ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE - 2013 FULL TEST – 2 MARKS: 238

(ADVANCED PATTERN) PAPER - I

SECTION - I PHYSICS

PART I: Single Correct Answer Type

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct. (+3, –1)

l
1. Three charge q, Q and 4q are placed in a straight line of length l at points distance 0,and l
2
respectively from one end. In order to make the net force on q zero, the charge Q must be equal to
q
(a) – q (b) – 2q (c) (d) q
2

2. A point charge q is placed at the midpoint of a cube of side L. The electric flux emerging from the
cube is
q q 6qL2
(a) (b) 2 (c) (d) ZERO
0 6L  0 0

3. The charge flowing through a resistor R varies as Q  t   t   t 2 . The total heat produced in R is
 3R  3R  3R  3R
(a) (b) (c) (d)
 2 3 6

4. A 2.0 V potentiometer is used to determine the internal resistance of a 1.5 V cell. The balancing
point of the cell in open circuit is 75 cm. When a resistor of 10  is connected across the cell, the
balance point shifts to 60 cm. the internal resistance of the cell is
(a) 1.5  (b) 2.5  (c) 3.5  (d) 4.5 

5. A current carrying wire RS is placed near an another long current carrying

wire PQ. If free to move, wire RS will have Q
(a) translational motion only I2
(b) rotational motion only I1 R S
(c) translational as well as rotational motion
(d) neither translational nor rotational motion P

6. A long straight wire along the z-axis carriers a current I in the negative z

direction. The magnetic vector field B at a point having coordinates (x, y) on the z = 0 plane is
 I  yiˆ  xjˆ   I  xiˆ  yjˆ   I  xjˆ  yiˆ   I  xiˆ  yjˆ 
(a) 0  2  (b) 0  2  (c) 0  2  (d) 0  2 
2  x  y 2
2  x  y 2
2  x  y 2
2  x  y 2 

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

7. A proton, a deutron and an  -particle having the same kinetic energy are moving in circular
trajectories in a constant magnetic field. If rp , rd and r denote respectively the radii of the
trajectories of these particles, then
(a) r  rP  rd (b) r  rd  rp (c) r  rd  rp (d) rp  rd  r

8. In the arrangement shown in the figure AC and BD are straight lines and CED and AFB are
semicircular with radii r and 4r, respectively. The entire setup is lying in the same plane. If I is
current entering at A what fraction of I will flow in the ACEDB such that resultant magnetic field at
O is zero E
A C r D B
O I

4r

3 4 1
(a) 1 (b) (c) (d)
5 5 5

PART II: Multiple Correct Answer(s) Type

This section contains 4 multiple choice questions. Each question has four choices (A),
(B), (C) or (D) out of which ONE or MORE are correct. (+4, –1)

9. A parallel plate capacitor having capacitance C has two plates X and Y each having a charge Q. The
plate X is now connected to the positive terminal of a battery and the plate Y to the negative terminal
Q
of the same battery of emf E  . Then it is observed that
C
2
(a) an energy CE is supplied by the battery.
(b) Q amount of charge flows, through the capacitor, from the positive terminal to the negative
terminal of the battery.
(c) the total charge on the plane X is 2Q.
(d) the total charge on the plate Y is zero.

10. Consider a conducting sphere A having radius a, charge Q placed concentrically inside a conducting
shell B having radius b (> a) and earthed. Let C is the common centre of the sphere A and the shell
B. If E and V be the respective electrostatic field and potential at a distance r  a  r  b  from C and
V be the electrostatic potential difference between the two shells, then
B
A Q
C a

1 Q Q 1 1 Q 1 1 
(a) E  0 (b) E    (c) V     (d) V    
4 0  r 2  4 0  a b  4 0  r b 

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

11. Three ammeters A1 , A 2 and A 3 having resistance R 1 , R 2 and R 3
A1 A2
respectively are connected between two points X and Y, such that A1
X Y
and A 2 are in series which in turn are in parallel with A3 . When some
potential difference is applied across the terminals X and Y, the A3
respective readings of the ammeters are I1 , I 2 and I3 . Which of the
following mathematical relations support the argument given here?
I R I1 R3
(a) I1  I 2 (b) I1R 1  I 2 R 2  I3R 3 (c) 2  3 (d) 
I3 R 1 I3 R 1  R 2

12. A current I is being driven through a battery of emf E and internal

resistance r, as shown. Then which of the following statement(s) best I + E,r
suit the above mentioned condition?
(a) The battery absorbs energy at the rate of EI.
 
(b) The battery stores chemical energy at the rate of EI  I2 r .
(c) The potential difference across the battery is E  Ir .
(d) Some heat is produced in the battery.

PART III: PARAGRAPH TYPE

This section contains 3 multiple choice questions relating to ONE paragraph. Each question
has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. (+3,0)

PARAGRAPH – I

Two capacitors C1  1F and C2  3 F are each charged to a e S1

a d
potential V0  100V but with opposite polarity, as shown. Switches
S1 and S2 are now closed. Based on the above facts, answer the C1 C2
following questions.
b c
13. What is the potential difference between points ‘e’ and ‘f’? f S2
(a) 25 V (b) 50 V (c) 75 V
(d) 100 V

14. What is the final charge on C1 ?

(a) 50 C (b) 75 C (c) 150 C (d) 300 C

15. What is the final charge on C2 ?

(a) 50 C (b) 75 C (c) 150 C (d) 300 C

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

 PART IV: Integer Answer Type

This section contains 4 questions. The answer to each question is a single/two digit
integer, ranging from 0 to 99 (both inclusive) (+5,–1)

16. A capacitor of capacitance C1  1 F withstands the maximum voltage V1  0.6 kV while another
capacitor of capacitance C 2  2 F withstands the maximum voltage V2  4 kV . What maximum
kilovolt will the system of these two capacitors withstands if they are connected in series?

17. A parallel plate capacitor of plate area A  103 metre 2 and plate separation d  10 2 m is charged to
V0  100 V . Then after removing the charging battery, a slab of insulating material of thickness
b  0.5  10 2 m and dielectric constant K = 7 is inserted between the plates. Calculate the free charge,
in pC, on the plates of the capacitor, electric field intensity, in kVm 1 , in the dielectric, potential
difference, in volt, between the plates and capacitance, in pF, with dielectric present.

18. A box contains a inductor of inductance L milli henry, a capacitor of capacitance C microfarad and a
resistor of resistance R ohm. When a 250 V dc is applied to the terminals of the box, a current of 1 A
flows in the circuit. When an ac source of 250 V rms flows. It is observed that the current rises with
frequency and becomes maximum at 4500 rads 1 . Find the values of C.

19. A coil of 15 turns and radius 10 cm surrounds a long solenoid of radius 2 cm and 1000 turns per
metre as shown. The current in the solenoid changes as I (in ampere) = 4 cos (250t). Find the induced
peak emf, in millivolt, in the 15 turn coil as a function of time. (Take  2  10 )
15 turn coil

R
I
~

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

 PART V: Matrix Match Type

This section contains 1 question. Each question contains statements given in two columns, which have
to be matched. The statements in Column-I are labelled A, B, C and D, while the statements in
Column - II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching
with ONE OR MORE statement(s) in Column- II. The appropriate bubbles corresponding to the
answers to these questions have to be darkened as illustrated in the following example: If the correct
matches are A - p , s and t ; B - q and r ; C - p and q ; and D - s and t. (+8, –1)

20. Column 1 Column 2 P

(a) JK process (P) W > 0
(b) KL process (Q) W < 0 30 J
(c) LM process (R) Q > 0
(d) MJ process (S) Q < 0 M
20

10 K L

10 20 V

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

 PAPER – I SOLUTION

1. (a)
 Fnet   0
Qq 4q 2
k k 0 l/2 l/2
2
 2 q Q 4q
 
2
1
where k 
40
 4Qq  4q 2  0  Q  q

2. (a)
According to Gauss Theorem
q
Flux   
0

3. (d)
dQ
I  I    2t
dt

Since at t 0  t  , I becomes zero. Hence we shall calculate the heat produced from
2
t0
 2
t  0 to t 0  H I R dt
2
0
 
2 2 1 2
2    2t 
 HR     2t  dt  HR
6
0 0
 3 3
   R
 H  R 0  R
 6  6


4. (b)
Since
l   75 
r    l R  r   1 10
l'   60 
15 5
 R   10  R   2.5
60 2

5. (c)
Since, the magnetic field due to wire PQ is non uniform. Neither the force nor the torque on wire RS
is zero. Therefore, it will have both translational as well as rotational motion.


Q F1

F2 
I1
F3

R S
I2
P
6. (a)

7. (a)
mc 2Km
Radius of the circular path is given by r  
Bq Bq
Here, K is the kinetic energy to the particle.
m
Therefore, r  if K and B are same.
q
1 2 4
 rp : rd : r 
: :  1: 2 :1
1 1 2
Hence, r  rp  rd

8. (d)
0 I1 0 I2
If I1 is current in ACDB then 
4 r 4 4r
I1 1 I I1 1
   I1   
I2 4 5 I 5

9. (a, b, c, d)

10. (b, c, d)

11. (a, b, d)

12. (a, b, c, d)

13. (d)
Let V1 and V2 be the voltage across 1 and 2 F capacitors respectively. Then V1  V2  300 V
Q Q
In series the charge Q on each capacitor is same, therefore we have   300
C1 C 2
 1 1 
   Q  300
 C1 C2 
Here C1  1 F, C2  2 F

Q
3000C1C2 300 110

6

2  106  
C1  C 2 
1 106  2 106 
Q 200 C
 Q  200 106 C  200 C  V1    200 V
C1 1 F
Q 200C
V2    100 V
C2 2F

14. (c) C1
When the plates of same polarity are connected together, the capacitors are Q '1
in usual parallel combination. In parallel the potential difference across
+ -
each capacitor is the same C2
 The common potential difference
Q  Q2 2Q 2   200C  400 C 400 Q '2
V 1   V   V
C1  C 2 C1  C 2 1F  2F  3F 3 V'
 If Q1' and Q'2 are new charges on the respective capacitors, then
 400  400  400  800
Q1'  C1V  1F    V  C Q'2  C 2 V   2F    V  C
 3  3  3  3

15. (a)
When the opposite plates of SITUATION(I) are connected together, the charge will flow from the
capacitor of higher potential to that of lower potential until their potentials are same. The net charge
is then  Q1  Q2 
C1 C1
+ - Q"1
Charge Flow + - + -
+ -- + -
+
 200 V  C2
- +C2
- + + -
- + + -
- + Q"2
 100 V   100 V " 
(a) (b)

If V '' is common potential difference across the capacitors, then

Q  Q2  200F  200 C 
V"  1  0
C1  C 2 1F  2F
The charge after sharing
Q1"  C1V"  C1  0   0 Q"2  C2 V"  C2  0   0

16. (9)
Given, V1  6kV, V2  4kV

C1 C2
q
 
V1 V2

Charge on first capacitor


q1  C1V1  1F  6  103 V   q1  6000 C
Charge on second capacitor
q 2  C2V2  
 q 2   2F   4 103 V  8000 C
In series the charge on each capacitor remains same, but maximum charge on first capacitor will be
6000 C . Therefore charge on second capacitor must also be 6000 C . The potential across second
capacitor.
q 6000 C
V2    3000 V  3kV
C2 2F
So, maximum voltage across system will be
 V1  V2  6kV  3kV  9kV

17. (16)
The capacitance C0 before the slab is introduced

V0 
0A


8.9  1012 102  
 8.9  1012 farad
d 2
10
 free charge
  
q  C0V0  8.9 1012 100  890 1012 C  890 pC
Now, Electric field intensity
V 100
E0  0   1 104 Vm 1  10 kVm1
d 10 2
Electric field intensity in dielectric
E 1 104
E 0   1.43 103 Vm1  1430 Vm1
K 7
Potential difference between the plates with dielectric present is given by
V  E 0  d  b   Eb

   
 V  1 104 102  0.6 102  1.43 103 0.5 102  
 V  57 V
The free charge on the plate is the same as before. The capacitance with dielectric present is
q 8.9 1010 C
C   16  1012 farad  16 pF
V 57 C

18. 1
Since, the capacitor is a dc blocking element, but still the current in the circuit for a dc source is not
zero, so all the elements must not be series. Further in case of ac, current rises with frequency and
has a maximum value at 4500 rads 1 , L and C should be in series. The circuit diagram therefore, be
as shown in figure.

R IR
R

L C L C

I
IR
~
250 V
CASE I : When dc is applied CASE II : When ac is applied

Case I : When dc is applied, we have

V 250
R   250
I 1
Case II: When AC is applied, then for
  2250 rads 1 , let the applied voltage be
V
V  V0 sin  t  . Then IR  0 sin  t 
R
250 2
IR  sin  t   2 sin  t  as Vrms  250 volt
250
V0  
and IL  IC  sin  t  
XC ~ XL  2
{ ' ~ ' indicates positive difference between X L and X C }
 V0 
 IL    cos  t 
 XC  XL 
So, the total current through the circuit at any instant is
V V0
I  I R  IC  0 sin  t   cos  t   I  I0 sin  t   
R XC  XL
 1 1 1 1
where I0  V0   Irms  Vrms 
R2  X C ~ X L 2 R2  X C ~ X L 2
2
1 1  1.25 
Given that, Vrms  250 volt, I rms  1.25 A  2 
2  250 
R  XC ~ X L 
2 2
1  1.25   1  1000
   XC ~ XL  
2  250  
 250  3
 XC ~ X L 
1 1000
 ~ L   …..(1)
C 3
Current in the circuit will be maximum at,
1
X L  XC  L0 
C0
1
 0 
LC
1 1
 LC  2  …….(2)
0  4500  2
Solving equations (1) and (2) with   2250 rads 1 , we get
C  106 F  1 F and L  0.049 H
So, C  1, L  49 and R  250

19. (24)
Since   BA  0 nI  Asolenoid 
2

   0n rsolenoid 
I , where n  1000
According to Faraday’s Laws, we have
Nd  dI 

dt
2

  N0 n rsolenoid 
  , where N  15
 dt 
dI
Since I  4 cos  250 t    1000  250t 
dt
  2
   15 4107 1000    0.02 1000  sin  250t 

 
   602 4 104 101 sin  250t   
   600  4  105 sin  250t     2400  105 sin  250  t

 
   24 103 sin  250t  volt   peak  24 mV

20. a   S  ; b   P, R  ; c   R  ; d   Q,S 
 SECTION - II CHEMISTRY

PART I: Single Correct Answer Type

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct. (+3, –1)

1. The correct order of bond angles of the XNX bond (where X is the surrounding atom or group of atoms)
(a) NH 4 >N(CH3 )3> NH3> NF3 (b) NH 4 < N(CH3)3< NH3< NF3
(c) NH3> NF3> NH 4 >N(CH3 )3 (d) NH3> NF3> N(CH3)3> NH 4

2. Which of the following compound responds to iodoform reaction?

(a) C2H5 – C – C2H5 (b) CH 3  CH 2  CH 2  COOH
O

(c) CH3 – C – CH2 – C – OC2H5 (d) CH3 – CH – CH3

O O Br

3. Which one of the following is not correct systematic name of corresponding compound?
(a) NaMn(CO)5: Sodium pentacarbonylmangnate(I)
(b) SnCl4(Et2NH)2: Tetrachlorobis(diethylamine)tin(IV)
(c) Ni(CO)2(PPh3)2: Dicarbonylbis(triphenylphosphine)nickel(0)
(d) Na2[Fe(CN)5NO]: Sodium pentacyanonitrosylferrate(II)

4. If o is the threshold wavelength for photoelectric emission,  the wavelength of light falling on the surface of
a metal and m is the mass of the electron, then the velocity of ejected electron is given by
1/ 2 1/ 2
 2h   2hc 
(a)  ( o   )  (b)  ( o   )
m   m 
1/ 2 1/ 2
 2hc   o     2h  1 1  
(c)    (d)    
 m   o   m   o  

5. The vapour pressure of the distillate obtained on condensation of the vapour formed above a solution
containing 2 mole of a liquid A ( PAo = 100 mm of Hg) and 3 mole of a liquid B ( PBo = 150 mm of Hg) at same
temperature would be
(a) 130 mm of Hg (b) 135 mm of Hg
(c) 140 mm of Hg (d) 145 mm of Hg

6. An inorganic salt (A) on reaction with H2O gives a solution (B) and a gas (C). Gas (C) on passing into
ammonical AgNO3 gives white precipitate of (D). CO2 gas turns solution (B) milky. The Compound (A)
would be
(a) BaSO4 (b) Na2SO4
(c) CaC2 (d) CaCO3

7. In the estimation of nitrogen by Duma’s method 1.18 g of an organic compound gave

224 ml of N2 at NTP. The percentage of nitrogen in the compound is about
(a) 20 (b) 11.8
(c) 47.5 (d) 23.7

8. Aluminium is not present in the mineral

(a) Feldspar (b) Fluorspar
(c) Cryolite (d) Mica

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 PART II: Multiple Correct Answer(s) Type

This section contains 4 multiple choice questions. Each question has four choices (A),
(B), (C) or (D) out of which ONE or MORE are correct. (5, –2)

9. Which of the following statements regarding phenols is correct?

(a) Phenols are stronger acid than water and alcohols.
(b) Phenols are weaker acids than carboxylic acids.
(c) Phenols are soluble in both aqueous NaOH and aqueous NaHCO3.
(d) Phenoxide ions are better resonance stabilised than the corresponding phenols.

10. When H2S gas is passed separately through an acidic solution of CuCl2, HgCl2, BiCl3 and CoCl2, which of the
following will precipitate out
(a) CuS (b) HgS (c) Bi2S3 (d) CoS

11. [Ni(CN)4]2 and [NiCl4 ]2 have dissimilarity in

(a) magnetic moment (b) coordination number and oxidation states
(c) structure (d) colour

12. Which of the following is correct under the same conditions of pressure and temperature?
(a) H2 gas diffuses four times faster than oxygen gas
(b) H2 gas diffuses 2.83 times faster than CH4 gas
(c) He escapes at a rate 2 times as fast methane does
(d) He escapes at a rate 4 times as much as sulphurdioxide

PART III: PARAGRAPH TYPE

This section contains 3 multiple choice questions relating to three paragraphs with two
questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct. (+4, –1)

PARAGRAPH FOR QUESTIONS 13 TO 15

The aldehydes not having -hydrogens react in presence of strongly basic medium to give cannizzaro reaction. The
mechanism followed is:
-
Step I O O

H OH
  H H
H OH
-
Step II O O
H H 
 H  H
OH OH
-
Step III O O
H H  
 H H
OH OH
-
Step IV O O
H  H H 
Pr oton
 HCOO   CH 3OH
transfer
OH OH
Second step is rate determining step.

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13. Which among the following can give cannizzaro reaction?
O
(a) (b)
H3C
O
CH3
(c) (d)
O O

O
|| 
OH
14. H  C  H  Ph  CHO 
Strongly basic
P
Among the products alcohol is?
Ph
(a) H3C OH (b)
OH
OH
O
(c) (d) H
OH

15. Though CCl3CHO has no -hydrogen it doesn’t give cannizzaro reaction. The reason is:
O

(a) There is no H attached to

–
(b) CCl3 is a weak base
–
(c) CCl3 is a strong base
(d) None of these

PART IV: Integer Answer Type

This section contains 4 questions. The answer to each question is a single digit
integer, ranging from 0 to 9 (both inclusive) (+4, 0)

16. The potential energy electron in an exited state of Be3+ is27.2 eV. Find the maximum types of photons
produced when it return to ground state.

17. A compound of Vanadium has a magnetic moment 1.73BM. The oxidation state of V in the compound is.

18. For a cell Cu+2 +In+2 = Cu+ +In+3

Given E0 (Cu2+/Cu+) = 0.15V
E0 (In+2/In+)= -0.40 V
And E0(In+3/In+)= -0.42V
The equilibrium constant is x×1010. Then the value of x is_________

19. The kinetic datas for the reaction: 2A + B2   2AB are as given below:
–1 –1
[A] mol L [B2] mol L Rate mol L–1 min–1
0.5 1.0 2.5  10–3
1.0 1.0 5.0  10–3
0.5 2.0 1  10–2
The sum of order of reaction with respect to A and B2 will be

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 PART V: Matrix Match Type

This section contains 1 question. Each question contains statements given in two columns, which have
to be matched. The statements in Column-I are labelled A, B, C and D, while the statements in
Column - II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching
with ONE OR MORE statement(s) in Column- II. The appropriate bubbles corresponding to the
answers to these questions have to be darkened as illustrated in the following example: If the correct
matches are A - p , s and t ; B - q and r ; C - p and q ; and D - s and t. (+8, 0)

20. Column – I (Chemical Tests) Column – II (Acid radicals)

(A) CO2 (p) Gives black ppt. with Pb(CH3COO)2 solution

(B) SO2 (q) Turns lime water milky
(C) H2S (r) Turns alkaline nitroprusside solution voilet
(D) SO 4 2 (s) Gives a white ppt. with BaCl2
(t) Smell of rotten eggs.

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 PAPER – I (SOLUTION)

1.
H

N 109°28’ N 107°

H H H H H H

more than 107° & Less than 107°

less than 109° as
methyl group is N
N bulkier than hydrogen
and one lone pair of F
electrons is present. F F
H3C CH CH3
3

Therefore, NH 4 >N(CH3)3> NH3> NF3

 (a)

2. Due to presence of active methylene group in (c), halogenation will take place at methylene carbon
(–CH2–) rather than at methyl carbon.
In the presence of alkali (NaOH), CH3CH(Br)CH3 will be converted to CH3CH(OH)CH3 which will
respond to iodoform test.
 (d)

3. Correct IUPAC name of NaMn(CO)5 is Sodium pentacarbonylmangnate(I)

 (a)

hc hc 1 1 1 1 
4.   mv 2 mv 2  hc   
 o 2 2  o 
1/ 2
 2hc   o   
 v=   
 m   o 
 (c)

5. Mole fraction of A in the distillate or in the vapour above the liquid mixture
2
 100
5 4
= 
2 3 13
 100   150
5 5
9
 Mole fraction of B in distillate =
13
4 9
Therefore, total vapour pressure above distillate =  100   150 = 134.61 mm of Hg
13 13
 (b)

6.  Ca(OH)2 + C2H2
CaC2 + H2O 
(A) (B) (C)
C2H2 + 2AgNO3 +2NH4OH  C2Ag2 + 2NH4NO3 + 2H2O
(D)
 (c)

7. (d)
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8. The composition of ores are
Feldspar KAlSi3O8, Fluorspar CaF2
Cryolite Na3AlF6, Mica = Al2O3.2SiO2.2H2O
 (b)

9. (a),(b),(d)

10. Comparatively cobalt sulphide is more soluble so it can not be precipitated by such a small
concentration of sulphide ion which is produced by passing H2S gas in acidic solution.
 (a), (b), (c)

11. In [Ni(CN)4]2 , the hybridization of nickel is dsp 2 (structuresquare planar) having no unpaired
electrons while in [NiCl4]2, the nickel is present in sp3 hybridization
(structure tetrahedral) with 2 unpaired electrons. Hence these two complexes differ in magnetic
moment, structure and colour but have similar coordination number and oxidation states.
 (a), (c), (d)

12. (a, b, c, d) 13. (d) 14. (b) 15. (b)

16. 6 17. 4 18. 1

19. 3
2.5  10–3 = k[0.5][1.0] …(1)
5  10–3 = k[1.0] [1.0] …(2)
1  10–2 = k[0.5] [2.0] …(3)
Dividing equation (1) and (2)

1 1
 
2 2
hence = 1
Dividing equation (1) and (3)

2.5  10 3  1.0 
 
1  10 2  2.0 

1 1
 
4  2
=2

20. (A – q, s), (B – q, s), (C – p, r, t), (D –s)

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 SECTION III : MATHEMATICS

PART I : Single Correct Answer Type

This section contains 6 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONLY ONE is correct. (+3, –1)

  
 sin  x  1  sin   x  1 
1 If [.] denotes the integral part of x and f  x    x    , then
 1  X 
 

(A) f  x  is continuous in R
(B) f  x  is continuous but not differentiable in R
(C) f ' x exists  x  R
(D) f  x  is discontinuous at all integral point in R.

2 If [X] represents the greatest integer less than or equal to x, then the solution of the
2
equation 2  4x   4  4x   6  0 is

1 3 1 3 3
(A) x (B) x (C) 1  x  (D)  2, 3
2 4 2 4 4

  
 sin  2  x   x   , x5
  
3 If   
f x  5  
b  1 , x  5 , is continuous at x  5,  a, b  R 
 x  11x  24
ab 2 , x 5
 x3
then ([.] denotes greatest integer function)
25 6 6 17
(A) a  ,b (B) a  ,b
108 5 13 29
1 25 23 6
(C) a  , b  (D) a  ,b
2 36 100 5

4 If AB, BE and CF are the altitudes of a triangle ABC whose vertex A is the point
 4, 5 . The coordinates of the points E and F are  4, 1 and  1,  4  respectively,,
then equation of BC is
(A) 3x  4y  28  0 (B) 4x  3y  28  0
(C) 3x  4y  28  0 (D) x  2y  7  0

5 ax 2  2hxy  by 2  2gx  2fy  c  0 represent two parallel lines if

(A) h 2  ab, f 2  bc (B) h 2  ab, hf  gb, f 2  bc
(C) h 2  ab, hf  gb, f 2  bc (D) none of these

6 x 2  a  1 x  1  x has exactly three real roots then one value of a

(A) 1 (B) 2 (C) 3 (D) 4

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 PART II : Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONE or MORE are correct. (+5, –2)

 sin 1 x 
7 lim   (where [.] denotes greatest integer function) is
x 0
 x 
(A) left hand limit is –2 (B) left hand limit is –1
(C) right hand limit is 1 (D) limit exists and both are equal to 1
2 n
8 Let 1  x 2  1  x   a 0  a 1 x  a 2 x 2  ..... if a 0 , a 1 , a 2 are in A.P., then the value of n is
(A) 3 (B) 5 (C) 4 (D) 2

9 Which of the following pair(s) of function have same graphs?

sec x tan x cos x sin x
(A) f  x    , gx  
cos x cot x sec x cosec x
  
(B) f  x   sgn  x 2  4x  5 , g  x   sgn  cos 2 x  sin 2  x   
  3 
where sgn denotes signum function.
(C) f  x   e 
ln x 3x  3 
2

, g  x   x 2  3x  3

sin x cos x 2 cos 2 x

(D) f  x    , g x  
sec x cosec x cot x

10 Which of the following statement(s) is True?

(A) P  n  : n 2  n  41 is prime for every n  N .

1  2n n
(B)   ln 2 is rational.
n 1 n!
 1 1 1 
(C) ln     .........  simplifies to an integer..
 1·3 1·2·3·5 1·2·3·4·5·7 
6 10
(D) Coefficient of x 5 in 1  x  is C6

PART III : Paragraph Type

This section contains 4 multiple choice questions relating to three paragraphs with two
questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct. (+4, –1)

PASSAGE 1
Consider a parabola P which touches y  0 at (1, 0) and x  0 at (0, 2).

11 The vertex of P is
16 2 4 2
(A)  ,  (B)  , 
25 25
  5 5
 12 6 
(C)  ,  (D) none of these
 25 25 

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12 Latus rectum of P is
9 16 5
(A) (B)
5 5 25
16 8
(C) (D)
25 25

PASSAGE 2
x a
f x  where a,b,c  R, f  1  0 and y  1 is an asymptotes of
bx 2  cx  2
y  f  x  , y  f 1  x  is inverse function of f  x 

13 f  x  is equal to
x 1 x 1
(A) f  x   (B) f  x  
x2 x2  x  2
x 1
(C) f  x   (D) none of these
x  2

14 f 1 : R  1  R then f 1  x  is
(A) one-one onto (B) one-one into
(C) many-one into (D) many-one onto

PART IV : Integer Answer Type

This section contains 4 questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive). (+4, 0)

15 Let two parallel lines L1 and L2 with positive slope are tangent to the circle
C1 : x 2  y2  2x  16y  64  0. If L1 is also tangent to the circle C 2 : x 2  y2  2x  2y  2  0 and
equation of L2 is a a x  by  c  a a  0 where a, b, c  N , then find the value of  a  b  c .

n n
n
16 If  Cm .m Cp  19 then find value of n.
p 1 m  p

17 Let C be the set of 6 consonants {b, c, d, f, g, h} and V be a set of 5 vowels {a, e, i, o, u}

and W be the set of seven letter words that can be formed with these 11 letters using both
the following rules.
(a) The vowels and consonants in the word must alternate.
(b) No letter can be used more than once in a single word.
K
If the number of words in the set W are K then is.
12000

18 A cricket player played n  n  1 matches during his career and made a total of
(n 2  12n  39)(4·6n  5·3n  1)
runs. If Tr represent the runs made by the player in rth match such
5
that T1  6 and Tr  3Tr 1  6r , 2  r  n then find n.

19 Find the number of solutions of log x  log x 2   x

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 PART V: Matrix Match Type

This section contains 1 question. Each question contains statements given in two columns, which have to
be matched. The statements in Column-I are labelled A, B, C and D, while the statements in Column -
II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching with ONE OR
MORE statement(s) in Column- II. The appropriate bubbles corresponding to the answers to these
questions have to be darkened as illustrated in the following example: If the correct matches are A - p , s
and t ; B - q and r ; C - p and q ; and D - s and t. (+8, 0)

20 Column I Column II

(A) If a  cosec2  cot 1 3  sec2  tan 1 2  then (P) x2

1 1  1  1
(B) If tan x  tan    tan 3 and y 2  y  56  0 then (Q) x 5
y
 
1
(C) If cos 1 x  tan 1 y and y 2  3 then (R) x
2

   3  1
(D) If sin 1  tan   sin 1  2
   0 and x  y then (S) x
 4  y 6 2

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PAPER - I (SOLUTION)
1
n   
Sol At x  n,f  n   sin 
n 1  n 1
f n

 
n 1 
 
f n 
n
sin
n
 f(x) is discontinuous at all n  I

2
Sol 2y2  7y  6  0 where y   4x 
3
 2y  3 y  2   0  y  2 or
2
, but y is an integer

 3
  4x   2 ; Hence 2  4x  3 or  x  
2 4

3
   
Sol  
f 5   lim sin   x   x     lim sin   x  4    1
x 5 2  x5 2 

ab2 x 2  11x  24 ab 2  x  3  x  8 

   lim
f 5 
x 5 x3
 lim
x 5 x3
 3ab2 .

2
 5  b  1  1  3ab
6 25
 b ,a  
5 108

4
5   4  9
Sol Slope of AF    3
4  1 3
1 1 A  4,5 
 Slope of CF   , Also F lies on CF
3 3
 Equation of CF : x  3y  11  0 ...(1) E  4,1
5 1 4 1
 1, 4  F
slope of AE   
4  4 8 2 O
1 B C
BE   2, D
Slope of 1 Also E lies on BE

2
 Equation of BE : 2x  y  7  0 ...(2)
solving (1) and (2), we get point O   2, 3
Since CB is passing through intersection of AC & FC
 Equation of CB : x  2y  6    x  3y  11  0
 or x    1  y  2      6  11   0 ...(3)

 1 5   3  4
slope of CB  ; also slope of AO  
3  2 4  2 3
 1 4
since CB  AO ;    1 or   2;
3  2 3
Equation of BC : 3x  4y  28  0.

Sol
  hx  f   h 2

 ab x 2  gx  hf  gb   f 2  bc
y
b

6
Sol a  1, x 2   a  1 x  1   x
D  0, a  0, 4
A  1, x 2   a  1 x  1  x
D  0, a  0, 4.

7
 sin 1 h   sin1 h   sin1 h 
Sol LHL  lim    lim    2 , RHL  lim    1.
h 0
 h  h0  h  h 0
 h 
8
Sol 1  x 4
 2x 2  n

C 0  n C1x  n C 2 x 2  ...  a 0  a 1x  a 2 x 2  ...

By comparing, a 0  1,a1  n,a 2  2  n C 2

n  n  1
 2n  1  2   n 2  5n  6  0
2
 n  2, 3.

9
sec x tan x cos x sin x
[Sol.(A) We have f(x) =  , g(x) = 
cos x cot x sec x cosec x

k
Clearly both f(x) and g(x) are identical functions as x   k  I.
2

(B) As x2 – 4x + 5 = (x – 2)2 + 1 > 0

Hence f(x) = 1  x  R.
 
Also cos2 x + sin2  x   > 0
 2
Hence g(x) = 1  x  R.
 f(x) and g(x) are identical.
2
(C) f(x) = e ln(x 3x 3) 2
 3 3
As x2 + 3x + 3 =  x    > 0  x  R.
 2 4
Hence f(x) = x2 + 3x + 3  x  R.
 f(x) is identical to g(x).
 sin x

cos x 2 cos 2 x
(D) We have f(x) = , g(x) =
sec x cos ec x cot x
k
Clearly both f(x) and g(x) are identical functions as x   k  I. ]
2

10
[Sol.
(A) for n = 41, P(n) is not prime
ln 2 ln 2 2 ln 3 2 ln 4 ln 2 4 ln 3 8
(B)    .......    0
1! 2! 3! 1! 2! 3!
= (eln 2 – 1) + (eln 4 – 1) = 1 + 3 = 4 + Q  (B) is correct
2 4 6
(C)    ........
3! 5! 7!
2n  1  1 1 1 1 1 1 1 1 1 1 1
Tn =   =     ..... = 1     ..... =
(2 n  1)! (2n )! (2n  1)! 2! 3! 4! 5! 1! 2! 3! e
(D) 5 –6 10
Coefficient of x in (1 – x) = C5  (D) is not correct ]

11
Sol. A

12
Sol. B

Sol 13 to 14
xa
f  x 
bx 2  cx  2 f  x

f  1  0  a 1
x 1
f  x 
bx 2  cx  2
lim f  x   1
x 

 b0 & c 1
x 1 1
 x
 f  x  y f
x2
 x  1  yx  2 y

2 y  1 2  y  1  1
 x 
1 y 1 y

1 f 1
 x   2 for any x
 2 
1 y
15 [Ans. 14 ]

16 [Ans. n = 3]
n
n! m!
Sol. Cm . mCp = (n  m)! m ! × (m  p) ! p !

n! (n  p) !
= (n  p ) ! p ! . (n  m ) ! (m  p ) ! = nCp . n– pCm – p

n n
n n p
Now,   Cp . Cmp
p 1m p

n
=  n Cp (n – pC0 + n – pC1 + n – pC2 + ........ + n – pCn – p)
m p

n n
n
=  C p .2np = 
n
C p .2 n  p – 2n
p 1 p0

= 3n – 2n
further 3 n – 2 n = 19  n=3
17 [Ans. 3]
[Sol. Consonant  b, c, d, f, g, h (6)
Vowels  a, e, i, o, u (5)
w: × × × ×
Case I: If word begins with consonants
then ( 6C4 × 4!) × ( 5C3 × 3!) = 360 × 60= 21600
Case II : If word begins with vowels
( 5C4 × 4!) × ( 6C3 · 3!) = 120 × 120 = 14400
Total = 36000
36000
 K  K  3 Ans. ]
12000

18 [Ans. 6]
[Sol. We have Tr – 3Tr–1 = 6r
 Dividing both sides by 3r, we get
Tr Tr 1 r
r – r 1 = 2
3 3
n n
T T 
   3rr  3rr11  =  2 r
r 2 r

2
G.P.

T2 T1
 2

3 3
T3 T2
+ 3

3 32
T4 T3
+ 
34  33
  

Tn Tn 1 
+ n  n 1 
3 3  n
—————    2r
Tn T1  r 2
 
n–1
= 4(2 – 1).P.
G
3n 3 

Tn 6 
n – = 4(2n–1 – 1) ( T1 = 6)
3 3 
 T n = 2 · 3n + 4 · 3n · 2n – 1 – 4 · 3n = 2n + 1 · 3n – 2 · 3n
 Tn = 2(6n – 3n)
 n n n n
So, Sn = 2   6   3 
 1 1 

n6 n 3 
= 2  (6  1)  (3  1)
5 2 
3
 Sn =
5 4·6 n
 5 · 3n  1 
Now on comparing, we get
( n 2  12n  39) ( 4·6 n  5·3n  1) 3
5
=
5 4·6 n
 5 · 3n  1 
 n2 –12n + 39 = 3  (n –6)2 = 0
Hence n = 6 Ans. ]

19 [Ans. 0]
Sol. log x is defined for x > 0 only, |log x – log x2| = – x x0
 No solution.
20
Sol (A)  (q),(B)  (p,q),(C)  (r),(D)  (p)
(A) x  1  cot 2  cot 1 3  1  tan 2 tan 1  2 
x  5.
  1
x y  x
(B) tan 1    tan 1 3 if 1  y  0
x 1 
 y 

 x  5 & 2.
1 1
(C) x  cos   
1 y 2 2

1
x 
2
 3 
(D) sin 1 1  sin 1     0
 y 6
y  4 and x  2.
 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
FULL TEST – 2 (ADVANCED PATTERN)
PAPER – I (ANSWER KEY)

PHYSICS

1. A 2. A 3. C OR D 4. B 5. C 6. A 7. A

8. D 9. A, B, C, D 10. B, C, D 11. A, B, D 12. A, B, C, D

13. B 14. A 15. C 16. (9) 17. (16) 18. (1) 19. (24)

20. a   S  ; b   P, R  ; c   R  ; d   Q, S 

CHEMISTRY

1. (A) 2. (D) 3. (A) 4. (C) 5. (B)

6. (C) 7. (D) 8. (B) 9. (A,B,D) 10. (A,B,C)

11. (A,C,D) 12. (A, B, C, D) 13. (D) 14. (B) 15. (B)

16. (6) 17. (4) 18. (1) 19. (3)

20. (A – Q, S), (B – Q, S), (C – P, R, T), (D –S)

MATHS

1. D 2. A 3. A 4. A 5. C

6. D 7. A,C 8. A,D 9. A,B,C,D 10. B,C

11. A 12. B 13. A 14. B 15. 14

16. 3 17. 3 18. 6 19. 0

20. A  Q; B  P, Q;C  R; D  P

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

 PAPER – II

PHYSICS

1. D 2. A 3. C 4. C 5. D 6. C 7. B

8. D 9. A, C 10. B, C 11. A, B, C, D 12. B, C 13. A

14. A 15. A 16. (1) 17. (2) 18. (8) 19. (2)

20. a   P  ; b   P, Q,S ;c   Q  ; d   Q, R 

CHEMISTRY

1. (B) 2. (C) 3. (B) 4. (A) 5. (C)

6. (B) 7. (B) 8. (B) 9. (A,B,C,D) 10. (B, C, D)

11. (A, C, D) 12. (A, D) 13. (C) 14. (D) 15. (A)

16. (1) 17. (1) 18. (1) 19. (4)

20. (A) – (R), (S), (B) – (R), (C) – (P), (Q), (D) – (R), (S)

MATHS

1. C 2. D 3. C 4. C 5. A

6. C 7. B 8. C 9. A,B,C 10. A,B,C,D

11. A,B,C 12. B,C 13. C 14. C 15. D

16. 1210 17. 1 18. 6 19. 4

20. A  R; B  S;C  P,S; D  Q, R

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA