RESOLUCION DE EJERCICIOS

POR MEDIO DE LA ECUACION DE

LEE KESLER
HECHO POR: Huayta Farfán Mariela de la Merced Zolanch
SEMESTRE: 6º
CALCULAR Z Y V PARA EL VAPOR DE AGUA A 400 C Y 40 BAR
MEDIANTE LA ECUACION DE LEE KESLER
𝑇 = 400𝐶 = 673.15𝐾
𝑃 = 40𝐵𝑎𝑟
𝑃𝑐 = 220.55 𝐵𝑎𝑟
𝑇𝑐 = 647.1 𝐾
𝜔 = 0.345
𝑃. 𝑀. = 18.015𝑔/𝑚𝑜𝑙
𝑇𝑟 = 1.021.05

𝑇𝑟 𝑃𝑟
𝑃𝑟1= 0.10 𝑃𝑟 = 0.1813 𝑃𝑟2 = 0.20
𝑇𝑟1 = 1.02 0.9969 0.9343
𝑇𝑟 = 1.0402 𝑍0
𝑇𝑟2 = 1.05 0.9971 0.9401
 0
0.20 − 0.1813 0.1813 − 0.10
𝑍 = [( ) ∗ 0.9969 + ( ) ∗ 0.9343]
0.20 − 0.10 0.20 − 0.10
1.05 − 1.0402
∗( )
1.05 − 1.02
0.20 − 0.1813 0.1813 − 0.10
+ [( ) ∗ 0.9971 + ( )
0.20 − 0.10 0.20 − 0.10
1.0402 − 1.02
∗ 0.9401] ∗ ( )
1.05 − 1.02
𝑍 0 = 0.9518

𝑇𝑟 𝑃𝑟
𝑃𝑟1= 0.10 𝑃𝑟 = 0.1813 𝑃𝑟2 = 0.20
𝑇𝑟1 = 1.02 -0.0051 -0.0102
𝑇𝑟 = 1.0402 𝑍1
𝑇𝑟2 = 1.05 -0.0029 -0.0054

0.20 − 0.1813 0.1813 − 0.10

𝑍1 = [( ) ∗ (−0.0051) + ( )
0.20 − 0.10 0.20 − 0.10
1.05 − 1.0402
∗ (−0.0102)] ∗ ( )
1.05 − 1.02
0.20 − 0.1813 0.1813 − 0.10
+ [( ) ∗ (−0.0029) + ( )
0.20 − 0.10 0.20 − 0.10
1.0402 − 1.02
∗ (−0.0054)] ∗ ( )
1.05 − 1.02
𝑍1 = −0.0063
𝑍 = 𝑍 0 + 𝜔 ∗ 𝑍1 = 0.9518 + 0.345 ∗ (−0.0063)
𝑍 = 0.9496
 0.9496 ∗ 83.14 ∗ 673.15
𝑉= = 1328.6255 𝑐𝑚3 /𝑚𝑜𝑙
40
(1 − 0.9496)
%𝐸𝑟𝑟𝑜𝑟 = 100 ∗ = 5.04%
1

CALCULAR Z Y V PARA EL VAPOR DE ETILENO A 25C Y 12 BAR

MEDIANTE LA ECUACION DE LEE KESLER
𝑇 = 25°𝐶 = 298.15𝐾
𝑃 = 12 𝐵𝑎𝑟
𝑃𝑐 = 50.40𝐵𝑎𝑟
𝑇𝑐 = 282.3𝐾
𝜔 = 0.087
𝑃. 𝑀. = 28.054
𝑇𝑟 = 1.051.10

𝑇𝑟 𝑃𝑟
𝑃𝑟1= 0.20 𝑃𝑟 = 0.2380 𝑃𝑟2 = 0.40
𝑇𝑟1 = 1.05 0.9401 0.8743
𝑇𝑟 = 1.0561 𝑍0
𝑇𝑟2 = 1.10 0.9485 0.8930
 0
0.40 − 0.2380 0.2380 − 0.20
𝑍 = [( ) ∗ 0.9401 + ( ) ∗ 0.8743]
0.40 − 0.20 0.40 − 0.20
1.10 − 1.0561
∗( )
1.10 − 1.05
0.40 − 0.2380 0.2380 − 0.20
+ [( ) ∗ 0.9485 + ( )
0.40 − 0.20 0.40 − 0.20
1.0561 − 1.05
∗ 0.8930] ∗ ( )
1.10 − 1.05
𝑍 0 = 0.9288

𝑇𝑟 𝑃𝑟
𝑃𝑟1= 0.20 𝑃𝑟 = 0.2380 𝑃𝑟2 = 0.40
𝑇𝑟1 = 1.05 -0.0054 -0.0092
𝑇𝑟 = 1.0561 𝑍1
𝑇𝑟2 = 1.10 0.0007 0.0038

0.40 − 0.2380 0.2380 − 0.20

𝑍1 = [( ) ∗ (−0.0054) + ( )
0.40 − 0.20 0.40 − 0.20
1.10 − 1.0561
∗ (−0.0092)] ∗ ( )
1.10 − 1.05
0.40 − 0.2380 0.2380 − 0.20
+ [( ) ∗ (0.0007) + ( )
0.40 − 0.20 0.40 − 0.20
1.0561 − 1.05
∗ (0.0038)] ∗ ( )
1.10 − 1.05
𝑍1 = −0.0052

𝑍 = 0.9288 + 0.087 ∗ (−0.0052) = 0.9283

0.9283 ∗ 83.14 ∗ 298.15
𝑉= = 1917.5731 𝑐𝑚3 /𝑚𝑜𝑙
12
 (1−0.9283)
%𝐸𝑟𝑟𝑜𝑟 = 100 ∗ =7.17%
1