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Fhkdh\kdbc]hkm^Zjkl\_ggucmgb\_jkbl_l

bf_gbF<Ehfhghkh\Z
Obfbq_kdbcnZdmevl_l
DZn_^jZZgZeblbq_kdhcobfbb

AZqzlgZyaZ^ZqZihZgZeblbq_kdhcobfbb

Klm^_glZ]jmiiu

Ij_ih^Z\Zl_ev
NZ^__\Z<B
Kh^_j`Zgb_

P_evjZ[hlu 2
DZq_kl\_ggucZgZeba 3
Ij_^\Zjbl_evgu_bkiulZgby 3
Kbkl_fZlbq_kdbcoh^ZgZebaZ 3
H[ahjebl_jZlmju 6
F_lh^ujZaeh`_gbybjZa^_e_gby 6
F_lh^ujZkl\hj_gby 6
F_lh^ujZa^_e_gby 6
=jZ\bf_ljbq_kdb_f_lh^uhij_^_e_gbyZexfbgby 7
G_hj]Zgbq_kdb_hkZ^bl_eb 7
Hj]Zgbq_kdb_hkZ^bl_eb 8
3.3. Lbljbf_ljbq_kdb_f_lh^uhij_^_e_gbyZexfbgby 10
Ijyfh_dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_ 10
3.H[jZlgh_dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_ 11
3.3.3. Dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_aZf_klbl_ey 12
Bkihevah\Zgb_^jm]bodhfie_dkhgh\ 12
Hdbkebl_evgh\hkklZgh\bl_evgh_lbljh\Zgb_ 13
Dbkehlghhkgh\gh_lbljh\Zgb_ 13
<u\h^u 13
Wdki_jbf_glZevgZyqZklv 15
=jZ\bf_ljbq_kdh_hij_^_e_gb_Zexfbgby 15
Ko_fZZgZebaZ 15
JZkqzlb\a\_rb\Zgb_gZ\_kdbh[jZapZ 15
F_lh^bdZjZkl\hj_gby 16
F_lh^bdZboh^hij_^_e_gby 16
4.2. Dhfie_dkhghf_ljbq_kdh_hij_^_e_gb_Zexfbgby 17
Ko_fZZgZebaZ 17
JZkqzlb\a\_rb\Zgb_gZ\_kdbh[jZapZ 17
F_lh^bdZjZkl\hj_gby 17
F_lh^bdZboh^hij_^_e_gby 18
AZdexq_gb_ 19
Kibkhdebl_jZlmju 20

1
P_evjZ[hlu

P_evxgZklhys_cjZ[hluy\ey_lkydZq_kl\_ggucZgZebaijbjh^gh]hbebijhfure_g-
gh]h h[t_dlZ b hij_^_e_gb_ kh^_j`Zgby h^gh]h ba we_f_glh\ \oh^ysbo \ khklZ\ ^Zggh]h
h[t_dlZ

2
DZq_kl\_ggucZgZeba

Ij_^\Zjbl_evgu_bkiulZgby
H[jZa_p ij_^klZ\ey_l kh[hc kljm`db k_j_[jbklh]h p\_lZ lh _klv \_jhylgh y\ey_lky
kieZ\hf H[jZa_p qZklbqgh jZkl\hjy_lky \ szehqb k \u^_e_gb_f ]ZaZ g_jZkl\hjb\rbcky
hkZ^hdhdjZr_g\dhjbqg_\ucp\_lIhwlhfmfh`ghij_^iheh`blvqlhZgZebabjm_fuch[t-
_dl ±wlhkieZ\h^gbfbahkgh\guodhfihg_glh\ dhlhjh]h y\ey_lky Zexfbgbc HklZlhd hl
jZkl\hj_gby \ szehqb iheghklvx jZkl\hjy_lky \  F HNO3. >Zevg_crbc ZgZeba ijhba\h-
^bekyihf_lh^bd_hibkZgghc\[1].

Kbkl_fZlbq_kdbcoh^ZgZebaZ

:gZeba ijh\h^beb ih ko_f_ ijb\_^zgghc \ur_ H[jZa_p bkke_^m_fh]h h[t_dlZ jZk-
l\hjbeb\ghfjZkl\hj_NaOH; ihemq_ggZy\uly`dZ[ueZhl^_e_gZhlhkZ^dZWlhlhkZ-
^hd\k\hxhq_j_^vjZkl\hjbeb\FZahlghcdbkehl_Szehqgmx jZkl\hj bZahlghdbk-
emx jZkl\hj \uly`dbZgZebabjh\Zebhl^_evgh J_amevlZluZgZebaZijb\_^_gu\lZ[ebp_

3
LZ[ebpZKbkl_fZlbq_kdbcoh^dZq_kl\_ggh]hZgZebaZh[t_dlZ

:gZebabjm_fuc Ij_^iheZ]Z_fuckhklZ\nZa
‹ J_Z]_glu GZ[ex^_gby <u\h^u
h[t_dl JZkl\hj HkZ^hd

HkZ^hdg_\u- Al(III), Sn(II), Zn(II),


1. JZkl\hj Na2CO3 Hlkmlkl\m_l Ca —
iZ^Z_l Cr(III)
<uiZ^Z_l[_- <hafh`ghijbkmlkl- JZkl\hj3: Zn(II), HkZ^hd2: Al(III),
2. JZkl\hj NH4Cl
euchkZ^hd \b_$ObebSn Cr(III) Sn(II)
HCl, HkZ^hdg_\u-
3. JZkl\hj 3 Hlkmlkl\m_lZn Cr(III) —
(NH4)2Hg(SCN)4 iZ^Z_l
NaOH, H2O2, ^bn_- Hj]Zgbq_kdZy
4. JZkl\hj3 gbedZj[Zab^bah- nZaZhdjZr_gZ Hlkmlkl\m_lCr — —
Zfbeh\uckibjl \a_ezgucp\_l
<uiZ^Z_l[_-
5. HkZ^hd2 HCl, Hg(NO3)2 Ijbkmlkl\m_lSn Sn(II), Al(III) —
euchkZ^hd
HCl, ZebaZjbgh\uc
H[jZam_lky
6. HkZ^hd2 djZkgucNH3, Ijbkmlkl\m_l$O Sn(II), Al(III) —
djZkguceZd
CH3COOH
NH3 ^hpH = 5, Hj]Zgbq_kdZy Fe(III), Co(II), Ni(II),
7. JZkl\hj KSCN, bahZfbeh- nZaZhdjZr_gZ Ijbkmlkl\m_l)H Mn(II), Cu(II), Cd, Mg, —
\uckibjl \djZkgucp\_l Hg(I), Ag, Pb(II)
NaF, NH3^hpH = 5, Hj]Zgbq_kdZy Fe(III), Ni(II), Mn(II),
8. JZkl\hj KSCN, bahZfbeh- nZaZg_hdjZ- Hlkmlkl\m_l&R Cu(II), Cd, Mg, Hg(I), —
\uckibjl r_gZ Ag, Pb(II)

4
Fe(III), Ni(II), Cu(II),
JZkl\hj[_k-
9. JZkl\hj NaBiO3 Hlkmlkl\m_lMn Cd, Mg, Hg(I), Ag, —
p\_l_g
Pb(II)
NH3 ^hpH = 6, ^b- HkZ^hdg_\u- Fe(III), Cu(II), Cd, Mg,
10. JZkl\hj Hlkmlkl\m_l1L —
f_lbe]ebhdkbf iZ^Z_l Hg(I), Ag, Pb(II)
HkZ^hdg_\u- Hlkmlkl\mxlAg,
11. JZkl\hj HCl (1:4) Fe(III), Cu(II), Cd, Mg —
iZ^Z_l Pb(II), Hg(I)
<uiZ^Z_l
NH3 ^hpH = 5, <_jhylghijbkmlkl\m-
12. JZkl\hj [e_^gh`zeluc JZkl\hj5: Cd, Mg HkZ^hd4: Cu, Fe
Na2S2O3 _lCu
hkZ^hd
Na2HPO4, NH3 ^h HkZ^hdg_\u-
13. JZkl\hj5 Hlkmlkl\m_lMg Cd —
pH = 9 iZ^Z_l
HCl ^hpH = 0.5, HkZ^hdg_\u-
14. JZkl\hj5 Hlkmlkl\m_lCd — —
Na2S iZ^Z_l
HNO3 (6 M), <uiZ^_l[mjuc <_jhylghijbkmlkl\b_
15. HkZ^hd KX —
K4Fe(CN)6 hkZ^hd Cu
Ihy\ey_lkykb-
16. HkZ^hd HNO3 (6 M), NH3 g__hdjZrb\Z- Ijbkmlkl\m_lKX Cu —
gb_

LZdbf h[jZahf bkke_^m_fuc h[t_dl y\ey_lky kieZ\hf hkgh\gu_ dhfihg_glu ± Zexfbgbc b f_^v LZd`_ ijbkmlkl\mxl heh\h b \
hq_gvg_[hevrbodhebq_kl\Zo`_e_ah

5
H[ahjebl_jZlmju

F_lh^ujZaeh`_gbybjZa^_e_gby
F_lh^ujZkl\hj_gby
JZaeh`_gb_kieZ\h\y\ey_lky^hklZlhqghijhklhcaZ^Zq_cihkdhevdmex[hckieZ\fh-
`_l[ulvjZkl\hjzg\kf_kbdbkehlbebs_ehq_c>eyjZkl\hj_gbykieZ\h\gZhkgh\_Zexfb-
gbyih^oh^yldZddbkehlulZdbszehqbH[uqgh[_jml^hklZlhqghdhgp_gljbjh\ZggucjZk-
l\hj szehqb ~ 30 %-guc  lZdhc kihkh[ jZaeh`_gby bkihevamxl ^ey kieZ\h\ Zexfbgby b
fZ]gby [2] L_f g_ f_g__ \ >@ b >@ g_ mdZaZgZ \hafh`ghklv jZkl\hj_gby ^jm]bo kieZ\h\
gZijbf_jZexfbgbykf_^vx \szehqbOhly\>@^eyhij_^_e_gbyf_^b\Zexfbgb_\hf
kieZ\_bkihevam_lkybf_gghwlhlf_lh^
<Z`ghchkh[_gghklvxZexfbgbyy\ey_lky_]hiZkkb\ZpbyjZkl\hjZfbZahlghcdbkehlu
dhlhju_ ke_^h\Zl_evgh g_ijb]h^gu ^ey jZkl\hj_gby H^gZdh Zexfbgbc jZkl\hjy_lky \h
fgh]bo ^jm]bo dbkehlZo ihwlhfm gZb[he__ ih^oh^ysbc j_Z]_gl ^ey jZkl\hj_gby kieZ\h\
Zexfbgby±kf_kvZahlghckheyghcb\hafh`ghk_jghcdbkehl<[2]mdZaZgke_^mxsbckh-
klZ\ kf_kb dbkehl ^ey jZkl\hj_gby kieZ\h\ Zexfbgby k f_^vx  fe H2SO4 (1:1),  fe
HNO3 (kiehlghklvx]/kf3 bfedhgp_gljbjh\ZgghcHCl. GZ]kieZ\Z[_jmlfelZ-
dhckf_kbL_fg_f_g__qZklhh]jZgbqb\Zxlkykf_kvxZahlghcbkheyghcdbkehl[3].

F_lh^ujZa^_e_gby
<^ZgghfiZjZ]jZn_[m^mlaZljhgmluebrv\hijhkuhl^_e_gbyZexfbgbyhlf_^bih-
kdhevdmjZa^_e_gb_lhevdhwlbowe_f_glh\g_h[oh^bfh^ey^ZgghcjZ[hluG_dhlhju_f_lh-
^u jZa^_e_gby Zexfbgby b ^jm]bo f_lZeeh\ ijb\_^_gu \ jZa^_eZo ihk\yszgguo dhgdj_l-
gufkihkh[Zfhij_^_e_gby
GZb[he__ jZkijhkljZgzgguc f_lh^ jZa^_e_gby – hkZ`^_gb_ HkZ`^Z_fufb nhjfZfb
y\eyxlkyeb[h]b^jhdkb^Zexfbgbyeb[h^jm]b_fZehjZkl\hjbfu_kh_^bg_gbyf_^bHkZ-
`^_gb_]b^jhdkb^ZZexfbgbyih^jh[g__hibkZgh\Hkgh\gZyijh[e_fZaZdexqZ_lky\
g_hij_^_ezgghklb hilbfZevgh]h agZq_gby jG hkZ`^_gby ihkdhevdm ijb [he__ \ukhdbo pH
\hafh`ghkh\f_klgh_hkZ`^_gb_]b^jhdkb^Zf_^bZijb[he__gbadbo±g_ihegh_hkZ`^_gb_
ZexfbgbyLZd>@mdZau\Z_lgZg_ijb]h^ghklv^Zggh]hf_lh^Z^eyhl^_e_gbyZexfbgbyhl
f_^b;he__m^h[ghhkZ`^_gb_]b^jhdkb^Zf_^b\kbevghs_ehqghckj_^_]b^jhdkb^Zexfb-
gbyiheghklvxjZkl\hjy_lkykh[jZah\Zgb_f]b^jhdkhdhfie_dkh\H^gZdha^_kvlh`_kms_-
kl\mxl ijh[e_fu \ kbevghs_ehqghc kj_^_ f_^v fh`_l h[jZah\u\Zlv ]b^jhdkhdhfie_dku

6
ohly bo dhebq_kl\h g_\_ebdh Ihwlhfm mdZaZggu_ f_lh^u fZeh bkihevamxlky gZ ijZdlbd_
ohly[3] \kz`_j_dhf_g^m_li_j_hkZ`^_gb_ijbpH ~ 6,0.
;he__p_e_khh[jZagucf_lh^jZa^_e_gby±bkihevah\Zgb_hkZ^bl_e_ckh^_j`Zsbok_-
jmLZd\[4]ij_^eh`_gh^h[Z\eylvdkbevghs_ehqghfmjZkl\hjmijh[ukmevnblgZljby^ey
hkZ`^_gbyjZkl\hjzgghcf_^b<hafh`ghlZd`_ijbf_g_gb_lbhkmevnZlZgZljby\keZ[hdb-
kehckj_^_±\wlhfkemqZ_\uiZ^Z_lhkZ^hdCu2S. ?szh^bgm^h[gucbqj_a\uqZcghk_e_d-
lb\gucf_lh^hkZ`^_gbyf_^bhibkZg\>@dZgZebabjm_fhfmjZkl\hjm^h[Z\eyxl\bggmx
dbkehlm g_cljZebamxl jZkl\hj ih bg^bdZlhjm ijbeb\Zxl Zahlgmx dbkehlm hij_^_ezgghc
dhgp_gljZpbb Z aZl_f ± guc wlZghevguc jZkl\hj hdkbobghebgZ < wlbo mkeh\byo k_-
e_dlb\gh \uiZ^Z_l hkZ^hd hdkbobghebgZlZ f_^b Z [hevrbgkl\h ^jm]bo dZlbhgu gZijb-
f_jAl, Fe, Ti, Mn, Ni, Co, Cd, Zn) g_h[jZamxlhkZ^dh\
<hafh`gh lZd`_ hl^_e_gb_ f_^b wdkljZdpb_c dmin_jhgZlZ kf   beb we_dljheb-
ahfgZjlmlghfdZlh^_bajZa[Z\e_ggh]hk_jghdbkeh]hjZkl\hjZ\wlhfkemqZ_\jZkl\hj_hk-
lZxlkylhevdhAl, Be, j_^dha_f_evgu_s_ehqgu_bs_ehqgha_f_evgu_f_lZeeuMn [7].

=jZ\bf_ljbq_kdb_f_lh^uhij_^_e_gbyZexfbgby
G_hj]Zgbq_kdb_hkZ^bl_eb
HkZ`^_gb_\\b^_]b^jhdkb^ZgZb[he__jZkijhkljZgzggufhkZ^bl_e_fbkihevam_fuf
^eyihemq_gby]b^jhdkb^ZZexfbgbyy\ey_lkyjZkl\hjZffbZdZ>Zggu_h[hilbfZevghfjG
hkZ`^_gbyijhlb\hj_qZl^jm]^jm]m\[3]mihfygmlubgl_j\Zeu±±HkZ`^_-
gb_ ij_^eZ]Z_lky ijh\h^blv ba fZeh]h h[tzfZ ^ey mf_gvr_gby jZkl\hjbfhklb Al2O3·xH2O;
ijhfu\Zgb_ \h^hc g_^himklbfh ke_^m_l bkihevah\Zlv ]hjyqbc guc jZkl\hj NH4NO3 k
^h[Z\e_gb_f ZffbZdZ IjhdZeb\Zgb_ hkZ^dZ ijh\h^yl ijb l_fi_jZlmjZo g_ gb`_ 0 K
h^gZdh ihke_ ijhdZeb\Zgby ijb lZdhc l_fi_jZlmj_ hdkb^ Zexfbgby hklZzlky ]b]jhkdhibq-
guf HilbfZevgZy l_fi_jZlmjZ ijhdZeb\Zgby ± 0 K ihkdhevdm ihke_ ljzoqZkh\h]h hl-
`b]Zijbwlhcl_fi_jZlmj_hkZ^hdklZgh\blkyiheghklvxg_]b]jhkdhibqguf[3].
HkZ`^_gb_ jZkl\hjhf ZffbZdZ g_k_e_dlb\gh \ wlbo mkeh\byo g_ hkZ`^Zxlky lhevdh
s_ehqgu_bs_ehqgha_f_evgu_f_lZeeuZlZd`_Mg. H^gZdhfgh]b_we_f_glufh]ml[ulv
hl^_e_gui_j_hkZ`^_gb_fijbhij_^_ezgguoagZq_gbyojG<[5]lZd`_ij_^eh`_gh]jZ\b-
f_ljbq_kdh_ hij_^_e_gb_ kmffu Zexfbgby b ^jm]bo f_lZeeh\ ]b^jhdkb^u dhlhjuo hkZ`-
^Zxlky\l_o`_mkeh\byohij_^_e_gb_ijbf_k_cbgufbkihkh[Zfbbihke_^mxs__hij_^_-
e_gb_ZexfbgbyihjZaghklb
;he__p_e_khh[jZaghhkZ`^_gb_keZ[ufbhj]Zgbq_kdbfbhkgh\ZgbyfblZdbfbdZdib-
jb^bgα-ibdhebgbebmjhljhibgIj_bfms_kl\ZfbwlbohkZ^bl_e_cy\eyxlky[he__ieZ\gh_
baf_g_gb_jGZlZd`_h[jZah\Zgb_dhfie_dkh\khfgh]bfbi_j_oh^gufbf_lZeeZfb\_^m-

7
s__dbofZkdbjh\ZgbxLZdbfh[jZahfagZqbl_evghih\urZ_lkyk_e_dlb\ghklvf_lh^Z[3].
Ohlyba^_kv_klvk\hbg_^hklZldbgZijbf_jijbbkihevah\ZgbbwlbohkZ^bl_e_cihemqZxl-
kyh[tzfgu_hkZ^dbZhkZ`^_gb_ZffbZdhfijb\h^bldihemq_gbx[he__dhfiZdlguohkZ^-
dh\f_g__ih^\_j`_gguoaZ]jyag_gbx[7].
?szh^bgijbzfhkZ`^_gby]b^jhdkb^ZZexfbgby±bkihevah\Zgb_khe_ckeZ[uog_hj-
]Zgbq_kdbo dbkehl gZijbf_j lbhkmevnZlZ gZljby gbljblZ Zffhgby dZj[hgZlh\ Ijb ^h-
[Z\e_gbb jZkl\hjh\ wlbo khe_c d ZgZebabjm_fhfm jZkl\hjm ih\urZ_lky jG \uau\Zy hkZ`-
^_gb_ ]b^jhdkb^Z Zexfbgby Ij_bfms_kl\h wlbo hkZ^bl_e_c ± h[jZah\Zgb_ [he__ iehlguo
hkZ^dh\ [3].

HkZ`^_gb_\\b^_djbheblZ [3]:lbibqgufhkZ^bl_e_f\wlhff_lh^_y\ey_lkynlhjb^
gZljbyIjb_]hkms_kl\_gghfba[uld_bajZkl\hjh\kh^_j`ZsboZexfbgbcdhebq_kl\_ggh
hkZ`^Z_lkydhfie_dkkhklZ\ZNa3AlF6; ijbf_gvrboba[uldZodhfie_dk bf__l bghc khklZ\
F_lh^ \ukhdh k_e_dlb\_g b iha\hey_l hij_^_eylv Zexfbgbc \ ijbkmlkl\bb fgh]bo ^jm]bo
f_lZeeh\ h[jZamxsbo [he__ jZkl\hjbfu_ nlhjb^gu_ dhfie_dku D g_^hklZldZf f_lh^Z
ke_^m_lhlg_klbijh^he`bl_evghklv \qZklghklbhq_gvf_^e_ggh_nbevljh\Zgb_hkZ^dZ Z
lZd`_g_lhqghklvh[mkeh\e_ggmxg_kl_obhf_ljbqghklvx\uiZ^Zxs_]hhkZ^dZ<gZklhys__
\j_fydjbheblgucf_lh^ihqlbg_bkihevam_lky^eyhij_^_e_gbyZexfbgbyAZlhhggZrze
ijbf_g_gb_^eyhl^_e_gbyZexfbgbyhldZlbhgh\^jm]bof_lZeeh\hkZ^hddjbheblZjZkl\h-
jyxlZihemq_ggucjZkl\hjZgZebabjmxl[he__lhqguff_lh^hf

HkZ`^_gb_\\b^_nhknZlZ [5]: ^Zggucf_lh^ij_^mkfZljb\Z_lhkZ`^_gb_Zexfbgby\


\b^_ AlPO4; dhgljhev jG hkZ`^_gby  ±   iha\hey_l hl^_eblv Zexfbgbc hl ba[uldh\
fgh]bo f_lZeeh\ F_lh^ bkihevamxl ijb ZgZeba_ kieZ\h\ ihkdhevdm bf_ggh hg iha\hey_l
hl^_eylv Zexfbgbc hl f_lZeeh\ \oh^ysbo \ khklZ\ klZe_c Fe, Cr, V, Sn, Mn, Zn, Ni). Hk-
gh\gufg_^hklZldhfy\ey_lkygbadZylhqghklvh[mkeh\e_ggZyaZ]jyag_gb_fhkZ^dZkhhkZ`-
^zgguf P2O5. Djhf_ wlh]h ]jZ\bf_ljbq_kdZy nhjfZ ± AlPO4 – ]b]jhkdhibqgZ b qZklbqgh
jZaeZ]Z_lkyijb\ukhdbol_fi_jZlmjZo

3.2.2. Hj]Zgbq_kdb_hkZ^bl_eb
HkZ`^_gb_ \ \b^_ hdkbobghebgZlZ hdkbobghebg h[jZam_l hkZ^db kh fgh]bfb dZ-
lbhgZfb ihwlhfm _]h k_e_dlb\ghklv gbadZ H^gZdh ijb bkihevah\Zgbb ih^oh^ysbo fZkdb-
jmxsboj_Z]_glh\bebhl^_e_gbbf_rZxsbodZlbhgh\f_lh^^hklZlhqgh[ukljbijhkl
HkZ`^_gb_ ijh\h^yl ijb jG  ±  [5] P_e_khh[jZagh ijb[Z\eylv jZkl\hj 
hdkbobghebgZ d keZ[h dbkehfm ZgZebabjm_fhfm jZkl\hjm Z aZl_f f_^e_ggh ^h[Z\eylv

8
CH3COONH4. Ijb lZdhf ihjy^d_ ijb[Z\e_gby j_Z]_glh\ h[jZamxlky [he__ djmigu_ djb-
klZeeu g_`_eb \ h[jZlghf kemqZ_ HkZ`^_gb_ ke_^m_l ijh\h^blv ba oheh^gh]h jZkl\hjZ Z
aZl_f gZ]j_\Zlv kbkl_fm. Hdkbobghebg fh`gh ijbf_gylv \ \b^_ jZkl\hjh\ \ mdkmkghc beb
jZa[Z\e_gghckheyghcdbkehlZo [3].
>ey ijhfu\Zgby hkZ^dZ p_e_khh[jZagh bkihevah\Zlv ,guc jZkl\hj hdkbobgh-
ebgZbebgucjZkl\hjZp_lZlZZffhgbyFh`ghlZd`_bkihevah\Zlv\h^mghlhevdhoh-
eh^gmx >Zggu_ ih l_fi_jZlmj_ ^hklb`_gby ihklhyggh]h \_kZ hkZ^dhf hdkbobghebgZlZ
ZexfbgbylZd`_jZagylkyhl^h 0K [3] j_dhf_g^m_l \ukmrb\Zgb_ ijb 0 K
=jZ\bf_ljbq_kdZynhjfZ±hdkbobghebgZlZexfbgby
DZdm`_hlf_qZehkv\ur_f_lh^g_k_e_dlb\_ghkZ`^_gbxg_f_rZxlebrvMg, Be,
s_ehqgu_bs_ehqgha_f_evgu_f_lZeeu<hafh`ghhl^_e_gb_f_^bihf_lh^bd_hibkZgghc
\ur_ kf bebfZkdbjh\Zgb_f_^bpbZgb^bhgZfbbW>L:\ZffbZqghfjZkl\hj_ijb
jG ±[3].
LZd`_kms_kl\m_ljy^f_lh^h\]hfh]_ggh]hhkZ`^_gby\hafh`ghf_^e_ggh_h[jZah-
\Zgb_hkZ^bl_ey bkihevamxlZp_lhdkbobghebg ihkl_i_ggh_mklZgh\e_gb_jG bkihevam-
xlZp_lZfb^mjhljhibgfhq_\bgm bebhkZ`^_gb_bakf_kbjZkl\hjbl_e_c wlhlijbzfhk-
gh\ZggZaZf_^e_gbbh[jZah\Zgbyg_dhlhjuohkZ^dh\\ijbkmlkl\bb[hevrbodhebq_kl\jZk-
l\hjbl_eykh\j_f_g_fjZkl\hjbl_evme_lmqb\Z_lkybgZqbgZ_lky\uiZ^_gb_hkZ^dZ [3].

HkZ`^_gb_ \ \b^_ [_gahZlZ [7] wlh h^bgbagZb[he__ lhqguo ]jZ\bf_ljbq_kdbo f_lh-


^h\ hij_^_e_gby Zexfbgby < dZq_kl\_ hkZ^bl_ey bkihevamxl [_gahcgmx dbkehlm hilb-
fZevgh_agZq_gb_jGhkZ`^_gby±F_lh^fZehk_e_dlb\_gghfgh]b_f_rZxsb_dZ-
lbhgufh]ml[ulvfZkdbjh\Zgulbh]ebdhe_\hcdbkehlhc<hafh`ghlZd`_]hfh]_ggh_hkZ`-
^_gb_kbkihevah\Zgb_ffhq_\bgu=jZ\bf_ljbq_kdZynhjfZ±Al2O3.

HkZ`^_gb_ \ \b^_ kmdpbgZlZ [5] \ wlhf f_lh^_ Zexfbgbc hkZ`^Zxl ba dbiysbo jZk-
l\hjh\kh^_j`ZsboyglZjgmxdbkehlmbfhq_\bgmF_lh^g_kdhevdh mklmiZ_l ih lhqghklb
[_gahZlghfmh^gZdhagZqbl_evghij_\hkoh^bl_]hihk_e_dlb\ghklb±\hafh`ghhkZ`^_gb_
Zexfbgbyba jZkl\hjh\ kh^_j`Zsbo ba[ulhd ^\mo\Ze_glguo f_lZeeh\ lZdbo dZd Mn, Co,
Ni, Cu). =jZ\bf_ljbq_kdZynhjfZ±Al2O3.

HkZ`^_gb_\\b^_^bn_gZlZ [3]ZffhgbcgZykhev^bn_gh\hcdbkehluh[jZam_lkZex-
fbgb_f ljm^ghjZkl\hjbfmx hkgh\gmx khev =eZ\gh_ ij_bfms_kl\h f_lh^Z ± hl^_e_gb_ hl
dZlbhgh\^\mo\Ze_glguof_lZeeh\h[jZamxsbok^bn_gh\hcdbkehlhcohjhrhjZkl\hjbfu_

9
kheb L_f g_ f_g__ ljzo\Ze_glgu_ f_lZeeu hkZ`^Zxlky kh\f_klgh k Zexfbgb_f ihwlhfm
lj_[m_lkyboij_^\Zjbl_evgh_hl^_e_gb_ =jZ\bf_ljbq_kdZynhjfZ±Al2O3.

HkZ`^_gb_ \ \b^_ kheb dhjbqghc dbkehlu [3] dhjbqgZy dbkehlZ lZd`_ h[jZam_l jZk-
l\hjbfu_ kheb k ^\mo\Ze_glgufb f_lZeeZfb ?z ij_bfms_kl\Zfb dZd hkZ^bl_ey y\eyxlky
\hafh`ghklvhl^_e_gbyg_dhlhjuodhebq_kl\lblZgZbpbjdhgbyaZkqzlhkZ`^_gbyijb [h-
e__ gbadbo jG kh\iZ^_gb_ hkZ`^Z_fhc b ]jZ\bf_ljbq_kdhc nhjf ± Zexfbgb_\Zy khev dh-
jbqghcdbkehlu bf__l ihklhygguc khklZ\ bohjhrh \ukmrb\Z_lky ijb \_kvfZ gbadbo l_f-
i_jZlmjZo ~ 110 0K  =jZ\bf_ljbq_kdZynhjfZ±Al(C9H7O2)3.

HkZ`^_gb_\\b^_dmin_jhgZlZ: dmin_jhghkZ`^Z_lfgh]b_f_lZeeuh^gZdh\Zjvbjmy
jG fh`gh ^h[blvky ^hklZlhqgh \ukhdhc k_e_dlb\ghklb hkZ`^_gby Zexfbgby wlbf j_Z]_g-
lhf L_f g_ f_g__ hkZ^hd dmin_jhgZlZ h[uqgh hdZau\Z_lky aZ]jyagzg ke_^Zfb hdbke_gby
dmin_jhgZDjhf_wlh]hkZfdmin_jhgZlZexfbgbyg_bf__lihklhyggh]hkhklZ\ZIhwlhfm
[he__ rbjhdh_ ijbf_g_gb_ bf__l k_e_dlb\gZy wdkljZdpby Zexfbgby \ \b^_ dmin_jhgZlZ
Zp_lbeZp_lhghf beb oehjhnhjfhf [5] H^gZdh kms_kl\mxl b ZgZeh]b dmin_jhgZ ^Zxsb_
ih^oh^ysb_hkZ`^Z_fu_b]jZ\bf_ljbq_kdb_nhjfuWlhgZijbf_jljbwlZghZfbggZykhev
klbev[_gbegbljhah]b^jhdkbeZfbgZ ba\_klgZy dZd ©kljbedmin_jhgª Hg iha\hey_l k g_-
iehohck_e_dlb\ghklvxhkZ^blvZexfbgbcZaZl_f\ukmrblvihemq_gguchkZ^hdbbkihev-
ah\Zlv_]h\dZq_kl\_]jZ\bf_ljbq_kdhcnhjfu[3].

JZg__ lZd`_ ijbf_gyebkv f_lh^u hkZ`^_gby \ \b^_ Zp_lZlZ beb nhjfbZlZ H^gZdh \
wlbo kemqZyo h[jZamxlky klm^g_h[jZagu_ ljm^ghnbevljmxsb_ky hkZ^db BaaZ wlh]h lhq-
ghklvlZdbof_lh^h\g_\ukhdZbgug_hgbihqlbg_ijbf_gyxlky [3].

3.3. Lbljbf_ljbq_kdb_f_lh^uhij_^_e_gbyZexfbgby
Ijyfh_dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_[3].
GZb[he__jZkijhkljZgzgguf kihkh[hf y\ey_lky lbljh\Zgb_ k I:G b g_[hevrbfb dh-
ebq_kl\Zfbdhfie_dkhgZlZf_^b:exfbgbclbljmxl\gZ]j_luo^hdbi_gbyjZkl\hjZokjG
Hg\ul_kgy_lf_^vbadhfie_dkhgZlZ\u^_eb\rZykyf_^vh[jZam_ldjZkgu_dhfie_dkuk
I:GIhke_k\yau\Zgby\k_]hZexfbgbykW>L:hggZqbgZ_l\ul_kgylvf_^vbadhfie_dkZk
I:G±hdjZkdZjZkl\hjZbadjZkghci_j_oh^bl\`zelmxGZlhqghklvlbljh\Zgby\eby_lih-
jy^hd ijb]hlh\e_gby lbljm_fh]h jZkl\hjZ ± gZb[he__ lhqgu_ j_amevlZlu fh]ml [ulv ihem-
q_gu ijb g_cljZebaZpbb Zp_lZlhf Zffhgby dbkeuo jZkl\hjh\ ^h jG  k ihke_^mxsbf ^h-
[Z\e_gb_f mdkmkghc dbkehlu ^h jG  Ijb h[jZlghf ihjy^d_ g_cljZebaZpby dbkeh]h jZk-

10
l\hjZ ZffbZdhf ^h jG  k ihke_^mxsbf ^h[Z\e_gb_f Zp_lZlgh]h [mn_jZ  ijhbkoh^bl eh-
dZevgh_ ih\ur_gb_ jG \_^ms__ d h[jZah\Zgbx iheby^_jguo dhfie_dkh\ Zexfbgby f_^-
e_ggh j_Z]bjmxsbo k EDTA. <h \j_fy lbljh\Zgby ke_^m_l ih^^_j`b\Zlv jZkl\hj ijb l_f-
i_jZlmj_[ebadhcdl_fi_jZlmj_dbi_gby^jm]bfkihkh[hfijZ\bevgh]hnbdkbjh\Zgbylhq-
dbwd\b\Ze_glghklby\ey_lky^h\_^_gb_hllbljh\Zggh]hjZkl\hjZ^hdbi_gbyb_]h^hlbljh-
\u\Zgb_
F_lh^fZehk_e_dlb\_g±hij_^_e_gbxg_f_rZxlK, Na, Ca, Mg. @_e_ahbpbgdlbl-
jmxlkydhebq_kl\_gghojhf qZklbqghhllbljh\u\Z_lkybaaZ\ukhdhcl_fi_jZlmjujZkl\hjZ
L_fg_f_g__dhg_plbljh\ZgbymklZgZ\eb\Z_lkyhq_gvqzldhqlhijb\h^bld\ukhdhclhq-
ghklbkZfh]hf_lh^Z
Kms_kl\mxlbbgu_f_lh^uijyfh]hdhfie_dkhghf_ljbq_kdh]hlbljh\ZgbyZexfbgby
_kebk\yaZlvZexfbgbc\dhfie_dkkfhehqghcbeb]ebdhe_\hcdbkehlZfblh\hafh`ghijy-
fh_ lbljh\Zgb_ k bg^bdZlhjhf ]_fZlhdkbebghf Fh`gh lZd`_ hllbljh\Zlv Zexfbgbc ijb
pHkbg^bdZlhjhfojhfqbklh]hem[uf\ijbkmlkl\bbg_[hevrbodhebq_kl\f_^bKms_kl-
\m_l f_lh^ ijyfh]h lbljh\Zgby k bg^bdZlhjhf ojhfZamjhehf S, dhlhjuc h^gZdh g_lhq_g
\\b^mg_qzldh]hi_j_oh^ZhdjZkdb

H[jZlgh_dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_
GZb[he__lhqguff_lh^hfy\ey_lkyh[jZlgh_lbljh\Zgb_kdkbe_gheh\ufhjZg`_\uf
Ijyfh_lbljh\Zgb_kwlbfbg^bdZlhjhfg_\hafh`ghbaaZ[hevr_cmklhcqb\hklbdhfie_dkZ
Zexfbgbykdkbe_gheh\ufhjZg`_\ufihkjZ\g_gbxkdhfie_dkhgZlhfZexfbgbyIhwlhfm
ba[ulhd W>L: hllbljh\u\Zxl jZkl\hjZfb khe_c k\bgpZ lhjby beb pbgdZ GZ[ex^Z_lky
hq_gv j_adbc i_j_oh^ hdjZkdb hl `zelhc q_j_a hjZg`_\mx \ djZkgmx KZf ih k_[_ f_lh^
fZehk_e_dlb\_g g_f_rZxlebrvs_ehqgu_f_lZeeuZffhgbcMg, Ca, Sr bBa)h^gZdhk_-
e_dlb\ghklv fh`_l [ulv ih\ur_gZ k ihfhsvx ijbzfZ RZch [3] Ba[ulhd W>L: hllbljh-
\uZxljZkl\hjhfZp_lZlZpbgdZaZl_fjZajmrZxldhfie_dkhgZlZexfbgbynlhjb^bhgZfb
\gh\v^h[Z\eyxlba[ulhdW>L: bhklZlhdhllbljh\u\ZxljZkl\hjhfZp_lZlZpbgdZDhebq_-
kl\h Zexfbgby jZkkqblu\Zxl ih j_amevlZlZf \lhjh]h lbljh\Zgby Ih\ur_gb_ k_e_dlb\gh-
klbk\yaZghkl_fqlhnlhjb^bhguki_pbnbqghjZajmrZxldhfie_dkhgZlZexfbgbyh[jZ-
amydjbhebl<f_klhdkbe_gheh\h]hhjZg`_\h]hfh`gh\dZq_kl\_bg^bdZlhjZbkihevah\Zlv
f_lbelbfheh\uckbgbcqlhijb\h^bldg_dhlhjhfmbaf_g_gbxagZq_gbyjGlbljh\Zgby[3].
Fh^bnbdZpbybaeh`_ggh]h\ur_f_lh^Z±lbljh\Zgb_jZkl\hjhfkhebpbgdZ\\h^gh
wlZghevghc kj_^_ k bg^bdZlhjhf ^blbahghf G_^hklZldhf f_lh^Z y\ey_lky g_h[oh^bfhklv
bkihevah\ZgbywlZgheZ^eym^_j`Zgby^blbahgZ\jZkl\hj_H^gZdhlhqghklvhklZzlkyg_hk-
ihjbfuf^hklhbgkl\hfLbljh\Zgb_k^blbahghfklhev`_fZehk_e_dlb\ghdZdbkdkbe_gh-

11
eh\ufhjZg`_\uf f_rZxl\k_f_lZeeuh[jZamxsb_dhfie_dkhgZluijbh[uqguomkeh\b-
yo h^gZdh\ebygb_[hevrbgkl\ZbagbomkljZgy_lkyihf_lh^mRZch[7]?szh^gZfh^bnb-
dZpbywlh]h`_f_lh^Z±lbljh\Zgb_khevxpbgdZ\ijbkmlkl\bb[_gab^bgZbhdbkebl_evgh
\hkklZgh\bl_evghc iZju n_jjhpbZgb^±n_jjbpbZgb^ Ihke_ ^hklb`_gby dhg_qghc lhqdb
lbljh\ZgbybhgupbgdZk\yau\Zxln_jjhpbZgb^\fZehjZkl\hjbfh_kh_^bg_gb_\j_amevlZ-
l_ihl_gpbZehdbkebl_evgh\hkklZgh\bl_evghckbkl_fuih\urZ_lkyb[_gab^bghdbkey_lky
hdjZrb\ZyjZkl\hj<f_klh[_gab^bgZbpbZgb^guodhfie_dkh\fh`ghbkihevah\Zlv\ZjbZ-
fbgh\uckbgbcjh^Zgb^bkhev^\mo\Ze_glghcf_^b [3].
<hafh`ghlZd`_h[jZlgh_lbljh\Zgb_jZkl\hjhfkheb`_e_aZkkZebpbeh\hcbebkmev-
nhkZebpbeh\hcdbkehlZfbLbljh\Zgb_ijh\h^yl\oheh^guojZkl\hjZoijbjG ±\h
ba[_`Zgb_\ul_kg_gbyZexfbgbybadhfie_dkhgZlZF_lh^fZehk_e_dlb\_gf_rZxl\k_f_-
lZeeuh[jZamxsb_dhfie_dkhgZlukW>L:, ZlZd`_pbZgb^nlhjb^nhknZlZgbhguk\y-
au\Zxsb_dZlbhguZexfbgby[3].
M^h[guff_lh^hfh[jZlgh]hlbljh\ZgbyZexfbgbyy\ey_lkylbljh\Zgb_jZkl\hjhfkh-
ebf_^b\ijbkmlkl\bbI:GA^_kvdZdb\kemqZ_ijyfh]hlbljh\Zgby\ijbkmlkl\bbdhf-
ie_dkhgZlZf_^b kf dhg_qgZylhqdZlbljh\Zgbyhij_^_ey_lkyihbaf_g_gbxhdjZkdb
jZkl\hjZba`zelhc\djZkgmx[1].
<k_ f_lh^uijb\_^zggu_\ur_iha\heyxlijhba\h^blvh[jZlgh_ lbljh\Zgb_ Zexfb-
gby \ dbkehc kj_^_ H^gZdh lZdh_ lbljh\Zgb_ \hafh`gh b \ s_ehqghc kj_^_ ^ey wlh]h bk-
ihevamxl jZkl\hj kheb pbgdZ k bg^bdZlhjhf wjbhojhfqzjguf L Lbljh\Zgb_ ijh\h^yl gZ
oheh^m ^ey ij_^hl\jZs_gby h[jZah\Zgby dhfie_dkZ Zexfbgby k bg^bdZlhjhf F_lh^ fZeh
k_e_dlb\_gbh[uqghg_bkihevam_lky[3].

3.3.3. Dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_aZf_klbl_ey
Lbljh\Zgb_ aZf_klbl_ey ijb hij_^_e_gbb Zexfbgby ihqlb g_ bkihevam_lky ?^bgkl-
\_ggucf_lh^mdZaZgguc\[3], – lbljh\Zgb_kdhfie_dkhgZlhf\ZgZ^by<u^_eb\rbcky\Z-
gZ^bclbljmxlW>L: c lZdbfbbg^bdZlhjZfbdZd^bn_gbedZj[ZahgibjhdZl_obgh\ucnbh-
e_lh\ucfhjbgdZjfbgh\ZydbkehlZK_e_dlb\ghklvf_lh^ZgbadZbk\yaZgZkl_fqlh\ZgZ-
^bc\ul_kgy_lkybak\h_]hdhfie_dkhgZlZfgh]bfbf_lZeeZfb

3.3.4. Dhfie_dkhghf_ljbq_kdh_lbljh\Zgb_kjZaebqgufbdhfie_dkhgZfb
Kj_^b hlebqguo hl W>L: dhfie_dkhgh\ ij_^eh`_gguo ^ey lbljh\Zgby Zexfbgby
gZb[hevr__ agZq_gb_ bf__l ^bZfbghpbdeh]_dkZgl_ljZmdkmkgZy dbkehlZ >PL: . HgZ
hq_gv [ukljh j_Z]bjm_l k Zexfbgb_f m`_ ijb dhfgZlghc l_fi_jZlmj_ b djhf_ wlh]h k
[hevrbgkl\hff_lZeeh\h[jZam_lg_kdhevdhbgu_dhfie_dkug_`_ebdhfie_dkhgZluW>L:.

12
GZijbf_jijblbljh\Zgbb>PL: \hafh`ghfZkdbjh\Zgb_f_^blbhfhq_\bghcZlZd`_hi-
j_^_e_gb_Zexfbgby\ijbkmlkl\bbojhfZb\ijbkmlkl\bb[hevrh]hdhebq_kl\ZojhfZlZg_
hdbkeyxs_]hdhfie_dkhg [3].

3.3.5Hdbkebl_evgh\hkklZgh\bl_evgh_lbljh\Zgb_
GZb[he__ jZkijhkljZgzgguc f_lh^ hdbkebl_evgh\hkklZgh\bl_evgh]h lbljh\Zgby
Zexfbgbyk\yaZgkhkZ`^_gb_fhdkbobghebgZlZAZl_fhkZ^hdjZkl\hjyxl\dbkehl_bhi-
j_^_eyxlhdkbobghebgkihfhsvx[jhfZlhf_ljbbbebbh^hf_ljbbMkeh\byk_e_dlb\gh]h
hkZ`^_gby hdkbobghebgZlZ Zexfbgby hibkZgu \  Ij_bfms_kl\hf ijbf_g_gby lbl-
jh\ZgbyZg_]jZ\bf_ljbby\ey_lkyf_gvrZyijh^he`bl_evghklvZgZebaZijblhc`_lhqgh-
klbhij_^_e_gby [7].
<hafh`ghhkZ`^_gb_Zexfbgby\\b^_Zjk_gZlZjZkl\hj_gb_hkZ^dZ\dbkehl_\hkklZ-
gh\e_gb_ ^h Zjk_gblbhgZ b lbljh\Zgb_ ihke_^g_]h jZkl\hjhf bh^Z F_lh^ ^hklZlhqgh k_-
e_dlb\_g b lhq_g gh fZehijb]h^_g ^ey ZgZebaZ baaZ \ukhdhc lhdkbqghklb kh_^bg_gbc
furvydZ [3].

3.3.6Dbkehlghhkgh\gh_lbljh\Zgb_ [3].
>Zgguc f_lh^ k_cqZk jZkijhkljZg_gu ^hklZlhqgh fZeh \\b^m k\h_c gbadhc lhqghklb
H^bgbakihkh[h\hij_^_e_gbyZexfbgbydbkehlghhkgh\guflbljh\Zgb_fk\yaZgki_j_\_-
^_gb_f _]h \ ]b^jhdkhdhfie_dk b ^Zevg_crbf ^h[Z\e_gb_f ba[uldZ nlhjb^Z gZljby Ijb
wlhf\u^_eyxlky]b^jhdkb^bhgudhlhju_g_cljZebamxlba[uldhfjZkl\hjZdbkehluHklZ-
lhddbkehluhllbljh\u\ZxlklZg^ZjlgufjZkl\hjhf]b^jhdkb^ZgZljby<hafh`gub^jm]b_
f_lh^ugZijbf_jhkZ`^_gb_]b^jhdkb^ZZexfbgbyjZkl\hj_gb_\ba[uld_dbkehlublbl-
jh\Zgb_hklZldZdbkehluhkZ`^_gb_hkgh\gh]hdZj[hgZlZZexfbgby_]hihke_^mxs__jZk-
l\hj_gb_ \ klZg^Zjlghf jZkl\hj_ nhknhjghc dbkehlu b lbljh\Zgb_ jZkl\hjZ kh^_j`Zs_]h
Al(H2PO4)3, szehqvx ?klv lZd`_ ]jmiiZ ZedZebf_ljbq_kdbo f_lh^h\ hkgh\Zgguo gZ h[jZ-
ah\Zgbbdhfie_dkh\Zexfbgbykhj]Zgbq_kdbfbhdkbdbkehlZfbbhllbljh\u\Zgbb\u^_eb\-
rbokyijhlhgh\

<u\h^u
GZhkgh\_ZgZebaZebl_jZlmjguo^Zgguo[uehj_r_ghbkihevah\Zlv^\_f_lh^bdbjZk-
l\hj_gbykieZ\Z±\szehqb ih[4]) b\kf_kbZahlghcbkheyghcdbkehl ih [2]). >hklhbgkl-
\hfi_j\h]hf_lh^Zy\ey_lky\hafh`ghklvihqlbihegh]hhl^_e_gbyf_^bg_ihkj_^kl\_ggh
ijbjZkl\hj_gbbg_^hklZldhf±\hafh`ghklvg_ihegh]hi_j_oh^ZZexfbgby\jZkl\hjIj_-

13
bfms_kl\h\lhjh]hf_lh^Z±ihegh_jZkl\hj_gb_h[jZapZF_lh^jZa^_e_gby±hkZ`^_gb_
ZffbZdhfkihke_^mxsbfi_j_hkZ`^_gb_f.
>ey dhebq_kl\_ggh]h hij_^_e_gby j_r_gh [ueh bkihevah\Zlv ^\Z kihkh[Z h[jZlgh_
dhfie_dkhghf_ljbq_kdh_ lbljh\Zgb_ jZkl\hjZ h[jZapZ \ szehqb jZkl\hjhf kheb f_^b k
I:Gb]jZ\bf_ljbq_kdh_hij_^_e_gb_hkZ`^_gb_f]b^jhdkb^ZZexfbgbyZffbZdhfbajZk-
l\hjZh[jZapZ\dbkehlZo

14
4. Wdki_jbf_glZevgZyqZklv

=jZ\bf_ljbq_kdh_hij_^_e_gb_Zexfbgby
Ko_fZZgZebaZ

JZkqzlb\a\_rb\Zgb_gZ\_kdbh[jZapZ
Ijb[ebabl_evgh_kh^_j`Zgb_Zexfbgby\kieZ\_±HkZ^hd]b^jhdkb^ZZexfbgby
Zfhjnguc ihwlhfm hilbfZevgZy fZkkZ ]jZ\bf_ljbq_kdhc nhjfu m = 0,07 –  ] =jZ\b-
f_ljbq_kdbc nZdlhj F =  <_ebqbgm gZ\_kdb jZkkqblu\Zxl ih nhjfme_
mF 0,1⋅ 0,5292
g= 100 = 100 ≈ 0, 0962 ]
P 55
<a\_rb\Zgb_gZ\_kdb
FZkkZ[xdkZk FZkkZimklh]h
‹
h[jZaphf] [xdkZ]
FZkkZ[xdkZkh[jZaphf]
1 23,5148 23,3554 FZkkZimklh]h[xdkZ]
FZkkZgZ\_kdb]
2 23,5151 23,3551
3 23,5149 23,3553

15
F_lh^bdZjZkl\hj_gby
Lhqgh\a\_r_ggmxgZ\_kdmkieZ\Zi_j_ghkyl\obfbq_kdbcklZdZggZfeb^h[Z\-
eyxlkf_kvfedhgp_gljbjh\ZgghcHCl bfeFHNO3. Hklhjh`ghgZ]j_\Zxlijbih-
klhygghf i_j_f_rb\Zgbb ^h ij_djZs_gby \u^_e_gby ]ZaZ b ihegh]h jZkl\hj_gby h[jZapZ
AZl_fhoeZ`^ZxlbjZa[Z\eyxl\h^hc^hfe

F_lh^bdZboh^hij_^_e_gby
F_lh^bdZhij_^_e_gbybkke_^m_fucjZkl\hjgZ]j_\Zxlihqlb^hdbi_gby\\h^ylg_-
kdhevdh dZi_ev f_lbeh\h]h djZkgh]h b ba [xj_ldb ^h[Z\eyxl ih dZieyf jZkl\hj ZffbZdZ
 ^hbaf_g_gbyhdjZkdbbadjZkghc\`zelmx<h\j_fyijb[Z\e_gbyZffbZdZjZkl\hjg_-
ij_ju\gh i_j_f_rb\Zxl GZ]j_\Zxl jZkl\hj  fbg ^Zxl hlklhylvky hkZ^dm \ l_q_gb_ 
fbgbhlnbevljh\u\ZxlgZnbevlj©djZkgZye_glZªIheghklvxi_j_ghkylhkZ^hdgZnbevlj
b, ^h[Z\eyxl  F HCl, jZkl\hjyxl hkZ^hd gZ nbevlj_ kh[bjZy jZkl\hj \ qbkluc klZdZg
Ih\lhjyxlhi_jZpbxhkZ`^_gbyjZkl\hj\gh\vhlnbevljh\u\ZxlgZnbevlj©kbgyye_glZª
Ijhfu\ZxlgufjZkl\hjh\NH4NO3, g_cljZebah\ZggucZffbZdhfih f_lbeh\hfm djZk-
ghfm^_dZglZpb_c±jZaZi_j_ghkylhkZ^hdgZnbevljb\gh\vijhfu\Zxll_f`_jZkl\h-
jhf ^h hljbpZl_evghc j_Zdpbb gZ oehjb^bhgu ih jZkl\hjm AgNO3, ih^dbke_gghfm  F
HNO3) \ nbevljZl_. <hjhgdm k nbevljhf ihf_sZxl \ kmrbevguc rdZn b ke_]dZ ih^kmrb-
\Zxl hkZ^hd AZl_f nbevlj k hkZ^dhf ihf_sZxl \ ^h\_^zgguc ^h ihklhygghc fZkku ijb
l_fi_jZlmj_hdheh 0Klb]_evhklhjh`ghgZ]hj_ed_h[m]eb\Zxlnbevljihke_q_]hih-
f_sZxllb]_ev\fmn_evgmxi_qvbijhdZeb\Zxlqijbl_fi_jZlmj_hdheh 0KIjhdZ-
eb\Zgb_hkZ^dZih\lhjyxl^h^hklb`_gbyihklhygghcfZkku
<a\_rb\Zgb_lb]ey
FZkkZimklh]h FZkkZlb]eyk
‹
lb]ey] \_s_kl\hf]
FZkkZimklh]hlb]ey699]
1 12,3704 12,5429 FZkkZlb]eyk\_s_kl\hf2]
FZkkZAl2O3: 0,1723]
2 12,3700 12,5421
3 12,3699 12,5421

JZkqzlkh^_j`Zgby:
mAl = F ⋅ mAl2O3 = 0,5292 ⋅ 0,1723 = 0, 0912 ]
0, 0912
ω Al = 100% ≈ 57, 07%.
0,1598

16
4.2. Dhfie_dkhghf_ljbq_kdh_hij_^_e_gb_Zexfbgby
Ko_fZZgZebaZ

JZkqzlb\a\_rb\Zgb_gZ\_kdb
Ijb[ebabl_evghkh^_j`Zgb_ZexfbgbyZexfbgby\kieZ\_±JZkl\hjm^h[ghkh-
[jZlv\f_jgmxdhe[mgZfedhgp_gljZpbybhgh\Zexfbgbyg_h[oh^bfZy^eydhfie_d-
khghf_ljbq_kdh]hlbljh\Zgbyk FIhwlhfmfZkkZgZ\_kdb
cVM Al 0, 04 ⋅ 0, 2 ⋅ 26,98154
g= 100 = 100 ≈ 0,3925 ]
P 55

<a\_rb\Zgb_gZ\_kdb
FZkkZ[xdkZk FZkkZimklh]h
‹
h[jZaphf] [xdkZ]
FZkkZ[xdkZkh[jZaphf]
1 23,8464 23,3569 FZkkZimklh]h[xdkZ]
FZkkZgZ\_kdb]
2 23,8465 23,3568
3 23,8464 23,3569

4F_lh^bdZjZkl\hj_gby
Lhqgh\a\_r_ggmxgZ\_kdmkieZ\Zi_j_ghkyl\obfbq_kdbcklZdZggZfeb^h[Z\-
eyxlfeghcszehqb. Hklhjh`ghgZ]j_\Zxlijbihklhygghfi_j_f_rb\Zgbb^hij_-
djZs_gby\u^_e_gby]ZaZIhemq_ggucjZkl\hjjZa[Z\eyxl\h^hc^h fe hlnbevljh\u-

17
\ZxlgZnbevlj_©[_eZye_glZªNbevljZlkh[bjZxl\f_jgmxdhe[mgZfeb^h\h^yl^h
f_ldbijbeb\ZyHCl (1:1).

F_lh^bdZboh^hij_^_e_gby
F_lh^bdZ Zebd\hlmfeihemq_ggh]hjZkl\hjZi_j_ghkyl\dhgbq_kdmxdhe[m^ey
lbljh\ZgbygZfe^h[Z\eyxlfeklZg^Zjlgh]hjZkl\hjZW>L: k ~ 0,05 F Zp_lZl-
guc[mn_j^hpH bgZ]j_\Zxl\l_q_gb_fbgg_^h\h^y^hdbi_gbyD]hjyq_fmjZkl\hjm
^h[Z\eyxlg_kdhevdhdZi_ev]hwlZghevgh]hjZkl\hjZI:GblbljmxlklZg^ZjlgufjZk-
l\hjhfCuSO4 ^hi_j_oh^ZhdjZkdbba`zelhc\qbklhnbhe_lh\mx
J_amevlZlulbljh\Zgby
‹ V (CuSO4), fe
1 12,87 Kj_^gbch[tzfjZkl\hjZCuSO4, ihr_^rbcgZ
lbljh\Zgb_V = fe
2 12,98
3 12,92
4 12,90

JZkqzlkh^_j`Zgby
k KuSO4) =  F k W>L:    F ihwlhfm h[tzf W>L: hllbljh\Zgguc jZk-
c(CuSO 4 ) ⋅V (CuSO 4 ) 0, 02 ⋅12,91
l\hjhf CuSO4 khklZ\ey_l V1 = = ≈ 5, 23 fe  H[tzf W>L:
c(W>L:  
ihr_^rbcgZlbljh\Zgb_Al3+ khklZ\ey_l V2 = V0 − V1 = 15, 00 − 5, 23 = 9, 77 fe LZdbfh[jZahf

V2 ⋅ c (W>L: 9, 77 ⋅ 0, 04937
dhgp_gljZpbyZexfbgby\jZkl\hj_khklZ\beZ cAl = = ≈ 0, 0483 M.
V (Al3+ ) 10, 00
 fe ijb]hlh\e_ggh]h jZkl\hjZ kh^_j`Zeb mAl = cAl ⋅ V ⋅ M Al = 0, 0483 ⋅ 0, 2 ⋅ 26,98154 ≈

0, 2608
≈ 0, 2608 ] ω Al = 100 ≈ 53, 27%.
0, 4896

18
AZdexq_gb_
<oh^_jZ[hluijh\_^zgdZq_kl\_ggucZgZebah[jZapZZlZd`_dhebq_kl\_ggh_hij_^_-
e_gb_ kh^_j`Zgby h^gh]h ba hkgh\guo dhfihg_glh\ IhdZaZgh qlh ZgZebabjm_fuc h[t_dl
y\ey_lky kieZ\hf Zexfbgby b f_^b k g_[hevrbfb ijbf_kyfb `_e_aZ b heh\Z Kh^_j`Zgb_
Zexfbgby\kieZ\_khklZ\ey_l
– ihj_amevlZlZf]jZ\bf_ljbq_kdh]hZgZebaZ
– ihj_amevlZlZflbljbf_ljbq_kdh]hZgZebaZ

19
Kibkhdebl_jZlmju
1. Hkgh\uZgZeblbq_kdhcobfbbIjZdlbq_kdh_jmdh\h^kl\h/Ih^j_^X:Ahehlh\Z
F<ukrZyrdheZk
2. ;hdJF_lh^ujZaeh`_gby\ZgZeblbq_kdhcobfbbFObfbyk
3. Lbohgh\<G:gZeblbq_kdZyobfbyZexfbgbyFGZmdZk
4. >ufh\:FL_ogbq_kdbcZgZebajm^bf_lZeeh\FF_llZemj]ba^Zlk
5. =bee_j[jZg^<NE_g^_ev=W;jZcl=:=hnfZg>BIjZdlbq_kdh_jmdh\h-
^kl\hihg_hj]Zgbq_kdhfmZgZebamF=hkobfba^Zlk
6. Pbg[_j]KEAZ\h^kdZyeZ[hjZlhjbyL‹K±
7. RZjeh = F_lh^u ZgZeblbq_kdhc obfbb Dhebq_kl\_gguc ZgZeba g_hj]Zgbq_kdbo
kh_^bg_gbcQFObfbyk

20

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