Carbon oxides.
.
Product Information Product does not present an acute toxicity hazard based on known or supplied information
and
Inhalation Specific test data for the substance or mixture is not available. May cause drowsiness
dizziness.
Eye Contact Specific test data for the substance or mixture is not available.
Skin Contact Specific test data for the substance or mixture is not available.
if
Ingestion Specific test data for the substance or mixture is not available. Potential for aspiration
swallowed . May be fatal if swallowed and enters airways.
Component Information
Oral LD50 Dermal LD50 Inhalation LC50

Chemical Name
> 5000 mg/kg (Rat) = 3000 mg/kg (Rabbit) > 5.28 mg/L (Rat}4h
Solvent naphtha (petroleum),
medium aliphatic
64742-88-7
Symptoms Difficulty in breathing. Vapors may cause drowsiness and dizziness.
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Mutagenic Effects No information available.
Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity No information available.
Target Organ Effects Respiratory system.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
ATEmix (dermal)
3,000.00 mg/kg (ATE)
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water
Microorganisms Flea)
Solvent naphtha (petroleum), 96h EC50: =450 mg/L 96h LC50: = 800 mg/L 48h EC50: > 100 mg/L
medium aliphatic (Pseudokirchneriella (Pimephales promelas)
64742-88-7 subcapitata)
Persistence and Deqradability

Bioaccum ulation
Other adverse effects

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Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
US EPA Waste Number 0001
California Hazardous Waste Codes 213
DOT NOT REGULATED (If shipped in NON BULK packaging by ground transport)
Proper Shipping Name NON-REGULATED
Hazard Class N/A
Emergency Response Guide 128
Number
TOG
UN-No. UN1268
Proper Shipping Name PETROLEUM DISTILLATES, N.O.S.
Hazard Class 3
Packing Group Ill
MEX
UN-No. UN1268
Proper Shipping Name Petroleum distillates, n.o.s.
Hazard Class 3
Packing Group Ill
Description UN1268 Petroleum distillates, n.o.s., 3, Ill
ICAO
UN-No. UN1268
Hazard Class 3
Packing Group Ill
Description 1268,Petroleum distillates, n.o.s.,3,PG Ill
IATA
UN-No. 1268
Proper Shipping Name PETROLEUM DISTILLATES, N.O.S.
Hazard Class 3
Packing Group Ill
Description UN1268,Petroleum distillates, n.o.s.,3,PG Ill
IMDG/IMO
UN-No. 1268
Page 9 / 12
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Hazard Class 3
Packing Group Ill
EmS No. F-E, S-E
Description 1268, Petroleum distillates, n.o.s.,3,PG Ill, FP 42C
RID
UN-No. 1268
Hazard Class 3
Packing Group Ill
Classification code F1
Description 1268 Petroleum distillates, n.o.s.,3,11I
ADR
UN-No. UN1268
Hazard Class 3
Packing Group Ill
Description UN1268 Petroleum distillates, n.o.s.,3,11I
ADN
UN-No. UN1268
Hazard Class 3
Packing Group Ill
Description UN1268 Petroleum distillates, n.o.s.,3, Ill
Hazard Labels 3
Limited Quantity LQ7
Ventilation VE01
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA- United States Toxic Substances Control Act Section 8(b) Inventory
SARA313
SARA311/312 Hazard Categories

Acute Health Hazard Yes
Fire Hazard Yes
Reactive Hazard No
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This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This product does not contain any Proposition 65 chemicals.
Chemical Name New Jerse Massachusetts Penns lvania Rhode Island Illinois
Solvent naphtha (petroleum), medium aliphatic X
64742-88-7
International Regulations
Canada
WHMIS Hazard Class
B3 - Combustible liquid
NFPA Health Hazards Flammability 2 Instability O Physical and

Chemical Hazards -
HMIS Health Hazards Flammability 2 Physical Hazard O Personal Protection
X
Prepared By Product Stewardship

23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Note No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
Page 11 / 12
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Page 12 / 12
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I3M™Primer 94 (Ampoules) 02/20/18
Safety Data Sheet

Copyright,2018,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 07-0925-3 Version Number: 21.02

Issue Date: 02/20/18 Supercedes Date: 01/19/18
1.1. Product identifier

3MTMPrimer 94 (Ampoules)
Product Identification Numbers

70-0062-1013-5, 70-0064-4727-3, 70-0160-5482-0, 70-0160-5483-8, 70-0160-5484-6, 70-0160-5498-6, 70-0160-5509-0, 70-
0160-9260-6, 75-0400-2413-7, 75-3500-1055-1
1.2. Recommended use and restrictions on use
Recommended use
Adhesive Primer, Industrial use
1.3. Supplier's details

MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: l-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)
2.1. Hazard classification

Flammable Liquid: Category 2.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.
Aspiration Hazard: Category 1.
Reproductive Toxicity: Category lB.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements

Signal word
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I3MTMPrimer 94 (Ampoules) 02/20/18
Danger
Symbols
Flame I Exclamation mark I Health Hazard I
Pictograms
Hazard Statements
Highly flammable liquid and vapor.

May be fatal if swallowed and enters airways.
May damage fertility or the unborn child.
Suspected of causing cancer.
Causes damage to organs:

sensory organs I
Causes damage to organs through prolonged or repeated exposure:

nervous system I
May cause damage to organs through prolonged or repeated exposure:

sensory organs I
Prevention:
Obtain special instructions before use.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electricaVventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
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j 3MTMPrimer 94 (Ampoules) 02/20/18
If skin irritation or rash occurs: Get medical advice/attention.

Wash contaminated clothing before reuse.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Do NOT induce vomiting.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Keep cool.
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2% ofthemixture consists of ingredients ofunknown acute oral toxicity.

2% of the mixture consists of ingredients of unknown acute dermal toxicity.
Ingredient C.A.S. No. %byWt

Cyclohexane 110-82-7 30 - 60 Trade Secret *
Xylene 1330-20-7 20 - 3 5 Trade Secret *
Ethylbenzene 100-41-4 < 11 Trade Secret *
Ethyl Alcohol 64-17-5 5 - 10 Trade Secret*
Ethyl Acetate 141-78-6 1 - 5 Trade Secret *
Acrylic Polymer (NITS Reg No 04499600-5984P) Trade Secret* 1 - 5 Trade Secret *
Chlorinated Polyolefin 68609-36-9 < 2 Trade Secret *
Methyl Alcohol 67-56-1 0.1 - 1.0 Trade Secret *
Epoxy Resin 25068-38-6 < 0.5 Trade Secret*
Toluene 108-88-3 < 0.5 Trade Secret*
Chlorobenzene 108-90-7 <= 0.11 Trade Secret *
NITS or NJTSRN: New Jersey Trade Secret Registry Number.
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms
develop, get medical attention.
Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.
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I3M™ Primer 94 (Ampoules) 02/20/18
If Swallowed:
Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products

Substance Condition
Aldehydes During Combustion
Formaldehyde During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion
5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
6.1. Personal precautions, protective equipment and emergency procedures

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with
fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn
or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection,
ventilation, and peF~onal prote.;tive equipment.
6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up

Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up
residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and
follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
Page 4 of 18
Page 416 of 516
7.1. Precautions for safe handling

Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot
surfaces. - No smoking. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in
eyes, on skin, or on clothing. Do not eat, chink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash
contaminated clothing before reuse. A void contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal
protective equipment (gloves, respirators, etc.) as required.
7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from
acids. Store away from oxidizing agents.
8.1. Control parameters
Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
£or th e component.
In~redient C.A.S.No. A~ency Limit type Additional Comments
Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm)
Ethylbenzene 100-41-4 ACGIH TWA:20ppm A3: Confirmed animal
carcin.
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human
carcm
Chlorobenzene 108-90-7 ACGIH TWA:10 ppm A3: Confirmed animal
carcin.
Chlorobenzene 108-90-7 OSHA TWA:350 mg/m3(75 ppm)
Cyclohexane 110-82-7 ACGIH TWA:l0Oppm
Cyclohexane 110-82-7 OSHA TWA: 1050 mg/m3(300 nnm)
Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human
carcin
Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm)
Ethyl Acetate 141-78-6 ACGIH TWA:400ppm
Ethyl Acetate 141-78-6 OSHA TWA:1400 mg/m3(400 ppm)
Ethyl Alcohol 64-17-5 OSHA TWA:1900 mg/m3(1000 ppm)
Ethyl Alcohol 64-17-5 ACGIH STEL:1000 ppm A3: Confirmed animal
carcin.
Methyl Alcohol 67-56-1 OSHA TW A:260 mg/m3(200 ppm)
Methyl Alcohol 67-56-1 ACGIH TW A:200 ppm;STEL:250 ppm SKlN
ACGIH: Amencan Conference of Governmental lndustnal Hyg1emsts
AIHA : American Industrial Hygiene Association
CMRG: Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2 ..Exposure controls
8,2.1. Engineering controls

l,Jse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Page 5 of 18
Page 417 of 516
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respirat01y protection equipment.
Use explosion~proofventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
Halffacepiece or full facepiece supplied-air respirator
For questions about suitability for a specific application, consult with your respirator manufacturer.
9.1. Information on basic physical and chemical properties

General Physical Form: Liquid
Specific Physical Form: Liquid
Odor, Color, Grade: Amber colored, solvent odor
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point 170 °F
Flash Point 1 °F [Test Method.·Closed Cup]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) 1%
Flammable Limits(UEL) 11%
Vapor Pressure 68 mmHg [@ 68 °F]
Vapor Density No Data Available
Density 0.82 g/ml
Specific Gravity 0.82 [@ 77 °F] [RefStd:WATER=I]
Solubility in Water Negligible
Solubility- non-water No Data Available
PartitiOll coefficient: n-octanol/ water No Data Available
Page 6 of 18
Page 418 of 516
Autoignition temperature No Data Available

Decomposition temperature No Data Available
Viscosity 1 - 35 centipoise [@ 73.4 °F]
Hazardous Air Pollutants 35.2 - 45.3 % weight [Test Method:Calculated]
Molecular weight No Data Available
Volatile Organic Compounds 781 g/1 [Test Method.·calculated SCAQMD rule 443.1]
[Details: low solids less exempts]
Percent volatile 95.3 - 97 % weight [Test Method.·Estimated]
VOC Less H2O & Exempt Solvents <=97 % [Test Method:calculated per CARB title 2]
10.1. Reactivity
This material is considered to be non reactive under nonnal use conditions.
10.2. Chemical stability

Stable.
10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.
10.4. Conditions to avoid

Heat
Sparks and/or flames
10.5. Incompatible materials

Strong oxidizing agents
10.6. Hazardous decomposition products

Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
May be harmful if inhaled.
Respiratory Tract IITitation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
Page 7 of 18
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I3MrM Primer 94 (Ampoules) 02/20/18
May cause additional health effects (see below).
Skin Contact:
May be harmful in contact with skin.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin
Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth,
difficulty breathing, bluish colored skin (cyanosis ), and may be fatal.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Additional Health Effects:
Single exposure may cause target organ effects:

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause target organ effects:

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
In redient CASNo. Class Descri tion Reaulation

Eth !benzene 100-41-4 G . 2B: Possible human care. International A enc , for Research on Cancer
Additional Information:
This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the
International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human
consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the
foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
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Name Route Species Value

Overall product Dermal No data available; calculated ATE2,000 - 5,000 mg/kg
Overall product Inhalation- No data available; calculated ATE20 - 50 mg/I
Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Cyclohexane Dermal Rat LD50 > 2 000 mg/kg
Cyclohexane Inhalation- Rat LC50 > 32.9 mg/I
Vapor (4
hours)
Cyclohexane Ingestion Rat LD50 6,200 mg/kg
Xylene Dem1al Rabbit LD50 > 4,200 mg/kg
Xylene Inhalation- Rat LC50 29mg/I
Vapor (4
hours)
Xvlene Ingestion Rat LD50 3,523 mg/kg
Ethyl benzene Dermal Rabbit LD50 15,433 mg/kg
Ethyl benzene Inhalation- Rat LC50 17.4 mg/I
Vapor (4
hours)
Ethyl benzene Ingestion Rat LD50 4,769 mg/kg
Ethyl Alcohol Dermal Rabbit LD50 > 15,800 mg/kg
Ethyl Alcohol Inhalation- Rat LC50 124.7 mg/I
Vapor (4
hours)
Ethvl Alcohol Ingestion Rat LD50 17,800 mg/kg
Ethyl Acetate Dermal Rabbit LD50 > 18,000 mg/kg
Ethyl Acetate Inhalation- Rat LC50 70.5 mg/I
Vapor (4
hours)
Ethvl Acetate Ingestion Rat LD50 5,620 mg/kg
Chlorinated Polyolefin Dermal Guinea LD50 > 1,000 mg/kg
pig
Chlorinated Polyolefrn Ingestion Rat LD50 > 3,200 mg/kg
Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg
Methyl Alcohol Inhalation- LC50 estimated to be 10 - 20 mg/I
Vapor
Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg
EooxvResin Dermal Rat LD50 > 1,600 mg/kg
Eooxv Resin Ingestion Rat LD50 > 1,000 mg/kg
Toluene Dermal Rat LD50 12 000 mg/kg
Toluene Inhalation- Rat LC50 30mg/I
Vapor (4
hours)
Toluene Ingestion Rat LD50 5 550 rug/kg
Chlorobenzene Dermal Rabbit LD50 2 212 mg/kg
Oilorobenzene Inhalation- Rat LC50 16.7 mg/I
Vapor (4
hours)
Chlorobenzene Ingestion Rat LD50 1,419 mg/kg
ATE = acute toxicity estimate
Name Species Value
Cvclohexane Rabbit Mild irritant

Xylene Rabbit Mild irritant
Ethvlbenzene Rabbit Mild irritant
Ethyl Alcohol Rabbit No significant irritation
Ethyl Acetate Rabbit Minimal irritation
Chlorinated Polyolefin Guinea No significant irritation
pig
Methyl Alcohol Rabbit Mild irritant
Epoxy Resin Rabbit Mild irritant
Toluene Rabbit Irritant
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Chlorobenzene Rabbit Irritant
senous E,ve D amaee rn a 10n

Name Species Value
Cvclohexane Rabbit Mild irritant

Xvlene Rabbit Mild irritant
Ethvlbenzene Rabbit Moderate irritant
Ethyl Alcohol Rabbit Severe irritant
Ethvl Acetate Rabbit Mild irritant
Chlorinated Polyolefin Professio Mild irritant
nal
judgeme
nt
Methvl Alcohol Rabbit Moderate irritant
Epoxy Resin Rabbit Moderate irritant
Toluene Rabbit Moderate irritant
Chlorobenzene Rabbit Mild irritant
Skin Sensitization
Name Species Value
Ethvlbenzene Human Not classified
Ethvl Alcohol Human Not classified
Ethyl Acetate Guinea Not classified
pig
Methyl Alcohol Guinea Not classified
pig
Epoxy Resin Human Sensitizing
and
animal
Toluene Guinea Not classified
oig
Chlorobenzene Multiple Not classified
animal
soecies
Resmra t orv sensI"fIZafIon

Name Species Value
EooxvResin Human Not classified
Germ Cell Mutae:enicitv

Name Route Value
Cvclohexane In Vitro Not mutagenic

Cyclohexane In vivo Some positive data exist, but the data are not
sufficient for classification
Xylene In Vitro Not mutagenic
Xylene In vivo Not mutagenic
Ethvlbenzene In vivo Not mutagenic
Ethyl benzene In Vitro Some positive data exist, but the data are not
Ethyl Alcohol In Vitro Some positive data exist, but the data are not
Ethyl Alcohol In vivo Some positive data exist, but the data are not
Ethyl Acetate In Vitro Not muta_genic
Ethvl Acetate In vivo Not mutagenic
Methyl Alcohol In Vitro Some positive data exist, but the data are not
Methyl Alcohol In vivo Some positive data exist, but the data are not
Epoxy Resin In vivo Not mutagenic
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Epoxy Resin In Vitro Some positive data exist, but the data are not
Toluene In Vitro Not mutagenic
Toluene In vivo Not muta.e;enic
Chlorobenzene In Vitro Not mutagenic
Carcinogenicity
Name Route Soecies Value
Xvlene Dem1al Rat Not carcinogenic
Xylene Ingestion Multiple Not carcinogenic
animal
species
Xylene Inhalation Human Some positive data exist, but the data are not
Ethyl benzene Inhalation Multiple Carcinogenic
animal
soecies
Ethyl Alcohol Ingestion Multiple Some positive data exist, but the data are not
animal sufficient for classification
species
Methyl Alcohol Inhalation Multiple Not carcinogenic
animal
soecies
Epoxy Resin Dermal Mouse Some positive data exist, but the data are not
Toluene Dermal Mouse Some positive data exist, but the data are not
Toluene Ingestion Rat Some positive data exist, but the data are not
Toluene Inhalation Mouse Some positive data exist, but the data are not
Chlorobenzene Ingestion Multiple Not carcinogenic
animal
species
Reproductive Toxicity
R epro duct1ve an d/ or D eve opmenta I Effects

Name Route Value Species Test Result Exposure
Duration
Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL24 2 generation
mg/I
Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL24 2 generation
mg/I
Cyclohexane Inhalation Not classified for development Rat NOAEL6.9 2 generation
mg/I
Xylene Inhalation Not classified for female reproduction Human NOAELNot occupational
available exposure
Xylene Ingestion Not classified for development Mouse NOAELNot during
available organogenesi
s
Xylene Inhalation Not classified for development Multiple NOAELNot during
animal available gestation
soecies
Ethyl benzene Inhalation Not classified for development Rat NOAEL 4.3 premating &
mg/1 during
gestation
Ethyl Alcohol Inhalation Not classified for development Rat NOAEL38 during
mg/I gestation
Ethyl Alcohol Ingestion Not classified for development Rat NOAEL5,200 prernating &
mg/kg/day during
gestation
Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600 21 days
mg/kg/day
Methvl Alcohol Ingestion Toxic to develooment Mouse LOAEL4,000 during
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mg/kg/day organogenesi
s
Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 during
mg/I organogenesi
s
Epoxy Resin Ingestion Not classified for female reproduction Rat NOAEL 750 2 generation
mg/kg/dav
Epoxy Resin Ingestion Not classified for male reproduction Rat NOAEL 750 2 generation
mg/kg/dav
Epoxy Resin Dermal Not classified for development Rabbit NOAEL300 during
s
Epoxy Resin Ingestion Not classified for development Rat NOAEL 750 2 generation
mg/kg/day
Toluene Inhalation Not classified for female reproduction Human NOAELNot occupational
available exoosure
Toluene Inhalation Not classified for male reproduction Rat NOAEL2.3 1 generation
mg/I
Toluene Ingestion Toxic to development Rat LOAEL520 during
mg/kg/day gestation
Toluene Inhalation Toxic to development Human NOAELNot poisonmg
available and/or abuse
Chlorobenzene Inhalation Not classified for female reproduction Rat NOAEL2.07 2 generation
mg/I
Chlorobenzene Ingestion Not classified for development Rat NOAEL300 during
s
Chlorobenzene Inhalation Not classified for development Rat NOAEL2.07 2 generation
mg/I
Chlorobenzene Inhalation Not classified for male reproduction Rat NOAEL2.07 2 generation
mg/I
Lactation
Name Route S ecies Value

X Jene In estion Mouse Not classified for effects on or via lactation
Target Organ(s)
Suecific Tar2:et Or2:an Toxicity - sin2:le exuosure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Cyclohexane Inhalation central nervous May cause drowsiness or Human NOAELNot
system depression dizziness and available
animal
Cyclohexane Inhalation respiratory irritation Some positive data exist, but the Human NOAELNot
data are not sufficient for and available
classification animal
Cyclohexane Ingestion central nervous May cause drowsiness or Professio NOAELNot
system depression dizziness nal available
judgeme
nt
Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 8 hours
mg/I
Xylene Inhalation central nervous May cause drowsiness or Human NOAELNot
svstem deoression dizziness available
Xylene Inhalation respiratory irritation Some positive data exist, but the Human NOAELNot
data are not sufficient for available
classification
Xylene Inhalation eyes Not classified Rat NOAEL3.5 not available
mg/I
Xylene Inhalation liver Not classified Multiple NOAELNot
animal available
species
Xylene Ingestion central nervous May cause drowsiness or Multiple NOAELNot
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system depression dizziness animal available

species
Xylene Ingestion eyes Not classified Rat NOAEL250 not applicable
mg/kg
Ethyl benzene Inhalation central nervous May cause drowsiness or Human NOAELNot
Ethyl benzene Inhalation respiratory irritation Some positive data exist, but the Human NOAELNot
data are not sufficient for and available
classification animal
Ethyl benzene Ingestion central nervous May cause drowsiness or Professio NOAELNot
system depression dizziness nal available
judgeme
nt
Ethyl Alcohol Inhalation central nervous May cause drowsiness or Human LOAEL2.6 30 minutes
system depression dizziness mg/I
Ethyl Alcohol Inhalation respiratory irritation Some positive data exist, but the Human LOAEL9.4 not available
data are not sufficient for mg/I
classification
Ethyl Alcohol Ingestion central nervous May cause drowsiness or Multiple NOAELnot
system depression dizziness animal available
species
Ethyl Alcohol Ingestion kidney and/or Not classified Dog NOAEL
bladder 3,000 mg/kg
Ethyl Acetate Inhalation central nervous May cause drowsiness or Human NOAELNot
system depression dizziness available
Ethyl Acetate Inhalation respiratory irritation Some positive data exist, but the Human NOAELNot
classification
Ethyl Acetate Ingestion central nervous May cause drowsiness or Human NOAELNot
Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAELNot occupational
available exposure
Methyl Alcohol Inhalation central nervous May cause drowsiness or Human NOAELNot not available
system depression dizziness available
Methyl Alcohol Inhalation respiratory irritation Some positive data exist, bnt the Rat NOAELNot 6 hours
classification
Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAELNot poisoning
available and/or abuse
Methyl Alcohol Ingestion central nervous May cause drowsiness or Human NOAELNot poisoning
svstem deoression dizziness available and/or abuse
Toluene Inhalation central nervous May cause drowsiness or Human NOAELNot
svstem depression dizziness available
Toluene Inhalation respiratory irritation Some positive data exist, but the Human NOAELNot
classification
Toluene Inhalation immnne system Not classified Mouse NOAEL 3 hours
0.004mg/I
Toluene Ingestion central nervous May cause drowsiness or Human NOAELNot poisoning
svstem deoression dizziness available and/or abuse
Chlorobenzene Inhalation central nervous May cause drowsiness or Human NOAELNot
svstem depression dizziness available
Chlorobenzene Inhalation respiratory irritation Some positive data exist, but the Human NOAELNot occupational
data are not sufficient for available exposure
classification
Specific Tar~et Or~an Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Cyclohexane Inhalation liver Not classified Rat NOAEL24 90 days
mg/I
Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 90 days
mg/I
Cyclohexane Inhalation kidney and/or Not classified Rabbit NOAEL2.7 10 weeks
bladder mg/l
Cvclohexane Inhalation hematopoietic Not classified Mouse NOAEL24 14weeks
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svstem mg/I
Cyclohexane Inhalation peripheral nervous Not classified Rat NOAEL 8.6 30 weeks
svstem mg/I
Xylene Inhalation nervous system Causes damage to organs through Rat LOAEL0.4 4 weeks
prolonged or repeated exposure mg/I
Xylene Inhalation auditory system May cause damage to organs Rat LOAEL 7.8 5 days
though prolonged or repeated mg/I
exposure
Xylene Inhalation liver Not classified Multiple NOAELNot
animal available
species
Xylene Inhalation heart I endocrine Not classified Multiple NOAEL3.5 13 weeks
system I animal mg/I
gastrointestinal tract species
I hematopoietic
system I muscles I
kidney and/or
bladder I respiratory
system
Xylene Ingestion auditory system Not classified Rat NOAEL900 2 weeks
mg/kg/day
Xylene Ingestion kidney and/or Not classified Rat NOAEL 90 days
bladder 1,500
mg/kg/dav
Xylene Ingestion liver Not classified Multiple NOAELNot
animal available
species
Xylene Ingestion heart I skin I Not classified Mouse NOAEL 103 weeks
endocrine system I 1,000
bone, teeth, nails, mg/kg/day
and/or hair I
hematopoietic
system I immune
system I nervous
system I respiratory
svstem
Ethyl benzene Inhalation kidney and/or Some positive data exist, but the Rat NOAEL 1.1 2 years
bladder data are not sufficient for mg/I
classification
Ethylbenzene Inhalation liver Some positive data exist, but the Mouse NOAEL 1.1 103 weeks
data are not sufficient for mg/I
classification
Ethyl benzene Inhalation hematopoietic Not classified Rat NOAEL3.4 28 days
system mg/I
Ethyl benzene Inhalation auditory system Not classified Rat NOAEL2.4 5 days
mg/I
Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 103 weeks
mi?/!
Ethyl benzene Inhalation gastrointestinal tract Not classified Rat NOAEL3.3 2 years
mg/I
Ethyl benzene Inhalation bone, teeth, nails, Not classified Multiple NOAEL4.2 90 days
and/ or hair I animal mg/I
muscles species
Ethylbenzene Inhalation heart I immune Not classified Multiple NOAEL3.3 2 years
system I respiratory animal mg/1
svstem species
Ethyl benzene Ingestion liver I kidney and/or Not classified Rat NOAEL680 6 months
bladder mg/kg/day
Ethyl Alcohol Inhalation liver Some positive data exist, but the Rabbit LOAEL 124 365 days
data are not sufficient for mg/1
classification
Ethyl Alcohol Inhalation hematopoietic Not classified Rat NOAEL25 14 days
system I immune mg/I
svstem
Ethyl Alcohol Ingestion liver Some positive data exist, but the Rat LOAEL 4 months
data are not sufficient for 8,000
classification mg/kg/dav
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Ethyl Alcohol Ingestion kidney and/or Not classified Dog NOAEL 7 days
bladder 3,000
mg/kg/day
Ethyl Acetate Inhalation endocrine system I Not classified Rat NOAEL 90 days
liver I nervous 0.043 mg/I
system
Ethyl Acetate Inhalation hematopoietic Not classified Rabbit LOAEL16 40 days
system n1g/l
Ethyl Acetate Ingestion hematopoietic Not classified Rat NOAEL 90 days
system I liver I 3,600
kidney and/or mg/kg/day
bladder
Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55 4 weeks
mg/I
Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1 6 weeks
mg/I
Methyl Alcohol Ingestion liver I nervous Not classified Rat NOAEL 90 days
system 2,500
mg/kg/day
Epoxy Resin Dermal liver Not classified Rat NOAEL 2 years
1,000
mg/kg/day
Epoxy Resin Dermal nervous system Not classified Rat NOAEL 13 weeks
1,000
mg/kg/day
Epm.'y Resin Ingestion auditory system I Not classified Rat NOAEL 28 days
heart I endocrine 1,000
system I mg/kg/day
hematopoietic
system I liver I eyes I
kidney and/or
bladder
Toluene Inhalation auditory system I Causes damage to organs through Human NOAEL Not poisoning
nervous system I prolonged or repeated exposure available and/or abuse
eyes I olfactory
system
Toluene Inhalation respiratory system Some positive data exist, but the Rat LOAEL2.3 15 months
data are not sufficient for mg/1
classification
Toluene Inhalation heart I liver I kidney Not classified Rat NOAEL 11.3 15 weeks
and/or bladder mg/I
Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 4 weeks
mg/I
Toluene Inhalation immune system Not classified Mouse NOAELNot 20 days
available
Toluene Inhalation bone, teeth, nails, Not classified Mouse NOAEL 1.1 8 weeks
and/or hair mg/I
Toluene Inhalation hematopoietic Not classified Human NOAELNot occupational
system Ivascular available exposure
system
Toluene Inhalation gastrointestinal tract Not classified Multiple NOAELll.3 15 weeks
animal mg/I
species
Toluene Ingestion nervous system Some positive data exist, but the Rat NOAEL625 13 weeks
data are not sufficient for mg/kg/day
classification
Toluene Ingestion heart Not classified Rat NOAEL 13 weeks
2,500
mg/kg/day
Toluene Ingestion liver I kidney and/or Not classified Multiple NOAEL 13 weeks
bladder animal 2,500
species mg/kg/day
Toluene Ingestion hematopoietic Not classified Mouse NOAEL600 14 days
system mg/kg/day
Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 28 days
mg/kg/day
Toluene Ingestion immune svstem Not classified Mouse NOAEL 105 4 weeks
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mg/kg/dav
Chlorobenzene Inhalation kidney and/or Some positive data exist, but the Rat LOAEL 0.69 2 generation
bladder data are not sufficient for mg/I
classification
Chlorohenzene Inhalation liver Not classified Rat NOAEL2.1 2 generation
mg/I
Chlorobenzene Inhalation blood Not classified Rat NOAEL 0.35 24 weeks
mg/I
Chlorobenzene Ingestion bone marrow Some positive data exist, but the Rat NOAEL250 13 weeks
classification
Chlorobenzene Ingestion liver Some positive data exist, but the Rat NOAEL 188 192 days
classification
Chlorobenzene Ingestion kidney and/or Some positive data exist, but the Rat NOAEL 125 13 weeks
bladder data are not sufficient for mg/kg/day
classification
Chlorobenzene Ingestion immune system Not classified Rat NOAEL 750 13 weeks
mg/kg/dav
. t"IOU Hazar d
AsiPira
Name Value
Cvclohexane Aspiration hazard
Xvlene Aspiration hazard
Ethvlbenzene Asoiration hazard
Toluene Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
13.1. Disposal methods

Dispose of contents/ container in accordance with the locaVregional/nationaVintemational regulations.
Incinerate in a permitted waste incineration facility. Combustion products will include halogen acid (HCI/HF/HBr). Facility
must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D00l (Ignitable), D021 (Chlorobenzene)
Page 16 of 18
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!For Transport Inf01mation, please visit http://3M.com/Transp01iinfo or call 1-800-364-3577 or 651- 737-6501.
15.1. US Federal Regulations

Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:

hysical Hazards
lammable (gases, aerosols, liquids, or solids)
Health Hazards
Aspiration Hazard
Carcinogenicity
Respirat01y or Skin Sensitization
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % b:yWt

Cyclohexane 110-82-7 Trade Secret 30 - 60
Xylene 1330-20-7 Trade Secret 20 - 35
Xylene (Benzene, dimethyl-) 1330-20-7 20- 35
Ethylbenzene 100-41-4 Trade Secret< 11
15.2. State Regulations

15.3. Chemical Inventories

The components of this material are in compliance with the China "Measures on Environmental Management ofNew
Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information.
The components of this product are in compliance with the chemical notification requirements ofTSCA.
15.4. International Regulations

IThis SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
NFPA Hazard Classification

Health: 2 Flammability: 3 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-tem1, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
Page 17 of 18
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the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group: 07-0925-3 Version Number: 21.02

Issue Date: 02/20/18 Supercedes Date: 01/19/18
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANT ABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M
3M USA SDSs are available at www.3M.com
Page 18 of 18
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STRIPE-OFF™
RHOMAR Safety Data Sheet www.rhomar.com
Prepared Date: 11/12/2014 Print Date: 8/24/2015 Revision: 3
Produc;;tIdentifier
Product Name Product Form Product Code

STRIPE-OFF™ Aerosol RH-870
Relevant identified uses of the substance or mixture:

Release agent.

Rhomar Industries, Inc.
21 07 E. Rockhurst St.
Springfield, MO 65802 USA
T 417-866-5592; F 417-866-5593
solutions@rhomar.com
Emergency telephone number

l -800-535-5053
Classification:
Physical Hazards
Flammable aerosols (Category 1)
Health Hazards
Signal Word:
Acute toxicity, inhalation (Category 3)
Danger
OSHA Defined Hazards
Not classified
Hazard Statements:
Extremely flammable aerosol. May be fatal if swallowed and enters airways. Toxic if inhaled. May cause drowsiness
or dizziness. Suspected of damaging fertility. Suspected of damaging the unborn child. Toxic to aquatic life. Toxic to
aquatic life with long lasting effects.
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Response:
Inhalation: Remove person to fresh air and keep comfortable for breathing. Call a poison center/ doctor. Do not
induce vomiting.
Ingestion: Immediately call a poison center/ doctor.
Other: Collect spillage.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose
to temperatures exceeding l 22°F.
Disposal:
Dispose of contents/container in accordance with local, regional, national, and international regulations.
Page 1 of 5
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Prepared Date: 11/12/2014 STRIPE-OFF™
Supplemental Information
15% of the mixture consists of component(s) of unknown acute inhalation toxicity. 60.65% of the mixture consists of
component(s) of unknown acute hazards to the aquatic environment. 60.55% of the mixture consists of component(s)
of unknown long-term hazards to the aquatic environment.
Mixture
Name CAS #
Distil{atE?s(Petroleum); .·; ' .
,, Hyclrotreated.··t-ieavy .•Naphthenic
Distillates (Petroleum),
Hydrotreated Light
Zinc Oxide
CydcihexaneC "
Toluene
Othei.c:ompon.~fiJs}b~low ..r~portahle
·le~e1f·' -- >-•·'•"~. - .•· -·•· -
Any concentration shown as a range is to protect confidentiality or is due to process variation.
#: This substance has workplace exposure limit(s).

*Designates thats specific chemical identity and/ or percentage of composition has been withheld as a trade secret.
Composition Comments: The full text for all R-phrases is displayed in Section l 6 of the SDS.
First Aid Measures

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a Poison Center
or doctor /physician, if symptoms persist.
Eve Contact: Rinse with water.
Ingestion: Rinse mouth. Get medical attention of symptoms persist.
Skin Contact: Wash with soap and water.
Most Important Symptoms and Effects, both Acute and Delayed

May cause drowsiness, dizziness, headache, nausea, and vomiting. Aspiration may cause pulmonary edema and
pneumonitis.
Indication of any Immediate Medical Attention and Special Treatment Needed

Provide general supportive measures and treat symptomatically.
General Information
If exposed or concerned, get medical advice/attention. If you feel unwell, seek medical advice. Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance.
Suitable Extinguishing Media

Powder, alcohol resistant foam, dry chemicals, carbon dioxide (CO2).
Page 2 of 5
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Unsuitable Extinguishing Media

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame. Fire may produce
irritating, corrosive and/or toxic gases.
Protective Equipment and Precautions for Firefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective clothing will only provide limited
protection.
Specific Methods
Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire
area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.
General Fire Hazards

Extremely flammable aerosol.
Personal Precautions, Protective Equipment and Emergency Procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear
appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering
them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see
section 8 of the SDS.
Methods and Material for Containment and Cleaning Up

Eliminate all ignition sources. Wipe up with absorbent material. Clean surface thoroughly to remove residual
contamination. For waste disposal, dispose of contents/container in accordance with local, regional, national, and
international regulations. This material and its container must be disposed of as hazardous waste.
Precautions for Safe Handling

Pressurized container, do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not
spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is
thoroughly dry.
Conditions for Safe Storage, Including any Incompatibilities

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding l 22°F. Store away from
incompatible materials (see Section l O of the SDS).
Exposure Guidelines
Chemical Name CAS # OSHA- PEL
1050 mg/m 3
Cydohexane l l 0-82-7
•. .. 300ppm
2000 mg/m 3
n-Heptane 142-82-5
500ppm
4800mg/m3
Propane 74-98-6
1000 ppm
5 mg/m 3 (Respiable fraction)
Zinc Oxide 1314-13-2 5mg/m 3 (fume)
15 mg/m 3 (total dust}
Page 3 of 5
Page 433 of 516

Appropriate Engineering Controls

Engineering Controls: Not available
Individual Protection Measures, such as Personal Protective Equipment

Eye/Face Protection: Chemical goggles are recommended.
Skin and Body Protection: Wear appropriate chemical resistant gloves, suitable protective clothing. Use of an
impervious apron is recommended.
Respiratory Protection: If permissible levels are exceeded us NIOSH mechanical filter/organic vapor cartridge or an
air-supplied respirator.
General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice.
Information on Basic Physical and Chemical Properties
Physical State Gas

Color Not available
Not available . ' Melting Point/Freezing Point .:tifofovailable.' , , i;'

Boiling Point/Boiling Range 36.65°F Flash Point - l 56.0°F Propellant estimated
Upper Flammable Limits 8.4% estimated Lower Flammable Limits l % estimated

VaporPressure L .. ci . 55.O8psig@70f estimated. Vapor Density ....·, "ic.
Specific Gravity 0.36 estemated Water Solubility Not available
Autoignition Temperatu.re
..
i
Decomposition Temperature Not available Viscosity Not available

- --
__
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical Stability
Risk of explosion.

Hazardous polymerization does not occur.
Conditions to Avoid
Heat, flames, sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible Materials

No hazardous decomposition products are know.
Information on Likely Routes of Exposure

Product Information
Inhalation: Toxic if inhaled. May cause drowsiness, drowsiness, dizziness, headache, nausea, vomiting, narcotic
effects.
Eye Contact: Direct contact with eyes may cause temporary irritation.
Skin Contact: No adverse effects due to skin contact are expected.
Page 4 of 5
Page 434 of 516

Ingestion: Droplet of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical
pneumonia.
Skin corrosion/irritation: Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation: Direct contact with eyes may cause temporary irritation.
Respiratory sensitization: Not available.
Skin sensitization: This product is not expected to cause skin sensitization.
Germ cell mutagenicity: No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Reproductive toxicity: Suspected of damaging the unborn child. Suspected of damaging fertility.
Specific target organ toxicity - single exposure: May cause drowsiness and dizziness.
Specific target organ toxicity - repeated exposure: Not classified.
Aspiration hazard: May be fatal if swallowed and enters airways.
Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA.
the
The information herein is presented in good faith and believed to be correct as of the date hereof. However,
Users must make their own determination
manufacturer makes no representation as to the completeness and accuracy thereof.
as to the suitability of the product for their purposes prior to use.
or of any other
No representations or warranty's, either express or implied of merchantability, fitness for a particular purpose
shall in no event be
nature with respect to the product or to the information herein is made hereunder. The manufacturer
resulting from the publication or use of or reliance
responsible for any damages of whatsoever nature directly or indirectly
upon information contained herein.
Page S of S
Page 435 of 516

Page 436 of 516
SAFETY DATA SHEET
TM5642
ISection 1. Identification
Product name SETFAST® VOC Solvent Based Acrylic Zone Marking Paint
Blue
Product code TM5642
Other means of Not available.
identification
Product type Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Manufacturer THE SHERWIN-WILLIAMS COMPANY

101 W. Prospect Avenue
Cleveland, OH 44115
National contact Sherwin-Williams Canada Inc.
180 Brunel Road
Mississauga, Ontario L4Z 1T5 Canada
Emergency telephone US/ Canada: (216) 566-2917

number of the company Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours/ 365 days a year
Product Information US / Canada: (800) 524-5979

Telephone Number Mexico: Not Available
Regulatory Information US/ Canada: (216) 566-2902

Transportation Emergency US / Canada: (800) 424-9300

Telephone Number Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours/ 365 days a year
ISection 2. Hazards identification

Classification of the FLAMMABLE LIQUIDS - Category 2
substance or mixture SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 36.4%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 62.1 %
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 62.
1%
GHS label elements
Hazard pictograms
Signal word Danger
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TM5642
Blue Page 437 of 516
SETFAST® VOC Solvent Based Acrylic Zone Marking Paint SHW-85-NA-GHS-CA
/Section 2. Hazards identification
Hazard statements Highly flammable liquid and vapor.
May cause cancer.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling.
Response Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothin9. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Adequate
ventilation required when sanding or abrading the dried film. If Adequate ventilation
cannot be provided wear an approved particulate respirator (NIOSH approved). Follow
respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM
LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release
Crystalline Silica which has been shown to cause lung damage and cancer under long
term exposure.
Please refer to the SOS for additional information. Keep out of reach of children. Do
not transfer contents to other containers for storage.
Hazards not otherwise None known.
classified
/section 3. Composition/information on ingredients

Substance/mixture Mixture
Other means of : Not available.
identification
CAS number/other identifiers
Ingredient name % by weight CAS number
Calcium Carbonate 34.79 1317-65-3
Acetone 25.67 67-64-1
Xylene 2.44 1330-20-7
Titanium Dioxide 1.65 13463-67-7
Ethylbenzene 0.44 100-41-4
Crystalline Silica, respirable powder 0.27 14808-60-7
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
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SETFAST® VOC Solvent Based Acrylic Zone Marking Paint
Blue
SHW-85-NA-GHS-CA
!section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
Isection 4. First aid measures

Description of necessary first aid measures
Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 1O
minutes. Get medical attention.
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.

Potential acute health effects
Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact Causes skin irritation.
Ingestion Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation Adverse symptoms may include the following:
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact Adverse symptoms may include the following:
irritation
redness
Ingestion No specific data.
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jsection 4. First aid measures
Indication of immediate medical attention and special treatment needed. if necessary
Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments No specific treatment.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
ISection 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing Use dry chemical, CO 2 , water spray (fog) or foam.
media
Unsuitable extinguishing Do not use water jet.
media
Specific hazards arising Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Hazardous thermal Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
carbonyl halides
metal oxide/oxides
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
jsection 6. Accidental release measures

For non-emergency No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
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SETFAST®VOC Solvent Based Acrylic Zone Marking Paint
Blue
SHW-85-NA-GHS-CA
!section 6. Accidental release measures
Small spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
!section 7. Handling and storage

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
Isection 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits (OSHA United States)
Ingredient name Exposure limits
Calcium Carbonate NIOSH REL (United States, 10/2016).
TWA: 5 mg/m 3 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 3 10 hours. Form: Total
OSHA PEL (United States, 6/2016).
fraction
TWA: 15 mg/m 3 8 hours. Form: Total dust
Acetone ACGIH TLV (United States, 3/2016).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
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SETFAST®VOC Solvent Based Acrylic Zone Marking Paint
Blue
SHW-85-NA-GHS-CA
ISection 8. Exposure controls/personal protection
TWA: 590 mg/m 3 10 hours.
Xylene ACGIH TLV (United States, 3/2016).
STEL: 651 mg/m 3 15 minutes.
Titanium Dioxide ACGIH TLV (United States, 3/2016).
Ethylbenzene ACGIH TLV (United States, 3/2016).
Crystalline Silica, respirable powder OSHA PEL 23 (United States, 6/2016).
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
TWA: 10 mg/m 3 / (%SiO2+2) 8 hours. Form:
Respirable
TWA: 50 µg/m3 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m 3 8 hours. Form:
Respirable fraction
TWA: 0.05 mg/m 3 10 hours. Form: respirable
dust
Occupational exposure limits (Canada}

Acetone CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1200 mg/m 3 8 hours.
15 min OEL: 1800 mg/m 3 15 minutes.
8 hrs OEL: 500 ppm 8 hours.
15 min OEL: 750 ppm 15 minutes.
CA British Columbia Provincial (Canada,
7/2016).
CA Ontario Provincial (Canada, 7/2015).
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 500 ppm 8 hours.
TWAEV: 1190 mg/m 3 8 hours.
STEV: 1000 ppm 15 minutes.
STEV: 2380 mg/m 3 15 minutes.
CA Saskatchewan Provincial (Canada,
TM5642
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Blue
SHW-85-NA-GHS-CA
/section 8. Exposure controls/personal protection
7/2013).
Xylene CA Alberta Provincial (Canada, 4/2009).

7/2016).
7/2013).
Ethylbenzene CA Alberta Provincial (Canada, 4/2009).

7/2016).
7/2013).
Occupational exposure limits (Mexico)

Acetone NOM-01 0-STPS-2014 (Mexico, 4/2016).

Xylene NOM-01 0-STPS-2014 (Mexico, 4/2016).
Ethylbenzene NOM-010-STPS-2014 (Mexico, 4/2016).
voe
TM5642 SETFAST®
Solvent Based Acrylic Zone Marking Paint SHW-85-NA-GHS-CA
Appropriate engineering Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
!section 9. Physical and chemical properties

Appearance
Physicat state Liquid.
Color Not available.
Odor Not available.
pH Not available.
Melting point Not available.
Boiling point 55°C (131°F)
Flash point Closed cup: -17°C (1.4 °F) [Tagliabue Closed Cup]
Evaporation rate 5.6 (butyl acetate = 1)
Lower and upper explosive Lower: 1%
(flammable) limits Upper: 12.8%
Vapor pressure 24 kPa (180 mm Hg) [at 20°C]
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jsection 9. Physical and chemical properties
Vapor density 2 [Air= 1]
Solubility Not available.
Partition coefficient: n- Not available.
octanol/water
Viscosity Kinematic (40°C (104°F)): >0.205 cm 2/s (>20.5 cSt)
Molecular weight Not applicable.
Aerosol product
Heat of combustion : 8.525 kJ/g
jSection 10. Stability and reactivity

Reactivity No specific test data related to reactivity available for this product or its ingredients.
Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Incompatible materials Reactive or incompatible with the following materials:

oxidizing materials
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
jsection 11. Toxicological information

Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LOSO Oral Rat 5800 mg/kg -
Xylene LCS0 Inhalation Gas. Rat 5000 ppm 4 hours
LOSO Oral Rat 4300 mg/kg -
Ethylbenzene LOSO Dermal Rabbit >5000 mg/kg -
LOSO Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Eyes - Severe irritant Rabbit - 24 hours 5 -
TM5642 SETFAST® VOC Solvent Based Acrylic Zone Marking Paint SHW-85-NA-GHS-CA
!section 11. Toxicological information I
milligrams
Skin - Mild irritant Rat - 8 hours 60 -
microliters
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Skin - Moderate irritant Rabbit - 100 Percent -
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 -
Micrograms
Intermittent
Ethylbenzene Eyes - Severe irritant Rabbit - 500 -
milligrams
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Xylene - 3 -
Titanium Dioxide - 2B -
Ethyl benzene - 2B -
Crystalline Silica, respirable - 1 Known to be a human carcinogen.
powder
Not available.
Teratogenicity
Not available.
Soecific taraet oraan toxicitv (sinale exoosure\

Name Category Route of Target organs
exposure
Calcium Carbonate Category 3 Not applicable. Respiratory tract
irritation
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Xylene Category 3 Not applicable. Respiratory tract
irritation
Ethylbenzene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
exposure
Acetone Category 2 Not determined Not determined
Xylene Category 2 Not determined Not determined
Ethyl benzene Category 2 Not determined Not determined
Crystalline Silica, respirable powder Category 1 Inhalation Not determined
Aspiration hazard
TM5642 SETFAST® VOC Solvent Based Acrylic Zone Marking Paint
Blue Page 446 of 516 SHW-85-NA-GHS-CA
!section 11. Toxicological information
Name Result
Xylene ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1
Information on the likely : Not available.

routes of exposure
Symptoms related to the physical. chemical and toxicological characteristics

pain or irritation
watering
redness
coughing
nausea or vomiting
headache
d rowsi ness/fatig ue
dizziness/vertigo
unconsciousness
irritation
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate Not available.
effects
Potential delayed effects Not available.
Long term exposure
effects
Potential chronic health effects
Not available.
General May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Numerical measures of toxicity

Acute toxicity estimates
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Route ATE value
Oral 111882.5 mg/kg
Dermal 17063.6 mg/kg
Inhalation (gases) 77561.8 ppm
jsection 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 7200000 µg/I Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 6000000 µg/I Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 6900 mg/I Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/I Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 0.1 mg/I Fresh water Fish - Fundulus heteroclitus 4 weeks
Xylene Acute LC50 8500 µg/I Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/I Fresh water Fish - Pimephales promelas 96 hours
Titanium Dioxide Acute LC50 > 1000000 µg/I Marine water Fish - Fundulus heteroclitus 96 hours
Ethylbenzene Acute EC50 4600 µg/I Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/I Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 6530 µg/I Fresh water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2930 µg/I Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/I Fresh water Fish - Oncorhynchus mykiss 96 hours

Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Xylene - - Readily
Ethylbenzene - - Readily
Product/ingredient name LogPow BCF Potential
Xylene - 8.1 to 25.9 low
Mobility in soil
Soil/water partition Not available.
coefficient (Koc)
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Page 448 of 516
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SHW-85-NA-GHS-CA
/section 13. Disposal considerations
Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
/section 14. Transport information

DOT TOG Mexico IATA IMDG
Classification Classification Classification
UN number UN1263 UN1263 UN1263 UN1263 UN1263
UN proper PAINT PAINT PAINT PAINT PAINT

shipping name
Transport 3 3 3 3 3
hazard class(es)
♦ ♦ ♦ ♦ ♦
Packing group II II II II II
Environmental No. No. No. No. No.
hazards
Additional - Product classified - Emergenci

information as per the schedules F-E, S-
following sections E
of the
Transportation of
Dangerous Goods
Regulations: 2.
18-2.19 (Class 3).
ERG No. ERG No. ERG No.
128 128 128
Special precautions for user Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Transport in bulk according Not available.

to Annex II of MARPOL and
the IBC Code
Proper shipping name Not available.
Ship type Not available.
Pollution category Not available.
Date of issue/Date ofrevision : 212712018 Date of previous issue : 1116/2018 Version : 5.01 13115
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Page 449 of 516
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SHW-85-NA-GHS-CA
/section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
/section 16. Other information
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Caution: HMIS® ratings are based on a 0-4 rating scale, with O representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY- Category 1A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Calculation method
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
History
Date of printing 2/27/2018
Date of issue/Date of 2/27/2018
revision
Date of previous issue 1/16/2018
Version 5.01
Key to abbreviations A TE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA= International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SOS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SOS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
Date of issue/Date of revision : 2127/2018 Date of previous issue : 1/16/2018 Version :5.01 14/15
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Page 450 of 516
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SHW-85-NA-GHS-CA
!section 16. Other information
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SOS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SOS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
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Page 451 of 516
Blue
SHW-85-NA-GHS-CA
Page 452 of 516
SAFETY DATA SHEET
TM5628
!section 1. Identification
Product name SETFAST® VOC Compliant Solventbased Acrylic Traffic Marking Paint
Red
Product code TM5628
identification
Not applicable.

Cleveland, OH 44115
180 Brunel Road
Mississauga, Ontario L4Z 1TS Canada

number of the company Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Regulatory Information US/ Canada: (216) 566-2902

Transportation Emergency US/ Canada: (216) 566-2917


substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 53.3%
3%
GHS label elements
Hazard pictograms
Signal word Danger
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Page 453 of 516
SETFAST® VOC Compliant Solventbased Acrylic Traffic Marking Paint
Red
SHW-85-NA-GHS-CA
J Section 2. Hazards identification
May cause cancer.
Causes damage to organs through prolonged or repeated exposure. (lungs)
been read and understood, Wear protective gloves. Wear eye or face protection.
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
respirator manufacturer's directions for respirator use. DELA YEO EFFECTS FROM
term exposure.
classified
Jsection 3. Composition/information on ingredients

identification
Acetone 29.53 67-64-1
Feldspars 16.6 68476-25-5
Xylene 2.51 1330-20-7
Mica 1.19 12001-26-2
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TM5628
Red Page 454 of 516
SETFAST® VOC Compliant Solventbased Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
Isection 4. First aid measures
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
or waistband.
Most important symptoms/effects. acute and delayed

Skin contact No known significant effects or critical hazards.
pain or irritation
watering
redness
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact No specific data.
Indication of immediate medical attention and special treatment needed. if necessary

TM5628
Red Page 455 of 516
!section 4. First aid measures
!section 5. Fire-fighting measures

Extinguishing media
media
media
Specific hazards arising Highly flammable liquid and vapor. Runoff to sewer may create tire or explosion hazard.
carbon monoxide
nitrogen oxides
halogenated compounds
carbonyl halides
metal oxide/oxides
ISection 6. Accidental release measures


Date of issue/Date of revision : 212712018 Date of previous issue : 919/2017 Version : 4.01 4/15
TM5628 SETFAST® VOC Compliant Solventbased Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
Red Page 456 of 516
ISection 6. Accidental release measures
!section 7. Handling and storage

measures.

Control parameters
TWA: 2400 mg/m3 8 hours.
Feldspars None.
Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016).
Respirable
Respirable
TWA: 50 µg/m 3 8 hours. Form: Respirable
: 2127/2018 Date of previous issue : 9/9/2017 Version : 4. 01 5/15

Date of issue/Date of revision
SHW-85-NA-GHS-CA
TM5628
Red Page 457 of 516
jsection 8. Exposure controls/personal protection
dust
Respirable fraction
TWA: 0.05 mg/m 3 1O hours. Form: respirable
dust
Mica ACGIH TLV (United States, 3/2016).
fraction
fraction
OSHA PEL 23 (United States, 6/2016).
TWA: 20 mppcf 8 hours.
Occupational exposure limits (Canada)

7/2016).
7/2013).
Crystalline Silica, respirable powder CA British Columbia Provincial (Canada,
7/2016).
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 9/912017 Version : 4.01 6/15
TM5628
Red Page 458 of 516
Respirable
TWAEV: 0.1 mg/m 3 8 hours. Form:
Respirable dust.
TWA: 0.1 mg/m 3 8 hours. Form: Respirable
fraction.
CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 0.025 mg/m 3 8 hours. Form:
Respirable particulate
7/2013).
fraction
15 min OEL: 651mg/m 3 15 minutes.
7/2016).
7/2013).
7/2016).
7/2013).
Occupational exposure limits (Mexico}
Date of issue/Date of revision : 2127/2018 Date of previous issue :919/2017 Version : 4.01 7115
TM5628
Page 459 of 516
Red
SHW-85-NA-GHS-CA
Acetone NOM-010-STPS-2014 (Mexico, 4/2016).
Crystalline Silica, respirable powder NOM-010-STPS-2014 (Mexico, 4/2016).
Respirable fraction
Xylene NOM-010-STPS-2014 (Mexico, 4/2016).

Skin protection
aspects of use.
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Page 460 of 516
Red
SHW-85-NA-GHS-CA
Appearance
Odor Not available.
pH Not available.
Flash point Closed cup: -17°C (1.4°F) [Tagliabue Closed Cup]
Evaporation rate 5.6 (butyl acetate= 1)
octanol/water
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Aerosol product
ISection 10. Stability and reactivity

reactions

oxidizing materials
voe Compliant
TM5628 SETFAST®
Red Page 461 of 516
Solventbased Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
Jsection 11. Toxicological information
Acute toxicity
Acetone LOSOOral Rat 5800 mg/kg -
Xylene LCSO Inhalation Gas. Rat 5000 ppm 4 hours
LOSOOral Rat 4300 mg/kg -
Ethyl benzene LOSODermal Rabbit >5000 mg/kg -
per million
milligrams
milligrams
milligrams
milligrams
microliters
milligrams
milligrams
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
powder
Xylene - 3 -
Ethylbenzene - 28 -
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 9/9/2017 Version : 4. 01 10115
TM5628
Red Page 462 of 516
exposure
irritation and
Narcotic effects
Feldspars Category 3 Not applicable. Respiratory tract
irritation
irritation
irritation and
Narcotic effects
exposure
Mica Category 1 Inhalation lungs
Ethylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result

routes of exposure
Skin contact No known significant effects or critical hazards.

pain or irritation
watering
redness
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact No specific data.
Short term exposure
Date of issue/Date of revision : 2127/2018 Date of previous issue : 91912017 Version : 4.01 11115
TM5628
Red Page 463 of 516
effects
Long term exposure
effects
Not available.
General Causes damage to organs through prolonged or repeated exposure.


Route ATE value
bral 130583. 7 mg/kg
Dermal 20472.1 mg/kg
1lnhalation (gases) 93054.9 ppm
ISection 12. Ecological information

Toxicity
Neonate
pugio
subcapitata
subcapitata
Nauplii
Neonate

Acetone - - Readily
Xylene - - Readily
voe Compliant
TM5628 SETFAST®
Red Page 464 of 516
Solventbased Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
!section 12. Ecological information
Mobility in soil
coefficient (Koc)
Other adverse effects : No known significant effects or critical hazards.
ISection 13. Disposal considerations

ISection 14. Transport information


shipping name
Transport 3 3 3 3 3
hazard class(es)
♦ ♦ ♦ ♦ ♦

hazards
Additional - Product classified - Emergency

of the
Transportation of
Dangerous Goods
Regulations: 2.
18-2.19 (Class 3).
128 128 128
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TM5628
Red Page 465 of 516
!section 14. Transport information
Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not

the IBC Code
!section 15. Regulatory information

SARA 313
California Prop. 65
reproductive harm.
!section 16. Other information
CARCINOGENICITY - Category 1A Calculation method
SPECIFIC TAR GET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
Category 3
SPECIFIC TAR GET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category Calculation method
1
History
revision
Version 4.01
Date of issue/Date of revision : 2127/2018 Date of previous issue :9/9/2017 Version : 4. 01 14/15
voe
TM5628 SETFAST®
Red Page 466 of 516
Compliant Solventbased Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
/section 16. Other information
Key to abbreviations ATE= Acute Toxicity Estimate
IATA = International Air Transport Association
Log Pow= logarithm of the octanol/water partition coefficient
UN = United Nations
Notice to reader
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requi-rements are subject
any other source.
TM5628
Page 467 of 516
Red
SHW-85-NA-GHS-CA
Page 468 of 516
SAFETY DATA SHEET
TM5712
ISection 1. Identification
Product name PROMAR® Solvent Based Acrylic Traffic Marking Paint
White
Product code TM5712
identification
Not applicable.

Cleveland, OH 44115
180 Brunel Road
Mississauga, Ontario L4Z 1T5 Canada

Regulatory Information US / Canada: (216) 566-2902

Transportation Emergency US / Canada: (216) 566-2917


CARCINOGENICITY- Category 1A
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
2%
GHS label elements
Hazard pictograms
Signal word Danger
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1117/2018 Version :4.01 1/15
TM5712 PROMAR® Solvent Based Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
White Page 469 of 516
May cause cancer.
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Supplemental label DELAYEO EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
respirator manufacturer's directions for respirator use. DELAYEO EFFECTS FROM
term exposure.
classified
jsection 3. Composition/information on ingredients

identification
Ingredient name ¾ by weight CAS number
Acetone 24.33 67-64-1
Xylene 5.05 1330-20-7
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1/17/2018 Version :4.01 2115
!section 4. First aid measures

or waistband.

pain or irritation
watering
redness
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
PROMAR® Solvent Based Acrylic Traffic Marking Paint SHW-85-NA-GHS-CA
TM5712
J Section 4. First aid measures
Indication of immediate medical attention and special treatment needed, if necessary
Jsection 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing Use dry chemical, CO2 , water spray (fog) or foam.
media
media
carbon monoxide
carbonyl halides
metal oxide/oxides
J Section 6. Accidental release measures

Date of issue/Date ofrevision : 2127/2018 Date of previous issue : 1117/2018 Version : 4. 01 4115
/section 6. Accidental release measures
/Section 7. Handling and storage

measures.
/Section 8. Exposure controls/personal protection

Control parameters
fraction
fraction
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1117/2018 Version :4.01 5115
TM5712
Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016).
Respirable
Respirable
TWA: 50 µg/m3 8 hours. Form: Respirable
dust
Respirable fraction
dust

7/2016).
Date of issue/Date of revision : 2127/201 B Date of previous issue : 1/17/2018 Version :4.01 6115
TM5712
Page 474 of 516
PROMAR® Solvent Based Acrylic Traffic Marking Paint
White
SHW-85-NA-GHS-CA
7/2013).

7/2016).
7/2013).
Ethyl benzene CA Alberta Provincial (Canada, 4/2009).
7/2016).
7/2013).
Occupational exposure limits (Mexico}


Xylene NOM-010-STPS-2014 (Mexico, 4/2016).
TM5712
Page 475 of 516
White
SHW-85-NA-GHS-CA
jsection 8. Exposure controls/personal protection

Skin protection
resp·Iratory protection program to ensure proper fitting, training, and other important
aspects of use.
ISection 9. Physical and chemical properties

Appearance
Odor Not available.
pH Not available.
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1/17/2018 Version :4.01 8/15
TM5712
Vapor density 2[Air=1]
octanol/water
Viscosity Kinematic (40°C (104 °F)): >0.205 cm 2 /s (>20.5 cSt)
Aerosol product
Heat of combustion 8.682 kJ/g
jsection 10. Stability and reactivity

reactions

oxidizing materials
jsection 11. Toxicological information

Acute toxicity
Xylene LCS0 Inhalation Gas. Rat 5000 ppm 4 hours
per million
milligrams
milligrams
milligrams
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1117/2018 Version :4.01 9115
TM5712
Jsection 11. Toxicological information
I
milligrams
microliters
milligrams
Micrograms
Intermittent
Ethyl benzene Eyes - Severe irritant Rabbit - 500 -
milligrams
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Xylene - 3 -
Titanium Dioxide - 2B -
Ethyl benzene - 2B -
powder
Not available.
Teratogenicity
Not available.

exposure
irritation
irritation and
Narcotic effects
irritation
irritation and
Narcotic effects
exposure
Ethyl benzene Category 2 Not determined Not determined
Aspiration hazard
TM5712
Page 478 of 516
White
SHW-85-NA-GHS-CA
Name Result

routes of exposure

pain or irritation
watering
redness
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
Short term exposure
effects
Long term exposure
effects
Not available.

Teratogen icity No known significant effects or critical hazards.

Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1117/2018 Version : 4.01 11/15
TM5712
Route ATE value
bral 39288.8 mg/kg
Dermal 4753.2 mg/kg
jsection 12. Ecological information

Toxicity
Neonate
pugio
Titanium Dioxide Acute LC50 >1000000 µg/I Marine water Fish - Fundulus heteroclitus 96 hours
subcapitata
subcapitata
Nauplii
Neonate

Acetone - - Readily
Xylene - - Readily
Mobility in soil
coefficient (Koc)
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TM5712
Page 480 of 516
White
SHW-85-NA-GHS-CA
JSection 13. Disposal considerations
Jsection 14. Transport information

DOT TDG Mexico IATA IMDG

shipping name
Transport 3 3 3 3 3
hazard class(es)
♦ ♦ ♦ ♦ ♦
hazards
Additional - Product classified - Emergencll

of the
Transportation of
Dangerous Goods
Regulations: 2.
18-2.19 (Class 3).
128 128 128

the IBC Code
jsection 15. Regulatory information
SARA 313
California Prop. 65
reproductive harm.
jsection 16. Other information
Caution: HMIS® ratings are based on a 0--4 rating scale, with 0 representing minimal hazards or risks, and 4
SPECIFIC TAR GET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
Category 3
History
revision
Version 4.01
Key to abbreviations ATE= Acute Toxicity Estimate
IATA = International Air Transport Association
LogPow = logarithm of the octanol/water partition coefficient
UN= United Nations
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
here applies only to the product as shipped. The additron of any material can change the composition, hazards
Date of issue/Date of revision : 2127/2018 Date of previous issue : 1/17/2018 Version :4.01 14/15
TM5712
Page 482 of 516
White
SHW-85-NA-GHS-CA
Isection 16. Other information
product for any purpose other than the purpose shown in the applicable section of this 5D5 without first
information such as manufacturer-specific 5D5, the manufacturer cannot be responsible for SDSs obtained from
any other source.
TM5712
Page 484 of 516
SAFETY DATA SHEET
TM5713
ISection 1. Jdentification
Product name PROMAR® Solvent Based Acrylic Traffic Marking Paint
Yellow
Product code TM5713
identification
Not applicable.

Cleveland, OH 44115
180 Brunel Road
Mississauga, Ontario L4Z 1TS Canada

Product Information US/ Canada: (800) 368-2026
Regulatory Information US / Canada: (216) 566-2902

Transportation Emergency US/ Canada: (216) 566-2917


SPECIFIC TAR GET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TAR GET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
3%
GHS label elements
Hazard pictograms
Signal word Danger
TM5713
Yellow Page 485 of 516
May cause cancer.
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
respirator manufacturer's directions for respirator use. DELA YEO EFFECTS FROM
term exposure.
classified

identification
Acetone 24.81 67-64-1
Xylene 3.83 1330-20-7
TM5713 PROMAR® Solvent Based Acrylic Traffic Marking Paint
Yellow Page 486 of 516 SHW-85-NA-GHS-CA
Section 3. Composition/information on ingredients
ISection 4. First aid measures

or waistband.

pain or irritation
watering
redness
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
/section 4. First aid measures
Indication of immediate medical attention and special treatment needed, if necessary
!section 5. Fire-fighting measures

Extinguishing media
media
media
carbon monoxide
carbonyl halides
metal oxide/oxides
/section 6. Accidental release measures

Date of issue/Date of revision : 2127/2018 Date of previous issue : 1/17/2018 Version :5.01 4115
!section 6. Accidental release measures
ISection 7. Handling and storage

measures.

Control parameters
fraction
fraction
J Section 8. Exposure controls/personal protection I
TWA: 590 mg/m 3 1O hours.
Ethyl benzene ACGIH TLV (United States, 3/2016).
TWA: 100 ppm 1O hours.
Crystalline Silica, respirable powder OSHA PEL 23 (United States, 6/2016).
Respirable
Respirable
TWA: 50 µg/m 3 8 hours. Form: Respirable
dust
Respirable fraction
dust

7/2016).
7/2013).

7/2016).
7/2013).
7/2016).
7/2013).
Occupational exposure limits {Mexico)


Xylene NOM-01 0-STPS-2014 (Mexico, 4/2016).
Date of issue/Date of revision : 2127/201 B Date of previous issue : 1/17/2018 Version : 5. 01 7115
TM5713
Page 491 of 516
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SHW-85-NA-GHS-CA

Skin protection
aspects of use.

Appearance
Odor Not available.
pH Not available.
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1/17/2018 Version : 5. 01 8/15
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Page 492 of 516
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SHW-85-NA-GHS-CA
octanol/water
Viscosity Kinematic (40°C (104 °F)): >0.205 cm 2/s (>20.5 cSt)
Aerosol product
Isection 10. Stability and reactivity

reactions

oxidizing materials

Acute toxicity
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
per million
milligrams
milligrams
milligrams
TM5713
/section 11. Toxicological information I
milligrams
microliters
milligrams
Micrograms
Intermittent
milligrams
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Xylene - 3 -
Titanium Dioxide - 28 -
Ethylbenzene - 28 -
powder
Not available.
Teratogenicity
Not available.

exposure
irritation
irritation and
Narcotic effects
irritation
irritation and
Narcotic effects
Specific target organ toxicity {repeated exposure)
exposure
Ethylbenzene Category 2 Not determined Not determined
Aspiration hazard
Date of issue/Date of revision : 212712018 Date of previous issue : 1/17/2018 Version : 5.01 10115
TM5713
Name Result

routes of exposure

pain or irritation
watering
redness
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
Short term exposure
effects
Long term exposure
effects
Not available.


Route ATE value
Oral 51131.2 mg/kg
Dermal 5949.6 mg/kg
\section 12. Ecological information

Toxicity
ProducUingredient name Result Species Exposure
Neonate
pugio
Titanium Dioxide Acute LC50 >1000000 µg/I Marine water Fish - Fundulus heteroclitus 96 hours
subcapitata
subcapitata
Nauplii
Neonate

ProducUingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Xylene - - Readily
ProducUingredient name LogPow BCF Potential
Mobility in soil
coefficient (Koc)
Date of issue/Date of revision : 2127/2018 Date of previous issue : 1117/2018 Version : 5. 01 12115
TM5713
/Section 13. Disposal considerations
/Section 14. Transport information


shipping name
Transport 3 3 3 3 3
hazard class(es)
♦ ♦ ♦ ♦ ♦

hazards
Additional - Product classified - Emergency:

of the
Transportation of
Dangerous Goods
Regulations: 2.
18-2.19 (Class 3).
128 128 128

the IBC Code
Date of issue/Date of revision : 2/2712018 Date of previous issue : 1117/2018 Version : 5.01 13115
SHW-85-NA-GHS-CA
TM5713
ISection 15. Regulatory information
SARA 313
California Prop. 65
reproductive harm.
ISection 16. Other information
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
Category 3
History
revision
Version 5.01
Key to abbreviations ATE = Acute Toxicity Estimate
IATA= International Air Transport Association
Log Pow= logarithm of the octanol/water partition coefficient
UN = United Nations
Notice to reader
Date of issue/Date of revision : 2/27/2018 Date of previous issue : 1/17/2018 Version :5.01 14115
TM5713
Page 498 of 516
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SHW-85-NA-GHS-CA
Isection 16. Other information
any other source.
TM5713
Page 500 of 516
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: STYROFOAM TM 2.00 x 48 Inch Square Edge Wide Issue Date: 09/04/2015
Extruded Foam Insulation
Print Date: 06/16/2016
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: STYROFOAM™ 2.00 x 48 Inch Square Edge Wide Extruded Foam Insulation

Identified uses: Thermal insulation.
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND Ml 48674-0000
UNITED STATES
Customer Information Number: 800-258-2436

SDSQuestion@dow.com
EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: CHEMTREC +1 800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is not hazardous under the criteria of the Federal OSHA Hazard Communication
Standard 29CFR 1910.1200.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature: Construction and composite applications

This product is an article.
Component CASRN Concentration
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 10

company of Dow
Page 501 of 516
Product name: STYROFOAM™ 2.00 x 48 Inch Square Edge Wide Issue Date: 09/04/2015
2-Propenenitrile, polymer with ethenylbenzene 9003-54-7 > 60.0 - < 100.0 %
Styrene, polymers 9003-53-6 <= 10.0 %
1, 1, 1,2-Tetrafluoroethane 811-97-2 >= 5.0 - <= 10.0 %
Note
Extruded polystyrene foam containing a halogenated flame retardant system.
4. FIRSTAID MEASURES
General advice: If potential for exposure exists refer to Section 8 for specific personal protective
equipment.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Skin contact: Wash off with plenty of water.
Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Ingestion: No emergency medical treatment necessary.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.

Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
5. FIREFIGHTINGMEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam.
Unsuitable extinguishing media: No data available
Special hazards arising from the substance or mixture

Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. In smoldering or
flaming conditions, carbon monoxide, carbon dioxide and carbon are generated. Combustion
products may include and are not limited to: Hydrogen halides. Based on combustion toxicity testing,
the effects of combustion from this foam are not more acutely toxic than the effects of combustion from
common building materials such as wood.
Page 2 of 10
Page 502 of 516
Unusual Fire and Explosion Hazards: Mechanical cutting, grinding or sawing can cause formation
of dusts. To reduce the potential for dust explosion, do not permit dust to accumulate. This product
contains a flame retardant to inhibit accidental ignition from small fire sources. This plastic foam
product is combustible and should be protected from flames and other high heat sources. For more
information, contact Dow. Dense smoke is produced when product burns.
Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Soak
thoroughly with water to cool and prevent re-ignition. If material is molten, do not apply direct
waterstream. Use fine water spray or foam. Cool surroundings with water to localize fire zone.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing

apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.
6. ACCIDENTAL RELEASE
MEASURES
Personal precautions, protective equipment and emergency procedures: Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Collect in suitable and properly labeled containers. See Section 13, Disposal Considerations, for
additional information.
7. HANDLING AND STORAGE

Precautions for safe handling: Fabrication methods which involve cutting into this product may
release the blowing agent(s) remaining in the cells. Use ventilation adequate to keep exposures
below recommended exposure limits. See the safety datasheet. Do not enter confined spaces unless
adequately ventilated. Mechanical cutting, grinding or sawing can cause formation of dusts. To reduce
the potential for dust explosion, do not permit dust to accumulate. This product is combustible and
may constitute a fire hazard if improperly used or installed. See Section 8, EXPOSURE CONTROLS
AND PERSONAL PROTECTION.
Conditions for safe storage: When large quantities of this product are stored or fabricated, blowing
agents may be released. Released blowing agents may thermally decompose to form gases which
may accelerate corrosion or rust formation of heaters, boilers, gas fired recirculating air furnaces or
heaters, or gas water heaters.
Storage stability
Shelf life: Use within 360 Month
Page 3 of 10
Page 503 of 516
8. EXPOSURECONTROLS/PERSONALPROTECTION
Control parametets
Ex osure limits are listed below, if the exist.
Component Re ulation T pe of listin Value/Notation
1,1, 1,2-Tetrafluoroethane US WEEL TWA 1,000 ppm
Concentrations of the blowing agents anticipated incidental to proper handling are expected to be well
below those which cause acute inhalation effects and below exposure guidelines.
Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Eye/face protection: Eye protection should not be necessary. For fabrication operations
safety glasses (with side shields) are recommended. If there is a potential for exposure to
particles which could cause eye discomfort, wear chemical goggles.
Skin protection
Hand protection: Use gloves to protect from mechanical injury. Selection of gloves
will depend on the task.
Other protection: No precautions other than clean body-covering clothing should be
needed.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, wear respiratory protection when adverse effects, such as
respiratory irritation or discomfort have been experienced, or where indicated by your risk
assessment process. In dusty or misty atmospheres, use an approved particulate respirator.
When respiratory protection is required for certain operations, including but not limited to saw,
router or hot-wire cutting, use an approved air-purifying respirator.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.
9. PHYSICALAND CHEMICAL PROPERTIES

Appearance
Physical state Board
Color Blue
Odor None
Odor Threshold Odorless
pH Not applicable
Melting point/range 90 - 130 °C ( 194 - 266 °F) Estimated.
Freezing point Not applicable
Boiling point (760 mmHg) Not applicable
Flash point closed cup Not applicable
Page 4 of 10
Page 504 of 516
Evaporation Rate (Butyl Acetate Not applicable

= 1)
Flammability (solid, gas) Not expected to form explosive dust-air mixtures.
Lower explosion limit Not applicable
Upper explosion limit Not applicable
Vapor Pressure Not applicable
Relative Vapor Density (air= 1) Not applicable
Relative Density (water= 1) 0.027 - 0.064 Estimated.
Water solubility Insoluble in water
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature 354 °C {669 °F) ASTM 01929
Decomposition temperature No test data available
Kinematic Viscosity Not applicable
Explosive properties No
Oxidizing properties No
Molecular weight No test data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITYAND REACTIVITY

Reactivity: No dangerous reaction known under conditions of normal use.
Chemical stability: Thermally stable at typical use temperatures.
Possibility of hazardous reactions: Polymerization will not occur.
Conditions to avoid: Avoid temperatures above 300°C (572°F) Exposure to elevated temperatures
can cause product to decompose. Avoid direct sunlight.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Aldehydes.
Amines. Esters. Liquid fuels. Organic solvents.
Hazardous decomposition products: Does not normally decompose. Evolution of small amounts of
hydrogen halides occur when heated over 250°C (482°F). Decomposition products depend upon
temperature, air supply and the presence of other materials. Decomposition products can include and
are not limited to: Aromatic compounds. Aldehydes. Ethylbenzene. Hydrogen halides. Polymer
fragments. Styrene. Under high heat, non-flaming conditions, small amounts of aromatic
hydrocarbons such as styrene and ethylbenzene are generated.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Page 5 of 10
Page 505 of 516
Acute toxicity
Acute oral toxicity
Swallowing is unlikely because of the physical state. Very low toxicity if swallowed. Harmful
effects not anticipated from swallowing small amounts.
As product: Single dose oral LOSOhas not been determined.
Acute dermal toxicity

Skin absorption is unlikely due to physical properties.
As product: The dermal LOSOhas not been determined.
Acute inhalation toxicity

Dust may cause irritation to upper respiratory tract (nose and throat). Fumes/vapors released
during thermal operations such as hot wire cutting may cause respiratory irritation.
Concentrations of the blowing agents anticipated incidental to proper handling are expected to
be well below those which cause acute inhalation effects and below exposure guidelines.
The LCS0 has not been determined.,
Essentially nonirritating to skin.
Mechanical injury only.

Solid or dust may cause irritation or corneal injury due to mechanical action.
Fumes/vapor released during thermal operations such as hot-wire cutting may cause eye irritation.
Sensitization
Relevant data not available.
For respiratory sensitization:

Specific Target Organ Systemic Toxicity (Single Exposure)

Available data are inadequate to determine single exposure specific target organ toxicity.
Specific Target Organ Systemic Toxicity (Repeated Exposure)

Based on available data, repeated exposures are not anticipated to cause significant adverse effects.
Additives are encapsulated in the product and are not expected to be released under normal
processing conditions or foreseeable emergency.
Carcinogenicity
Teratogenicity
Contains a component(s) that is/are encapsulated in the product and are not expected to be released
under normal processing conditions or foreseeable emergency
Contains a component(s) that is/are encapsulated in the product and are not expected to be released
under normal processing conditions or foreseeable emergency
Mutagenicity
Page 6 of 10
Page 506 of 516
Product name: STYROFOAM™ 2.00 x 48 inch Square Edge Wide Issue Date: 09/04/2015
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
COMPONENTS INFLUENCING TOXICOLOGY:
2-Propenenitrile, polymer with ethenylbenzene

Acute oral toxicity
LD50, Rat, > 5,000 mg/kg Estimated.

The dermal LD50 has not been determined.
For similar material(s): LD50, Rabbit, > 2,000 mg/kg Estimated.
Styrene, polymers
Acute oral toxicity
Single dose oral LD50 has not been determined.

1,1,1,2-Tetrafluoroethane
Acute oral toxicity
Single dose oral LD50 has not been determined.

12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.

Biodegradability: Surface photodegradation is expected with exposure to sunlight. No
appreciable biodegradation is expected. 1, 1,1,2-tetrafluoroethane (HFC-134a) remains in the
foam and diffuses out slowly, most of it degrading in the troposphere to CO2 and HF. 1,1, 1,2-
Tetrafluoroethane (HFC-134a) has a stratospheric ozone depletion potential (ODP) of zero,
relative to CFC 12 (ODP=1 ).
Bioaccumulation: No bioconcentration is expected because of the relatively high molecular
weight (MW greater than 1000).
Mobility in soil
In the terrestrial environment, material is expected to remain in the soil.
Page 7 of 10
Page 507 of 516
In the aquatic environment, material is expected to float.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Landfill. Incinerator or other thermal destruction device.
14. TRANSPORT INFORMATION
DOT
Not regulated for transport
Classification for SEA transport (IMO-IMDG):

Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard

This product is not a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Page 8 of 10
Page 508 of 516
Product name: STYROFOAM™ 2.00 x 48 Inch Square Edge Wide lss ue Date: 09/04/2015
Superfund Amendments and Reauthorization Act of 1986 Title Ill (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
This product is not a hazardous chemical under 29CFR 1910.1200, and therefore is not covered by
Title Ill of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title Ill (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known GAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title Ill, Section 313.
Pennsylvania Worker and Community Right-To-Know Act:

To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
United States TSCA Inventory (TSCA)

The product meets the definition of an article and is exempt from inventory requirements.
16. OTHER INFORMATION
Revision
Identification Number: 10119557 4 I A001 / Issue Date: 09/04/2015 / Version: 11.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
TWA 8-hrTWA
US WEEL USA. Workplace Environmental Exposure Levels WEEL
Information Source and References

This SOS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
Page 9 of 10
Page 509 of 516
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
Page 10 of 10
Page 510 of 516
Specialty Vermiculite Corp.
SAFETYDATA SHEET
Product Name: Masonry Insulation
SOS ID Number: Z-01792 SOS Date: 4/17/2015
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Masonry Insulation
SDS Number: Z-01792
Cancelled MSDS Number: Z-01713
Chemical Family Name: Expanded Vermiculite (Enoree, South Carolina); Magnesium-
Aluminosilicate Mineral
Product Use: Aggregate Insulating Material for Masonry Applications
11
Chemical Formula: (Mg, Ca, K, Fe )3 (Si, Al, Fe 111
) 4 0 10 (OH)2 ·4(H 20)
CAS # (Chemical Abstract Service Mixture-NIA
Number):
Manufactured by:
Specialty Vermiculite Specialty Vermiculite
rd
26383 Hwy 221 N 14810- 123 Avenue
Enoree, SC 29335 Edmonton, Alberta T5L 2Y5
In Case of Emergency Call:
Enoree Plant: 800 342.2017 Edmonton Plant: 780 454.4511
SECTION 2- HAZARDS IDENTIFICATION
Classifications:
Acute toxicity (oral, dermal, inhalation): Category 4
Pictogram:
Signal Word:
WARNING
Hazard Statements:
H305: May be harmful if swallowed and enters airways.
H320: Causes eye irritation
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection
Page 511 of 516

Response:
P301: IF SWALLOWED: Dilute with large quantities of water. Consult a physician if symptoms develop.
P302: IF ON SKIN: Wash with soap and water. If discomfort or irritation persists, consult a physician.
Remove contaminated clothing and wash before reuse.
P304: IF INHALED: Get fresh air. If symptoms persist, consult a physician. If breathing has stopped, give
artificial respiration then oxygen if needed.
P305: IF IN EYES: Flush eyes with water for at least 15 minutes while holding eyelids open. If discomfort
or irritation persists, consult a physician.
Storage:
P402: Store in a dry place.
Disposal:
P501: Consult all regulations (federal, state, provincial, local) or a qualified waste disposal firm when
characterizing waste for disposal. According to EPA (40 CFR § 261 ), waste of this product is not defined
as hazardous. Dispose of waste in accordance with all applicable regulations. According to US EPA (40
CFR § 261.3) waste of this product is not defined as hazardous.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS# Percent (max)

Vermiculite 001318-00-9 50-100
Quartz 014808-60- 7 1-10
SECTION 4- FIRST AID MEASURES:

Skin Contact: Wash with soap and water. If discomfort or irritation persists, consult a physician. Remove
contaminated clothing and wash before reuse.
Eye Contact: Flush eyes with water for at least 15 minutes while holding eyelids open. If discomfort or
irritation persists, consult a physician.
Ingestion: Dilute with large quantities of water. Consult a physician if symptoms develop. Never give
anything by mouth to an unconscious person.
Inhalation: If symptoms develop, get fresh air. If symptoms persist, consult a physician. If breathing has
sto ed, ive artificial res iration then ox en if needed.
Extinguishing Media: Not Applicable. Product will not burn.

Special Fire Fighting Procedures: None
No special procedures specific to this product.
Unusual Fire and Ex losion Hazards: None.
SECTION 6-ACCIDENTAL RELEASE MEASURES:
Spills/Leaks: Carefully shovel or sweep up spilled material and place in suitable container for recycle or
disposal. Dampen with water spray or use other methods to clean spill which avoid creating dust. Discard
empty packaging promptly. Avoid excessive handling of empty packaging, which may result in
unnecessar release of airborne articulates.
Handling Procedures:
Material is for professional use only. Keep out of the reach of children.
Precautionary Measures:
Avoid contact with eyes, skin and clothing.
Avoid creating and inhaling airborne dust or particulates.
Do not take internally.
Page 512 of 516

Practice good personal hygiene to avoid ingestion.
Use only with adequate ventilation.
Wash clothing before reuse.
Respiratory Protection: Respiratory protection may be desirable if dust is created in handling and is
required at or above the Permissible Exposure Limit (PELs). A dust respirator such as a 3M type P-95 is
recommended.
Skin Protection: Gloves are recommended.
Eye Protection: Safety glasses or goggles should be worn.
Work/Hygienic Practices: Use good personal hygiene practices.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
EXPOSURE GUIDELINES (US)
lnaredient ACGIHTLV OSHA PEL Other
TWA STEL Ceilinq TWA STEL Ceilinq
Vermiculite - - - - - -
0.025 mg/m" TWA 0.1 mg/m"TWA
Quartz
(respirable fraction) (respirable dust)
In addition to the exposure limits referenced above, the following non-specific limits for dust apply to this
product; OSHA, 15 mg/m 3 - TWA or Total Dust and 5 mg/m 3- TWA as Respirable Dust, ACGIH, 10 mg/m 3 -
TWA as Total Dust and 3 mg/m 3 - TWA as Respirable Dust.
EXPOSURE GUIDELINES (CANADA)
Employers should consult local Provincial regulatory limits for exposure guidelines which may vary locally.
Engineering Controls: General ventilation may be desirable and should be used where appropriate.
Personal Protective Equipment:
Respiratory Protection: Respiratory protect may be desirable if dust is created in handling and is
required at or above the Permissible Exposure Limit (PEL) for nuisance particulates.
Skin Protection: Gloves are recommended.
Eye Protection: Safety glasses or goggles should be worn.
Work/Hygienic Practices: Use good personal hygiene practices.
Quartz (Crystalline silica) is a naturally occurring mineral that is commonly contained in materials that are
mined from the earth's surface such as sand, limestone, clay and gypsum (calcium sulfate). Total quartz
is a value usually representing the combined fraction of large, non-respirable sized particles and of
respirable sized particles (less than ten micros in aerodynamic diameter). It is only the respirable sized
fraction of total quartz that is recognized as hazardous by professionals in the field of Occupational Health
and b most re ulato a encies
Physical State: Solid

Appearance/Odor: Brown or Grey free flowing aggregate
Odor Threshold: (ppm) Not Determined
pH: Not Applicable
Melting point/Freezing point: >1320°C
Vapor Pressure: (Mm Hg) Unknown
Vapor Density: (Air = 1) Unknown
Solubility In Water: Negligible
Specific Gravity: (Water= 1) Not Applicable
Evaporation Rate: (Butyl Acetate=1) Not Applicable
Boiling Point: Not Applicable
Flammability: Not Available
Viscosity: Not Applicable
Bulk Density: (pounds/Cubic Foot) (Pcf) 4-10 PCF
% Volatiles (gr/L): (?0°F) (21°C) Not Available
Partition coefficient: n-octanol/water Not Available
Flash Point: Not Applicable
Flash Point Method: Not Applicable
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Auto-Ignition Temperature: Not Available
Decomposition Temperature: Not Available
Page 513 of 516

Chemical Stability: Stable
Hazardous Reactivity Potential: Will not occur
Conditions to Avoid: Expanded Vermiculite is often used as a chemical absorbent.
When contact with highly reactive chemicals or chemicals that
can off-gas at temperatures above room temperature (such as
Hydrogen peroxide solutions) care should be taken to neutralize
or make these materials inert prior to absorption. If possible
consult the SOS or supplier of the material being absorbed.
Hazardous Polymerization: Will not polymerize.
Hazardous Decomposition Products: None known for this product.
SECTION 11 -TOXICOLOGICAL INFORMATION
Ingredient (No data unless listed.) CAS Number LD50 and LC50
Carcinoqenicitv·
IARC IARC IARC NTP NTP
Ingredient OSHA
Group 1 Group 2A Group 2B Known Suspect
Vermiculite No No No No No No
Quartz Yes No No Yes No Yes
Mutagenicity: Not applicable.
Teratogenicity: Not applicable.
Reproductive Toxicity: Not applicable.
Possible routes of exposure:
Inhalation: May cause irritation.
Ingestion: May cause irritation.
Skin: May cause irritation.
E es: Ma cause irritation.
Environmental Fate: No data available for product.
Ecotoxicity: No data available for product.
SECTION 13- DISPOSAL CONSIDERATIONS

Waste Disposal Procedures:
Consult all regulations (federal, state, provincial, local) or a qualified waste disposal firm when
characterizing waste for disposal. According to EPA (40 CFR § 261 ), waste of this product is not defined
as hazardous. Dispose of waste in accordance with all applicable regulations. According to US EPA (40
CFR § 261.3) waste of this product is not defined as hazardous.
SECTION 14 - TRANSPORATION INFORMATION
Proper Shipping Name: Not Applicable
UN/NA Number: Not Applicable
Domestic Hazard Class: Nonhazardous
Surface Freight Classification: Vermiculite, other than Crude
Label/Placard Required: Not Applicable
REGULATORY CHEMICAL LISTS:

CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
Chemical Name CAS# Wt % CERCLA RQ
SARA Title Ill (Superfund Amendments and Reauthorization Act)
SARA Section 312/Tier I & II Hazard Categories
Health Immediate (acute) Yes
Health Delayed (chronic) Yes
Flammable No
Reactive No
Pressure No
Page 514 of 516

302 Reportable Ingredients (Identification Threshold 1 %.):
Chemical Name CAS# Wt % SARA 302 TPQ
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name CAS# Wt %
National Volatile Organic Compound Emission Standards For Architectural Coatings:
Volatile Organic Content: (gr/L) Not Applicable
WHMIS Classification(s): D2 B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR). This MSDS contains all the information required by the CPR.
State Regulatory Information:
California Proposition 65: WARNING! This product contains substances known to the state of California to
cause cancer, birth defects or other reproductive harm.
Massachusetts Hazardous Substance List (Identification threshold 0.001% (1 ppm)):
Chemical Name CAS# Wt %
Quartz 014808-60-7 < 1%
New Jersey Hazardous Substance List (Identification threshold (0.1 %)):
Chemical Name CAS#
Pennsylvania Hazardous Substance List (Identification threshold 0.01 %):
Chemical Name CAS#
CHEMICAL INVENTORY STATUS:
All chemicals in this product are listed or exempt from listing in the following countries:
us CANADA EUROPE AUSTRALIA JAPAN KOREA PHILIPPINES
TSGA DSL I NDSL EINEGS/ELINGS AIGS ENGS EGL PIGGS
Yes Yes I No Yes Yes Yes Yes Yes
SECTION 16 - OTHER INFORMATION I
Non-Hazardous Ingredient Disclosure:
Chemical Name CAS Number
Page 515 of 516

Vermiculite
WARNING
Maybehannfulif swallowed
andentersairways.Causeseyeirritation.
Donoteat,drinkor smokewhenusingthisproduct.
WearProtective
gloves/protective
clothing/eye
protectionlface
protection.
If SWALLOWED:Dilutewithlargequantities
of water.Consulta physician
if symptons
develop.
Never
giveanything
bymouthtoanunconscious person.
IfONSKIN:Washwithsoapandwater,lf discomfort
or irritationpersists,
consulta physician.
Remove
contaminated
clothingandwashbeforereuse.
8
lf INHALED: Getfreshair.lf symptons ifbreathing
presisi,consulta physician. hasstopped,
give :::c
artificialrespiration
thenoxygenifneeded. C>
lf!N EYES:Flusheyeswithwaterforat least15minutes

whileholdingeyelidsopen.If discomfort
or
irritation
persist.consul!a physician.
Storein a dryplace.
Specialty Vermiculite Corp. 26383 Hwy 221N. Enoree, SC 29335 800-342-2017
Prepared by: EH&S Department

Approved by:
Approved Date:
Disclaimer:
"The data included herein are presented in accordance with various environment, health and safety regulations. It
is the responsibility of a recipient of the data to remain currently informed on chemical hazard information, to
design and update its own program and to comply with all national, federal, state and local laws and regulations
applicable to safety, occupational health, right-to-know and environmental protection."
For additional information please~cont;!;:les Technician for your area:

Southeast Canada
Donna Frassrand avid Jeffery Brian Colbert
(770)262.0396 I 830)714.5447 (905)302.5824
Customer Service Contacts:
Laura Cody Donna Ernst Grace Cruz Darlene Lord LindaArdnt
Enoree Plant Pompano Plant Phoenix Plant Winnipeg Plant Edmonton Plant
(800)342.2017 (800)432.7394 I (602)272.6663 (204)786.5681 (780)454.4511
SPV Corp & SPV Canada Corp Plant & Office Locations:
ENOREE,SC PHOENIX, AZ POMPANO BEACH, FL ALBERTA MANITOBA
26383 Hwy 221 N 4220 West Glenrosa 1200 NW 15th Avenue 14810- 123'' Avenue 1140 Pacific Avenue
Enoree, SC 29335 Phoenix, AZ, 85019 Pompano Beach, FL 33069 Edmonton, Alberta T5L 2Y5 Winnipeg, MB R3E I G6
P(864 )969 .3353 P(602)272.6663 P(800)432.7394 P(780)454.451 l
F(602)278.5504 F(954)968.5586 F(403)452.1883
P(204)786.5681
F(864)969.9923
F(204)783.0308
We hope that the information given here will be helpful. It is based on data and knowledge considered to be true and accurate and is offered for the user's consideration,
investigation and verification but we do not warrant the results to be obtained. Please read all statements, recommendations or suggestions in conjunction with our conditions
of sale which apply to all goods supplied by us. No statement, recommendation or suggestion is intended for any use which would infringe any patent or copyright.
Page 516 of 516

Concrete SDS 2018

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Concrete SDS 2018

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INVENTORY OF HAZARDOUS

CHEMICALS FOR SDS BOOKS

3 Concrete - 2255 White Concrete Curing Compound

197 Concrete - Spec Mix, Masonry Cement Mortars

305 Concrete - Stamped & Curbing, Sika-Rugasol-S Retardant

Product: 2255-WHITE Part Number: 3122550

HMIS HAZARD STATEMENTS

SARA Vapor Pressure LEL

FLASHPOINT: 110 degrees F Method 1010

product from freezing. Keep away from ignition so

HAZARDOUS/NON-HAZARDOUS MATERIAL: Non-hazardous by ground transportation.

PREPARED BY: Dave Carey

Product: 3405 REGULAR (LOW SULFUR) Part Number: 4215000

HMIS HAZARD STATEMENTS

% by SARA Vapor Pressure LEL

Prevent job-site damage.

HAZARDOUS/NON-HAZARDOUS MATERIAL: Not regulated by DOT.

Date Revised: 5/24/10 Date Printed: 4/1/15

MANUFACTURER: SIERRA CORP/TK PRODUCTS EMERGENCYPHONE: 1-800-424-9300

HAZARD CLASS HAZARD CATEGORY

SECTION 3 - COMPOSITION/INFORMATIONON INGREDIENTS

*** NO REPORTABLE QUANTITIES OF HAZARDOUS INGREDIENTS ARE PRESENT***

PRIMARY ROUTES OF EXPOSURE:

SECTION 4 - FIRST AID MEASURES

SECTION 5 - FIRE AND EXPLOSION HAZARD DATA==========

Date Revised: 5/24/10 Date Printed: 4/1/15

SPECIAL FIREFIGHTING PROCEDURES:

UNUSUAL FIRE AND EXPLOSION HAZARDS:

SECTION 6 - ACCIDENTAL RELEASE MEASURES

SECTION 7 - HANDLING AND STORAGE

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

SECTION 10 - STABILITY AND REACTIVITY DATA

Date Revised: 5/24/10 Date Printed: 4/1/15

SECTION 11 - TOXICOLOGICAL INFORMATION

SECTION 12 - ECOLOGICAL INFORMATION

SECTION 13 - DISPOSAL CONSIDERATIONS

SECTION 14 - TRANSPORT INFORMATION

STATE SPECIFIC REQUIREMENTS:

STATE LISTED COMPONENTS CAS NUMBER STATE CODE

=============SECTION 16 - OTHER INFORMATION

Product: ACRY-LOK™ BONDING AGENT Part Number: 3620000

Manufacturer: W.R. Meadows®, Inc. Address: 300 Industrial Drive

HMIS HAZARD STATEMENTS

emical or carbon dioxide.

HAZARDOUS POLYMERIZATION: Will not occur.

HAZARDOUS/NON-HAZARDOUS MATERIAL: Non-hazardous.

SAFETY DATA SHEET

Recommended use and restriction on use

Contact person: EH&S Department

Hazard Symbol: No symbol

Signal Word: No signal word.

Hazard Statement: not applicable

Precautionary not applicable

Other hazards which do not None.

Chemical Identity GAS number Content in percent(%)'

Ammonium hydroxide 1336-21-6 0.1 -1%

Inhalation: Move to fresh air.

Eye contact: Rinse immediately with plenty of water.

Most important symptoms/effects, acute and delayed

Symptoms: May cause skin and eye irritation.

Indication of immediate medical attention and special treatment needed

Treatment: Get medical attention if symptoms occur.

Suitable (and unsuitable) extinguishing media

* NO REPORTABLE QUANTITIES OF HAZARDOUS INGREDIENTS ARE PRESENT*