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Scratch Testing of Metals and Polymers
Scratch Testing of Metals and Polymers
Scratch Testing of Metals and Polymers
Wear
journal homepage: www.elsevier.com/locate/wear
a r t i c l e i n f o a b s t r a c t
Article history: An experimental and numerical study of the scratch test performed on metals and polymers was con-
Received 28 September 2007 ducted. The materials tested, being both metallic and polymeric, were related to the well known Johnson’s
Received in revised form 28 April 2008 parameter, often used to correlate indentation experiments. The aim was to determine whether it was
Accepted 27 May 2008
possible to use the numerical approach presented by Wredenberg and Larsson [F. Wredenberg, P.-L.
Available online 21 July 2008
Larsson, On the numerics and correlation of scratch testing, Journal of Mechanics of Materials and Struc-
tures 2 (2006) 573–594] to describe the scratch mechanism and of course also to investigate whether
Keywords:
or not important scratch quantities can be determined with sufficient accuracy from standard scratch
Scratch test experiments
Finite element analysis
experiments.
Contact © 2008 Elsevier B.V. All rights reserved.
Metals
Polymers
1. Introduction been gained over the years regarding the mechanical behaviour
at indentation. Sharp indenters are most often used, for practical
The understanding of the mechanical behaviour of scratch- reasons, at least when modern experimental devices such as the
ing is not as developed as that for indentation testing, although nanoindenter (or other types of instrumented indentation devices)
early mechanical analyses concerning different aspects of scratch- are at issue. For such indenters semi-empirical relations for mate-
ing exist and are presented by, for example, Goddard and Wilman rial characterisation were derived and used already in the late 1940s
[2], Childs [3], Vathaire et al. [4] and Gilormini and Felder [5]. and early 1950s, in particular for metals and alloys, cf., e.g. Tabor [7].
It is possible to distinguish between two main different types of In short, from comprehensive experimental investigations Tabor [7]
mechanism at scratching. The first one, which here is termed mild derived a relation
scratching, is when the behaviour does not involve or is not sig-
H = Crepr , (1)
nificantly influenced by any interface properties. If the material is
sufficiently tough the scratch deformation will be governed by the between the indentation hardness H, here defined as the mean con-
bulk constitutive properties, typically plastic for metallic materi- tact pressure at indentation and scratching, and the material yield
als or non-linearly viscoelastic for polymers. In this context, tough stress repr at a representative value on the accumulated (effective)
meaning without chipping, spalling or delaminating. The second plastic strain, repr . Furthermore in Eq. (1), C is a constant that only
type, termed s evere scratching, occurs if the material toughness is depends on the geometry of the indenter. For a Vickers indenter
sufficiently low and the formation of cracks takes place. Alterna- Tabor [7] determines the values C ≈ 3 and repr ≈ 8% while Atkins
tively, when scratching of coatings is at issue, delamination occurs. and Tabor [8] find C ≈ 2.54 and repr ≈ 11% for a conical indenter
It appears likely, at least if no cracks develop, that the scratch pro- with an angle of ˇ = 22◦ (similar to the Vickers indenter) between
cess is very similar to conventional indentation testing and that the indenter and the undeformed surface (see Fig. 1). These results
thus the scratch process can be well described by conventional for sharp indenters have lately been validated and further improved
material properties. In fact, scratch tests have been used to measure (and also extended to other types of constitutive behaviour) using
elastic and plastic properties [6]. finite element simulations, cf., e.g. [9–12].
Indentation testing and scratch testing show many similar fea- Based partly on the above discussed results, further progress is
tures. When it comes to indentation a great deal of knowledge has achieved by Johnson [13,14], who shows from theoretical consid-
erations that indentation testing on different materials can be well
correlated by using a parameter,
∗ Corresponding author. Tel.: +46 8 790 60 00; fax: +46 8 411 24 18.
E tan ˇ
= , (2)
E-mail address: pelle@hallf.kth.se (P.-L. Larsson). (1 − 2 )repr
0043-1648/$ – see front matter © 2008 Elsevier B.V. All rights reserved.
doi:10.1016/j.wear.2008.05.014
F. Wredenberg, P.-L. Larsson / Wear 266 (2009) 76–83 77
2. Background
Cartesian coordinates) as shown in Fig. 4 and material properties, enabled the measurement of the residual scratch depth, which
alone. √ could later be related to the contact area.
In this context, A should be interpreted as a representative
contact length and the indices norm and tan represent the nor- 3.2. Specimens
mal and tangential components of the scratch quantities. The fact
that the normal and tangential scratch hardness are constant dur- The experiments were performed on two aluminium alloys,
ing a cone scratch test, is valid at classical elastoplastic material three polymers and one stainless steel. These materials were cho-
behaviour, as assumed here, but fails at for example strain gradient sen in order to achieve a reasonable spread in Johnson’s parameter
material behaviour as then a characteristic length is present in the and in strain hardening. The material properties were deter-
constitutive equation, cf., e.g. Fleck and Hutchinson [21]. mined by uniaxial tensile tests, alternatively by compression for
Epoxy and PMMA (see Table 1). For these materials the results for
3. Experimental analysis the compression test rather than for the uniaxial tensile test was
used since then it was possible to reach higher strain levels without
In conjunction with the scratch experiments uniaxial tensile fracture. Also polymers have a tendency for higher yield stresses in
tests were performed in order to characterise the scratched speci- compression than in tension and since the material predominantly
men materials. Also purely frictional measurements were made to undergoes compression during the scratch test the compression
determine the diamond–specimen coefficient of friction. All exper- test was considered suitable. To extract the plastic material param-
iments were performed at room temperature. eters from the compression test an inverse analysis was performed
using ABAQUS and MATLAB where the materials were assumed to
be elastic perfectly plastic as indicated by the compression tests.
3.1. The scratch setup
The polymeric materials in Table 1 were to some limited extent
rate dependent. Thus the yield stress and consequently , would
Scratching experiments were performed by dragging a conical
depend on the rate of which the specimens were loaded. The speci-
diamond (with the angle ˇ = 22◦ ) over the surface of a specimen,
mens were therefore loaded slowly in a quasi static manner, similar
using a MTS 66202A-01 bi-axial servo-hydraulic machine with an
to the situation at scratching. During scratching at different veloc-
Instron 8500 control unit. The normal forces were measured with
ities no significant difference in the results were found and this
a MTS load cell and the tangential forces were measured by a load
matter was therefore not dwelled upon further.
cell built in-house. During the test normal and tangential forces
were recorded and steady-state conditions were ensured. The rota-
tional motion of the actuator was transformed to a translational 3.3. Indentation
motion by a carriage sliding on a rail (see Fig. 3). During scratch-
ing the normal load was held constant to allow for the stylus to In order to be able to correlate the scratch quantities to
follow the contours of the specimen. All specimens were scratched the indentation counterparts, indentation experiments were per-
with a speed of 0.4 mm/s and 0.9 mm/s and in some cases with a formed on the scratch specimens. The same conical indenter as
higher speed of 1.8 mm/s. No significant difference in global scratch for scratching was used also for indentation and was pressed into
parameters between the different scratch speeds could however be the specimens by a servo hydraulic MTS machine. The residual
detected. The normal load was held at constant at 250 N or 500 N indent (1–2 mm in diameter) was measured using an optical micro-
for the polymers while the metallic specimens were scratched with scope and the normally projected contact area was calculated. The
a normal load of 500 N, 1 kN or 1.5 kN. indentation experiments on the polymers were performed with a
After the specimen was scratched the residual groove was mea- maximum load of 500 N and with a hold time of 5 s. The on and off
sured both using an optical microscope and a profilometer (Form loading was virtually instantaneous. For the metallic materials, the
Talysurf Mk1) with a stylus radius of 0.2 m. The profilometer maximum load was varied between 1.0 kN and 3.5 kN.
3.4. Friction
Table 1
Material properties determined by uniaxial/compression testing
Table 2 integrity. The mesh was composed of some 30,000 eight node linear
Results from frictional measurements (standard deviation)
elements and is shown in Fig. 4. These elements were chosen since
Material i they show a faster convergence with respect to mesh refinement
Vinyl ester 0.14 (21 × 10−3 )
than tetrahedral elements and do not have the inherent contact
PMMA 0.33 (35 × 10−3 ) problems of quadratic elements [23]. The stylus was assumed
Epoxy 0.11 (33 × 10−3 ) to be perfectly rigid and Coulomb friction was assumed when
Al 7050 0.09 (9 × 10−3 ) appropriate.
Al SS 4120 0.14 (40 × 10−3 )
As regards boundary conditions, the surface outside the con-
Stainless steel SS 2333 0.08 (9 × 10−3 )
tact area was assumed traction free and within the area of contact
At least four experiments were performed for each material.
unilateral kinematic constraints, given by the shape of the conical
indenter/stylus depicted in Fig. 1, had to be accounted for.
frictional measurements were limited to one sliding speed. The nor-
mal load was also varied between the different measurements in 5. Results and discussion
order to investigate its effect on the friction. The polymer specimens
were washed with a mild detergent and the metallic with 2- Below, experimental and numerical results are presented, eval-
propanol (as was the stylus) to remove any grease from the surfaces. uated and compared in relation to different important features of
The results from the frictional measurements are shown in Table 2. substantial interest at scratching. In all subsequent figures when
nondimensionalised parameters are introduced, a representative
4. Numerical analysis stress, repr , was used, being the stress at a representative level
of plastic strain (repr = 35%) at scratching found by Wreden-
In order to verify the model developed by Wredenberg and Lars- berg and Larsson [1] in their numerical analysis of the problem.
son [1] each scratch experiment was numerically simulated using The level of the representative strain is not of fundamental
finite element methods implemented in the commercial FEM pack- importance in the present analysis as repr is only used for
age ABAQUS [23]. a qualitative classification of the materials mainly through the
As for details of the numerical analysis (including validation of parameter , Eq. (2). Cracking of the material was in generally not
the procedure) we refer to Wredenberg and Larsson [1] and here observed at scratching of metals and polymers. However epoxy,
it should just be mentioned that regarding the constitutive specifi- occasionally showed crazing at the very bottom of the residual
cation the incremental, rate independent Prandtl–Reuss equations groove.
for classical large deformation von Mises plasticity with isotropic In Figs. 7–13 the error bars indicate the standard deviation. All of
hardening according to the presented results are pertinent to a perfectly sharp conical sty-
lus. In order to ensure a relevant comparison between experimental
(p ) = Y + 0 np , (6) and numerical results, experimental scratch depths were chosen in
were implemented. In Eq. (6), (p ) is the flow stress, Y the ini- such a way that any influence from the stylus tip defect was neg-
tial yield stress, p the effective plastic strain and n the hardening ligible (as investigated carefully in each case through numerical
exponent. At elastic loading, or unloading, a hypoelastic formu- simulations).
lation of Hooke’s law, pertinent to the first elastic part of the
Prandtl–Reuss equations, was relied upon. Obviously, within the 5.1. Contact area
present setting, kinematic hardening effects were not included
in the analysis. Such effects could certainly have influenced the When the scratch hardness is to be determined, it is in gen-
outcome of scratch test but would also have increased the num- eral easy to acquire the load, the contact area however is more
ber of required numerical computations substantially (due to an challenging. Unlike normal indentation where the contact area is
increased number of constitutive parameters) and would have relatively accurately estimated from the residual indent, cf., e.g.
made a straightforward interpretation of the results more diffi- Tabor [7], the scratch contact area can only be roughly estimated
cult. For this reason, it was thought advisable, as a first attempt, to by the residual groove and requires assumptions about the con-
restrict the analysis to classical von Mises plasticity with isotropic tact area shape to be made. Below, the contact was assumed only
hardening. In particular so, as mainly the loading part of the scratch to occur on the front face of the indenter. Also the elastic effects
test was of primary interest here. As the material experienced very were assumed to be small, i.e. the contact width was the same as
large strains, adaptive meshing was used to maintain the element the residual groove width. The latter assumption is again based on
corresponding indentation results by Tabor [7].
As the real normal contact area was not easily measurable it was
(when not stated otherwise) approximated using
w 2
Anorm = , (7)
2 2
ing this matter are presented in Fig. 5 and in many of the following
figures and tables.
Fig. 6. Contact area at scratching of Al 4120 (simulated). Interfacial friction i = Fig. 7. Experimental results for ploughing friction. Numerically simulated results
0.18. The scratch direction is indicated by the arrow. are also shown.
F. Wredenberg, P.-L. Larsson / Wear 266 (2009) 76–83 81
Fig. 8. Scratch normal hardness divided by the representative stress repr . Plotted Fig. 10. Scratch tangential hardness divided by the representative stress repr . Plot-
against Johnson’s parameter . Experimental results. ted against Johnson’s parameter . Experimental results.
Fig. 9. Scratch normal hardness with adjusted contact area. Plotted against John- Fig. 12. Scratch normal hardness divided by tangential scratch hardness, plotted
son’s parameter . Experimental and numerical results. against Johnson’s parameter . Experimental and numerical results.
82 F. Wredenberg, P.-L. Larsson / Wear 266 (2009) 76–83
Fig. 13. Scratch normal hardness divided by indentation hardness, plotted against
Johnson’s parameter . Experimental results.
Table 3 Fig. 14. Typical cross section of the remaining groove (simulated). The groove width
Scratch quantities at simulated scratching w is indicated.
mechanical behaviour at scratching. This is particularly so for [8] A.G. Atkins, D. Tabor, Plastic indentation in metals with cones, Journal of The
polymeric materials where, for example, the standard assump- Mechanics and Physics of Solids 13 (1965) 149–164.
[9] A.E. Giannakopoulos, P.-L. Larsson, R. Vestergaard, Analysis of vickers indenta-
tion of a contact area restricted to only the front of the stylus tion, International Journal of Solids and Structures 31 (1994) 2679–2708.
leads to inaccurate results. [10] P.-L. Larsson, A.E. Giannakopoulos, E. Söderlund, D.J. Rowcliffe, R. Vestergaard,
• The numerical approach presented previously by Wredenberg Analysis of berkovich indentation, International Journal of Solids and Structures
33 (1996) 221–248.
and Larsson [1] is a reliable tool for investigating scratching in [11] A.E. Giannakopoulos, P.-L. Larsson, Analysis of pyramid indentation of pressure-
a detailed manner. However the present study also shows that an sensitive hard metals and ceramics, Mechanics of Materials 25 (1997) 1–35.
accurate characterisation of the frictional behaviour at scratching [12] P.-L. Larsson, A.E. Giannakopoulos, Tensile stresses and their implication to
cracking at pyramid indentation of pressure-sensitive hard metals and ceram-
is essential at interpretation of many relevant scratch quantities. ics, Materials Science and Engineering A 254 (1998) 268–281.
[13] K.L. Johnson, The correlation of indentation experiments, Journal of The
Acknowledgements Mechanics and Physics of Solids 18 (1970) 115–126.
[14] K.L. Johnson, Contact Mechanics, Cambridge University Press, UK, 1985.
[15] X.-L. Gao, X.N. Jing, G. Subhash, Two new expanding cavity models for indenta-
The authors want to acknowledge the support through grant tion deformations of elastic strain-hardening materials, International Journal
621-2005-5803 from the Swedish Research Council. The authors of Solids and Structures 43 (2005) 2193–2208.
[16] J.L. Bucaille, E. Felder, G. Hochstetter, Mechanical analysis of the scratch test on
also wish to thank Professor Fred Nilsson for providing valuable
elastic and perfectly plastic materials with three-dimensional finite element
advice and discussions, and for reading and commenting on the modeling, Wear 249 (2001) 422–432.
manuscript, Professor Anders Hult and Professor Mats Johansson [17] B.J. Briscoe, P.D. Evans, S.K. Biswas, S.K. Sinha, The hardness of poly
for their help in choosing and acquiring polymer materials, Mr. (methylmethacrylate), Tribology International 29 (1996) 93–104.
[18] C. Gauthier, S. Lafaye, R. Schirrer, Elastic recovery of a scratch in a polymeric
Hans Öberg for his help and advise in the laboratory and Messrs. surface: experiments and analysis, Tribology International 34 (2001) 469–479.
Bertil Dolk and Kurt Lindqvist for manufacturing specimens and [19] J.L. Bucaille, E. Felder, G. Hochstetter, Experimental and three-dimensional
experimental equipment. finite element study of scratch test of polymers at large deformations, Journal
of Tribology 126 (2004) 372–379.
[20] E. Felder, J.-L. Bucaille, Mechanical analysis of the scratching of metals and
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