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Alterasi Batuan - Geyserite - Siliceous Sinter
Alterasi Batuan - Geyserite - Siliceous Sinter
Alteration
Febryanto Masulili, S.T, M.Sc
Kuliah Alterasi Batuan – Universitas Prisma, Manado
November 2019
Introduction
Geyserite is the name given to siliceous or calcareous mineral deposits at & in the
vicinity of hot springs and geysers, typically develop at the intersection of the water
table and the Earth’s surface in subaerial volcanic terrains (Sillitoe 1993; Guido and
Campbell 2011).
Siliceous hot spring deposits characteristics (Fournier 1985; Cady and Farmer 1996;
Fournier and Rowe 1966; Lynne et al. 2008; Guido and Campbell 2011; Lynne 2012) :
• Chemically precipitated,
• Bedded, erosion-resistant mounds and sheet deposits,
• Metres to tens of metres thick,
• Typically occurring in the geologic record as topographical highs,
• Containing a myriad of sedimentary features with environmental significance (i.e.
lithofacies),
• Produced from the thermal fluid discharge of dilute brines heated in the
subsurface.
Introduction
Fig. 2. Schematic diagram showing how siliceous sinters and pseudosinters of thermogene travertines, silica
residue, silicified volcanics, silicified fluvial sediments, silicified lake sediments and epithermal veins relate to
geothermal up-flow and outflow (modified from Buchanan 1981; Tosdal et al. 2009; and Hamilton et al. 2018).
Introduction
Sinter deposits are surface manifestations of geothermal systems, largely produced
by near-neutral pH alkali chloride fluids that are oversaturated in silica.
Fig 1. Solubility curves of silica with temperature (modified from Gunnarsson and
Arnórsson 2000; Rodgers et al. 2004; Lynne et al. 2019).
Geyserite - What’s Important ?
• Due to their common spatial relationship with epithermal ore deposits, thereby
providing a useful tool in exploration (Sillitoe 2015; Hamilton et al. 2018).
• Sinters also trap extremophiles in situ in a durable mineral deposit, therefore
preserving life from extreme environments within the fossil record, which has
implications for recognising early signs of life on the Archean Earth (Djokic et al.
2017), and for narrowing the search for possible ancient life on Mars (Ruff and
Farmer 2016).
• The preserved organic material within sinters also can be utilised to reconstruct
paleoclimatic conditions (Goldie 1985).
Sinter – Lithofacies
(Cady and Farmer 1996)
• Silica infiltrate
• Spring conduits
• Geyserite (specular, nodular, radiating macrobotryoidal, geyser eggs)
• Finely laminated
Vent-related: Silica Infiltrate
• Definition: Spring conduits are usually open, tortuous, cylindrical central holes
occurring within mounds or fissures, through which very high temperature geothermal
fluids are expelled at the surface in relatively high volumes (vents) to produce geysers
and spouters (Braunstein and Lowe 2001; Guido and Campbell 2009; Guido et al. 2010;
Guido and Campbell 2011).
Vent-related: Spring Conduits
• Description: Geyser mounds with associated
conduits are tens of centimetres to metres in
diameter and range up to metres in height. The
mounds contain cylindrical holes that are a few
centimetres to up to a few metres in diameter.
• Formation Environment: fluid flow pathways
that exit to the land surface. Localised to the
spring vent area.
• Formation Temperature: >~75–100°C at the
surface; tens of metres beneath the surface
temperatures may be up to ~180°C
(Giggenbach et al. 1994).
• Flow Direction: upwards and outwards in
vicinity of conduit exit points.
• Definition: Nodular geyserite consists of small rounded, clumped nodular humps (≤1
cm in diameter) of dense, finely laminated sinter that predominantly forms around
slightly drier portions of vent areas subjected to less splash but still at very high
temperatures (Walter 1976; Braunstein and Lowe 2001; Walter et al. 1992; Campbell et
al. 2015a).
Proximal Apron: Nodular Geyserite
• Description: individual nodules (≤1.5 cm wide,
≤4 cm high) of geyserite are cemented
together and commonly merge, and comprise
thin, dense, smooth, relatively even laminae
(~5–50 μm thick), which occur adjacent to and
stacked upon one another.
• Formation Environment: occurs in the outer
splash zones in vent areas, or on vent rims
vertically above the air-water interface of the
spring source hot pool.
• Formation Temperature: >~75°C.
• Extent: localised to vent margins over lateral
distances of a few metres.
• Definition: Geyser eggs, or geyser beads are spherical to somewhat irregular, densely
laminated sinter (geyserite) that may be smooth on their exteriors, or spicular upon
their tops. These overall rounded geyserite spheroids (<10 cm in diameter) form at the
air-water interface in the splash zone of fountaining geysers, in very shallow pools of
proximal vent areas at high temperatures (Walter 1976; Jones et al. 2001; Campbell et
al. 2015a).
Proximal Apron: Geyser Eggs
• Description: concentric, dense silica laminae
in rounded spheres (up to 10 cm in diameter),
some of which display spicular geyserite on
their upper surfaces. Somewhat flattened where
subsequently cemented to the substrate.
• Formation Environment: in splash areas of
effusive geysers and fountains that are often
disturbed by surging vent fluids.
• Formation Temperature: >~75 °C.
• Extent: localised to vent areas over lateral areas
of a few metres to tens of metres in large
fountain geysers.
• Definition: fine laminations of silica that accumulate where fast flowing geothermal
fluids debouch from the vent on the proximal slope and in upper apron outflow
channels at high temperatures (Guido and Campbell 2011).
Proximal Apron: Finely Laminated
• Description: lamination composed of silica, up
to 2 mm thick, that is laterally continuous for
tens of centimetres, in places with small
wavelets that have amplitudes up to 5 mm and
crests up to 1 cm apart.
• Formation Environment: develops on the
proximal slope adjacent to vents, where
episodic deposition takes place (Walter et al.
1996; Guido and Campbell 2011).
• Formation Temperature: ~60 - 75 °C.
• Flow Direction: flow is parallel to lamination.
• Extent: lateral extent is centimetres to metres.
• Definition: domed to convexly curved stromatolites that grow upwards from the
bottom of relatively deep pools at moderate temperatures of the mid-apron (Drake et
al. 2014).
Middle Apron: Domal Stromatolites
• Description: stromatolites comprising thin (<5
mm), domed, wavy laminae and bands of sinter
that are continuous within domes.
• Formation Environment: domal stromatolites
grow from the base of deep (>1.5 m), calm,
moderate temperature pools, metres to tens of
metres from vent areas.
• Formation Temperature: ~45 - 60 °C.
• Fluid Volume: high volumes of thermal fluids
are required.
• Flow Direction: grow perpendicular to water
level, upward accumulation of mat and sinter.
• Extent: Decimetres to tens of metres.
• Definition: network fabric is a surface feature that constitutes irregular threads of silica
(<1mm) in a webbed pattern. Found along the drying margins of moderate-
temperature pools of the mid-apron, where EPS exuded by cyanobacteria becomes
dried out and web-like as it silicifies (Guido and Campbell 2011; Handley and
Campbell 2011).
Middle Apron: Network Fabric
• Description: Irregular, silicified, webbed
features.
• Formation Environment: Wetting and drying
of mats around pool margins, metres to tens of
metres from vent areas.
• Formation Temperature: ~45 - 60 °C.
• Fluid Volume: low fluid volumes, in areas of
drying out microbial sinter.
• Extent: localised to pool margins, centimetres
to metres in extent.
• Definition: ropy pool mats form as irregularly contorted to torn, thick, green and
orange layers (mm’s to cm’s thick) of rubbery (soft) microbial mats growing along the
margins of and across the surfaces of deep (>1 m), moderate-temperature pools in the
middle apron (Guido et al. 2010).
Middle Apron: Ropy Pool Mats
• Description: silica sinter beds (individually
mm’s to cm’s thick), up to 1 m in length, that
may transition from minor contortions to twisted
and torn morphologies.
• Formation Environment: At the margins of or
on the surfaces of deep (>1 m) pools,
especially where spring discharge channels
enter pools, metres to tens of metres away from
vent areas.
• Formation Temperature: ~45 - 60 °C.
• Fluid Volume: fluctuating thermal fluid input
are required to form ropy pool mats.
• Definition: bubble mats, or curved lenticular to spherical voids within wavy laminated
sinter (Cady and Farmer 1996; Campbell et al. 2001), form where gases become
trapped within the exopolymeric substance (EPS) of the matrix of the cyanobacterial
mats during photosynthesis, at moderate temperatures of the mid-apron (Hinman and
Lindstrom 1996), or from thermal spring emissions of exsolved volatiles.
Middle Apron: Bubble Mat Texture
• Description: Spherical to elongated voids
parallel to bedding, up to 5 cm in diameter,
surrounded by silica, which later may be
infilled by silica.
• Formation Environment: gas bubbles form
subaqueously, becoming trapped as microbial
mats exude oxygen during photosynthesis
(Hinman and Lindstrom 1996) or as the pool
degases from physicochemical processes,
occurring over extensive areas in shallow
pools.
• Formation Temperature: ~45 - 55 °C.
• Extent: bubbles may form over laterally
extensive areas, from metres to tens of metres.
• Definition: plant-rich fabric consists of silicified branches, twigs, reeds and leaves,
which commonly show a preferred orientation. Plants are encrusted with fluffy, fine
grained opaline silica in modern hot-springs within the geothermally influenced marsh
at ambient temperatures (Weed 1889; Channing et al. 2004).
Marsh Lithofacies: Plant-rich Sinter
• Description: Fine-grained silica can replace,
encrust and form casts of plant material. Insects
and other eukaryotes also may be associated.
• Formation Environment: At low temperatures,
where plants are able to grow in the interfluves
between the thermal spring discharge channels
on the distal apron.
• Formation Temperature: <35 °C
• Extent: May form over widely extensive areas,
metres to hundreds of metres away from vent
areas.
• Definition: Thermogene travertines are hot spring deposits (~100–30 °C) precipitated
from CO2-rich fluids, forming constructional calcium carbonate deposits within
mounds and terrances (Pentecost 2005).
Pseudo-Sinter: Silicified Thermogene Travertine
• Description: commonly associated textures -
very thick palisade fabrics (A), stromatolites
(B), fenestral fabrics (C), and spherulites (D).
• Formation Environment:
• CO2-rich thermal fluids + bicarbonate springs
(Henley and Ellis 1984; Renaut and Jones 2011),
• derived from magmatic sources (Gibert et al. 2009),
or
• situated in ancient carbonate stratigraphy (Chafetz
and Guidry 2003).
• Formation Temperature: ~100 °C - ambient
temperatures
• Distinguishing (Petrography):
• feathery microtextures
• remnant calcite and aragonite (Fouke et al. 2000;
Pentecost 2005: Guido and Campbell 2017).
• Definition: Silica rich veins are produced in epithermal systems to paleo depths of ~1
km by near-neutral pH alkali chloride fluids traversing country rock in focused veins
and conduits (Lindgren 1933; Simmons et al. 2005).
Epithermal Veins
• Description: Vein textures indicate episodic,
multistage accumulation of ore minerals from
various fluid processes, principally boiling
(Simmons et al. 2005; Christie et al. 2007).
• crustiform (B),
• colloform banded chalcedonic veins (A, D),
• quartz pseudomorphism of lamellar calcite (C).
• Formation Environment: The veins occur in
zones of epithermal fluid up-flow within the
shallow subsurface (<3 km depth), cross-cutting
lithology.
• Formation Temperature: ~200 - 300 °C
• Extent: Epithermal veins are generally
localised in fractures and faults.