Question Paper

(Batches: SANKALP – 921 Lot)
IIT – JEE, 2021 Paper Code

100276
(CLASS XII)
Time: 1 ½ Hours Maximum Marks: 108
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.
B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section 1 contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE is correct.
5. Section 2 contains 2 paragraphs. Based upon one of the paragraphs 3 multiple choice questions and
based on the other paragraph 2 multiple choice questions have to be answered. Each of these questions
has four choices (A), (B), (C) and (D) out of the ONLY ONE is correct.
6. Section 3 contains 2 questions. The answer to each of the questions is a single-digit integer, ranging from 0
to 9 (both inclusive)
C. Marking Scheme
7. For each question you will be awarded 3 marks if you darken only the bubble corresponding to the correct
answer and zero mark if no bubble is darkened. In all other cases, minus one (−1) mark will be awarded.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax
26513942
website: www.fiitjee.com.
IT-2021-SANKALP-921 Lot-XII-PCM-(100276)-2
PART I : PHYSICS
SECTION – 1 : (Only One Options Correct Type)
This section contains 5 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
1. Charge Q is distributed on a small hollow conducting sphere

(radius r) as shown inside a spherical cavity of radius r1
made inside a solid conducting sphere of radius r2 as shown r1
Q
in the figure. The total energy of the system is r
 1 1 1
(A) kQ2  − +  r2
2r
 2 2r1 2r 
1 1 1 
(B) KQ2  + + 
 r1 r2 2r 
 1 1 1
(C) kQ2  + + 
 2r1 4r2 2r 
 1 1 1
(D) kQ2  + + 
4r
 1 2r2 2r 
2. A non-conducting wire is bent into a semi-circle of radius R and a

+ +
charge + Q is uniformly distributed over it as shown in the figure. +
+Q +
V  +
Find the ratio  A  of the potential (VA) to the magnitude of the A
O
 EA  B
+
+ EA, VA
electric field (EA), both evaluated at the other end A of diameter
AB that bisects the wire (as shown in the figure) +
+
(A) R +
++
(B) 2R
(C) R ln (1+ 2 )
(D) 2R ln (1+ 2 )
Space for rough work
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3. Consider the capacitor circuit shown in the figure C 2C

1
Initially only K1 is closed and after sufficiently long time, K2 is
also closed. The charge flowing through section 1 → 2 after
K2
closing the K2 is
CE
(A) − from 2 to 1
2 K1 2
E
CE
(B) − from 2 to 1
6
(C) −CE from 2 to 1
CE
(D) from 1 to 1
4
4. Consider a hypothetical condition in which charge is uniformly distributed in whole space. If net
flux passing through the surface of imaginary cone of base diameter D and slant length D is φ
then flux passing through the surface of imaginary sphere of radius D will be:
32
(A) 32φ (B) φ
3
(C) 32 3 φ (D) 2φ
5. A point positive charge q0 is placed at a point C inside the cavity in

spherical conductor as shown in figure. Find the potential at P. 2a
Kq0 Kq0
(A) (B)
2a a C
a
2kq0 3Kq0 q0
(C) (D)
a 2a a/2
 1 
here,k =  P
 4 π ∈0 
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SECTION – 2 : Comprehension type (Only One Option Correct)

This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions and
2 multiple choice questions have to be answered. Each of these questions has 4 choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
Paragraph for Question Nos. 6 to 8
Four large metallic plates of area A each are kept parallel to V K1

each other with a small separation between them, as shown in
the figure. A cell of emf V is connected across the two
outermost plates through a switch K1. The two inner plates are
similarly connected with a cell of emf 2V through a switch K2.
1 2 3 4
Initially, both switches are open and the plates, starting from left
to right (i.e., number 1 to 4) are given charges Q, 2Q, −2Q, −Q
respectively. Now answer the following questions.
d d 2d
2V K2
6. The charge appearing on the outer surface of plate -1, when switches K1, K2 are open
(A) zero (B) Q
(C) −Q (D) −3Q
7. If K1 is closed and K2 is open, the charge appearing on the right surface of plate-2 is
Q  ε0 A  V  ε A  V 3Q
(A) +  (B)  0  +
2  d 4  d 4 2
ε AV Q 3Q
(C)  0  − (D)
 d 4 2 2
8. If both switches are closed, the charge appearing on the plate 4 is

ε A ε AV
(A)  0  V (B) Q + 0  
 d  d 2
ε0 A  V   ε A  V 
(C) Q −   (D)  0   
d 2  d  3 
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An uncharged spherical conductor of radius R centered

at the origin has a cavity of some arbitrary shape carved
out of it as shown in figure. Some where within the cavity
is a charge ‘q’ lies as shown in figure. O
r1 P
r r2
q
9. The field at P outside the sphere due to induced charge on the sphere is
Kqr1 r r 
(A) 3
(B) Kq  13 + 23 
r1  r1 r2 
r r   r r 
(C) Kq  13 − 23  (D) Kq  − 13 + 23 
r
1 r2   1r r2 
10. The potential at P due to induced charge is

1 1 1 1
(A) Kq  −  (B) Kq  + 
 r1 r2   r1 r2 
 1 1 Kq
(C) Kq  − +  (D)
 r1 r2  r1
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SECTION – 3: (Only Integer Value Correct Type)

This section contains 2 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
11. Conducting shell of radius R carrying charge Q, another 3R

charge Q is placed at 3R distance from centre of shell. If
11 KQ R
the potential at point P due to charge on shell is ,
3n R
O P
Then the value of n is Q
R/2
12. A charge +Q is located somewhere inside a vertical cone such

that the depth of the charge from the free surface of the cone is
H
H. It is found that the flux associated with the cone with the
+Q
3Q
curved surface is . If the charge is raised vertically through
5ε0
a height 2H, the flux associated with the cone with the curved
ηQ
surface is . What should be the value of η?
20ε0
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PART II : CHEMISTRY
SECTION – 1 : (Only One Option Correct Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1.
Monochlorination
 → ( X ) 
Mg
Ether
→ ( Y ) 
HOCH2 CH2 C ≡ CH
3.5 gm
→ ( Z ) + salt
70 gm
The number of moles of (Z) produced would be (assuming the yield to be 100%)?
(A) 1 (B) 0.01
(C) 0.1 (D) 10 mol
Cl MgCl
Monochlorination
 → Mg

Ether
→ HOCH2 CH2 C ≡ CH
 →
1 mol ( X) (Y) 0.1 mol
1 mol 1 mol (Z)
2. Which is the major product obtained in the following reaction ?

CH3 OH
H SO
CH3 C CH CH3 
2
∆
4

→
CH3
(A) (CH3 )2 C = C(CH3 )2 (B) (CH3 )3 C = CH = CH2
(C) (CH3 )2 C = CHCH3 (D) (CH3 )2 C = CHCH2 CH3
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3. In the following sequence of reaction

CH3
Ph H alc. KOH Br2 /CCl4
E2
→ A  →B
Ph Br
CH3
The product (B) is:
CH3 CH3
Ph Br Ph Br
(A) (B)
Ph Br Br Ph
CH3 CH3
Ph Ph
Ph Br Br Ph
(C) (D)
H3C Br H3C Br
CH3 CH3
OH
4. OH (i) PhSO2Cl(1 eqv.), Py

(ii) H3O+
→
The major product formed is:

OH
OH
(A) (B)
(C) (D) None of these
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5. Which one of the following will most readily be dehydrated in acidic condition?
O OH OH
(A) (B)
O O
(C) (D)
OH OH
Paragraph for Questions 6 to 8
Generally Arylhalides do not react with most nucleophiles under ordinary conditions. But under highly
Θ
forcing conditions they do react. Eg. Bromo Benzene reacts with very powerful base N H2 in liquid
ammonia.
Br NH2
Θ -330 C
+ K + N H2 + KBr
NH3
Mechanism:
Br Br NH2
- NH3 - Br- NH2
H
NH2
NH3
NH2
NH2 +
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From the above mechanism it is known that first elimination of HBr takes place to give Benzyne and then
addition of ammonia takes place to give the product. Hence this type of reaction is called an Elimination
addition reaction.
Cl
+ −
K N H2
6. Product In this reaction the product is, Here * indicates the carbon
NH 3
14
labeled with C isotope.
NH2
(A) (B)
NH2
(C) Equimolar mixture of (A) and (B) (D) No reaction takes place
7. CF3
Cl
NaNH2
Major Product Here the product is:
NH 3
CF 3 CF3
NH2
(A) (B)
Only
Only
NH2
CF 3
(C) Equimolar mixture of (A) and (B) (D)
NH 2
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CH3
Br
8. NaNH2
Product
CH3 NH3
Here the product is:

CH3 CH3
NH2
(A) Only (B)
CH3 CH3
NH2
(C) Equimolar mixture of (A) and (B) (D) No reaction
Paragraph for Questions 9 to 10
Alcohols can be prepared by the acid catalysed hydration of alkenes. One complication with alkene
hydration is the occurrence of rearrangements. However alcohols can be prepared from alkenes by
oxymercuration-demercuration and hydroboration-oxidation reactions.
9
H2 O/H2SO4
 → A
(Major product )
The product (A) is:
OH
(A) (B)
OH
OH
(C) OH (D)
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10. In the following reaction
() 3
I BH − THF
→
(II) H O /OH−
B
2 2 (Pr oduct )
The product (B) is:
(A) (B)
OH
OH
(C) (D)
OH
OH
(both inclusive).
11.
( excess) → ( x ) 
( excess ) → ( y )unstable 
NBS KOH/H2 O ∆
 → z.
2
The sp -hybridised carbon atoms present in one molecule of the end product z (keto form) is:
12. H H
Lucas reagent Fractional
Ph CH3  → m 
distillation
→n
( all possible compounds )
CH3 OH
(optically pure)
Then the value of n is
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PART III : MATHEMATICS

SECTION – 1 : (Only One Options Correct Type)
This section contains 5 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
1. A function f : R → R satisfying the following properties

(i) f(–x) = –f(x) (ii) f(x + 1) = f(x) + 1 ∀ x ∈ R
2
(iii) f(1/x) = f(x) / x ∀ x ∈ R – {0}, if f(3) = 3, then f(4) is equal to
(A) 2 (B) 4
(C) 5 (D) 13
2. The range of the function f : R → R, f (x) =

( x 2 + 1 − 3x ) is
x2 + 1 + x
(A) (0, ∞) (B) (–1, ∞)
(C) (–∞, –1) (D) none of these
3. If f : R → R is a function satisfying the property f(2x + 3) + f(2x + 7) = 2, ∀ x ∈ R, then the period

of f(x) is
(A) 3 (B) 5
(C) 8 (D) 11
1 3
4. If fractional part of
2
and x for some x ∈ ( 2, 3 ) are equal then the value of x –
4
is
x x
(A) 3 (B) 5
(C) 7 (D) 0
1 1 –1
5. If f(x) = + and g(x) = sin (2|x|), then f(x) = g(x) has
|| x | −2 | || x | −3 |
(A) no solution (B) less than 2 solutions
(C) atleast 1 solution (D) none of these
26513942

+
Let x ∈ R such that 3[x], 6{x}, 2x form a G.P., where [.] denotes the greatest integer function and {.}
denotes the fractional part function.
6. Common ratio of the G.P. is

1
(A) (B) 1
2
4
(C) (D) 2
3
7. The value of x is
3 9
(A) (B)
2 2
(C) 2 (D) 2
8. Sum of the terms of the G.P. is

13 17
(A) (B)
2 2
(C) 9 (D) 5
If f: R → R and f(x) = g(x) + h(x) where g(x) is a polynomial and h(x) is a continuous and differentiable
bounded function on both sides, then f(x) is onto if g(x) is of odd degree and f(x) is into if g(x) is of even
degree. To check whether f(x) is one-one we need to differentiate f(x). If f′(x) changes sign in domain of f
then f is many-one else one-one.
3 5 2n + 1 –1
9. f: R → R and f(x) = a1x + a3x + a5x + ... + a2n + 1x – cot x where 0 < a1 < a3 < ... < a2n + 1,
then the function f(x) is
(A) one-one into (B) many-one onto
(C) one-one onto (D) many-one into
x ( x 4 + 1) ( x + 1) + x 4 + 2
10. f: R → R and f(x) = , then f(x) is
x2 + x + 1
(A) one-one into (B) many-one onto
(C) one-one onto (D) many-one into
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(both inclusive).
11. A function f: R → R satisfies sinx cosy (f(2x + 2y) – f(2x – 2y)) = cosx.siny(f(2x + 2y) + f(2x – 2y)).
1
If f′(0) = , then the value of 4f″(x) + f(x) is ____________
2
12. The number of solutions of the equation tan−1 | x | = (x 2 + 1)2 − 4x 2 is ______
26513942

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(Batches: SANKALP – 921 Lot)

IIT – JEE, 2021 Paper Code

B. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

1. Charge Q is distributed on a small hollow conducting sphere

2. A non-conducting wire is bent into a semi-circle of radius R and a

Space for rough work

3. Consider the capacitor circuit shown in the figure C 2C

5. A point positive charge q0 is placed at a point C inside the cavity in

Space for rough work

SECTION – 2 : Comprehension type (Only One Option Correct)

Paragraph for Question Nos. 6 to 8

Four large metallic plates of area A each are kept parallel to V K1

8. If both switches are closed, the charge appearing on the plate 4 is

Space for rough work

Paragraph for Question Nos. 9 to 10

An uncharged spherical conductor of radius R centered

10. The potential at P due to induced charge is

Space for rough work

SECTION – 3: (Only Integer Value Correct Type)

11. Conducting shell of radius R carrying charge Q, another 3R

12. A charge +Q is located somewhere inside a vertical cone such

Space for rough work

2. Which is the major product obtained in the following reaction ?

Space for rough work

3. In the following sequence of reaction

4. OH (i) PhSO2Cl(1 eqv.), Py

The major product formed is:

(C) (D) None of these

Space for rough work

SECTION – 2 : Comprehension type (Only One Option Correct)

Paragraph for Questions 6 to 8

Space for rough work

(C) Equimolar mixture of (A) and (B) (D)

Space for rough work

Here the product is:

Paragraph for Questions 9 to 10

Space for rough work

10. In the following reaction

The product (B) is:

SECTION – 3: (Only Integer Value Correct Type)

Space for rough work

PART III : MATHEMATICS

1. A function f : R → R satisfying the following properties

2. The range of the function f : R → R, f (x) =

3. If f : R → R is a function satisfying the property f(2x + 3) + f(2x + 7) = 2, ∀ x ∈ R, then the period

Space for rough work

SECTION – 2 : Comprehension type (Only One Option Correct)

Paragraph for Question Nos. 6 to 8

6. Common ratio of the G.P. is

8. Sum of the terms of the G.P. is

Paragraph for Question Nos. 9 to 10

Space for rough work

SECTION – 3: (Only Integer Value Correct Type)

12. The number of solutions of the equation tan−1 | x | = (x 2 + 1)2 − 4x 2 is ______

Space for rough work

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