12-5 Missen

A gas-phase decomposition, A  R + S, is to be conducted in a batch reactor, with initial

conditions of T0, = 300 K, V0 , = 0.5 m3, and a (constant) total pressure of 500 kPa. The values
of Cp , for A, R, and S are, respectively, 185.6, 104.7, and 80.9 J mol -1 K-1. The enthalpy of
reaction is -6280 J (mol A)-l, and the reaction is first-order with respect to A, with k A = 1014e
h . Determine the profiles of fA and T versus t, if the process is adiabatic, and T and t for
-10,000/T -l

fA = 0.99

Dik :
To 300 K Cpr 104.7 mol-1K-1
Vo 0.5 m3 Cps 80.9 mol-1K-1
P 500 kPa fa 0.99
Cpa 185.6 mol-1K-1 -6280 J (mol A)-1
ka 10^14e-1000h-1

Jawab
niCp 185.6 nAo

j fa T/K Ka/h-1 G G* t/h

1 0.00 300.0 0.334 3.00 0.00
2 0.10 303.4 0.484 2.30 2.65 0.25
3 0.20 306.8 0.696 1.80 2.05 0.44
4 0.30 310.1 0.993 1.44 1.62 0.59
5 0.40 313.5 1.405 1.19 1.31 0.72
6 0.50 316.9 1.975 1.01 1.10 0.82
7 0.60 320.3 2.755 0.91 0.96 0.92
8 0.70 323.7 3.817 0.87 0.89 1.00
9 0.80 327.0 5.253 0.95 0.91 1.10
10 0.90 330.4 7.183 1.39 1.17 1.23
11 0.99 333.5 9.467 10.56 5.98 1.97