Alumno: Cruz, Matías Nicolás Reg.

:29073

5. PROBLEMA
Construir el diagrama de Kellogg para el sistema Cu-S-O, para 700 y 900 °K.

1
Alumno: Cruz, Matías Nicolás Reg.:29073

Desarrollo: para 900°K

1.
2𝐶𝑢𝑆 + 𝑂2 ↔ 𝐶𝑢2 𝑆 + 𝑆𝑂2
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 17,599
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,736
(𝑎𝑆𝑂2 ) ∗ (𝑎𝐶𝑢2𝑆 )
𝐾=
(𝑎𝐶𝑢𝑆 )2 ∗ (𝑎𝑂2 )

(𝑝𝑆𝑂2 )
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
𝐾 log 𝐾 = log 𝑝𝑆𝑂2 − log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = log 𝑝𝑂2 − 0,133

2.
𝐶𝑢2 𝑆 + 𝑂2 ↔ 2𝐶𝑢0 + 𝑆𝑂2
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 11,167
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,823
(𝑎𝑆𝑂2 ) ∗ (𝑎𝐶𝑢0 )2
𝐾=
(𝑎𝐶𝑢2𝑆 ) ∗ (𝑎𝑂2 )

(𝑝𝑆𝑂2 )
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = log 𝑝𝑆𝑂2 − log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = log 𝑝𝑂2 − 0,084

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Alumno: Cruz, Matías Nicolás Reg.:29073

3.
4𝐶𝑢0 + 𝑂2 ↔ 2𝐶𝑢2 𝑂
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 12,312
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,807
(𝑎𝐶𝑢2𝑆 )2
𝐾=
(𝑎𝐶𝑢0 )4 ∗ (𝑎𝑂2 )
1
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = − log 𝑝𝑂2
∴ log 𝑝𝑂2 = 0,093

4.
2𝐶𝑢2 𝑂 + 𝑂2 ↔ 4𝐶𝑢𝑂
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 5,268
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,912
(𝑎𝐶𝑢𝑂 )4
𝐾=
(𝑎𝐶𝑢2𝑆 )2 ∗ (𝑎𝑂2 )
1
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = − log 𝑝𝑂2
∴ log 𝑝𝑂2 = 0,040

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Alumno: Cruz, Matías Nicolás Reg.:29073

5.
2𝐶𝑢2 𝑆 + 3𝑂2 ↔ 2𝐶𝑢2 𝑂 + 2𝑆𝑂2
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 34,646
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,547
2
(𝑎𝑆𝑂2 ) ∗ (𝑎𝐶𝑢2𝑂 )2
𝐾=
(𝑎𝐶𝑢2𝑆 )2 ∗ (𝑎𝑂2 )3
2
(𝑝𝑆𝑂2 )
𝐾=
(𝑝𝑂2 )3
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = 2 ∗ log 𝑝𝑆𝑂2 − 3 ∗ log 𝑝𝑂2
3
∴ log 𝑝𝑆𝑂2 = log 𝑝𝑂2 − 0,131
2

6.
4𝐶𝑢𝑂 + 2𝑆𝑂2 + 𝑂2 ↔ 2𝐶𝑢𝑂 ∗ 𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 8,254
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,866
(𝑎𝐶𝑢𝑂∗𝐶𝑢𝑆𝑂4 )2
𝐾= 2
(𝑎𝐶𝑢𝑂 )4 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )
1
𝐾= 2
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −2 ∗ log 𝑝𝑆𝑂2 − log 𝑝𝑂2
1
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,031
2

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Alumno: Cruz, Matías Nicolás Reg.:29073

7.
2𝐶𝑢𝑂 ∗ 𝐶𝑢𝑆𝑂4 + 2𝑆𝑂2 + 𝑂2 ↔ 4𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 6,902
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,887
(𝑎𝐶𝑢𝑆𝑂4 )4
𝐾= 2
(𝑎𝐶𝑢𝑂∗𝐶𝑢𝑆𝑂4 )2 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )
1
𝐾= 2
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −2 ∗ log 𝑝𝑆𝑂2 − log 𝑝𝑂2
1
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,026
2

8.
2𝐶𝑢2 𝑂 + 2𝑆𝑂2 + 𝑂2 ↔ 2𝐶𝑢𝑂 ∗ 𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 13,522
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,790
(𝑎𝐶𝑢𝑂∗𝐶𝑢𝑆𝑂4 )2
𝐾= 2
(𝑎𝐶𝑢2𝑂 )2 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )2
1
𝐾= 2
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )2
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −2 ∗ log 𝑝𝑆𝑂2 − 2 ∗ log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,051

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Alumno: Cruz, Matías Nicolás Reg.:29073

9.
2𝐶𝑢2 𝑂 + 4𝑆𝑂2 + 3𝑂2 ↔ 4𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 20,424
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,701
(𝑎𝐶𝑢𝑆𝑂4 )4
𝐾= 4
(𝑎𝐶𝑢2𝑂 )2 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )3
1
𝐾= 4
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )3
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −4 ∗ log 𝑝𝑆𝑂2 − 3 ∗ log 𝑝𝑂2
3
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,039
4

10.
𝐶𝑢2 𝑆 + 𝑆𝑂2 + 3𝑂2 ↔ 2𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 27,535
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,619
(𝑎𝐶𝑢𝑆𝑂4 )2
𝐾=
(𝑎𝐶𝑢2𝑆 ) ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )3
1
𝐾=
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )3
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = − log 𝑝𝑆𝑂2 − 3 ∗ log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = − 3 log 𝑝𝑂2 + 0,208

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Alumno: Cruz, Matías Nicolás Reg.:29073

Desarrollo: para 700°K

1.
2𝐶𝑢𝑆 + 𝑂2 ↔ 𝐶𝑢2 𝑆 + 𝑆𝑂2
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 22,163
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,680
(𝑎𝑆𝑂2 ) ∗ (𝑎𝐶𝑢2𝑆 )
𝐾=
(𝑎𝐶𝑢𝑆 )2 ∗ (𝑎𝑂2 )

(𝑝𝑆𝑂2 )
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
𝐾 log 𝐾 = log 𝑝𝑆𝑂2 − log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = log 𝑝𝑂2 − 0,168

2.
𝐶𝑢2 𝑆 + 𝑂2 ↔ 2𝐶𝑢0 + 𝑆𝑂2
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 13,821
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,786
(𝑎𝑆𝑂2 ) ∗ (𝑎𝐶𝑢0 )2
𝐾=
(𝑎𝐶𝑢2𝑆 ) ∗ (𝑎𝑂2 )

(𝑝𝑆𝑂2 )
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = log 𝑝𝑆𝑂2 − log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = log 𝑝𝑂2 − 0,105

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Alumno: Cruz, Matías Nicolás Reg.:29073

3.
4𝐶𝑢0 + 𝑂2 ↔ 2𝐶𝑢2 𝑂
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 16,172
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,754
(𝑎𝐶𝑢2𝑆 )2
𝐾=
(𝑎𝐶𝑢0 )4 ∗ (𝑎𝑂2 )
1
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = − log 𝑝𝑂2
∴ log 𝑝𝑂2 = 0,122

4.
2𝐶𝑢2 𝑂 + 𝑂2 ↔ 4𝐶𝑢𝑂
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 8,508
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,862
(𝑎𝐶𝑢𝑂 )4
𝐾=
(𝑎𝐶𝑢2𝑆 )2 ∗ (𝑎𝑂2 )
1
𝐾=
(𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = − log 𝑝𝑂2
∴ log 𝑝𝑂2 = 0,064

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Alumno: Cruz, Matías Nicolás Reg.:29073

5.
2𝐶𝑢2 𝑆 + 3𝑂2 ↔ 2𝐶𝑢2 𝑂 + 2𝑆𝑂2
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 43,814
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,466
2
(𝑎𝑆𝑂2 ) ∗ (𝑎𝐶𝑢2𝑂 )2
𝐾=
(𝑎𝐶𝑢2𝑆 )2 ∗ (𝑎𝑂2 )3
2
(𝑝𝑆𝑂2 )
𝐾=
(𝑝𝑂2 )3
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = 2 ∗ log 𝑝𝑆𝑂2 − 3 ∗ log 𝑝𝑂2
3
∴ log 𝑝𝑆𝑂2 = log 𝑝𝑂2 − 0,166
2

6.
4𝐶𝑢𝑂 + 2𝑆𝑂2 + 𝑂2 ↔ 2𝐶𝑢𝑂 ∗ 𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 15,224
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,767
(𝑎𝐶𝑢𝑂∗𝐶𝑢𝑆𝑂4 )2
𝐾= 2
(𝑎𝐶𝑢𝑂 )4 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )
1
𝐾= 2
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −2 ∗ log 𝑝𝑆𝑂2 − log 𝑝𝑂2
1
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,057
2

9
Alumno: Cruz, Matías Nicolás Reg.:29073

7.
2𝐶𝑢𝑂 ∗ 𝐶𝑢𝑆𝑂4 + 2𝑆𝑂2 + 𝑂2 ↔ 4𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 13,964
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,784
(𝑎𝐶𝑢𝑆𝑂4 )4
𝐾= 2
(𝑎𝐶𝑢𝑂∗𝐶𝑢𝑆𝑂4 )2 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )
1
𝐾= 2
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −2 ∗ log 𝑝𝑆𝑂2 − log 𝑝𝑂2
1
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,053
2

8.
2𝐶𝑢2 𝑂 + 2𝑆𝑂2 + 𝑂2 ↔ 2𝐶𝑢𝑂 ∗ 𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 23,732
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,661
(𝑎𝐶𝑢𝑂∗𝐶𝑢𝑆𝑂4 )2
𝐾= 2
(𝑎𝐶𝑢2𝑂 )2 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )2
1
𝐾= 2
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )2
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −2 ∗ log 𝑝𝑆𝑂2 − 2 ∗ log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,090

10
Alumno: Cruz, Matías Nicolás Reg.:29073

9.
2𝐶𝑢2 𝑂 + 4𝑆𝑂2 + 3𝑂2 ↔ 4𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 37,696
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,519
(𝑎𝐶𝑢𝑆𝑂4 )4
𝐾= 4
(𝑎𝐶𝑢2𝑂 )2 ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )3
1
𝐾= 4
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )3
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = −4 ∗ log 𝑝𝑆𝑂2 − 3 ∗ log 𝑝𝑂2
3
∴ log 𝑝𝑆𝑂2 = − log 𝑝𝑂2 + 0,071
4

10.
𝐶𝑢2 𝑆 + 𝑆𝑂2 + 3𝑂2 ↔ 2𝐶𝑢𝑆𝑂4
0 0
∆𝐺𝑟0 = 𝛴𝑚∆𝐺𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚∆𝐺𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 = 40,755
∆𝐺 0
− 𝑟
𝐾= 𝑒 𝑅∗𝑇 = 0,492
(𝑎𝐶𝑢𝑆𝑂4 )2
𝐾=
(𝑎𝐶𝑢2𝑆 ) ∗ (𝑎𝑆𝑂2 ) ∗ (𝑎𝑂2 )3
1
𝐾=
(𝑝𝑆𝑂2 ) ∗ (𝑝𝑂2 )3
log 𝐾 = 𝛴𝑚 log 𝐾𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − 𝛴𝑚 log 𝐾𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
log 𝐾 = − log 𝑝𝑆𝑂2 − 3 ∗ log 𝑝𝑂2
∴ log 𝑝𝑆𝑂2 = − 3 log 𝑝𝑂2 + 0,308

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