Material Safety Data Sheet

AVA X-PRIMA

1. IDENTIFICATION OF THE SUBSTANCES/PREPARATION AND THE COMPANY UNDERTAKING

Product Name AVA X-PRIMA

Application Lost circulation material.

Supplier Ava S.p.A.

via Salaria 1313/C
00138 ROMA
Italy

Emergency telephone number Off.: +39 06 885611324; +39 06 885611326; +39 06 885611373
Mob.: +39 3355897280; +39 3355234619; +39 3355710385

Telefax +39-06-8889363

2. HAZARD IDENTIFICATION
Inhalation Excessive concentrations of a nuisance dust may cause coughing,
sneezing, and nasal irritation.
This product may contain trace amounts of crystalline silica which can
cause lung diseases such as silicosis and
lung cancer.

Skin contact Irritation of the skin and possible chemical burns due to alkalinity and
dehydration may result.

Eye contact Irritation and possible chemical burns due to alkalinity and
dehydration may result

Ingestion Irritation to the throat, esophagus, and stomach lining may occur.

Human health hazards - Acute Irritating to the respiratory tract if inhaled.

Human health hazards - Chronic
Inhalation of dust in excess of the Threshold Limit Value (TLV)
recommended by the American Conference of Governmental
Industrial Hygienists (ACGIH) over an extended number of years may
cause pneumoconiosis. Pneumoconiosis is a disabling lung disease
which may be progressive and, on rare occasions, may ultimately be
fatal.

Environmental hazards No adverse effects expected. Do not allow to enter water courses

Physical and chemical hazards Avoid contact with strong acids

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical description Mixture of calcium hydroxide and diatomaceous earth

Hazardous Impurities Calcium hydroxide 25-50% Xi Irritant R36/38

Diatomaceous earth 15-30% Xn Harmful R20/40
Crystalline Silica (Quartz) <1% Xn Harmful R20/40
EINECS-No.

CAS No. Calcium hydroxide 1305-62-0

Diatomaceous earth 61690-53-2
Quartz 14808-60-7

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AVA X-PRIMA

4. FIRST AID MEASURES

Inhalation Move victim to fresh air. If breathing is difficult, apply oxygen and
seek medical attention.

Skin contact Wash with soap and running water for 15 minutes. If symptoms
persist, seek medical attention

Eye contact Flush with large amounts of water for 15 minutes. If symptoms
persist, seek medical attention

Ingestion Product contains Hydrated Lime, an alkaline material which is soluble

in water. If ingested, drink 3-4 glasses of milk or water to dilute,
followed by a glass of fruit juice or dilute vinegar. Get immediate
medical attention.

Other information

5. FIRE FIGHTING MEASURES

Extinguishing media Water, carbon dioxide or sand.

Unsuitable extinguishing media None

Fire and explosion hazard 40g/m3 (LEL). Dust may form explosive mixture with air in high
concentrations

Protective equipment Evacuate all unnecessary personnel. Wear appropriate safety

equipment for fire conditions including SCBA.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions Avoid contact with eyes. Take off all contaminated clothing

Environmental precautions Do not discharge into drains or the environment. Do not contaminate
ground water system

Methods for cleaning up Wear suitable protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Use a clean shovel to carefully place
material into clean, dry container, cover and remove from
area. Flush spill area with water.

7. HANDLING AND STORAGE

Handling Do not eat, drink or smoke in working area. Handle in well ventilated
area. Avoid breathing dust.

Storage conditions Store in a dry cool area 40 – 120 F.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering measures Local exhaust and ventilation system is recommended if handled in a
confined area.

Exposure limits (ACGIH 2006) 10 mg/m3 total dust for products containing <1% quartz

Personal protection equipment

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Respiratory protection Use NIOSH/OSHA approved respirator.

Hand/skin protection Use long-sleeved clothing and gloves

Eye protection Use safety glasses with side shields

Hygiene measures Eyewash fountain near-by.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form Powder

Colour Grey

Odour Odorless

Boiling point N/A

Melting point N/A

Flash point - (PMCC) N/A

Auto ignition N/A

Explosion limits N/A

Vapour pressure N/A

Relative density 1.70-2.00 g/cm³

Solubility in water <1%

pH 11.5

Viscosity N/E

Bulk density N/A

Freezing point N/A

Pour point N/E

Abbreviations: N/A = Not Applicable - N/E = Not Evaluated
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions

Conditions to avoid Heat, flame and sources of ignition

Materials to avoid Strong acids

Hazardous decomposition products Carbon dioxide, carbon monoxide, oxides of sulfur and nitrogen

11. TOXICOLOGICAL INFORMATION

Acute toxicity No data available

Primary irritation skin/eye Irritant

Sensitisation No data available

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Chronic toxicity data No data available

12. ECOLOGICAL INFORMATION

Persistency and degradation No ecological data is available for this product.

Mobility and Bioaccumulation No ecological data is available for this product.

Ecotoxicological effects No ecological data is available for this product.

13. DISPOSAL CONSIDERATIONS

Do not discharge into drains or the environment, dispose to an authorized waste collection point

14. TRANSPORT INFORMATION

Description Not regulated

UN Number N/A

Packing group N/A

ADR/RID

Class ADR 2003 Label: --

ADR 2003 Classif. Code: --
Hazard Identification

IMDG

Class Subsidiary risk: -

Em S

IATA

Class
15. REGULATORY INFORMATION
EC Classification Xn Harmful

Hazard Symbol

contains: Mixture of calcium hydroxide and diatomaceous earth

Risk Phrases R20: Harmful by inhalation

R36/38: Irritating to eyes, respiratory system and skin
R40: Limited evidence of a carcinogenic effect

Safety Phrases S22: Do not breathe dust

S24/25: Avoid contact with eyes and skin.

16. OTHER INFORMATION

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AVA X-PRIMA

This material safety data sheet provides health and safety information. The product is to be used in applications consistent
with AVA technology. Individuals handling this product should be informed of the safety precautions and should have
access to this information.

Revision date Jun 2008 Page 5/4