! CHEMISTRY TEST portion of the page of the answer sheet that you will use to take the Chemistry Test must be filled in exactly as below. When your supervisor tells you to fill inthe circle next to the name of the test you are about to take, irk your answer sheet as shown. Lace © Mananecesivatt fry partons page egal | | -120-CHEMISTRY TEST—Continued ® ‘Questions 19-20 Questions 21-23 refer to the following phase diagram for a pure substance. (A) NH,CI (8) Nacio | © Hr 4 © (0) Kou = = , © KHCO, Es £ OO) tea strong acid in aqueous solution Ea ©). sa strong base in aqueous solution a a) ' & 1 ® 2 © , oly, | 90-80 -70 -60 -50 -40 ~30 : Temperature (°C) 4 21. Where are the vapor presstire fp solid and the pressure of the gas equal? 22. Where does the solid exist in equilibiummygth the gut? € 23. Whete does the substance exist only asa gas? GO ONTOTHE NEXT PAGE ) -121-© CHEMISTRY TEST—Continued ® PLEASE GO TO THE SPECIAL SECTION AT THE LOWER LEFT-HAND CORNER OF THE PAGE OF THE ANSWER SHEET YOU ARE WORKING ON AND ANSWER QUESTIONS 101-115 ACCORDING TO THE FOLLOWING DIRECTIONS. Part B Directions: Each question below consists of two statements, 1 in the left-hand column and IL in the righthand column, For each question, determine whether statement Tis true or false and whether statement If is trac or false ‘and fill in the corresponding T or F circles on your answer sheet. Fill in circle CE only if statement JLis a correct explanation of the tne statement 1, EXAMPLES 1 as EX1. 1,80, is astrongacid BECAUSE 1,S0, contains sulfur. EX2, Anatom ofoxygenis BECAUSE an oxygen atom contains an equal , electrically neutral ‘number of protons and electrons. SAMPLE ANSWERS 1 u 101. The orbital diagram for a nit Fer tiom in its BECAUSE the most giaisameomfpamerton for chree 2 ‘ground state is clectrons is three ulfpaired electrons. LUUt 102. Ata fixed temperature al of the moléfules in Eat constant preSure, fe volume occupied by ‘given volume of an ideal gas have th same 4 fixed quantity of an\eal gas is proportional speed to the absolute tempergre 103. The CO, mine] BECAUSE the bonfSipotegin the CO, mffecu Fe : one another. - 104. All endothermic reactions are nonsyg@fMeous BECAUSE in en the total energy of the products is Hfeher than the total energy of the reactants. mT [co on 70 wi Wext a wee > “122 waa coal eg eae x Fad! ag RS,CHEMISTRY TEST—Continued ® ' St. n «5. The bonds in solid sodium chloridefhave more BECAUSE sodium is a milammtfd aluminum is a ' ionic character than the bonds in sofjd ‘nonmetal, aluminum chloride have | — , 6. A catalyst increases the rate of afemical BECAUSE a catalyst increifes the activation energy of a yy Teaction reaction ; { (07. All pure hydrocarbons hfe same BECAUSE hydrocarbons edntain only ffe elements i , has CHEMISTRY TEST—Continued BECAUSE BECAUSE BECAUSE BECAUSE BECAUSE ® nL there is more itfermolecular hydrogen bonding in CHP than in 11,0. at a gfventenpetature, ator ind Xe have the samdaverage kin mand He has a lower alfmic mass th the nuct Tes a very 5 foot the volune en om the freezing jowered in proportion to the co tration of independent solute particles. the chlorine atom fess electronegative than the carbon atom is. RETURN TO THE SECTION OF YOUR ANSWER SHEET YOU STARTED FOR CHEMISTRY AND. ANSWER QUESTIONS 24-70. A24- GO ONTOTHE NEXT PAGE a \. Ao yuan salamatFr 4 CHEMISTRY TEST—Continued ® Part C |ectins: Hach of te questions or incomplete staeméns below is followed by five suggested answers or mpletions, Select the one that is best in each case and then fill inthe corresponding cicle on the answer sheet. [Positive ong are formed when neal toms CHG) + 21,0@) 2 COlg) + 41) (A) gain neutrons 1B) gain nuclear charge 27. Which of the following is the correct expression, (C) release energy for the equilibrim constant, K,., for the reaction (D) lose protons represented by the equation above? AWD lose clectrons { (cH, }{#,0] 5. The oxidation number of hydrogen is negative () Ke = "Teo, Io] jin which ofthe following compounds? aa (cH, J[H,0F (8) NHS (co, J[x, |* ene (co, fH} ORG) [CO] + 4{u, » Al (BE) KOH © K.= (ea », Electrons in atoms absorb and emit energy only (Co, }f¥t)] (A) in amounts large enough for ionization © «= are in discrete amounts called quanta (CH, [420] (©) in the visible region of the spectrum i(D) when the atoms are in molecules co, [t1,} HEE) when the tomate in colored molecules e.- bt [cH,][,0} | ee sae gw ie [so onToTHE wares) 125-® 28, Which of the following is a characteristic of nonmetals? (A) Being malleable (B) Being an electrical conductor Having an oxide that forms acidic solutions (D) Having high density ©) Appearing on the left side of the periodic table 29. The following data were collected to determine the density ofa liquid. Mass of bottle filled with liquid 21.245 g Mass of empty bottle 10.234 g ‘Volume of liquid in bottle 1.0.mL, “The density ofthe liquid is best recorded as (A) 0.1 pin, (B) 1 g/mL © Wyn. B00 pm. (E) 1.001 g/mL 2NOa) 2 NO4a) + enerBy 30. NO4fg) is sealed in a glass tube and allowed to reach equilibrium at coom temperature according to the equation above, Placing the tube in ice ‘water will esult in whieh of the following? 1. Aniincrease in gas volume IL, An increase in gas pressure TH A decrease in concentration of NO,(8) (A) Lonly (B) Tonly @ Wony (D) Land only ©) Ul, end ttl CHEMISTRY TEST—Continued ® 31, How many electrons does the chlorine-37 ion, Fer’, have? (a) 16 ® 7 o. (D) 36 ©) 38 2CO(g) + Oxle) > 2 COs) 432, At standard temperature and pressure, when 1 mol of CO and 1 mol of O, ate mixed and heated, the redction represented above takes place. When the reaction has progressed as completely as possible and the reagtion chamber has retwmed to original conditions of temperature and pressure, the final system contains (A) Lmol of CO, only (B) 05 mot of CO, only (C) 05 mol of CO, and 0.5 mol of Op (D) 1 mol of CO, and 0.5 mol of CO @ 1161 0F CO, and 05 mot of O, 33, A cylinder is filled with butane gas to 2 pressure cof 3.20 atm at 47°C. What is the pressure in the cylinder when the temperature is 27°C? (A) 0320 atm (B) 1.00atm © 224 am @ 3.00am (6) 448 atm P® aA L Ce 09 \ 1 B® Bw 2 a GO ONTO THE NEXT PAGE 126-CHEMISTRY 1) 1. The molar concentration of hydrogen ions in a _polasion of pH is (a) 108M 106M {© om “O) 8M © 106M Mg(s) + 2H"(aq) > Hy(g) + Me**(ag) i. What volume of 4.0 M HCK(aq) is required for complete reaction with 12 g of Mg(s) according }o the reaction represented above? afd) O12L 1 025k (©) 0501. , (0) 0754. \B 1.0L Characteristics of a 0.1 M aqueous solution of HNO, include all of the following EXCEPT: (A) It conducts electricity, (B) Itturns blue litmus paper red {C) Itseacss with magnesium to produce hydrogen gas. thas a hydroxide ion concentration of | 107M. (E) Wreacts with 01M KOH. Qn. +(.n,0.0 93 no ff 00) ‘When the equation above is balanced and all ‘coefficients are reduced to lowest whole-number sqtermns, the coefficient for No(g) is 1a) ST—Continued 38. A freshly opened can of carbsnated beverage fizzes because (A) an acid is reacting with dissolved solids (B) the solution is boiling (©) oxygen from the air reacts with dissolved catbon (D) air is a catalyst for an otherwise slow reaction © Gissoived gos escapes when the pressure is reduced Hg,"*(aq) + Zn(s) >» 2Hg() + Zn?*(ag) 39. The reaction represented above could be comectly described as (A) a proton transfer reaction (B) aneutron transfer reaction @ an electron transfer reaction (D) a hydronium ion transfer reaction (B) a nuclear reaction 40. Which of the following contains the greatest percent chlorine by mass? xa (B) KcIO © Keo, (0) Ke10, © KeIo, 41, All ofthe following are good laboratory practices, EXCEPT (A) fire-polishing all sherp edges of glass tubes and rods (B) heating substances in test tubes only when the test tubes are pointed away from everyone ©@ slowly adding water to acid when diluting concentrated acids (D) conducting reactions that produce gaseous products in a fume hood (©) removing any nearby flammable reagents before lighting a bumer [soonroreneirnce )® 42. A sample originally contained 8.0 g of Ra-225, If the half-life of Ra-225 is 15 days, in how ‘many days will the sample contain only 1.0 g of Ra225? (A) 8 days B) 15 days (©) 30 days @ 45 cays (E) 60 days 60.15 +25 kd AH? AH XYq(g) > Xia) + Yale) xx) > X¥l8) 43. According to the reactions represented above, what is the standard enthalpy of reaction, AH”, for the following reaction? XYq() > X(g)+ Yale) 110%3 8510 ~60.10 35 Kd +25K5 44, A pH meteris used to measure the pH of a solution of NH,C1. Whena dilute solution of [NH is added to this solution, a change in pH js observed. The pH of the NH,CI solution would change in the same direction if which of the following were added to it? (A) HCI solution @ KOH solution (©) Solid NHCL (0) Solid NaCl () Solid sugait CHEMISTRY TEST—Continued 45. 46, Of the following, which i the strongest Bronsted- 48, [Fan aqueous solution containing 4 mol of NaOH “128° ® x65) + »CeS¥9) Sys) > When the equation above is balanced and all coefficients are reduced to lowest whole-mumber terms, the coefficient for Cr(s) is (A) 2 (B) 3 © 4 () 8 @» Lowry base? (a) NA, (B) Coy © H,0 @) a eur ‘To calculate the molar mass of a pore gas from experimental data, one must know all of the following for a sample of the gas EXCEPT its (A) mass boiling point © pressure (D) temperature (E) volume is mixed with one containing 3 mol of HCI, the final solution contains 1 mol of NaOH and 3 mol of NaCl L mol of HCI and 3 mol of NaCl (©) 3imolof NaOH and 1 molof NaC (D) 3 mol of NaOH and 1 mol of HCI (B) 4 mol of NaOH and 3 mol of HCl —__—_—— [ [eoowroTieneir ce) sponge 5 ea ~ oH aea CHEMISTRY TEST—Continued ® 9. When 1 mol of Cr+ is oxidized to form 1 mol 53, The mass of a piece of copper wire and the mass {of CrOJ*, how many mole of electrons are of a crucible are measured. ‘The copper wire is Ulansfered? placed in the crucible, covered with sulfur, and " heated to redness. The mass of the crucible DW 3 mo! containing the product is measured after cooling, |B) 4 mol All of the following are possible experimental (©) Sol - observations EXCEPT: @ : = (A) The products black, j (8) The productis sola (©) The product weighs more than the copper. Which of the following would most likely be © The bea With a reaction that cours at a high @ Bech copper atom has ost two electrons ate? ‘~) The copper wire has disappeared. (A) A large activation energy 54, ‘Which of the following configurations is that of an element ofthe group in the periodic table that contains nitrogen? A small activation energy ©) A low temperature * {D) A low concentration of reactants 2 asdag8 ‘E) A decrease in entroy (A) 15? 25229! " B) 12 25279632 ‘The best piece of equipment for delivering exactly W132 25%p53.2595 17.50 mL, of 0.3175 M hydrochloric acid into a (D) 1s? 2522p6 3923p5 clean, dry flask is a (B) 1s? 2522p 3,23p53a5 ds? 2p* 3839 (A) graduated cylinder ) Volumetric flask 55. Suppose that 0.5 mol of oxygen gas and 0.5 mol (©) beaker of nitrogen gas are placed in the same container ‘D) tet be and that no reaction occurs. In the container, the buret ratio of the pressure exerted by the nitrogen tothe * pressure exerted by he oxygen is equal io (a) os Al(s) + Chg) + AICI (5) w 3 “Vhen the equation above is balanced and all 3 beffcients are reduced to lowest whole-umber e terms, what is the coefficient for Al(s) ? 32 OF © 2 orped copying or Mots ae [soowro THe waxrmce i “129.® ‘56, Which ofthe following represents the relation between the volume and the absolute temperature ‘of 1 mol of an ideal gas at constant pressure? LL Absolut ‘Temperature (A) Volume, @) Volume Absolute ‘Temperature Volum Absolute: a Temperature 3 Volume ‘Absolute Temperature a Absolute ‘Temperature ® Volume CHEMISTRY TEST—Continued ® + i ZnS(s) + ---Ox(g) > ---Za0(s) +. SOK) | 57, When the equation for the reaction represented | above is balanced and all the coefficients are reduced to the Jowest whole-number terms, the | coefficient for O,(g) is wt @)2 7 ! 4 5 ® 5 } CHy(g) + 20,2) > COLS) + 24,00 58. Ifa mixture of 0.5 mol of CH,(g) and 2 mol of Og(g) react as represented above, how manly moles of each gas are present after the reactants 53 ae react as completely as possible? 1 chy 0; i w@ 05 tS | @ os os | © 0 0505 i @) 0 ot | @ 0 1 05 KCM(s) > K'(aq) + Ci-(aq) AH = +17.648 59. Based on the information above, which of the following conclusions is correct? (A) Atroor temperature, KCI is practically] i insoluble in water. (B) Athigher temperatures, KCI dissolves at very slow rate (©) The solubility of KCI in water decreases as temperature increases . (D) Heat is released as KCI dissolves in water @ Heats released as KCI crystallizes from 2 ‘water solution, @ -130-CHEMISTRY TES 280,(@) + O,(g) > 280,(e) “0. [fall measurements aré made under the same conditions, what volume of SO,(e) is produced | when 40 mL of SO,(g) and 20 mL of O;(e) react completely according to the equation above? » (A) 10mL (B) 20 at © @ 40m 5 ©) oot 1 @ 80mL 61. Which ofthe following can be observed when 120.0 mL of 1.0 M NaOH(aq), 10.0 mL of 1.0. HICK(aq), and a few drops of phenol- ,,phihalein ae combined and react? (BDA clear, pink sotution only (B) A clear, colorless solution only » (©) A white sold and a clea, colorless solution (D) A pink solid and 2 clear, colorless solution (E) A white solid and a clear, pink solution 4.1100. mL of each of the following aqueous solations is mixed with 100. mL. samples of 10 -M NaOH(ag), the greatest amount of heat | is liberated by (A) 0.010 M1 H,S0, (B) 0.010 Mf HCL (©) 0.10 a HCL (D) 0.10 H,S0, @omnc 53, Allof the following are good electrical conductors EXCI ) molten NaC @ gasoline (©) acopper wire (D) A silver soon © 1M HCI 131 T—Continued ® CHLOH() + ...0,(¢)(excess) > 64, Products of the complete combustion above include which of the following? 1Lco 11. CO, ML. 1,0 - (A) Lonly (B) Land If only Land IMT only (C) Wand 11 only F) 1, U0, and IL WO, + 3H, > W +3H,0 65, Which ofthe following is true for jhe reaction represented above? (A) WO, is oxidized. (B) W is the oxidizing agent. (©) H0 is reduced (0) H, is reduced 4% isthe reducing agent 2X43Y 4 4Z 66, According to the balanced equation above, the ‘maximum amount of compound Z that can be produced from a mixture of 0.10 mol of compound X and 0.12 mol of compound Y is @ 0.16 mol (B) 0.20 mot ©) 0.30 mot (D) 036 mol ©) 0.48 mol [soonron ono THENBATPaGE Pia)® 67. Mg{s) and No( following? (A) MeN ®) MeN (©) MeN, @ MeN, ©) MesNy ) react to form which of the 68, Sulfur has oxidation states of ~2, +2, +4, and +6 ‘and can be expected to form all of the following stable compounds EXCEPT (A) SP (B) SO, @ sc, (D) SO, (8) HLS 69. For which ofthe following clements in the ground state are there valence electrons in p orbitals? 1. Chlorine U. Oxygen IHL Magnesium (A) Lonly (B) U only Fond Honly (D) Land Mit only (B) 1,0, and UL CHEMISTRY TEST—Continued ® 10. A container with a volume of 22.4 L contains 2.0 g of Hy(e) and 32 g of O,(g) at 0°C. In this container {A) the total pressure is 760 mun Hg, (B) the average kinetic energy of the. Ox(@) molecules is 8 times the average kinetic energy of H(g) molecules {@@ the partial pressures of the gases are equal {D) allof the molecules in the system have the same average speed (&) allof the molecules have stopped moving because the temperature is 0°C STOP IF YOU FINISH BEFORE TIME IS CALLED, YOU MAY CHECK YOUR WORK ON THIS TEST ONLY DO NOT TURN TO ANY OTHER TEST IN THIS BOOK. [unsamocted copying or reuse o [sy par ti age toga A32- TT,