K3Fe(CN)6(.0025 H2O dest.

Concentracion
Tubos HNO3 (.1 mol dm-3) ml Abs
mol dm-3) ml ml final (mol dm-3)

1 4 1 5 1.002 0.01
2 3 1 6 0.817 0.0075
3 2 1 7 0.501 0.005
4 1 1 8 0.238 0.0025
5 0.25 1 8.75 0.111Curva patrón
0.000625
1.2

1
Pendiente 99.68 f(x) = 99.6817679558012 x + 0.022930939226519
R² = 0.991678697042128
Ordenada 0.0229 0.8

Absorbancia
R2 0.9916
0.6

0.4

0.2

0
0 0.002 0.004 0.006 0.008 0.01
Concentracion
 Concetracion
D.R.
calculada

0.0098224318 1.78%
0.0079664928 -6.22%
0.0047963483 4.07%
0.0021579053 13.68%
patrón 0.0008838283 -41.41%

022930939226519

0.006 0.008 0.01 0.012

centracion
Tiempo (s) Abs Conc. Calc. x ln 1/[ ]
0 0.713 0.0069231541 0 0 0
20 0.678 0.0065720305 0.0003511236 0.05204862 7.7171412
40 0.648 0.0062710674 0.0006520867 0.09892488 15.0196516 0.008
60 0.62 0.0059901685 0.0009329856 0.14475191 22.4973766 0.007
80 0.596 0.0057493981 0.001173756 0.18577629 29.4884167 0.006 f(x) = − 1.06483604677
R² = 0.98594865098208
100 0.57 0.0054885634 0.0014345907 0.23220491 37.7542046

Concentracion
0.005
120 0.549 0.0052778892 0.0016452648 0.27134521 45.0268482
0.004
140 0.528 0.0050672151 0.001855939 0.31208009 52.9042256
0.003
160 0.508 0.004866573 0.0020565811 0.35248146 61.0405711
0.002
180 0.49 0.0046859952 0.0022371589 0.39029315 68.9590068
200 0.473 0.0045154494 0.0024077047 0.42736673 77.019063 0.001

220 0.456 0.0043449037 0.0025782504 0.46586787 85.7118643 0

0 50 1
240 0.441 0.0041944222 0.0027287319 0.50111588 93.9690288
260 0.427 0.0040539727 0.0028691814 0.53517414 102.228782
280 0.402 0.0038031701 0.0031199839 0.59903649 118.495704

Orden 0
0.0035 0.7

0.003 f(x) = 1.06483604677826E-05 x + 0.00024545211343 0.6

R² = 0.985948650982088 f(x) = 0.002055
0.0025 0.5 R² = 0.9978347

0.002 0.4

ln
X

0.0015 0.3

0.001 0.2

0.0005 0.1
0 0
0 50 100 150 200 250 300 0 50
Tiempo (seg)
 C vs T
0.008
0.007
0.006 f(x) = − 1.06483604677826E-05 x + 0.006677701979668
R² = 0.985948650982088
0.005
0.004
Orden 2
0.003 120

0.002 100
f(x) = 0.392386381312619 x − 1.05764527464426
0.001 R² = 0.999393575861385
80
0
0 50 100 150 200 250 300

1/[ ]
60
Tiempo (s)
40

20

0
Orden 1 0 50 100 150 200

0.7 Tiempo (seg)

0.6
f(x) = 0.002055269900936 x + 0.016826722099435
0.5 R² = 0.997834700594141

0.4
ln

0.3

0.2

0.1

0
0 50 100 150 200 250 300
Tiempo (seg)
 Orden 2

12619 x − 1.05764527464426
1385

100 150 200 250 300

Tiempo (seg)
Tiempo (s) Abs Conc. Calc. x ln 1/[ ]
0 0.614 0.00592998 0 0 0
40 0.564 0.00542837 0.00050161 0.0883811 15.5825863 C
80 0.525 0.00503712 0.00089286 0.1631859 29.8914412 0.007
120 0.493 0.00471609 0.00121388 0.22903977 43.4052427
0.006
160 0.464 0.00442516 0.00150482 0.2927136 57.3457545
0.005 f(x) = − 5.79326371862487E
200 0.44 0.00418439 0.00174559 0.34865921 70.3487084 R² = 0.966471873384075

Concentacion
240 0.416 0.00394362 0.00198636 0.40792118 84.9394054 0.004
280 0.396 0.00374298 0.002187 0.46013873 98.5322306 0.003
320 0.376 0.00354234 0.00238764 0.5152339 113.664883
0.002
360 0.358 0.00336176 0.00256822 0.56755621 128.828695
400 0.341 0.00319121 0.00273876 0.61961941 144.72583 0.001

440 0.325 0.0030307 0.00289928 0.67122712 161.322219 0

0 100 200
480 0.311 0.00289025 0.00303973 0.71867757 177.356227
520 0.297 0.0027498 0.00318018 0.7684922 195.028148

Orden 0
0.0035 250
f(x) = 5.79326371862487E-06 x + 0.000411316211878
0.003 R² = 0.966471873384075
200
0.0025 f(x) = 0.36856885318
150 R² = 0.998545060949
0.002

1/[ ]
x

0.0015 100
0.001
50
0.0005

0 0
0 100 200 300 400 500 600 0 100
Tiempo (seg)
 C vs T
0.007
Orden 1
0.006
0.9
0.005 f(x) = − 5.79326371862487E-06 x + 0.005518659711075
R² = 0.966471873384075 0.8
0.004 f(x) = 0.001437156201238 x + 0.044256952312642
0.7 R² = 0.994146950644843
0.003 0.6
0.5
0.002

ln
0.4
0.001 0.3
0 0.2
0 100 200 300 400 500 600
0.1
Tiempo (s) 0
0 100 200 300 400
Tiempo (seg)
Orden 2
250

200
f(x) = 0.368568853187139 x − 1.47280393405139
150 R² = 0.998545060949865
1/[ ]

100

50

0
0 100 200 300 400 500 600
Tiempo (seg)
 Orden 1

38 x + 0.044256952312642
3

00 300 400 500 600

Tiempo (seg)
Tiempo (s) Abs Conc. Calc. x ln 1/[ ]
0 0.42 0.00398375 0 0 0
Cv
60 0.374 0.00352227 0.00046148 0.12311705 32.8878244
0.0045
120 0.34 0.00318118 0.00080257 0.22497096 63.3288916
0.004
180 0.312 0.00290028 0.00108347 0.31741549 93.7742946
0.0035
240 0.287 0.00264948 0.00133427 0.40786032 126.412896 f(x) = − 2.90274115264083E-0
0.003 R² = 0.937911851587782

Concentracion
300 0.267 0.00244884 0.00153491 0.48661016 157.337336
0.0025
360 0.248 0.00225823 0.00172552 0.56764339 191.805517
0.002
420 0.233 0.00210774 0.001876 0.63660453 223.420848
0.0015
480 0.219 0.0019673 0.00201645 0.7055634 257.292191
0.001
540 0.206 0.00183688 0.00214687 0.77415569 293.382072
0.0005
600 0.194 0.00171649 0.00226726 0.84193996 331.56339
0
660 0.184 0.00161617 0.00236758 0.90216285 367.726226 0 100 200 300
720 0.174 0.00151585 0.0024679 0.96624627 408.675672 Ti
780 0.166 0.00143559 0.00254815 1.02064445 445.555927
840 0.157 0.0013453 0.00263844 1.08560235 492.305982

orden 0
0.003
f(x) = 2.90274115264083E-06 x + 0.000465573167469
0.0025 R² = 0.937911851587782
600
0.002
500
0.0015
f(x) = 0.577
x

400 R² = 0.9973
0.001

1/[ ]
300
0.0005
200
0
0 100 200 300 400 500 600 700 800 900
100
Tiempo (s)
0
0 100
 C vs T
0.0045
0.004
0.0035 Orden 1
f(x) = − 2.90274115264083E-06 x + 0.00351817482611
0.003 R² = 0.937911851587782 1.2
0.0025 f(x) = 0.001252678380516 x + 0.077910871224782
1 R² = 0.989813916558537
0.002
0.0015 0.8
0.001
0.6

ln
0.0005
0 0.4
0 100 200 300 400 500 600 700 800 900
Tiempo (s) 0.2

0
0 100 200 300 400 500 600
Tiempo (s)

Orden 2
600

500
f(x) = 0.577245222786099 x − 10.0783889848672
400 R² = 0.997386492057764
1/[ ]

300

200

100

0
0 100 200 300 400 500 600 700 800 900
Tiempo (s)
 Orden 1

380516 x + 0.077910871224782
58537

300 400 500 600 700 800 900

Tiempo (s)
Tiempo (s) Abs Conc. Calc. x ln 1/[ ]
0 0.384 0.00362259 0 0 0
80 0.349 0.00327147 0.00035112 0.1019508455 29.6276896
160 0.323 0.00301063 0.00061196 0.1850391758 56.1105312 0.004
240 0.296 0.00273977 0.00088283 0.2793168998 88.9490907 0.0035
320 0.271 0.00248896 0.00113363 0.3753230376 125.728062
0.003
400 0.25 0.00227829 0.0013443 0.4637644792 162.880167

Concentracion
0.0025
480 0.236 0.00213784 0.00148475 0.5273933892 191.716197
0.002
560 0.219 0.0019673 0.0016553 0.6105301951 232.266669
0.0015
640 0.19 0.00167636 0.00194623 0.7705624927 320.483608
0.001
720 0.177 0.00154595 0.00207665 0.851553186 370.807276
800 0.166 0.00143559 0.002187 0.9256112417 420.530404 0.0005

880 0.156 0.00133527 0.00228732 0.9980542029 472.865177 0

0 200
960 0.147 0.00124498 0.00237761 1.0680672361 527.17779
1040 0.138 0.0011547 0.0024679 1.1433536126 589.984123

Orden 1
0.003
1.4
0.0025 f(x)
1.2 R² =
f(x) = 0.001118592156175 x + 0.011226364075926
1 R² = 0.996640255268898 0.002

0.8 0.0015

x
ln

0.6 0.001
0.4
0.0005
0.2
0
0 0
0 200 400 600 800 1000 1200
Tiempo (s)
 C vs T
0.004
0.0035
0.003
Concentracion

0.0025
0.002
0.0015
0.001
0.0005
0
0 200 400 600 800 1000 1200
Tiempo (s)

Orden 0
0.003
Orden 2
700
0.0025 f(x) = 2.3426613514896E-06 x + 0.00026800045861
R² = 0.968549553810334 600
0.002 f(x) = 0.575644576260916 x − 42.9689807671631
500
R² = 0.981626425745598
0.0015 400
x

1/[ ]

0.001 300

0.0005 200

100
0
0 200 400 600 800 1000 1200
0
0 200 400 600 800
Tiempo (s)
Tiempo (s)
 Orden 2

44576260916 x − 42.9689807671631
6425745598

400 600 800 1000 1200

Tiempo (s)