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Chem Academy: Quantum Chemistry
Chem Academy: Quantum Chemistry
Assignment
Home Work DPP
CHEM ACADEMY
where C1 and C2 are constants
(iii) The operator L2 commute with Lx + Ly.
(a) i, iii (b) i, ii (c) ii, iii (d) only iii
4. When the operator 2 d 2 /dx 2 operates on a function e–ikx the result is
(a) k 2 2 e ikx (b) k 2 2e ikx (c) i 2 e ikx (d) 2 e ikx
5. If an operator d 2
/ dx 2 16x 2 is operated on an fucntion e–2x2 than corresponding eigenvalue is
(a) –2 (b) –4 (c) 2 (d) 4
6. h 2
/ 8 2 m d 2 /dx 2 h 2 2 x 2 / 2 2 m e x 2 C h 2 /4 2 e xh (h, , m constant), value of
C is
(a) 2/m (b) 2m (c) /m (d) /m
7. The eigenfunctions of the Hamiltonian H (H = T + V) of a harmonic oscillator are (where T and V
are kinetic energy and potential energy operators, respectvely)
(a) eigenfunctions of T as well as V (b) eigenfunctions of T, but not of V
(c) eigenfunctions of V but not of T (d) eigenfunctions of neither T nor V
8. The probability of finding the particle in a one dimensional box of length 'L' in the region between
1 3L
and for quantum number n = 1 is
4 4
1 1 1 1 1 2
(a) (b) (c) (d)
2 2 2 3
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9. Consider the statements
1. Momentum and kinetic energy may be determined simultaneously but momentum and total
energy can not be determined simultaneously.
2. Normalization constant for a particle that is confined to move in a box of length 900 nm is 0.2
(nm)1/2.
3. A wave function becomes zero at infinite.
True statements above are
(a) 1, 2 (b) 2, 3 (c) 1, 3 (d) 1, 2, 3
(e) 1 only (f) 2 only (g) 3 only
10. Consider the statements
1. If the wavefunction for system is an eignfunction of operator associated with observable A than
<An> = <A>n
2. The probability of finding the particle in 1 D box of length 1 within the middle half of the box in
first excited state is 82%
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14. <x> in the ground staate for a particle that is confined to move in a one d box of length –L to L is
(a) L (b) L/2 (c) –L (d) 0
15. Consider a particle of mass m moving n a one dimensional box under the potential V = 0 for 0 < x
< a and V = infinite outside the box.
(i) When the particle is in lowest energy state, the average momentum <px> of the particle is
(a) <Px> = 0 (b) <Px> = (h/a) (c) <px> = (h/2a) (d) <px> = (h/2a)
(ii) The uncertainty in the momentum px of the particle in its lowest energy state is
(a) px = 0 (b) px = (h/a) (c) px = (h/2a) (d) px = (h/2a)
3
16. For the particle in a box problem (0, L), the value of <x > int eh n would be
(a) L3/6 (b) L3/4 (c) L3/4 (d) L4/4
17. The mathematical expression e i kx wt represents
(a) a wave stationary in space but oscillating in time
(b) a travelling wave moving in the positive x direction
(c) a wave stationary in time but periodically varying in space
(d) a travelling wave moving in the negative x direction
CHEM ACADEMY
Head Office: North Delhi: 72, Mall Road, G.T.B. Nagar, New Delhi - 110009
Branch Office: Jaipur: S1, Vikash Marg, Near Vodafone Store, Mansinghpura, Tonk Road, Jaipur- 302015. Mob.: 9587959709 3
Toll Free: 1800 120 5848, Ph.: 011-41415514, 09136597244, Web.: www.chemacademy.co.in