Benzene: Physical Properties

Benzene
Other names: 1,3,5-Cyclohexatriene; Benzeen; Benzen; Benzin;

Benzine; Benzol; Benzole; Benzolene; Benzolo; Bicarburet of hydrogen;
Carbon oil; Coal naphtha; Cyclohexatriene; Fenzen; Mineral naphtha;
Motor benzol; NCI-C55276; NSC 67315; Phene; Phenyl hydride;
Pyrobenzol; Pyrobenzole; Rcra waste number U019; UN 1114;
[6]Annulene.
InChI: InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H
InChI Key: UHOVQNZJYSORNB-UHFFFAOYSA-N
Formula: C6H6
SMILES: c1ccccc1
Molecular Weight: 78.11
CAS: 71-43-2
Physical Properties
Property Value Unit Source
PAff 750.40 kJ/mol NIST Webbook
PAff 746.40 kJ/mol NIST Webbook
BasG 725.40 kJ/mol NIST Webbook
BasG 721.70 kJ/mol NIST Webbook
∆cH°liquid -3267.50 ± 0.42 kJ/mol NIST Webbook
∆cH°liquid -3280.00 kJ/mol NIST Webbook
∆fG° 121.68 kJ/mol Joback Method
∆fH°gas 82.90 ± 0.90 kJ/mol NIST Webbook
∆fH°gas 82.80 kJ/mol NIST Webbook

∆fH°gas 82.93 ± 0.50 kJ/mol NIST Webbook
∆fH°gas 79.90 kJ/mol NIST Webbook
∆fH°liquid 49.00 ± 0.90 kJ/mol NIST Webbook
∆fH°liquid 46.00 kJ/mol NIST Webbook
∆fusH° 5.73 kJ/mol Joback Method
∆subH° 44.40 kJ/mol NIST Webbook
∆vapH° 33.92 kJ/mol NIST Webbook
∆vapH° 33.90 ± 0.10 kJ/mol NIST Webbook
IE 9.24 ± 0.00 eV NIST Webbook
IE 9.20 eV NIST Webbook


logPoct/wat 1.69 Crippen Method
Pc 4895.00 ± 6.00 kPa NIST Webbook

S°liquid 173.26 J/mol×K NIST Webbook
S°liquid 175.30 J/mol×K NIST Webbook
S°solid,1 bar 45.56 J/mol×K NIST Webbook
Tboil 353.35 ± 0.30 K NIST Webbook

Tboil 353.30 K NIST Webbook






Tc 562.05 ± 0.07 K NIST Webbook
Tc 562.10 K NIST Webbook

Tfus 278.67 ± 0.01 K NIST Webbook



Ttriple 278.67 ± 0.00 K NIST Webbook
Vc 0.26 m3/kg-mol NIST Webbook
Vc 0.26 ± 0.03 m3/kg-mol NIST Webbook

Temperature Dependent Properties
Property Value Unit Temperature (K) Source
Cp,gas 93.32 ± 0.06 J/mol×K 333.15 NIST Webbook
Cp,gas 95.81 J/mol×K 341.6 NIST Webbook
Cp,liquid 131.40 J/mol×K 287.8 NIST Webbook


Cp,solid 47.86 J/mol×K 90.0 NIST Webbook
η 0.00 Pa×s 358.38 Joback Method
∆fusH 9.88 kJ/mol 278.55 NIST Webbook

∆subH 53.90 ± 0.80 kJ/mol 193.0 NIST Webbook
∆subH 49.40 ± 0.40 kJ/mol 193.0 NIST Webbook
∆subH 43.30 kJ/mol 226.0 NIST Webbook
∆vapH 35.60 kJ/mol 285.5 NIST Webbook
∆vapH 33.00 ± 0.10 kJ/mol 313.0 NIST Webbook

∆fusS 35.50 J/mol×K 278.55 NIST Webbook

Sources
Joback Method: https://en.wikipedia.org/wiki/Joback_method

NIST Webbook: http://webbook.nist.gov/cgi/inchi/InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H
Crippen Method: http://pubs.acs.org/doi/abs/10.1021/ci990307l
Legend
PAff: Proton affinity (kJ/mol).

BasG: Gas basicity (kJ/mol).
∆cH°liquid: Standard liquid enthalpy of combustion (kJ/mol).
Cp,gas: Ideal gas heat capacity (J/mol×K).
Cp,liquid: Liquid phase heat capacity (J/mol×K).
Cp,solid: Solid phase heat capacity (J/mol×K).
η: Dynamic viscosity (Pa×s).
∆fG°: Standard Gibbs free energy of formation (kJ/mol).
∆fH°gas: Enthalpy of formation at standard conditions (kJ/mol).
∆fH°liquid: Liquid phase enthalpy of formation at standard conditions (kJ/mol).
∆fusH°: Enthalpy of fusion at standard conditions (kJ/mol).
∆fusH: Enthalpy of fusion at a given temperature (kJ/mol).
∆subH°: Enthalpy of sublimation at standard conditions (kJ/mol).
∆subH: Enthalpy of sublimation at a given temperature (kJ/mol).
∆vapH°: Enthalpy of vaporization at standard conditions (kJ/mol).
∆vapH: Enthalpy of vaporization at a given temperature (kJ/mol).
IE: Ionization energy (eV).
logPoct/wat: Octanol/Water partition coefficient .
Pc: Critical Pressure (kPa).
∆fusS: Entropy of fusion at a given temperature (J/mol×K).
S°liquid: Liquid phase molar entropy at standard conditions (J/mol×K).
S°solid,1 bar: Solid phase molar entropy at standard conditions (J/mol×K).
Tboil: Normal Boiling Point Temperature (K).
Tc: Critical Temperature (K).
Tfus: Normal melting (fusion) point (K).
Ttriple: Triple Point Temperature (K).
Vc: Critical Volume (m3/kg-mol).
Latest version available from:
https://www.chemeo.com/cid/12-667-8/Benzene
Generated by Cheméo on Thu, 28 May 2020 20:59:10 +0000.
Cheméo (https://www.chemeo.com) is the biggest free database of chemical and physical data for the
process industry.

Benzene: Physical Properties

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Benzene: Physical Properties

Uploaded by

Copyright:

Available Formats

Benzene

Other names: 1,3,5-Cyclohexatriene; Benzeen; Benzen; Benzin;

Property Value Unit Source

PAff 750.40 kJ/mol NIST Webbook

PAff 746.40 kJ/mol NIST Webbook

BasG 725.40 kJ/mol NIST Webbook

BasG 721.70 kJ/mol NIST Webbook

∆cH°liquid -3267.50 ± 0.42 kJ/mol NIST Webbook

∆cH°liquid -3280.00 kJ/mol NIST Webbook

∆cH°liquid -3267.00 ± 0.40 kJ/mol NIST Webbook

∆cH°liquid -3267.60 ± 0.42 kJ/mol NIST Webbook

∆cH°liquid -3265.00 kJ/mol NIST Webbook

∆cH°liquid -3278.00 kJ/mol NIST Webbook

∆cH°liquid -3271.26 kJ/mol NIST Webbook

∆cH°liquid -3247.00 kJ/mol NIST Webbook

∆cH°liquid -3267.20 kJ/mol NIST Webbook

∆fG° 121.68 kJ/mol Joback Method

∆fH°gas 82.90 ± 0.90 kJ/mol NIST Webbook

∆fH°gas 82.80 kJ/mol NIST Webbook

∆fH°gas 82.93 ± 0.50 kJ/mol NIST Webbook

∆fH°gas 79.90 kJ/mol NIST Webbook

∆fH°liquid 49.00 ± 0.90 kJ/mol NIST Webbook

∆fH°liquid 48.95 ± 0.54 kJ/mol NIST Webbook

∆fH°liquid 49.04 ± 0.50 kJ/mol NIST Webbook

∆fH°liquid 46.00 kJ/mol NIST Webbook

∆fusH° 5.73 kJ/mol Joback Method

∆subH° 44.40 kJ/mol NIST Webbook

∆vapH° 33.92 kJ/mol NIST Webbook

∆vapH° 33.90 ± 0.10 kJ/mol NIST Webbook

∆vapH° 33.90 ± 0.10 kJ/mol NIST Webbook

∆vapH° 33.80 ± 0.10 kJ/mol NIST Webbook

∆vapH° 33.90 kJ/mol NIST Webbook

∆vapH° 33.85 kJ/mol NIST Webbook

∆vapH° 33.80 kJ/mol NIST Webbook

∆vapH° 33.84 kJ/mol NIST Webbook

∆vapH° 33.90 kJ/mol NIST Webbook

∆vapH° 34.00 kJ/mol NIST Webbook

∆vapH° 30.80 ± 0.10 kJ/mol NIST Webbook

IE 9.24 ± 0.00 eV NIST Webbook

IE 9.24 ± 0.00 eV NIST Webbook

IE 9.24 ± 0.00 eV NIST Webbook

IE 9.20 eV NIST Webbook

IE 9.25 ± 0.00 eV NIST Webbook

IE 9.23 ± 0.03 eV NIST Webbook

IE 9.25 eV NIST Webbook

IE 9.23 eV NIST Webbook

IE 9.25 eV NIST Webbook

IE 9.24 ± 0.00 eV NIST Webbook

IE 9.44 eV NIST Webbook

IE 9.25 eV NIST Webbook

IE 9.22 eV NIST Webbook

IE 9.24 eV NIST Webbook

IE 9.25 ± 0.02 eV NIST Webbook

IE 9.25 ± 0.07 eV NIST Webbook

IE 9.24 eV NIST Webbook

IE 9.70 eV NIST Webbook

IE 9.25 eV NIST Webbook

IE 9.20 ± 0.10 eV NIST Webbook

IE 9.26 ± 0.06 eV NIST Webbook

IE 9.27 eV NIST Webbook

IE 9.24 ± 0.01 eV NIST Webbook

IE 9.25 ± 0.01 eV NIST Webbook