P_1=100

T_1=800
X_1= F(T_1 y P_1)
s_1= F(T_1 y P_1)
v_1= F(T_1 y P_1)
h_1= F(T_1 y P_1)
u_1= F(T_1 y P_1)
If v_2=v_1
X_2= F(v_2 y P_2)
s_2= F(v_2 y P_2)
u_2= F(v_2 y P_2)
h_2= F(v_2y P_2)
 s2-s1= (0.8524-1.845) Btu/lb R=-0.9926 ) Btu/lb R
v2=v1= 7.446 pies3/lb
h2-h1=-878.5 Btu/lb
u2-u1=-768.1 Btu/lb
x1=1
x2=0.37
𝐵𝑡𝑢
If 𝑄 = (𝑢2 − 𝑢1 ) + 𝑤 = −768.1 ; w=0 ( the process undergoes at constant
𝑙𝑏
volumen=0).
𝐶𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒 ∆𝑆𝑡𝑜𝑡𝑎𝑙 𝑖𝑛 𝑙𝑎𝑠𝑡 𝑒𝑥𝑒𝑟𝑐𝑖𝑠𝑒 𝑖𝑓 𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 𝑜𝑓 𝑠𝑖𝑛𝑘 𝑖𝑠 95°𝐹
𝐵𝑡𝑢
𝑄𝑠𝑦𝑠𝑡𝑒𝑚 = −768.1
𝑙𝑏
𝐵𝑡𝑢
𝑄𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠= 768.1
𝑙𝑏
𝐵𝑡𝑢
∆𝑠𝑠𝑦𝑠𝑡𝑒𝑚 = −0.9926
𝐿𝑏 𝑅
𝐵𝑡𝑢
𝑄𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 768.1
∆𝑠𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 = = 𝑙𝑏
𝑇𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 (95 + 459.6)𝑅
𝐵𝑡𝑢
∆𝑠𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 = 1.38
𝐿𝑏 𝑅
∆𝑠𝑡𝑜𝑡𝑎𝑙 = ∆𝑠𝑠𝑦𝑠𝑡𝑒𝑚 + ∆𝑠𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠
𝐵𝑡𝑢 𝐵𝑡𝑢
∆𝑠𝑡𝑜𝑡𝑎𝑙 == −0.9926 + 1.38
𝐿𝑏 𝑅 𝐿𝑏 𝑅

𝐵𝑡𝑢
∆𝑠𝑡𝑜𝑡𝑎𝑙 = 0.3874
𝐿𝑏 𝑅
 s2-s1= (0.5772-0.341) kJ/kg K=0.2362 ) kJ/kg K
v2=v1= 0.03382 m3/ kg
u2-u1=64.09 kJ/kg
x1=0.4
x2=0.7793
𝑘𝐽
If 𝑄 = (𝑢2 − 𝑢1 ) + 𝑤 = 64.09 ; w=0 ( the process undergoes at constant volumen=0).
𝑘𝑔

𝐶𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒 ∆𝑆𝑡𝑜𝑡𝑎𝑙 𝑖𝑛 𝑡ℎ𝑖𝑠 𝑒𝑥𝑒𝑟𝑐𝑖𝑠𝑒 𝑖𝑓 𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 𝑜𝑓 𝑠𝑖𝑛𝑘 𝑖𝑠 35°𝐶

𝑘𝐽
𝑄𝑠𝑦𝑠𝑡𝑒𝑚 = 64.09
𝑘𝑔
𝑘𝐽
𝑄𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠= − 64.09
𝑘𝑔
𝑘𝐽
∆𝑠𝑠𝑦𝑠𝑡𝑒𝑚 = 0.2362
𝑘𝑔𝐾
 𝑘𝐽
𝑄𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 −64.09
𝑘𝑔
∆𝑠𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 = =
𝑇𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 (35 + 273.16)𝐾
𝑘𝐽
∆𝑠𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 = −0.2079
𝑘𝑔 𝐾
∆𝑠𝑡𝑜𝑡𝑎𝑙 = ∆𝑠𝑠𝑦𝑠𝑡𝑒𝑚 + ∆𝑠𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠
𝑘𝐽 𝑘𝐽
∆𝑠𝑡𝑜𝑡𝑎𝑙 == 0.2362 − 0.2079
𝑘𝑔𝐾 𝑘𝑔 𝐾

𝑘𝐽
∆𝑠𝑡𝑜𝑡𝑎𝑙 = 0.0283
𝑘𝑔𝐾
A rigid tank contains an ideal gas that is being stirred by a paddle wheel. The temperature
of the gas remains constant as a result of heat transfer out. The entropy change of the gas
is to be determined.
Assumptions The gas in the tank is given to be an ideal gas.
Analysis The temperature and the specific volume of the gas
remain constant during this process. Therefore, the initial and
the final states of the gas are the same. Then s2 = s1 since

entropy is a property. Therefore, ∆𝑠𝑦𝑠𝑡𝑒𝑚=0