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Effect of The Switching Time On The Performance of An Adsorption Chiller
Effect of The Switching Time On The Performance of An Adsorption Chiller
www.springerlink.com/content/1738-494x(Print)/1976-3824(Online)
DOI 10.1007/s12206-016-0449-2
(Manuscript Received September 16, 2015; Revised December 26, 2015; Accepted January 11, 2016)
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Abstract
The switching time is an important operating condition that must be correctly anticipated for an effective adsorption cooling system.
Before the adsorption (or desorption) process begins, time is required to cool down (or heat up) the bed temperature so that the bed pres-
sure reaches the evaporator pressure (or condenser pressure). During the switching time, the supplied heat is reduced and pressure over-
load conditions can be avoided. The switching time cannot be estimated early on, and an improper switching time degrades the system
performance. Thus, this study provides guideline with which to determine the required time to open this valve, i.e., the switching time,
and carefully examines the thermo-physical behavior in the adsorption bed during this period. A two-dimensional numerical method with
the composite sorbent of SWS-1L and a water pair is applied to a fin-tube type adsorption chiller. Three cases of no switching time, the
optimal switching time and a double the optimal switching time are examined. The results show that no consideration of the switching
time overestimates the performance of the adsorption cooling system in terms of the Coefficient of performance (COP) and the Specific
cooling power (SCP). On the other hand, if the switching time exceeds the optimal value, the performance of the adsorption cooling sys-
tem is also reduced compared to that when using the optimal switching time. The dependency of the optimal switching times on various
design parameters, such as the fin pitch, fin height and heating temperature, is also examined.
Keywords: Switching time; Adsorption chiller; COP; SCP
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tance causes system delays, unlike an ideal cycle, where inter- Table 1. Parameter values and operating conditions.
particle mass transfer resistance is neglected. Thus, an analysis
Parameter Symbol Values
which considers the switching time is more accurate for esti-
Fin pitch Zo 3 mm
mating the system performance levels of adsorption chillers.
Saha et al. [10] examined the effect of the switching time on Fin height Lo 10 mm
the system performance using a numerical method. A CaCl2- Fin thickness δ 0.5 mm
in-silica gel (SWS-1L)-water system was used with a fin-tube Inner diameter of metal tube Di 10 mm
type adsorption chiller. The optimal switching time, showing Outer diameter of metal tube Do 12 mm
the highest cooling capacity, was determined. Niazmand and Particle diameter Dp 200 μm
Dabzadeh [12] considered the mass and energy balance during Evaporator temperature Teva 15°C
an isosteric process and calculated the boundary pressure at Condenser temperature Tcon 30°C
the bed and chamber interface. With this, they examined the
Cooling temperature TL 30°C
temperature, water uptake distribution and velocity field.
Heating temperature TH 80°C
However, they overlooked the impact of the switching time on
Average fluid velocity uf 1 m/s
the system performance and also the dependency of the
switching time on the bed geometries or various operating Density of adsorbent ρb 700 kg/m3
conditions. Mahdavikhah and Niazmand [13] examined the Specific heat of adsorbent CP,b 920 J/kg K
pressure and velocity fields during the isosteric phase and Thermal conductivity of adsorbent kb 0.2 W/m K
isobaric phase for a plate fin-tube type adsorption chiller with Heat of adsorption ΔH 2760000 J/kg
SWS-1L. They ascertained that as the number of fins in- Porosity of the particle εp 0.43
creases, which enhances the heat transfer due to the extended Porosity of the bed εb 0.36
surface, the time required for the isosteric process becomes
shorter, i.e., a shorter switching time. Myat et al. [14] studied
the variation of the COP with the switching time for a driving aims to estimate the optimal switching time based on several
heat source temperature range of 55°C ~80°C, finding that the important parameters (the fin pitch, fin height and heating
lower the driving heat temperature, the longer the switching temperature) for a SWS-1L/water fin-tube type adsorption
time. El-Sharkawy et al. [8] studied system performance im- chiller [7, 10, 12, 13].
provements in terms of the cooling capacity and the COP by a
reallocation of adsorption/desorption cycle times. A lumped 2. Numerical method
parameter model was used to describe the energy balance of
2.1 Mathematical model
adsorber/desorber reactors in which both the adsorbent and
heat exchanger metals are assumed to be at the same tempera- Fig. 1 shows the schematics of the transient two-dimensional
ture. The result showed that the system COP increases with an numerical model used here to solve the heat and mass transfer
increase in the adsorption/desorption time and that the effect kinetics of an adsorption bed. The parameter values and typical
of switching time is marginal. They performed an excellent operating conditions are shown in Table 1. More details can be
analysis of the system performance, including the effect of the found in the authors’ other researches [6, 7].
switching time. However, the lumped parameter model has an
inherent limitation because it does not include the effects of
2.2 Assumptions
design parameters such as the bed geometry. No studies have
attempted to find the optimal switching time according to The mathematical modeling is based on the following as-
design parameters or operating conditions. sumptions [7, 10, 12, 13].
The importance of the switching time has been well recog- (1) The particles in the adsorption bed are all spherical with
nized, and the switching time was included in an analysis to a uniform size and uniform porosity.
develop a more practical model for estimating the system (2) Local thermal equilibrium between the adsorbed and
performance of an adsorption chiller. However, with regard to vapor phases is assumed.
experiments, it is not easy to find the appropriate switching (3) The flow in the adsorption bed is axisymmetric.
time for every specific case, with various geometries and dif- (4) The adsorbed phase is assumed to be liquid and the re-
ferent operating conditions. Thus, it is common to determine frigerant vapor is considered to be an ideal gas.
the optimal switching time by trial and error. If the chosen (5) No heat loss through the chamber wall is considered and
switching time is too short, the performances of the condenser the effect of radiation heat transfer is assumed to be negligible.
and evaporator are reduced and more heat energy is required (6) The thermo-physical properties of the thermal fluid, tube,
due to the absence of pre-heating and pre-cooling phases. On fins, dry adsorbent, adsorbate liquid, and gas are assumed to
the other hand, if the switching time is too long, the perform- be constant except for the density of the adsorbate gas.
ance of the adsorption bed is degraded and the system durabil- (7) The condenser and evaporator are assumed to be ideal
ity worsens due to a pressure overload. Therefore, this study with a constant pressure and temperature during all processes.
S. W. Hong et al. / Journal of Mechanical Science and Technology 30 (5) (2016) 2387~2395 2389
2.3 Governing equations Substituting Eq. (2) into Eq. (1) yields the final form of the
non-isobaric model with respect to the dependent variable P,
Our recent research showed that the inter- and intra-particle as follows:
mass transfer kinetics have a considerable influence on the
simulation results and it is highly recommended to choose æ P ö
¶ç ÷
models which consider a valid range of the diffusion ratio [6, RT æ K ö ¶q
15]. D/rp2 = 0.000368 is larger than the critical value e t è v ø = Ñ × ç r v app ÑP ÷ - r v =0. (8)
¶t è m ø ¶t
(0.000192) of silica gel (Hong et al. (2014)). Thus, in the pre-
sent study, a non-isobaric model and a Linear driving force
(LDF) model are used for the inter- and intra-particle mass LDF model
transfer models, respectively. ¶q D æ E ö *
= 15 2so exp çç - a ÷÷ ( q - q ) . (9)
¶t rp è RuTb ø
Non-isobaric model
¶r r ¶q In this model, Dso is a pre-exponent constant and Ea denotes
e t v + Ñ × ( r vuv ) + r v =0 (1)
¶t ¶t the activation energy of diffusion, with values of 0.000254
m2/s and 42000 J/mol, respectively. q represents the equilib-
r
where uv is the velocity of the vapor through the adsorption rium water uptake, as determined by an isotherm curve which
bed, which can be determined by Darcy’s law, is dependent on the type of adsorbent used. In this study, the
isotherm curve of SWS-1L from Saha et al. [10] is used.
r K
uv = - app ÑP (2)
mv 1.6 ´ 10-12 Cq*
q* = 1/1.1
(10)
1.1
é ù
where μ is the viscosity of the vapor and Kapp denotes the per- ( -12
êë1 + 2 ´ 10 Cq* ) úû
meability of the porous bed, as obtained by the following pro- æ DH ö
cedures [16-18]: Cq* = Pexp çç ÷÷ . (11)
è RvTb ø
e b mv
K app = K d + Deq (3) The energy equation for the adsorption bed is
tP
3 2
e d
Kd = b p
(4) ¶Tb r
150 (1 - e b )
2
r CP + Ñ × ( r vC P,v uvTb )
¶t
-1
æ ö ¶q
ç ÷ = Ñ × ( kbÑTb ) + r b DH (12)
1 1 ¶t
Deq = ç + ÷ (5)
ç 3
T /M 48.5d pore Tb / M v ÷
ç 0.02628 b 2 v ÷ where ρCP denotes the total heat capacity, which can be ex-
è Ps W ø
pressed as follows:
d pore = 0.6166d p (6)
-0.4
t =e b . (7) r CP = e t ( r vCP,v ) + r b ( CP,b + qCP,a ) (13)
notes the amount of heat energy transferred from the heat where hCR denotes the contact resistance between the adsorp-
transfer fluid to the adsorption bed. The convection coefficient tion bed and the fin-tube surface, which is obtained by the
h is determined by the following correlation [19]: correlation designed by Zhu and Wang [20].
2.4 Initial and boundary conditions Boundary conditions for heat transfer fluid
Initial conditions
Tf = TL at Z = 0 (28)
Adsorption process
for the isosteric and isobaric cooling phases.
Rm < R < Ro , 0 < Z < Z o : Tinitial = Tdes
Pinitial = Pcon (18) Tf = TH at Z = 0 (29)
0 < r < rp , qinitial = qdes . (19)
for the isosteric and isobaric heating phases.
Desorption process
2.5 Performance index
Rm < R < Ro , 0 < Z < Z o : Tinitial = Tads
The widespread application of adsorption systems is limited
Pinitial = Peva (20)
by their relatively large size and low performance compared to
0 < r < rp , qinitial = qads . (21) other types of refrigeration systems. In order to examine the
effect of the switching time on the performance of the adsorp-
Boundary conditions tion chiller, the COP and SCP are used. These are defined by
the following equations:
The boundary conditions for an adsorbent particle are de-
termined via
Qeva
COP = (30)
*
Qin
r = rp : q = q (22)
Qeva
SCP = . (31)
M btcycle
where q can be obtained from Eq. (10).
The boundary conditions for the adsorption bed are deter-
mined by In these equations, Qeva denotes the cooling energy ob-
tained from the evaporator and Qin denotes the input heat
¶Tc energy supplied to the adsorption bed from the heating water
R = Ri , 0 £ Z £ Z o : h (Tc - Tf ) = kc (23)
¶R during the desorption process. Mb is the total mass of the solid
R = Rm , 0 £ Z £ Z o : sorbent and tcycle indicates the cycle time.
S. W. Hong et al. / Journal of Mechanical Science and Technology 30 (5) (2016) 2387~2395 2391
(a) (b)
Fig. 3. Variations of (a) COP; (b) SCP as a function of the switching time for various fin pitches.
(a) (b)
Fig. 4. Variations of (a) COP; (b) SCP as a function of the switching time for various fin heights.
(a) (b)
Fig. 5. Variations of (a) COP; (b) SCP as a function of the switching time for various heating temperatures.
S. W. Hong et al. / Journal of Mechanical Science and Technology 30 (5) (2016) 2387~2395 2393
4. Conclusion
Fig. 7. Variations of the optimal switching time for various fin heights This study examined the effect of the switching time on the
with fin pitch of 3 mm.
system performance of a SWS 1L/water fin-tube type adsorp-
tion chiller by a numerical method. Switching time is required
to operate the adsorption cooling cycle for the pre-cooling and
pre-heating processes, where the valve connecting the adsorp-
tion bed with the evaporator or condenser is closed until the
bed pressure reaches the pressure of the evaporator or the con-
denser. Complex transport phenomena in the adsorption bed
during isosteric processes were carefully examined. The re-
sults are given below.
(1) Three switching time cases (0 s, the optimal switching
time, and a double the optimal switching time) are considered
while changing the parameters of the fin pitch, fin height and
heating temperature. The COP and SCP decrease as the
switching time increases due to the reduced inter-particle mass
Fig. 8. Variations of the optimal switching time for various heating
temperatures with fin pitch of 3 mm and fin height of 12 mm.
transfer capacity during the isosteric process. The COP and
SCP are overestimated by as much as 3.4% and 2.9%, respec-
tively, when no switching time is considered, and correspond-
shorter than that of the isosteric cooling phase. As the fin pitch ingly they decrease by as much as 3.8% and 5.2% when the
increases, the optimal switching time also increases, as the switching time is doubled compared to the optimal switching
increased volume requires extra heat energy to heat up or cool time. However, the increased performance in the case of no
down the adsorption bed during the isosteric phase. Therefore, switching time or an extremely short switching time is unreal-
more time is required to increase or decrease the bed pressure istic due to the assumption of a constant pressure which is
to Pcon or Peva. maintained in the evaporator and the condenser. As discussed
Fig. 7 shows the variations of the optimal switching times earlier, in real situations, the performance will decrease if the
for various fin heights. The fin height is related to the volume switching time is not long enough and optimal switching
of the adsorption bed, as is the fin pitch. Therefore, the opti- times are available for a high COP and SCP.
mal switching time increases for the same reason associated (2) The COP and SCP with the optimal switching time were
2394 S. W. Hong et al. / Journal of Mechanical Science and Technology 30 (5) (2016) 2387~2395
estimated for various fin pitches, fin heights and heating tem- STopt : Optimal switching time (s)
peratures. The optimum values of the fin pitch (3 mm), fin T : Temperature (K)
height (12 mm) and heating temperature (85°C) were found t : Time (s)
for COP. On the other hand, SCP increases with a decrease in Z : Axial distance (mm)
the fin pitch and fin height and with an increase in the heating Zo : Fin pitch (mm)
temperature.
(3) The switching time increases monotonically with an in-
Greek symbols
crease in the fin pitch and the fin height and decreases with an
increase in the heating temperature. α : Thermal diffusivity (m2/s)
(4) The optimal switching time for the isosteric heating δ : Fin thickness (mm)
phase is shorter than that of the isosteric cooling phase. σ : Collision diameter for Lennard-Jones potential (Å)
ε : Porosity (-)
ρ : Density (kg/m3)
Acknowledgment
μ : Dynamic viscosity (Pa s)
This work was supported by the Energy Efficiency & Re- ν : Kinematic viscosity (m2/s)
sources (No. 20122010100120) of the Korea Institute of En- τ : Tortuosity factor (m2/s)
ergy Technology Evaluation and Planning (KETEP) grant Ω : Collision integral
funded by the Korea Government Ministry of Knowledge
Economy.
Subscripts
Nomenclature------------------------------------------------------------------------ a : Adsorbent
ads : Adsorption process
A : Area (m2) b : Solid adsorbent
CP : Specific heat (J/kg K) c : Copper
COP : Coefficient of performance (-) cycle : Cycle
Deq : Equivalent diffusivity (m2/s) con : Condenser
Dso : Pre-exponent constant of surface diffusivity (m2/s) eva : Evaporator
Di : Inner tube diameter (mm) f : Fluid
dp : Particle diameter (mm) H : High
dpore : Equivalent pore diameter (mm) i : Inner
Ea : Activation energy of diffusion (J/mol) in : Inlet
h : Convection coefficient (W/m2 K) initial : Initial condition
1/hCR : Contact resistance (m2 K/W) L : Low
ΔH : Heat of adsorption (J/kg) m : Middle
Kapp : Apparent permeability of adsorbent bed (m2) o : Outer
Kd : Bed permeability (m2) out : Outlet
k : Thermal conductivity (W/m K) p : Particle
Le : Latent heat at evaporation temperature (J/kg) t : Total
Lo : Fin height (mm) v : Vapor
Lv : Latent heat of vaporization (J/kg)
Mb : Mass of adsorbent (kg)
Mv : Molar mass of vapor (kg/mol)
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