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Unit 11 Packet PDF
Unit 11 Packet PDF
Unit 11 Packet PDF
1. SELF-IONIZATION OF WATER
a) Water molecules collide, causing a very small number to ionize in a reversible reaction:
H2O(l) + H2O(l) ↔ H3O+(aq) + OH-(aq)
water molecules hydronium ion hydroxide ion
b) The hydronium ion (H3O+) consists of a water molecule attached to a hydrogen ion
(H+) by a covalent bond; thus, H3O+ and H+ can be used interchangeably in a chemical
equation to represent a hydrogen ion in aqueous solution.
Simplified equation for self-ionization of water:
H2O(l) ↔ H+(aq) + OH-(aq)
c) Water is considered neutral since it produces equal numbers of H+ and OH- ions.
Hydrogen ion concentration, shown as [H+], for water = 1.0 x 10-7M
Hydroxide ion concentration, shown as [OH-], for water = 1.0 x 10-7M
Self-ionization produces a tiny number of ions but explains how pure water can behave
as a very weak electrolyte.
d) Water is the usual solvent for acids and bases; the dissociation of acids or bases in an
aqueous solution increases either the [H+] or [OH-], resulting in an aqueous solution
that is no longer neutral.
7. NEUTRALIZATION REACTIONS
a) A neutralization reaction is a reaction in which an acid and a base react in aqueous
solution to produce a salt and water.
Acid + Base → Salt + Water
b) It is a double replacement reaction where the H+ ion in the acid replaces the metal
cation in the base (forming H2O) and the metal cation of the base replaces the H+ ion in
the acid (forming an ionic salt).
Examples:
HNO3 + KOH → KNO3 + H2O
nitric acid potassium hydroxide potassium nitrate water
2HCl + Mg(OH)2 → MgCl2 + 2H2O
hydrochloric acid magnesium hydroxide magnesium chloride water
H2SO4 + 2NaOH → Na2SO4 + 2H2O
sulfuric acid sodium hydroxide sodium sulfate water