Brenntag Polska Sp. z o.o.

ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

Issue: I Last revision: 17 Aug 2017.

Material Safety Data Sheet

[grounds: Commission Regulation (EU) № 453/2010 of 20 May 2010, amending Regulation (EC) № 1272/2008 (REACH)]

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Commercial name: BRENNTAHIB CL75
Identifier: 67-48-1
REACH registration №:
Commodity code: 518704
Other names:

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: clay stabilizing agent

1.3 Details of the supplier of the safety data sheet

Name and address: Brenntag Polska Sp. z o.o.; 47-224 Kędzierzyn-Koźle; ul. Bema 21; Poland
Phone №: 48 (77) 47 21 500
Fax №: 48 (77) 47 21 600
Person responsible for developing this safety data
sheet: e-mail address: kch@brenntag.pl

1.4 Emergency telephone number (in Poland)

998 or 112, or contact the nearest local Fire Department.

Polish Toxicological Information Centre: +48 (42) 631 47 24 (7 am – 3 pm).

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) № 1272/2008, of 16 December 2008, on classification,

labelling and packaging of substances and mixtures (CLP):

General hazards:
This product is not classified as hazardous according to legislation in force.
Human health effects:
Not applicable.

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Company
Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

Hazardous properties:
Not applicable.
Environmental hazard:
Not applicable.

2.2 Label elements

Hazard pictogram(s):

Signal word: –
Hazard statements:
H000 – This product is not classified as hazardous according to legislation in force.
Precautionary statements:

2.3 Other hazards

No data available.

3. Composition / Information on ingredients

Composition according to Regulation (EC) № 1272/2008:

70-80 % Choline chloride
CAS №: 67-48-1
Index №: not applicable
EC №: 200-655-4

If the ingredient as named above is hazardous, please refer to Section 16 where the full text of
each relevant hazard statement is presented.

4. First aid measures

4.1 Description of first aid measures

Inhalation:
In case of exposure by inhalation, evacuate the affected person from the place of exposure to fresh
air. Keep at rest. Use artificial respiration if breathing stops. Provide medical advice immediately.
Skin contact:
In case of skin contact, wash the affected skin area with plenty of water and soap. Seek medical
advice in case of dermal irritation.
Eye contact:
In case of eye contact, rinse with running water for at least 15 minutes, keeping the eyelids forcibly
apart. Seek medical advice in case of irritation.

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

Ingestion:
After incidental ingestion, rinse mouth with water and drink plenty of water. Seek medical advice in
case of need.

4.2 Most important symptoms and effects, both acute and delayed

No data available.

4.3 Indication of any immediate medical attention and special treatment needed

No data available.

5. Fire-fighting measures

5.1 Extinguishing media

Water spray, alcohol-resistant fire foams and dry chemical powders.

5.2 Special hazards arising from the substance or mixture

The product is non-flammable, it is an aqueous solution. Thermal decomposition and/or

combustion may release toxic nitrogen oxides, cyanides and/or hydrochloric acid.

5.3 Advice for fire-fighters

Collect the fire residues and contaminated fire water and dispose of in compliance with the
applicable regulations.
Use self-contained breathing apparatus.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment as recommended. Avoid any direct contact with the skin and/or
eyes.

6.2 Environmental precautions

Prevent any uncontrolled product dispersal and its uncontrolled entry to sewage systems, water
courses and/or soil.

6.3 Methods and material for containment and cleaning up

Contain large spills and pump the liquid for recovery or disposal. Collect small spills with the use of
a suitable fixing agent, place it in a sealable container and transfer for disposal.

6.4 Reference to other sections

For information on applicable personal protective equipment, refer to Section 8.

For information on waste disposal procedures, refer to Section 13.

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

7. Handling and storage

7.1 Precautions for safe handling

Use/handle in well-ventilated rooms/places only. Do not eat, drink or smoke when using this
product. Wash your hands after handling. Remove contaminated clothing and protective equipment
before entering eating areas.

7.2 Conditions for safe storage, including any incompatibilities

Store in tightly closed containers, at temperatures from -5 to +40 C.

7.3 Specific end use(s)

No data available.

8. Exposure controls / personal protection

8.1 Control parameters

Occupational exposure limit values:

PEL, STEL – these have not been laid down
(in accordance with the Regulation of the Minister of Labour and Social Policy, of 6 June 2014;
Journal of Laws 2014, item 817).

Recommended monitoring procedures for contents of airborne hazardous components – methods

of measurements:
– Regulation of the Minister of Health on tests and measurements applicable for hazardous
substances and other adverse factors which are present in the workplace, of 2 February 2011
(Journal of Laws № 33, item 166).
– PN-89/Z-01001.06: Air purity protection. Terminology and units. Terminology relating to air
quality testing in workplaces.
– PN-Z-04008-7:2002: Air purity protection. Sampling. Principles of air sampling in work
environment and interpretation of results.
– PN-EN 689:2002: Workplace atmosphere. Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and measurement strategy.
Note: When the concentration of a substance has been determined and it is known, the specific
personal protection items should be selected after due consideration of the concentration present
in the workplace atmosphere, time of exposure, and work to be done by the worker(s). In
emergency situations, when the workplace concentration of a substance is not known, use the
personal protection controls capable of providing the highest class of performance.
Every employer is obliged to see if the means of personal protection, working clothing and boots,
provide the adequate protective and functional performance, and he is responsible for washing,
maintenance, repair and disinfection of those items.
The entry medical examinations and subsequent routine examinations of the employees should
follow the recommendations provided for in the Regulation of the Minister of Health and Public
Assistance on medical

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

examinations of employees, on the scope for preventive health care services available to
employees, and on medical certificates to be issued for the purposes stipulated in the Labour
Code, of 30 May 1996 (Journal of
Laws № 69/1996, item 332, with amendments as per Journal of Laws № 37/2001, item 451).

8.2 Exposure controls

The adopted personal protection measures should satisfy the requirements specified in the
Regulation of the Minister of Economy on basic requirements for personal protection controls, of 21
December 2005 (Journal of
Laws № 259, item 2173).
Respiratory protection:
It is not required under normal conditions.
Eye protection:
Safety goggles with side shields.
Hand protection:
Protective gloves (e.g. made of neoprene).
Appropriate engineering controls: Local ventilation systems.
Other protective measures/equipment:
Protective clothing.
General recommendations:
Do not eat, drink or smoke when using this product. Wash your hands thoroughly at the end of
work. Wash contaminated clothing before its re-use.
Prevent any uncontrolled product entry to sewage systems and/or ground water.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance: clear liquid, light amber coloured

Odour: faint
Odour threshold: no data available
pH: 6-9
Melting point/freezing point [ C]: -10 (crystallization)
Initial boiling point/boiling range [ C]: no data available
no data available
Evaporation rate: no data available
Flammability (solid, gas): not applicable to liquids
Upper explosive limit [vol. %]: no data available
Lower explosive limit [vol. %]: no data available
Vapour pressure, 22.872
Vapour density (air = 1): no data available
3
]: 1100
Solubility in water: complete
Solubility in other solvents: no data available
n-Octanol/water partition coefficient: -3.77

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

Auto- 330
> 300
26.2
Explosive properties: no data available
Oxidising properties: not classified as oxidizer
Refractive index: no data available
Molecular weight: 139.62
State of aggregation: liquid

9.2 Other information

Minimum ignition energy [mJ]:

Electrical conductivity [pS/m]:

10. Stability and reactivity

10.1 Reactivity

No data available.

10.2 Chemical stability

This product is stable under normal conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions are known under normal conditions.

10.4 Conditions to avoid

No data available.

10.5 Incompatible materials

None known.

10.6 Hazardous decomposition products

Thermal decomposition and/or combustion may release toxic nitrogen oxides, cyanides and/or
hydrochloric acid.

11. Toxicological information

Acute toxicity – oral: LD50 > 3500 mg/kg (rat)

Acute toxicity – skin: no data available
Acute toxicity – other routes of exposure: no data available
Skin corrosion/irritation: not irritating (rabbit)
Serious eye damage/irritation: not irritating (rabbit)

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

Sensitisation through inhalation or skin contact: it has not been observed

Germ cell mutagenicity: tests in animals revealed no mutagenicity
Carcinogenicity: no carcinogenicity is expected
Reproductive toxicity: tests in animals revealed no teratogenicity
Specific target organ toxicity – single exposure: no data available
Specific target organ toxicity – repeated exposure: no data available
Hazard resulting from aspiration: no data available

12. Ecological information

12.1 Toxicity

Ecotoxicity:
– to fish: LC50 > 10000 mg/l/96 h (Leuciscus idus)
– to invertebrates: EC50 > 500 mg/l/48 (Daphnia magna)
– to aquatic plants: EC50 > 500 mg/l/72 h
– to bacteria: EC50 = 132,8 mg/l/17 h (Pseudomonas putida)
The product is not expected to upset the operation of activated sludge if it is discharged to a
biological sewage treatment plant at a suitably low concentration.
The product is biodegradable; it’s elimination is > 60 % (DIN 38409, part 51).
Prevent product discharge to water bodies with no previous treatment in a biological sewage
treatment plant.

12.2 Persistence and degradability

The product is easily biodegradable.

12.3 Bioaccumulative potential

No data available.

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

No data available.

12.6 Other adverse effects

No data available.

13. Disposal considerations

13.1 Waste treatment methods

Provisions of the following legislation should be observed:

– Waste Disposal Law, of 14 December 2012 (Journal of Laws 2013, item 21), with further
amendments.

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

– Law on packages and spent packages, of 13 June 2013 (Journal of Laws 2013, item 888).
– Regulation of the Minister of Environment on wastes catalogue, of 9 December 2014 (Journal of
Laws 2014, item 1923).

Waste code:
16 03 06* Organic wastes other than those mentioned in 16 03 05, 16 03 80

Dispose of by incineration in compliance with the applicable waste disposal regulations.

14. Transport information

14.1 Road/rail transport (ADR/RID)

UN number: –
UN proper shipping name:
Transport hazard class: not regulated
Packing group: no limitations
Hazard identification number: –
Warning label: not applicable
Mark: not applicable
Tunnel restriction code: not applicable
Other information:

14.2 Sea transport (IMDG)

Not regulated.

14.3 Air transport (ICAO)

Not regulated.

14.4 Inland water transport (ADN)

Not regulated.

14.5 Environmental hazards

The product is not environmentally hazardous according to the criteria of the UN Model
Regulations.

14.6 Special precautions for user

No data available.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance

 Law on chemical substances and mixtures thereof, of 25 February 2011 (Journal of Laws №
63, item 322), with further amendments. 

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75

 Regulation of the Minister of Environment on wastes catalogue, of 9 December 2014 (Journal

 of Laws 2014, item 1923). 
 Regulation (EC) № 1907/2006, of the European Parliament and of the Council, of 18
December 2006, concerning the Registration, Evaluation, Authorisation and Restriction of
 Chemicals (REACH), with further amendments. 
 Regulation (EC) № 1272/2008, of the European Parliament and of the Council, of 16
December 2008, on classification, labelling and packaging of substances and mixtures,
amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) № 1907/2006 (Official Journal of the European Union L 353/1, of 31 December 2008),
with further amendments. 

15.2 Chemical safety assessment

16. Other information

The above information has been compiled on the basis of the current knowledge and it is
applicable to the product in the form in which it is normally used. The figures and other properties
have been presented for the product to illustrate the safety requirements only and they DO NOT
form any product quality specification. When the producer cannot control the conditions of use, the
user assumes full responsibility for safe application of that product.
Every employer is obliged to instruct all his employees in contact with this product on hazards and
personal protection as specified in this MSDS.
This MSDS has been developed on the basis of the MSDS document provided by the producer
and/or the information and data available in the Internet, and on the basis of effective codes
applicable to hazardous substances and formulations.

This product is not classified as hazardous.

No Exposure Scenarios are required.

List of H and EUH statements:

Modifications in relation to previous version:

Not applicable.

Advice on training:
Those involved in handling, marketing, transport, etc., of any hazardous substance (or product)
should be instructed on applicable procedures and on occupational safety and health rules.

List of abbreviations:
Expl. – Explosive substance or mixture
Flam. Gas – Flammable gas
Flam. Aerosol – Flammable aerosol
Ox. Gas – Oxidising gas
Press. Gas – Gas under pressure (compressed gas)
Flam. Liq. – Flammable liquid
Flam. Sol. – Flammable solid

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Brenntag Polska Sp. zo.o.
ul. J.Bema 21
47-224 Kędzierzyn-Koźle; Poland
tel.(48/77) 4721500; fax (48/77) 4721600

BRENNTAHIB CL75
Self-react. – Self-reactive substance or mixture
Pyr. Liq. – Pyrophoric liquid
Pyr. Sol. – Pyrophoric solid
Self-heat. – Self-heating substance or mixture
Water-react. – Substance or mixture which reacts with water, liberating flammable gases
Ox. Liq. – Oxidising liquid
Ox. Sol. – Oxidising solid
Org. Perox. – Organic peroxide
Met. Corr. – Substance or mixture which is corrosive to metals
Acute Tox. – Acute toxicity
Skin Corr. – Skin corrosion
Skin Irrit. – Skin irritation
Eye Dam. – Serious damage to eyes
Eye Irrit. – Eye irritation
Resp. Sens. – Respiratory sensitisation
Skin Sens. – Skin sensitisation
Muta. – Germ cell mutagenicity
Carc. – Carcinogenicity
Repr. – Reproductive toxicity
STOT SE – Specific target organ toxicity – single exposure
STOT RE – Specific target organ toxicity – repeated exposure
Asp. Tox. – Aspiration toxicity
Aquatic Acute – Substance which is hazardous to the aquatic environment, and its toxicity is acute
Aquatic Chronic – Substance which is hazardous to the aquatic environment, and its toxicity is
chronic
Ozone – Ozone-layer depletion
Lact. – Reproductive toxicity; additional category for effects on or via lactation
NDS – Permissible exposure level/concentration (Polish)
NDSCh – Short-term exposure level/concentration (Polish)
NDSP – Permissible ceiling exposure level/concentration (Polish)
vPvB – (Substance) very Persistent and very Bioaccumulative
PBT – (Substance) Persistent, Bioaccumulative, Toxic
PNEC – Predicted No Effect Concentration DN(M)EL – Derived No
Effect Level
LD50 – Lethal dose 50; dose/amount of a substance which kills 50 % of the test population LC50 – Lethal
concentration; concentration of a substance which kills 50 % of the test population
ECX – Effective concentration; concentration of a substance which produces X % of the maximum
possible effect response
LOEC – Lowest Observed Effect Concentration NOEL – No Observed Effect Level
RID – Regulations Concerning the International Carriage of Dangerous Goods by
Rail ADR – Agreement Concerning the International Carriage of Dangerous Goods
by Road IMDG – International Maritime Dangerous Goods Code
ICAO/IATA – International Civil Aviation Organization/International Air Transport Association
ADN – Agreement Concerning the International Carriage of Dangerous Goods by Inland
Waters UVCB – Unknown or Variable Composition Biological (substance)

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