WELCOME

PT ENERGI SEJAHTERA MAS

LUBUK GAUNG
DUMAI

5th February 2018

17 Oct 2016

This document is for the use of Sinarmas Cepsa personnel only. It should not be published, duplicated, or shown to others without permission.
 SITE OVERVIEW LUBUK GAUNG

PT ENERGI SEJAHTERA MAS

This document is for the use of Sinarmas Cepsa personnel only. It should not be published, duplicated, or shown to others without permission.
Oleochemical Industry

Fatty Acid & their derivatives

Fatty Acid Amide
Fatty Alcohol & derivatives
Glycerine & derivatives
Tocotrienol, Tocopherol, Beta
Carotene
Fatty Acid Esters (IPP, IPM, CP,
OO)
(R&D)
Oleochemicals are….
Oleochemicals are….

In Southeast Asia, the major raw

Oleochemicals refer material being used to produce
chemicals derived from oleochemicals are palm oil, palm
natural oils and fats of both kernel oil, and coconut oil as these
plant and animal origin. crops are grown abundantly in this region

1. Refinery Overview
The source of the raw material will
impact the applications .

The raw material we will consider is

Crude Palm Kernel Oil (CPKO), Crude
Coconut Oil (CNO), Crude Palm Oil (CPO),
and Refined Bleached Deodorized Palm
Stearine (RBDPS)
Oleochemicals and Derivatives

Raw Material Basic Oleochemical Derivatives

Sulfo Fatty Acid Ester

Fatty Acid Fatty Alcohol

Methyl Ester EO – PO – Adduct

Guerbet Alcohols Fatty Alcohol Ether

Alkyl Chlorides Sulphates
Fatty AlcoholEthoxylate
FattyAlcoholSulphates
Technical Esters Fatty alcohol Ether
Fatty
Alkyl Polyglycosides Phosphate
Alcohol
Fatty Alcohol Ether
Sulfosuccinates
Oil and Fats
Fatty Acid

Conjugated Fatty Acids

Alkyl Epoxyester
Dimer Fatty Acids
Fatty Acid Ethoxylates
Acelaine / Pelargon Acid
Fatty Acid Ester

Co - Product
Tricetines
Glycerine
Partial Glycerines
Medium Chain Triglyceride (MCT)
Fatty Acid Composition of Oil and Fat
Fatty Acid Composition of Oil and Fat

Palm Palm Jatropha

Fatty Acid in %weight Coconut Palm Kernel Palm Canola Soy Bean
Olein Stearine Curcas
Caproic C6:0 0–1 0.2

Caprylic C8:0 5 – 10 3–6

Capric C10:0 5 – 10 3–5

Lauric C12:0 43 – 53 40 – 52 Trace 0 – 0.5 1 Max.

Miristic C14:0 15 – 21 14 – 18 0–2 0.5 – 1.5 2 Max 0 – 0.5 Trace Trace

Palmitic C16:0 7 – 11 6 – 10 30 – 48 38 – 41 57 - 63 12 – 17 3–6 7 – 12

Stearic C18:0 2–4 1–4 3–6 1.4Refinery

–5 Overview
3-7 5–7 1 – 1.25 2–6

Oleic C18:1 6–8 9 – 16 38 – 44 43 – 44 25 - 30 37 – 63 52 – 66 20 – 30

Linoleic C18:2 1–3 1–3 9 – 12 10 -11 4–8 19 – 40 17 – 25 48 – 58

Linolenic C18:3 0 – 0.5 8 – 11 6 – 11

Arachidic C20:0 Trace 0 – 0.3 0–1 0 – 0.5 1 Max. 0 – 0.3 0–1 Trace

Behenic C22:0 Trace Trace Trace

Gadoleic 1.5 – 5 0–1

Malva - / sterculic

Iodine Value and Sap.Value

IV, (g I2/100g) 8 – 12 14 – 23 44 – 54 56 – 58 34 – 38 93 – 107 81 – 112 120 – 140

SV, (mg KOH/g) 250 – 264 245 – 255 194 – 206 205 195 – 210 188 – 197 180 – 197 190 – 195
Advantages

 Competitiveness with petrochemical raw materials

 In the last decade, the oleochemical industry has been growing

steadily due to increased global demand for more environment-
friendly product.

 This is because of oleochemicals attractive traits:

 Derived from renewable resources (raw material availability)
 Non toxic
 Readily biodegradable
 “Green image”
 Better dermatological compatibility
Market Trends

 Europe/USA: Market stable

 South America: growing market
 SEA/China/India: Higher growing market

 Future Market leaders will be the Oil

producers, which will drive the
Oleochemical capacity growth;
 Oil producers will go further
downstream Oleochemical production
What is Fatty Acids ?

Fatty Acids
 Are aliphatic acids with chain length from C6 up to C22
CH3(CH2)nCH2COOH, (n = 4 – 20)
 General formula of CnH2nO2, for Saturated Fatty Acid
 Whereas the Unsaturated ones have the formulas CnH2n-2O2,
CnH2n-4O2 and CnH2n-6O2 for the acids containing single, double and
triple bond respectively.
n = number of Carbon atoms
 Are predominantly linear and monohydric.
 Can be saturated or have one or more double bonds.
 Are classified as natural or synthetic depending on the raw
materials.
 Their derivatives are used in major components in toilet soap
manufacture, Plasticizer, High – performance lubricant, food/
medium – chain triglyceride, polymers, oil additives and cosmetics
ingredient.
What is Glycerine?
A colorless, odorless, hygroscopic and sweet tasting viscous liquid.
Glycerine is very soluble in water, even at room temperature.
A three carbon alcohol.
The backbone of the triglyceride molecule.
Glycerine has the chemical structure shown below :

Names for Glycerine:

HCH OH  Glycerol
 Glycerine
HC OH  1,2,3 – propanetriol
 Propane – 1,2,3 – triol
HCH OH  Trihydroxy propane
 Glycyl alcohol
What is Fatty Alcohols?

Fatty Alcohols
Are aliphatic alcohols with chain length from C6 up to C22
CH3(CH2)nCH2OH, (n = 4 – 20)
Are predominantly linear and monohydric.
Can be saturated or have one or more double bonds.
Are classified as natural or synthetic depending on the raw materials.
Melting point and boiling points increase uniformly with chain length.
Decanol and higher fatty alcohols can be considered as immiscible with
water.
A slight hygroscopic is observed water vapour from air during storage.
Their derivatives are used in base of surfactants for laundry detergent
product, shampoos, dishwashing liquids, and cleaning agent, defoamer,
excellent plasticizer/ PVC, and cosmetics.
 Oleochemical
Oleochemical main markets
main markets

1. Soap Market;
2. Detergents market (Powder/
Liquid);
3. Shampo and personal care
market;
4. Cosmetic market;
5. Textile/ Lubricating market;
6. Specialty fats market;
Fatty Acid Applications

Toilet Soaps
Personal care products like lotions and creams
Other derivatives for:
High – performance - Lubricants
Textile/ fabric care
Plastics Industry
Cosmetics
Food
Metal working
Paper
Rubber
Glycerine Applications

USP / EP grade Refined Glycerine at 99.7% minimum of purity.

Used in the manufacture of:

Toothpaste

Cosmetics and Personal care

Pharmaceuticals

Food and beverage

Explosives, urethane foams, alkyd resins for paints, esters for

dietary fats, cigarettes, etc.
 Fatty
Fatty Alcohol
Alcohol Product
Product & Applications
& Applications

Includes :
Short Chain Fatty Alcohol (C6 – C10)
Mid-cut alcohols and Mixture Alcohol (C12 / C14 / C12 – C14)
Long chain alcohols - Cetyl / Stearyl alcohols (C16 / C18 / C16 – C18)

Used in:
Production of surfactants for detergents, toothpastes, shampoo, fabric
care/textiles, etc.
Plasticizer and metal working
Cosmetic formulations like lipsticks and lotions.
 Agenda

Site Overview

Fatty Acid Plant

Glycerine Plant

Fatty Alcohol Plant

Utilities and Supporting Facilities

Sinarmas Cepsa | 16
 Organization Chart
PT Energi Sejahtera Mas – Site

Site GM
Harunasir Atan

Logistic/PPIC Production Project Finance

HR&GA Manager Improvment QA/QC Manager HSE Manager
Manager Manager Manager
Arief Setiono Manager Suhaimi Mai Rini Ambarwati
Kukuh Imantyoko Ulama Wong Wai Lam
Linawati

Energy
Process & Technical Maintenance
Manager
Services Manager
Herman
Enrique Turegano Abdul Aziz
Rambe

Deputy Deputy
Energy Maintenance
Manager Manager
Ang Nyuk Lai Zaini Sujak

Total Site Head Counts: 309

Sinarmas Cepsa | 17
 PT Energi Sejahtera Mas (ESM)
Site Overview

Total ESM Land size: 24.45 Hectares

Admin Building
& Canteen
HE, Maintenance and
Fatty Acids & Chemical warehouse
Fatty Alcohol Buildings
Plants Finishing Plants &
FA & FOH Tank farms Solid Products
Warehouse
Water Treatment
Centralized Plants
Control Room &
Laboratory
Wastewater
Treatment Plant

Coal Fired Power

Plant & Boilers
 PT Energi Sejahtera Mas (ESM)
List of Unit of Operations
CAPACITY
PLANT MAIN UNIT OPERATIONS FINAL PRODUCTS
Mt/annum

200 KTPA • Splitter

• Fractionation
• Fractionation (Short Cut). • Fractionated Fatty Acids
Fatty Acids • Distillation (heavy Cut) • Oleic Acids
• FA Hydrogenation • Stearic Acids
40 KTPA • Oleic Plant
• Tank Farm
Glycerine 26 KTPA • Glycerine Distillation • Refined Glycerine
• Wax Ester Unit
160 KTPA
• Hydrogenation
• Fractionation
• Carbonyl Conversion • Fractionated Fatty Alcohols
Fatty Alcohol
• Tank Farm

• Hydrogen Plant
7,300 Nm3/hr
(HYDROCHEM)
• Solidified Fatty Acids
• Beading
• Solidified Fatty Alcohols
Packaging 110 KTPA • Pastillation
• Glycerine
• Drumming
• Fatty Acids

Sinarmas Cepsa | 19
 PT Energi Sejahtera Mas (ESM)
List of Unit of Operations
FACILITIES Capacity/ hr MAIN UNIT OPERATIONS QUANTITY

• 70 m3/hr • Water Treatment Plant 1

• 100 MT/hr • Coal Fired Boilers 2
• 15 MW • Steam Turbine Generator 1
• 5.7 MW • DG Set 2
Centralized Utilities & Power • 5 MT/Day (COD) • Waste Water Treatment 1
Plant

• Fire Fighting system 1

• 51 MW • Oil Thermal Heater 3
• 888 Nm3/hr • Compressed and Instrument Air 1

• 6 bay • Isotank Loading 1

Logistic & Warehouse
• 6,400 MT/ 8 bay • Warehousing & Truck Loading 1

• Administration buildings 1
• QC/QA 1
• Multipurpose Hall 1
• Canteen 1
Others
• Jetty 1
• Coal Yard and Coal Shed 1
• Container Yard 1
• Weighing Bridge 2

Sinarmas Cepsa | 20
 PT Energi Sejahtera Mas (ESM)
Production Flow: Acids and Alcohol
Fatty Acid & Fatty Alcohol
Glycerine Raw materials
CPKO

Oil splitting
Wax Ester Unit

Water

Evaporation Fractionation Hydrogen

Hydrogenation Catalyst

Hydrogen
Oleic Acid Unit Catalyst
Fractionation

FA Hydrogenation

Glycerine Distillation Fractionation

Distillation (Heavy Cut) (Short Cut) Carbonyl Conv.

Refined • Fractionated Fatty Fractionated

glycerine Acids Fatty acid
• Oleic Acid Fractionated
• Stearic acid Fatty Alcohol

Isotanks, bulks, drums, bags

Sinarmas Cepsa | 21
 Agenda

Site Overview

Fatty Acid Plant

Glycerine Plant

Fatty Alcohol Plant

Utilities and Supporting Facilities

Sinarmas Cepsa | 22
OIL SPLITTING (SEC 101)
Fatty Acid Plant
Oil Splitting (Sec 101) Splitting
Column
SPLIT FATTY ACID
Splitting Column
WATER • Capacity : 600 mt/day
• Diameter : ID 2 m
• Height : 60 m

OIL

LP STEAM
GLYCERINE-
WATER

O O
H2C O C R1 HO C R1 H2C OH
O O
HC O C R2 + 3H2O HO C R2 + HC OH
O O
H2C O C R3 HO C R3 H2C OH
TRIGLYCERIDE WATER FATTY ACID GLYCERINE

Sinarmas Cepsa | 23
FA FRACTIONATION (SEC 105)
Fatty Acid Plant
FA Fractionation (Sec 105)

Fractionation 1 (I) Fractionation 3 (III)

• Capacity : 600 mt/day • Capacity : 168 mt/day
• Diameter : ID 2/2.5 m • Diameter : ID 3 m
• Height : 25 m • Height : 25.3 m
• Product : • Product :
FA C6C8 FA C16
FA C8C10

III II I Fractionation 2 (II) Distillation (IV)

• Capacity : 552 mt/day • Capacity : 160 mt/day
• Diameter : ID 3.8/3.5 m • Diameter : ID 2.5 m
IV
• Height : 26.6 m • Height : 13.4 m
• Product : • Product :
FA C12C14 FA C16C18
Residue

Sinarmas Cepsa | 24
 Fatty Acid Plant
Oleic Acid and FA Batch Hydrogenation

Capacity : 120 mt/day

Crystallizer : 5 Unit ( 1 unit = 12 Crystallizer Tube)
Height : 4.5 m
Diameter : OD 0.6 m
Product : Oleic Acid and Stearic Acid

Crystallizers

FA BATCH HYDROGENATION
Capacity : 15 mt/batch
120 mt/day (8 batch)

Hydrogenation Reactor
Diameter : OD 2 m
Height : 7.3 m
Product : Hydrogenated FA C8C10
Hydrogenated Stearic Acid
Hydrogenation Reactor

Sinarmas Cepsa | 25
 Agenda

Site Overview

Fatty Acid Plant

Glycerine Plant

Fatty Alcohol Plant

Utilities and Supporting Facilities

Sinarmas Cepsa | 26
 Glycerine Plant
Pre-treatment, Evaporator, Distillation

Glycerine Pretreatment Glycerine Evaporator Glycerine Distillation

Notes:
Glycerine Plant
Capacity : 78 mt/day
(base on Ref. Glycerine)

Glycerine Distillation Column

Diameter : ID 2.8 m
Height : 17.9 m
Product : Refined Glycerine

Sinarmas Cepsa | 27
 Agenda

Plant Overview

Fatty Acid Plant

Glycerine Plant

Fatty Alcohol Plant

Utilities and Supporting Facilities

Sinarmas Cepsa | 28
 Carbonyl
Wax Ester Unit Hydrogenation Fractionation
Conversion

Fatty Alcohol Plant

Wax Ester Unit (Sec 110) and Hydrogenation (Sec 111)

R04 R03 R02 R01

R02 R01

Hydrogen Recycle
Wax Ester Preparation Hydrogenation Reactor
Compressor

Wax Ester Preparation Plant Hydrogenation Reactor

Capacity : 1100 mt/day Capacity : 1100 mt/day
Diameter : OD 5.7 m Diameter : ID 3.2 m
Height : 14.5 m Effective Hght : 12.8 m
Product : Wax Ester Product : Fatty Alcohol

R1-CH2-COOH + R2-CH2-OH R1-CH2-COO-CH2-R2 + H2O

Fatty Acid Fatty Alcohol Wax Ester Water
R1 & R2 = CnH2n+1

R1-CH2-COO-CH2-R2 2H2 R1-CH2-CH2OH R2-CH2OH

Wax Ester + Hydrogen Fatty Alcohol + Fatty Alcohol

Sinarmas Cepsa | 29
 Carbonyl
Wax Ester Unit Hydrogenation Fractionation
Conversion

Fatty Alcohol Plant

Fractionation (Sec 112) and Carbonyl Conversion (Sec 113)

Fractionation I Fractionation II Fractionation III

Capacity : 1100 mt/day Capacity : 490 mt/day Capacity : 225 mt/day
Diameter : ID 2.8 m Diameter : ID 2.9 m Diameter : ID 3.5 m
Height : 26 m Height : 20 m Height : 11.8 m
Product : Hydrocarbon Product : Fatty Alcohol Product : Fatty Alcohol
Residue

FOH Fractionation

113R11 113R21 113R31

Capacity : 485 mt/day Capacity : 340 mt/day Capacity : 220 mt/day
Diameter : OD 1.6 m Diameter : OD 1.3 m Diameter : OD 1.1 m
Height : 4.3 m Height : 4.4 m Height : 4.2 m
Product : FOH C8C10 Product : FOH C8 Product : FOH C10
FOH C12C14 FOH C18 FOH C16
FOH C16C18

Carbonyl Conversion

Sinarmas Cepsa | 30
 Agenda

Site Overview

Fatty Acid Plant

Glycerine Plant

Fatty Alcohol Plant

Utilities and Supporting Facilities

Sinarmas Cepsa | 31
 Supporting Facilities
Tank Farms

Raw Materials &

Methanol Tank
Products Tanks

Extensive tanking capability with more than 80

nos of tanks with various capacities

Sinarmas Cepsa | 32
 Supporting Facilities
Utilities

Capacity 15 MW Capacity 100 MT/hr Capacity 70 m3/hr DW

Steam Turbine Generator Boiler & Stack Water Treatment Plant

Capacity 5 MT/Day COD Circulation Rate 7,000 m3/hr Capacity 51 MW

Waste Water Treatment

Cooling Water Oil Thermal Heater
Plant

Sinarmas Cepsa | 33
 Supporting Facilities
Other Supporting Facilities

Liquid Jetty, Containers Jetty Capacity 2 x 60 MT Capacity 7,000 MT

Jetty Weigh Bridges Coal Shed

Capacity 6,400 MT GC, Centrifuge, etc.

Packaging Warehouse DCS Lab Equipment

Sinarmas Cepsa | 34
THANK YOU