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Tappi 2006 Vol.5no.3p.15-20
Tappi 2006 Vol.5no.3p.15-20
ABSTRACT: A calculation procedure was developed for a rotary drum vacuum filter used in brownstock
washing. In the model of a rotary drum vacuum filter, brownstock washing is split into a set of basic unit
operations. These operations are described, combining mass balance equations with constant-pressure
filtration equations. This set of equations is solved using the system/engineering methodology. The results
for a typical rotary drum vacuum filter are presented.
Application: A computer program using these calculations will facilitate the management of brownstock
washing operations.
rownstock washing is the pulping Several studies have dealt with the sci- phenomena could be introduced as sug-
B process operation in which the
organic and inorganic substances dis-
entific fundamentals of brownstock
washing [2–9]. The knowledge devel-
gested by Cullinan [7].
The RDVF process was split into a set
solved in the black liquor are removed oped in these examples has enabled engi- of basic unit operations, as proposed by
from the cellulose pulp. The pulp is neers to design improved filtering equip- Edwards [8]. Mass balances and specific
decontaminated of those substances, the ment. However, there have been very few RDVF equations were applied to these
valuable inorganic chemicals are recov- studies aimed at aiding process managers unit operations, providing a set of equa-
ered, and the organic material is burned in their daily routine. In Brazil, which is a tions that describe the entire RDVF
in the recovery steam boiler. major producer of pulp and paper, this operation.
Brownstock washing is one of the type of knowledge is essential to improv- We treated this set of equations by the
most important operations in the pulping ing operational efficiency, a requirement system/engineering analysis as proposed
process [1]. Efficient washing requires for maintaining competitiveness in this by Barton [10,11].The purpose was to set
accurate control of the amount of wash- market. the values of all variables available to the
ing fluid. Greater quantities of washing Our objective was to develop a practi- brownstock washing manager for per-
fluid result in cleaner pulp but lead to cal calculation procedure in the form of a forming the operational RDVF diagnostic.
higher steam consumption in the evapo- computer program. This program would Basic unit operations for RDVF
rator system. Lower quantities of washing Figure 1 is a diagram of the main streams
fluid result in lower energy consumption Unwashed Pulp Washed Pulp of an RDVF. The entering streams are
in the black liquor concentration but Washer unwashed pulp and wash liquor, and the
entail a greater expenditure of bleaching exiting streams are washed pulp and
chemicals. In short, efficient brownstock Black Liquor Wash Liquor black liquor.
washing contributes to greater energy 1. The main streams of a rotary drum Figure 2 illustrates the division of the
conservation, decreased water usage, and vacuum filter. RDVF process into six basic unit opera-
lower expenditure of chemicals. It also tions.The feed suspension (1) is diluted in
helps to limit the discharge of polluting furnish brownstock washing managers a mixing tank that feeds (2) the suspen-
effluents. with information complementary to that sion trough of the RDVF with pulp of a
A brownstock washing set uses a series available on the instrument panel and to specific consistency.
of filters through which the filtrate flows that obtained through chemical analysis. In the cake formation zone, the liquid
countercurrent to the brownstock being phase (5) is separated from the cake (4).
washed. The rotary drum vacuum filter In the washing zone, the washing fluid (7)
(RDVF) is one of the earliest filtering sys- METHODOLOGY
is sprayed over the cake, resulting in a
tems and is still in use in many pulping Overview
washed cake (6) and contaminated wash-
plants. In brief, a perforated drum rotates In early studies [7–9], the brownstock
washing operation was described using a ing fluid (8).
partially immersed in the pulp suspen-
mass balance approach to correlate In the cake dewatering zone, the
sion. Its surface is covered with a filter
medium, over which the cake is formed brownstock washing variables. Our study washed cake is dried into a dried cake (9).
by the effect of a vacuum applied within complements those earlier studies by The liquid removed (10) is drained into
the drum.A set of sprinklers disperse the including the variables and equations the sewage tank, where two of the other
washing fluid over the cake surface to that describe the macroscopic behavior streams (5 and 8) are also collected.At the
wash the pulp. The cake is finally dis- of the RDVF. In a subsequent step, micro- split, Stream 11 is divided into a recycling
charged when the vacuum is interrupted. scopic aspects related to mass transport stream (3) and an outlet stream (12).
VOL. 5: NO. 3 TAPPI JOURNAL 15
BROWNSTOCK WASHING
Operational Conditions
(18) (25) Dilution factor, DF
Fiber consistency at system inlet, SSP1
Fiber consistency at system outlet, SSP9
(19) (26) Solids at system inlet, XS1
Solids at washing fluid inlet, XS7
Angular velocity of the filter’s drum, ω
(20) (27) Cake Formation Zone
Cake humidity, FWS
Pressure drop, ΔPC
(21) Filter media resistance, RMF
(28)
Fiber consistency in the suspension
trough, SSP2
(22)
Specific cake resistance, α
(29) Filtrate viscosity in Stream 5, μ5
Filtrate density in Stream 5, ρ5
(23) Washing Zone
(30)
Fluid density in Stream 8, ρ8
(24) In the RDVF, the washing area AL is different RDVF Geometry
from cake formation area AF, requiring that Filtration area, AF
Eqs. 22 and 23 connect cake formation zone
parameters with mass balances variables. Eq.
the coefficients KCL and KMFL be adjusted for Filtration sector angle, θF
24 connects WP4 with the ratio of wet cake this in Eqs. 28 and 29. Eq. 30 connects the
Washing sector angle, θL
mass to dry cake mass (FWS). washing time and washing fluid volume with
mass balance variables. Local Washing Efficiency
II. Equations for the cake formation xF factor
III. Equations for the washing zone.
zone.
IV. Subcategories for the five major
Fourth, the quantity of solids (MW5XS5
where E = ∞ corresponds to the plug and MW8XS8) in Streams 5 and 8 is consid- categories.
flow model applied to the black box, and ered negligible when compared with the
E = 1 corresponds to the perfect mixture WP4 = FWS − 1 (51)
amount of water (MW5 and MW8).
model applied to the black box. Therefore, Eqs. 22 and 30 can be simpli- Finally, the specific cake resistance (α)
Note that RD, Y, and E are parameters fied to Eq. 42 and 43: is assumed to be determined experimen-
defined for the overall system and that YL
V tally by the Leaf Test Procedure [15].
and xF are defined for the washing unit M W 5 = ρ5 F For compressible cellulose pulp cakes,
only. tF (42)
this value could be estimated for several
Assumptions of the calculation filtering pressures using the equation
VL
procedure M W 8 = ρ8 proposed by Reynol [16]:
A number of assumptions were made in tL (43)
this version of the calculation procedure. α = 7.76•105 ΔPC0.77 (52)
Fifth, the following equalities hold:
First, we assume there is no loss of cel-
lulose pulp in the basic RDVF unit oper- XS4 = XS2 (44) SYSTEM/ENGINEERING
ations.Therefore, the fraction of pulp lost ANALYSIS
in each case is equal to zero, or f1 = f2 = XS5 = XS2 (45) The set of equations can be managed
f3 = f4 = 0. using the system/engineering analysis
Second, the pressure drop in the
XS9 = XS6 (46) method [10,11] to obtain the desired cal-
washing zone (ΔPL) is assumed to be the XS10 = XS6 culation procedure. The procedure is
same as that in the cake formation zone (47) obtained through the following steps.
(ΔPF): XS11 = XS3 1. Determine the degrees of freedom.
(48)
Number of variables at the set of equa-
ΔPL = ΔPF (40) tions = 61. Number of independent equa-
XS12 = XS3 (49)
Third, the amount of solids in Stream tions = 43. Degrees of freedom = 61 – 43
Sixth, since the value of XSi is very = 18 (design variables).
4 (MP4WP4XS4) is considered negligible
small in comparison to the value of WPi, 2. Select the design variables. These
when compared with the amount of cel-
Eqs. 1 and 24 can be simplified to Eq. 50 18 variables were chosen by the follow-
lulose pulp (MP4). Therefore, Eq. 23 can
and 51: ing major categories: operational condi-
be simplified to Eq. 41:
1 − SSPi tions, cake formation zone, washing
S SP 2 ρ 5 VF W Pi = zone, RDVF geometry, and local washing
M P4 = S SPi (50)
(1− S SP 2 FWS ) t F (41) efficiency. Subcategories are listed in
Table IV.
1.0
DISPLACEMENT RATIO, DR
100 0.5
XSi
As Fig. 5 shows, the loss in washing practical calculation procedure in the
0.003
DF = 2
(1 – Y) is related strongly to the xF factor. form of a computer program that could 0.002 DF = 3
At xF = 1, washing system efficiency is be a useful tool in the management of DF = 4
high but limited by the concentration of 0.001 DF = 5
the brownstock washing operation. DF = 6
washing liquid used. In our case, XS7 = We plan to present a detailed application 0
1 2 4 6 9
0.0005. For the perfect mixture model of this calculation procedure in the near INDEX I
(xF = 0), washing system efficiency is future. TJ
lower and depends on the DF. 6. Ratio between the mass of soluble
Figure 6 presents the concentration solids and the mass of water in the
ACKNOWLEDGEMENT
of solids (XSi) in the pulp stream in the suspension (XSi), by dilution factor,
The authors would like to thank the
different steps of the system, assuming xF for the pulp stream for the system
Brazilian Conselho Nacional de
= 0.7, XS1 = 0.005, and XS7 = 0.0005. depicted in Fig. 2. (The index I corre-
Desenvolvimento Científico e
The results illustrate that the dilution
Tecnológico (CNPq, Council for sponds to the stream number.)
unit is as important as the washing unit
Scientific and Technological
in determining the system efficiency. 4. Kukreja, V.K., Ray, A.K., and Singh,
Development) for partially funding this
study (Grant No. 131359/03-7). We are V.P., Indian J. Chem. Tech. 5(3):
CONCLUSIONS also grateful to the staff of Papel Ripasa 276(1998).
A calculation procedure is presented for 5. Hagen, N., and Berg, J.E., Tappi J.
S.A. for their assistance with the RDVF 72(6): 93(1989).
rotary drum vacuum filters used in data.
brownstock washing. The RDVF opera- 6. Kovasin, K., Norden, H.V., and
tion is split into basic steps that repre- Ahonen, L., Filtration & Separation
LITERATURE CITED 25(1): 42(1988).
sent unit operations. These unit opera- 1. Rogers, J., Funo, P., and Nery, J., 7. Cullinan, H.T., Tappi J. 69(8):
tions are modeled by the mass balances 1995 Congresso Anual de Celulose 90(1986).
and the fundamental equations of the e Papel na ABTCP, Vol. 28, ABTCP, 8. Edwards, L., Peyron, M., and
classical filtration theory.This set of equa- São Paulo, Brazil, p. 179. Minton, M., Pulp Paper Can. 87(1):
tions was solved using the system/engi- 2. Kovasin, K., “Modeling ultrafiltra- T17(1986).
neering analysis methodology. By provid- tion and filtration phenomena 9. Hakamaki, H., and Kovasin, K.,
ing insight about each unit operation, the applied in chemical pulping Pulp Paper Can. 86(9): T243(1985).
procedure enables the macroscopic processes,” Ph.D. thesis, Dept. of 10. Barton, P.I., “Structural analysis of
analyses of the overall system operation. Chemical Technology, Helsinki systems of equations,” lectures
University of Technology, Helsinki, notes, Dept. of Chemical
The xF parameter is useful in defining
2003. Engineering, MIT, Cambridge,
the efficiency of the washing operation 3. Kukreja, V.K., Ray, A.K., Singh, V.P., 1995.
in isolation, independent of the other et al., “Evaluation of filtration rates 11. Barton, P.I., “Modeling and analy-
operations. There are correlations of continuous filters,” IPPTA sis of systems from physical prin-
between xF and the commonly used Convention Issue, Ind. Pulp Paper ciples,” lectures notes, Dept. of
parameters (DF, DR, 1 – Y, and Norden Tech. Assoc., CPPRI, Saharanpur, Chemical Engineering, MIT,
E). The relationships between xF and 1994, p. 41. Cambridge, 1998.
12. Svarovsky, L., Solid–Liquid E = Norden efficiency WPi = ratio between mass of water and
Separation, 3rd edn., Butterworth, fi = fraction of pulp lost mass of pulp in the suspension,
Elsevier, New York, 1990. FWS = ratio between wet cake mass and kg/kg
13. Gullichsen, J., and Paulapuro, H. dry cake mass, kg/kg Y = overall washing system efficiency
(Ed.), Papermaking Science and KC = characteristic coefficient of the YL = local washing efficiency
Technology, Fapet Oy, Jyäskylä,
filtration zone, N•s/m8 YLi = lower limit of local washing effi-
2000, 1 CD-ROM.
14. Casey, J.P., “Brownstock washing,” KCL = characteristic coefficient of the ciency
in Pulp and Paper Chemistry and washing zone, N•s/m8 YLS = upper limit of local washing effi-
Chemical Technology, Wiley KMF = characteristic coefficient of filter ciency
Interscience, New York, 1980, p. media in the filtration zone, α = average specific cake resistance,
443. N•s/m5 m/kg
15. Perry,R.H., and Green, D.W., KMFL = characteristic coefficient of filter µ5 = filtrate viscosity in Stream 5,
Perry’s Chemical Engineers’ media in the washing zone, kg/(m•s)
Handbook, 7th edn., McGraw-Hill, N•s/m5 ω = RDVF angular velocity, radians/s
1997. MPi = mass flow rate of pulp, kg/s ρ5 = filtrate density in Stream 5, kg/m3
16. Reynol, A.S., Jr., “Estudo da
MWi = mass flow rate of water, kg/s ρ8 = filtrate density in Stream 8, kg/m3
Lavagem da Polpa Marrom do
Processo Sulfato: Mecanismos da ΔPC = pressure drop of cake, Pa ρ10 = filtrate density in Stream 10,
Filtração e Balanços de Massa,” ΔPF = pressure drop of filtering zone, Pa kg/m3
M.S. dissertation, Escola ΔPL = pressure drop of washing zone, Pa θF = filtration zone angle, radians
Politécnica, Universidade de São RMF = Filter medium resistance, m-1 θL = washing zone angle, radians
Paulo, São Paulo, 2005. SSP = consistency of the brownstock,
17. Kukreja, V.K., Ray, A.K., Singh, V.P., kg/kg This paper was originally published in
et al., Indian Chem. Engr., Section tF = filtration time, s P o r t u g u e s e i n O Papel , A p r i l , 2 0 0 5 .
A 37(3): 113(1995). tL = washing time, s This edited version is published through
vF = filtrate volume collected during a cooperative agreement between
NOMENCLATURE filtration time, m3 ABTCP /O Papel a n d T A P P I / TAPPI
AF = filtration zone area, m2 vL = washing liquid volume collected JOURNAL .
AL = washing zone area, m2 during washing time, m3
CSP = concentration of solids in suspen- xF = washing parameter This paper is also published on TAPPI’s
sion, kg/m3 XSi = ratio between mass of soluble web site <www.tappi.org> and
DF = dilution factor, kg/kg solids and mass of water in the summarized in the March Solutions! for
DR = displacement ratio suspension, kg/kg People, Processes and Paper magazine
(Vol. 89 No. 3).
INSIGHTS FROM THE AUTHORS dilution unit is as important as the washing unit with
Several studies have been published that deal with the regard to system efficiency.
scientific fundamentals of brownstock washing. Our next step is to present a detailed application of
However, there have been very few studies on this calculation procedure in terms of a parametric
brownstock washing that are aimed at aiding process analysis of the rotary drum vacuum filter.
managers in their daily routines.
In early studies the brownstock washing operation Pacheco and de Paiva are with the Chemical Engineering Dept.
was described using a mass balance approach to of Escola Politécnica at São Paulo University, Travessa 3 nº 380,
correlate the variables. Our research complements Caixa Postal 61548 – CEP 05424-970, São Paulo, Brazil. Reynol is
those earlier studies by including the variables and with Air Products Brazil in the Global Application Development
equations that describe the macroscopic behavior of Dept. Email Pacheco at crfp@usp.br, de Paiva at
the rotary drum vacuum filter and the xF parameter that jolpaiva@usp.br, and Reynol at reynolas@airproducts.com.
defines the efficiency of the washing operation.
In addition, the equations are solved in our study by the
system/engineering analysis methodology.
We discovered that the washing parameter xF is
useful in defining the efficiency of the washing
operation. It was correlated to the commonly used
parameters of dilution factor, displacement ratio, and
Norden efficiency. An interesting point is that the Pacheco de Paiva Reynol