®

Pyrolite 15

Selection & Specification Data Substrates & Surface Preparation

Generic Type A gypsum based, Spray applied Fire Resistive be applied prior to completion of concrete work on
Material (SFRM) designed for the fire protection of steel floor decking.
interior structural steel. Painted/Primed Apply to painted/primed steel decking only if permitted
Description A 15 lbs./ft³ density SFRM intended for the fire Steel Decks by the UL design. If the painted/primed deck is not an
protection of interior structural columns, beams, approved substrate, metal lath must first be secured
joists, decks, walls, roofs, girders, floors and pre- to the deck surfaces in accordance with the UL
cast concrete units. It is tested and certified for fire requirements.
resistance ratings up to 4 hours. Painted/Primed Painted steel joists do not require adhesive, lath or
Features • Durable cementitious formulation Steel Joists fastening devices. It is acceptable to apply directly to
• Noncombustible steel joists.
• Can be injected with Accelerator A-20 for fast set Painted/Primed Painted/primed structural steel is generally not
and increased yield (optional) Structural Steel approved by UL as an acceptable substrate for
• Asbestos-free – complies with EPA and OSHA SFRMs unless the paint or primer was included in
regulations. the fire test and/or UL listed for SFRM applications
• Mineral Wool free – no airborne fibers. to structural steel. UL has established conditions that
• Styrene free – no toxic decomposition gases. must be satisfied for application to primed or painted
• Economical – Maintains project on budget. structural steel, including: minimum bond strength
• Design flexibility with over 40 UL designs. criteria; dimensional limitations for the structural
Color Non-Uniform Tan members; use of a bonding agent or adhesive such
Finish Textured as Pyroprime 775 WB; use of metal lath to provide
a mechanical bond; or, use of mechanical breaks of
Primer Primers are not required or recommended. If a primer metal lath strips or steel pins and disks. Refer to the
is specified, or steel is primed, bond strength must UL Fire Resistance Directory-Volume 1 for details or
meet minimum UL criteria. Pyroprime 775 WB is used contact Carboline Technical Service before applying to
as a primer/bonding agent to meet this requirement any painted/primed steel beams or columns.
where specified. Southwest Type DK3 spatter coat
must be used as a primer/bonding agent on cellular
decks and roof decks per UL design requirements. Performance Data
Contact Carboline Technical Service for further
Test Method Results
information. Pyrolite fireproofing materials neither
ASTM C177 Insulation K Factor 0.73 BTU in/hr ft²-°F @ 75°F
promote nor prevent corrosion. Fireproofing should not
be considered part of the corrosion protection system. ASTM E136 Combustibility Passed (non-combustible)
1 15 pcf (240 kg/m³)
Fireproofing Generally not required. In severely corrosive ASTM E605 Density
average
Topcoats atmospheres, consult Carboline Technical Service for
ASTM E736 Cohesion/Adhesion 515 psf (24.6 kPa)
selection of coating most suitable for the operating
ASTM E759 Deflection Passed
environment.
ASTM E760 Impact Passed
Film Build 1/2" - 5/8" (12.7 - 15.9 mm) on initial pass ASTM E761 Compresive Strength 6,019 psf (288 kPa)
Limitations Not intended for permanent direct exposure to ASTM E84 Surface Burning Flame Spread: 10
weather or excessive physical abuse beyond normal Smoke Development: 0
construction cycles. Not recommended for use as ASTM E859 Air Erosion 0.00 g/ft² (0.00 g/m²)
refractory cement or where operating temperatures ASTM E937 Corrosion Passed
exceed 200°F (93°C).
ASTM G21 Fungi Resistance Passed (no growth)
Specific Heat 0.37 BTU/lb°F
Substrates & Surface Preparation 1
Air dry at ambient conditions to constant weight. Do not force cure. Use ASTM E605 Positive Bead
Displacement method utilizing #8 lead shot. Test density in accordance with AWCI Technical Manual
General Prior to application, all substrates must be clean and 12-A (Standard Practice for the Testing and Inspection of Field Applied Sprayed Fire-Resistive
free of loose scale, dirt, oil, grease, condensation, Materials, an Annotated Guide).
or any other substance that would impair adhesion. All values derived under controlled laboratory conditions.
Test reports and additional data available upon written request.
Contact Carboline Technical Service for further
information. Fireproofing shall be applied to the
underside of roof deck assemblies only after all roofing
work has been completed, and all roof traffic has
Mixing & Thinning
ceased. When applying to flexible roof systems it is Mixer 1. Use a minimum 12 to 16 cubic foot heavy-duty
required that Southwest Type DK3 spattercoat is used. mortar mixer capable of rotating at 40 rpm with rubber
Also be sure that all roof work is completed and water tipped blades that wipe the sides.
tight before commencing installation of fire protection. 2. Use continuous feed mixer. Contact Carboline
Roof traffic shall be limited to maintenance after fire Technical Service for recommendation. Densities may
protection is applied and cured. No fireproofing shall vary when using this type of mixing equipment.

August 2015 0149

To the best of our knowledge the technical data contained herein is true and accurate on the date of publication and is subject to change without prior notice. User must contact Carboline Company
to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for
coverage, performance or injuries resulting from use. Liability, if any, is limited to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY CARBOLINE,
EXPRESS OR IMPLIED, STATUTORY, BY OPERATION OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline® and Carboguard®
are registered trademarks of Carboline Company.
Page 1 of 3
 ®
Pyrolite 15
Mixing & Thinning
Mixing Always mix with clean potable water. The mixer
shall be kept clean and free of any previously mixed
materials which may cause premature setting of
product. A 2 bag mix is recommended for paddle type
mixers. Mix time should be approximately 2 minutes
per bag at 52 rpm. Do not over mix. The material
volume should not go over center bar of mixer. Use 10
¾ ± 1 ½ gallons (40.6 ± 5.6 liters) of water per 45 lb.
(20.4 kg) bag. Add water to the mixer first with blades
stopped. With mixer turned on, add material to the
water and begin mixing.
Pot Life 2 hours at 70°F (21°C) and less at higher
temperatures. Pot life ends when the material thickens
and becomes unusable.
Density For information and recommendations obtaining the
proper density and yield, contact the local Carboline
representative or Carboline Fireproofing Technical
Service.
Application Equipment Guidelines
Listed below are general equipment guidelines for the application of this product. Job site conditions
may require modifications to these guidelines to achieve the desired results.
Pump This material can be pumped with a wide range of
piston, rotor stator and squeeze pumps designed to
pump cement & plaster materials including:
Essick - model# FM9/FM5E (Rotor Stator/2L4)
Putzmeister - model# S5EV(Rotor Stator/2L6)
Hy-Flex - model# HZ-30E(Rotor Stator/2L6)
Hy-Flex - model# H320E (Piston)
Strong Mfg. - model# Spraymate 60 (Rotor Stator/2L6)
Airtech - model# Swinger (Piston)
Mayco - model# PF30 (Dual Piston)
Thomsen - model# PTV 700 (Dual Piston)
Marvel kit must be removed from piston pumps.
Ball Valves Ball valves should be located at the manifold and at
the end of the surge hose to facilitate cleaning.
Material Hose Use 15 to 25 feet (4.5 m to 7.6 m) of 3” (76 mm) I.D.
or larger surge hose from the manifold. Follow with a
16” (406 mm) tapered fitting to a 2” (50 mm) I.D. hose
to the spray area. Taper to 15 to 20 feet (4.5 m to 6 m)
of minimum 1-1/4” or 1” (25 mm) whip hose.
Standpipe Use 3” (76 mm) I.D. aluminum tubing with quick
external disconnections. Elbows should be 3” (76 mm)
I.D. with minimum 36” (0.9 m).
Nozzle/Gun Use a minimum 1” (25 mm) I.D. plaster type nozzle
with shut off valve, swivel and air shut off valve.
Orifice Size and 9/16 to 5/8” (9.5 mm - 15.9 mm) I.D. “blow-off” tips
Shields (mini shields optional)
Compressor Compressor on pump must be capable of maintaining
minimum 30 psi (206 kPa) and 9 to 11 cfm at the
nozzle.
Air Line Use 5/8” (15.9 mm) I.D. hose with a minimum bursting
pressure of 100 psi (689 kPa).
August 2015
To the best of our knowledge the technical data contained herein is true and accurate on the date of publication and is subject to change without prior notice. User must contact Carboline Company
to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for
coverage, performance or injuries resulting from use. Liability, if any, is limited to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY CARBOLINE,
EXPRESS OR IMPLIED, STATUTORY, BY OPERATION OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline® and Carboguard®
are registered trademarks of Carboline Company.
Application Procedures
General Thicknesses of 1/2" - 5/8" (12.7 mm - 15.9 mm) or
less can be applied in one pass. When additional
coats are required to reach specified thickness, apply
subsequent coats after prior coat has set. If preceding
coat has dried, dampen the surface with water prior to
application of additional coats. Material can be injected
with Accelerator A-20 solution to increase set time
and yield. Type DK3 (Spatter Coat) shall be applied
to all cellular floor units and to all roof deck systems
where indicated by the UL design. Contact Carboline
Fireproofing Technical Service for further information.
Field Tests Test for thickness and density in accordance with the
applicable building code, AWCI Technical Manual 12-
A (Standard Practice for the Testing and Inspection
of Field Applied Sprayed Fire-Resistive Materials, an
Annotated Guide), and ASTM E605 (Standard Test
Methods for Thickness and Density of Sprayed Fire-
Resistive Materials Applied to Structural Members).
Finishing Normally left as a sprayed texture finish.
Application Conditions
Condition Material Surface Ambient Humidity
Minimum 40 °F (4 °C) 40 °F (4 °C) 40 °F (4 °C) 0%
Maximum 100 °F (38 °C) 125 °F (52 °C) 110 °F (43 °C) 95%
Air and substrate temperatures shall be maintained 24 hours before, during and 24 hours after
application. Gypsum based products are susceptible to water and must be protected accordingly.
Contact Carboline Fireproofing Technical Service for recommendations.
Curing Schedule
Surface Temp. & 50% Dry to Recoat
Relative Humidity
77 °F (25 °C) 4 Hours
Recoat times will vary based upon ambient conditions and air movement. Material can be injected
with Accelerator A-20 for fast set time and increased yield.
Cleanup & Safety
Cleanup Pump, mixer and hoses should be cleaned with
potable water. Sponges should be run through the
hoses to remove any material remaining in the hoses.
Wet overspray must be cleaned up with clean, potable
water. Cured overspray material may be difficult to
remove and may require chipping or scraping to
remove.
Safety Follow all safety precautions on the Material Safety
Data Sheet. It is recommended that personal
protective equipment be worn, including spray suits,
gloves, eye protection and respirators.
Overspray Adjacent surfaces shall be protected from damage
and overspray. Sprayed fireproofing materials may
be difficult to remove from surfaces and may cause
damage to architectural finishes.
Ventilation In enclosed areas, ventilation shall not be less than 4
complete air exchanges per hour until the material is
dry.
0149
Page 2 of 3
 ®
Pyrolite 15
Testing / Certification / Listing
Underwriters Tested in accordance with ASTM E119/UL 263 at
Laboratories, Inc. Underwriter’s Laboratories, Inc. and listed by UL in the
following designs:
Columns:
Y707, Y708
Roof Assembly:
P734, P735, P736, P737, P738, P739, P926, P927,
P928, P929
Roof Beams:
S731, S732, S733
Beams:
N771, N772, N773, N774, N775
Floor/Ceiling Assembly (Restrained/Unrestrained):
D767, D768, D769, D770, D771, D772, D773, D774,
D775, D776, D777, D927, D928
Walls:
U704
Pre-cast Concrete & Steel Joists:
G706, G707, G708, J713, J714, J715, J716
City of New York MEA No. 147-95-M (Floor/Ceiling)
MEA No. 148-95-M (Beam)
MEA No. 149-95-M (Floor/Ceiling)
MEA No. 150-95-M (Roof/Ceiling)
MEA No. 151-95-M (Column)
MEA No. 152-95-M (Wall)
MEA No. 153-95-M (Beam for Roof Covering)
MEA No. 154-95-M (Floor/Ceiling)
MEA No. 155-95-M (Roof/Ceiling)
MEA No. 156-95-M (Floor/Ceiling)

Packaging, Handling & Storage

Shelf Life 12 months
Shipping Weight 45 lb. (20.4 kg)
(Approximate)
Storage Store indoors in a dry environment between
32°F - 125°F (0°C - 52°C)
Material must be kept dry or clumping of material may occur.

Packaging 45 lb. (20.4 kg) bags

August 2015 0149

To the best of our knowledge the technical data contained herein is true and accurate on the date of publication and is subject to change without prior notice. User must contact Carboline Company
to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for
coverage, performance or injuries resulting from use. Liability, if any, is limited to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY CARBOLINE,
EXPRESS OR IMPLIED, STATUTORY, BY OPERATION OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline® and Carboguard®
are registered trademarks of Carboline Company.
Page 3 of 3
Date Printed: 11/4/2014 Page 1 / 4

CHEMTREC Transportation Emergency Phone:

800-424-9300
Material Safety Pittsburgh Poison Control Center Health
Emergency No.: 412-681-6669

Data Sheet NOTE: The CHEMTREC Transportation Emergency

Phone is to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure, or
accident involving chemicals

1. Identification
Product Name: PYROLITE 15 Revision Date: 11/4/2014

Identification Number: 0149S7NL Supercedes Date: 7/20/2011

Product Use/Class: Cementitious Inorganic Fireproofing - FOR INDUSTRIAL USE ONLY

Manufacturer: Carboline Company Preparer: Regulatory Department

2150 Schuetz Road
St. Louis, MO 63146
800-848-4645

2. Hazard Identification
EMERGENCY OVERVIEW: Irritating to respiratory system. Material can create slippery conditions.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: May cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: May be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: No hazards to be specially mentioned.
MEDICAL CONDITIONS PRONE TO AGGRAVATION: AsthmaDermatitis
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

3. Composition/Information On Ingredients

Hazardous Ingredients

Weight % ACGIH TLV- ACGIH TLV- OSHA PEL-

Chemical Name CAS-No. OSHA PEL-TWA
Less Than TWA STEL CEILING
15 MG/M3
GYPSUM 26499-65-0 60.0 10 MG/M3 N/E TOTAL, 5 MG/M3 N/E
RESPIRABLE

4. First-aid Measures
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

AFTER SKIN CONTACT: Wash off with soap and plenty of water.

AFTER INHALATION: Remove person to fresh air. If signs/symptoms continue, get medical attention.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call a poison
control centre or doctor immediately.
Date Printed: 11/4/2014 Page 2 / 4

5. Fire-fighting Measures
Flash Point, °F: None Lower Explosive Limit, %: N/A
(N/A) Upper Explosive Limit, %: N/A
Extinguishing Media: None Known

UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information

SPECIAL FIREFIGHTING PROCEDURES: The product is not flammable.

6. Accidental Release Measures

PERSONAL SAFETY MEASURES/ENVIRONMENTAL MEASURES/METHOD OF CLEANING/CONTAINMENT: Use personal
protective equipment.

7. Handling and Storage

INSTRUCTIONS FOR SAFE HANDLING : Avoid breathing dust. Do not get in eyes, on skin, or on clothing. Wash thoroughly after
handling.

STORAGE CONDITIONS: Keep containers tightly closed in a dry, cool and well-ventilated place.

8. Exposure Controls/Personal Protection

ENGINEERING CONTROLS: Avoid dust accumulation in enclosed space.

RESPIRATORY PROTECTION: Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in
case of product release (dust). Use NIOSH approved respiratory protection. Respirator with a dust filter

SKIN PROTECTION: For prolonged or repeated contact use protective gloves.

EYE PROTECTION: Safety glasses with side-shields

OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.

PROTECTION AND HYGIENE MEASURES : Do not breathe dust. Wash hands before eating, drinking, or smoking. Handle in
accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Boiling Range: N/A - N/A Vapor Density: N/A
Odor: Dusty Odor Threshold: N/D
Appearance: White to Greyish Powder Evaporation Rate: N/A
Solubility in Water: N/D Specific Gravity: 0.12
Freeze Point: N/D pH: N/D
Physical State: Solid Vapor Pressure: No Information

(See section 16 for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Exposure to moisture.

MATERIALS TO AVOID: Strong oxidizing agents

Date Printed: 11/4/2014 Page 3 / 4
HAZARDOUS DECOMPOSITION PRODUCTS: None known.

HAZARDOUS POLYMERIZATION: Hazardous polymerisation does not occur.

STABILITY: Stable under normal conditions.

11. Toxicological Information

Chemical Name CAS-No. LD50 LC50
GYPSUM 26499-65-0 >5000 mg/kg,oral, rat Not Available

12. Ecological Information

ECOLOGICAL INFORMATION: No information available.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of in accordance with local regulations.

14. Transport Information

DOT Proper Shipping Name: Not Regulated Packing Group: N/A
DOT Technical Name: N/A Hazard Subclass: N/A
DOT Hazard Class: None Resp. Guide Page: N/A
DOT UN/NA Number: None
Additional Notes: No Information

15. Regulatory Information

U.S. Federal Regulations:
CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

None Known

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No Sara 313 components exist in this product.

Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

Date Printed: 11/4/2014 Page 4 / 4

U.S. State Regulations:

New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS-No.
PLASTER MIXTURE
VERMICULITE 1318-00-9
CELLULOSE FIBERS 65996-61-4
Pennsylvania Right-To-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS-No.
PLASTER MIXTURE
VERMICULITE 1318-00-9
CELLULOSE FIBERS 65996-61-4
CALIFORNIA PROPOSITION 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
Chemical Name CAS-No.
MICROCRYSTALLINE SILICA 14808-60-7
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.

No Proposition 65 Reproductive Toxins exist in this

product.

International Regulations:
CANADIAN WHMIS:

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class: Not WHMIS Regulated

16. Other Information

HMIS Ratings:
Health: 2 Flammability: 0 Reactivity: 0 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 0

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained herein is, to the best of our knowledge and belief accurate. However, since the conditions of handling
and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this
material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations.
 ®
Carboguard 893 SG

Selection & Specification Data Substrates & Surface Preparation

Generic Type Epoxy polyamide with corrosion inhibitor (zinc General Surfaces must be clean and dry. Employ adequate
phosphate) methods to remove dirt, dust, oil and all other
Description Versatile corrosion resistant coating. Used either as contaminants that could interfere with adhesion of the
a primer, intermediate coat, or self-priming finish over coating.
steel and zinc primers. May be topcoated with itself, or Steel For most applications: SSPC-SP6 to obtain a blast
a broad variety of high performance finish coats. Has profile of 1.0-2.0 mils (25-50 microns). May also be
surface tolerant properties. Optional (LT) cure for 35°F applied over SSPC-SP 3 for certain applications.
cure capability. See separate data sheet. Galvanized Steel Galvanizing requires a roughened surface for optimum
Features • Ready to apply after mixing; no sweat-in time or adhesion/performance of high build epoxies. Remove
thinning required. any contaminants per SSPC-SP1; ensure there
• Economical fit for use epoxy are no chemical treatments that may interfere with
• Available in a variety of rapid tint colors adhesion; and abrade the surface to establish a
• Attractive low sheen for tank exteriors suitable roughness (typically 1 mil). SSPC-SP7 or
• Used as a primer, intermediate, or finish coat SP11 are acceptable methods.
• Power tool cleaned surfaces acceptable Concrete or CMU Concrete must be cured 28 days at 75°F (24°C) and
• Optional low temperature (LT) cure Part B 50% relative humidity or equivalent. Prepare surfaces
• VOC compliant to current AIM regulations in accordance with ASTM D4258 Surface Cleaning of
Color Primer color (0700) gray. Variety of other finish coat Concrete and ASTM D4259 Abrading Concrete. Voids
colors in rapid tint service. See Limitations when using in concrete may require surfacing.
(LT) cure.
Finish Eggshell Performance Data
Primer Self-priming. May be applied over zinc rich primers. A
Test Method System Results
mist coat may be required to minimize bubbling over
ASSTM D522 Flexibility Blasted Steel 90 bend produced
inorganic zinc rich primers.
1 ct. 893 SG no cracking ,
Dry Film Thickness 3.0 - 6.0 mils (76 - 152 microns) per coat 3/4" Cylindrical
Mandrel Bend
3-5 mils (75-125 microns) can be used as a primer or intermediate coat. ASTM D4541 Adhesion Blasted Steel 1600 psi (Pneumatic)
Two coats may be used direct-to-metal. 2 ct. 893 SG
4-6 mils (100-150 microns) can be used as a finish coat over a primer.
Do not exceed 10 mils (250 microns) in a single coat. Excessive film Test reports and additional data available upon written request.
thickness over inorganic zincs may increase damage during shipping or
erection.

Solids Content By Volume 62% +/- 2% Mixing & Thinning

Theoretical 2 2
994 ft at 1.0 mils (24.4 m /l at 25 microns)
Coverage Rate 2 2
331 ft at 3.0 mils (8.1 m /l at 75 microns)
2 2
166 ft at 6.0 mils (4.1 m /l at 150 microns)
Allow for loss in mixing and application.
VOC Values Thinner 10 15 oz/gal = 3.26 lbs/gal (391 g/l)
Thinner 229 16 oz/gal: 3.3 lbs/gal (395 g/l)
Thinner 236 E 16 oz/gal = 2.80 lbs/gal (336 g/l)
Thinner 243 E 16 oz/gal = 2.80 lbs/gal (336 g/l)
Thinner 33 16 oz/gal = 3.31 lbs/gal (397 g/l)
As Supplied 2.80 lbs/gal (336 g/l)
These are nominal values and may very slightly with color.
Dry Temp. Continuous: 300 °F (149 °C)
Resistance
Prolonged exposure above 200°F/93°C may cause discoloration
(darkening), but will not affect performance.
Mixing Power mix separately, then combine and power mix.
DO NOT MIX PARTIAL KITS.
Thinning Normally not required but may thin as follows: Spray:
Up to 15 oz/gal (12%) with Thinner #10. Brush &
Roller: Up to 16 oz/gal (12%) with Thinner #33.
Thinner 236E or 243E may be used as an exempt
thinner in lieu of those listed above. Thinner 229
is used when very hot surfaces up to 140°F are
encountered. Use of thinners other than those
supplied or recommended by Carboline may adversely
affect product performance and void product warranty,
whether expressed or implied.
Ratio 1:1 Ratio (A to B)
Pot Life 4 Hours at 75°F (24°C) for either 893 SG or LT
cure. Pot life ends when coating thickens and loses
application properties. Pot life times will be less at
higher temperatures.

Limitations Epoxies lose gloss, discolor and eventually chalk

in sunlight exposure. LT Cure will cause additional
discoloration as it weathers and/or ages.
Topcoats May be coated with Acrylics, Epoxies, Alkyds, or
Polyurethanes depending on exposure and need.

November 2016 1000

To the best of our knowledge the technical data contained herein is true and accurate on the date of publication and is subject to change without prior notice. User must contact Carboline Company
to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for
coverage, performance or injuries resulting from use. Liability, if any, is limited to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY CARBOLINE,
EXPRESS OR IMPLIED, STATUTORY, BY OPERATION OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline® and Carboguard®
are registered trademarks of Carboline Company.
Page 1 of 2
 ®
Carboguard 893 SG
Application Equipment Guidelines Cleanup & Safety
Listed below are general equipment guidelines for the application of this product. Job site conditions Ventilation When used in enclosed areas, thorough air circulation
may require modifications to these guidelines to achieve the desired results.
must be used during and after application until the
Spray Application The following spray equipment has been coating is cured. The ventilation system should be
(General) found suitable and is available from equipment capable of preventing the solvent vapor concentration
manufacturers. from reaching the lower explosion limit for the solvents
used. User should test and monitor exposure levels
Conventional Pressure pot equipped with dual regulators, 3/8” to insure all personnel are below guidelines. If not
Spray I.D. minimum material hose, .070” I.D. fluid tip and sure or if not able to monitor levels, use MSHA/NIOSH
appropriate air cap. approved respirator.
Airless Spray Pump Ratio: 30:1 (min.)*
GPM Output: 2.5 (min.)
Material Hose: 3/8” I.D. (min.)
Packaging, Handling & Storage
Tip Size: .017”-.021” Shelf Life Part A & B: Min. 36 months at 75°F (24°C)
Output PSI: 2100-2300 *Shelf Life: (actual stated shelf life) when kept at recommended storage
Filter Size: 60 mesh conditions and in original unopened containers.
*PTFE packings are recommended and available from
the pump manufacturer. Shipping Weight 2 Gallon Kit - 26 lbs. (12 kg)
(Approximate) 10 Gallon Kit - 127 lbs. (58 kg)
Brush & Roller Multiple coats may be required to obtain desired
(General) appearance, recommended dry film thickness and Storage 40° - 110°F (4°- 43°C)
adequate hiding. Avoid excessive re-brushing or re- Temperature & 0-100% Relative Humidity.
rolling. For best results, tie-in within 10 minutes at Humidity
75°F (24°C). Flash Point Part A: 75°F (24°C)
Brush Use a medium bristle brush. (Setaflash) Part B: 75°F (24°C)
Roller Use 3/8” nap phenolic core roller. Storage Store indoors
This product is solvent based and not affected by excursions below
these published storage temperatures, down to 10°F, for a duration of no
Application Conditions more than 14 days. Always inspect the product prior to use to make sure
it is smooth and homogeneous when properly mixed.
Condition Material Surface Ambient Humidity
Minimum 50 °F (10 °C) 50 °F (10 °C) 50 °F (10 °C) 0% In White Base 1.97 Gallon Kit - (Short Filled) Part A
(WITE)
Maximum 90 °F (32 °C) 140 °F (60 °C) 110 °F (43 °C) 95%
9.84 Gallon Kit - (Short Filled) Part A
This product simply requires the substrate temperature to be above the dew point. Condensation
due to substrate temperatures below the dew point can cause flash rusting on prepared steel and
interfere with proper adhesion to the substrate. Special application techniques may be required
above or below normal application conditions. • Surface and ambient temperatures may be reduced
to 35°F when using the (LT) cure.

Curing Schedule
* Dry to Recoat Maximum Recoat Time
Surface Temp.
50 °F (10 °C) 24 Hours 365 Days
60 °F (16 °C) 10 Hours 365 Days
75 °F (24 °C) 7 Hours 365 Days
90 °F (32 °C) 4 Hours 365 Days
These times are based on a 4.0-6.0 mil (100-150 micron) dry film thickness for atmospheric
exposures. Higher film thickness, insufficient ventilation or cooler temperatures will require longer
cure times and could result in solvent entrapment and premature failure. Excessive humidity or
condensation on the surface during curing can interfere with the cure, can cause discoloration
and may result in a surface haze. Any haze or blush must be removed by water washing before
recoating. If the maximum recoat times have been exceeded, the surface must be abraded by sweep
blasting or sanding prior to the application of additional coats. For force curing, contact Carboline
Technical Service for specific requirements.

Cleanup & Safety

Cleanup Use Thinner #2 or Acetone. In case of spillage, absorb
and dispose of in accordance with local applicable
regulations.
Safety Read and follow all caution statements on this
product data sheet and on the MSDS for this product.
Employ normal workmanlike safety precautions.
Hypersensitive persons should wear protective
clothing, gloves and use protective cream on face,
hands and all exposed areas.

November 2016 1000

To the best of our knowledge the technical data contained herein is true and accurate on the date of publication and is subject to change without prior notice. User must contact Carboline Company
to verify correctness before specifying or ordering. No guarantee of accuracy is given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for
coverage, performance or injuries resulting from use. Liability, if any, is limited to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY CARBOLINE,
EXPRESS OR IMPLIED, STATUTORY, BY OPERATION OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline® and Carboguard®
are registered trademarks of Carboline Company.
Page 2 of 2
Date Printed: 09/12/2017 Product: 1000A1NL

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 1000A1NL

Product Name: CARBOGUARD 893 SG PART A Revision Date: 09/12/2017

Supercedes Date: 06/28/2017
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Alotta, Vicki - ehs@stoncor.com

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 4

Hazardous to the aquatic environment, Chronic, category 2
Carcinogenicity, category 1A
Eye Irritation, category 2
Flammable Liquid, category 3
STOT, repeated exposure, category 1
Skin Irritation, category 2
Skin Sensitizer, category 1

Page 1 / 11
Date Printed: 09/12/2017 Product: 1000A1NL

2.2 Label elements

Symbol(s) of Product

Signal Word
danger

Named Chemicals on Label

ORTHO-XYLENE, ETHYL BENZENE, PARA-XYLENE, META-XYLENE, MICROCRYSTALLINE SILICA, EPOXY RESIN

HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour.

Skin Irritation, category 2 H315 Causes skin irritation.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Carcinogenicity, category 1A H350-1A May cause cancer.
STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment, H411 Toxic to aquatic life with long lasting effects.
Chronic, category 2
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention
P314 Get medical advice/attention if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

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Date Printed: 09/12/2017 Product: 1000A1NL

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
14808-60-7 MICROCRYSTALLINE SILICA 25-50
13463-67-7 TITANIUM DIOXIDE 25-50
25036-25-3 EPOXY RESIN 10-25
25068-38-6 EPOXY RESIN 10-25
108-38-3 META-XYLENE 2.5-10
106-42-3 PARA-XYLENE 2.5-10
7779-90-0 ZINC PHOSPHATE 2.5-10
1333-86-4 CARBON BLACK 2.5-10
100-41-4 ETHYL BENZENE 2.5-10
108-65-6 1-METHOXY-2-PROPANOL ACETATE 2.5-10
95-47-6 ORTHO-XYLENE 2.5-10

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

14808-60-7 GHS08 H350-372 0
13463-67-7 0
25036-25-3 GHS07 H315-317-319 0
25068-38-6 GHS07-GHS09 H315-317-319-335-411 0
108-38-3 GHS02-GHS07 H226-312-315-332 0
106-42-3 GHS02-GHS07-GHS08 H226-304-312-315-332-335-371 0
7779-90-0 GHS09 H400-410 0
1333-86-4 GHS07-GHS08 H319-335-351-372 0
100-41-4 GHS02-GHS07-GHS08 H225-304-315-319-332-373-412 0
108-65-6 GHS02 H226 0
95-47-6 GHS02-GHS07 H226-312-315-332 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness. This product contains silica which is classified by IARC as a known human carcinogen (Group 1).
Crystalline silica is known to cause silicosis.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour

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Date Printed: 09/12/2017 Product: 1000A1NL

in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks with water spray. Flammable.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

For personal protection see section 8. Ensure adequate ventilation. Evacuate personnel to safe areas. Evacuate personnel
to safe areas. Remove all sources of ignition. Remove all sources of ignition. To avoid ignition of vapours by static electricity
discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13). Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools.
Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal
protection.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

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Date Printed: 09/12/2017 Product: 1000A1NL

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name % ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- OEL Note
TWA STEL TWA CEILING
MICROCRYSTALLINE SILICA 25-50 0.025 mg/m3 N/E 0.05 mg/m3 N/E
(respirable) (respirable)
TITANIUM DIOXIDE 25-50 10 MGM3 N/E 10 MGM3 N/E
EPOXY RESIN 10-25 N/E N/E N/E N/E
EPOXY RESIN 10-25 N/E N/E N/E N/E
META-XYLENE 2.5-10 100 PPM 150 PPM 435 MG/M3 N/E
PARA-XYLENE 2.5-10 100 PPM 150 PPM 435 MGM3 N/E
ZINC PHOSPHATE 2.5-10 10 mg/m3 10 mg/m3 N/E N/E
CARBON BLACK 2.5-10 3.0 MG/M3 N/E 3.5 MG/M3 N/E
ETHYL BENZENE 2.5-10 20 PPM N/E 435 MGM3 N/E
1-METHOXY-2-PROPANOL ACETATE 2.5-10 N/E N/E N/E N/E
ORTHO-XYLENE 2.5-10 100 PPM 150 PPM 435 MG/M3 N/E

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier.
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
Lightweight protective clothing
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Viscous Liquid, Various Colors

Physical State Liquid

Odor Solvent
Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) 149 F (65 C) - 500 F (260 C)
Flash Point, (°C) 24
Evaporation rate Slower than Ether

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Date Printed: 09/12/2017 Product: 1000A1NL

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 0.9 - 13.1

limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: 324

Specific Gravity (g/cm3) app. 1.47

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

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Date Printed: 09/12/2017 Product: 1000A1NL

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available

13463-67-7 TITANIUM DIOXIDE 25000 mg/kg, oral (rat) Not Available Not Available

>2000 mg/kg, dermal,

25036-25-3 EPOXY RESIN >2000 mg/kg, oral, rat
rat
Not Available

23000 mg/kg, dermal,

25068-38-6 EPOXY RESIN 11400 mg/kg, rat, oral
rabbit
>20 mL/kg skin, sensitizer

108-38-3 META-XYLENE Not Available Not Available Not Available

106-42-3 PARA-XYLENE Not Available Not Available Not Available

7779-90-0 ZINC PHOSPHATE 3846mg/kg, oral rat Not Available Not Available

1333-86-4 CARBON BLACK 8000 mg/kg oral, rat Not Available Not Available

>5000 mg/l, dermal

100-41-4 ETHYL BENZENE 3500 mg/kg rat, oral
rabbit
17.2 mg/L Inh, Rat, 4Hr

108-65-6 1-METHOXY-2-PROPANOL ACETATE 8532 mg/kg, oral (rat) >5000 mg/kg 101 ppm/4 hr, rat, inh

95-47-6 ORTHO-XYLENE Not Available Not Available Not Available

Additional Information:
This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This product may
contain Titanium Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate
evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This product may contain Carbon Black,
which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of
carcinogenicity in humans and sufficient evidence in experimental animals. The classification(s) is/are relevant when exposed to
these respirable substances in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other
surface preparation activities.

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12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

14808-60-7 MICROCRYSTALLINE SILICA No information No information No information

13463-67-7 TITANIUM DIOXIDE No information No information No information
25036-25-3 EPOXY RESIN No information No information No information
25068-38-6 EPOXY RESIN 2.1 mg/l (daphnia) 11 mg/l (algae) 1.3 mg/l (fish)
108-38-3 META-XYLENE No information No information No information
106-42-3 PARA-XYLENE No information No information No information
0.136 - 0.150 mg/l
0.04 - 0.86 mg/l 0.14 - 0.26 mg/l (Rainbow
7779-90-0 ZINC PHOSPHATE (Daphnia Magna)
(Selenastrum
Trout)
capricornutum)
1333-86-4 CARBON BLACK No information No information No information
1.8 mg/l (Daphnia
100-41-4 ETHYL BENZENE Magna)
4.6 mg/l (Green Algae) 4.2 mg/l (Rainbow Trout)

408 mg/l (Daphnia >1000 mg/l (Green

108-65-6 1-METHOXY-2-PROPANOL ACETATE Magna) Algae)
161 mg/l (Fathead Minnow)

95-47-6 ORTHO-XYLENE No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

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Date Printed: 09/12/2017 Product: 1000A1NL

14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint
Technical name N/A
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard N/A
14.4 Packing group III
14.5 Environmental hazards Marine Pollutant: Yes (Epoxy Resin)
14.6 Special precautions for user Unknown
EmS-No.: F-E, S-E

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
META-XYLENE 108-38-3
PARA-XYLENE 106-42-3
ZINC PHOSPHATE 7779-90-0
ETHYL BENZENE 100-41-4
ORTHO-XYLENE 95-47-6
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name CAS-No.
MODIFIED UREA-FORMALDEHYDE RESIN TRADE SECRET
U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

No NJ Right-To-Know components exist in this
product.

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Date Printed: 09/12/2017 Product: 1000A1NL

Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

IRON OXIDE 1309-37-1
COLOR PIGMENT 5567-15-7
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.

MICROCRYSTALLINE SILICA 14808-60-7
TITANIUM DIOXIDE 13463-67-7
CARBON BLACK 1333-86-4
ETHYL BENZENE 100-41-4
FORMALDEHYDE 50-00-0
METHYL ISOBUTYL KETONE 108-10-1
BENZENE 71-43-2
CUMENE 98-82-8
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.
Chemical Name CAS-No.
TOLUENE 108-88-3
METHYL ALCOHOL 67-56-1
METHYL ISOBUTYL KETONE 108-10-1
BENZENE 71-43-2

International Regulations: As follows -

* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H351 Suspected of causing cancer.
H371 May cause damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

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Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

Page 11 / 11
Date Printed: 09/12/2017 Product: 1000B1NL

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 1000B1NL

Product Name: CARBOGUARD 893 SG PART B Revision Date: 09/12/2017

Supercedes Date: 06/28/2017
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Alotta, Vicki - ehs@stoncor.com

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 4

Hazardous to the aquatic environment, Chronic, category 3
Carcinogenicity, category 1A
Flammable Liquid, category 3
STOT, repeated exposure, category 1
Skin Corrosion, category 1
Skin Sensitizer, category 1

Page 1 / 9
Date Printed: 09/12/2017 Product: 1000B1NL

2.2 Label elements

Symbol(s) of Product

Signal Word
danger

Named Chemicals on Label

ORTHO-XYLENE, ETHYL BENZENE, PARA-XYLENE, META-XYLENE, MICROCRYSTALLINE SILICA, TOFA, REACTION
PRODUCTS WITH TEPA
HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour.

Skin Corrosion, category 1 H314-1 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Carcinogenicity, category 1A H350-1A May cause cancer.
STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment, H412 Harmful to aquatic life with long lasting effects.
Chronic, category 3
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P308+313 IF exposed or concerned: Get medical advice/attention
P314 Get medical advice/attention if you feel unwell.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures

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Hazardous Ingredients
CAS-No. Chemical Name %
14808-60-7 MICROCRYSTALLINE SILICA 50-75
108-38-3 META-XYLENE 2.5-10
68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA 2.5-10
106-42-3 PARA-XYLENE 2.5-10
100-41-4 ETHYL BENZENE 2.5-10
64742-95-6 AROMATIC HYDROCARBON 2.5-10
67-63-0 ISOPROPANOL 2.5-10
95-47-6 ORTHO-XYLENE 2.5-10

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

14808-60-7 GHS08 H350-372 0
108-38-3 GHS02-GHS07 H226-312-315-332 0
68953-36-6 GHS05-GHS07 H314-317 0
106-42-3 GHS02-GHS07-GHS08 H226-304-312-315-332-335-371 0
100-41-4 GHS02-GHS07-GHS08 H225-304-315-319-332-373-412 0
64742-95-6 GHS02-GHS07-GHS08-GHS09 H226-304-315-319-332-335-336-411 0
67-63-0 GHS02-GHS07 H225-319-336 0
95-47-6 GHS02-GHS07 H226-312-315-332 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness. This product contains silica which is classified by IARC as a known human carcinogen (Group 1).
Crystalline silica is known to cause silicosis.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

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In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks with water spray. Flammable.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
For personal protection see section 8. Ensure adequate ventilation. Evacuate personnel to safe areas. Evacuate personnel
to safe areas. Remove all sources of ignition. Remove all sources of ignition. To avoid ignition of vapours by static electricity
discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13). Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools.
Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal
protection.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection

8.1 Control parameters

Ingredients with Occupational Exposure Limits

(US)

Name % ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- OEL Note
TWA STEL TWA CEILING
MICROCRYSTALLINE SILICA 50-75 0.025 mg/m3 N/E 0.05 mg/m3 N/E
(respirable) (respirable)
META-XYLENE 2.5-10 100 PPM 150 PPM 435 MG/M3 N/E
TOFA, REACTION PRODUCTS WITH TEPA 2.5-10 N/E N/E N/E N/E
PARA-XYLENE 2.5-10 100 PPM 150 PPM 435 MGM3 N/E
ETHYL BENZENE 2.5-10 20 PPM N/E 435 MGM3 N/E
AROMATIC HYDROCARBON 2.5-10 N/E N/E N/E N/E
ISOPROPANOL 2.5-10 200 PPM 400 PPM 980 MGM3 N/E

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ORTHO-XYLENE 2.5-10 100 PPM 150 PPM 435 MG/M3 N/E

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier.
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
Lightweight protective clothing
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Brown, Viscous Liquid
Physical State Liquid
Odor Solvent
Odor threshold N/D
pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) 176 F (80 C) - 500 F (260 C)
Flash Point, (°C) 24
Evaporation rate Slower than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 0.9 - 12.0

limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

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9.2 Other information

VOC Content g/l: 324

Specific Gravity (g/cm3) 1.45

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available

108-38-3 META-XYLENE Not Available Not Available Not Available

68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA 4750 mg/kg oral, rat Not Available

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106-42-3 PARA-XYLENE Not Available Not Available Not Available

>5000 mg/l, dermal

100-41-4 ETHYL BENZENE 3500 mg/kg rat, oral
rabbit
17.2 mg/L Inh, Rat, 4Hr

3670 ppm/8 hours, rat,

64742-95-6 AROMATIC HYDROCARBON 4700 mg/kg, oral, rat Not Available
inhalation
12800 mg/kg, dermal, 22500 ppm/8hrs rat,
67-63-0 ISOPROPANOL 4720 mg/kg rat, oral
rabbit inhalation

95-47-6 ORTHO-XYLENE Not Available Not Available Not Available

Additional Information:
This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. The classification(s) is/
are relevant when exposed to these respirable substances in dust or powder form only, including cured product that is subject to
sanding, grinding, cutting, or other surface preparation activities.

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

14808-60-7 MICROCRYSTALLINE SILICA No information No information No information

108-38-3 META-XYLENE No information No information No information
68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA No information No information No information
106-42-3 PARA-XYLENE No information No information No information
1.8 mg/l (Daphnia
100-41-4 ETHYL BENZENE Magna)
4.6 mg/l (Green Algae) 4.2 mg/l (Rainbow Trout)

64742-95-6 AROMATIC HYDROCARBON No information No information No information

67-63-0 ISOPROPANOL No information No information No information
95-47-6 ORTHO-XYLENE No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

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14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint
Technical name N/A
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard N/A
14.4 Packing group III
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: F-E, S-E

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
META-XYLENE 108-38-3
PARA-XYLENE 106-42-3
ETHYL BENZENE 100-41-4
ISOPROPANOL 67-63-0
ORTHO-XYLENE 95-47-6
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name CAS-No.
No TSCA 12(b) components exist in this product.
U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

POLYAMIDE RESIN TRADE SECRET
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

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POLYAMIDE RESIN TRADE SECRET

California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.

MICROCRYSTALLINE SILICA 14808-60-7
ETHYL BENZENE 100-41-4
CUMENE 98-82-8
BENZENE 71-43-2
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.
Chemical Name CAS-No.
TOLUENE 108-88-3
BENZENE 71-43-2

International Regulations: As follows -

* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H371 May cause damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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