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CAPE Chemistry 2009 U1 P1 PDF
CAPE Chemistry 2009 U1 P1 PDF
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TESTCODE02112010
FORMTP2009155 Slpsture
MAYIJUNE2009
2. In, addition to this test booklet, you should have an answer sheet.
3. Do not be concerned that the answer sheet provides spaces for more answers than there are items in
this test.
4. Each item in this test has four suggested answers lettered(A), (B), (C), (D). Read each item you are
-
about to answer and decide which choice is best.
5. On your answer sheet, find the number which corresponds to your item and shade the space having
the same letter as the answer you have chosen. Look at the sample item below.
Sample Item
(A)
(B)
(C)
(D)
n to cr•
n to it•
cr to a•
Tt to 7t*
Sample Answer
-
The best answer to this item is "er to er•", so answer space (C) has been shaded.
6. Ifyou wanttochangeyouranswer, be sure to erase your itcompletcly before you fill in your new choice.
7. Whenyouaretoldtobegin,tumthepageandworkasquicklyandascarefullyasyoucan. lfyoucannot
answeranitem,omititandgoontothenextone. Youcancomebacktotheomitted item later. Your
score will be the total number of correct answers.
8. Youmaydoanyroughworkinthisbooklet.
9. Figures arc not necessarily drawn to scale.
--=
.....
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! !!!
.....
!!!!!!!
iii
I 0. Theuseofnon-programmable calculators is allowed .
Copyright02009CaribbeanExaminationsCouncil.
All rights reserved.
iiiii 021120 IOCAPE2009
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1. Which of the following has the GREATEST 2. A radioactive clement, M, ofmass number
polarizing power? A, and atomic number Z, undergoes ll decay,
followed by a decay. The final elemem, N,
(A) ca>+ will be
(B) Be 2•
(C) Li'
(A) ~-1 N
(B) A-<N
z
(D) Sr2'
(C) A-4N
Z+I
(D) A-<N
Z-1
c
Relative ~
Abunduce
D
B
E
. . . . . . . I.
~ ~ ~ ~ ~ " q ~ m ~ •
m/e
3. If peak A represents the ion " Cl• , which possible ions would give the peaks, B
andE?
37
(A) Cl' and ( 37 Cl- 37 Cl)'
(B) ("Cl _>Sci)' and (37 Cl- 37 CI)'
37
(C) Cl' and ('s Cl-'s Cl)'
37
(D) CI' and ('sCl- 37 CI)'
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'021120IOICAPB2009
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4. The electronic configuration ofthe Cu" ion 8. Which of the following is true about 5 dm' of
is represented as hydrogen and 5 dm' of oxygen at 0 °C and
101 kPa?
(A) (Ar)3s 2 3p 6 3d 10 4s 1 They react to produce 5 dm' of water.
(A)
(B) 2
[Ar)3s 3p 3d 6 10 (B) They possess the same amount of
kinetic energy.
(C) [Ar] 3s 2 3p 6 Jd' 4s 2 (C) They contain the same number of
(D) 2
[Ar)3s 3p 3d 6 9 molecules.
(D) They react completely with each
other.
5. Which of the fol lowing factors increases the
first ionisation energy of an atom?
9. For complete reaction, 0.25 g of a monobasic
acid requires 10 cm' of 0.2 mol dm·' sodium
(A) Increased screening by inner
hydroxide. What is the relative molecular
electrons
mass of the acid?
(B) Larger number of valence electrons
(C) Greater nuclear charge
(A) 12.5
(D) Larger atomic radius
(B} 62.5
(C) 125
(D) 250
6. Which oftlie following describes potassium
bromide?
10. When86 gofthe ionic salt, Caso,. xH,O, is
(A) A network of covalently bonded
heated so that all ofits water of crystallisation
atoms
is driven off and 68.0 g of CaSO, remain,
(B) A substance which boils at 59 "C and
the value ofx is
decomposes at high temperatures
(C) A solid with a very high molar
(A) 1
enthalpy ofvaporization which does
(B) 2
not conduct when in a liquid state
A non-conducting solid which melts
tC) 3
(D)
(D) 4
to form a liquid that conducts
electricity
(A) 1
(B) 2
(C) 3
(D) 4
(A)
.
a Energy
.!
"
;;.
Pressure
.a
~~~~} __
(B)
"
~ ProduCll
.
~
(C)
a 13 . What is the activation energy of the
.!
REVERSE reaction?
~
(A) p
Pressure
(B) Q
(C) (Q+ P)
~
(D)
~ (D) (Q- P)
~
I/Pressure
(D)
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0211201 OK:!APE2009
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1
14. . The second ionisation energy ofcalcium is 1150 k J mol- •
(A) -932
(B) -712
(C) -492
(D) +492
16. An increase in temperature by about l 0 ° C usually doubles the rate ofa chemical reaction. This is
because the
(A) number ofmolecules having energy greater than the activation energy increases
(B) kinetic energy and temperature ofthe molecules decrease
(C) activation energy ofthe molecules required for reaction increases
(D) collision frequencyofthemolecules Huctuates
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02112010ICAPE2009
-'6 -
Item_!] refers to the table which shows the rate results for the reaction A+ B-> C
(A) Zero
(B) First
(C) Second
(D) Thiid
18. Thi diagrams show the Maxwell-Boltzmann distribution. Which of the following diagrams represents
the effect of an increase in temperature from 70 "C (T,) to 80 °C (T,)?
T,
(A) (C)
T,
(B) T (D)
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021•12010CAPE2009
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19. Which of the following statements about 22. The Haber Process can be represented by
dynamic equilibrium is NOT true? · theequation
(A) 0.1 mol dm' 24. When I cm' of dilute HCI is added to an
(B) 0.1 moI- 1 dm-2 alkaline buffer the
(C} 10 mo! dm-'
(D) IO mol- 1 dm' (A) pH increases drastically
(B) pH decreases drastically
(C) pH alters slightly
(D) buffer is destroyed
25. A buffer is made by dissolving 28.8 g of 27. Given that solubility of zinc sulphide in
sodium benzoate, C 6 H,C00Na, in l dm' of water at 25 °C is 1.0 x 10- 12 mol drn-3 ,
0.4 mol dm» benzoic acid, C 6 H,COOH. what is the K,. value at 25 °C?
Ko(benz<Hcocidl =6.4 x lO"'moldm"'. The pH of
the buffer is (A) l.O x 10· 12 mol2 drn ..
(B) 5.0 x 10·11 mol 1 dm ..
(A) 2.3 (C) 5.0 x 10·24 moi2 dm ..
(B) 3.9
(C) 4.2 (D) l.O x 10·1• mol 1 dm ..
(D) 5.0
(A)
3
e" OH-
(B)
(Fc(OH),
Platinised -+---;---+
platinum --+--1.0 mol dm.a H+
electrode
28. What needs to be changed to make this hydrogen electrode have.an E6 = O.OOV?
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02112010ICAPE2009
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29. A cell consists of aluminium metal in contact Item 30 refers to the cell diagram below.
with AP+ ions and copper metal in contact
Zn(s) IZn 2• (aq)llcu 2• (aq)jCu(s)
with Cu,. ions. The half-cell values are given
below.
30. Which of the following will cause an
E9N increase in cell potential?
--
Al>+ + 3e· ___,Al
Cu,. + 2e· ~ Cu
-1.66
+-0.34
(B)
Increasing concentration of Zn'' ions
only
Decreasing concentration of
Zn"(aq) ions and increasing con-
(in volts) is centration ofCu2•(aq) ions
(C) Decreasing concentration of Cu 2•
(A) 2.30 ions only
(B) 2.00. (D) Adding NaOH to cu>+ solution and
(C) 1.84 increasing the concentration of
(D) 1.32 Zn2• ions
(A) Na,0
(B) Si02
(C) so,
(D) c1,o,
pH of aqueous solution IO 7 0 I
i
Match each oxide below with one of the options above. Each option may used once,
more than once of not at all.
33. Oxideofsulphur
36. Which of the following chlorides of Group N (D) Cl-, 1-, Br-
elements is the BEST electrical conductor?
t
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40. Which ofthe following is NOT considered to 42. Cu(Il) sulphate gives
be a transition metal?
(a) a deep blue solution .with excess
(A) Zinc NH,(aq)
(B) Iron
(C) Cobalt (b) a yellow-green solution with excess
(D) Chromium concentrated HCI.
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02i 12010ICAPE2009
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44. Four solutions are each tested with aqueous 45. The ionic equation for the fonnation of lead
NH, which is added dropwise Wltil in excess. sulphate from lead{II) nitrate ( aq) and sodium
The following observations are noted . sulphate (aq) is
I II III IV
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02112010/CAPE2009