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MITSUBISHI
SYNTHESIS
SYNTHESIS GAS
GAS PROCESS
PROCESS
FOR
FOR CO
CO22 EMISSION
EMISSION FREE
FREE
GTL
GTL PLANT
PLANT
CO
CO22 EMISSION
EMISSION in
in GTL
GTL PLANT
PLANT
In GTL Plant about 70% of carbon in natural
gas is converted in diesel oil and kerosene,
30% of carbon is emitted into atmosphere as
CO2.
CO 2 mitigation
70,000 BBL/D merit
Plant in GTL Plant.
• Product value ... 70,000 BBL/D × 25 US$/BBL
= 1.75 Million US$/D
• CO2 Emission Debit
... 13,700 Ton/D × 20 US$/T
= 0.274 Million US$/D
If CO2 emitted into atmosphere is mitigated,
about 15% of commercial value can be enjoyed.
PARTIAL
PARTIAL OXYDATION
OXYDATION V.S.STEAM
V.S.STEAM REFORMING
REFORMING
• GTL Process Developer Believe
1) Partial Oxidation process only can adjust CO & H2 ratio (1:2) for FT synthesis
2) Partial Oxidation process may increase 1 train capacity to enjoy scale of economy
(1 train capacity is limited by FT reactor and oxygen plant)
• Chemical Reaction
Steam Reforming : CH4 + H2O CO + 3H2
CO2
Compressor
*1
CO2, Disposal
Steam
CO2
Reformer Removal
Natural Gas
Steam
Steam TO GTL Synthesis
H2 : CO ≈ 2:1
Fuel
Gas
C:100% Note
Steam CO2 CO2 Disposal
Steam C :19%
Recovery
Reformer
FT Hydro
Synthesis Cracking
FT Oil Aquifer or
C : 77% Oil Field
Steam
Reformer
Gas
CO2
WHB Recovery
180MMSCFD
3500 T/D
Steam
Reformer
H2 : CO = 2.33 : 1
Hydrocracking Product
FT 20,000 BBL/D.
Synthesis
WHB