Technological Institute of the

Compressor 5

∆ H 106 ∆ H 107

T =450 ° C T =470 ° C

P=1 atm P=2 atm

Equipment Type Compressor

Equipment Number C-105 A/B
Operating Temperature 470°C
Operating Pressure 2 atm

Energy Balance for Compressor

❑ ❑
∆ H = ∑ ni (∆ H t )−∑ ni ( ∆ H t )
outlet inlet

Substances Inlet Outlet

N Hin (kJ/hr) n Hout (kJ/hr)
(kmol/hr) (kmol/hr)
Butane(a) 3.1587 -69,151.3062 3.1587 12,128.8265 H107a

Butene(b) 4.0771 -77,236.7092 4.0771 13,553.9844 H107b

Butadiene(c 7.8117 -135,234.448 7.8117 23,829.2568 H107c

)
Water(d) 16.1694 -68,348.3142 16.1694 12,249.40 H107d

Carbon 3.8161 -21,108.4203 3.8161 3,773.1569 H107e

Dioxide(e)
Hydrogen(f) 8.2954 -26,984.8296 8.2954 4,895.1024 H107f
 Technological Institute of the

Oxygen(g) 1.7432 -6,429.3701 1.7432 1,156.5463 H107g

Nitrogen(h) 51.3349 -173,659.511 51.3349 31,354.1390 H107h

Inlet

KJ
( ∆ H S−106 )=−578,188.1067 hr

Outlet

473.15
H 108 a=n ∫ CpdT
743.15

kJ
¿ ( 3.1587 ) ( 3839.79 )=12,128.82651
hr

473.15
H 108 b=n ∫ CpdT
743.15

kJ
¿ ( 4.0771 ) ( 3324.41 )=13,553.98443
hr

473.15
H 108 c=n ∫ CpdT
743.15

kJ
¿ ( 7.8117 )( 3050.44 )=23,829.2568
hr

473.15
H 108 d=n ∫ nCpdT
743.15

kJ
¿ ( 16.1694 ) ( 757.57 )=12,249.40165
hr
 Technological Institute of the

473.15
H 108 e=n ∫ CpdT
743.15

kJ
¿ ( 3.8161 )( 988.75 )=3,773.1569
hr

473.15
H 108 f =n ∫ CpdT
743.15

kJ
¿ ( 8.2954 )( 590.10 )=4,895.10329
hr

473.15
H 108 g= ∫ nCpdT
743.15

kJ
¿ ( 1.7432 )( 663.45 )=1,156.5463
hr

473.15
H 108 h= ∫ nCpdT
743.15

kJ
¿ ( 51.3349 ) ( 610.78 )=31,354.1390
hr
∆𝐻 =n H108a + n H108b + n H108 c+ n H108d + n H108e+ n H108f + n H108g+ n H108h
kJ
Hout=∑ ( H 108 a → H 108 h ) =102,940.4141
hr
∆𝐻 = ΔH107 - ΔH106
kJ 1 hr
¿ 102,940.4141−(−578,188.1067 ) =681,128.5208 × =189.20 kilowatts
hr 3600 S

Heat Exchanger 3 - Cooling

ΔH107 ΔH108
Heat Exchanger
T = 470°C
P = 2 atm
 Technological Institute of the

T = 200°C
P = 2 atm

Equipment Type Heat Exchanger

Equipment Number E-103 A/B
Operating Temperature 200°C
Operating Pressure 2 atm

Energy Balance for heat exchanger

∆ H = ∑ ni ( ∆ H t ) −∑ ni ( ∆ H t )
outlet inlet

Inlet Outlet
Substances N Hin (kJ/hr) n Hout (kJ/hr)
(kmol/hr) (kmol/hr)
Butane 3.1587 12,128.8265 3.1587 -144,253.5783 H108a

Butene 4.0771 13,553.9844 4.0771 -161,399.6501 H108b

Butadiene 7.8117 23,829.256 7.8117 -285,813.2225 H108c

Water 16.1694 1.22E+04 16.1694 -158,929.8463 H108d

Carbon 3.8161 3,773.1569 3.8161 -48,135.5904 H108e

Dioxide
Hydrogen 8.2954 4,895.1024 8.2954 -65,817.8131 H108f

Oxygen 1.7432 1,156.5463 1.7432 -15,090.2808 H108g

Nitrogen 51.3349 31,354.1390 51.334 -415,793.8068 H108h

 Technological Institute of the

Inlet:
kJ
¿ ∆ H 107 =102,940.4141
hr
Outlet:
∆𝐻 =n H108a +n H108b + n H108 c+ n H108d + n H108e+ n H108f + n H108g+ n H108h

473.15
H 108 a=n ∫ CpdT
743.15

kJ
¿ ( 3.1587 ) (−45668.39 ) =−144,253.5783
hr

473.15
H 108 b=n ∫ CpdT
743.15

kJ
¿ ( 4.0771 ) (−39586.73 )=−161,399.6501
hr

473.15
H 108 c=n ∫ CpdT
743.15

kJ
¿ ( 7.8117 )(−36587.64 )=−258,813.225
hr

473.15
H 108 d=n ∫ CpdT
743.15

kJ
¿ ( 16.1694 ) (−9829.07 )=−158,929.8463
hr

473.15
H 108 e=n ∫ CpdT
743.15

kJ
¿ ( 3.8161 )(−12613.88 )=−48,135.5904
hr
 Technological Institute of the

473.15
H 108 f =n ∫ CpdT
743.15

kJ
¿ ( 8.2954 )(−7934.22 )=−65,817.8131
hr

473.15
H 108 g=n ∫ CpdT
743.15

kJ
¿ ( 1.7432 )(−8656.52 )=−15,090.2808
hr

473.15
H 108 h=n ∫ CpdT
743.15

kJ
¿ ( 51.3349 ) (−8099.64 ) =−415,793.8068
hr

kJ
Hout=∑ ( H 108 a → H 108 h ) =−1,295,233.7882
hr

∆𝐻 = ΔH108 - ΔH107
kJ 1 h r
¿ (−1,295,233.7882 ) – ( 102,940.4141 )=−1 ,398,174.202 (
hr 3600 s)=−388.38 kilowatts

Cooling Water Requirement

Q ¿ =−Q H O2

( mCpdt )¿ =( mCpdt )H 2 O

( mCpdt )¿ 1297394.72 kmole

mH O = = =215.97
2
( Cpdt ) H O 6007.307323
2
hr
 Technological Institute of the

kmole 18 kg kg
¿ 215.97 (
hr kmole )=3890.69
hr