Top of Pyramid - Test #50- Solutions

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1.
The latent heat of vapourisation of water is 540 cal g-1 at
The vapour density of undecomposed N2O4 is 46. When 100°C. Kb for water is
heated, vapour density decreases to 24.5 due to its
dissociation to NO2. The percent dissociation of N2O4 at (a) 0.562 K.mole-1
the final temperature is: 
(b) 1.86 K.mole-1
(a) 87                                         (b) 60
(c) 0.515 K.mole-1
(c) 40                                         (d) 70
(d) 5.12 K.mole-1
2.
 
The molal depression constant for water=1.85 deg/molal
and for benzene is 5.12 deg/molal. If the ratio of the 7.
latent heats of fusion of benzene to water is 3:8, calculate
the freezing point of benzene. Which of the following aqueous solution has osmotic
pressure nearest to that an equimolar solution of
(a) 5.75°C K4[Fe(CN)6]?
(b) 5.12°C (a) Na2SO4
(c) 4.97°C
(b) BaCl2
(d) 6.1°C
(c) Al2(SO4)3
3.
(d) C12H22O11
Which of the following colligative properties is
associated with the concentration term 'molarity'? 8.
(a) Lowering of vap.pressure The ratio of the vapour pressure of a solution to the
(b) Osmotic pressure vapour pressure of the solvent is

(c) Depression in freezing point (a) Equal to the mole fraction of the solvent

(d) Elevation in boiling point (b) Proportional to the mole fraction of the solute

4. (c) Equal to the mole fraction of the solute

The vapoure pressure of a dilute aqueous solution of (d) None of the above
glucose is 750mm of mercury at 373K. The mole fraction 9.
of solute in the solution is-
A two phase system consisting of a liquid dispersed in
(a) 1/10 another liquid is known as-
(b) 1/76 (A) Foam 
(c) 1/7.6 (B) Suspension
(d) 1/35 (C) Emulsion
5. (D) Mist
Which one of the folowing pairs of solution can we 10.
expect to be isotonic at the same temperature-
The partial pressure of ethane over a saturated solution
(a) 0.1 (M) urea and 0.1 (M) NaCl
containing 6.56 X 10-2 g of ethane is 1 bar. If the solution
(b) 0.1 (M) urea and 0.2 (M) MgCl2 contains 5.00 X 10-2 g of ethane, then what shall be the
partial pressure of the gas.
(c) 0.1 (M) NaCl and 0.1 (M) Na2SO4
(a) 0.76 bar
(d) 0.1 (M) Ca(NO3)2 and 0.1 (M) Na2SO4
(b) 0.16 bar
6.
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(c) 1.16 bar (2) 0.1

(d) 3.12 bar (3) 2
11. (4) 3
An aqueous solution of hydrochloric acid - 16.
(a) obeys Raoult's law The relative lowering of vapour pressure caused by
dissolving 71.3 g of a substance in 1000 g of water is
(b) Shows negative deviations from Raoult's law
7.13 X 10-3. The molecular mass of the substance is :-
(c) Shows positive deviations from Raoult's law
(1) 180
(d) Obeys Henry's law at all compositions
(2) 18
12.
(3) 1.8
Osmotic pressure of equimolar solution of BaCl2, NaCl
(4) 360
and glucose will be in the order -
17.
(a) BaCl2 > NaCl > glucose
Total vapour pressure of mixture of 1mol 
(B) glucose > NaCI > BaCl2 A(P = 150  torr)  and 2 mol  B(P
0
= 240  torr)  is
0

A B

(C) NaCl > BaCl2 >glucose 200 torr. In this case:

(D) NaCl> glucose > BaCl2
13.
The boiling point of an azeotropic mixture of water and
ethanol is less than that of water and ethanol. The (4) none of those
mixture shows
(1) No deviation from Raoult's law
(2) Positive deviation from Raoult's law
(3) Negative deviation from Raoult's law
(4) That the solution is unsaturated
14.
20g of naphthoic acid (C11H8O2) dissolved in 50g of
benzene (Kf=1.72 K Kg mol-1) shows a depression in
freezing point of 2K. The Vant Hoff factor is?
(1) 0.5
(2) 0.1
(1) there is positive deviation from Raoult's law
(2) there is negative deviation from Raoult's law
(3) there is no deviation from Raoult's law
18.
One litre aqueous solution of sucrose (molar mass = 342
g/mol) weighing 1015 g is found to record an osmotic
pressure of 4.8 atm at 293K. What is the molarity of the
sucrose solution ? (R= 0.0821 L atm K-1 mol-1) :
(1) 0.84
(2) 0.21
(3) 0.42
(4) 0.63
19.
The Van't Haff factor of a 0.005 M aqueous solution of
KCl is 1.95. The degree of ionisation of KCl is:

(3) 2 (1) 0.95

(4) 3 (2) 0.97

15. (3) 0.94

20 g of naphthoic acid(C11H8O2) dissolved in 50 g of (4) 0.96

benzene(Kf=1.72 K Kg mol-1) shows a depression in 20.
freezing point of 2 K. The vant Hoff factor is ? K4[Fe(CN)6] is 60% ionised. Then the value of Van't
(1) 0.5 Hoff factor is

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(1) 1.6   A solution containing 10 g per dm3 of urea (molecular

(2) 2.4 mass = 60 g mol-1) is isotonic with a 5% solution of a
non-volatile solute. The molecular mass of this non-
(3) 3 volatile solute is:
(4) 3.4
(a) 250 g mol-1                (b) 300 g mol-1
21.
(c) 350 g mol-1                (d) 200 g mol-1
Which of the following is dependent on temperature?
27.
(a) Molality
(b) Molarity 1.00 g of a non-electrolyte solute (molar mass 250g mol)
(c) Mole fraction was dissolved in 51.2 g of benzene. If the freezing point
(d) Weight percentage depression constant, Kf of benzene is 5.12 K kg mol-1,
22. the freezing point of benzene will be lowered by:-

Which one is not equal to zero for an ideal solution? (a) 0.4 K
(a)ΔHmix  (b) 0.3 K
(b)ΔSmix (c) 0.5 K
(c)ΔVmix (d) 0.2 K
(d)ΔP=PObserved-PRaoult 28.

23. Consider equimolal aqueous solutions of NaHSO4 and

NaCl with ATb and Arb as their respective boiling point
Which one of the following elctrolytes has
elevations. The value of lim
ΔTb

the same value of van't Hoff's factor(i) as ΔT

′
will be :
x→0 b

that of Al2(SO4)3  (if all are 100% ionised)? 

(1) 1
(a) K2SO4
(b) K3[Fe(CN)6] (2) 1.5
(c) Al(NO3)3 (3) 3.5
(d) K4[Fe(CN)6]
(4) 3
24. 29.
Of the following 0.10 m  aqueous solutions, which one 15 g of methyl alcohol is dissolved in 35 g of water. The
will exhibit the largest freezing point depression? weight percentage of methyl alcohol in solution is
(a) KCl (1) 30%
(b) C6H12O6 (2) 50%
(c) Al2(SO4)3 (3) 70%
(d) K2SO4 (4) 75%

25. 30.

The van't Hoff factor, i for a compound which undergoes Sea water contains 5.8 × 10–3 g of dissolved oxygen per
dissociation in one solvent and association in other kilogram. The concentration of oxygen in parts per
solvent is respectively. million is
(a) less than one and less than one (1) 5.8 ppm
(b) greater than one and less than one (2) 58.5 ppm
(c) greater than one and greater than one (3) 0.58 ppm
(d) less than one and greater than one (4) 0.05 ppm
26. 31.
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Amount of NaOH present in 200 ml of 0.5 N solution is  . When a non-volatile substance B is added to this solvent
its vapour pressure drops to 0.6 atm. the mole fraction of
(1) 40 g B in the solution is [MP PMT 2000]
(2) 4 g (1) 0.25
(3) 0.4 g (2) 0.50
(4) 4.4 g (3) 0.75
32. (4) 0.90
50 ml of 10N H SO , 25ml of 12 N HCl and 40 ml of 37.
2 4

5N H N O were mixed together and the volume of the

3

mixture was made 1000 ml by adding water. The Osmotic pressure is 0.0821 atm at a temperature of 300
normality of the resulting solution will be  K. find concentration in mole/litre [Roorkee 1990]
(1) 1 N (1) 0.033
(2) 2 N (2) 0.066
(3) 3 N (3) 0.33 × 10–2
(4) 4 N (4) 3
33. 38.
Equal volumes of 0 .1 M AgNO and 0.2 M NaCl are
3 The osmotic pressure of 5% (mass-volume) solution of
mixed. The concentration of NO ions in the mixture
−

3
cane sugar at 150°C (mol. mass of sugar = 342) is [BHU
will be  1995]
(1) 0.1 M (1) 4 atm
(2) 0.05 M (2) 5.07 atm
(3) 0.2 M (3) 3.55 atm
(4) 0.15 M (4) 2.45 atm
34. 39.

Amount of oxalic acid ((COOH) . 2H O) in grams that

2 2
A solution containing 3.3 g of a substance in 125 g of
is required to obtain 250 ml of a semi-molar solution is  benzene (b.p. 80°C) boils at 80.66°C. If Kb for one litre
of benzene is 3.28°C, the molecular weight of the
(1) 17.25 g substance shall be [CPMT 1992]
(2) 17.00 g (1) 127.20
(3) 15.75 g (2) 131.20
(4) 15.00 g (3) 137.12
35. (4) 142.72
Volume of 10 M HCl should be diluted with water to 40.
prepare 2.00 L of 5 M HCl is 
The molal b.p. constant for water is 0 .513 C kg mol .
o −1

(1) 2 L When 0.1 mole of sugar is dissolved in 200 g of water,

(2) 1.5 L the solution boils under a pressure of 1 atm at [AIIMS
1991]
(3) 1.00 L
(1) 100.513°C
(4) 0.5 L
(2) 100.0513°C
36.
(3) 100.256°C
The vapour pressure of a solvent A is 0.80 atm
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(4) 101.025°C
Fill OMR Sheet
41.
What is the molality of solution of a certain solute in a
solvent if there is a freezing point depression of 0.184°
and if the freezing point constant is 18.4 
(1) 0.01
(2) 1
(3) 0.001
(4) 100
42.
The molar freezing point constant for water is
1.86°C/mole. If 342 g of cane sugar (C H O ) is12 22 11

dissolved in 1000 g of water, the solution will freeze at 

(1) –1.86°C
(2) 1.86°C
(3) –3.92°C
(4) 2.42°C
43.
The depression in freezing point of 0.01 M aqueous
solutions of urea, sodium chloride and sodium sulphate is
in the ratio of [Roorkee 1990; DCE 1994]
(1) 1 : 1 : 1
(2) 1 : 2 : 3
(3) 1 : 2 : 4
(4) 2 : 2 : 3
44.
The Van't Hoff factor for 0.1 M Ba (NO ) solution is
3 2

2.74. The degree of dissociation is [IIT 1999]

(1) 91.3%
(2) 87%
(3) 100%
(4) 74%
45.
Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water
gave a solution of density 1.15 g/mL. The molarity of the
solution is:
1. 7.78 M
2. 2.00 M
3. 2.05 M
4. 2.22 M

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