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Air Based Hazards Sources of Air Pollutants
Air Based Hazards Sources of Air Pollutants
II. Transport
This is mobile and most leading source of CO. Combustion in engines is mainly fueled by
Gas, petrol, diesel, and kerosene. Jet engines of sub sonic long range air crafts are major
source of NOx, Traffic on road is considered as non-point or line source, addition to that
harbors and turbine engines of huge ships are also emits tons of greenhouse gases and toxic
particles in the air.
III. Industry
Most of the industries are directly or indirectly depend on fossil fuel, as they produce CO and
CO2, sulfur hexafluoride and particle matters. Mainly cement industry releases large amount
of particle matters in the environment. There is an array of hazardous volatile compounds that
are released from paints, electronics, dry cleansing, decreasing agents. Furthermore,
utilization of HFC, Oxides of Nitrogen, PFC and SF6 produces pollutants.
IV. Households
Carbon and soot emission during the cooking by the use of fossil fuels can be considered
here. Volatile toxicants such as Permethrine compounds of from insecticides could
contaminate in the air or even food and resulting in the intoxication.
V. Agricultural practices
Agriculture activities such as use of natural fertilizer release greenhouse gases. Pesticides
release persistent organic pollutants (POP). Enteric fermentation in cattle ranching produces
green house gases mainly methane. Toxic chemicals found in pesticide and weedicide also
reduces the quality of air inhaled.
Primary pollutants
These are gases and particles released to the atmosphere and remain in the same form
as it is from the source.
o Sulphur compounds
Flue gas desulphurization plants (FGD), coal power plant (about 0.02-
2% of emission) , furnace oil (Sulphur content is generally 2.3 per cent
by weight), paper mills, steel industry, refineries and sewage treatment
plants, petroleum refinery and vehicles engines, burning rubber,
crackers and match smoke. Naturally sources such as volcanoes,
marshes, bogs and swamps emit sulphur compounds. Found as SO2,
H2S, CS2, COS, Methyl mercaptan, Dimethyl sulphur, and Dimethyl
disulphide.
o Nitrogen compounds
Major source is combustion such as get engines, NH 3 come from
fertilizers, livestock & poultry wastes, and vegetation, burning of
biomass and ocean spray, energy production, petroleum refinery, forest
fire, volcanic activity, bacterial breakdown of organic nitrates. It
promotes acidification. NO2 favours photochemical smoke and reduce
visibility. 77% of combustion gas of coal consist oxides of Nitrogen. In
high concentration causes pulmonary edema, airway injury, impaired
lung defenses, dissolved atmospheric NOx as in acid rain destroys fish
and plant life and N2O is a greenhouse gas causes global warming.
o Carbon monoxide
Mainly from automobiles and during the combustion of fossil fuel, gas,
charcoal and wood, naturally from forest fires and volcanoes causes
difficulty in breathing as it compete with oxygen by forming
carboxyhemoglobin, Asphyxia, damage to heart and nervous system.
o Carbon dioxide
CO2 is considered as an air pollutant as it defined by the clean air act.
And it is a greenhouse gas increasing levels of CO 2 causing global
warming. CO2 emission is available from all kind of combustion both
natural and manmade.
o Ground level Ozone
Auto mobile emission, air craft cabins, Ozone generators
o Polycyclic aromatic hydrocarbon
Which are released from cigarette smoke and stove smoke, can cause
lung cancer.
o Radon
Released naturally from volcanic eruption, it is a radioactive material
ionizes biological molecules, causes cell disruption and causing lung
cancer.
o Asbestos
Asbestos fiber dust released from building material, mines, mills and
insulations causes Mesothelioma, lung cancer, Asbestosis.
o Arsenic
Found in copper smelters and cigarette smoke causing in lung cancer.
o Allergens
House dust, Pollen, animal dander causes Asthma and rhinitis.
o Particle matter SPM, PM10, PM2.5
Suspended particles are formed in every type of combustion and
originated from various sources; PM 2.5 can even reach the blood
circulation via the respiratory tract.
o HCl
Released naturally from volcanic activities, causes eye irritation and
damages mucus membrane and affects respiratory system.
o Dioxin
Dioxin is a toxic gas produced from burning of electronic wastes and
plastic materials; it could cause cancer and affect the immune system
and leads to developmental reproductive disorders.
o Furans
Furans are released during the burning of plastic products such as
nylon, containing various harmful compounds.
o Mercury
Gold refinery is the major source of Mercury and it is a known
carcinogen
o Lead
Lead particle found in petrol smoke and cause health issues such as
affects respiratory system, blood and kidneys also cause dyslexia and
hyperactivity in children, however currently it is completely banned
from fuel as use of lead free gasoline. Burning of lead containing
electronic wastes causes the adverse effect to the atmosphere.
o Compounds of Cadmium, Antimony, Arsenic, Zinc and Copper.
These metallic elements often toxic and irritating smoke causes
adverse health effects, generally found in pesticides and fumes and gas
emission during the burning of plastic and electronic wastes.
o Volatile organic compounds (VOCs)
VOCs are xylene, ethyl benzene and tri-methyl benzene compounds
commonly found in Air freshener, air cleaners (with ozone), cleaning
and disinfecting chemicals, cosmetics, gasoline, fuel oil, moth balls
and vehicle exhaust. There is an array of compounds listed in this
category such as Acetone, Benzene, Ethyl glycol, Formaldehyde,
Methylene chloride, Perchloro ethylene, Toluene, Xylene, 1, 3-
butadiene.
o Persistent Organic Pollutants (POPs)
Main sources are industrial products such as Poly chlorinated biphenyl
(PCB), pesticides such as DDT, industrial by products and burning of
waste products such as dioxins and furans.
Secondary pollutants
Ground level Ozone
o It is the major component of Fog and it is produced by the photochemical
reaction between NOx and Volatile Organic Compounds. Causes breathing
difficulty and aggravates the lung diseases such as Emphysema and chronic
bronchitis.
Peroxyacetylnitrate (PAN)
o PAN is formed due to photochemical reaction of NO x with hydrocarbons in the
sunlight, it is a component of photochemical smog, smog is a mixture of air
pollutants such as gases and particles react with sun light. PAN often causes
irritation to eye and together with Ozone it lowers the lung capacity and
increases breathing rate.
CFC
o CFC formed by chemical reaction of fog in the atmosphere during volcanic
activity, causes depletion of Ozone layer. Used as propellant in sprays,
deodorants and repellants, this is now completely banned.
Halons
o Brominated organic compounds used as fire retardant which is also an Ozone
depleting compound.
H2SO4
o Sulpuric acid formed due to the reaction of oxides of Sulphur with
atmospheric water vapour, causes acid rain and respiratory problems.
Industrial Air Pollutants
o Major sources are Thermal Power Plants, Boilers, Thermic Fluid Heaters,
Incinerators, Cupola, blast furnace, Coke oven, Basic Oxygen Furnace,
Induction and air Furnace and Cement kilns.
1. Identify all potential hazards and accidental events that may lead to an accident
2. Rank the identified accidental events according to their severity
3. Identify required hazard controls and follow-up actions
Several variants of PHA are used, and sometimes under different names like
Whether or not a PHA will be a sufficient analysis depends both on the complexity of the
system and the objectives of the analysis.
PHA scope
The PHA shall consider:
Hazardous components
Safety related interfaces between various system elements, including software
Environmental constraints including operating environments
Operating, test, maintenance, built-in-tests, diagnostics, and emergency procedures
Facilities, real property installed equipment, support equipment, and training
Safety related equipment, safeguards, and possible alternate approaches
Malfunctions to the system, subsystems, or software
I. PHA prerequisites
PHA team
A typical PHA team may consist of:
A team leader (facilitator) with competence and experience in the method to be used
A secretary who will report the results
Team members (2-6 persons) who can provide necessary knowledge and experience
on the system being analyzed
How many team members who should participate will depend on the complexity of the
system and also of the objectives of the analysis. Some team members may participate only in
parts of the analysis.
System functions
As part of the system familiarization it is important to consider:
System breakdown
To be able to identify all hazards and events, it is often necessary to split the system into
manageable parts, for example, into three categories
System parts (e.g., process units)
Activities
Exposed to risk (who, what are exposed?)
Selection of PHA worksheet
The results of the PHA are usually reported by using a PHA worksheet (or, a computer
program). A typical PHA worksheet is shown below. Some analyses may require other
columns, but these are the most common.
Hazard checklist
To get a complete survey of all possible hazards it may be beneficial to use a hazard
checklist.
Common sources of hazards are:
Sources and propagation paths of stored energy in electrical, chemical, or mechanical
form
Mechanical moving parts
Material or system incompatibilities
Nuclear radiation
Electromagnetic radiation (including infra-red, ultra-violet, laser, radar, and radio
frequencies)
Collisions and subsequent problems of survival and escape
Fire and explosion
Toxic and corrosive liquids and gases escaping from containers or being generated as
a result of other incidents
Deterioration in long-term storage
Noise including sub-sonic and supersonic vibrations
Biological hazards, including bacterial growth in such places as fuel tanks
Human error in operating, handling, or moving near equipment of the system
Software error that can cause accidents
The risk related to an accidental event is a function of the frequency of the event and
the severity of its potential consequences.
To determine the risk, we have to estimate the frequency and the severity of each
accidental event.
Severity classes
The severity of an event may be classified into rather broad classes. An example of such a
classification is:
Frequency estimation
Frequency classes
The frequency of events may be classified into rather broad classes. An example of such a
classification is:
Generally requires additional follow-up analyses. Because the PrHA is conducted early in
the process and uses preliminary design information, additional analyses are generally
required to more fully understand and evaluate hazards and potential accidents identified by
the PrHA team.
Quality of the results is highly dependent on the knowledge of the team. At the time of a
PrHA, there are few or no fully developed system specifications and little or no detailed
design information. Therefore, the risk assessment relies heavily on the knowledge of subject
matter experts. If these experts do not participate in the risk assessment, or if the system is a
new technology having little or no early operational history, the results of the PrHA will
reflect the uncertainty of the team in many of its assessments and assumptions.
Heat
Heat acts as the source of ignition and anything that gives off heat can start a fire.
It is important to be aware that the source of heat can not only be equipment and activities
which, by design, involve the production of heat, but may also include a variety of other
circumstances with which heat may not be expected at all. Range of equipment which
generate heat when in proper use, e.g. welding torches, blow-lamps, soldering irons, space
heaters, hot plates, ovens, electric fires, light bulbs and electric irons.
Fuel
The fuel for a fire does not have to be a recognized fuel in the sense of petrol or gas. It may
be any combustible material. Carbon or hydrocarbon based materials will burn readily at the
sort of temperatures often generated in a workplace or domestic environment. They include
solids such as paper and wood, and gases such as petrol vapour, natural (town) gas or propane
(bottled gas). However, other materials may also combust at relatively low temperatures.
The type of fuel is also important because different substances behave in different ways when
they burn, e.g. the amount of flames or smoke they give off may depend upon the
circumstances (temperature and air conditions) and because the means of extinguishing the
fire may vary.
Oxygen
The oxygen essential for combustion is usually supplied from the surrounding air. However,
the naturally present oxygen may be enhanced by the presence of other sources of oxygen
such as compressed air, the pure oxygen in gas cylinders used for welding, or by the
combustion of peroxides, nitrates, and similar chemicals. (These chemicals give off oxygen
as they burn, further aiding their own combustion. They are sometimes known as oxidising
agents.)
Classification of Fires
Fires are classified into five categories according to the fuel type.
Class A
These are fires involving solid materials, normally of an organic nature, such as paper, wood,
coal and natural fibres. These fires usually produce burning embers.
Class B
These are fires involving flammable liquids or liquefied solids, such as petrol, oil, grease, fats
and paint.
Class C
These are fires involving gases or liquefied gases, such as methane, propane, and mains gas.
Class D
These are fires where the fuel is a metal such as aluminium, sodium, potassium or
magnesium.
Class F
These are fires fuelled by cooking fats, as in the case of deep fat frying.
Convection currents created in the air by fire are a major means of fire spread. They may
carry burning materials through the air and into contact with other combustible materials and
also, depending upon the intensity of the fire and the heat generated, create strong localised
winds which may fan the flames and cause flare ups.
Conduction
Convection Currents
Heat may be transmitted through certain materials, known as conductors, without those
materials themselves actually burning. This is particularly the case with metals. The heat
generated by a fire (or any other process producing heat) may therefore be transferred to a
separate location where it can act as a source of ignition.
This has important implications for many steel frame buildings which feature widespread use
of metal within the structure of the building (e.g. steel girders) and the services which run
through it, such as pipes and various types of ducting.
Radiation
Radiation is the general term for the process by which energy is lost from a source without
direct contact. Heat radiation refers to the process whereby the heat given off by hot objects
passes through air and through certain types of transparent material such as glass. This
radiant heat can in itself be sufficient to act as a source of ignition.
For example, radiators are an obvious source of heat and clothes which are left to dry too
close to them may catch fire. Similarly, light bulbs give out heat (and in the case of certain
types of spot lights, a large amount of heat) and any fabrics or flammable materials which are
too close may start to burn.
The intensity of radiant heat diminishes with the distance from its source. However,
depending on the temperature of the source, heat transfer may take place over quite large
distances. For example, a fire burning on one side of a street may be sufficient to cause
materials on the other side of the street to ignite.
Direct Burning
This occurs where heat is transferred directly by contact from one substance to another. If a
piece of paper catches alight then the heat (in the form of flames) can spread to the next piece
of paper and then to the next until a whole area is on fire. Similarly, oil based paint on walls
can spread fire, as can a pool or trail of flammable liquid.
Note that direct burning can take place across a gap where the wind conditions allow for
flames to be fanned and thereby come into contact with other separate combustible materials.
This fanning may be the result of simply opening a window or door, allowing more air into
an enclosed space. Note, too, that localised winds are created by convection.