96 / srorcritoMETRi' SIiLI'-Lln AJ'jD IlS COitl;'C;UivnS '/ 97

S $dd dsd*l
G -a:rgu e = (2.92+ I .2522+w)t1 2Ol i I I /8 I ) \ tt +y' * 2S ) 4,{w I con'r,ersion of SO, to SO. = (4.0846/5 84) x 100 = 70 ANS
so. = a motes
. b) %o

\ y" /.u i
Converter Gas n
Tota-l Wt of cinder = 451.216 + 148"l4g w + g0 a SO, = 5.84 - 4.0846 t'7554'
Or'=O.ZZ = i"5(4.0846) 7'6777
SoMng simultaneously: N, = 84'44
w=0.36268a=0.25
'fu*,07,
Wt of Pfrite/1O0 moles SO, free BC
sb, = 2.2545 + 4.o846 = ###
= (2.92+1.2522+.3G268XI20) / .81 = 6Zt.S4
NRSORBEF- ANALYSIS:
SO, in BG = 2.5045 - .25 = 2.2548 . O, in waste $as = (84.44/.9123) x 'OZB2 = 7'238
O, reacling = 7.€i77V - 7.238 = 0'44
n) Complete AnaJysis of BG For tlre reactiotl: SO, + I/2 02 - SO.
88 .44 .88'
ci.s n Vo
SO, 5.84 5.71 SO, avaiiable for absorplion = 6.339i + '88 = 7'2tgt
o2 9.72 9"51
N2 84.M 82.58 lrt y = wt of 6070 H2SO4 acid charge -- ^^ formed
SO, 2.2545 2.2 y + 7 .21g i^(80) = y + 577 -528 = wi of 9Oo/a FI?-SO{
02.2545 _t
SO, Balance:
CON\DRTER ANALYSIS: (80/98) ('9)
,156/98) (.6) + 577.528 = (y + 577.528)
I.el b = moles SO, converted to SO. in converter Y = 625.655
. The reacuon. is: SO, n ,rr'fr= c) Wt of dilute 600/o acjd/ hr.= (625 655/671"834)
tO. x 1000 = 931.26 FJ'JS {
6yu,,\ o(1ro1
i$^st:)
L1i"old Ylh(
GAS n ah
l-et z = wt of 88% acid
SO, 5.84-b l.B7oto z + 577.528 = wt of l2o/o oleum
a2 9.72 - .5b
N2 84 ++ H^SO. Balance:
r i00 . 1.5b olAA ) + 577.528{98,180) = (0. 12Xz+577 .528){98 I 80)
+ 0.88(z+577.528)
1';'7 QOr,
forSo^: 584-b =org7
-l_-ttt.aJJ
-
' i00 - i.5b
o}i{tof88%acid/hI=|777895/67].834]-x1000=1]57.87ANS
b = 4.0846