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Petrology: Petroleum Geology I 2011-2012
Petrology: Petroleum Geology I 2011-2012
Petroleum Geology I
2011-2012
P.B.Jadhav
Petroleum Geology I P B Jadhav
Petrology
Earth is a system made up of many interacting parts. This idea is better
illustrated in the rock cycle. As it can be seen from this figure, magma, which
is a molten material, form inside the Earth. Magma cools a nd solidifies. This
process called crystallization and may occur either beneath the surface or
following a volcanic eruption at the surface. In both cases, the resulting rocks
are called igneous rocks.
If igneous rocks are exposed a t the surface, they will undergo weathering, in
which the atmosphere slowl y affects these rocks and disintegrate and
decompose them. The resultant materials move downslope by gravit y or by
many other erosional agents such as running water, glaciers, winds or waves.
These particles and dissolved particles are called sediments. Sediments come
to rest in the ocean or other depositional sites such as river floodplains, desert
basins, swamps and dunes.
The accumulated sediments undergo lithification (i.e. solid ify to rocks)
changing into sedimentary rocks. If the resulting sedimentary rocks are buried
deep within the Earth, it will be subjected to great pressure and or heat
changing into metamorphic rocks. When metamorphic rocks are subjected to
additional pressure or heat, it will melt, creating magma, which will eventuall y
crystallize into igneous rocks.
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Minerals
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occurring. Some minerals like gold or sulfur are made entirel y of one element,
but most minerals are a combination of two or more elements, joined to form a
chemicall y stable compound.
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There can exist several minerals all sharing the same composition. We call
these pol ymorphs (literall y, "many forms"). A good example is the pol ymorph
of C. Diamond is a 3D, cubic lattice of covalentl y bonded carbon atoms.
Graphite is also pure carbon, but here the carbon atoms form sheets that are
held together by weak v an der Waals forces. These pol ymorphs can exist
together, but they are not formed at similar pressure and temperature
conditions. To understand this we need to examine the phase diagram of C. At
high pressures and temperatures, diamond is the preferred min eral. At low
temperatures and pressures, graphite is more stable.
In the diagram, the geothermal gradient (how temperature varies with depth or
pressure in the Earth) is superimposed on the stabilit y fields of Carbon. Thus
we know that when we find diamon d it came from someplace in the Earth
where the temperature is greater than 1500oC and the pressure is higher than
50,000 atmospheres (equivalent to a depth of about 170 km).
Minerals are solids formed by inorganic processes . Each mineral has an orderl y
arrangement of atoms (crystalline structure) and a definite chemical
composition, which give it a particular set of physical properties. Because the
internal structure and chemical composition of a mineral are difficult to
determine without the aid of sophisticated tests and equipment, the more easil y
recognized physical properties are frequentl y used in identification. The
following are the main physical properties of minerals:
Crystal form
Most inorganic solid objects are co mposed of crystals, however, most crystals
do not exhibit their crystal form.
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Crystal form is the external expression of a mineral that reflects the orderl y
internal arrangement of atoms.
Luster
Colour
Streak
Streak is the colour of the mineral powder and it is obtained by robbing the
mineral across a piece of unglazed porcelain termed streak plate. The streak
colour may be different from the colour of the mineral and it is generall y mo re
reliable tool in mineral identification. Metallic minerals generall y have a
dense, dark streak.
Hardness
Hardness is one of the most useful diagnostic properties, which is the measure
of the resistance of a mineral to abrasion or scratching. This proper t y is
determined by rubbing a mineral of unknown hardness against one known
hardness or vice versa.
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Hardness of some
Relative scale Mineral
common objects
Hardest 10 Diamond
9 Corundum
8 Topaz
7 Quartz
6 Feldspar
5.5 glass,
5 Apatite
pocketknife
4 Fluorite
3 Calcite 3 copper penny
2 Gypsum 2.5 fingernail
Softest 1 Talc
Cleavage
In the crystal structure of a mineral, some bonds are weaker than others. These
bonds are where a m ineral will break when it is stressed. Cleavage is the
tendency of a mineral to break along planes of weak bonding. Not all minerals
have definite planes of weak bonding but those that posses cleavage can be
identified by the smooth surfaces that are produ ced when the mineral is
broken.
Some minerals have cleavage in one direction such as mica breaking into thin,
flat sheets. Some minerals have several cleavage planes, which produce smooth
surfaces when broken (calcite), while others exhibit poor cl eavage and others
have no cleavage at all (quartz).
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Fracture
Minerals that do not exhibit cleavage when broken, such as quartz are said to
fracture. These that break into smooth curved surfaces resembling broken glass
have a conchoidal fracture. Others break into fibers or splinters, but most
minerals fracture irregularl y.
Specific gravity
Taste: salt
Magnetism: Magnetite
Ductile: Gold
Feeling: Talc has a soapy feeling, graphite has a greasy feeling.
Double refraction: calcite
Bad smell (rotten egg): Sulfur
Effervescence when treated with diluted acid: Calcite
The silicates are the most abundant mineral group and have the silicate ion
(SiO4-4) as their building block. The major silicate groups and common
examples are given in table ( 2.2). The feldspars are the most plentiful silicate,
comprising over 50% of Earth's crust. Quartz, the second most abundant
mineral in the continental crust, is the onl y common mineral made completel y
of silicon and oxygen.
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Most silicate minerals form (crystallize) as molten rock is cooling. This
cooling can occur at or near Earth's surface (low temperature and pressure) or
at great depth (high temperature and pressure). The environment during
crystallization and the chemical composition of the molten rock determine to a
large degree which minerals are produced.
Some silicate minerals form at Earth's surface from the weathered products of
older silicate minerals. Others formed under the extreme pressure associated
with mountain building. Therefore, each sil icate mineral has a structure and a
chemical composition that indicate the conditions under which is formed.
The dark or ferromagnesian silicates are those minerals containing ions of iron
(iron: Ferro) and / or magnesium i n their structure. Because of their iron
content, ferromagnesian silicates are dark in colour and have a greater specific
gravit y. The most common dark silicate minerals are:
Olivine: olivine is a famil y of high -temperature silicate minerals that are black
to olive green in colour and have a glassy luster and a conchoidal fracture.
Olivine is composed of small, rounded crystals.
Biotite is the dark iron -rich member of the mica famil y. Like other micas,
biotite posses a sheet structure that give it excellent cleavage in one direction.
Biotite has also a shiny black appearance.
As the name implies, the light (or nonferromangnesian) silicates are generall y
light in colour and have a specific gravity of about 2.7, which is lower than the
ferromagnesian silicates. These differences are attributed to the presence or
absence of iron and magnesium. The light silicates contain varying amounts of
aluminum, potassium, calcium and sodium rather than iron and magnesium.
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Muscovite is a common member of the mica famil y. It is light in colour and has
a pearl y luster. Like other micas, muscovite has excellent cleavage in one
direction.
Feldspar the most common mineral group can form under a very wide range of
temperatures and pressures. All of the feldspars have similar physical
properties. They have two planes of cl eavage meeting at near 90 degree and are
relativel y hard (6 on the Moh's scale) and have a luster that ranges from glass y
to pearl y.
The group member rich in potassium is called Orthoclase, the group that
contains both sodium and calcium ions are called pl agioclase.
Quartz is the onl y common silicate mineral consisting entirely of silicon and
oxygen. As such, the term silica is applied to quartz, which has the chemical
formula SiO2. In a pure form, quartz is clear and has hexagonal crystal form.
If contains impurities, it may take several colours. The most common are
milky, smoky, rose and pinky.
There are three principal groups with wh ich we are concerned and they are
distinguished by their structure which controls their behavior. These groups
are the montmorillonite / smectite (expanding lattice , three layer t ype ), the
kaolinite (two layer structures) and the illite (non-expanding lattice, three
layer structure) .
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Other mineral groups can be considered rare when compared to the silicates ,
although many are important economically.
Carbonate minerals : the carbonate minerals have less complex structure than
silicates. This group is composed of the carbonate ion (CO2 -2) and one or
more kinds of positive ions. The two most common carbonate mi nerals are
calcite (CaCO3) and dolomite (CaMg (CO 3 ) 2 ). When calcite is the dominant
mineral, the rock is called limestone, whereas, dolostone results from a
predominance of dolomite.
Halite and Gypsum (Evaporites): Both minerals are commonl y found in thick
layers that deposited from ancient seas. Both are important nonmetallic
resources. Halite is the mineral name for the common salt table (NaCl).
Gypsum (CaSO4.2H2O) is the mineral of which plaster and other similar
building materials are composed.
The Native Elements are just that, minerals of a single element. Native Copper
(Cu) is an example. These are usuall y found in places where very warm water
has reacted with other rocks, enriching it in elements that don't enter into rock -
forming minerals readil y.
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Igneous Rocks
Igneous rocks form the major part of the Earth's crust. They along with the
metamorphic rocks constitute 95% in terms of weight proportion in the earth’s
crust. When it comes to volume proportion the igneous and metamorp hic rocks
(20% + 5%) cover 25% of the earth’s surface.
The term Igneous is derived from the Latin root ignis, which means fire,
because these rocks form as molten rocks that cool and solidify. The parent
materials for igneous rocks are called magma, which form by partial melting of
rocks within the Earth's crust and upper mantle at depths that may be more
than 200 km.
Once formed, the magma will rise toward the surface because it is less dense
than the surrounding rocks. In some cases, molten rocks break through
surrounding rocks forming volcanoes. Magma that reaches Earth surface is
called lava.
Based on the relationship with the parent rocks the igneous rocks are classified
as intrusive and extrusive rocks (figure below). The intrusive rocks maintain
concordant or discordant relationship with parent rock and the extrusive rocks
overlie the parent rock. The intrusive rocks are further divided into Plutonic
(deep seated) and Hypabyssal (shallow depth) based on their depth of
crystallization.
The concordant intrusions grow parallel to the parent rock and are called sills
while the discordant intrusions maintain angular contact with host and based
on their geometry abs scale of development they are given different names
(dyke, batholith, laccolith)
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Pyroclastic
Extrusive
Intrusive
Shallow
Intrusion
Although volcanic eruption may be the most violent events in nature, more
magma is placed depth. Thus, an understanding of intrusive igneous activit y is
as important to geologists as the study of volcanic events. The structures that
result from the emplacement of igneous material at depth are called plutons,
named for Pluto, the god of the lower world in Greek m ythology. Because all
plutons form out of vi ew beneath Earth's surface, they can be studied onl y
after uplifting and erosion have exposed them. The challenge lies in
reconstructing the events that generated these structures millions or even
hundreds of millions of years ago.
Nature of Plutons
Plutons are said to be discordant if they cut across existing structures and
concordant if they form parallel to features such as sedimentary strata. As you
can see in Figure plutons are closel y associated with volcanic activit y. Many
of the largest intrusive bo dies are the remnants of magma chambers that once
fed ancient volcanoes.
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Dikes
Dikes are tabular discordant bodies that are produced when magma is injected
into fractures. The force exerted by the emplaced magma can be great enough
to separate the walls of the fracture further. Once crystallized, these sheetlike
structures have thicknesses ranging from less than a centimeter to more than a
kilometer. The largest have lengths of hundreds of kilometers. Dikes often
weather more slowly than the surrounding rock. When exposed by erosion,
these have the appearance of a wall, as shown in Figure
Sills
Sills are tabular plutons formed when magma injected along bedding surfaces
and along the boundary. Horizontal sills are the most common, at all
orientations, even vertical. Because of their relativel y uniform thickness and
large areal extent, sills are likel y the product of very fluid magmas. Magmas
having low silica content are very fluid; so most sills are composed of the rock
basalt.
In many respects , sills closel y resemble buried lava flows. Both are tabular and
often exhibit columnar jointing. Columnar joints form as igneous rocks cool
and develop shrinkage fractures that produce elongated, pillar like columns.
Further, because sills generall y form in near-surface environments and may be
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onl y a few meters thick, the emplaced magma often cools quickl y enough to
generate an aphanitic texture .
Laccoliths
Laccoliths are similar to sills because they form when magma is intruded
between sedimentary layers in a near-surface environment. However, the
magma that generates laccoliths is more viscous. This less fluid magma
collects a lens -shaped mass that arches the overl ying strata upward.
Batholiths
These are the largest intrusive igneous bodies; they occur i n groups that form
linear structures several hundreds of kilometers long and up to 100 km wide.
Smaller batholiths less than 100 km 2 are called stocks.
Magma is molten rock that contains suspended crystals and dissolved gases,
mainl y water vapor that is co nfined within the magma by the pressure of the
surrounding rocks. The bulk of magma is composed of mobile ions of eight
most abundant elements of the Earth's crust. These elements include silicon,
oxygen, aluminum, potassium, calcium, sodium, iron and mag nesium.
As the magma cools, the movement of these ions slow and they begin to
arrange themselves into crystalline structures. This process is called
crystallization, and lead to the precipitation of minerals from the magma.
Igneous Textures
Texture: is the overall appearance of the rock based on the size, shape and
arrangement of its interlocking crystals. Texture can reveal a great deal about
the environment in which the rock is formed.
There are three factors that affect th e crystal size of igneous rocks:
1. The rate at which magma cools: rapid cooling produces fine grained
textures and vice versa. Very rapid cooling produces glass: amorphous
materials with no texture.
2. The amount of silica present.
3. The amount of dissolved gases in the magma.
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In some aphanitic rocks, there are void left by gas bubbles that escape during
the magma cooling. These are called vesicles and the resultant texture many be
called vesicular.
Phaneritic (coarse -grained) textu re: When magma slowl y solidifies far below
the surface, they form igneous rocks that exhibit a coarse -grained texture
described as phaneritic. These rocks consist of intergrown crystals, roughl y
equal in size and large enough to be identified with the unai ded eye.
Glassy texture: Rapid cooling may generate rocks having a glassy texture.
Glass results when unordered ions are "frozen" before they are able to unite
into a crystalline form. Obsidian is a common t ype of natural glass.
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Magmas with high silica content tend to form long structures before full
crystallization. Magma movement is a function of its viscosit y, which is a
measure of a fluid's resistance to flow.
As magma cools, these elements combine to form two major groups of silicate
minerals: the dark (or ferromagnesian) silicates that are rich in iron and / or
magnesium and low in silica, and the light silicates that include quartz,
muscovite and the most abundant group, the feldspar.
Despite their great compositional diversity, igneous rocks can be divided into
broad groups according to their content of light and dark minerals.
1. Granitic rocks: these are rocks composed mainl y of the light -coloured
silicates- quartz and feldspar. They contain 70% silica and they form the
continental crust.
Igneous rocks with compositions between these major groups as well as those
totall y devoid of either light or dark minerals are also known.
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Dunite
Basalt
Syenite
Diorite
Granite
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react with the remaining melt to form the mineral pyroxene (single chain). As
the magma cools further, the pyroxene crystals will react with the melt to
generate amphibole (double -chain). This reaction will continue until the last
mineral in this series, biotite is formed. This branch of Bowen's series is called
discontinuous reaction series because at each step a different silicate structure
emerges.
Continuous reaction series : represents the right branch of the reaction series
and illustrates that c alcium-rich plagioclase feldspar crystals react with sodium
ions in the melt to become progressively more sodium -rich. During the last
stage of crystallization, after much of the magma has solidified, potassium
feldspar forms. Finally the remaining melt ha s excess silica, the mineral quartz
will precipitate.
Magmatic differentiation
Once a magma body forms, its composition can change through the
incorporation of foreign material. This process is called assimilation. This
process may operate in a near -surface environment where rocks are brittle. As
the magma pushes upward, stress causes numerous cracks in the overl ying
rock. The force of the injected magma is often strong enough to dislodge
blocks of "foreign" rock and incorporate them into the magma body. In other
environments, the magma may be hot enough to simpl y melt and assimilate
some of the surrounding host rock.
Magma mixing: this is another process that occurs whenever one magma body
intrudes another. Once combined, the two magmas generate a fluid with a
different compositio n. Magma mixing may occur during ascent, as a more
buoyant magma body overtakes a mass of magma that is rising more slowl y.
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basaltic is often used to describe any rock of similar composition.
Furthermore, because basaltic rocks contain high pe rcentage of ferromagnesian
minerals, these rocks are also called mafic rocks (from magnesium and
ferrum), the Latin name for iron). They are t ypicall y darker and denser than
other igneous rocks.
* Among the last minerals to crystallize are potas sium feldspar and quartz, the
primary components of the abundant rock granite. Igneous rocks in which these
two minerals predominate are said to have a granitic composition. Geologists
refer to granitic rocks as being felsic (from feldspar and silica: quar tz).
Granite
Granite is perhaps the best known of all igneous rocks. This is because of its
natural beaut y, which is enhanced when it is polished, and partl y because of its
abundance in the continental crust.
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Granite is a phaneritic rock composed of between 25 -35% quartz and over 50%
potassium Fe;feldspar and sodium -rich plagioclase. The quartz crystals, which
are roughl y spherical in shape, are often glassy and clear to light -gray in
colour. In contrast to quartz, feldspar crystals are not as glassy, are generall y
white to gray or pink in colour and exhibit a rectangular shape.
Other common constituents of granite are muscovite and some dark silicates,
mainl y biotite and amphibole. Although the dark components generall y make
up less than 20% of most granites, dark minerals appears to be more prominent
than their percentage would indicate.
Rhyolite
Rhyolite has the same mineral components of granite but with a fine -grained
volcanic texture. Like granite, this rock is composed of light -coloured
silicates. This fact accounts for its colour, which is usually buff to pink or
sometimes very light grey. Rhyolite is usuall y aphanitic and frequentl y
contains glassy fragments and voids indicating rapid cooling in the surface.
Obsidian
Obsidian is a dark -coloured, glassy rock that forms when silica -rich lava cool
rapidl y. This rock is not composed of minerals in the same sense as most other
rocks.
Although black or reddish -brown in colour, it has a high silica content, Silica
is clear like window glass, the dark colour results from the presence of
metallic ions.
Pumice
Pumice is a volcanic rock that, like obsidian, has a glassy texture. Usuall y
found with obsidian, pumice forms when large amount of gas escape through
lava to generate a grey, frothy mass. In some samples, the voids are noticeable.
Because of the large percentage of voids, many samples of pumice will float
when placed in water.
Andesite
Diorite
Diorite is a coarse -grained plutonic rock that looks similar to grey granite. It
can be distinguished from granite by the absence of visible quartz crystals. The
main components of diorite are sodium -rich plagioclase and amphibole. with
lesser amount of biotite.
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Mafic (Basaltic) rocks
Basalt
Basalt is a very dark green to black, fine -grained volcanic rock composed
mainl y of pyroxene and calcium -rich plagioclase with lesser amount of olivine
and amphibole. It is the most common volcanic igneous rock. Man y volcanic
islands such as the Hawaiian Islands are composed mainl y of basalt. The upper
layer of the oceanic crust consists of basalt also.
Gabbro
Gabbro is the plutonic equivalent of basalt. Like basalt, it is very dark green to
black in colour and compo sed primaril y of pyroxene and calcium -rich
plagioclase. Gabbro makes up a significant percentage of the oceanic crust.
Pyroclastic rocks
Metamorphic Rocks
Metamorphic Environments
Recall from the sectio n on the rock cycle that metamorphism is the
transformation of one rock t ype into another. Metamorphic rocks can be
transformed from igneous, sedimentary, or even from other metamorphic rocks.
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temperatures approach those at which rocks melt. However, during
metamorphism some mate rial must remain solid, for if complete melting
occurs, we have entered the realm of igneous activit y.
Contact metamorphism
2. The least common t ype of metamorphism occurs along fault zones and is
called cataclastic metamorp hism. Here rock is broken and pulverized as crustal
blocks on opposite sides of a fault grind past one another.
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Dynamothermal
Metamorphism
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Agents of Metamorphism
As stated earlier, the agents of metamorphism include heat, pre ssure (stress),
and chemicall y active fluids. During metamorphism, rocks are often subjected
to all three metamorphic agents simultaneousl y. However, the degree of
metamorphism and the contribution of each agent vary greatl y from one
environment to another . In low-grade metamorphism, rocks are subjected to
temperatures and pressures onl y slightl y greater than those associated with the
lithification of sediments. High -grade metamorphism, on the other hand,
involves extreme tectonic forces and temperatures cl ose to those at which
rocks melt.
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per kilometer. When buried to a depth of onl y a few kilometers, certain
minerals, such as clay, become unstable and begin to recrystallise into
minerals, such as muscovite (mica), that are stable in this environment. Other
minerals, particularly those found in crystalline igneous rocks, are stable at
relativel y high temperatures and pressures and therefore may require burial to
20 kilometers or more before metamorphism will occur.
Differential stress can also cause a rock to sh ear. Shearing is similar to the
slippage that occurs between individual cards when you hold a deck flat
between your hands and slide your hands in opposite directions, shearing the
deck. In near-surface environments, shearing results when relativel y brittl e
rock breaks into thin slabs that are forced to slide past one another. This
deformation grinds and pulverizes the original mineral grains into small
fragments. By contrast, because rocks located at great depths are warmer, and
under greater confining pre ssure, they tend to behave plasticall y during
deformation. This accounts for their abilit y to flow and bend into intricate
folds when subjected to shearing .
Chemicall y active fluids also enhance the metamorphic pro cess. Most
commonl y, the fluid is water -containing ions in solution. Water is plentiful,
because some water is contained in the pore spaces of virtually every rock. In
addition, many minerals are hydrated (have water bound chemicall y) and thus
contain water within their crystalline structures.
When deep burial occurs, rocks become more compact, reducing the amount of
pore space. Thus, water is forced out of the rock and becomes available to aid
in chemical reactions. Further, heating causes the dehydration of minerals and
the release of water. Water that surrounds the crystals acts as a catal yst by
aiding ion migration. In some instances water promotes the recrystallization of
minerals, which form more stable configurations. In other cases, ion exchange
among minerals results in the formation of completel y new minerals.
Complete alteration of rock by hot, mineral -rich water has been observed in
the near-surface environment of Yellowstone National Park. On a much larger
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scale similar activit y occurs along the mid-ocean ridge system. Here, seawater
circulates through the still -hot basaltic rocks, transforming iron - and
magnesium-rich minerals into metamorphic minerals such as serpentine and
talc.
Textural Changes
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The crystals of some minerals, such as micas (plat y minerals) and hornblende
(needlelike minerals), will recrystallize with a preferred orientation. The new
orientations will be essentiall y perpendicular to the direction of the
compressional force as shown on the right side in Figure 7.5. The resulting
mineral alignment usuall y gives the rock a layered or banded texture termed
foliation (Figure 7.5). Simpl y put, a foliated texture results whenever the
minerals and structural features of a metamorph ic rock are forced into parallel
alignment.
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Nonfoliated Texture. Not all metamorphic rocks have a foliated texture. Those
that do not are nonfoliated. Metamorphic rocks composed of onl y one mineral
that exhibits equidi mensional crystals usuall y are not visibl y foliated. For
example, when a fine-grained limestone (made of a single mineral, calcite) is
metamorphosed, the small calcite crystals combine to form relativel y large
interlocking crystals. The resulting rock, mar ble, has a texture similar to that
of a coarse-grained igneous rock. Although most marbles are nonfoliated,
microscopic investigation of marble may reveal some flattening and
parallelism of the grains.
Further, some limestones contain thin layers of clay m inerals that may become
distorted during metamorphism. The "impurities" will often appear as curved
bands of dark material flowing through the marble, a clear indication of
metamorphism.
Mineralogical Changes
In the metamorphism of shale to slate, you saw that clay minerals recrystallize
to form mica crystals. During most recrystallization, including this example,
the chemical composition of the rock does not change (except for the loss of
water and carbon dioxide). Rather, the existing minerals and availab le ions in
the water will recombine to form minerals that are stable in the new
environment. A common example is when limestone (CaCO3), containing
abundant quartz (SiO2), is heated during contact metamorphism. The calcite
and quartz crystals chemicall y re act to form wollastonite (CaSiO3), and carbon
dioxide is liberated. In some environments, however, new materials are
actuall y introduced during the metamorphic process. For example, rock
adjacent to a large magma body would acquire new elements from hydrot her-
mal solutions (hot water). Many metallic ore deposits are formed by the
deposition of minerals from hydrothermal solutions.
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With the development of plate tectonics, it became clear that some metal -rich
hydrothermal deposits originate along ancient spre ading centers (mid-ocean
ridges). As seawater percolates through newl y formed oceanic crust, it
dissolves metallic sulfides from the basaltic rocks. The hot, metal -rich fluids
rise along fractures and gush from the seafloor as particle -filled clouds called
black smokers. Upon mixing with the cold seawater, the sulfides precipitate to
form massive metallic deposits. This is the origin of the copper ores mined
today on the island of C yprus. Some of Earth's richest copper deposits have
formed in this manner.
Foliated Rocks
Slate. To review, slate is a very fine -grained foliated rock composed of minute
mica flakes. The most noteworthy characteristic of slate is its excellent rock
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cleavage, or tendency to break into flat slabs. This propert y traditionall y made
slate a most useful rock for roof and floor tile, blackboards, and billiard tables
(Figure 7.7).
Schist. Schists are strongl y foliated rocks that can be readily split into thin
flakes or slabs. By definition, schists contain more than 50 percent plat y and
elongated minerals that commonl y include mica (muscovite, biotite) and
amphibole. Like slate, the parent material from which many schists originate is
shale, but to form schist, the metamorphism is more intense. In addition, most
schists are products of major mountain -building episodes.
The term schist describes the texture of a rock. To denote the composition, the
mineral names are used as well. For example, schists composed primaril y of
the micas muscovite and biotite are called mica schists. Depending upon the
degree of metamorphism and composition of the paren t rock, mica schists often
contain accessory minerals unique to metamorphic rocks. Some common
accessory minerals include garnet, staurolite, and sillimanite, in which case the
rock is called garnet -mica schist, staurolite -mica schist and so forth (Figure
7.10). Some schists contain another accessory mineral, graphite, which is used
as pencil "lead," graphite fibers (used in fishing rods), and lubricant
(commonl y for locks).
Gneiss. Gneiss is the term applied to banded metamorphic rocks that contain
mostl y elongated and granular (as opposed to plat y) minerals. The most
common minerals 4n^ gneiss are quartz, potassium feldspar, and sodium
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Petroleum Geology I P B Jadhav
feldspar. Lesser amounts of muscovite, biotite, and hornblende are common.
The segregation of light and dark silicates is developed in gneisses, giving
them a characteristic banded appearance. Thus, most gneisses consist of
alternating bands of white or reddish feldspar -rich zones and layers of dark
ferromagnesian minerals. Folding and flowing often deform these banded
gneisses while in a plastic state. Some gneiss will split along the layers of
plat y minerals, but most break in an irregular fashion.
Those gneisses that have a composition similar to that of granite are probabl y
derived from granite or its aphanitic equivalent. However, they may also form
from the high-grade metamorphism of shale. In this instance, gneiss represents
the last rock in the sequence of shale, slate, phyllite, schist, and gneiss.
Like schists, gneisses may also include large crystals of accessory min erals
such as garnet and staurolite. Gneisses can also be made up primaril y of dark
minerals such as those that compose basalt. For example, an amphibole -rich
rock that exhibits a gneissic texture is called ampbibolite gneiss.
Nonfoliated Rocks
Marble. Marble is a coarse, crystalline rock whose parent rock was limestone
or dolostone. Pure marble is white and composed essentially of the mineral
calcite. Because of its attractive color and relative softness (hardness of 3),
marble is a popular building stone in banks and government buildings. White
marble is particularly prized as a stone from which to carve monuments and
statues, such as the famous statue of David by Michelangelo. Unfortunatel y,
because marble is basicall y calcium carbonate, it is readil y att acked by acid
rain. Some historic monuments and tombstones already show severe chemical
weathering.
Often the limestone from which marble forms contains impurities that color the
marble. Thus, marble can be pink, gray, green, or even black. Also, when
impure limestone is metamorphosed, the resulting marble may contain a variet y
of accessory minerals (chlorite, mica, garnet, and commonl y wollastonite).
When marble forms from limestone interbedded with shales, it will appear
banded. Under extreme deformation, such banded marble may become highl y
contorted and give the rock a rather artistic design.
Quartzite. Quartzite is a very hard metamorphic rock most often formed from
quartz sandstone (Figure). Under moderate -to-high-grade metamorphism, the
quartz grains in sandstone fuse like chips of glass melting together (inset in
Figure). The recrystallization is so complete that when broken, quartzite will
not split between the original quartz grains, but through them. In some
instances, such sedimentary features as crossbedding are preserved and give
the rock a banded appearance. Quartzite is t ypicall y white, but iron oxide may
produce reddish or pinkish stains. Dark mineral grains may impart a gray
color.
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Petroleum Geology I P B Jadhav
Contact Metamorphism
Contact metamorphism occurs when magma i nvades cooler rock Here, a zone
of alteration called an aureole (or halo) forms around the emplaced magma.
Small intrusive magma bodies that generate dikes and sills have aureoles onl y
a few centimeters diick. By contrast, large magma bodies that crystalli ze to
form batholiths may create zones of metamorphic rock several kilometers
thick. These large aureoles often consist of distinct zones of metamorphism.
Near the magma body, high -temperature minerals such as garnet may form,
whereas farther away such low -grade minerals as chlorite are produced.
In addition to the size of the intrusive magma body, the mineral composition of
the host rock and the availabilit y of water greatl y affect the size of the aureole
produced. In chemicall y active rock such as limestone, the zone of alteration
can extend 10 kilometers or more from the magma body. Here the occurrence
of minerals such as garnet and wollastonite mark the areas of metamorphism.
Most contact metamorphic rocks are fine grained, dense, tough, and of various
chemical compositions. For example, during contact metamorphism, clay
minerals are baked, as if placed in a kiln, and can generate a very hard, fine -
grained rock resembling porcelain. Because directional pressure is not a major
factor in forming t hese rocks, they generall y are not foliated. Homfe l is the
name applied to the wide variet y of rather hard, nonfoliated metamorphic rocks
formed during contact metamorphism.
When large igneous plutons cool, hot, ion -rich fluids (hydrothermal solutions)
that do not crystallizeare expelled. These solutions percolate through the
surrounding host rock, chemicall y reacting with it and promoting the
metamorphic process. In addition, hydrothermal solutions are the source of a
variet y of metallic ore deposits that can be profitabl y extracted from
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Petroleum Geology I P B Jadhav
metamorphic rocks. Such deposits include ores of copper, zinc, lead, iron, and
gold.
Near the surface, rock behaves like a brittle solid. Consequentl y, movement
along a fault zone fractures and pulverizes rock. In some cases, rock may even
be milled into very fine components. The result is a loosel y coherent rock
called fault breccia that is compo sed of broken and crushed rock fragments.
Displacements along California's San Andreas fault have created a zone of
fault breccia and related rock t ypes over 1000 kilometers long and up to 3
kilometers wide. This type of localized metamorphism, which invol ves purel y
mechanical forces that pulverize individual mineral grains, is called cataclastic
metamorphism.
Much of the intense deformation associated with fault zones occurs at great
depth. In this environment the rocks deform by ductile flow, which genera tes
elongated grains that often give the rock a foliated or lineated appearance.
Rocks formed in this manner are termed mylonites. Worldwide, the quantit y of
metamorphic rock generated solel y by faulting is small when compared to the
other processes. Never theless, in some areas these granulated rocks are quite
abundant.
Regional Metamorphism
building. During these dynamic e vents, large segments of Earth's crust are
intensel y squeezed and become highl y deformed . As the rocks are folded and
faulted, the crust is shortened and thickened, like a rumpled carpet. This
general thickening of the crust results in terrains that are l ifted high above sea
level.
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Petroleum Geology I P B Jadhav
Consequentl y, the cores of many mountain ranges consist of folded and faulted
metamorphic rocks often intermixed with igneous rocks. As these deformed
rock masses are uplifted, erosion removes the overl ying material to expose the
igneous and metamorphic rocks that comprise the central core of the mountain
range
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