Sec: Sr.

Inter/XII Completed/Target Batch/LT-Revision

DPA -23 DATE: 04-05-2020

MATHS TOPIC:PARABOLA
1. If m1 , m2 , m3 are slopes of normals  m1  m2  m3  drawn through the point  9, 6  to the parabola
y 2  4 x. A   aij  such that aij  1 for i  j , aij  mi for i  j and then det A 
33

1) 6 2) 4 3) 9 4) 8
2. If the line y  x  2 does not intersect any member of family of parabolas y 2  ax  a  R  at distinct
points, then maximum value of Latusrectum of parabola is
1) 4 2) 8 3) 32 4) 7
3. A circle with its centre at the focus of the parabola y 2  4ax and touching its directix intersects the
parabola at points A, B. Then AB  _____
1) a 2) 4a 3) 2a 4) 7a
4. The axis of a parabola y  x and vertex and focus are at a distance 2 and 2 2 respectively from the
origin. If the focus and vertex lie in the first quadrant then the equation of the parabola is
2 2
1)  x  y   8  x  y  2  2)  x  y   2  x  y  2 
2 2
3)  x  y   4  x  y  2  4)  x  y   2  x  y  2 

5. If the parabola y   a  b  x 2   b  c  x   c  a  touches the x-axis then the line ax  by  c  0 is always

passes through a fixed points is
1)  2, 1 2)  1, 2  3)  2, 2  4)  2,1

6. Minimum area of circle which touches the parabola y  x 2  1 and y 2  x  1

9 9 9 9
1) sq.units 2) sq.units 3) sq.units 4) sq.units
16 8 32 4
7. The locus of point of intersection of two normals drawn to the parabola y 2  4ax which are at right
angles is
1) y 2  2a  x  2a  2) y 2  a  x  3a  3) y 2  3a  x  3a  4) y 2  a  x  a 

8. If the normal to the parabola y 2  4ax at the point P  at12 , 2at1  cuts the parabola again at

Q  at22 , 2at2  , then the minimum value of t22 is

1) 2 2) 4 3) 8 4) 2 2

2
9. The equation of the common tangent touching the circle  x  3  y 2  9 and the parabola
y 2  4 x above the x-axis is
 1) 3 y  3 x  1 2) 3 y   x  3 3) 3 y    x  3 4) 3 y    3x  1
10. Locus of the point of intersection of perpendicular tangents drawn one each to the parabolas
y 2  4  x  1 , y 2  8  x  2  is
1) x  12  0 2) x  4  0 3) x  3  0 4) x  8  0
11. Equation of the common tangent to the parabolas y 2  32 x and x 2  108 y is
1) x  2 y  4  0 2) 2 x  3 y  36  0 3) 2 x  3 y  6  0 4) 2 x  3 y  6  0
12. The triangle formed by the tangent to the parabola y 2  4 x at the point whose abscissa lies in the
interval  a 2 , 4a 2  , the ordinate and the x-axis, has the greatest area equal to

1) 16a 3 2) 12a 3 3) 36a3 4) 20a 3

13. Minimum number of common normals of y 2  4ax and x 2  4by may be equal to
1) 2 2) 3 3) 4 4) 5
14. The number of distinct normals drawn to the parabola y 2  4 x from the point 8, 4 2 is  
1) 2 2) 3 3) 0 4) 1
15. A ray of a light moving parallel to the x-axis gets reflected from a parabolic mirror whose equation is
2
 y  2  4  x  1 . Then the point on the axis of the parabola through which the ray must pass after
reflection.
1)  1, 2  2)  0, 2  3)  2, 2  4)  0, 4 

16. The number of common chords of the parabolas x  y 2  6 y  11 and y  x 2  6 x  11 is

1) 1 2) 2 3) 4 4) 6
17. The locus of foot of the perpendicular drawn from the focus on any tangent is the tangent at the______
of the parabola
1) Focus 2) End of the latusrectum
3) Vertex 4) Directrix
2
18. The length of the double ordinate of the parabola  y  3  16  x  2  which is at a distance of 9 units
from  2,3 is
1) 36 2) 12 3) 18 4) 24
2
19. If the focus of the parabola y  4  x    always lies between the line x  y  1 and x  y  3 ,
then
1) 0      2 2) 1      2 3) 0      1 4) 1      1
20. The circle x 2  y 2  2 x  0,   R, touches the parabola y 2  4 x externally. Then
1)   1 2)   0 3)   0 4)   0
21. The co-ordinates of the point on the parabola y  x 2  7 x  2, which is nearest to the straight line
y  3x  3 are
1)  2, 8  2) 1,10  3)  2, 20  4)  1, 4 

2
22. If a  0, and the line 2bx  3cy  4d  0 passes through the points of intersection of the parabolas
y 2  4ax and x 2  4ay, then
2 2 2 2
1) d 2   3b  2c   0 2) d 2   3b  2c   0 3) d 2   2b  3c   0 4) d 2   2b  3c   0

23. The tangent at the vertex of a parabola whose directrix is x  y  2  0 and focus is  3, 4  is
1) 2 x  2 y  3  0 2) x  y  1  0 3) 2 x  2 y  1  0 4) x  y  2  0
24. The centroid of the triangle formed by joining the feet of the normals drawn from any point to the
parabola y 2  4ax, lies on
1) Axis 2) Directrix 3) Latus rectum 4) Tangent at vertex
25. The equation of the parabola with axis 3 x  4 y  4  0, the tangent at the vertex 4 x  3 y  7  0 and with
length of latusrectum 4 is
2 2
1)  3 x  4 y  4   5  4 x  3 y  7  2)  3 x  4 y  4   20  4 x  3 y  7 
2 2
3)  3 x  4 y  4   4  4 x  3 y  7  4)  3 x  4 y  4   10  4 x  3 y  7 

MATHS KEY

1) 4 2) 3 3) 2 4) 1 5) 4 6) 3 7) 2 8) 3 9) 2 10) 3

11) 2 12) 1 13) 4 14) 1 15) 2 16) 4 17) 3 18) 4 19) 1 20) 4

21) 1 22) 4 23) 3 24) 1 25) 2

MATHS SOLUTIONS:
1. y 2  4 x  4a  4  a  1
Equation of a normal to the parabola having a slope ‘m’ is y  mx  2am  am3
by data it passes through  9, 6 

m3  7m  6  0
 m  1 m  2  m  3  0
m  1, 2,3 m1  m2  m3
2  1  3
 m1 1 1
A   aij  1 m2 1
33  
 1 1 m3 
| A | 8
2. y  x  2  1 , y 2  ax   2 
2
Solving 1 2  :  x  2   ax
By data   0

3
 2
  4  a   4 1 4   0
0a8
a  8
 4a  4  8   32
3. When focus as the centre, then the focal chord is the latusrectum AB  LL '  4a
4.

N P

2
yx
Z A S M
 0,0 1,0

2 2

Z S
 A  Z  2A  S
2
Equation of a tangent at the vertex A 1,1 and slope ‘ 1 ’ is x  y  2  0

 PM 2  4a PN
2
 x y   x  y  2
  4 2
 11  11
2
 x  y   8  x  y  z 

5. y  0   a  b  x2  b  c  x   c  a   0
By data parabola touches the x-axis 2a  b  c  0 , i.e.,   0
 The line ax  by  c  0 always passes through a fixed point  2,1

6. Any point on y  x 2  1 is p  t , t 2  1

Any point on y 2  x  1 is Q  t 2  1, t 

PQ  2 | t 2  t  1|
d 1
For shortest distance,  PQ   0  t 
dt 2
3 2 3 2
Shortex distance  r 
2 8
9
 Area   r 2  sq.units
32
7. Slope of normals at t1 , t2 are t1 , t2
 m1m2  1  t1t2  1

  2

P. o I of normals  x, y   2a  a  t1  t2   t1t2 , at1t2  t1  t2  
y2
x  3a   y 2  a  x  3a 
a
4
8. Equation of normals at P  t1  is y  xt1  2at1  at13

Passes through Q  t2 

2at2  at22 t1  2at1  at13

2  t1  t1  t2 

t12  t2 .t1  2  0
0
 t22  8
1
9. y 2  4 x  1  y  mx    2
m
2
 x  3  y 2  9   3

By data  2  is a tangent to the circle  3

1
i.e., r  d  m  
3
1
y x 3
3
3 y    x  3
1
It will make an acute angle with x-axis, i.e., m  0
3
 Equation of common tangent is 3y  x  3
10. y 2  4  x  1 , y 2  8  x  2 

y 2  4a  x  a  , y 2  4b  x  b 
 Locus of P is x  a  b  0
x 1 2  0
x3 0
11. y 2  32 x, x 2  108 y
y 2  4ax, x 2  4by
a  8, b  27
1 1 2 2
 Equation of common tangent to the given parabolas is a x  b y  a b  0
3 3 3 3

2 x  3 y  36  0
1
12. Slope of a tangent of P is tan  
t
2t 1
  TM  2t 2
TM t
1
Area of a PTM   PM TM   2t 3 ,  a 2  t 2  4a 2 , a  t  2a
2
5
 Area will be maximum when “t” is maximum  t  29
 maximum Area = 16a 3
13. Equation of any normal to y 2  4ax is y  mx  2am  4m3  1

Equation of any normal to x 2  4by is x  m ' y  2bm ' bm '3   2 

The two parabolas will have common normal
If 1 2  represents the same
1 2
i.e., m  1
and  2am  am3  2b  bm1
m
 am5  2am3  2bm 2  b  0
Thus, is an equation of degree 5 and so pt can have maximum 5 roots
 Given the parabolas can have maximum 5 common normal
14. y2  4x
Equation of normal to y 2  4 x is y  xt  2t  t 3

Passes through 8, 4 2  
 t 3  6t  4 2  0
2
t  2  t  2 2   0
t has 3 values  2,  2, 2 2
 no of distinct normal  2
2
15.  y  2  4  x  1
2
y  4a  x   

Focus   a,     1  1, 2 
16. Clearly given parabolas are symmetrical about the line y  x
 They intersect each other at 4 distinct points
 No of common chords  4c2  6
a
17. Equation of tangent to y 2  4ax is y  mx   1
m
1
Equation of a line through s  a, 0  and perpendicular to 1 is y   x  a    2
m
1 a
 2  in 1   x  a   mx 
m m
 1
xm    0  x  0
 m
 Locus of P is x  0 which is tangent at vertex
18. Vertex of a parabola is  2,3
a  4, P  9
6
  length of double ordinate  4 ap   4 4  9   24
19. Focus    1,  

Clearly, focus must lie to the opposite side of the  0, 0  w.r.t x  y  1  0 and same side as  0, 0  w.r.t
x  y  3  0 . Hence,     0 and     2.
20. Centre of circle must be on negative x-axis. For that  must be positive as centre of circle is   , 0 

21. Any point on the parabola is  x, x 2  7 x  2 

3x   x 2  7 x  2   3
Its distance from the line y  3x  3 is given by P 
9 1

x2  4x  5

10
 as x 2
 4 x  5  0, x  R 

dp
 0  x  2 so requested point is  2, 8 
dx
22. P.O.I of y 2  4ax and x 2  4ay
We get  0, 0  and  4a, 4a 
Substituting in the given equation of line in the 2bx  3cy  4d  0
2
We get d  0 and 2b  3c  0  d 2   2b  3c   0
23.

S 3,4
Z A

x y2  0

Equation of directrix is x  y  2  0
Equation of latus rectum is x  y  1  0
1
Equation of a tangent at the vertex is x  y  0
2
2x  2 y 1  0
24. Let m1 , m2 , m3 are slope of normal meeting at  x, y 

 y  mx  2am  am3  am3   2a  x  m  y  0

m1  m2  m3  0

 a  m12  m22  m32  2a 

Centroid = 

,  m1  m2  m3  

3 3
 
 y co-ordinate  0
7
  centroid lies on x-axis
25. 4a  4  a  1
3x  4 y  4 4x  3 y  7
PM  , PN 
9  16 16  9
PM 2  4a PN
2
3x  4 y  4  4
 4x  3 y  7
25 5
2
  3 x  4 y  4   20  4 x  3 y  7 

8
 Sec: Sr. Inter/XII Completed/Target Batch/LT-Revision
DPA -23 DATE: 04-05-2020

PHYSICS-CURRENT ELECTRICITY
1. Suppose the colours on the resistor are brown, yellow, green and gold as read from left to right. Then
the resistance of the resistor is

1) 1.4  0.07  M  2) 1.4  0.02  M  3)  2.3  0.07  M  4)  2.3  0.02  M 

2. The current in a conductor varies with time ‘t’ as I  3t  4t 2 . Where I in amp and t in sec. the electric
charge flows through the section of the conductor between t  1 s and t  3s
100 127 140 150
1) C 2) C 3) C 4) C
3 4 3 3
3. In a straight conductor of uniform cross section charge q is flowing for time t. let s be the specific
charge of an electron. The momentum of all the free electrons per unit length of the conductor, due to
their drift velocity only is
2
q q q
1) 2)   3) 4) qts
ts  ts  ts

4. A rod of length L and cross-section area A lies along the x-axis between x  0 and x  L. The material
obeys Ohm’s law and its resistivity varies along the rod according to   x    0 e  x / L . Find the total

resistance of the rod. The end of the rod at x  0 is at a potential V0 and it is zero at x  L.

x0 x L

0 L  1  0 L 0 L  1  0 L
1)   2) e 3) 1   4)  e  1
A e A A  e A

5. Three ammeters P,Q and R with internal resistance r, 1.5r, 3r respectively. Q and R parallel and this
combination is in series with P, the whole combination connected between X and Y. When the battery
connected between X and Y, the ratio of the readings of P,Q and R is
1) 2 : 1 : 1 2) 3 : 2 : 1 3) 3 : 1 : 2 4) 1 : 1 : 1
6. The potential difference between the points A and B is
9
 1) 1.50 V 2) 2.50 V 3) 1.00 V 4) 0.50 V
7. ABCD is a square where each side is a uniform wire of resistance 1 . A point E lies on CD such that if
a uniform wire of resistance 1 is connected across AE and constant potential difference is applied
across A and C, if B and E are equipotential then
A B

D E C
CE CE 1 CE 1 CE
1) 1 2)  3)  4)  2
ED ED 2 ED 2 ED
8. In the circuit shown in figure, the potentials for B,C and D are:

1) VB  6V ;VC  9V ;VD  11V 2) VB  11V ;VC  9V ;VD  6V

3) VB  9V ;VC  11V ;VD  6V 4) VB  9V ;VC  6V ;VD  11V
9. A heater coil rated at 1000W is connected to a 110V mains. How much time will take to melt 625gm of
ice at 00 C. (for ice L  80 cal/gm)
1) 100s 2) 150s 3) 200s 4) 210s

10
10. In a experiment for calibration of voltmeter a standard cell of emf 1.5V is balanced at 300 cm length of
potentiometer wire. The P.D across a resistance in the circuit is balanced at 1.25m. If a voltmeter is
connected across the same resistance it reads 0.65V. The error in the volt meter is
1) 0.5V 2) 0.025V 3) 0.05V 4) 0.25V
11. Two wires ‘A’ and ‘B’ of the same material have their lengths in the ratio 1:2 and radii in the ratio 2:1.
The two wires are connected in parallel across a battery. The ratio of the heat production in ‘A’ to the
heat produced in ‘B’ for the same time is
1) 1 : 2 2) 2 : 1 3) 1 : 8 4) 8 : 1
12. Three bulbs with their power and working voltage are connected as shown in the circuit diagram to a
12V battery. The total power consumed by the bulbs is (ignore the internal resistance of the battery
shown)

1) 24 W 2) 12 W 3) 6 W 4) 15 W
13. When a conducting wire is connected in the right gap and known resistance in the left gap, the
balancing length is 60 cm. the balancing length becomes 42.4 cm when the ire is stretched so that its
length increases by
1) 10% 2) 20% 3) 25% 4) 42.7%
14. When ‘n’ wires which are identical are connected in series, the effective resistance exceeds that when
they are in parallel by X/Y  . Then the resistance of each wire is
xn yn xn yn
1) 2) 3) 4)
y  n 2  1 x  n2  1 y  n  1 x  n  1

15. If in the circuit shown below, the internal resistance of the battery is 1 and VP and VQ are the potentials
at P and Q respectively, the potential difference between the points P and Q is

11
 1) 9 V 2) 11 V 3) 7 V 4) 6 V
16. A cell develops the same power across two resistances R1 and R2 separately. The internal resistance of
the cell is
1) R1R2 2) 2R1R2 3) R1  R2 4) R1  R2
17. For a cell, the graph between the p.d. (V) across the terminals of the cell and the current I drawn from
the cell is shown in the fig. the emf and the internal resistance of the cell is E and r respectively.

V(Volt)
2

O
I(in amp) 5

1) E  2V , r  0.5 2) E  2V , r  0.4 3) E  2V , r  0.5 4) E  2V , r  0.4

18. In the following circuit, 5 resistor develops 45J/s due to current flowing through it. The power
developed across 12 resistor is

1) 16 W 2) 192 W 3) 36 W 4) 64 W
12
19. The charge flowing through a resistance R varies with time t as Q  at  bt 2 . The total heat produced in
R is
a3 R a3 R a3 R a3 R
1) 2) 3) 4)
6b 3b 2b b

20. The cross-section area and length of cylindrical conductor are A and  respectively. the specific

conductivity varies as   x    0 , where x is the distance along the axis of the cylinder from one of
x
its ends. Compute the resistance of the system along the cylindrical axis
3  2 2  
1) 2) 3) 4)
2 A 0 3A 0 3A 0 A 0
21. Equivalent resistance between A and B in Fig. is

1) 8r/7 2) 7r/8 3) 3r/4 4) r

22. The plot represents the flow of current through a wire at three different times. The ratio of charges
flowing through the wire at different times is

1) 2 : 1 : 2 2) 1 : 3 : 3 3) 1 : 1 : 1 4) 2 : 3 : 4
23. Figure shows a circuit that may be used to compare the resistance R of an unknown resistor with a
100 standard. The distance l from one end of the potentiometer slider wire to the balance point are
400mm and 588 mm when X is connected to Y and Z, respectively. The length of the slide wire is
1.00m. What is the value of resistance R?

13
 1) 32 2) 47 3) 68 4) 147
24. What resistor should be connected in parallel with the 20  resistor in branch ADC in the circuit shown
in fig. So that potential difference between B and D may be zero?

1) 20  2) 10 3) 5 4) 5
25. For the circuit shown in Fig, the equivalent resistance between A and C is

12 13 14 15
1) r 2) r 3) r 4) r
11 11 11 11

14
 PHYSICS KEY

1) 1 2) 3 3) 1 4) 3 5) 2 6) 4 7) 4 8) 2 9) 4 10) 2
11) 4 12) 3 13) 4 14) 1 15) 1 16) 1 17) 2 18) 2 19) 1 20) 3
21) 2 22) 3 23) 2 24) 1 25) 4

PHYSICS SOLUTIONS:
1.
Brown Yellow Green Gold

1 Brown Green Gold

4 Yellow x105 +5%

 5 
14 105  1  
 100 
 1.4  0.07 106   1.4  0.07  M 
Some times tolerance is missing from the code and there are only three bands. Then the tolerance is
20%.
t2

2. q   I .dt
t1

I q /t
3. I  nAevd or vd  
nAe nAe
No of free electrons per unit length of conductor N  nA  1
 Momentum of all the free electrons is p  Nmvd
 dx 0e  x / L dx
4. dR  
A a
0 L  X / L
Rtotal  e dx
A 0
L
   XL  0 L  1 
 0 e    L   1
a  0 A  e 
V
5. i
R
6.

15
 For the first loop 12  5i  i1
For the second loop 0  7  i  i1   i1

Or 8i1  7i or , i1   7 / 8  i
7 47i
Therefore, we obtain 12  5i  i 
8 8
12  8
Or, i  A  2.04 A
47
7
i1   2.04 A  1.79 A
8
Thus, the p.d across A and B is
VA  VB   i  i1   2  0.25  2  0.50V
7.
1
A B

1 1 1

C
D x E 1x 

Equivalent resistance between A and E is y 

 x  1
x2
RAE REC x 1 1 x
For B and E to be at equal potential, we get   
RAB RBC  x  2 1 1
Solving x  2  1
CE 1  x
Now   2
ED x
8. Potential at O is zero being earthed. Applying Kirchhoff’s second law
i 1  2  3  12  6 or i  1A

VA  VD  1  2  3  1  6V

16
 VA  VB  1 1  1V
VA  VC  1  2   1  3V
Also, VA  VO  12V or VA  12V
Thus, VD  12  6  6V ,
VB  12  1  11V ,VC  12  3  9V
9. JQ  P  t
J  mL  P  t
80  4.2
1 625 103   1000  t
103
t  210 s
V1 I1
10.   V2  0.625V
V2 I 2
 Error  0.65  0.625  0.025
V2
11. Q 
R
Q1 R2 l2 r12
  
Q2 R1 l1 r22
2
Q1 2  2  8
  2 
Q2 1 1 1
V2
12. P
R
X 60 X 42.4
13.  ;  ;
R 40 R ' 57.6
R ' 60 57.6
 
R 40 42.4
R l 2
l1  l  R1  R 
 100     100
l  R 
 
X
14. Rs  R p   
Y 
V
15. i 
R
2
2  E 
16. P1  i R1    R1
 R1  r 
2
2  E 
P2  i R2    R2
R
 2  r 
17. V  E  ir
17
 i  0,V  E  2V
E
V  0, r   0.4
i
18. P  i 2 R  192W
19. Q  at  bt 2 or i  dQ / dt  a  2bt
t0
i  0 for t  t0  a / 2b, i.e., current flows from t  0 to t  t0 . the heat produced is  i 2 R dt  a3 R / 6b.
0

20. Resistance of thin elementary disc is

 dx 1 dx x dx
dR   
A  A  01 A
1
1 1/ 2 1 l 3/ 2 2 l
 0 IA 0
Rtotal  x dx  
 0 IA 3 / 2 3 A 0

21. The figure can be redrawn as shown. Connect a battery beween A and B. Now Req  V / I .

I  2 I1
In ACEA, I1r  r   I  2 I1  r or 3I  8 I1
2
1 3 I 7r
In FACBGF ,V  I1r  r  Ir  r  I
2 8 2 8
V 7r
Or Req  
I 8
22. Charge  area under the current – time graph
1
q1  2  1  2, q2  1 2  2, and q3   2  2  2
2
18
 q1 : q2 : q3  2 : 2 : 2  1:1:1
23. When X is connected to Y, the balance length l is proportional to the potential difference across the
100 resistor. When X is connected to Z, the balance length is proportional to the potential difference
across the 100 resistor and resistor R.
100  R 588
 or R  47
100 400

24.
 20R  /  20  R   20 or R  20
5 10
25. At junction E or F:
I1  I3  I 4  I 2  I 3 or I1  I 2  2 I 3  I 4  0
Loop AFBA or loop ECDE:
rI1  rI 2  rI3 or I1  I 2  I3

Loop BEFB or loop EDFE:

r  I 2  I 3   rI 4  rI 3 or I 2  2 I 3  I 4  0
Loop AFDCMA or ABECMA:
V  rI1  r  I 2  I 3   rI 2  rI1  2rI 2  rI 3
Solve to get I1  2V / 5r , I 2  V / 3r
V V V 15r
Req     .
I I1  I 2 2V / 5r  V / 3r 11

19
 Sec: Sr. Inter/XII Completed/Target Batch/LT-Revision
DPA -23 DATE: 04-05-2020

CHEMISTRY-15TH GROUP & 16TH GROUP

1. List-1 List-2
A) Phosphorite 1) KNO3
B)Bengal salt petre 2) Ba  NO3 2
C) Flourapatite 3) NaNO3
D)Chile salt petre 4) 3Ca3  PO4  2 CaF2

5) Ca3  PO4 2
The correct match is
A B C D A B C D

1) 1 2 3 5 2) 2 4 3 1

3) 4 3 5 2 4) 5 1 4 3

2. NO2 can’t be obtained by heating

1) KNO3 2) Pb  NO3  2 3) Cu  NO3  2 4) Hg  NO3  2
3. How do we get pure N 2 gas
1) NH 3  NaNO2 2) NH 4 Cl  NaNO2 3) N 2O  Cu 4) Ba  N 3  2
4. Silver chloride dissolves in excess of NH 4OH .The cation present in solution is
  
1) Ag  2)  Ag  NH 3  4  3)  Ag  NH 3  2  4)  Ag  NH 3 6 

5. Undustrically O2 is ob tained by

1)Fractional distillation of air 

2) KClO3 

3) Ag 2O  4)Electrolysis of H 2O
6. Moles of oxygen that can oxidise one mole of NH 3 to NO
1)1 2)1.25 3)2.5 4)5

20
7. The reaction of white phosphorous with Aq NaOH gives phosphine and another phosphorous
containing compound. The reaction type, the oxidation state of phosphorous in phosphine and other
products are respectively.
1)redox reaction, -3 and -5 2)redox reaction, +3 and +5
3)disproportion reaction -3 and +1 4) disproportion reaction -3 and +3
8. The hybrization of atomic orbitals of Nitrogen in NO2 , NO3 and NH 4 are
1) Sp, Sp3 and Sp 2 respectively 2) Sp, Sp 2 and Sp 3 respectively
3) Sp 2 , Sp and Sp 3 respectively 4) Sp 2 , Sp 3 and Sp respectively
9. Phosphate + Con HNO3   NH 4  2 M 0O4 solution  Yellow precipitate
The composition of yellow precipitate is
1)  NH 4 3 PO4 .M 0O3 2)  NH 4 3 PO4 .12M 0O3

3)  NH 4  2 PO4 .12M 0O3 4)  NH 4  2 PO4 .M 0 O3

10. The statements regarding oxy acids of phosphorous are
I) HPO3 molecule of monobasic Acid
II) H 4 P2 O6 molecule has P  P bond
III) H 4 P2 O7 molecule has P  O  P linkage
The correct combination is
1)All are correct 2)Only II is correct 3)II & III are correct 4)I & II are correct
11. The total number of  and  bonds in purophosphoric Acid are respectively.
1)8,2 2)10,2 3)12,2 4)8,4
 
12. In solid state PCl5 exists as ionic solid i.e  X  Y  , shapes of X  and Y  are respectively.
1)Tetrahedral, pyramidal 2) Tetrahedral, octahedral
3)octahedral, Linear 4)octahedral, trigonal bipyramidal
13. In which of the following acids P-P bond is present
1)Tetrapolyphosphoric Acid 2)Pyrophosphoric Acid
3)Hypo Phosphoric Acid 4)Poly metaphosphoric Acid
  A 
14. For NH 4 Cl  NaNO3  Cu  B  X . Which of the following is correct ?
gas

1) ' B ' is anamphoteric oxide

2) ' X ' is an colourless, diamagnetic gas which combines with Al on heating.
3) ' X ' can be produced by action of  Zn  NaOH  on NaNO2
4) ' X ' is a coloured, Paramagnetic gas combines with ' Al ' on heating
15. The bottles of liquid NH 3 are opened after cooling then in ice for sametime. If is because Liq NH 3 .
1)High vapour pressure at RT 2)Is corrosive Liquid
3)Is an explosive 4)Brings trars in eyes

21
16. Which of the following statements regarding Sulphur is incorrect ?
1) S 2 molecule is paramagnetic
2)The vapour at 2000 C consist molecules S8 rings
3)At 6000 C , the gas mainly consist of S 2 molecules
4)The oxidation state of Sulphur is never less than +4 its compounds
17. The correct order of the O-O bond length in O2 , H 2O2 and O3 is
1) O2  O3  H 2O2 2) O2  H 2O2  O3 3) O3  H 2O2  O2 4) H 2O2  O3  O2
18. The statements regarding hydrides of VI A group elements are
I) The order of volatility H 2O  H 2Te  H 2 Se  H 2 S
II) The order of B.P H 2O  H 2Te  H 2 Se  H 2 S
III) The order of Bond Angles H 2O  H 2 S  H 2 Se  H 2Te
The correct combination is
1)All are correct 2)Only I is correct 3)II & III are correct 4)I & III are correct
19. SF6 is exceptionally stable due to
1) S  F bond is strong 2)Steric reasons
3) Unsymmetrical geometry 4) Exothermic compoundo
20. What are the products formed when moist chlorine gas is reacted with Hypo ?
1) Na2 SO4 , S , HCl 2) Na2 SO3 , S , HCl 3) Na2 S 4O6 , Na2 SO3 , HCl 4) Na2 S 4O6 , NaCl , HCl
21. Which of the following has no S  S bond.
1) H 2 S2 O4 2) H 2 S2 O5 3) H 2 S2 O6 4) H 2 S2 O7
22. The Oxidation states of Sulphur in the anionis follow the order
1) S 2O42  SO32  S 2O62 2) S 2O42  S 2O32  S2O62
3) S 2O42  S2O62  SO32 4) S 2O62  S2 O42  SO32
23. Which of the following is incorrect match.
1)Stability H 2O  H 2 S  H 2 Se  H 2Te 2)Bond Enthalpy H 2O  H 2 S  H 2 Se  H 2Te
3) K a H 2O  H 2 S  H 2 Se  H 2Te 4) B.P H 2 S  H 2 Se  H 2Te  H 2O
24. In correct match is
1) H 2 S2 O7 a) S  O  S linkage
2) H 2 SO5 b) O  O linkage
3) H 2 S 2O3 c) S  S linkage
4) H 2 S x  2 O6 d) S  O  S linkage
25. Which one of the following reactions does not occur
1) BaO  O3  BaO2  O2 2) PbS  4O3  PbSO4  4O2
3) H 2O2  O3  H 2O  2O2 4) 2Hg  O3  Hg 2O  O2

22
26. Which reaction produce SO2
 
1) 2 Na2 S5  3O2 
air
 2) 2 Na2 SO3  S 
( Excess )

3) 2 Na2 SO3  2 HCl  4) 2Na2 SO3  Cl2  H 2O 

27. Which of the following is not oxidized by O3 ?
1) KI 2) FeSO4 3) KMnO4 4) K 2 MnO4
28.  X   H 2 SO4  Y  ( a colourles gas with irritating smell )

Y   K 2Cr2O7  H 2 SO4  Green solution. X and Y are

1) SO32 , SO2 2) Cl  , HCl 3) S 2 , H 2 S 4) CO32 , CO2

29. Which of the following contains P  d  bonds.
1) NO2 2) SO3 3) SO2 4)Both 2 & 3
30. Electron affinity order of chalcogens is
1) S  Se  Te  O 2) O  S  Se  Te  Po
3) S  O  Se  Te  Po 4) O  Po  Te  Se  S

KEYSHEET
1 2 3 4 5 6 7 8 9 10
4 1 4 3 1 2 3 2 2 1
11 12 13 14 15 16 17 18 19 20
3 2 3 2 1 4 4 1 2 1
21 22 23 24 25 26 27 28 29 30
4 1 3 4 1 3 3 1 4 1

1. Conceptual
2. 4 KNO3  2 K 2O  2 N 2  5O2
S S  g g

3. Ba  N 3 2  Ba  3 N 2
Very pure nitrogen can be obtained by the axemmal decomposition of sodium (or) baxium acidc
4. AgCl s   2 NH 4OH   Ag  NH 3  2  Cl  2 H 2O
White ppt  aq  Colurler

5. 2,3,4 are laboratory methods

Liquidair F
ractional Distillation
 liqN2 liqO2
 liqN2 liqO2  More volatile (remains in
(Easily escape) the solution)
Pt
6. 4 NH 3  5O2   4 NO  6 H 2O


23
 5 mole of O2  1 mole of NO
5
mole of O2  1 mole of NO
4
i.e, 1.25mole of O2 that can oxide
1 mole of NH 3 to NO
7. P4  3NaOH  3H 2  PH 3  3 NaH 2 PO2
O 3 1

Here ‘p’ changes from O to -3 (Reduction)

O to +1 (Oridation)
Hence, it is disproportion.
1
8. No of Hybid orbitals  V  M  C  A
2
1 4
NO2  5  1   2  sp
2 2
1 6
NO3  5  1   3  sp 2
2 2
1 8
NH 4  5  4  1   4  sp 3
2 2
9. PO43  Con HNO3   NH 4 2 MoO4   NH 4 3 PO4 .12MoO3
It is test for ‘p’
10.
O O O O O

O POH HOPPOH OHPOPOH

| | | |
OHOH OH O H
Acid Hypo phosphoric acid Peroxy phosphoric acid
11.
O O

HOPOPOH 12
| |
H O O H 2
 
12. PCl5 in solid state exist as  PCl4   PCl6 
sp 3 sp3 d 2
Tetrahedral Octahedral

13.

24
 O O O O O

O POH HOPPOH OHPOPOH

| | | |
OHOH OH O H
Acid Hypo phosphoric acid Peroxy phosphoric acid

Cu
14. NH 4Cl  NaNO3  N 2O   CuO  N 2
 A  B X 

N 2  Al   AlN
15. Conceptual
16. ‘S’ can exhibit 2, 2, 4, 6 in its compounds
In H 2 S O.S of S  2
SCl2 O.S of S  2
17. Bond order of O2 O3 O22
  
2 1.5 1

1
Bond order 
Bond length
18. Conceptual
19. Due to Steric reasons
20. Na2 S 2O3  Cl2  H 2 O  S  HCl  Na2 SO4
21.
O O O O O O O O

HOS S OH HOS S OH HOS S OH HOS OS OH

O OHOH OH OH
Dithionous acid Pyrosulphurous acid Dithionic acid Disulphuric acid
 AS
2 2O4 H2S2O5  H2S2O6   H2S2O7 
22.
O O O O
 
 
OS S O SO32 OS S O
+3 +3 x62
x4
O O

+5 +5

 order is S 2O42  SO32  S 2O62

25
23. H 2O  H 2 S  H 2 Se  H 2Te  Ka order
24.
O O

HOS  S x S OH

O O
25. BaO2  O3  BaO  2O2
26. Na2 S 2O3  2 HCl  2 NaCl  SO2  S  H 2O
27. O3 oridises Manganate into permanganate
2 K 2 MnO4  H 2 O  O3  2 KMnO4  2 KOH  O2
28. x  SO32 , y  SO2
K 2Cr2O7  3SO2  H 2 SO4  K 2 SO4  Cr  SO4 3  H 2O
Chromic sulphate (green)
29.
O

S S

O O O
O
It has one P  P It has one P  P
Two p  d  bonds one p  d 
30. Conceptual

26