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Msdsdvb80eu PDF
Msdsdvb80eu PDF
DVB 80
Page: 1
Compilation date: 25/06/2012
Revision No: 5
Classification under CHIP: Xi: R36/37/38; Sens.: R43; Xn: R63; N: R50/53
Classification under CLP: Aquatic Chronic 1: H410; STOT SE 3: H335; Repr. 2: H361d; Skin Irrit. 2: H315;
Skin Sens. 1: H317; Eye Irrit. 2: H319
Most important adverse effects: Irritating to eyes, respiratory system and skin. May cause sensitisation by skin
contact. Possible risk of harm to the unborn child. Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
2.2. Label elements
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SAFETY DATA SHEET
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H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H361d: Suspected of damaging the unborn child.
H410: Very toxic to aquatic life with long lasting effects.
Signal words: Warning
Hazard pictograms: GHS07: Exclamation mark
GHS08: Health hazard
GHS09: Environmental
3.1. Substances
Skin contact: Wash immediately with plenty of soap and water. Remove all contaminated clothes
and footwear immediately unless stuck to skin. Drench the affected skin with
running water for 10 minutes or longer if substance is still on skin.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Do not induce vomiting. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If
unconscious, check for breathing and apply artificial respiration if necessary.
Consult a doctor. If unconscious and breathing is OK, place in the recovery
position.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and pain.
Ingestion: low toxicity if swallowed There may be soreness and redness of the mouth and
throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
4.3. Indication of any immediate medical attention and special treatment needed
Immediate / special treatment: Show this safety data sheet to the doctor in attendance. In case of shortness of
breath, give oxygen. A decontamination shower should be available on the
premises. Eye bathing equipment should be available on the premises.
Extinguishing media: Carbon dioxide. Dry chemical powder. Alcohol resistant foam. Water fog. General
purpose synthetic foams are preferred.
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SAFETY DATA SHEET
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5.2. Special hazards arising from the substance or mixture
Exposure hazards: Toxic. In combustion emits toxic fumes of carbon dioxide / carbon monoxide.
Container may rupture upon polymerisation
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent
contact with skin and eyes. Contain fire water if possible.
Personal precautions: Refer to section 8 of SDS for personal protection details. Eliminate all sources of
ignition. If outside do not approach from downwind. Mark out the contaminated area
with signs and prevent access to unauthorised personnel. Mechanically ventilate
the spillage area whilst avoiding the formation of explosive concentrations - see
section 9 of SDS. Do not attempt to take action without suitable protective clothing
- see section 8 of SDS.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. Inform
the authorities in case of spillage entering the sewers or water courses.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Avoid all incompatible materials in clean-up
procedure - see section 10 of SDS. Transfer to a closable, labelled salvage
container for disposal by an appropriate method. Refer to section 13 of SDS for
suitable method of disposal.
6.4. Reference to other sections
Handling requirements: Ensure there is sufficient ventilation of the area. Avoid the formation or spread of
mists in the air. Earth any equipment used in handling. Smoking is forbidden. Do
not handle in a confined space.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. Keep away from direct sunlight. Maintain
Inhibitor and dissolved oxygen level. See handling brochure for full details.
Suitable packaging: Must only be kept in original packaging.
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SAFETY DATA SHEET
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7.3. Specific end use(s)
State: Liquid
Colour: Colourless
Odour: Aromatic
Solubility in water: 36 mg/l
Viscosity: Non-viscous
Kinematic viscosity: 1.1 mm2/s
Viscosity test method: Kinematic viscosity @25 C
Boiling point/range°C: 195 Flammability limits %: lower: 0.64
upper: 6.1 Flash point°C: 69 CC
Part.coeff. n-octanol/water: 3.8 Autoflammability°C: 494
Vapour pressure: 13 mm Hg Relative density: 0.91 @ 25
9.2. Other information
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SAFETY DATA SHEET
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10.1. Reactivity
Hazardous reactions: Polymerisation may occur on exposure to conditions or materials listed below.
Elevated temperatures can cause hazardous polymerization. Maintain inhibitor and
dissolved oxygen levels.
10.4. Conditions to avoid
Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide.
Toxicity values:
Route Species Test Value Units
DERMAL RBT LD50 >8000 mg/kg
ORAL RAT LD50 >2000 mg/kg
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and pain.
Ingestion: low toxicity if swallowed There may be soreness and redness of the mouth and
throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
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SAFETY DATA SHEET
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12.1. Toxicity
Ecotoxicity values:
Species Test Value Units
Daphnia magna 48H EC50 1.1 mg/l
FISH 96H LC50 7.5 mg/l
GREEN ALGA (Selenastrum capricornutum) 72H ErC50 1.7 mg/l
Mobility: Final destination of reacted products is soil / sediment. Partition Coefficient (Koc)
933 (OECD 121)
12.5. Results of PBT and vPvB assessment
Persistence (P-):
Persistence result: not P-
Bioaccumulation (B-):
Bioconcentration factor (BCF): <2000
Bioaccumulation result: not B-
Toxicity (T-):
Toxicity result: not T-
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.
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SAFETY DATA SHEET
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14.1. UN number
UN number: UN3082
14.2. UN proper shipping name
Transport class: 9
14.4. Packing group
Tunnel code: E
Transport category: 3
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU)
No 453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and 3: H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H361d: Suspected of damaging the unborn child.
H410: Very toxic to aquatic life with long lasting effects.
R36/37/38: Irritating to eyes, respiratory system and skin.
R43: May cause sensitisation by skin contact.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R63: Possible risk of harm to the unborn child.
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SAFETY DATA SHEET
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Legal disclaimer: The above information is believed to be correct but does not purport to be all
inclusive and shall be used only as a guide. This company shall not be held liable
for any damage resulting from handling or from contact with the above product.
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