Chapter # 4

MATERIAL AND
ENERGY BALANCE:
 MATERIAL AND ENERGY
BALANCE:

BASIS :
25°C of Temperature
1atm of pressure
FEED FLOW RATE = 9881kg/hr
 OVERALL MATERIAL AND ENERGY BALANCE:

46

STREAMS(kg/hr) IN OUT
1 (FEED) 9881 _

1-A (SOLVENT) 3006 _

5 (C-2 non aro) _ COMP. FEED3615

SOL. EXT. RAF.
(kg/hr) (1) (3) (2) (4)
24 (V-1 non aro) _ 4308

C6H6 1258 _ 1240 17

29 (BENZENE) _ 1193

C7H8 1613 _ 1589 23

36 (TOLUENE) _ 1554

C8H10 2130 _ 2088 43

43 (XYLENE) _ 1981

C9H12 492 _ 464 33

46 (C-8 BOT) _ 153

C6H14 884 _ 504 379

TOTAL 12887 12804
C7H16 1484 _ 266 1218

C8H18 1194 _ 0 1194

C9H20 826 _ 0 826

ACROSS EXTRACTOR:
SOLVEN _ 19860 18264 1596
T

OVERAL 9881 19860 24415 5331

T (°C) 25 100 90 90
P (atm) 1 0.51 0.68 1

H (kJ/hr) 0 3.2×106 2.5×106 5×105

ACROSS WATER WASH
 COMP. FEED WATER RAF EXT.
(kg/hr) (4) (7) (5) (6)

C6H6 18 _ 15 2

C7H8 24 _ 22 2

C8H10 44 _ 35 8

C9H12 34 _ 32 2

C6H14 379 _ 352 27

C7H16 1218 _ 1183 36

C8H18 1194 1163 31

C9H20 827 _ 810 17

SOLVEN 1596 _ 0 1596

T

WATER _ 0 1620

OVERALL 5334 _ 3615 3340

T(°C) 90 _ 72 61

P(atm) 1 _ 1 _

H(kJ/hr) 5×10 2.15×10 3.1×10 3.8×10

5 5 5 5

ACROSS STRIPPER
COMP. FEED (8+9) BOT. O-H
(kg/hr) (14) (12)

C6H6 1240 1171 69

C7H8 1589 1559 30

C8H10 2086 2059 26

C9H12 464 458 6

C6H14 504 86 503

C7H16 266 2 264

SOLVENT 20256 20040 168

OVERALL 26406 25291 1068

T(°C) 121 178 121

P(atm) 42 1.7 1.4

H(kJ/hr) 2.5×105 2.9×106 2.5×105

ENTHALPY OF (9+8) + REBOILER DUTY ~ENTHALPY OF (14+12) + CONDENSER

DUTY

5.2×106 + 2.6×105 ~ 3.15×106 + 2.25×106

RECOVERY COLUMN
 RECOVERY COLUMN RECEIVER
COMP FEED STEAM(17 O-H BOT.
(kg/hr) (14) ) (15) (18)

COMP. FEED BOT.

C6H6 1171 _ TOP. 117 0
(kg/hr) (22) (21) (7) 1
C7H8 1159 _ 115 0
C6H6 1171 1171 0 9
C8H10 2059 _ 201 48
C7H8 1559 1559 0 2
C9H12 458 _ 149 309
C8H10 2008 2008 0
SOLVEN 2013 _ 0 2013
C9H12 148 T 148 6 0 6

STEAM 1620 STEAM _ 1843 1620 162 25

OVERALL 6509 4889

OVERAL 2498 1843 0 611 2051
L 6 1 8
T(°C) 50 50 50
T(°C) 178 _ 184 145
P(atm) _ _ _
P(atm) 1.7 _ _ 1.5
H(kJ/hr) 2.2×105 -_ _-
H(kJ/hr) _ _ _ _
WATER STRIPPER
COMP. FEED O-H BOT. (17)
(kg/hr) (6) (13)

C6H6 2 2 0

C7H8 1.8 1.8 0

C8H10 8.4 8.4 0

C9H12 2.4 2.4 0

C6H14 26 0

C7H16 26 35 0
35
C8H18 30 30 0

C9H20 16 16 0

SOLVENT 1764 84 1680

WATER 1764 140 1620

OVERALL 3652 348 3300

T(°C) 61 110 145

P(atm) _ 1.2 1.5

H(kJ/hr) 3.8×105 5.7×104 5.1×106

 ENTHALPY OF (6+25) + REBOILER DUTY ~ENTHALPY OF (13+18+17)
5.92 ×106 ~ 5.91×106

BENZENE COLUMN COMP. FEED O-H BOT.

(kg/hr) (20) (29) (32)

C6H6 1171 1171 0

C7H8 1559 22 1528

C8H10 2008 0 2008

C9H12 1488 0 1488

OVERAL 4908 1193 3705

T(°C) 50 85 145

P(atm) 1.5 1 1.2

H(kJ/hr) 1.8×105 3.3×104 1.06×105

ENTHALPY OF (20) + REBOILER DUTY ~ENTHALPY OF (27+32)+COND. DUTY

5.78×106 ~ 5.76×106
 TOLUENE COLUMN
COMP. FEED O-H BOT.
(kg/hr) (32) (36) (39)

C7H8 1528 1528 0

C8H10 2011 26 1985

C9H12 148 0 148

OVERALL 2134

T(°C) 145 1554 160

P(atm) 1.2 1.2 _

H(kJ/hr) 1.06×105 2.2×105 3×105

ENTHALPY OF (32) + REBOILER DUTY ~ENTHALPY OF (34+39)+COND. DUTY

8.86×105 ~ 8.85×105

XYLENE COLUMN
 COMP. FEED O-H BOT.
(kg/hr) (39) (43) (46)

C8H10 1985 1977 8

C9H12 149 4 145

OVERALL 2134 1981 153

T(°C) 160 139 175

P(atm) _ _ 1

H(kJ/hr) 3×105 5.2×105 2.7×105

ENTHALPY OF (39) + REBOILER DUTY ~ENTHALPY OF (41+46)+COND. DUTY

9.5×105 ~ 9.48×105