2.

0 STUDENT 1: MASS BALANCE

Overall mass balance

Stoichiometric Equation;

ClCH2CH2Cl CH2CHCl + HCl

A B+C

Where;
Element A: ClCH2CH2Cl with (Molecular Weight = 98.96 g/mol)
Element B: CH2CHCl with (Molecular Weight = 62.50 g/mol)
Element C: HCl with (Molecular Weight = 36.46 g/mol)

Given;
Production Rate : 100000 lbm/year
ṁB : 5384.53 g/hr
ṁC : 5236.97 g/hr
Temperature : 500oC
Conversion : 60% (0.60)
Assuming working days in a year : 351 days

Mass Balance Table

Table 1.0: Mass Balance Table
Types of species Inlet (g/hr) Outlet (g/hr)
A 14209.71 5683.89
B - 5384.64
C - 3141.19
Total 14209.71 14209.71
 The production rate for vinyl chloride production was given at 100,000 lbm/year.
Calculation was made based on the change of species mass flowrate if the production rate
increased from 0% to 100%. A graph was plotted for each specific mass increment.

Table 2.1 Increment Table for Each Species Mass Flowrate.

Increment Production Mass Flowrate A Mass Flowrate B Mass Flowrate C
(%) Rate (g/hr) (g/hr) (g/hr)
(lbm/year)
Inlet Outlet Inlet Outlet Inlet Outlet
0 100000 14209.71 5683.89 - 5384.53 - 3141.19
20 120000 17051.31 6820.52 - 6461.44 - 3769.35
40 140000 19893.29 7957.27 - 7538.34 - 4397.57
60 160000 22735.07 9094.03 - 8615.25 - 5025.79
80 180000 25576.96 10230.78 - 9692.19 - 5654.02
100 200000 28418.83 11367.53 - 10769.0 - 6282.24
6
 mass flowrate against production rate increment for each species inlet and outlet
250000 30000
28418.83

25576.96
25000
200000
200000
22735.07
180000
Production Rate per year (lbm/year)

19893.29
160000 20000

Mass Flowrate(g/hr)
150000 17051.31 140000

14209.71 120000 15000

100000
100000
10769.06
11367.53
9692.19
10230.78 10000
8615.25
9094.03
7538.34
7957.27
6461.44
6820.52 6282.24
5384.53
50000 5654.02
5683.89 5025.79
4397.57 5000
3769.35
3141.19

0 0
0 20 40 60 80 100

production rate per yearProduction RateA Increment

Outlet (%) C
Outlet Outlet B Inlet A

Figure 1.0 shows a graph of Mass Flowrate against Production Rate Increment for Each Species Inlet and Outlet was plotted.
Increment Tables for 20%,40%,60%,80% and 100% from Production Rate

Table 2.2 shows the increment of 20% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 17051.31 6820.52
B - 6461.44
C - 3769.35
Total 17051.31 17051.31

Table 2.3 shows the increment of 40% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 19893.29 7957.27
B - 7538.34
C - 4397.57
Total 19893.29 19893.29

Table 2.4 shows the increment of 60% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 22735.07 9094.03
B - 8615.25
C - 5025.79
Total 22735.07 22735.07

Table 2.5 shows the increment of 80% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 25576.96 10230.78
B - 9692.19
C - 5654.02
Total 25576.96 25576.96

Table 2.6 shows the increment of 100% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 28418.83 11367.53
B - 10769.06
C - 6282.24
Total 28418.83 28418.83
STUDENT 1: MASS BALANCE

Mass Flowrate from The Production Rate of Vinyl Chloride:

lbm 1kg 1000 g 1 yr 1day
100000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 5384.53 g/hour

Species Inlet (g/hr) Outlet (g/hr)

 FB  FA0 X FA  FA0 (1  X )
86.15428 mol FA  143.59047 mol  (1  0.6)
FA0  hr hr
0.60 FA  57.436188 mol
A hr
FA0  143.59047 mol
hr 
g

g m  57.436188 mol hr  98.96 mol
m  143.59047 mol hr  98.96 mol 
g

g m  5683.89 hr
m  14209.71 hr
FB 0  0 mol 5384.53
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  86.15428 mol
hr

g
m  86.15428 mol hr  62.5 mol

g
m  5384.64 hr
FC 0  0 mol FC  FA0 X
hr
 FC  143.59047 mol  0.6
hr
m  FC 0  M m
 FC  86.15428 mol
hr
C
m  0g
hr 
g
m  86.15428 mol hr  36.46 mol

g
m  3141.19 hr
Total 14209.71 14209.71
Increment of 20%
lbm 1kg 1000 g 1 yr 1day
120000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 6461.44 g/hour

Species Inlet (g/hr) Outlet (g/hr)

FB  FA0 X FA  FA0 (1  X )
103.38304 mol FA  172.30507 mol  (1  0.6)
FA0  hr hr
0.60 FA  68.92203 mol
A hr
FA0  172.30507 mol
hr 
g

g m  68.92203 mol hr  98.96 mol
m  172.30507 mol hr  98.96 mol 
g

g m  6820.52 hr
m  17051.31 hr
FB 0  0 mol 6461.44
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  103.38304 mol
hr

g
m  103.38304 mol hr  62.5 mol

g
m  6461.44 hr
FC 0  0 mol FC  FA0 X
hr
 FC  172.30507 mol  0.6
hr
m  FC 0  M m
 FC  103.38304 mol
hr
C
m  0g
hr 
g
m  103.38304 mol hr  36.46 mol

g
m  3769.35 hr
Total 17051.31 17051.31
Increment of 40%
lbm 1kg 1000 g 1 yr 1day
140000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 7538.3437 g/hour

Species Inlet (g/hr) Outlet (g/hr)

FB  FA0 X FA  FA0 (1  X )
120.6135 mol FA  201.0225 mol  (1  0.6)
FA0  hr hr
0.60 FA  80.409 mol
A hr
FA0  201.0225 mol
hr 
g

g m  80.409 mol hr  98.96 mol
m  201.0225 mol hr  98.96 mol 
g

g m  7957.27 hr
m  19893.19 hr
FB 0  0 mol 7538.3437
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  120.6135 mol
hr

g
m  120.6135 mol hr  62.5 mol

g
m  7538.34 hr
FC 0  0 mol FC  FA0 X
hr
 FC  201.0225 mol  0.6
hr
m  FC 0  M m
 FC  120.6135 mol
hr
C
m  0g
hr 
g
m  120.6135 mol hr  36.46 mol

g
m  4397.57 hr
Total 19893.19 19893.19
Increment of 60%
lbm 1kg 1000 g 1 yr 1day
160000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 8615.25 g/hour

Species Inlet (g/hr) Outlet (g/hr)

FB  FA0 X FA  FA0 (1  X )
137.8440 mol FA  229.74 mol  (1  0.6)
FA0  hr hr
0.60 FA  91.896 mol
A hr
FA0  229.74 mol
hr 
g

g m  91.896 mol hr  98.96 mol
m  229.74 mol hr  98.96 mol 
g

g m  9094.03 hr
m  22735.07 hr
FB 0  0 mol 8615.25
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  137.844 mol
hr

g
m  137.844 mol hr  62.5 mol

g
m  8615.25 hr
FC 0  0 mol FC  FA0 X
hr
 FC  229.74 mol  0.6
hr
m  FC 0  M m
 FC  137.844 mol
C g hr
m0 hr 
g
m  137.844 mol hr  36.46 mol

g
m  5025.79 hr
Total 22735.07 22735.07
Increment of 80%
lbm 1kg 1000 g 1 yr 1day
180000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 9692.15619 g/hour

Species Inlet (g/hr) Outlet (g/hr)

FB  FA0 X FA  FA0 (1  X )
155.075 mol FA  258.4575 mol  (1  0.6)
FA0  hr hr
0.60 FA  103.383 mol
A hr
FA0  258.4575 mol
hr 
g

g m  103.383 mol hr  98.96 mol
m  258.4575 mol hr  98.96 mol 
g

g m  10230.78 hr
m  25576.96 hr
FB 0  0 mol 9692.15619
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  155.075 mol
hr

g
m  155.075 mol hr  62.5 mol

g
m  9692.19 hr
FC 0  0 mol FC  FA0 X
hr
 FC  258.4575 mol  0.6
hr
m  FC 0  M m
 FC  155.075 mol
hr
C
m  0g
hr 
g
m  155.075 mol hr  36.46 mol

g
m  5654.02 hr
Total 25576.95 25576.95
Increment of 100%
lbm 1kg 1000 g 1yr 1day
200000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 10769.06 g/hour

Species Inlet (g/hr) Outlet (g/hr)

FB  FA0 X FA  FA0 (1  X )
172.30496 mol FA  287.17493 mol  (1  0.6)
FA0  hr hr
0.60 FA  114 .86997 mol
A hr
FA0  287.17493 mol
hr 
g
 m  114 .86997 mol hr  98.96 mol
m  287.17493 mol hr  98.96 g
mol 
g

g m  11367 .53 hr
m  28418.83 hr
FB 0  0 mol 10769.06
g
hr
 FB  hr
g
mF B0  Mm 62.5
 mol
B g
m0 hr FB  172.30496 mol
hr

g
m  172.30496 mol hr  62.5 mol

g
m  10769.06 hr
FC 0  0 mol FC  FA0 X
hr
 FC  287.17493 mol  0.6
hr
mF C0  Mm
 FC  172.30496 mol
hr
C
m  0g
hr 
g
m  172.30496 mol hr  36.46 mol

g
m  6282.24 hr
Total 28418.83 28418.83