Scribd Logo
Upload

Welcome to Scribd!

  • 10 views

    9,3 Dan 9,4

    Uploaded by

    Gielf Cia
    The document contains two chemistry problems involving calculations of ion concentrations in solutions. The first problem calculates the concentration of Zn2+ ions in a solution containing 1 × 10-4 M ZnY2- at pH 10 using given equilibrium and stability constants. The calculated concentration is 2.12 × 10-6 M and the pZn2+ is 14.37. The second problem calculates the concentration of Ca2+ ions in a solution containing 1 × 10-3 M CaY2- and an excess of 1.0 × 10-2 M EDTA using given equilibrium and stability constants for the CaY2- complex.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content

    You might also like

    9,3 Dan 9,4

    Uploaded by

    Gielf Cia
    10 views1 page
    The document contains two chemistry problems involving calculations of ion concentrations in solutions. The first problem calculates the concentration of Zn2+ ions in a solution containing 1 × 10-4 M ZnY2- at pH 10 using given equilibrium and stability constants. The calculated concentration is 2.12 × 10-6 M and the pZn2+ is 14.37. The second problem calculates the concentration of Ca2+ ions in a solution containing 1 × 10-3 M CaY2- and an excess of 1.0 × 10-2 M EDTA using given equilibrium and stability constants for the CaY2- complex.

    Original Description:

    Original Title

    9,3 dan 9,4

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document contains two chemistry problems involving calculations of ion concentrations in solutions. The first problem calculates the concentration of Zn2+ ions in a solution containing 1 × 10-4 M ZnY2- at pH 10 using given equilibrium and stability constants. The calculated concentration is 2.12 × 10-6 M and the pZn2+ is 14.37. The second problem calculates the concentration of Ca2+ ions in a solution containing 1 × 10-3 M CaY2- and an excess of 1.0 × 10-2 M EDTA using given equilibrium and stability constants for the CaY2- complex.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    10 views1 page

    9,3 Dan 9,4

    Uploaded by

    Gielf Cia
    The document contains two chemistry problems involving calculations of ion concentrations in solutions. The first problem calculates the concentration of Zn2+ ions in a solution containing 1 × 10-4 M ZnY2- at pH 10 using given equilibrium and stability constants. The calculated concentration is 2.12 × 10-6 M and the pZn2+ is 14.37. The second problem calculates the concentration of Ca2+ ions in a solution containing 1 × 10-3 M CaY2- and an excess of 1.0 × 10-2 M EDTA using given equilibrium and stability constants for the CaY2- complex.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    of 1

    9.

    3
    Calculate pZn+ in a solution containing 1 × 10-4 M ZnY2- at pH 10,0 if known α Zn 2+¿
    ¿ = 2,0 ×

    10-9 ; and K Zn Y 2−¿ = 3,16 × 1016.


    ¿

    Answer:
    2−¿ ¿
    4−¿⇄ZnY
    K ZnY =¿ ¿ ¿
    ¿

    Zn2+¿+Y ¿

    K ZnY =K ZnY 2−¿


    ¿¿

    K ZnY 2−¿
    ¿¿

    −4
    ( 3,16 ×1 016 ) ( 2,0 ×10−9 ) ( 0,35 )= 1× 102
    [ Zn' ]

    1 ×10−4
    [ Zn' ]=
    √ 0,221 ×10 8
    =2,12 ×10−6

    ¿
    −15

    p Zn2 +¿=− log4,24 × 10 =14,37¿

    9.4
    Calculate the concentration of Ca2+ in solution containing 1 × 10-3 CaY2- and 1,0 × 10-2 M
    EDTA excessive, if known K CaY 2−¿
    =5,01 ×10 10 ¿ ; α Ca
    2+ ¿
    =4,2×10−3 ¿ ; αY 4−¿
    =6,4 × 10−1 ¿

    2−¿ ¿
    4−¿⇄Ca Y ¿

    Ca2+¿+Y ¿

    K CaY =K CaY 2−¿


    ¿¿

    −3
    ( 5,01 ×1010 ) ( 6,4 ×10−1 )= 1׿10
    ¿

    1× 10−3
    32,064 ×10 9= ¿¿

    You might also like