Class: SZ2 JEE-ADV (2016-P2) MODEL Date: 17-05-20

Time: 3hrs WAT-12_INITIAL KEY Max. Marks: 186

Jee-Adv_Model_Initial Key

SZ2 Physics Initial Key Dt.17-05-2020

Q.No. 01 02 03 04 05 06 07 08 09
Ans. A C D B D B ABD AB ABCD
Q.No. 10 11 12 13 14 15 16 17 18
Ans. BC AD CD D AC A B C A

SZ2 Chemistry Initial Key Dt. 17-05-2020

Q.No. 19 20 21 22 23 24 25 26 27
Ans. B A C A C C AD BD BCD
Q.No. 28 29 30 31 32 33 34 35 36
Ans. A AB BCD ACD ABD C D A B

SZ2 Mathematics Initial Key Dt. 17-05-2020

Q.No. 37 38 39 40 41 42 43 44 45
Ans. B C A B A C AB AC BCD
Q.No. 46 47 48 49 50 51 52 53 54
Ans. AC ABD BC AD AC C A B C

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02. Let m be the mass and r the density of solid

Volume = m/r

m
m1g mg dg …..(1)
r 1

m
m2g mg dg …….(2)
r 2

m
m3g mg dg …….(3)
r 3
d2 d1
Eq (2) –Eq.(1), r m
m1 m2

d3 d1
Eq (2) – eq(3), r m
m2 m3

d2 d1 d3 d1
m= m
m1 m2 m2 m3

d2 d1 m2 d2 d1 m3 m1 m2 d3 d2

d2 d1 m1 m1 m2 m2 d 3 d1 m1 d3 d2
Or m3 =
d2 d1 d2 d1
v v
04. r 2 1 vs
3 3

r 2 3s

05. From the diagram, we have

PB + gH − aL = PA
Given PB = PA = Po  Po + gH − aL = Po

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gH
gH = aL  a =
L
2
06. From diagram tan  = ..........(1)
5
a
Also tan  = ..........................(2)
g

From (1) and (2)

a 2 2 2
=  a = g =  10  a = 4ms −2
g 5 5 5
07. F=upthrust= Vd F g

Equilibrium of A, Vd F g = T + wA = T + Vd A g ….(i)

Equilibrium of B, T + Vd F g = Vd B g …..(ii)

On adding eqs. (i) and (ii), we get

2d F = d A + d B

From eq.(i), we can see that d F  d A (as T>0)

From eq.(ii) we can see that d B  d F

08. The level of interface rise & the upper most level rises

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09. The horizontal component of the forces on the left and right-side

inclined faces will cancel each other

The weight of the section lettered A is supported by vertical

component of forces acting on the inclined faces.

Force exerted by the liquid on the base of the vessel is ( p0 + gh ) A

where  is the density of the liquid and A is base area of the vessel
Net force exerted by liquid on the base of the vessel is in the vertical
downward direction.
10. The balance B will read more than 5 kg

The balance A will read less than 2 kg

11. Density of sphere > density of liquid

FB − FA  mg
l 12
13. h1 = = = 2.4cm , In the first case,
5 5

FB = mg  1l 2 h1 g = mg  1l 2 h1 = m

After water is poured = 1 (l − h2 )l 2 g + 2 h2l 2 g = mg

= 1 (l − h2 )l 2 + 2 h2l 2 = 1l 2 h1  (2 − 1 )h2 = 1 (h1 − l )

(1 − 2 )h2 = 1 (l − h1 )  (13.6 − 1)h2 = 13.6(5h1 − h1 )  h2 = 10.4cm

15. & 16.
ax − g x
tan  =
g y − ay

17. & 18.

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w2 2
y=  x2 − x12 
2g  

19. In 0.1 m AgNO3:

AgCl (s ) Ag + (aq ) + Cl − (aq )

AgNO3 Ag + + NO3−
0.1 0.1

K sp =  Ag +  Cl −  = ( 0.1 + s )( s )
  
S <<<0.1, presence of common ion decreases solubility)
S(0.1)= 1.5  10−10  S=1.5  10−9 mollitre-1
x B  1000 0.2  1000
21. m= ,m = = 3.2
(1 − xB ) mA 0.8  78
Where x B is mole fraction of solute, m A is molar mass of solvent
wB 1000 c 1000 c 1000
22. Molality (m ) =  b =   mB = 
mB wA mB (a − c ) b (a − c )
23. Total mass of solution = 1000 + 120 = 1120 g
1120
Total volume of solution in (L) =  10−3
1.15
W 1 120 1.15  103
M =  =  = 2.05 M
Mw V (in L ) 60 1120
27. The solubility of the gas in liquids decreases with the increase in
value of K H at a given pressure.
28. Let the solubility of Ni(OH)2 be equal to S. Dissolution of S mol/L
of Ni(OH)2 provides
S mol/L of Ni2+ and 2S mol/L of OH–, but the total concentration
of OH–= (0.10 +2S) mol/L because the solution already contains
0.10 mol/L of OH– from NaOH.
–15
Ksp= 2.0  10 = [Ni2+] [OH–]2= (S) (0.10 + 2S)2
As Ksp is small, 2S << 0.10,
thus, (0.10 + 2S) ≈0.10
2.0 × 10–15 = S (0.10)2
S = 2.0 × 10–13 M = [Ni2+]

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31. Solubility of AgCl in water

AgCl = Ag + + Cl −
K sp =  Ag +  Cl −  = ( S1 )( S1 ) = S12

 S1 = K sp = 1.34  10 −5 mole / litre

Solubility of AgCl in 0.01M CaCl2
 Ag +  = S 2 ; Cl −  = ( 2  0.0 + S 2 )

K Sp =  Ag +  Cl − 

 S2 = 9 10−9 mole / litre

Solubility of AgCl in 0.01M NaCl
 Ag +  = S3 ; Cl  = ( 0.01 + S3 )

1.8  10−10 = S3 ( 0.01 + S3 )

 S3 = 1.8 10−8 mole / litre
Solubility of AgCl in 0.05M AgNO3
 Ag +  = ( 0.05 + S 4 ) ; Cl −  = S 4

 S4 = 3.6 10−9 mole / litre

From the values of solubility we get S1  S3  S2  S4
5g
35. Moles of NaOH = = 0.125 mol
40 g mol −1
Volume of the solution in litres = 450 mL / 1000 mL L-1
0.125 mol  1000 mL L−1
Molarity = = 0.278 M
450 mL
36. Assume that we have 100 g of solution (one can start with any
amount of solution because the results obtained will be the same).
Solution will contain 20 g of ethylene glycol and 80 g of water.
20 g
Moles of C2H 6O2 = = 0.322mol
62 g mol −1
80 g
Moles of water = = 4.444mol
18 g mol −1
moles of C2H 6O2
X glycol =
moles of C2H 6O2 + moles of H 2O
0.322mol
X glycol = = 0.068
0.322mol + 4.444 mol

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1
37. cos 2 x = sin x tan x
6
sin 2 x
6 cos 2 x =  6 cos3 x + cos 2 x − 1 = 0
cos x
1 
cos x =  x = 2n 
2 3

( cot x + 3 )
2
38. + cot 2 x + 4coseex + 5 = 0

( cot x + 3 )
2
+ cos ee2 x + 4coseex + 4 = 0

( cot x + 3 ) + ( cos eex + 2 ) = 0

2 2

cot x = − 3 or cos eex = −2


x = 2 n − , n  Z
6
3 −1 3 +1
39. + =2
2 2 sin x 2 2 cos x
 
sin cos x + cos sin x = sin 2 x
12 12
 
sin 2 x = sin  x + 
 12 
 
2x = x + x=
12 12

sin ce x 2 + x −2 = ( x − x −1 ) + 2 , 2 and 2 cos 2

2 x 2
40. sin x  2
2
The given equation is valid only if
x 2
2 cos 2 sin x = 2
2
x
cos sin x = 1 ,
2
Which can not be true
 2 3
41. y = 5x2 + 2 x + 3 = 5  x2 + x + 
 5 5

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 1 3 1 
2 2
 1  14
5  x +  + −  = 5  x +  +  2
 5  5 25   5 5

Since y = 2sin x  2, no points of interception

( sin x + cos 2 x ) − 2sin 2 x cos 2 x + sin 2 x +  = 0

2
42. 2

sin 2 2 x − 2sin 2 x − 2 − 2 = 0
Let sin 2 x = y, then y 2 − 2 y − 2 (1 +  ) = 0

Where −1  y  1
For real   0
−3
3 + 2  0   
2
−1  y  1  −1  1 − 3 + 2  1
1
3 + 2  4   
2
−3 1

2 2
43. 4sin 4 x = 1 − cos4 x = (1 − cos2 x )(1 + cos2 x ) = sin 2 x ( 2 − sin 2 x )

sin 2 x ( 5sin 2 x − 2 ) = 0

2
sin x = 0 or sin x = 
5

2
x = n or x = n  sin −1
5

( sin x − 1) =2
2
44.

sin x −1 =  2,sin x = 1 − 2

There are two solution s,n  o, 2

And 2 more in  2, 4

Then n = 4,5
45. 1 + cos3x = 2cos 2x
1 + 4cos3 x − 3cos x = 2 ( 2cos2 x − 1)

4 cos3 x − 4 cos 2 x − 3cos x + 3 = 0

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4cos 2 x ( cos x − 1) − 3 ( cos x − 1) = 0

( cos x −1) ( 4cos2 x − 3) = 0

3
cos x = 1 or cos x = 
2

x = 2n or x = n 
6
2 2
46. x+ y = y= −x
3 3

 2   3 1 
sin x = 2sin  − x  = 2  cos x + sin x  = 3 cos x + sin x
 3   2 2 

cos x = 0  x = n + , n  Z
2
2  
y= − n − = − n
3 2 6
 3 5 7 
for x   0, 4  x = , , ,
2 2 2 2
 7  13 19
for x   0, 4  x = , , ,
6 6 6 6
y+3
47. cos 2 x − 2 cos x + 1 = 3 −
2y + 5
5y + 2 5y + 2
( cos x − 1) = o
2
,
2y + 5 2y + 5
−1  cos x  1
5y + 2
o  ( cos x − 1)  4 , 0 4
2

2y + 5

 −8  12 
y   −,  ,  ,  
 3 5 

1 + 1 + 4a
48. sin x =
2
1 + 1 + 4a
We must have 1 + 4a  o and −1  1
2
−1
The above two conditions are equivalent  a  o, 4 solutions for x
4

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 1 
49.  cos x +   2, (1 + tan 2 y ) ,1, 2  3 + sin 3 z  4 , only possibility is
2 2

 cos x 
2

1
cos 2 x + 2
= 2, 1 + tan 2 2 y = 1,3 + sin 3z = 2
cos x
cos x = 1, tan 2 y = 0,sin 3 z = −1
n 
x = m, y = , Z = ( 4 p − 1)
2 6
m, n, p  Z

 2 
sin x = 2 sin  − x
 3 
 3 1 
2  cos x + sin x  = 3 cos x + sin x
 2 2 

cos x = 0  x = n + ,n Z
2
2  
y= − n − = − n
3 2 6
 3 5 7
For x   0, 4  x = , , ,
2 2 2 2
 7  13 19
For x   0, 4  y = , , ,
6 6 6 6
1
50. y+ = 2 and sin x + cos x = 2
y

But sin x + cos x  2

1
y+ = 2 and sin x + cos x = 2
y

  
y = 1 and sin  x +  = 1  x =
 4 4
51. Given cubic function is
f ( x ) = ( x − 1)( x − cos  )( x − sin  )

Roots are 1,sin , cos 


If 1 = sin    =
2

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If 1 = cos    = 0, 2
 5
If sin  = cos    = ,
4 4
The number of values of   0, 2 us 5

52. Again the maximum possible difference be tureen the roots is 2

3
1 − sin  = 2   =
2
2
1 − cos  = 2   =

x
53. Graphs of y = sin x and y = meet exactly six times
10
Number of solutions = 6
5
54. 3 x + 2 tan x =
2
5 3
tan x = −
4 2
5 3
Graphs of y = − and y = tan x
4 2
Meet exactly 3 times in  0, 2

Number of solutions = 3

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