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Refractory Material Selection For Steelmaking: Emerging Ceramics & Glass Technology
Refractory Material Selection For Steelmaking: Emerging Ceramics & Glass Technology
Refractory
Material Selection
for Steelmaking
NSF awards in Ceramics Program •
Students plan advancement opportunities •
EMA, ICACC 2016 recaps •
Ceramic Leadership Summit, Ceramics Expo •
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Overview of Global Economy and Supply Chain Business Acquisition Strategy – David Gunderson,
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feature articles
Refractory Material Selection for Steelmaking . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Tom Vert
Excerpt selections by Eileen De Guire
Selecting refractories for steelmaking operations requires detailed analysis of service environ-
ments, knowledge of refractory products and steelmaking operations, and a systematic methodol-
ogy.
meetings
EMA 2016 recap and highlights . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
ICACC’16 recap and highlights . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
5th Ceramic Leadership Summit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Ceramics Expo 2016 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Glass and Optical Materials Division Annual Meeting . . . . . . . . . . . . . . . . . . . 39
Materials Challenges in Alternative and Renewable Energy . . . . . . . . . . . . . . 40 feature
Innovations in Biomedical Materials and Technologies . . . . . . . . . . . . . . . . . . . 41 National Science Foundation awards
in the Ceramics Program
columns Credit: Boise State University
– page 30
Deciphering the discipline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
Theresa Davey
Expanding my ceramic networks to reach around the world
resources departments
News & Trends . . . . . . . . . . . . . 4
New Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 ACerS Spotlight . . . . . . . . . . . . . 8
Calendar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43
Classified Advertising . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Ceramics in Biomedicine . . . . . . 13
Display Advertising Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Advances in Nanomaterials. . . . 14
Ceramics in Energy. . . . . . . . . . . 15
Research Briefs . . . . . . . . . . . . . . 18
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Martin Harmer, Director 2015–2018 bit.ly/1RWa5uK
Edgar Lara-Curzio, Director 2013–2016
Hua-Tay (H.T.) Lin, Director 2014–2017 Better, lighter, stronger
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ACSBA7, Vol. 95, No. 2, pp 1–48. All feature articles are covered in Current Contents.
CARBOLITE GERO -
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The sophisticated designs are employed for specimens requiring treat- Elemental Analyzers
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industry, metal powder injection molding, tempering of sapphires, heat for C, H, N, O, S
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Credit: Tethon 3D
window, and rear engine cover made
optimize additive manufactur-
with Gorilla Glass. According to a
ing of ceramics.
Corning press release, this will save
“There has never been a An object 3-D printed with Tethon 3D’s new com- more than 12 pounds of vehicle weight,
powder-based 3-D printer pression-enhanced printer. The object was designed
while nonetheless providing a wind-
designed specifically for ceram- as a sphere, so adjustments are needed to achieve
the desired shape and size. shield five times stronger than standard
ics before now,” says Karen
window glass.
Linder, cofounder, president, pression is the key to making a strong
The GT windshield has three lay-
and CEO of Tethon 3D, in an email. product. “The act of compression is
ers, the interior of which is a specially
“Tethon 3D developed Tethonite essential for producing strong por-
designed automotive version of Gorilla
ceramic powder for 3-D printing and celain, stoneware, and earthenware
Glass. The exterior layer is annealed
released it in 2014 to solve some of the 3-D-printed objects, and this printer
soda-lime glass, with a noise-absorbing
problems encountered when 3-D print- design could possibly also improve the
thermoplastic interlayer in between.
ing ceramics. The new printer design production of objects printed in other
“The result is a windshield and rear
that we filed the patent for is the next powder materials,” Linder says in a
engine cover approximately 32% lighter
step in improving the ceramics 3-D PRweb news release.
than competitive vehicles,” according to
printing industry.” Tethon 3D continues to process
a Ford press release. “During develop-
Tethon 3D’s new printer design strength tests for the new 3-D-printed
ment, we tried different glass variations
incorporates compression into the addi- ceramics, but Linder says in the email
before we found a combination that pro-
tive-manufacturing process. The com- that “early results are good.”
vided both weight savings and the dura-
pany recently built a prototype design “Additional printing time is required
bility needed for exterior automotive
that “utilizes the compression plate to for the compression sequencing, so we
glass,” Paul Linden, Ford body exteriors
apply mechanical pressure to the entire shortened other processing steps to
engineer, continues in the release. “We
build bed in repetitive motions at pre- ultimately condense the overall length
learned, somewhat counterintuitively,
determined intervals,” Linder says in of time to create a ceramic 3-D printed
that the strengthened interior layer of
the email. “The result is a ceramic 3-D object while improving its quality,”
the windshield is key to the success of
printed object that is stronger and more Linder adds.
the hybrid window.”
dense than was previously possible.” After successful testing with the
The Gorilla Glass hybrid windshield
Akin to traditional ceramics, com- prototype printer, the company is now
is just 3–4 millimeters thick—compared
attempting to patent the design and
to the 4–6 millimeters thickness of tradi-
is evaluating business development
tional laminate—making it 25–50% thin-
partners for engineering and manufac-
ner and approximately 30% lighter than
turing of the new 3-D printer design,
traditional glass, according to a Ford
Linder says.
press release.
Although the timeline will depend
“Plus, the glass is more robust due
on several factors, she adds that com-
to advanced processes for contami-
mercialization of the new 3-D printer
nant reduction, chemical strengthen-
could happen as soon as 12 months. n
Tethon 3D’s logo. ing, unique edge treatment, and lami-
Credit: Ford
the center of gravity and will have a posi- engine cover.
tive impact on acceleration, fuel econo-
my, and braking performance, according “This collaboration demonstrates Wendell P. Weeks, Corning chairman
to Ford. what Corning does best—applying our and CEO, says in the Ford release.
According to the auto giant, Ford expertise in glass and materials science Although Gorilla glass—stronger,
approached Corning to develop auto- to help industry leaders solve tough chal- thinner, lighter, better—seems like a no-
motive applications of Gorilla Glass in lenges, unleash new capabilities, and brainer for auto applications, it does not
response to vehicle lightweighting efforts. enhance experiences for customers,” come cheap. According to the Associated
www.mo-sci.com • 573.364.2338
ISO 9001:2008 • AS9100C
St. Louis Section/RCD 52nd Annual
Symposium: St. Louis Section/RCD 52nd Annual
The new Dilatometer
Schedule at-a-glance Symposium: March 30–31 DIL 402 Expedis
ACerS St. Louis Section and the with revolutionary
March 29, 2016
5 p.m. Kickoff event – St. Louis Blues hockey
Refractory Ceramics Division (RCD) NanoEye measuring cell
Game will hold their 52nd annual symposium
March 30–31. “Refractories for the
March 30, 2016 t the
ferrous industry: A historical perspec- abou :
7:15 a.m. Registration and coffee ou t more chnology
Find noEye te 2285
6
8 a.m. Welcome and introductions tive, present, and future directions” N a
new etzsch.co
m /n
St. Louis Section Chairman www
.n
Roger Smith, Imrie-Gielow Inc.
is the theme for this year’s meeting at
Refractory Ceramics Division Chair the Hilton St. Louis Airport Hotel in
Ben Markel, Resco Products St. Louis, Mo. A kickoff event will be
Co-Program Coordinators
Simon Leiderman, U.S. Steel Research and held at the St. Louis Blues hockey game
Technology March 29.
Bill Davis, Harbison-Walker
8:15 a.m. Morning technical sessions Organizers for the event include
• Overview of blast furnace hearth Simon Leiderman of U.S. Steel
construction
• Evolution of anhydrous taphole clay in
Research and Technology and Bill Davis
NAFTA – 1970s to present
• Use of metals in refractories
of Harbison-Walker. Register by March
25 to receive the discounted rate.
Every
DIL 402 Expedis Supreme
Nanometer
• Changes in North American blast furnace
operations and their effect on casthouse A discounted block of rooms ($107
refractory practice – 1970s to present per single/double per night) has been
• Trends in clean steel technology and
reserved at the Hilton. When booking
refractory engineering
• Raw materials used in tundish linings and your accommodations, refer to Group counts
their effect on performance
1 p.m. Afternoon sessions
Code ACT. All reservations must be
• Presentation of T.J. Planje-St. Louis received on or before March 7. For
Refractories Award to Bjørn Myhre, Elkem more information, contact Patty Smith
Silicon Materials
• Possibilities to determine refractories' at 573-341-6265 or psmith@mst.edu.
influence on inclusion formation during For more event and registration infor- The new Dilatometer
clean steel production
• Engineering refractory aggregates – mation, including a list of tabletop DIL 402 Expedis
potentials to facilitate the installation and exhibitors, visit ceramics.org/sections/ with revolutionary
improve the performance of refractories
• New higher temperature resistant
st-louis-section. n NanoEye measuring cell
microporous insulation for molten iron and
steel refractory applications
• Development of a novel hybrid method for the Planje Award the
bout
production of macroporous foam ceramics
The 2016 Theodore J. t more a nology:
ou h
4:45 p.m. RCD annual members meeting Find noEye tec n22856
5–7 p.m. Exposition and cocktail hour Planje–St. Louis Refrac- Na m/
new etzsch.co
7 p.m. Dinner .n
tories Award will be pre- www
March 31, 2016 sented to Bjørn Myhre of
6:30 a.m. Refractory Ceramics Division breakfast Elkem Silicon Materials
meeting
8:15 a.m. Morning technical sessions in Oslo, Norway, where
• Steel related refractory research at the he works in research and Myhre
PSMRC
• A first approach to in-situ spinel development regarding uses of micro-
formation in Al2O3-MgO systems silica and other raw materials for the
• Slide gate refractories and systems:
Adapted solutions for high-quality steel
refractory industry. An ACerS member
• A study of the kinetics for carbon transfer and member of the Refractory Division,
from magnesia-graphite ladle refractories Myhre has authored and co-authored DIL 402 Expedis Supreme
to ultra low carbon steel
• Heat transfer, erosion, and stress analysis approximately 85 papers on refractory
for refractory castables, holds one patent, and has two
• Steelmaking refractories - 2030 dream
scenario patent applications pending. n
12 p.m. Questions and discussion
12:30 p.m. St. Louis Section officer business meeting
and lunch
NEW4.1
i o n
EQUILIBRIA 2016 Future Leaders Program at
Ceramic Leadership Summit
Vers rium
of P
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E q uilib
Soo
n! DIAGRAMS Nominate the rising stars in your orga-
nization for the ACerS Future Leaders
ing Program. Held in conjunction with the
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elite group of young professionals who
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Version 4.0 contains and glass industry. The program includes
25,000 phase diagrams, full participation in the Ceramic
Leadership Summit and opportunities to
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interact with expert speakers and other
1,000 new diagrams. high-level participants. A maximum of
four future leaders per company may be
ORDER TODAY ceramics.org/phase nominated. Visit ceramics.org/future-
leadersprogram for more information. n
Student and outreach First endowment fund established to support ceramic materials students
(continued) The Ceramics and Glass Industry Foundation (CGIF) announced its first permanently endowed
fund—the Theodore H. Church Student Leadership Fund—to help support ACerS student lead-
ership program the President’s Council of Student Advisors (PCSA).
Refractories scholarship
The fund was established by a gift from the Theodore H. Church Foundation, which was founded
opportunities by Theodore (Ted) H. Church, former president and owner of Superior Technical Ceramics in
The Refractories Institute (TRI) will Saint Albans, Vt. Before his death in 2008, Church was active in many social and professional
award a limited number of scholarships organizations, including the Association of American Ceramic Component Manufacturers, ACerS,
for the 2016–2017 academic year based and the National Association of Manufacturers. His foundation was established to continue sup-
on academic merit and demonstrated porting his many philanthropic interests.
experience and interest in the field of "We are very excited about the Theodore H. Church Student Leadership Fund at CGIF,” says
refractories. Scholarships will be award- Brian H. Gold, vice president of Corporate Development at Superior Technical Ceramics, the
ed as one-time grants of $5,000 each and company founded by Church. “Ted always held higher education in highest regard. The PCSA
are available to college undergraduate represents some of the finest up and coming professionals in our industry. We are proud to
or graduate students studying in North participate in their development.”
America who are enrolled full-time for Lisa Rueschoff, Ph.D. candidate at Purdue University and PCSA chair, expressed gratitude on
the 2015-2016 academic year in pursuit behalf of the PCSA. “The PCSA is very grateful for this generous support that will allow us to
of an undergraduate or advanced degree provide even more outreach, learning, and growth opportunities to young students and leaders
in ceramic engineering, materials science in the ceramic and glass materials community."
or similar discipline. Deadline for appli- The Theodore H. Church Student Leadership Fund will provide the PCSA with a steady stream of
cations is March 11. For more informa- support and help increase its ability to attract, inspire, and train the next generation of ceramic
tion, visit refractoriesinstitute.org. n and glass professionals.
To find out more about the CGIF and to learn how you can help, visit foundation.ceramics.org or
contact Marcus Fish, CGIF development director, at 614-794-5863 or mfish@ceramics.org. n
Credit: Qiang Fu
folds that alone can repair successfully
large defects in load-bearing bones.
“This is the first demonstration of a
synthetic material that can bridge a large Direct ink writing can deposit bioglass scaffolds layer by layer (left), fabricating intri-
segmental bone defect, without using cate and porous structures (middle) that can be implanted in bone. Micro-CT image
(right) of a 2B63 scaffold implanted in a rabbit femur bone (* = glass scaffold, # =
growth factors or bone marrow stromal
mineralized callus, ‡ = trabecular bone).
cells, in a relatively large animal (rabbit)
model,” Qiang Fu, senior author on the
paper, says in an email. Fu helped develop the glass scaf- large animal models and clinical practice.”
folds at Berkley Lab and is now with Corning Incorporated. The paper, published in Advanced Healthcare Materials,
Using direct ink writing, the team fabricated two types is “Bioactive glass for large bone repair” (DOI: 10.1002/
of scaffolds with different bioglass compositions, silicate adhm.201500447). n
glass 13-93 and borosilicate glass 2B6Sr. The technique,
which builds structures layer by layer, allows precise con-
trol of microstructure by creating regular pores in the bio-
glass scaffold.
Before even testing how well the scaffolds could integrate
with living bone, however, the researchers demonstrated
that the strength of 3-mm cubic samples of their bioglass
scaffolds were far superior to previously reported scaffolds.
According to Berkeley Lab, the bioglass scaffolds are ~100
times stronger than polymer scaffolds and 4–5 times stron-
ger than ceramic and glass scaffolds with similar porosities.
Such high strength means that the researchers could
implant 6-mm × 10-mm samples of the bioglass scaffolds
into rabbit femur bones. Nine months after the rabbits
received their bioglass fix, the scientists took a closer look
at how well the bones repaired themselves. Compared with
the gold standard autologous bone grafts, the bioglass scaf-
folds repaired bone equally as well.
Rabbit cells had infiltrated the scaffolds, which dissolved
to help rebuild new bone with their constituent elements.
In the paper, the authors explain, “The release of soluble Si,
Ca, P, and Na ions as a result of glass surface reaction and
degradation is reported to give rise to the osteoinductive
and osteogenic properties in bioactive glass.” The scaffolds
resorbed as they did so, leaving behind only repaired bone.
Perhaps most importantly, the researchers also showed
that after nine months, bioglass-regenerated bone was just
as hard as normal bone.
Fu says, “The unique combination of high strength, high
porosity, and excellent bioactivity is believed to contrib-
ute to their superior performance. Our work opens a new 303-433-5939
avenue for the reconstruction of large bone defects in both
University of Connecticut.
Chromium poisoning leads to perfor-
mance degradation and compromises
long-term stability of the fuel cell.
“Although surface coatings and bulk
material chemistry modifications have
been utilized to reduce the overall evapo-
ration of chromium from the metallic
When a new silicon and perforated gold film are immersed in a solution of hydro-
components present in the cell stacks
fluoric acid and hydrogen peroxide, the gold film sinks into the silicon substrate and
nanopillars pop up through holes in the film.
and balance of plant sub systems, the
Email: sales@isquaredrelement.com
www.isquaredrelement.com
Research News
Low-cost nickel-based catalyst shows promise for fuel cells Tunable materials clear the way for advanced optics
Researchers at the University of Delaware (Newark, Del.) recently reported A multi-institutional team of researchers, including those at the
a breakthrough that promises to bring down the cost of hydrogen fuel cells University of Wisconsin-Madison, has developed a way to precisely
by replacing expensive platinum catalysts with less expensive ones made engineer the temperatures at which vanadium dioxide will undergo
from metals like nickel. The researchers achieved the breakthrough by phase transition. The researchers not only changed vanadium dioxide’s
switching the operating environment from acidic to basic, and they found intrinsic shift point from 155°F to below 70°F, but they successfully
that nickel matched the activity of platinum. The hydroxide exchange tuned its transition across a variety of specific temperatures.
membrane can offer high-performance fuel cells at an unprecedented low Additionally, because optical and physical properties result from the
cost, according to the researchers, which ultimately will make fuel cell same underlying physical principles, vanadium dioxide’s thermal and
vehicles more affordable. For more information, visit udel.edu. electrical conductivities also shift with the transition. The work could
lead to new types of tunable materials for optics, camouflage, and
thermal regulation. For more information, visit engr.wisc.edu/news.
Credit: NASA/JPL-Caltech
reducing the vast amounts of chemical de-icers that are cur-
rently used in the airline industry.
“It’s a little ironic that a bird that doesn’t fly could one day
help airplanes fly more safely,” Kavehpour says in the release. n A global view of Mars’ Valles Marineris.
conventional cementlike concrete on The open-access paper, available on the Chitons are a prey species that live
Earth—but it is highly anticorrosive and preprint server arXiv, is “A novel material attached to hard surfaces, such as
completely recyclable. for in-situ construction on Mars: Experi- rocks. So eyes allow chitons to detect
The sulfur-based concrete strength ments and numerical simulations.” n approaching predators, which allows
reaches similar levels to conventional them to clamp tightly onto those hard
cementitious concrete. The Martian con- Bifunctional material affords surfaces to hopefully prevent being dis-
crete is fast curing, has low-temperature lodged and eaten.
sustainability, is acid and salt environ-
chiton shells strength and Although the chitons’ tiny eyes—each
ment resistant, and is 100% recyclable, visibility with built-in eyes just 0.1 mm in diameter—had been previ-
all appealing superior characteristics, the Researchers now show that marine ously identified and were thought to per-
authors explain in the paper’s abstract. mollusks called chitons have an interest- form a photosensory function, a recent
The team heats the sulfur until it ing feature they use to adapt to their Science paper is first to report that the
reaches 240°C and liquefies, then mixes life under the sea—hundreds of tiny eyes eyes can form focused images.
it with aggregate—simulated Martian integrated in and scattered across their The authors include researchers from
soil—and lets the mixture cool. As the strong aragonite shells. Massachusetts Institute of Technology,
sulfur solidifies, it binds the soil and
hardens the material to make concrete.
Using compression testing, the team
found that Martian concrete reached a
compressive strength of 50 MPa or more,
thanks to the strong chemical bonds sul-
fur makes with the Martian soil during
curing. That is compared with standard
concretes used in buildings on Earth that
have a compressive strength of about 20
MPa, the authors explain.
And that improved compressive
strength will be necessary on Mars,
because the planet’s atmospheric pres-
sure and temperature range so widely
compared with Earth’s more hospi-
table conditions.
The potential to make concrete on
Mars without having to ship raw mate-
Credit: MIT
rials by space shuttle from home base
means that creating structures on site Close-up image of a part of a chiton shell shows the eyes (dark bumps with shiny
might be easier, cheaper, and more centers) that cover the shell surface. The small bumps with black centers are sensory
straightforward than ever imagined. organs called aesthetes, and the protective mounds in the shell are visible.
Research News
Ceramic particles supply digital X-ray plates ‘from an aerosol can’ Defects could improve solar cells
Researchers at the Leibniz Institute for New Materials (Saarbrücken, Scientists at the National Renewable Energy Lab (Golden, Colo.) are
Germany) and collaborators have developed new materials to manufacture studying what may seem paradoxical—certain defects in silicon solar
X-ray detectors inexpensively and on a large scale with greater image cells may actually improve their performance. Theoretical research
resolution. To do so, they embedded ceramic particles in a conductive suggests that defects with properly engineered energy levels can improve
plastic. The components of these “composite detectors” can be stirred into carrier collection out of the cell, or improve surface passivation of the
a solvent and then applied like paint by spraying. Detectors convert the absorber layer. Scientists ran simulations to introduce defects within a thin
light into an electric current, which is registered by the X-ray apparatus. tunneling silicon dioxide layer and within an aluminum oxide layer next to
This means that it might be possible to manufacture X-ray detectors the silicon cell wafer. In both cases, specific defects were identified to be
inexpensively and on a large scale with greater image resolution. For more beneficial. For more information, visit nrel.gov.
information, visit leibniz-inm.de/en.
Winner-Super 1900
For R&D High Temperature Sintering
For Dental Sintering Furnace
For Stable and Longer Life
Synthesis of atomically thin metallic boron, borophene,
expands 2-D materials
Scientists from Argonne National Lab (Lemont, Ill.), Northwestern Uni-
versity (Evanston, Ill.), and Stony Brook University (Stony Brook, N.Y.)
have created a 2-D sheet of boron—a material known as borophene.
Borophene is unusual because it shows many metallic properties at
the nanoscale, even though bulk boron is nonmetallic and semicon-
ducting. Although other 2-D materials look more or less smooth at the T E L : +82-31-683-1867~9
nanoscale, borophene looks like corrugated cardboard. The research- F A X : +82-31-683-1870
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Refractory Material
Selection for Steelmaking
By Tom Vert,
Excerpt selections by Eileen De Guire
Editor’s note—
“If you’re in the refractory business, you’re in the steel business.”—Conventional Wisdom.
A typical steel plant uses hundreds of types of refractories, each engineered for specific applications. Those
responsible for specifying refractories must understand the diverse and demanding service environments,
refractory product portfolio, and business drivers—and never compromise on safety to personnel, plant, and
environment.
It is a daunting task. Vert has been there—as the refractory selection engineer and as the expert training
others. Vert’s new book, Refractory Material Selection for Steelmaking, grew out of training materials he
developed for new engineers to teach the fine art of refractory selection for steelmaking. Vert takes the
reader/practitioner through his tried-and-true methods for establishing refractory selection goals. He reviews
refractory types and available materials. He guides the reader through specific applications in the steel plant,
and he pulls it all together with a chapter on refractory purchasing strategies.
To illustrate the increasing market value of the refractories industry and some salient statistics on its biggest
downstream market—the steel industry—see ACerS' infographic on pg 29. At a glance, see trends in the
worldwide production of crude steel and learn about the top five steel-producing countries and companies.
Because the book was in production at the time this excerpt was prepared, it may vary slightly from the
published book, but will match in its essentials.
Steelmaking glossary Adapted from American Iron and Steel Institute www.steel.org
Basic oxygen furnace (BOF) smelt iron from iron ore. The name refers to the bathtub) atop a continuous caster. As steel flows
A pear-shaped furnace, lined with refractory “blast” of hot air and gases forced up through from the tundish down into the water-cooled
brick, that refines molten iron from the blast the iron ore, coke, and limestone that load the copper mold of the caster, it solidifies into a rib-
furnace and scrap into steel. Up to 30% of the furnace. bon of red-hot steel. At the bottom of the caster,
charge into the BOF can be scrap, with hot Electric arc furnace (EAF) torches cut the continuously flowing steel to
metal accounting for the rest. Scrap is dumped A steelmaking furnace where scrap is gener- form slabs or blooms.
into the furnace vessel, followed by hot metal ally 100% of the charge. Heat is supplied from Ladle
from the blast furnace. A lance is lowered from electricity that arcs from the graphite electrodes A “bucket” lined with refractory brick, used to
above, through which blows a high-pressure to the metal bath. Furnaces may be either alter- transport molten steel from process to process
stream of oxygen to cause chemical reactions nating current or direct current. Direct current in a steel plant.
that separate impurities as fumes or slag. Once units consume less energy and fewer electrodes, Tundish
refined, the liquid steel and slag are poured into but they are more expensive. The shallow refractory-lined basin on top of the
separate containers.
Continuous caster (CC) continuous caster. It receives liquid steel from
Blast furnace (BF) Steel from the BOF or electric furnace is poured the ladle, prior to the cast, allowing the operator
A towering cylinder lined with refractory brick to into a tundish (a shallow vessel that looks like a to precisely regulate flow of metal into the mold.
therefore, cannot appreciate the refractory engineer. Vert presents industrially impor-
the effect of the former on the tant phase diagrams and walks the reader through cor-
latter. rect interpretation. The chapter addresses fundamental
The TMC analysis is then wear mechanisms and consequent engineering decisions.
These concepts tie together by coming back to TMC
compared against the refracto-
chapter 3
Wear rate
anisms for major steelmaking refractory compositions.
FeO, Fe2O3
As the total number of impurities
increases, the crystal size decreases, and, Fig. 3.13. B2O3 and MgO binary phase diagram.
then, the wear rate increases, as shown
in Figure 3.12.
Percent B2O3
At steelmaking temperatures
(1,600°C), even with small amounts of
B2O3 (less than 0.001%), a liquid will
form at 1,155°C as shown in the phase
diagram in Figure 3.13. It forms along
the grain boundaries, as shown in Figure
Credit: Wiley; Vert
chapter 11
Editor’s note—Final refractory selection combines technical
and operations requirements with business considerations.
Employing the analysis methods introduced throughout the
book, especially the total cost of ownership, the refractory-
selecting engineer will be well equipped to make a final
recommendation to the purchasing team.
Purchasing strategies
Selecting and purchasing refractories
is a very interesting part of the total
business. Recall that in Chapter 1.6
we talked about TCO—Total Cost of
References
1
L.D. Madsen, “NSF’s CAREER Class of 2015 in ceramics and cross-
cutting programs,” Am. Ceram. Soc. Bull., 94 [8] 36–39 (2015). n
details, including responsibilities. Oxide surfaces, from bulk to nanoparticles (1507101) Laurence Marks, Northwestern University
Probing and manipulating strained interfaces with oxide Judy Wu, University of Kansas Center for Research
Sustainable Chemistry, Engineering, superconductors (1508494)
and Materials (SusChEM) Real-time X-ray scattering studies of oxide epitaxial growth Randall Headrick, University of Vermont & State Agricultural
(1506930) College; Matthew Dawber
The SusChEM initiative (1.usa.
Science of electron-conducting filaments in ion-conducting Gang Chen, Ohio University; David Drabold
gov/1lTJ79P) addresses interrelated challeng- chalcogenide glasses (1507670)
es of sustainable supply, engineering, produc- Statics and dynamics of spatially and dimensionally constrained Vinayak Dravid, Northwestern University
tion, and use of chemicals and materials. oxides (1507810)
Collaborative Research: Bulk synthesis of stishovite near ambient Kai Landskron, Lehigh University
Faculty Early Career Development pressure and temperature (1463948, 1463974) Peter Kroll, University of Texas at Arlington
Program (CAREER) Collaborative Research: High-throughput quantification of solid-state Sossina Haile, Northwestern University
electrochemistry for next-generation energy technologies (1505103, Ichiro Takeuchi, University of Maryland College Park
The CAREER (1.usa.gov/1E4FrZn) 1505116)
solicitation is restricted to single investigators Collaborative Research: Integrated computational and experimental Scott Barnett, Northwestern University
who are assistant professors. The two awards studies of solid oxide fuel cell electrode structural evolution and Katsuyo Thornton, University of Michigan Ann Arbor
electrochemical characteristics (1506925, 1506055)
made in FY 2015 are detailed in the ACerS
Collaborative Research: On the origin of atomic layer deposition Kevin Huang, University of South Carolina at Columbia
Bulletin.1
enhanced activity and stability of nanostructured cathodes for Xinhua Liang, Missouri University of Science and Technology
intermediate-temperature solid oxide fuel cells (1464112, 1464111)
EArly-concept Grants for Exploratory SusChEM: Collaborative Research: Experimental and computational Alexandra Navrotsky, University of California-Davis;
Research (EAGER) study of structure and thermodynamics of rare-earth oxides above Sergey Ushakov
2000°C (1506229, 1505657) Axel van de Walle, Brown University
“The EAGER funding mechanism may be
SusChEM: Nanoscale insight into electric fatigue of lead-free Xiaoli Tan, Iowa State University
used to support exploratory work in its early piezoelectric ceramics (1465254)
stages on untested, but potentially transfor-
SusChEM: Rational design and synthesis of stable strain- and defect- Tewodros Asefa, Rutgers University
mative, research ideas or approaches.” Full rich Cu/ceramic nanocomposites for efficient CO2 reduction (1465254)
details are provided in the Grant Proposal CAREER: Defect-driven metal oxides for enhanced energy storage Hui (Claire) Xiong, Boise State University
Guide (1.usa.gov/1TSnOQu). systems (1454984)
CAREER: Understanding surface redox activity of atomically flat William Chueh, Stanford University
Grant Opportunities for Academic electroceramics (1455369)
Liaison with Industry (GOALI) EAGER: Biocompatibility of nanocrystalline YSZ transparent cranial Guillermo Aguilar, University of California-Riverside;
implant (1547014) Javier Garay
GOALI (1.usa.gov/1mpWVsv) promotes
EAGER: Fabrication and characterization of 3-D ceramic-coated Bridget Rogers, Vanderbilt University
university–industry partnerships by making polymer scaffolds (1547014)
project funds or fellowships and trainee-
GOALI: OP: Incongruent growth of single-crystal 3-D architecture for Himanshu Jain, Lehigh University; Daniel Nolan,
ships available to support universities work- new optical functionalities in glass (1508177) Volkmar Dierolf
ing with industry. One of these Ceramics GOALI: Zintl engineering of epitaxial ceramic films on gallium nitride John Ekerdt, University of Texas at Austin; Alexander
Program projects also was funded under (1507970) Demkov, Rytis Dargis
the Optics and Photonics area of interest GOALI: Nanostructured sapphire optical fiber for sensing in harsh Henry Du, Stevens Institute of Technology;
environment (1506179) Narciso Dominguez
(1.usa.gov/1Pb9ymt). Companies engaged
in the 2015 Ceramics Program projects GOALI: Atomistic understanding of non-Newtonian flow and related Sabyasachi Sen, University of California-Davis; Bruce Aitken
phenomena in chalcogenide glass-forming liquids (1505185)
are Corning Inc., Translucent Inc., and
GOALI: Collaborative Research: Understanding composition–structure Jincheng Du, University of North Texas
Fiberguide Industries Inc. –chemical durability relationships in multicomponent oxide glasses: Ashutosh Goel, Rutgers University; Nicholas Smith,
Influence of mixed network former effect (1508001, 1507131) Randall Youngman
T
he President’s Council of Student Advisors at Irvine, is working toward completing a set of
(PCSA) kicked off its annual business meeting extensive ceramic materials lesson plans that
days before MS&T15, where graduate and will be available for download by summer 2016
undergraduate ceramic student leaders from all (see inset). In addition, the committee filmed
over the world gathered in Columbus, Ohio, to dis- instructional videos of the existing student labo-
cuss plans for the upcoming year. Delegates for the ratory and teacher demonstration kits, which are
2015–2016 year planned outreach, programming, available at ceramics.org.
and professional development events to engage Theresa Davey, graduate student at Imperial
students worldwide as leaders in the ceramics College London, chairs the communications
community and encourage participation in ACerS. committee, which works to promote PCSA and
At the meeting, delegates elected an overall student activities within ACerS. The committee
council chair and chairs for each of the five PCSA presents the “Deciphering the Discipline” column tion at ICACC’16; is planning a new creative
committees, in addition to discussing and plan- and coordinates a special focus on students competition for ceramics students; compiles re-
ning opportunities for the advancement of ACerS in the June/July Bulletin. Check out the PCSA gional activities pamphlets for major materials
students. Delegates elected Lisa Rueschhoff, a Facebook page for biweekly updates on student conferences; and, with the help of ACerS Young
graduate student at Purdue University, to suc- accomplishments and ACerS Division events. Professionals Network and ACerS staff, held
ceed the previous chair, Jessica Rimsza. The programming committee, led by Megan the first Winter Workshop for ceramic students
The outreach committee, chaired by Kara Phillips, Wilson, graduate student at the University of and young professionals from around the world
a graduate student at the University of California Virginia, organized the Schott glass competi- during January 2016 (see more on page 11 and
page 48).
Ceramic and glass materials lesson plans The finance committee, chaired by Mark Hornak,
graduate student at The Ohio State University,
PCSA’s new ceramic and glass materials lesson plans, designed by the current and previous out- builds relationships with donors and raises funds
reach committees, will debut summer 2016 and will feature interactive student activities as well to support student travel to the PCSA annual
as teacher demonstrations that will help students learn more about processing, structure, and business meeting. All past and current delegates
properties of ceramics. Lesson plans will provide step-by-step instructions to perform laboratory of PCSA are grateful to the generous donors,
exercises and demonstrations as well as follow-up questions to lead discussions with students. who make PCSA programming, outreach, and
Hands-on activities outlined in the lesson plans teach students about the structural differences networking opportunities possible.
between amorphous glass and crystalline ceramic materials by building models of each struc- PCSA continually looks forward—the recruit-
ture. Examples of each class of material and its structure illustrate differences in bonding and, ment committee is on the lookout for 35 ceramic
subsequently, materials properties. student leaders to join PCSA as delegates for
The new kits also outline how to build an electrical circuit using batteries, various modified 2016–2017. PCSA offers immense opportunities
silicate glasses, and LED lights, an exercise that demonstrates how structure affects glass’s for students to become involved and network
electrical properties. This experiment demonstrates the effect of modifying ions in glass’s with other students and ceramic leaders.
structure and how those modifications affect the material’s electrical properties. Using the les- Interested undergraduate and graduate students
son plans, students also study mechanical properties—in compression and tension—of glasses from around the world are encouraged to apply.
and ceramics compared with metals to discover the dependence of those properties on atomic More information can be found at ceramics.org/
structure and bonding. PCSA, and questions can be directed toward
In addition, lesson plans explore sintering experiments using low-melting-point polymers to the recruitment committee chair, James Steffes
study the mechanisms of sintering and the dependence of starting spheres on size. These (james.steffes@uconn.edu), graduate student at
experiments serve as a foundation to introduce students to the importance and implications of the University of Connecticut.
sintering ceramics. PCSA delegates are grateful for the foundational
PCSA hopes its new lesson work of last year’s committee chairs, Sapna
plans, outlining these Gupta and Brian Donovan. PCSA owes its suc-
experiments and more, will cess to the multitude of ACerS advisors, liaisons,
be used in classrooms, and staff that makes all its work possible—
science fairs, and student thanks to Geoff Brennecka, Kristen Brosnan,
activity fairs across the Valerie Wiesner, Jessica Krogstad, Andrea Muller-
world to introduce students Hoff, David Shahin, and Tricia Freshour.
to—and spark interest in— Lisa Rueschhoff holds a ceramic tile on which a penny is heated Lisa Rueschhoff is chair of the 2015–2016
the world of ceramics and up during a demonstration to students. PCSA and is a Ph.D. candidate in the School
glass. n of Materials Engineering at Purdue University
(West Lafayette, Ind.). n
T
he 2016 edition of Electronic Materials and Applications—the meeting’s seventh
annual installment—took place in sunny Orlando, Fla., Jan. 20–22.
EMA is all about electronics—the meeting covers emerging needs, opportunities,
and key challenges within the field, highlighting the latest advances in electronics,
sensors, energy generation and storage, photovoltaics, and light emitting diodes. ACerS
Electronics Division and Basic Science Division jointly program the meeting.
And with more than 300 international attendees (a record attendance!), the conference is
sized just right—big enough to feature a variety of high-quality research and countless
networking opportunities, yet small enough to get to know fellow attendees.
In addition to high-quality technical talks spanning all electronic topics, a buzzing poster
reception, expert tutorials, and the not-to-be missed special symposium dedicated to
Haiyan Wang (center), one of the EMA 2016 organizers, poses learning from failed research, this conference also consistently delivers high-
with a couple of conference attendees during a coffee break. quality plenary lectures to get each day humming. This year’s plenary speakers were
Darrell Schlom, Herbert Fisk Johnson Professor of Industrial Chemistry at Cornell Univer-
sity (Ithaca, N.Y.); James Warren, technical program director for materials genomics at the
National Institute of Standards and
Technology’s Material Measurement
Laboratory (Gaithersburg, Md.); and
Thomas Detzel, senior manager of
gallium nitride technology at
Infineon Technologies Austria AG
(Villach, Austria).
EMA 2017 will continue the tradition
of bringing top-level research and
ACerS PCSA members (left to right) Brian Donovan, speakers to Orlando, Fla., Jan. 18–
Giorgia Franchin, and Theresa Davey. 20, 2017—join us for this opportu-
nity to connect and network with the The evening poster session was packed with eager attendees and
electronic materials community. n cutting-edge research on electronic materials and applications.
A
t the 40th International Conference on countries arrived and, besides participating in the
Advanced Ceramics and Composites opening technical program, celebrated the 40th jubilee an-
reception, almost all conversations began niversary of this conference.
with a version of “Did the storm affect your travels
Program chair Andy Gyekenyesi says, “The fact
to Daytona Beach?”
that around 50% of attendees are international,
The storm was Winter Storm Jonas, which ravaged representing 42 countries, demonstrates that this is
the eastern United States with several feet of snow truly an international event.”
and ice. Driving was treacherous, and airports
ICACC program chair Andy Gyekenyesi welcomes According to former ACerS president Jim McCau-
across the entire eastern seaboard were closed for
attendees on Monday to the opening session. ley, ICACC grew out of the “Refractory Composites
at least two days.
Workshop,” first held 41 years ago in Cocoa
Obviously, those who were most affected were not Beach, Fla. That success led the Ceramic-Metal
there to answer the question. The storm’s lingering Systems Division to establish ICACC. Ceramic-
impact was most noticeable on Monday afternoon Metal Systems later evolved into today’s Engineer-
when symposia sessions started, with many talks ing Ceramics Division.
cancelled or rescheduled because of travel delays.
In 2007, ICACC moved north to Daytona Beach
Eventually, about 1,080 attendees from 42 to accommodate higher attendance, and now it
Featured speakers:
Vertical Innovation Process for Product and Business Supply Chain for Innovation – Timothy Major, supply
Development – John Nottingham, Nottingham Spirk management director of science & technology, Emerging
Innovations Group, Corning Incorporated
Scaling Up for the Production of CMCs for Gas-Turbine Customers: The Importance of Market Validation and
Engines – Matthew O’Connell, industrialization leader, Ceramic Sales Channels – Vladimir Ban, CEO, PD-LD Incorporated
Matrix Composites, GE Aviation – Supply Chain Division, com-
posites value stream
Overview of Global Economy and Supply Chain Business Acquisition Strategy – David Gunderson, global
Economics – Susan Helper, special advisor to the undersecre- business development director, Advance Ceramics Platform,
tary for economic affairs of the U.S. Department of Commerce; 3M
former chief economist, U.S. Department of Commerce; Carlton
Professor of Economics at the Weatherhead School of Manage-
ment, Case Western Reserve University
Creating an Innovative Manufacturing Commercialization of Technology/Business
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ceramics.org/cls2016
April 24–26, 2016 | CLEVELAND, OHIO
Plenary Session – The future of the ceramics industry | April 26 | 10:30 – 11:30 A.M.
Main Stage Ceramics Expo – IX Center
The leader’s debate will provide attendees with the perspectives of the largest global ceramic manufacturers in the world. Market growth and
manufacturing challenges will be discussed, along with future expected trends of “onshoring” in relation specifically to the manufacturing of
technical ceramics and glasses in North America.
Contact Tricia Freshour at tfreshour@ceramics.org for special pricing information and to nominate a young professional.
The
American
Targeted Learning Workshops
Ceramic
Society’s ceramics.org/expoworkshops2016
Increase your knowledge with ACerS Targeted Learning Workshops, held in conjunction with Ceramics Expo in Cleveland, Ohio
Are you an engineer, scientist, operations professional, or student looking to sharpen your skills and expand your knowledge base? Continue your
education with ACerS Targeted Learning Workshops. Taught by experts, these courses expand on foundational topics and equip attendees with
additional skills needed for the workplace.
April 24, 1 – 6 p.m. and April 25, 8 a.m. – 2 p.m. April 27, 1 – 5 p.m.
OSHA 10-Hour Industrial Outreach Safety Course On the Plant Floor: A Practical Guide for
Instructor: Douglas Jeter, Verity Technical Consultants LLC, Leaders in the Manufacturing Plant
adjunct professor Instructors: Bryan D. Geary and Carlton F. Sorrell,
This course provides an introduction to general industry safety as well OPF Enterprises
as health hazard identification, avoidance, control, and prevention. This half-day course helps you become a more effective
Workers, supervisors, and managers who have not previously had for- Geary leader and manager in the manufacturing operation.
mal training in safety or OSHA regulations will benefit from this course. Designed as a practical guide to actual problem solving
and culture building at all levels in the manufacturing
April 26, 1 – 5 p.m. plant, real-life solutions to real-life problems are offered.
Capital for High-Growth Startups This course is practical—short on theory and long on
the reality of life in a factory, and is especially valuable for
Instructor: Bill Payne, Angel Investor
recent graduates or anyone new to life on the plant floor.
This half-day workshop is an important event for emerging or
startup entrepreneurs who know that understanding the scope of Sorrell
financing available to them is a key to success of new companies.
Best practices on how to finance a startup business will be described
and discussed interactively. Offered by ACerS Manufacturing Division
Materials Challenges in Alternative Renewable Energy (MCARE 2016) addresses emerging materials for a sustainable global society.
a rc h
This cutting-edge international conference brings together leading global experts from universities, industry, research and
development laboratories, and government agencies to collaboratively communicate materials technologies that advance affordable,
R e g i s te r b y M
sustainable, environmentally friendly, and renewable energy conversion technologies. MCARE’s engaging atmosphere promotes
student and research participation, providing an open forum for idea exchange with leading researchers.
ceramics.org/mcare2016
The extensive technical program features plenary and invited talks, thematically focused technical sessions, and poster
presentations, enabling delegates to network and exchange ideas with professional peers and acclaimed experts.
S1 Functional Materials for Photoelectrochemical and S6 Critical Materials for Energy
Electrocatalytic Hydrogen Production S7 Emerging Materials for Next-Generation Photovoltaics
S2 Spectral Conversion Materials for Energy Applications S8 Self-Power Generators
S3 Ferroelectrics and Multiferroics for Energy Applications S9 Direct Thermal-to-Electrical Energy Conversion Materials and Applications
S4 Material Challenges in Nuclear Energy S10 Batteries and Energy Storage
S5 Material Challenges in Fuel Cells S11 Hydrogen Materials and Economy
Program Cochairs
Hilton Clearwater Beach
400 Mandalay Avenue, Clearwater Beach, FL
Phone: (727) 461-3222 | (800) 753-3954
Rates
Sanjay Mathur, Steven Tidrow, Single/Double: $179
University of Frostburg State Government: Current Per Diem Rate
Cologne, Germany University, USA
Cut-off Date: On or before
March 15, 2016
BIOMEDICAL abstract by
March 14,
Ceramic and Glass Materials for Medical Implants, Medical Devices, and Tissue Engineering
July 29-31, 2016 | Rosemont Hyatt, Chicago, Ill., USA
The Innovations in Biomedical Materials 2016 meeting
will emphasize collaboration between R&D, medical Tracks:
practitioners, and biomedical materials manufacturers/ TRACK 1: Orthopedic Application – Where Are
marketers to better develop emerging technologies into We? Where Do We Need to Go?
marketable products. Three keynote speakers will be
highlighted, immediately followed by an expert panel Track 2: Dental and Maxillofacial
session where the audience can interact with renowned Applications
experts in the biomedical field. The six-track technical Track 3: Material Needs for Medical Devices
program provides a forum for scientists, engineers, medical
Track 4: Advanced Manufacturing
professionals, and industrial researchers to discuss recent
Technologies
advances in the field of biomedical materials.
Track 5: Power Sources, Energy Harvesting,
Program chairs: Power Transmission, and Telemetry
Track 6: Implantable and Wearable Sensors
Endorsed by:
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28–April 1 2016 MRS Spring 10–12 78th Annual PEI Technical 5–8 12th European SOFC and
Meeting and Exhibit – Phoenix Forum – Louisville, Ky.; SOE Form: 20th Conference in
Convention Center, Phoenix, Ariz.; www.porcelainenamel.com Series with Exhibition – Kulture-
www.mrs.org/spring2016 und and Kongresszentrum Lucerne,
18–22 WBC2016: 10th World Switzerland; www.EFCF.com
29–31 St. Louis/RCD 52nd Annual Biomaterials Congress – Montreal,
Symposium – Hilton St. Louis Airport Canada; www.wbc2016.org 10–13 3rd Int’l Congress on 3D
Hotel, St. Louis, Mo.; www.ceramics. Materials Science 2016 – Pheasant
org/sections/st-louis-section 22–26 Glass and Optical Materials Run Resort, St. Charles, Ill.; www.tms.
Division Meeting 2016 – The Madison org/meetings/2016/3DMS2016
April 2016 Concourse Hotel and Governor’s Club,
Madison, Wis.; 17–21 6th Int’l Conference on
3–6 5th Int’l Directionally Solidified www.ceramics.org/gomd2016 Recrystallization and Grain Growth –
Eutectic Ceramics Workshop: DSEC V Omni William Penn Hotel, Pittsburgh,
– Warsaw, Poland; www.dsec5.com 23–25 27th AeroMat Conference and Pa.; www.tms.org/meetings/2016/
Exposition – Meydenbauer Center, ReXGG2016
5–6 ACMA Composites Executive Bellevue, Wash.; www.asminter
Forum – Washington, D.C.; national.org/web/aeromat-2016 25–26 Diversity in the Minerals,
www.acmanet.org Metals, and Materials Professions –
June 2016 Northwestern University, Evanston, Ill.;
7–11 ICG XXIV Int’l Congress – www.tms.org/meetings/2016/
Shanghai, China; www.icglass.org 19–24 PDC Workshop: diversity2016
Membranes, Coatings, Fibers, and
17–21 MCARE 2016: Materials Composites – Boulder, Colo.; 28–31 Innovations in Biomedical
Challenges in Alternative and Renewable www.polymerceramics.weebly.com Materials and Technologies –
Energy – Hilton Clearwater Beach Resort, Rosemont Hyatt, Chicago, Ill.;
Clearwater, Fla.; www.ceramics.org 26–30 HTCMC 9 and GFMAT: 9th www.ceramics.org/biomed2016
Int’l Conference on High-Temperature
25–29 43rd ICMCTF: Int’l Conference Ceramic-Matrix Composites and 31–Aug. 5 Gordon Research
on Metallurgical Coatings and Thin Global Forum on Advanced Materials Conference on Ceramics and Solid
Films – San Diego, Calif.; www2.avs. and Technologies for Sustainable State Studies – Mount Holyoke
org/conferences/icmctf Development 2016 – Toronto Marriott College, South Hadley, Mass.;
Downtown Eaton Centre Hotel, www.grc.org/programs
26–28 2nd Ceramics Expo – IX Toronto, Canada; www.ceramics.org
Center, Cleveland, Ohio;
Dates in RED denote new entry in
www.ceramicsexpousa.com 27–29 Electroceramics XV –
this issue.
Limoges, France;
26–28 5th Ceramic Leadership www.electroceramics15.com Entries in BLUE denote ACerS
Summit – Cleveland, Ohio; events.
www.ceramics.org denotes meetings that ACerS
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Maintenance
Supervisor, Ceramic
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CerS-Wiley seeks new au-
thors or volume editors
American Ceramic Society, The www.ceramics.org Inside Front and Back covers, 10, 44
for textbooks, handbooks,
American Elements‡ www.americanelements.com Outside Back Cover
or reference books on ceramics and
Deltech Inc.‡ www.deltechfurnaces.com 13
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Verder Scientific www.verder-scientific.com 3 ing, processing, and usage; ceramic
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Advanced Ceramic Technology www.advancedceramictech.com 45
umes receive complimentary cop-
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Delkic & Associates 904-285-0200 44
Detroit Process Machinery www.detroitprocessmachinery.com 46 To learn more or to share an idea,
Geller Microanalytical Laboratory Inc. www.gellermicro.com 46
please contact:
Harper International Corp.‡ www.harperintl.com 45 Anita Lekhwani
Harrop Industries Inc.‡ www.harropusa.com 45, 46 Senior Acquisitions Editor
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Mayln Industrial Ceramics Inc. www.malyn.com 45 111 River Street
Mohr Corp.‡ www.mohrcorp.com 46 Hoboken, NJ 07030-5774
Tel: 201-748-7740
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North America LLC‡ Fax: 201-748-8888
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PPT - Powder Processing & www.pptechnology.com 45
Technology LLC
Greg Geiger
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Rauschert Technical Ceramics Inc. www.rauschert.com 44 The American Ceramic Society
Sem-Com Company www.sem-com.com 45 600 N. Cleveland Ave., Suite 210
Sonic Mill www.sonicmill.com 44 Westerville, Ohio 43082
Specialty Glass Inc. www.sgiglass.com 45 Tel: 614-794-5858
Fax: 614-794-5882
West Penn Testing Group www.westpenntesting.com 46
E-mail: ggeiger@ceramics.org
Zircar Zirconia Inc. www.zircarzirconia.com 44
Attendees at the ACerS Winter Workshop 2016 gather at the University of Central Florida in Orlando, Fla.
R G Energy
. O
C H Fundamentals, Characterization, and
ITE
Computational Modeling
SC
Iron and Steel (Ferrous Alloys)
AT Materials-Environment Interactions
M Nanomaterials
Processing and Manufacturing
Special Topics
3 2 4 2 5 2 6 2 7 2 8 2 9 2 10 2
1 2 3 4 5 6 7 8
Li Be B C N O F Ne
ite 11
6.941
Lithium
2
8
12
9.012182
Beryllium
2
8
semiconductors palladium shot 13
10.811
Boron
2
8
14
12.0107
Carbon
2
8
15
14.0067
Nitrogen
2
8
16
15.9994
Oxygen
2
8
17
18.9984032
Fluorine
2
8
18
20.1797
Neon
2
8
anode
Na Mg Al Si P S Cl Ar
1 2 3 4 5 6 7 8
cathode 22.98976928
Sodium
24.305
Magnesium nuclear 99.999% ruthenium spheres 26.9815386
Aluminum
28.0855
Silicon
30.973762
Phosphorus
32.065
Sulfur
35.453
Chlorine
39.948
Argon iron
19 2 20 2 21 2 22 2 23 2 24 2 25 2 26 2 27 2 28 2 29 2 30 2 31 2 32 2 33 2 34 2 35 2 36 2
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8
conesK Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
8 8 9 10 11 13 13 14 15 16 18 18 18 18 18 18 18 18
gallium lump
1 2 2 2 2 1 2 2 2 2 1 2 3 4 5 6 7 8
39.0983 40.078 44.955912 47.867 50.9415 51.9961 54.938045 55.845 58.933195 58.6934 63.546 65.38 69.723 72.64 74.9216 78.96 79.904 83.798
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
dielectrics
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2
liquids
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18
8 8 9 10 12 13 13 15 16 18 18 18 18 18 18 18 18 18
1 2 2 2 1 1 2 1 1 1 2 3 4 5 6 7 8
85.4678 87.62 88.90585 91.224 92.90638 95.96 (98.0) 101.07 102.9055 106.42 107.8682 112.411 114.818 118.71 121.76 127.6 126.90447 131.293
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
CIGS ionic
55 2 56 2 57 2 72 2 73 2 74 2 75 2 76 2 77 2 78 2 79 2 80 2 81 2 82 2 83 2 84 2 85 2 86 2
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18
18 18 18 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32
8 8 9 10 11 12 13 14 15 17 18 18 18 18 18 18 18 18
1 2 2 2 2 2 2 2 2 1 1 2 3 4 5 6 7 8
132.9054 137.327 138.90547 178.48 180.9488 183.84 186.207 190.23 192.217 195.084 196.966569 200.59 204.3833 207.2 208.9804 (209) (210) (222)
Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
rod 87
Fr
2
8
18
32
18
8
88
Ra
2
8
18
32
18
8
89
Ac
2
8
18
32
18
9
104
Rf
2
8
18
32
32
10
105
Db
2
8
18
32
32
12
106
Sg
2
8
18
32
32
11
107
Bh
2
8
18
32
32
13
108
Hs
2
8
18
32
32
14
109
Mt
2
8
18
32
32
15
110
Ds
2
8
18
32
32
17
111
Rg
2
8
18
32
32
18
112
Cn
2
8
18
32
32
18
113
Uut
2
8
18
32
32
18
114
Fl
2
8
18
32
32
18
115
Uup
2
8
18
32
32
18
116
Lv
2
8
18
32
32
18
117
Uus
2
8
18
32
32
18
118
Uuo
2
8
18
32
32
18
es
1 2 2 2 2 2 2 2 2 1 1 2 3 4 5 6 7 8
(223) (226) (227) (267) (268) (271) (272) (270) (276) (281) (280) (285) (284) (289) (288) (293) (294) (294)
Francium Radium Actinium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Flerovium Ununpentium Livermorium Ununseptium Ununoctium
photovoltaics 58 2 59
europium phosphors
2 60 2 61 2 62 2 63 2 64 2 65 2
quantum dots
66 2 67 2 68 2 69 2 70
neodymium foil
2 71 2
8 8 8 8 8 8 8 8 8 8 8 8 8 8
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
18 18 18 18 18 18 18 18 18 18 18 18 18 18
140.116 140.90765 144.242 (145) 150.36 151.964 157.25 158.92535 162.5 164.93032 167.259 168.93421 173.054 174.9668
Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
18 18 18 18 18 18 18 18 18 18 18 18 18 18
32 32 32 32 32 32 32 32 32 32 32 32 32 32
18 20 21 22 24 25 25 27 28 29 30 31 32 32
10 9 9 9 8 8 9 8 8 8 8 8 8 8
2 2 2 2 2 2 2 2 2 2 2 2 2 3
232.03806 231.03588 238.02891 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)
Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
Now Invent.
TM
optoelectronics mischmetal
Nd:YAG superconductors
macromolecules dysprosium pellets ultra high purit
sputtering targets neodymium foil erbium doped fiber optics
gadolinium wire cerium polishing powder thin film macromolecules
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