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Bentonitin İletkenliğe Etkisi Ali Hoca PDF
Bentonitin İletkenliğe Etkisi Ali Hoca PDF
Bentonitic Mixtures
A. Hakan Ören1; Tuğçe Özdamar Kul2; Merve E. Koç3; and Havva Demirkıran3
1
Associate Professor, Dept. of Civil Engineering, Dokuz Eylül Univ., Tınaztepe
Yerleşkesi, Buca-İzmir/Turkey (corresponding author).
2
Research Assistant, Dept. of Civil Engineering, Dokuz Eylül Univ., Tınaztepe
Yerleşkesi, Buca-İzmir/Turkey.
3
Graduate Student, Dept. of Civil Engineering, Dokuz Eylül Univ., Tınaztepe
Yerleşkesi, Buca-İzmir/Turkey.
Abstract: This study discusses and compares the hydraulic conductivities of GCLs to
those of sand-bentonit mixtures (SBMs)/zeolite-bentonite mixtures (ZBMs). ZBMs had
20% and 30%, whereas SBM had 20% bentonite contents. The effective stress applied
on GCLs was greater than bentonitic mixtures. Neither GCLs nor bentonitic mixtures
were prehydrated with water. The results showed that hydraulic conductivities of non-
prehydrated GCLs were significantly greater than those of ZBMs and SBMs. Applying
greater effective stress did not reduce the hydraulic conductivities of GCLs. Although
bentonitic mixtures were non-prehydrated during hydraulic conductivity tests, they had
been hydrated with water before compaction. In order to figure out this condition and to
make better comparison between the hydraulic conductivities of GCLs and bentonitic
mixtures, two brand new GCLs were prehydrated with DI water (DIW). Then,
permeation was begun with DIW until one pore volume of flow was passed through the
samples. Finally, the permeant was switched to landfill leachate and hydraulic
conductivities were determined. The results showed that initial permeation of GCLs
with DIW decreased the hydraulic conductivity when GCLs were further permeated with
landfill leachates. Also, the hydraulic conductivities of GCLs were less than those of
bentonitic mixtures. This may be attributed to greater effective stress applied on GCLs.
INTRODUCTION
Clays are the principal constituent of impermeable barriers. Not only compacted
clayey soils, but also bentonites can be used with sands, such as sand-bentonite mixtures
(SBMs), as barrier material (Kenney et al., 1992; Alston, et al., 1997). SBMs have some
physical advantages when compared to compacted clays. For example, flow is controlled
by the bentonite particles in the mixture; thus, the hydraulic conductivity of SBMs is
around 1.0×10-11 m/s which is less than that of many compacted clays (Gleason et al.,
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1997; Stern and Shackelford, 1998). In addition, SBMs have low volumetric shrinkage
with respect to compacted clays, resulting high resistance to desiccation cracking
(Kleppe and Olson, 1985).
Recently, a new bentonitic mixture, i.e. zeolite-bentonite mixture (ZBM), has been
proposed as an alternative to SBM (Kayabalı, 1997; Kayabalı and Mollamahmutoğlu,
2000). Zeolite is a rock forming material that has porous structure (Jacobs and Förstner,
1999). Moreover, zeolite has negatively charged surface and high specific surface area
(Mumpton, 1999). Because of these advantages, some researchers thought that it would
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be better if zeolite is replaced with sand in bentonitic mixtures (Kayabalı, 1997). On the
other hand, Ören et al. (2011) reported up to 20-30 times greater hydraulic conductivities
for ZBMs when compared to the hydraulic conductivities of SBMs at the same bentonite
contents. However, the hydraulic conductivity of ZBM is still lower than 1.0×10-9 m/s
which is suggested limit for the most environmental regulatory agencies.
Another barrier material whose use has been rising up over time is the geosynthetic
clay liner (GCL). GCLs are carpet-like thin materials that are composed of sodium or
polymer treated bentonites sandwiched between two geotextiles. The hydraulic
performance of GCLs is controlled by the bentonites. Thus, many studies have been
conducted to determine the factors controlling the hydraulic conductivity of GCLs
(Petrov et al., 1997; Shackelford et al., 2000; Jo et al., 2001; Guyonnet et al., 2005;
Katsumi et al., 2007; Guyonnet et al., 2009; Benson et al., 2010).
Sufficient knowledge has been acquired in the literature about the hydraulic
conductivity of GCLs. However, there is little information about the comparison of this
behavior between GCLs and bentonitic mixtures (Kraus et al., 1997). Thus, the aim of
this study is to investigate and discuss the hydraulic performance of SBM, ZBM and
GCLs in the case of permeation with landfill leachates.
Materials
GCLs (GCL-A and GCL-B) were supplied from local manufacturers. Both were
needle punched which connect the woven and nonwoven geotextiles. Although “lower
quality bentonite (LQB)” is referred to as the GCL having bentonite with lower amount
of montmorillonite content (Lee et al., 2005), GCL-A was named as “lower quality”
herein because of the lower liquid limit of bentonite (i.e. 108%). GCL-B was named as
“higher quality” on account of greater liquid limit value. GCL-B was polymer treated
and thus, the liquid limit of this GCL was 1163% (Ören and Demirkıran, 2015).
Clinoptilolite type of natural zeolite was supplied from Rota Madencilik Co.
(Manisa,Turkey). Zeolite was composed of sand sized uniform grains. Sand was
gathered from Manisa, but sieved in the laboratory to achieve the same grain size as with
zeolite. The maximum grain size was 1.2mm and fines contents were less than 2% for
both materials. Na-bentonite was provided from Karakaya Co (Ankara, Turkey). The
liquid and plastic limits were 529% and 38%, respectively.
The bentonite amount in the mixture was arranged based on the total weight. For
example, 20% SBM (or ZBM) means 20% bentonite was mixed with 80% of sand (or
zeolite) by dry weight. The other details about the sample preparation can be followed
from Ören et al. (2014) and Ören and Kaya (2014).
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The hydraulic conductivity tests were conducted with Type II DI water and landfill
leachates. The landfill leachates were gathered from İzmir and Aydın landfills. The
cation concentrations of the leachates (i.e. Na+, K+, Mg2+, Ca2+) were determined with
ICP-OES (Table 1). The pH and electrical conductivity of the leachates were determined
with Accumet XL50 and the results are presented in Table 1 as well.
Table 1. Cation concentrations, pH and electrical conductivity of landfill leachates.
Electrical
Landfill Na+ K+ Mg2+ Ca2+
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pH Conductivity
Leachate (mg/L) (mg/L) (mg/L) (mg/L)
(mS/cm)
LL-1 2903 1135 265 101 7.6 20.8
LL-2 1507 1643 173 409 8.3 21.1
Methods
The physical properties of the materials were determined following the ASTM
standards. The sieve and hydrometer analyses were conducted as described in ASTM
D421 and ASTM D422. The consistency limits of bentonites were determined following
ASTM D4318. Standard Proctor compaction tests were performed at 2% and 3-5% wet
of optimum water contents of SBM and ZBM (ASTM D698). The compaction
parameters of SBMs and ZBMs are presented in Table 2.
Table 2. Compaction parameters of bentonitic mixtures.
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Total of 14 hydraulic conductivity tests were conducted throughout the study. Because
limited flexible-wall permeameters were available in the laboratory, the hydraulic
conductivities of bentonitic mixtures with DIW were not measured. The test durations
for bentonitic mixtures were as long as 18 months whereas those of GCLs were as low
as couple days.
The chemical equilibrium of hydraulic conductivity tests were controlled with pH and
electrical conductivity measurements as suggested by ASTM D6766. Effluent values
were normalized with the influent values to determine pHout/pHin and ECout/ECin. The
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-7
10
-8
GCL-A (LL-1)
10 GCL-B (LL-1)
GCL-A (LL-2)
GCL-B (LL-2)
-9
10
0 5 10 15 20 25 30 35 40
Pore Volumes of Flow
FIG. 2 shows the hydraulic conductivities of SBM/ZBM with the landfill leachates. It
is obvious that the flow passed through the bentonitic mixtures were significantly less
than the flow passed through GCLs. The lower thickness (0.5 cm versus 5.8 cm) led to
have more PVFs for GCLs than for bentonitic mixtures.
Based on the last six readings, the final hydraulic conductivity for 20% SBM is
2.9×10-11 m/s (FIG 2a). The hydraulic conductivity of 20% ZBM decreased from
2.1×10-8 m/s to approximately 1.2×10-10 m/s after about 0.3 PVF and reduced
furthermore (9.2×10-11 m/s) with LL-1. Such kind of reduction was not seen for the
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hydraulic conductivity of 30% ZBM. As the bentonite content increased in the mixture,
the hydraulic conductivity of 30% ZBM became one half of the hydraulic conductivity
of 20% ZBM (FIG. 2a).
-7
30% ZBM
-9
10
-10
10
-11
10
a)
-12
10
0.0 0.2 0.4 0.6 0.8 1.0
Pore Volumes of Flow
-8
10
Hydraulic Conductivity (m/s)
20% SBM
LL-2 20% ZBM
-9
10 30% ZBM
-10
10
-11
10
b)
-12
10
0.0 0.2 0.4 0.6 0.8 1.0
The hydraulic conductivities of bentonitic mixtures permeated with LL-2 are shown in
FIG. 2b. The hydraulic conductivity of 20% SBM was as low as 2.9×10-11 m/s which is
equal to the hydraulic conductivity of 20% SBM permeated with LL-1. The hydraulic
conductivity behavior of 20% ZBM permeated with LL-2 was also similar to that of
20% ZBM permeated with LL-1. Considering the average of the last six readings, it can
be seen that the hydraulic conductivity of 30% ZBM was almost two times less than that
of 20% ZBM (FIG. 2b).
The pH and EC measurements on GCLs showed that termination criterion was
achieved at the end of all hydraulic conductivity tests. However, it was partially satisfied
with ZBMs. Regardless of the leachate type, pHout/pHin values were within 1.0±0.1 for
ZBMs. However, ECout/ECin values for %20 ZBM and 30% ZBM were 0.92 and 0.46
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when permeated with LL-1, 0.25 and 0.38 when permeated with LL-2, respectively.
Considering the time limits of the project, the hydraulic conductivity tests on ZBMs
were terminated without satisfying these criterions.
The comparison of the hydraulic conductivities between non-prehydrated GCLs and
bentonitic mixtures are shown in FIG. 3. The GCLs had up to 4 orders of magnitude
greater hydraulic conductivities when compared to SBMs and ZBMs. The reason is that
bentonitic mixtures were slightly prehydrated during compaction test. After applying
compactive effort, swollen bentonites block the inter-granular pores, resulting reduction
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in the hydraulic conductivity. The difference in the initial water contents is responsible
for the differences in the hydraulic conductivities.
It is easy to calculate the initial water contents of bentonites in the GCLs. However, it
is rather complex to calculate the water contents of bentonites in binary mixtures such as
SBMs and ZBMs. It is assumed for SBMs that sand has no affinity for water and only
bentonite particles uptake water (Kenney et al., 1992). However, zeolite has porous
structure and thus, the water is shared between zeolite and bentonite particles. Because
of this, bentonite water contents in SBMs are greater than bentonite water contents in
ZBMs. Calculations also shows that bentonite water content decreases as the bentonite
amount in the mixture increases. Thus, bentonite water content in 30% ZBM is less than
that in 20% ZBM. The details can be found in Ören et al. (2011). Based on this
calculation, the initial bentonite water contents for 20% SBM, 20% ZBM and 30% ZBM
were calculated as 103%, 87%, and 65%, respectively. On the other hand, the initial
bentonite water contents for GCLs were around 12% which are far below bentonitic
mixtures.
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It is obvious that the lower the bentonite water content in GCLs the lower is the swell
of bentonite particles when faced with landfill leachates. This allows preferential flow
paths along GCLs. The flow paths could not be closed even effective stress applied on
GCLs were greater than bentonitic mixtures.
To mimic the effect of GCL hydration on hydraulic conductivity, GCL-A and GCL-B
were permeated with DIW and subsequently with landfill leachates. As expected, the
hydraulic conductivities of non-prehydrated GCLs were significantly greater than the
hydraulic conductivities of prehydrated GCLs. The final hydraulic conductivities of
prehydrated GCL-A were 5.4×10-12 m/s and 9.7×10-12 m/s, when permeated with LL-1
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and LL-2, respectively. The hydraulic conductivities of prehydrated GCL-B with the
same leachates were almost one half the hydraulic conductivities of GCL-A.
Permeating the GCLs with DIW enable bentonite particles to swell and close the
preferential flow paths within GCLs. When the permeant is switched to landfill leachate,
negatively charged clay surface is started to be bombarded with the cations of leachates,
resulting cation exchange between permeant and the bentonite particles. Since bentonite
particles are already swollen with DIW, cation exchange slowly takes place which
depends on bentonite and permeant properties (Jo et al., 2001; Kolstad et al., 2004; Lee
and Shackelford, 2005). In this study, the test duration (~ 6 months) applied on
prehydrated GCLs were not sufficient to provide fully replacement of cations between
bentonite particles and landfill leachates. pH and electrical conductivity measurements
also revealed that hydraulic conductivity tests did not come to chemical equilibrium.
However, it can be stated that DIW permeated GCLs were unaffected from the adverse
effect of landfill leachates by means of short term hydraulic conductivity.
The hydraulic conductivities of prehydrated GCLs are also compared with those of
bentonitic mixtures (FIG. 4). It is depicted in FIG. 4 that hydraulic conductivities of
bentonitic mixtures were greater than GCL-A and GCL-B when permeated with L-1 and
LL-2. Regardless of leachate and GCL type, SBMs had up to one order of magnitude,
whereas ZBMs had up to 58 fold greater hydraulic conductivities than those of GCLs.
The differences in the hydraulic conductivities of GCLs and bentonitic mixtures are
possibly due to the higher effective stress applied on GCLs (90 kPa vs. 42.5 kPa).
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CONCLUSIONS
The hydraulic conductivities of GCLs and bentonitic mixtures (SBMs and ZBMs) to
two different landfill leachates (LL-1 and LL-2) were discussed and compared in this
study. Brand new two GCLs were used during the hydraulic conductivity tests one of
which was lower quality (GCL-A) and the other was higher quality (GCL-B) regarding
to their liquid limit values. Hydraulic conductivity tests were also carried out on SBMs
and ZBMs. To investigate the combined influence of effective stress and permeation
while comparing the hydraulic conductivities between GCLs and bentonitic mixtures,
the effective stress applied on bentonitic mixtures were set lower than those of GCLs.
The results showed that the hydraulic conductivity of 20% SBM was lower than that of
20% and 30% ZBMs. However, the hydraulic conductivities of non-prehydrated GCLs
were up to 4 orders of magnitude greater than those of bentonitic mixtures when LL-1
and LL-2 were used as the permeant. This shows that applying greater effective stress on
GCLs could not reduce the hydraulic conductivity.
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Impact of effective stress on the hydraulic conductivity was seen when GCLs were
initially permeated with DIW and then LL-1 or LL-2. In this case, the hydraulic
conductivities of DIW permeated GCLs were decreased to a level as low as 2.4×10-12
m/s. The hydraulic conductivities of DIW permeated GCLs were about 12 times and 58
times less than the hydraulic conductivities of SBM and ZBMs, respectively.
ACKNOWLEDGEMENT
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The main part of this study was occupied by the hydraulic conductivity results of
GCLs. This part was funded by the Scientific and Technical Research Council of
Turkey, TUBITAK (Grant No: 111M718). The second part of this study is related to the
hydraulic conductivities of bentonitic mixtures which was supported by Dokuz Eylül
University under Scientific Research Projects (Grant No: 2012.KB.FEN. 006). The
authors are grateful for both funding.
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Gleason, M.H., Daniel, D.E. and Eykholt, G.R. (1997). "Calcium and sodium bentonite
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Katsumi, T., Ishimori, H., Ogawa, A., Yoshikawa, K., et al. (2007). "Hydraulic
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