Professional Documents
Culture Documents
02-09-18 SR - IZ Jee-Adv 2011-P1 PTA-03 Q PDF
02-09-18 SR - IZ Jee-Adv 2011-P1 PTA-03 Q PDF
02-09-18 SR - IZ Jee-Adv 2011-P1 PTA-03 Q PDF
INDIA
Sec: Sr. IZ Date02-09-18
Time: 09:00 AM to 12:00 NOON Max. Marks: 240
2011_PAPER-I
02-09-18_Sr.IZ_Jee Adv_PTA-03_Weekend Syllabus
MATHS: Indefinite Integration: integration as the inverse process of differentiation, indefinite integrals of
standard functions. Integration by parts, integration by the methods of substitution and partial fractions.
PHYSICS: Electrostatics + Gauss law + Gravitation: Coulomb’s law; Electric field and potential; Electrical
potential energy of a system of point charges and of electrical dipoles in a uniform electrostatic field; Electric
field lines; Flux of electric field; Gauss’s law and its application in simple cases, such as, to find field due to
infinitely long straight wire, uniformly charged infinite plane sheet and uniformly charged thin spherical
shell. Law of gravitation; Gravitational potential and field; Acceleration due to gravity: Motion of planets
and satellites in circular orbits; Escape velocity.
JEE-ADVANCE-2011-P1-Model
Time: 3:00 Hour’s IMPORTANT INSTRUCTIONS Max Marks: 240
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Choice 3 -1 7 21
Sec – II(Q.N : 8 – 11) Questions with Multiple Correct Choice 4 0 4 16
Questions with Comprehension Type
Sec – III(Q.N : 12 – 16) 3 -1 5 15
(2 Comprehensions – 2 + 3 = 5Q)
Sec – IV(Q.N : 17 – 23) Questions with Integer Answer Type 4 0 7 28
Total 23 80
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 24 – 30) Questions with Single Correct Choice 3 -1 7 21
Sec – II(Q.N : 31 – 34) Questions with Multiple Correct Choice 4 0 4 16
Questions with Comprehension Type
Sec – III(Q.N : 35 – 39) 3 -1 5 15
(2 Comprehensions – 2 + 3 = 5Q)
Sec – IV(Q.N : 40 – 46) Questions with Integer Answer Type 4 0 7 28
Total 23 80
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 47 – 53) Questions with Single Correct Choice 3 -1 7 21
Sec – II(Q.N : 54 – 57) Questions with Multiple Correct Choice 4 0 4 16
Questions with Comprehension Type
Sec – III(Q.N : 58 – 62) 3 -1 5 15
(2 Comprehensions – 2 + 3 = 5Q)
Sec – IV(Q.N : 63 – 69) Questions with Integer Answer Type 4 0 7 28
Total 23 80
NaOC 2 H5 AlCl 3
A) B)
OH
2 H SO
4 3 2 BF , OEt
C) D)
2. Which of the following xylene(s) can give 1,3-dibromo product as one of the possible
product (as per IUPAC nomenclature) on reaction with Br2 / FeBr3 .
(Hint: Consider methyl group, CH 3 - as ortho / para directing group
Use dimethyl benzene as suffix, don’t use xylene as suffix)
CH3 CH3
CH3
CH3 CH3
CH3
Br2
CCl4
Br2
CCl4
Br2 Br2
CCl4
CCl4
A) B) C) D)
4. The major product of the following reaction is:
Br
H3C KOH
SN 2
NH2
CH3
OH
OH
CH3 H3C
H2N NH2
A) CH3
B) CH3
OH
OH
CH3
H3C
H2N NH2
C) CH3
D) CH3
6. For each of the following compounds, indicate which ring you would expect to be
attacked in nitration-
O2 N
O
O 2N
CH2 C O
, ,
NO 2
(P) (Q) (R) (S) (T) (U)
A) P, S, T B) Q, R, T C) Q, S, U D) P, S, U
Me Me
A) B)
C) Racemic mixture D) CH2 CH2
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct
8. When benzene is treated with Cl2 under the influence of UV-light, a solid material,
MW 291, [X] is formed. Quantitative analysis given its empirical formula CHCl.
When benzene is treated with Cl2 in the presence of FeCl3 , solid material, MW 285,
[Y] is formed. Quantitative analysis given its empirical formula CCl.
Identify the correct statement(s)-
A) [X] can show optical isomerism
B) [X] on reaction with alc. KOH / Δ gives [Y]
C) [X] formed by free radical substitution
D) [Y] formed by electrophilic substitution.
Sec: Sr. IZ space for rough work Page 6
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
9. Identify the product(s) in the given reactions I and II –
Et
, cat.AlCl3
Cl
Reaction(I)
CO 2Me
OMs , cat.AlCl3
O
Reaction(II)
(OMs Mesityl, -O S Me )
O
Et Et OAc OAc
A) B) C) D)
10. The major product of the following reaction is:
O
A) MeO O O B) M e O O
OMe OM e O
C) O O D) O
11. The reactivity of compound Z with halogen under appropriate condition is given
below
NO 2
Br2
FeBr3
Monosubstituted
product
CH3
[Z]
The observed product of electrophilic substitution reaction-
A) can be explained by electronic effect of methyl group.
B) can be explained as ortho product of methyl group.
C) can be explained by sterric effect of methyl group
D) can be explained by electronic effect of nitro group
Sec: Sr. IZ space for rough work Page 8
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
SECTION – III
(COMPREHENSION TYPE)
This section contains 2 groups of questions. One group has 3 questions and another group has 2 multiple choice
questions based on a paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY
ONE is correct.
Paragraph For Questions 12 and 13
Answer the Q12 and Q,13 by appropriately matching the information given in the
three columns of the following table
Column 1,2 and 3 contains starting materials, reactions condition and type of
reaction/ intermediates-
Column – 1 Column – 2 Column – 3
I) tert-butyl bromide i)EtMgBr ii)H3O P) Substitution
II) Toluene iii)Br2 / hν Q) Nu-addtion
III) Pentane-2, 4-dione iv)aq.NaOH R) free radical
IV) Acetophenone v)CH3 Cl / Anhyd.AlCl3 S) carbanion
12. The only correct combination that gives two different tertiary alcohols
A) (I) (iv) (P) B) (IV) (i) (ii) (Q)
C) (III) (iv) (Q) D) (II) (iii) (iv) (P)
13. Which of the following is NOT the correct combination-
A) (I) (iv) (P) B) (II) (iii) (P) C) (IV) (v) (S) D) (III) (i) (S)
Sec: Sr. IZ space for rough work Page 9
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
Paragraph For Questions 14 to 16
The reaction of compound P with CH3MgBr (excess) in C2H5 2 O followed by addition of
H2O gives Q. The compound Q on treatment with H2 SO 4 at 0°C gives R. The reaction
of R with CH 3COCl in the presence of anhydrous AlCl3 in CH2Cl2 followed by treatment
with H2O produces compound S. [Et in compound P is ethyl group]
CO 2Et
Q R S
P
14. The product R is
CH3
H3C
CH3
A) B)
SO 3H
H3C CH3 O CH3
C) D)
15. The reaction, Q to R is
A) Dehydration B) Aromatic sulfonation
C) Friedel-crafts alkylation D) Friedel – Crafts acylation
alc.KOH
Δ
Elimination product(s)
C9H16
19. Et Br
CH3 C2H5OH(aq)
acidicsolution
iii)
F
NaOH(aq)
F liberated
O 2N
iv) CH3
F
NaOH(aq)
F is not liberated
H3C
v) CH 2 NO 2
HBr
CCl4
22. Find the total number of monobromo products obtained during the reaction-
CH CH2
NBS
h
H3C
23. Find the total number of optically active products obtained in the following reaction-
Me
Na
D H
Et2O
CH.D.Cl
R2 R2
A) B)
GMh GMh
R2 2R 2
C) D)
GMh GMh
27. Two point masses each having a magnitude m are fixed at a separation l from each
other. P is a point between the masses on the line joining them at a distance x from
A) B)
C) D)
28. A long coaxial cable consists of a uniform cylindrical core of radius R with uniform
volume charge density and a hollow cylindrical sheath of outer radius 2R with
surface charge density .If the external electric field (i.e outside the cable) vanishes,
and are related as
2R
R
A) 2 R B) 4 R C) 2 R D)
Sec: Sr. IZ space for rough work Page 16
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
29. A sphere of uniform mass density is spread over the region x 2 y 2 z 2 a 2 . A portion
2 a2
of matter extending over the region x a / 2 y 2 z 2 is scooped out, the resultant
4
a
gravitational field intensity at the point 0, , 0 in the vector form?
2
A)
3 2
Ga ˆi 2 2 1 ˆj B)
3 2
Ga ˆi 2 2 1 ˆj
2
C) Gajˆ
3
D) Ga ˆi 2 2 1 ˆj
2
30. The +Q charge is fixed in position, and the +q charge is brought close to +Q and
released from rest. Which of the following graphs best depicts the acceleration (a) of
the +q charge as a function of its distance ( r ) from +Q ?
a
a
A) r B) r
a a
C) r D) r
Sec: Sr. IZ space for rough work Page 17
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct
31. A double star is a system of two stars rotating about their centre of mass only under
their mutual gravitational attraction. Let the stars have masses m and 2m and their
separation be l. Their time period of rotation about their centre of mass will be
proportional to
1 1
A) l 3/2 B) l C) m 2 D) m 2
32. A conductor A is given a charge of amount Q and then placed inside a deep metal
can B, without touching it. Then identify the correct alternative(s).
B
+Q
PSin Sin
A) Potential, V
4 0 r 2
PSin Cos
B) Potential, V
4 0 r 2
P
C) Electric field Intensity. E 3
1 3Sin 2 Sin 2
4 0 r
P
D) Electric field Intensity, E 3
1 3Cos 2 Sin 2
4 0 r
34. In a uniform electric field, equipotential surface must
A) be plane surfaces
B) be normal to the direction of the field
C) be spaced such that surfaces having equal differences in potential are separated by
equal distances
D) have decreasing potential in the direction of the field
Sec: Sr. IZ space for rough work Page 19
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 paragraphs. Based upon one of the paragraphs 3 multiple choice questions based on the 3
multiple choice questions have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Paragraph For Questions 35 and 36
Suppose in an insulating medium having dielectric constant K = 1, volume density of
positive charge varies with y- coordinate according to law = ay. A particle of mass
m having positive charge q is placed in the medium at point A (0, y0) and projected
with velocity V V0 i is as shown in figure.
y
V0 A
Neglecting gravity and frictional resistance of the medium and assuming electric field
strength to be zero at y = 0,
qa 3 qa
C)
m 0
y y03 D)
3m 0
2 y3 y03
36. The slope of trajectory of the particle as a function of y is
qa 2qa
2
A) y 3 y03 B) 2
y 3 y03
3m 0V0 3m 0V0
qa qa
C)
m 0V02
y3 y03 D)
2m 0V02
y 3 y03
Paragraph For Questions 37 to 39
The science-fiction writer RA. Heinlein describes the ‘‘skyhook’’ geostationary
satellite to consist, in its simplest form, of a uniform cable of mass per unit length,
placed in the equatorial plane, oriented radially and extending from just above the
surface of the Earth to a distance L above the Earth as shown in the diagram below.
( is the angular speed of Earth) g is the acceleration due to gravity on surface of
earth , R- radius of earth
L
R
between orbital velocity( V0 ) and radial distance of satellite from earth center (r) by
a
taking log V0 on Y-axis and log r on X- axis is . Find a+b (where a&b are +ve
b
numbers).
43. A uniform solid sphere of mass M and radius R is formed due to gravitational
compression. Treating earth to be a sphere, the pressure at its centre is
(approx) q 8.5 1010 Nm 2 . Find q.
[mass of earth = 5.98 x 1024 kg , radius of earth is 6.4 106 m]
44. The region between two concentric spherical shells of radii R1 and R2 includes a
a
volume charge density given by where a, is a constant and r is the distance from
r
the centre . There is a charge Q located at its centre. The value of ‘a’ for which the
Q
region R1 r R2 has a constant electric field intensity is . Find z
z R12
then
A) A = 2 B) B = -2 C) C = 2 D) A=0
2
d
50. If x3
dx 2
2 2
e x dx e x . f x C then the local maximum value of f x equals x R
A) 87/8 B) 2 C) 3 D) 0
tan
51. If f d is continuous function and f 0 0 then the value of
sin 2
2f f equals
4 3
1 1
A) 3 1 B) 2 1 C)
2
3 1 D)
2
2 1
Sec: Sr. IZ space for rough work Page 26
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
2
ax 2bx c
52. If 2
dx B 2 AC is a rational function of x then which is necessarily true
Ax 2
2 Bx C
A) 2Bb = Ac + aC B) 2Bb =Aa + cC
C) 2Cc = Ab + Ba D) 2aA=bB+cC
53. If e x x 4
2 dx
e x f x
C then which is correct
5/ 2 3/ 2
1 x2
1 x2
A) f 1 3 B) f 2 6 C) f 1 0 2 D) f x 0x R
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct
e x f 11 x e x f 1 x
54. Let f be a differentiable function satisfying 2x
1 and f 0 0, f 1 0 1
e
then which is/are correct
xf 1 x f x
A) 1 x 0
x 2e x
B) For, x > 0, f(x) is increasing function
C) For x < 0, f(x) is decreasing function
D) Number of solutions of 3f(x) + 1 =0 is 2
A) 2e sin x
c B)
1 e sin x
C
2
2
C) e sin x
e sin x
2 C D) e sin x
1 C
cos 2 x sin 4 x
57. If cos x 1 cos
dx A sec 2 x B ln 1 cos 2 x + C ln 1 cos2 2 x D then which is/are
4 2
2x
correct
A) A < B B) A = C C) A > C D) B > 1
. is GIF
1 3 sin x cos x B
64. If dx A.ln B tan 1 sin x cos x C then equals
sin x sec x 3 sin x cos x A
. is GIF
tan 4 x A
65. If 1 tan 2 x dx A tan x B ln sec 2 x tan 2 x C.x D then the value of BC equals
x2
66. If f x dx and f 0 0 then the value of f 1 equals . is GIF
1 x2 1 1 x2
Sec: Sr. IZ space for rough work Page 30
02-09-18_Sr.IZ_JEE-Adv_2011_P1_PTA-03_QP
t4 t2 3 dt then the value of equals
2
2t 2
3
cot x tan x
68. If dx x , x 0, and and maximum value of x is
2 cos x sin x 2 4 2
value of A + B equals