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Waste Materials and by Products As Mineral Fillers in Asphalt Mixtures
Waste Materials and by Products As Mineral Fillers in Asphalt Mixtures
https://doi.org/10.1007/s41062-018-0190-z
TECHNICAL PAPER
Received: 31 July 2018 / Accepted: 8 December 2018 / Published online: 15 December 2018
© Springer Nature Switzerland AG 2018
Abstract
Mineral filler has a significant effect on the asphalt mixtures performance. This paper presents the use of waste materials
(marble and granite) and by-product material (steel slag) as alternative to the mineral conventional filler. A control mix with
the limestone filler was designed by Marshall method then, a replacement of limestone filler by the waste and by-products
materials was done. Two types of mastic asphalt samples were prepared (virgin and aged by the rolling thin-film oven) with
the ratio of 1:1 (mineral filler/asphalt). The samples were tested in penetration, softening point and Brookfield rotational
viscosity. Furthermore, the transition electron microscope for fillers and scanning electron microscopy for mastics tests were
performed. Both virgin and RTFO granite mastics improved the penetration value; however, the marble mastics showed the
highest softening point temperature and RV viscosity. Marshall results showed that mixtures containing waste marble yielded
the highest stability. Moreover, results showed the ability of marble to improve the moisture damage resistance in terms of
tensile strength ratio and loss of stability. Finally, the field performance was predicted using Quality-Related Specifications
Software which is a simplification of the Mechanistic-Empirical Pavement Design Guide software. It was found that all
materials enhanced rutting resistance compared to the traditional limestone filler.
Keywords Waste material · TSR · Asphalt mastic · QRSS · Rutting · Fatigue cracking
Introduction For example, in India, more than 3000 metric ton of marble
and granite dust slurry are produced daily during manufac-
The quantities of waste materials and by-products increase turing. The iron and steel factories in Egypt result in approx-
with the increase of construction industries, population, imately 600,000 and 200,000 tons of blast furnace and basic
urbanization, development activities and changes in life- oxygen furnace slag, respectively, per year [1].
style. Marble and granite resulting from industries, plastic The landfills are usually filled quickly with the continuous
and ceramic wastes, cement dust and fly ash and by-products disposal of waste materials requiring more expansion in the
which have no commercial value and are considered wastes. dedicated landfills. Moreover, these wastes have detrimental
The amounts of these wastes are huge and increasing daily. effects on both human health and plant life. Consequently,
most of the people working with these waste materials are
suffering from silicosis, which is considered one of the most
* Abdelhalim M. Azam known industrials diseases, due to long period exposure to
Abdelhalim.azam@mans.edu.eg; amazam@ju.edu.sa calcium carbonate and silica particles [2]. The quantities of
Eman W. Tarbay toxic materials in these wastes can also increase the alkalin-
eman.wagdy@yahoo.com ity of water and affect soil fertility [3]. Even though many
Sherif M. El‑Badawy published research studies regarding the use of waste mate-
sbadawy@mans.edu.eg rials as filler in HMA are available, only a few studies are
1
Nile Institute for Engineering and Technology, Mansoura,
available that focuses on analytical methods for the predic-
Egypt tion of pavement performance.
2
Highway and Airport Engineering Laboratory, Public
Works Engineering Department, Mansoura University,
Mansoura 35116, Egypt
3
Civil Engineering Department, College of Engineering, Jouf
University, Al Jawf, Kingdom of Saudi Arabia
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of the investigated waste materials through Transmission conditions by using the Quality-Related Specifications Soft-
Electronic Microscopy (TEM) is provided in Fig. 1. ware (QRSS), which is a closed form simplified solution
The TEM images demonstrate that most of limestone of the AASHTO Mechanistic-Empirical Pavement Design
particles range from 90 to 187 nm. However, some particles Guide (MEPDG) software [16].
range from 33 to 49 nm (Fig. 1a) and from 50 to 145 nm
for the slag (Fig. 1b) which indicates that their particle size
distribution varies from large sizes to the small ones. Mar- Design and volumetric properties
ble and granite are finer than other fillers as the majority of of conventional and modified asphalt
their particles range from 25 to 62 nm as shown in Fig. 1c, d mixtures
which indicate a uniform particle size distribution.
The aggregates were blended together to achieve the Egyp-
tian specifications [11] for 4C wearing surface as illustrated
Experimental work in Fig. 2. The percentages of aggregate 1, aggregate 2, fine
aggregate and mineral filler by the total weight of the mix
To achieve the objectives of the study, the experimental were 32.5%, 23.5%, 38.5% and 5.5%, respectively. The con-
work is divided into three major tasks. The first task includes ventional asphalt mix was designed according to Marshall
the design of a conventional asphalt mix by Marshall method method [17] with the limestone as mineral filler (MF). The
using limestone as mineral filler then it was replaced by optimum asphalt content (OAC) of the control mix using
other filler types. The effect of the filler type on moisture limestone was 5.8% by weight of the mix.
damage through loss of stability and indirect tensile strength Then, three replicate Marshall specimens were prepared
tests was investigated. The second task involves laboratory at OAC replacing the limestone MF with the other types of
tests on the mastic (asphalt + filler). Finally, the results of fillers with the same limestone ratio (the only variable is
the experimental work were used to predict pavement per- the filler type). Marshall stability, flow, volumetric proper-
formance at two levels of design speeds and three climate ties, maximum theoretical and bulk specific gravities were
50.0
40.0
30.0
20.0
10.0
0.0
0.0 0.1 1.0 10.0 100.0
Sieve Size (mm)
Control 5.8 1020 3.30 2.283 2.386 4.4 16.53 73.54 12.2
Marble 1240 2.82 2.307 2.398 3.5 16.14 77.64 11.8
Granite 1115 3.02 2.329 2.410 3.2 15.72 79.18 11.5
Slag 965 2.56 2.354 2.448 3.8 16.07 76.14 10.3
Specification limits 4–7.5 900 Min. 2–4 – – 3–5 15 Min. – –
Va air voids in total mix, VMA voids in mineral aggregate, VFA voids filled with asphalt and Vbe volume of effective asphalt binder.
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determined. Table 2 summarizes Marshall parameters and then placed in a 60 °C distilled water bath for 24 h and then
volumetric properties of all mixes. It can be noted that the soaked in water bath at 25 °C for 1 h at least before testing.
asphalt mix containing marble yielded the highest stability After that, the samples were tested using a compression test-
value which is about 20% higher compared to the limestone ing machine.
conventional mix, followed by granite and steel slag fillers. Figure 4 presents the tensile strength ratio (TSR) values
The mixes containing marble and granite fillers showed for the different mixes which represent the water sensitiv-
bulk specific gravities higher than the limestone mix. This ity of mixture and equal to the ratio of tensile strength of
may be attributed to the finer particles as shown from the conditioned samples to unconditioned samples. The TSR
TEM results. All mixes had air voids within the specification for all mixes fulfilled the specification requirements of 80%
limits (3% to 5%). as specified by the Egyptian Code for Practice. The asphalt
mixture containing steel slag barely achieved the minimum
Loss of stability limit. It can be seen from the figure that the marble mix
exhibited higher TSR values compared to the control HMA.
The loss of stability test which expresses the resistance
of the asphalt mix to moisture damage was performed in
Asphalt mastic properties
accordance with [18]. The samples were compacted and
soaked in 60 °C water bath for 24 h (conditioned samples)
In order to understand the role of the mineral filler in the
then tested in Marshall apparatus. The loss of stability is
mix, asphalt mastic samples were prepared with ratio of 1:1
the ratio between stability of conditioned samples and dry
(filler to asphalt) by weight as designed ratios. These mastic
samples.
samples were evaluated with the following tests:
Figure 3 presents the loss of stability results for the dif-
ferent asphalt mixes. All mixes showed loss of stability
values less than the maximum allowable value which is Scanning electronic microscopy (SEM)
25% according to the Egyptian Code for Practice [11]. The
asphalt mixture containing granite as filler recorded the low- The scanning electronic microscopy (SEM) was performed
est loss of stability. to investigate the asphalt mastic properties. The prepared
samples were placed on the SEM testing beam. The beam
Indirect tensile strength was placed in a vacuum chamber and the binder was coated
with gold which interacts chemically with the asphalt binder
The indirect tensile strength test was also carried out to and the color changed to gray.
evaluate the moisture susceptibility of asphalt mixtures Figure 5 demonstrates the SEM images for the different
according to [19]. Several trials were made to determine the asphalt mastic samples for each type of filler. It can be noted
number of blows for achieving air void in range from 6% to that some particles tend to agglomerate and form masses in
8% for the compaction process. granite and marble (refer to Fig. 5a, b). Conversely, better
Two groups of samples were prepared; 3 samples were dispersion of limestone and slag in the binder was evident
tested in dry condition at 25 °C, and 3 conditioned samples as the agglomeration was rarely present in these samples
were subjected to vacuum to achieve 55–80% saturation (refer to Fig. 5c, d). The reason for that is probably due to
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the clay content in each type of the filler as reported by other (mineral filler/asphalt). The RTFO samples were heated at
literature studies [4] (Muniandy et al. [8]). 163 °C and were poured in eight glass bottles then rotated
to coat all the bottle sides and placed in the rotational oven
Rheological properties of asphalt cement mastics according to [20]. After that, the penetration, softening point
and Brookfield viscosity tests were conducted.
Two types of samples were prepared (virgin and aged by the The effect of adding the waste filler to the asphalt cement
rolling thin-film oven, RTFO aged samples) with ratio of 1:1 on the rheological properties is presented in Fig. 6. The
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Penetration (0.1mm)
50 48
42
40 37
35.5 35
31
30
25
20
Limestone Marble Granite Slag
MasticType
65
Mastic RTFO Aged Mastic
Softening Point Temperature
60
59.7
57.5
56
55 53.1
53
( C)
49 49.6 49.2
50
45
40
Limestone Marble Granite Slag
Mastic Type
penetration decreased while the softening point tempera- of temperature. As the temperature increases, the viscosity
ture increased after the addition of filler to asphalt especially decreases gradually. There were some changes in the viscos-
for aged asphalt. The penetration of the granite mastic was ity–temperature susceptibility (VTSi) values which represent
lower than the other types which decreased significantly the slope of the regression line between log (log(viscosity))
from 63 (0.1 mm) down to 35.5 and for aged samples from and log(temperature) for marble, granite and limestone aged
39.7 (0.1 mm) to 25. mastics. However, a significant improvement in the viscosity
The marble filler recorded a penetration value of 42 was observed for the marble aged mastic at all temperatures.
(0.1 mm) and 31 for virgin and aged asphalt, respectively. This resulted in good adhesion between asphalt and marble.
The agglomeration in limestone and slag mastics was less The Ai and VTSi values for virgin and aged mastics are
compared to the other filler types leading to better distribu- shown in Table 3.
tion and more homogenous mastic. In general, the softening As the results clearly show, relative improvements are
point values increased with the addition of waste materials evident in the mastic as well as the mixture properties due
as filler for both cases virgin or aged samples. The marble to the use of the different waste materials as mineral filler.
filler which is considered the finest filler yielded the highest The relative improvement was different from filler to filler.
value of softening point (the stiffest mastic) compared to the This is probably due to the different physical properties of
other types of filler. the fillers which include grain size distribution, surface area,
The asphalt viscosity for virgin and aged samples is pro- rigden voids and grain morphology (sphericity and round-
vided in Fig. 7. It is noticeable that an increase in the viscos- ness of fillers) as reported in many literature studies [21–23].
ity occurs with the use of waste materials as filler at all levels Chemical composition of the filler also plays significant
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Fig. 7 Viscosity temperature
susceptibility for virgin and
aged mastic
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role in stiffening the mastic and, hence, the mix. Therefore, Design Guide (MEPDG) which can predict pavement per-
silica and calcium oxide content in the fillers can enhance formance in terms of AC rutting, thermal cracking and
the chemical interaction with asphalt [24]. In this research, fatigue cracking at the end of the pavement design life
the TEM images show that the marble and granite powder by three input different levels depending on the available
were finer than the other fillers. Thus, their surface area is data. No laboratory measurements were collected at the
greater which increase the cohesiveness with binder beyond time of research so the inputs were mainly level two. The
the purely physical micro filling action. Moreover, the angu- program inputs are traffic, pavement structure, climate
lar, irregular shape and the rough surface of the steel slag and performance criteria. Climate data for three differ-
particles compared to the flaky limestone particles provide ent cities in Egypt (Alexandria, Aswan and Cairo) were
high internal friction and good interlocking mechanism so used in this analysis [25]. Alexandria climate represents
excellent bond with asphalt binder which was reported by coastal climate, Cairo climate represents moderately hot
Muniandy et al. [8]. climate, while the climate of Aswan is extremely hot cli-
mate. Two traffic speeds were selected, a slow speed rep-
resenting traffic speed at intersections and toll gates and
Predicted field performance a fast speed. These two speeds were selected in order to
study the effect of loading rate on the performance of the
Quality‑Related Specifications Software (QRSS) investigated mixes. The program input data is presented
in Table 4.
The Quality-Related Specifications Software (QRSS) is The prediction of HMA rutting and fatigue crack-
a simplification of the Mechanistic-Empirical Pavement ing depends mainly on traffic load, speed and climatic
Table 4 QRSS inputs
Group Input Value
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)2
log E∗ = −1.249937 + 0.029232P200 − 0.001767 P200 − 0.002841P4 − 0.058097Va
(
( )2
Vbeff 3.871977 − 0.0021P4 + 0.003958P38 − 0.000017 P38 + 0.00547P34
− 0.802208 ( )+ (3)
Vbeff + Va 1 + e−0.603313−(0.31335 log f )−(0.393532 log 𝜂)
where E* = asphalt mix dynamic modulus, 1 0 5 psi; seen from the figure that the mixes containing waste materi-
η = binder viscosity, in 1 06 poise.; f = loading frequency, als as mineral filler especially the slag exhibited better rut-
HZ; Va = air voids of the mix by volume, %; Vbeff = effective ting resistance compared to the traditional limestone filler.
bitumen content by volume, %; P34 = cumulative % retained The HMA performance in terms of AC rutting was almost
on the 3/4 in. sieve; P38 = cumulative % retained on the 3/8 the same for the different mixes containing other fillers. The
in. sieve; P4 = cumulative % retained on No. 4 sieve; P200 = % effect of the climatic conditions and speed on the predicted
passing the No. 200 sieve. AC rutting is shown clearly in the figure which increases as
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6.0
5.8
O.A.C. %
5.6
5.4
5.2
5.0
Limestone Marble Granite Slag
Filler Type
Economic study
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