Sri Chaitanya Narayana IIT Academy: Grand Test-6

GRAND TEST-6
Sri Chaitanya Narayana IIT Academy

(SRI SARVANI EDUCATIONAL SOCIETY)
COMMON CENTRAL OFFICE-MADHAPUR-HYDERABAD
Sec: Sr. IPLCO Date:20-03-16
Time: 9:00 AM to 12:00 Noon Max.Marks:360
Name of the Student: ___________________ I.D. NO:

IMPORTANT INSTRUCTIONS:
1) Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use
of pencil is strictly prohibited.
2) The test is of 3 hours duration.
3) The Test Booklet consists of 90 questions. The maximum marks are 360.
4) There are three parts in the question paper A, B, C consisting of Mathematics, Physics and Chemistry
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for
correct response.
5. Candidates will be awarded marks as stated above in instruction No. 4 for correct response of each
question. (1/4) (one fourth) marks will be deducted for indicating incorrect response of each question.
No deduction from the total score will be made if no response is indicated for an item in the answer
sheet.
6. There is only one correct response for each question. Filling up more than one response in any question
will be treated as wrong response and marks for wrong response will be deducted accordingly as per
instruction 5 above
Sri Chaitanya Narayana IIT Academy 20-03-16_Sr.IPLCO_PH-II_Jee-Main_ GTM-6_Q.P
20-03-16_Sr.IPLCO_Jee-Main_GTM-6_Syllabus
MATHS:
Total syllabus + Extra syllabus
PHYSICS:
CHEMISTRY:
Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 2

MATHS
1. If A,B are two 3x3 matrices such that 2 A  100, 3B  648 then number of positive
integral divisors of adj (5 AB ) equals
1) 140 2) 158 3) 165 4) 172
2. Sum of the last two digits in the value of 2999 equals
1) 8 2) 12 3) 14 4) 16
3. In a  ABC, with usual notation, if b>c then the distance between foot of median
and foot of altitude both drawn from vertex A on BC is
b2  c2 b2  c2 2 b2  c2  2b 2  c 2  bc
1) 2) 3) 4)
a 2a a a
4. The area of the triangle formed by the tangent, normal at origin on the curve
 
sin y  x sin   y  and the line x  3 in given by
3 
3 3 3 3 5 3 7 3
1) 2) 3) 4)
2 4 2 4

5. Let Z1, Z2, Z3, Z4 be the roots of the equation Z 4  Z 3  2  0 then the value of
 4   4 
Re  r 1  r 
 2 Z  1  i Im  r1  2Z r  1 equals
1) 28 2) 31 3) 42 4) 39
6. If a,b,c,d are distinct integers in A.P such that d=a2+b2+c2 then the value of
a+b+c+d equals
1) 1 2) 2 3) 16 4) 18
7. Let A, B be two sets such that n( A  B ) =6 and n( A  B ) =3 then the maximum
possible number of functions from A to B is
1) 216 2) 625 3) 729 4) 1024
8. If p.m  ql , bl  am, aq  pb
a b 1 qm l  p pm  ql
and if p q 1 m  b a  l bl  am  216
l m 1 bq p  a aq  pb
Then the minimum value of ( p m-ql)2+(bl-am)2+(aq- p b)2 equals

1) 6 2) 8 3) 12 4) 18

1 1
1 x 1 x
9. Let I   dx , J   dx then
0 1 x 0 1 x
1) I>J 2) I<J 3) I+J=2 4) IJ=1
10. The shortest distance from (1,2,3) to the line x  y  z is
1) 1 2) 2 3) ½ 4) 2
11. If the two lines x+2y+z-5=0=3x-y+z-4 and 2x  y  z  1  0   y  2z  5
are coplanar then the value of  equals
1) 1 2) 2 3) 3 4) 4
12. A circle with smallest radius is tangent to parabola y2=8x at (2,4) and is also
tangent to x-axis then its area equals

1) 32 3  2 2   
2)16 3  2 2  

3) 64 3  2 2   
4) 4 3  2 2  
sin A 3 cos A 5   sin( A  B)
If  and  , 0  A  , 0  B  then the value of equals
sin B 2 cos B 2 2 2 cos A cos B
13.
3 5 3 5
2 1
5 3 5
1) 2) 3) 4)
14. If the number of ways of giving away 3like objects and 4 other distinct objects to
3 persons is N than the number of positive integral divisors of N is
1) 20 2) 12 3) 10 4) 24
15.
Let f : (1,1)  R be a continuous function
sin 2 x
3 2 1 1 3
If  f (t )dt  .x then the value of f    equals
0
2   2 4 
1 1 2 4
1) 3 2) 2 3 3) 3 4) 3
16. If exactly two integers lie between the roots of the equation x2+ax-1=0, then the
sum of all possible integral values of ‘a’ equals
1) 0 2) 1 3) 2 4) -2

1 y 2   x2 1 
 
17. Solution of the differential equation   2  dx   2   dy  0 is
 x  x  y  x  y y 
x xy xy
1) ln  c 2) ln xy  c
y  x  y x
  y
xy xy
3)  ce x / y 4)  ce xy
 x  y  x  y
10 2r 1  r 2  2r  1
18. The value of 
r 1 r 2  r  1
2
 
903 823 701 504

1) 121 2) 121 3) 121 4) 121
19. The marks of some students were listed out of 75. The standard deviation was
found to be 12. Subsequently the marks were raised to a maximum of 100, then
the variance of new marks is
1) 144 2) 169 3) 256 4) 327

20. 
The value of Lt cos2  3 n3  n 2  2n equals n  N
n 

1 1 1 1
1) 3 2) 2 3) 4 4) 9
21. Let g(x) be the only invertible function from R→R which satisfies the equation
g3(x)-(x3+2)g2(x)+(2x3+1) g(x)-x3=0 then the value g1(8).(g-1)1 (8) equals(where
d
g1  x  
dx
 g  x  , g 1 isinverse of g 
1) 18 2) 16 3) -12 4) -8
1  x  1  x  x 2 1  x  x 2   x 2 
22. If  f  x  d x  F ( x)  c when f ( x)  then the
1  2 x  3 x 2  4 x3  3 x 4  2 x5  x 6
value of  F  24   F  0   equals [] is GIF 
1) 1 2) 2 3) 3 4) 7
23. Let f(x) be a continuous function satisfying the equation
x x
 f (t )dt   t f ( x  t )dt  e
x
 1 and f  0   1then the value of e10f(10) equals
0 0
1) 7 2) 9 3) 11 4) 12

3
24. The area bounded by y  cos1  sin x  sin 1  cos x  and x-axis when
2
 x  2 is equal
to
2
2 2 3 2
1)  2) 2 3) 4 4)
4
 2  x  a 2  9a  9 if x  2
25. Let f(x)= 9 x  17 if x  2
where a is positive constant. If f(x) has a local

minimum at x=2 then the smallest integral value of a equals
1) 7 2) 8 3) 9 4) 10
x4 y 2
26. The minimum length of intercept on any tangent to the ellipse 4  9  1 cut by
the circle x2+y2=25 is
1) 8 2) 9 3) 2 4) 1

2 2
27. The length of the shortest chord of the parabola 5 x  y  4 x  4  4 x  3 y  1 which
belongs to the family of lines 1  3  x   2    y  2 1  3   0 equals
14 8 7
1) 5 2) 5 3) 5 4) 1
28. The mean and median of all the proper divisors of 360 are connected by
1) median>mean 2) median<mean
3) median=mean 4) none
29. If p and q are two statements then the statement  p   q     p  q  is
1) a tautology 2) a contradiction
3) tautology and contradiction 4) neither a tautology nor a contradiction
30. Number of reflexive, symmetric relations on set A  1, 2,3, 4 is n1 and n2
respectively and if n1  n2  k  220  than k=
1) 17 2) 15 3) 18 4)12

PHYSICS
31. Two blocks of equal masses (M) are connected by a string and are kept on rough
horizontal surface as shown in figure. The coefficient of friction between the
blocks and the surface is  . If 0  F1  F2  2Mg , then choose the correct statement.
B A
F2 F1
1) The direction of friction on block A is towards right.
2) The direction of friction on block B may be towards left or right
3) Tension in the string must be zero

4) Friction force on block B must be zero

32. A small block of mass m is lying at rest at point P of a stationary wedge having a
smooth semi circular track of radius R. The maximum value of horizontal
acceleration a 0 that can be given to the wedge so that block does not leave the
track is
Q
a0 P
1) g/2 2) g 3) g 4) 2g
33. A uniform body of mass M and radius R has a small mass m attached at edge as
shown in the figure. The system is placed on a perfectly rough horizontal surface
such that mass m is at the same horizontal level as the centre of body. It is
assumed that there is no slipping at point A, If I A is the moment of the inertia of
combined system about point of contact A then the normal reaction at point A
just after the system is released from rest is (M = 6kg, m = 2kg, IA= 4kg .m2,
R = 1m, g = 10m/s2)
M
m
1) 60 N 2) 80 N 3) 75 N 4) 70 N

34. A ball of mass 10kg and density 1 g/cm3 is attached to the base of a container
having a liquid of density 1.1 g/ cm3 , with the help of a spring as shown in the
figure. The container is going up with an acceleration 2 m / s .If the spring
2
constant of the spring is 200 N/m, elongation in the spring is

2 m / s2
1) 2cm 2) 4cm 3) 6cm 4) 8cm

35. Two identical simple pendulums A and B are fixed at same point. They are
displaced by angles α and β as shown (α and β are very small and β > α) and
released from rest. Find the time after which B reaches its initial position for the
first time. Collisions are elastic and length of each string is  .
 
B
A
    2 
1)  2) 2 3) 4)
g g  g  g

36. A  cm long string fixed at both ends, sustains a standing wave such that all the
points on the string having displacement amplitude 1 mm (less than maximum
amplitude) are separated by d cm. The string is oscillating in its third overtone
then
   
1) 2 2) 3 3) 6 4) 8
d d d d
37. A car is moving towards a huge wall with a speed  c 10 , where c  speed of
sound in still air. A wind is also blowing parallel to the velocity of the car in the
same direction and with the same speed as car. If the car sounds a horn of
frequency f , then what is the frequency of the reflected sound of the horn heard
by driver of the car?
10 f 11 f 11 f 10 f
1) 2) 3) 4)
9 10 9 11
38. The temperature at the bottom of a water pond of depth L is maintained at 4 C .

The temperature of air, just above the layer of ice frozen at the pond’s surface, is
2 C for the past many days. Assume that the thermal conductivity of ice is three
times that of water. The thickness of the frozen layer of the ice in equilibrium
must be (Neglect the expansion due to freezing of water)
2L L L 3L
1) 2) 3) 4)
3 2 3 5

39. If the molar heat capacity of a gas in the process PT = constant is 5R, the number
of degrees of freedom of molecules in the gas is
1) 4 2) 5 3) 6 4) 3
40. The internal energy of an ideal gas is related as U=a + b (PV) (where P is the
pressure of gas, V is the volume of gas, ‘a’ and ‘b’ are constants of appropriate
dimensions. Then  of the gas is
1) a/b 2) 1+(b/a) 3) 1 + (1/a) 4) 1+(1/b)
41. An ideal gas is enclosed in a cylindrical vessel with one end closed by a freely
movable piston. Initial pressure in the vessel is P0 when the length is 2L. Cross
section area of piston is A. If the piston is made to execute SHM with x  L sin t
and the process is isothermal, then heat given to the gas will be
A P0
x
2L x0
 sin t   sin t 
1) 2 P0 LA ln  1  2) 2 P0 LA ln  1 
 2   2 
 sin t 
3) P0 LA ln   4) none of these
 2 

42. A cavity of radius r is made inside a solid sphere. The volume charge density of
the remaining sphere is  . An electron (charge e, mass m) is released inside the
cavity from point P on the surface of cavity as shown in figure. The centre of
sphere C1 and centre of cavity C2 are separated by a distance a. The time after
which the electron again touches the sphere is
C2
6 2r 0 m 2r 0 m 6r0 m r0 m

1) 2) 3) 4)
ea ea ea ea

43. An electric field given by E  4iˆ  3  y 2  2  ˆj passes through a Gaussian cube of side
1m placed in the first quadrant such that one of its corners is at the origin and
three of its sides represents x, y and z axes. The magnitude of net charge enclosed
within the cube is
1) 4 0 2) 3 0 3) 50 4) zero
44. Find the reading of the ideal ammeter connected in the given circuit. Assume that
the cells have negligible internal resistance.
10 V 4V 8V 6V
10  8 4 2 A
1) 0.8A 2) 0.25A 3) 1.95A 4) 0.05A

45. A vertical ring of radius r and resistance R falls vertically. It is in contact with
two vertical rails which are joined at the top with a conducting wire of zero
resistance. The rails are conducting, frictionless and have negligible resistance.
Horizontal uniform magnetic field of magnitude B perpendicular to the plane of
ring and rails exists. When the speed of ring is V, the current in the section PQ is:
2BrV 4BrV 8BrV

1) zero 2) 3) 4)
R R R

46. A wire carrying a current i from O to A is placed inside a uniform magnetic field

B   B 0 kˆ . The shape of the wire is parabolic and has equation Y  2x  x . The
2
force on the wire will be (y-axis is along vertical)

Y
x x x x x
x x x xB x
x x x x x
i i
x x x x x
O A
X
x x x x x
z
1) F  2B0i , upwards 2) F  2B0i , downwards

3) F  4B0i , upwards 4) F  4B0i , downwards
47. Two resistors with resistances R1 and R2 are connected in series and so are two
capacitors with capacitances C1 and C2, these two systems are connected to a
battery as shown in figure. Potential difference between a and b is zero in steady
state if
R1 a R2
C1 b C2
1) R1 + R2 = C1  C2 2) R1R2 = C1C2
3) R1C2 = R2C1 4) R1C1 = R2C2
48. A resistor of resistance R, an inductor of inductance L and a capacitor of
capacitance C are connected in series and the combination is connected to a
battery of emf  as shown. At t = 0, the switch S is closed. Let, after a very long
time, the thermal energy developed in circuit be Q, energy stored in circuit be U
and energy supplied by battery be E. Then
C
R L
 S
1) Q : U : E  1:1: 2 2) Q : U : E  1: 3 : 4
3) Q : U : E  3 :1: 4 4) Q : U : E  1: 2 : 3
49. In the circuit shown switch is connected to 1 for a very long time. At a particular
instant t = 0, switch is suddenly shifted to 2, the current in the circuit after a time
L
gap of is. ( use 1/e = 0.37 )
R
2 L
2L R
E
E E
1)1.74 2)0.63 3) 1.11 E 4) E
R R R R

50. The magnetic field in a plane electro magnetic wave is given by
By  2 107 sin  0.5 103 x  1.5 1011 t  T . The expression for electric field is
1) Ez  60 sin  0.5  103 x  1.5  1011 t  V / m
2) Ez  60 sin  0.5  103 x  1.5  1011 t  V / m
3) E y  60 sin  0.5  103 x  1.5  1011 t  V / m
4) E y  60 sin 0.5 103 x  1.5 1011 t  V / m
51. An LCR series a.c circuit is connected to an a.c source of variable angular
frequency  and a fixed voltage amplitude. The current amplitude in the circuit
is found to be 37 percent of the value at resonance for two angular frequencies 1
and  2 . The resonance angular frequency of this circuit must be

12 1   2
1) 1  2  2)
2
 1 2 2 1 2
3) 4)
1   2 1   2

52. When a thin transparent sheet of refractive index   3 is placed near one of the
2
slits in Young’s double slit experiment; the intensity at the centre of the screen
reduces to half of the maximum intensity. The minimum thickness of the sheet
should be
   
1) 2) 3) 4)
4 8 2 3
53. The x-z plane separates two media A and B of refractive indices µ1 = 1.5 and
µ2 = 2. A ray of light travels from A to B. Its directions in the two media are
 
given by unit vectors u1  aiˆ  bjˆ and u 2  ciˆ  djˆ . Then
a 4 a 3 b 4 b 3
1)  2)  3)  4) 
c 3 c 4 d 3 d 4
54. Light from source consists of two wavelength 1  650nm & 2  390nm . If D = 2m
and d = 6.5 mm, the minimum value of y where the minima of both the wave
lengths coincides is
1) 0.1 mm 2) 0.2 mm 3) 0.3 mm 4) 0.4 mm

55. A silver sphere (work function 4.6eV) is suspended in a vacuum chamber by an
insulating thread. Ultraviolet light of wavelength 0.2 µm strike on the sphere.

o
The maximum electric potential of the sphere will be (hc = 12400eV A )
1) 4.6V 2) 6.2V 3) 1.6V 4) 3.2V
56. A radioactive isotope is being produced at a constant rate X. Half-life of the
radioactive substance is Y. After some time the number of radioactive nuclei
become constant. The value of this constant is
XY X
1) 2) XY 3) XY log 2 4)
ln 2 Y
57. When the electron in a hydrogen atom jumps from the second orbit to the first
orbit, the wavelength of the radiation emitted is  . When the electron jumps from
the third to the first orbit, the wavelength of the radiation emitted as
9 4 27 32
1)  2)  3)  4) 
4 9 32 27
58. In the circuit shown, if each diode has a forward biased resistance of 75 Ω and
infinite resistance in reverse bias, what will be the values of currents i1, i2, i3 and
i4?
1) i1 =0.2 A, i2 = 0, i3 = 0.2 A, i4 = 0
2) i1 =0.26 A, i2 = 0, i3 = 0.26 A, i4 = 0
3) i1 =0.2 A, i2 = 0.07 A, i3 = 0.07 A, i4 = 0.07 A
4) i1 =0.2 A, i2 = 0.1A, i3 = 0 A, i4 = 0.1 A
59. In a junction transistor operating under common emitter connections in active
region, the base current is changed by 20  A . Due to this, base-emitter voltage is
changed by 0.02 volt and collector current changed by 2mA. Find the voltage
gain of amplifier if load resistance RL is 5000  .
1) 100 2) 300 3) 400 4) 500
60. A telescope has objective and eye piece of focal lengths 50 cm and 5 cm
respectively. The telescope is focused on a scale placed 2m from the objective
for the final image at near point (25cm). Calculate the separation between
objective and eyepiece.
1) 425/6 cm 2)225/6 cm 3) 55 cm 4) 33 cm

CHEMISTRY
One of the nicest application of reduction potential diagram is the prediction of
the products of reaction involving elements having several oxidation states.
Consider the reaction of iodine with permanganate in acid solution. The pertinent
diagram is shown below:
1.14 V 1.45 V 0.54V
IO 3   HOI   I3   I
1.20 V
1.239 V
0.56 V 2.26 V 1V 3 1.5 V

MnO 4  MnO
4  MnO 2  Mn   Mn2 
1.20 V
 Mn
1.69 V
Another application of the above diagram is to predict the species which are
unstable towards disproportionation.
61. When the reaction between I and MnO is carried out with iodide in excess, then
 
4
the products of the reaction are

1) I3 and MnO 
4 2) IO3 and MnO2
 2  2
3) I3 and Mn 4) IO3 and Mn
62. What are the species based on potential values shown above which are unstable
towards disproportionation?

1) I3 , HOI, Mn3+ 2)HOI, Mn3+, MnO 
4

3) HOI, MnO2, MnO4 4) HOI, I3 ,MnO
4
63. Acid hydrolysis of ester is first-order reaction and rate constant is given by
2.303 V – V0
k log 
t V – Vt
where V0, Vt and V are the volume of standard NaOH required to neutralise acid
present at a given time; if ester is 50% hydrolysed then:
1) V = Vt 2) V = (Vt – V0)
3) V = 2Vt – V0 4) V = 2Vt + V0

64. Compare the two methods shown for the preparation of carboxylic acids:
Mg i CO
Method # 1: R  Br   R  MgBr   RCO2H
2

Et O 2 ii H O 3

NaCN H /H O
Method # 2: R  Br  R  CN 

 RCO2H 2
Which of the following statement correctly describes this conversion
Br COOH
1) Both method 1 and method 2 are appropriate for carrying out this conversion.
2) Neither method 1 nor method 2 is appropriate for carrying out this conversion.
3) Method 1 will work well, but method 2 is not appropriate.
4) Method 2 will work well, but method 1 is not appropriate.
65. If Rutherford would have used   particles instead of   particles in his Gold-leaf
experiment, which of the following observations would definitely not have been
made:
1)   particles scattering beyond the gold foil.
2) Majority of   particles passing undeflected through the foil.
3) Very few   particles getting absorbed.
4) Particle nature of electron
66. Consider the following equilibria:
I. A  s  

 B s
II. 2A    

 B  


III. A  s 
 B  g
IV. A  g 

 B  g
Which of the above will not be disturbed by increase in pressure:

1) I and IV 2) I, II and IV
3) II, III and IV 4) IV only
67. CH3
HCl
OH  O C   X
CH3
[X] is:
CH3 CH3
1) HO C CH3 2) HO O C CH3
OH H
CH3 CH3
3) HO C C CH3 4) HO C OH
O OH CH3

68. When the following redox reaction is balanced using simplest ‘natural numbers’,
the stoichiometric coefficient of H2O will be:
Cr  OH3  IO3  OH I  CrO42  H2O
1) 2 2) 3
3) 5 4) it is impossible to balance this reaction
69. It is possible to liquefy a gas
1) at a temperature above critical temperature and at a pressure above critical
pressure.
2) at a temperature equal to critical temperature and at a pressure lower than
critical pressure.
3) at critical temperature and at a pressure equal to critical pressure
4) at a temperature above critical temperature and pressure below critical
pressure.
70. CHO
+ Acetonitrile
+ H2C = CH - PPh3 [X]
+
O Na
X is
OH
CH CH CH
CH3 CH CH2
(A)1) (B)2)
OH OH
CHO
(C)3) 4)
(D) CH CH2
..
O O
..
71. Number of hyperconjugation structure of following carbocation involving

C-H bonds
1) 3 2) 5 3) 6 4) 7

72. A reaction rate increases by a factor of 500 due to the presence of a catalyst at
37oC. If the reaction is carried out in presence of a catalyst at 127oC, by what
factor, compared to original rate in absence of catalyst at 27oC, the rate will
increase? Activation energy of original pathway is 106 kJ/mol
1) 5.05 × 10 – 6 2) 5.05 × 106
3) 5.05 4) 106
73. Which of the following is the most stable resonance structure
1) H2C CH C OH 2) H2 C CH C OH
CH CH
CHNH2 CHNH2
3) 4) H2C CH C OH
H2C CH C OH
CH
CH
CH
CHNH2
NH2
144 90
74. The number of neutrons accompanying the formation of 54 Xe and 38 Sr by the
absorption of a slow neutron by 92U235, followed by nuclear fission is:

1) 1 2) 2 3) 3 4) 4

75. CH3CHO(g) undergoes decomposition at very high temperature according to first
order parallel reactions:
k1
CH3CHO  g   CH4  g  CO  g
k2
CH3CHO  g   CH2CO  g  H2  g
The mol % of CH4 in the reaction mixture excluding CH3CHO would be:
50k1 100k1 150k1 200k1
1) k  k 2) k  k 3) k  k 4) k  k
1 2 1 2 1 2 1 2
76. Dimethyl terephthalate reacts with ethylene glycol under high temperature and
pressure to give a polymer called ‘Dacron’. Identify the correct statements out of
the following
(I) Dacron is polyethylene terphthalate
(II) Dacron is formed by step growth condensation polymerizations.
(III) Dacron is a polyester
(IV) Methanol molecules are removed during the polymerization process
1) Only (I) and (II) 2) Only (II), (III) and (IV)
3) Only (III) 4) All of the above
O
77.
H 3CO C H
+  Product

H C OCH3
O
Here, the product will be:
O O
1) H 2) H
C OCH3 C OCH3
C OCH3
C OCH3 H
H O
O
O
3) Both (A) and (B) in 4) H
C OH
equimolar ratio + CH3OH
C OH
H
O
78. Outline the best synthesis of 4, 4-dimethyl, 2-pentyne using NaNH2 in liquid NH3
also.
CH3 CH3
(i) CH3  CH (ii) (iii) (iv) CH3I (v) CH3  C  CBr
H3C C Br H3C C C CH
CH3
CH3
1) (i) + (ii) 2) (iii) + (v)

3) (iii) + (iv) 4) (ii) + (v)
79. Which of the following on treatment with CH  CH produce gas(es):
  
(i) NH2 (ii) C H3 (iii) OH (iv) Na in liq. NH3
1) (ii), (iii) and (iv) 2) (i), (ii) and (iii)
3) (i), (ii) and (iv) 4) (i), (iii) and (iv)
80. Which compound never exist
1) Iso-octane 2) Neo-pentane
3) Iso-propane 4) n-butane
81. Which of the following is the graphical representation of Aufbau principle
1) Pauling’s electro negativity scale
2) Bohr’s long form periodic table
3) Periodicity of ionisation potential
4) Stability of oxidation states of various elements
82. The false statement among the following when ionic compounds get dissolved in
water is
1) They involve heat changes
2) Inter ionic attraction is reduced due to solvation
3) Ions show dipole – ion attraction with water molecule
4) Anions are hydrated more than cation

83. Chemical ‘A’ is used for water softening to remove temporary hardness. ‘A’
reacts with sodium carbonate to generate caustic soda. When CO2 is bubbled
through ‘A’ it turns cloudy. What is the chemical formula of A?
1) CaCO3 2) Na2CO3. 10 H2O
3) Ca(OH)2 4) MgO
84. When aluminium chloride is dissolved in pure water the pH of the resulting
solution is not 7. This is best explained by :
1) Aluminium ions accept protons from water molecules leaving free OH- ions in
solution
2) Aluminium ions donate protons to water molecule forming H3O+ ions in
solution by taking OH- ions from water
3) Aluminium ions combine with water molecules to give complex [Al(H2O)6]3+
4) Chloride ions make the solution acidic
85. Which of the following statements is correct about silicon?
1) Forms molecular halides that are not hydrolyzed
2) Forms strong but unconjugated multiple bonds of the p -p variety,
especially with ‘O’ and ‘N’
3) Does not undergo coordination number expansion
4) Show more catenation power in halides than in hydrides
86. By green chemistry we mean
1) Producing chemicals of our daily use from green house gases
2) Performing chemical processes which are green plants
3) Performing only those reactions which are of biological origin
4) The use of non-toxic reagents and solvents to produce environmental friendly
products
87. The tendency to form complexes by actinides will be in the order
1) M 4  M 3  MO2 2  MO 2  2) MO2 2  MO2   M 4  M 3
3) M 4  MO2 2  M 3  MO2  4) MO2   MO2 2  M 3  M 4
88. Study the following thermo chemical equation at standard conditions:
A  B  100 kcal , B  C  80 kcal
The correct order of standard enthalpies of formation of A,B and C is
1) A<B<C 2) A<C<B 3) C<A<B 4) B<C<A

89. Carbon cannot reduce Fe2O3 to Fe at a temperature below 983k because
1) Free energy change for the formation of CO more negative than that of Fe2O3
2) CO is thermodynamically more stable than Fe2O3
3) Carbon has higher affinity towards oxygen than iron
4) Iron has higher affinity towards oxygen than carbon
90. In the formation of the dimer N2O4 from two molecules of NO2, the odd electron
on each of the nitrogen atoms of the NO2 molecules gets paired. In this process
` 1) Weak N-N bond is formed and all the four N-O bonds become equivalent
2) The ONO bond angle does not change appreciably (>10) before and after
dimerisation
3) All the atoms are in the same plane
4) All the above statements are correct

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GRAND TEST-6

Sri Chaitanya Narayana IIT Academy

Name of the Student: ___________________ I.D. NO:

Total syllabus + Extra syllabus

Total syllabus + Extra syllabus

Total syllabus + Extra syllabus

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 2

integral divisors of adj (5 AB ) equals

1) 140 2) 158 3) 165 4) 172

2. Sum of the last two digits in the value of 2999 equals

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 3

Then the minimum value of ( p m-ql)2+(bl-am)2+(aq- p b)2 equals

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 4

1) I>J 2) I<J 3) I+J=2 4) IJ=1

10. The shortest distance from (1,2,3) to the line x  y  z is

11. If the two lines x+2y+z-5=0=3x-y+z-4 and 2x  y  z  1  0   y  2z  5

are coplanar then the value of  equals

tangent to x-axis then its area equals

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 6

903 823 701 504

the variance of new marks is

1) 144 2) 169 3) 256 4) 327

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 8

minimum at x=2 then the smallest integral value of a equals

the circle x2+y2=25 is

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 9

belongs to the family of lines 1  3  x   2    y  2 1  3   0 equals

respectively and if n1  n2  k  220  than k=

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 10

horizontal surface as shown in figure. The coefficient of friction between the

1) The direction of friction on block A is towards right.

2) The direction of friction on block B may be towards left or right

3) Tension in the string must be zero

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 11

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 12

constant of the spring is 200 N/m, elongation in the spring is

1) 2cm 2) 4cm 3) 6cm 4) 8cm

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 13

38. The temperature at the bottom of a water pond of depth L is maintained at 4 C .

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 14

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 15

6 2r 0 m 2r 0 m 6r0 m r0 m

1) 0.8A 2) 0.25A 3) 1.95A 4) 0.05A

2BrV 4BrV 8BrV

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 17

force on the wire will be (y-axis is along vertical)

1) F  2B0i , upwards 2) F  2B0i , downwards

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 19

1) Ez  60 sin  0.5  103 x  1.5  1011 t  V / m

2) Ez  60 sin  0.5  103 x  1.5  1011 t  V / m

3) E y  60 sin  0.5  103 x  1.5  1011 t  V / m

4) E y  60 sin 0.5 103 x  1.5 1011 t  V / m

and  2 . The resonance angular frequency of this circuit must be

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 20

Sr.IPLCO_JEE-MAIN_Q.P space for rough work Page 21

insulating thread. Ultraviolet light of wavelength 0.2 µm strike on the sphere.

1) 4.6V 2) 6.2V 3) 1.6V 4) 3.2V

56. A radioactive isotope is being produced at a constant rate X. Half-life of the