Revision Date 07/03/2013 Revision 13

Revision 13

SAFETY DATA SHEET

CRYSTIC CRESTOMER 1152PA

1. IDENTIFICATION

Product Name CRYSTIC CRESTOMER 1152PA

Product No. OL1001
Identification No. 1866
Identified uses Resin.
Supplier Scott Bader, Inc.
4280 Hudson Drive
Stow, OH 44224
Ph: 330-920-4410
Fax: 330-920-4415
Emergency (24 hours) ChemTrec (USA +
Canada):
1-800-424-9300
E-mail: reach@scottbader.com
Contact Person Regulatory Affairs Manager

2. HAZARD(S) IDENTIFICATION

Appearance Paste
Color White.
Odor Strong. Acrylic.
GHS Pictogram

Signal Word Warning

Hazard Statements
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
Precautionary Statements
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/attention.
Contains 2-HYDROXYETHYL ACRYLATE
STYRENE
GHS Classification
Physical and Chemical Hazards Flam. Liq. 3 - H226
Human health Acute Tox. 4 - H312;Acute Tox. 4 - H332;Skin Irrit. 2 - H315;Eye Irrit. 2 -
H319;Skin Sens. 1 - H317
Environment Not classified.
Human Health
In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Vapors/aerosol
spray may irritate the respiratory system. Risk of sensitization or allergic reactions among sensitive individuals.
General Information
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
Inhalation
Vapors may irritate throat and respiratory system and cause coughing. May cause damage to mucous membranes in nose, throat, lungs
and bronchial system.

1/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
Ingestion
Causes burns. May cause chemical burns in mouth and throat. May cause stomach pain or vomiting.
Skin Contact
Causes burns. Risk of sensitization or allergic reactions among sensitive individuals.
Eye Contact
Causes burns. Extreme irritation of eyes and mucous membranes, including burning and tearing.
Environment
The product is not expected to be hazardous to the environment.
Physical And Chemical Hazards
The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures.

3. COMPOSITION/INFORMATION ON INGREDIENTS

2-HYDROXYETHYL ACRYLATE <1%

CAS No.: 818-61-1 EC No.: 212-454-9

GHS Classification
Acute Tox. 3 - H311; Skin Corr. 1B - H314; Skin Sens. 1 - H317; Aquatic Acute 1 - H400

COBALT(II) 2-ETHYLHEXANOATE <0.2%

CAS No.: 136-52-7 EC No.: 205-250-6

GHS Classification
Acute Tox. 4 - H302; Skin Sens. 1 - H317; Repr. 2 - H361f; Aquatic Acute 1 - H400; Aquatic Chronic 1 - H410

STYRENE 40-45%

CAS No.: 100-42-5 EC No.: 202-851-5

GHS Classification
Flam. Liq. 3 - H226; Acute Tox. 4 - H332; Skin Irrit. 2 - H315; Eye Irrit. 2 - H319

Composition Comments
Urethane Acrylate Resin in reactive solvent

4. FIRST-AID MEASURES

Description of first aid measures

General Information
General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious. Get medical attention if any
discomfort continues.
Inhalation
Place unconscious person on the side in the recovery position and ensure breathing can take place. If respiratory problems, artificial
respiration/oxygen. Get medical attention.
Ingestion
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly.
Provide rest, warmth and fresh air. Get medical attention immediately!
Skin Contact
Use appropriate hand lotion to prevent defatting and cracking of skin. Immediately remove contaminated clothing. Wash off promptly and
flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Get medical attention promptly if
symptoms occur after washing.
Eye Contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

Most important symptoms and effects, both acute and delayed

2/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
Indication of any immediate medical attention and special treatment needed

5. FIRE-FIGHTING MEASURES

Flash point (°C) 33 CC (Closed cup).

Extinguishing Media
Fire can be extinguished using: Water spray, fog or mist. Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc. Do
not use water jet as an extinguisher, as this will spread the fire.
Unusual Fire & Explosion Hazards
Fire causes formation of toxic gases.
Special Fire Fighting Procedures
Use pressurized air mask if product is involved in a fire. Cool containers exposed to flames with water until well after the fire is out. Keep
run-off water out of sewers and water sources. Dike for water control.
Protective Equipment For Fire-Fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions
Wear protective clothing as described in Section 8 of this material safety data sheet.
Environmental Precautions
Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate
regulatory body.
Spill Clean Up Methods
Keep combustibles away from spilled material. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb
in vermiculite, dry sand or earth and place into containers. Wash thoroughly after dealing with a spillage.

7. HANDLING AND STORAGE

Handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapors. Use approved
respirator if air contamination is above accepted level. Vapors are heavier than air and may spread near ground to sources of ignition.
Storage
Flammable/combustible - Keep away from oxidizers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container. Avoid contact with oxidizing agents.
Storage Class
Flammable liquid storage.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

COMPONENT STD TWA (8-hrs) STEL (15 min) Notes

2-ETHYLHEXANOIC ACID ACGIH 5 mg/m3

ISOPHORONE DI-ISOCYANATE ACGIH 0.005 ppm

STYRENE ACGIH 20 ppm 40 ppm A4

COMPONENT IDLH
STYRENE 700 ppm

ACGIH=American Conference of Governmental Industrial Hygienists.

A4: Not Classifiable as a Human Carcinogen.

Protective Equipment

Process Conditions
Provide eyewash station.
Engineering Measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. All handling to take place in well-ventilated area.

3/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
Respiratory Equipment
Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. At work in confined or
poorly ventilated spaces, respiratory protection with air supply must be used. Wear mask supplied with: Gas cartridge suitable for organic
substances.
Hand Protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Neoprene. Nitrile. Rubber (natural,
latex).
Eye Protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene Measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly
remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or
smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Paste
Color White.
Odor Strong. Acrylic.
Solubility Insoluble in water
Flash point (°C) 33 CC (Closed cup).

10. STABILITY AND REACTIVITY

Stability
Stable under normal temperature conditions.
Hazardous Polymerisation
May polymerise.
Conditions To Avoid
Avoid exposure to high temperatures or direct sunlight.
Materials To Avoid
Alkali metals. Strong oxidizing substances. Strong acids. Strong alkalis. Organic peroxides/hydroperoxides. Inorganic peroxides.
Hazardous Decomposition Products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors.

11. TOXICOLOGICAL INFORMATION

Skin sensitiser, may cause an allergic reaction

12. ECOLOGICAL INFORMATION

Ecotoxicity
The product is not expected to be hazardous to the environment.
Toxicity
Not environmentally hazardous
Persistence and degradability
No data available.
Bioaccumulative potential
No data available.
Mobility:
No data available.
Results of PBT and vPvB assessment
No data available.
Other adverse effects
No data available.

13. DISPOSAL CONSIDERATIONS

Waste Management
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.

4/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
Disposal Methods
Dispose of waste and residues in accordance with local authority requirements. Make sure containers are empty before discarding
(explosion risk). Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste collection point.

14. TRANSPORT INFORMATION

UN No. (DOT/TDG) 1866

UN No. (IMDG) 1866

UN No. (ICAO) 1866

DOT Proper Shipping Name RESIN SOLUTION

TDG Proper Shipping Name RESIN SOLUTION

DOT Hazard Class

3
DOT Hazard Label
Flammable Liquid
TDG Class 3

TDG Label(s) 3

IMDG Class 3

ICAO Class 3

Transport Labels

FLAMMABLE
LIQUID
3

DOT Pack Group III

IMDG Pack Group III

Air Pack Group III

Environmentally Hazardous Substance/Marine Pollutant

No.

EMS F-E, S-E

Transport in Bulk according to Annex II of MARPOL 73/78 and the IBC Code Notes
Not applicable.

15. REGULATORY INFORMATION

US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
The following ingredients are listed.
ISOPHORONE DI-ISOCYANATE; EPCRA 302 TPQ 500 lbs Tier II TPQ 500 lbs
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)
The following ingredients are listed.
1, 4-NAPHTHAQUINONE; 5, 000 lbs (2270 Kg)
STYRENE; 1, 000 lbs (454 Kg)
SARA Extremely Hazardous Substances EPCRA Reportable Quantities
The following ingredients are listed.
ISOPHORONE DI-ISOCYANATE; 500 lbs
SARA 313 Emission Reporting
The following ingredients are listed.
COBALT(II) 2-ETHYLHEXANOATE 0.12%
ISOPHORONE DI-ISOCYANATE 0.07%
STYRENE 44.49%
CAA Accidental Release Prevention
None of the ingredients are listed.

5/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
OSHA Highly Hazardous Chemicals
None of the ingredients are listed.

US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
The following ingredients are listed.
2-ETHYLHEXANOIC ACID; Known to the State of California to cause developmental and reproductive toxicity.
California Air Toxics “Hot Spots” (A-I)
The following ingredients are listed.
STYRENE
California Air Toxics “Hot Spots” (A-II)
None of the ingredients are listed.
Massachusetts "Right To Know" List
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-HYDROXYETHYL ACRYLATE
ISOPHORONE DI-ISOCYANATE
STYRENE
Rhode Island "Right To Know" List
The following ingredients are listed.
ISOPHORONE DI-ISOCYANATE
STYRENE
Minnesota "Right To Know" List
The following ingredients are listed.
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE
New Jersey "Right To Know" List
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
ISOPHORONE DI-ISOCYANATE
STYRENE
Pennsylvania "Right To Know" List
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-HYDROXYETHYL ACRYLATE
ISOPHORONE DI-ISOCYANATE
STYRENE

International Inventories
EU - EINECS/ELINCS
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
ISOPHORONE DI-ISOCYANATE
STYRENE
Canada – DSL/NDSL
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
FUMED SILICIA (CAB-O-SIL)
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE

6/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
US - TSCA
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE
US – TSCA 12(b) Export Notification
None of the ingredients are listed.
Australia - AICS
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
FUMED SILICIA (CAB-O-SIL)
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE
Japan – MITI
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE
Korea - KECI
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
FUMED SILICIA (CAB-O-SIL)
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE
China - IECSC
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
FUMED SILICIA (CAB-O-SIL)
ISOPHORONE DI-ISOCYANATE
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE
Phillippines – PICCS
The following ingredients are listed.
1, 4-NAPHTHAQUINONE
2-ETHYLHEXANOIC ACID
2-HYDROXYETHYL ACRYLATE
COBALT(II) 2-ETHYLHEXANOATE
DE-AROMATISED KEROSENE
FUMED SILICIA (CAB-O-SIL)
ISOPHORONE DI-ISOCYANATE

7/ 8
 Revision 13
CRYSTIC CRESTOMER 1152PA
PEG 6000 (POLYOXYETHYLENE GLYCOL)
STYRENE

16. OTHER INFORMATION

HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS)

HEALTH
1
FLAMMABILITY
2
PHYSICAL
1
PERSONAL PROTECTION

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)

FIRE
(2)
HEALTH
(1) (0)

INSTABILITY

SPECIAL

Revision Date 07/03/2013

Revision 13

Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
8/ 8