Sri Chaitanya IIT Academy 28-04-16_ Sr.

IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s

Sri Chaitanya IIT Academy, India

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR-HYD
Sec: Sr.IPLCO_IC_ISB_LIIT JEE–ADVANCE Date: 28-04-16
Time: 3 Hours 2011-P1-Model Max Marks: 240
PAPER-I
KEY & SOLUTIONS
CHEMISTRY
1 B 2 A 3 B 4 A 5 D 6 D

7 D 8 ABCD 9 ABCD 10 AD 11 ABCD 12 A

13 B 14 D 15 D 16 D 17 2 18 4

19 6 20 6 21 2 22 1 23 2

PHYSICS
24 C 25 A 26 C 27 A 28 D 29 C

30 B 31 AC 32 AC 33 BC 34 AC 35 C

36 B 37 A 38 D 39 B 40 1 41 5

42 4 43 6 44 8 45 5 46 3

MATHS

47 A 48 B 49 B 50 C 51 A 52 A

53 D 54 ABC 55 ABCD 56 ABC 57 ABD 58 C

59 B 60 B 61 C 62 C 63 8 64 1

65 3 66 6 67 9 68 1 69 2

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s

SOLUTIONS
CHEMISTRY
1. conceptual
2. Cl  is weaker ligand then H 2O
3. Na2 CO3  NO  NO2  2 NaNO2  CO2
4. conceptual
5. Weight of S8 in simple=160g
160
Moles of S8   0.625
32  8
Number of moles of O2 required  0.625  8
Volume of O2 required at STP  22.4  5
 Volume of air required at STP
100
 22.4  5   533.33 L
21
6. Gases deviates from ideal behavior at high pressure and low temperature.

7. For H 2  g   O2  g   H 2 O2  l 
 r H 20  r H10
 f H 0  H 2O2 , l    r H 30  
2 2
8. The rate of diffusion of H 2 is
more than D2 .( B) since the D-D bond
energy is more its activation energy with halogen is also more(.C)
H-H and D-D bond lengths are equal as their atomic sizes are
same. (D) Heat of fusion of D2 is mole than that of H 2
9. A) For solution Z 2 at P1 pressure
X A  0.25 X B  0.75
YA  0.5 YB  0.5
B) For solution Z2 at P3 pressure  solution will not vapourise so
X A  0.4; X B  0.6
C) For solution Z1 at P2 pressure  solution will not vapourise so
X A  0.2; X B  0.8
10. A) Fact
B) Probability of finding an electron is nearly 90% in an orbital
C) No of angular nodes are l
D) For 1s ψ 2 is maximum at nucleus
11. Conceptual
12. Conceptual
13. Conceptual
14. For ‘Q’ using steady state concept
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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
Rate of appereance of Q= Rate of disappeareance of Q
K1  P   K 2  Q 
Number of nuclei of Q
k1
  no.of nuclei of P
k2
10 / 60
  6 10 23  10 20
1000
For ‘R’
Since rate constant is very high for second step than first step
Number of nuclei of R= Number of nuclei of P disintegrated  6 1023
15. 6 PCl5  P4O10  10 POCl3
2 POCl3  3H 2O  2H 3 PO4  6 HCl
in one phosphorus and three oxygen atoms are involved in
H 3 PO4
sp 3
hybridization.
16. SO2  PCl5  SOCl2  POCl3
C2 H 5OH  PCl5  C2 H 5Cl  HCl  POCl3
H 2 SO4  2 PCl5  SO2Cl2  2 HCl  2 POCl3
G.l 2 K .V
17. m  
n n
1 400
  2 Scm 2 mol 1
100 2
18. i) It is enthalpy of hydration
ii) For atomization coefficient of NH 3 should be one
iii) Products should be in gaseous ionic form
iv) H r0  3 / 2  P P H 0
19. Conceptual
20. Conceptual
21. At freezing point vapour pressure of solid = vapour pressure if liquid.
300 200
10   5
T T
100
5
T
T=200 K
22. Let heat involved in step 5 is Q5
qtotal  Wtotal
500  800  Q5  700
Q5  600 J
Since S total=0
500 800 600
  0
200 200 T5
2  4  6  0.
T5  100 K

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
23. Conceptual

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
PHYSICS
 a a
24. rcm  iˆ  ˆj (considering A to be origin AD to x-axis and AB to be y-axis)
2 2
   a a 
Li  mrcm  vcm  m  iˆ  ˆj   v0 (2iˆ  4 ˆj )
2 2 
= mav0 (2kˆ  kˆ)  av0 kˆ
m a2   ma 2 ma 2 
L f   (a 2  a 2 )  m      
 6 2 
12 2  
From conservation of angular momentum about point A
Li  L f
2
ma 2   mav0
3
3v
  0
2a
a 3v0 a 3v
vcm    0
2 2a 2 2 2
mv R1 B2 1
25. R= ;  
qB R2 B1 2
R1 R
R2 sin  = R1 sin 300 sin   sin 300  1
R2 2 R2
1
sin  
4

26. Ray is emerging from hemisphere at 0o, ray OC should be incident on curved surface
radially means OC is coming from centre of hemisphere i.e., AO = R
60o
P A
30o
r
O

Applying snell’s law at P C

Sin60o = 3 sin r  r = 30o

So POA = 90o

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
2R
 PA =
3
hc hc
27. cutoff = , for Kk=
eV EK  EL
hc 3hc eV 21 
   E K  E L = 13.6  Z  1   1
EK  E L eV 3 4 
2
V 13.6  Z  1  3

3 4
4  13.6 10 3
 Z  1 2 =
9 13.6
Z = 22.

AS 2R B
28. AI1 = =  R/2
 4
3
3 S A
focal length of lens I1 I
1 1 1
 1.5  1  
fl R R

fl = R, focal length of mirror

fm = R/2
i.e., I1 is at focus of lens, so rays coming from I1 gets parallel after passing through
lens and they are again reflected by mirror which forms image at optical centre of lens
(focus of mirror)
so distance between object & image
2 R R 7R
=  = .
3 2 6
Pitch 1 mm
29. Least count = =  0.01 mm  0.001 cm
Number of divisions on circular scale 100
Zero error = – 0.03 mm
Measurement = 3.76 – (– 0.03) = 3.79 mm

v x cos 300  v y cos 600  vB cos 300 vX

30.
vY
vx 3  v y  12 … (i) vA vB

v y cos 300  v x cos 600  v A cos 600

v y 3  vx  8 … (ii)
Solving (i) and (ii), we get
v x  3 3  2m/s and v y  3  2 3 m/s
 vC  v x2  v y2  2 13 m/s
31. λmT = constt. E  T4
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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s

yb
32. x 
d
b
.b b2
x  2 =
d 2d

If certain wavelength are missing then they are making minima.

 1
x   n    for minima
 2

b2 3 b2
n = 1,  , 
2d 2 3d

b2  b2
n = 0,  , 
2d 2 d
dv
33. E
dx

Direction of electric field is from high potential to low potential

 in slab direction of electric field is downward (same as other two region so v will
increase.
mv p 2km
34. r  
qB qB qB

m  2k 
rH   A  A  
q  B 

1
= AA
1
rHe  2A

4
r0  A  2A
2
H+ will be deflected most because rH is shorter than rHe & r0 
 

+ ++
 rHe  r01 He and O will be deflected equally.

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
35. Velocity after collision O
 2  2 4  g  
v '  v cos  =  2 g · =
 3 3  3 

 3  
2/3 

v'

v
LOI
36. Impulse J = p of the ball along the thread O
= p f  pi

= 0  mv ' sin  l
2/3 l
4 gl 4 v' cos 
= m 1
3 3 9 
54 4 5
= m gl = m gl
3 3 3 9 3 v' sin 
1
37. m ( v ' cos ) 2  mg h
2
v'2 cos 2  16 g l 4 32l
h     .
2g 27 2  g 9 243
38. Applying Kirchoff’s Loop Law,
q0
  0    iR  0
C1
2  106
  4  2i  0
10 6
i  3A
39. Let final charge on C2 is q then by Kirchhoff’s loop law at steady state,
(q 0  q) q
  0
C1 C2

2  q  10 6  2  106 q  4  0  q  2  10 6 C
Wb  U  Q

1  4  1012  1  4  10 12 
2 106  4      + Q
2  0.5  10 6  2  106 

8  106  2  106  Q
Q  6  106 J  6 J

40. CONCEPTUAL
µ m1m2
41. T = 2 µ=  1.2 kg
k m1  m2
2 k 3 1000
     5 10
T µ 1.2 4

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
2 2
T=  = 0.4 s
5 10 5
 n = 5 oscillations in 2 sec
42. PT–n = constant
P (Pv)–n = const
n

PV  const
1 n

R  R 5R R
C = CV +   Solve to get n = 4.
1 x 2 2 1 n
1 n
3
 4S   4 3  P 4S  4  4  5R 
43.  P0    R    0    
 R  3   2 5R  3  4 
4 S 125 P0 25 S 96 S 16 nS
 P0     P0  
R 128 4R R R
 n=6
Q02 Q02 1 C
44. W  U f  Ui   ,   C' 
2C ' 2C C 9
9Q02 Q02
   9E  E  8E
2C 2C
 n8
50 5 XL
45. Peak current through R1 , I1   A
10 2 2
Peak current through R 2 450 R
50 5 450
I2   A
10 2 2

Phase difference between I1 and I2 is XC
2
 Peak current through the source is R1 = R2 = XL = XC

2 2
 5   5  5
I I12  I2 2
       2
 2  2 2
 I5 A
46. Applying energy conservation
2 2
1 a 1 a 1 1
k    2k    mv12  Mv 22 …(i)
2  2 2 2 2 2
By law of conservation of momentum
– mv1 + Mv2 = 0
v1 = 4v2 …(ii)
1  a2  ka 2 1 2 1
k    v1   4v22
2  4  4 2 2
2
3ka
v22 
80
v2 = 3 m/s.

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MATHS
A  ,      a  b 2 
47.   a  1  b    
B   ,      a  b 2 

Equation of AB : x  y        0 Solve with parabola
2
And using 0   a  1  4b       0
2
  a  1  4  a  1  0
  a  1 a  3  0
 a  1 or  a  3
    3
48.    
y 2  8 x  2 x 2 y  3x 2  6 x  0 in quadrate. But y  N
2
  4 x 2  x  4  4.3 x  x  2
 2
 
 4 x x  x  4  3 x  2  4 x x 3  8 x 2  13 x  6 
2 2
 4 x  x  1  x  6  4  x  1 x  x  6  x  x  6 must be perfect square

 x2  6 x  t 2
2
  x  3   9  t 2   x  t  3 x  t  3   9
Minimum value of x is 6
49. Given f  5  x   f  5  x   f '  5  x   f '  5  x   0
 G .I  0
50. f 1  x  3x 2  1  0  f is increasing  f  x  x
 x 3  27  0
  x  3  0  x  3
3
 a  3 and G.I=  f  x  dx  27  6  2.34
3
No of divisors = (1+1) (4+1)=10
51. conceptual
f    f    f    4 f   f   
52.     4    
    
f  x 2
Put   x and  1    4 1  x 
x 1
1
2  4 x3  4 5
f  x   6x  4x GI   3x 2    3 
 3 0 3 3
53. W  z  iz 2  z  iz 2

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Sri Chaitanya IIT Academy 28-04-16_ Sr.IPLCO_IC_ISB_LIIT _JEE-ADV_(2011_P1)_GTA-7_Key&Sol’s
2
Which is maximum when arg(z), arg(iz ) are equal
 1
 z  i  amp  Z     G.E  
2 2
 x  
2
2
 4  4e 2b2
   ab and  x  1  b 1  a 2   1 possesses equal roots  b 2e2  1
2
54.

 e2 x 2  2 x  b 2  0   a2 1  e2 e2  1  
2 2 2 2
   a b
2
 1  1 2
  . 2 2  2
 4
 e 1 e  e  e 1  e2   
d 2 2 2
de
 
  0  4e3  6e 5  0  e 2   e 
3 3
3 9 3 3
 b2  a 2   ab 
2 2 2
55. conceptual
56. conceptual
57. conceptual
 a b c
58 to 60 Let , substitute and solving we get
M  d e f
 
g h i
 b  1  a  b  1 
 e    2  &  d  e    1   a  0, d  3, g  2 Also
       
 h  3   g  h  1
 a + b + c  0   0 1 1 
 d + e + f    0   C  1, f  5, i  7  M   3 2 5 
     
 g + h + i   12  
2 3 7 
1 1 1
Rank of M=3
M  I  3 1 5
tr (adjM)=30
2 3 6
=14  0
4
61&62 n(A) coeff of x11 in  x1 +x 2  x1  x2  ....  x6 
4
 1  x6  2
 x 1  x  
5

 1 x    1  x
 x 3 1  x  1  x 6  4

  x  x 1  4 x 1  4c x  5c x  ... 

5 6 6
1 2
2

  x  x  4 x 1  4c x  5C x  ... 
5 6 11
1 2
2

9c3  8c3  4  1  84  56  4  136

 B  84 21
p   
 A  136 34
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 E  2  4  3!    5  4 p1 
P 2  
 E1  2  5 p4
48  40 88 11 11
   
2  120 2  120 2  15 30
0
18
1  cos 10r  18 1
63.    cos100  cos 20 0  ....  cos1800 
r 1 2 2 2
1
9   1  8.5
2
64. GE   log10  2.3  log10  3.4  log10  4.5  ....  log10 19.20
1
65. conceptual
z2  z1
66. z1  z2 w  z3 2  0   w
z3  z1
 Is isosceles with vertical angle 1200 and base 6
 Area = 3 3  a  b  6
67. Range =[3, 12]
Difference = 12-3=9
68.  gof  x  x  g '  f  x . f '   1  put x  1  GE  1
69. conceptual

Sr.IPLCO_IC_ISB_LIIT _P1_Solutions Page 12