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D C, P, C M E U E T, L (N C) : Important Instructions For Students
D C, P, C M E U E T, L (N C) : Important Instructions For Students
(b) A worker unintentionally cut 12-inch propane pipeline operating at 800 psi at a natural (6)
gas liquid point terminal. Huge vapor cloud projected to cover 35 acres which ignited about 10
minutes later by an unidentified source. Liquid products from 7 of 30 salt dome caverns fed
the fire with an estimated 16,000-29,000 gal of LPGs for 8 hours before being blocked in and
the fires extinguished. Both engine-driven fire pumps failed, one due to strong emitted heat
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damaged its ignition wires and the other because the explosion damaged sight glass fuel
gauge, leaking diesel fuel, which ignited and destroying fire pump engine. Distinguish the
situation to separate initiation, propagation, and termination steps for the above-mentioned
accident. Report ways to prevent or contain the accident.
(c) Analyze a situation in a process plant where gas toluene (mol. wt. 92g/mol) kept in
storage with designed storage capacity having length, width and depth equivalent to 16ft, 14ft (8)
and 7ft respectively. It is observed that the ventilation system installed in the store improves
the air quality entirely 6 times/hour. The Store room is also well-equipped with vapor
detection system which provides instantaneous alarm notification as soon as vapor
concentration is 25% of the lower flammable Limits (LFL) for toluene. Calculate minimum
spillage rate (lb/hr) of toluene, that will set off the flammable vapor alarm in the room?
Assume a pressure of 1 atm and a temperature of 540oR.
Also assume average ventilation conditions.
Given, parameters are: Rg = 0.73 ft3 atm/lb-mol R
For Toluene= 15,000ppm
Given Equation,
C ppm kQv PM
Qm = x 10 −6
RgT
K factor range at different Ventilation situations
vapors concentrations,
0-90 ppm = 1/12 (poor), 1/10 (average), 1/8 (good)
91-450 ppm = 1/7 (poor), 1/5 (average), 1/3 (good)
Above 450ppm= 1/6 (poor), 1/4 (average), 1/2 (good)
(d) A comprehensive analysis must be considered for safety conditions on a reactor (10)
system shown in the Figure 1. The system is provided with cooling system to eliminate
excessive energy generated as a result of exothermic reaction.
In case of cooling function is lost, the temperature of reactor would increment. This
would lead to increase reaction rate and thus result in extra energy discharge. The
outcome could be a runaway reaction with pressures surpassing the exploding reactor
pressure. The temperature inside the reactor is estimated and is utilized to regulate
cooling water stream rate through valve provided.
Analyze through HAZOP for the given process (Figure 1) which is widely applied in
industrial process design. Complete the missing comprehensive report given in Table
1 on guide words, deviations, causes, consequences and all possible actions to be
taken associated with the process.
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Table1. Provide the Missing Links
Guide Words Deviations Causes Consequences Actions
No No cooling
------------------------------------Good Luck--------------------------------
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